JP2018174712A - Cheese-like processed food having spinnability - Google Patents

Cheese-like processed food having spinnability Download PDF

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JP2018174712A
JP2018174712A JP2017073710A JP2017073710A JP2018174712A JP 2018174712 A JP2018174712 A JP 2018174712A JP 2017073710 A JP2017073710 A JP 2017073710A JP 2017073710 A JP2017073710 A JP 2017073710A JP 2018174712 A JP2018174712 A JP 2018174712A
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JP6190556B1 (en
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祐貴 武藤
Yuki Muto
祐貴 武藤
敦則 熊西
Atsunori Kumanishi
敦則 熊西
山本 浩志
Hiroshi Yamamoto
浩志 山本
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Ueda Oils and Fats Manufacturing Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a cheese-like processed food having a shape-retaining property and a texture peculiar to cheese in spite of substantially containing no milk protein, having processability such as cutting, machining and the like, and exhibiting excellent meltability and spinnability when heated, and to provide a cheese-like processed food containing no raw materials including milk constituents, having a possibility of causing food allergy.SOLUTION: A processed food has an emulsion structure where specific processed starch, oils and fats and water are contained and the periphery of countless finely divided oil droplet particles is covered with the starch swollen by the water. A cheese-like processed food has improved stability of emulsion structure by imparting specific physical properties to the fats and oils constituting the processed food, exhibits excellent meltability by heating while maintaining an excellent shape-retaining property at room temperature, and has a good appearance with a glossy surface.SELECTED DRAWING: None

Description

本発明は加熱時にチーズ様の曳糸性を有する実質的に乳タンパク質を含有しない加工食品に関するものである。 The present invention relates to a substantially milk protein-free processed food which has cheese-like spinnability when heated.

チーズは乳及び/または乳から得られる原料から造られている乳製品の一つであり、牛、水牛、山羊、羊等から得られる乳、中でも牛乳が最もよく使用されている。日本においてチーズとは法令上ナチュラルチーズ、プロセスチーズであり、チーズの文言が入るものとしてチーズフードがあるが、いずれも乳が成分として含まれており、製造方法や成分及びその量に厳格な制約がある。 Cheese is one of the dairy products produced from milk and / or raw materials obtained from milk, and milk obtained from cows, buffalo, goats, sheep, etc., among which milk is most commonly used. In Japan, cheese is legally natural cheese and processed cheese, and there is cheese food as a word that contains the wording of cheese, but all contain milk as an ingredient, and strict restrictions on the production method, ingredients, and their amount There is.

チーズの需要は年々増加しており、そのものを食するだけでなく様々な食品に使用され、調理には欠かせない原材料として定着している。使用する際の選択基準において、チーズの独特な風味の重要性はさることながら、硬さや弾力性、固形、半固形、流動状等の形状や切断、粉砕のし易さ、加熱時の溶け具合や焼き色等、用途が広がるほど種々要求される物性が多岐にわたっている。中でも加熱時に適度に溶けて、独特な粘性と曳糸性を持つというチーズ独特の性質が食する時の見た目と食感の点で好ましいものとしてとらえられている。これらの求められる性質に十分に対応するにはナチュラルチーズでは限界があるので、プロセスチーズやチーズフード、さらにはチーズに加えるための様々な食品原料や食品添加物の使用が検討され、チーズ風味食品と称するものが提案されている The demand for cheese is increasing year by year, and it is used not only for eating itself but also for various foods, and it has been established as an essential raw material for cooking. In terms of selection criteria when using it, the importance of the unique flavor of cheese is much more than hardness, elasticity, solid, semi-solid, flow-like shape or shape, cutting, easiness of crushing, degree of melting when heated There are a wide variety of required physical properties such as heat and color, as the usage is expanded. Among other things, it is considered to be desirable in terms of appearance and texture when eaten, as it has the unique properties of cheese that melts moderately when heated and has unique viscosity and spinnability. Because natural cheeses have limitations in meeting these required properties, the use of processed cheeses and cheese foods, as well as various food ingredients and food additives to be added to cheeses, is considered, cheese-flavored foods What is called has been proposed

チーズ特有の曳糸性という物性は調理において食感と見た目で非常に魅力的であるが、この物性を発現させるにはたとえ少量であってもチーズを加えるか、乳タンパク質の代わりとなるタンパク質を利用する必要があった。一方、近年、食物アレルギーを持つ人への配慮も社会的使命の1つであり、アレルギーの心配なく食事を楽しめるようにするには、アレルギーの原因となる乳タンパク質あるいは更に拡大してタンパク質を含有していないにもかかわらず、チーズ様の風味や食感を味わうことができるような食品を提供してほしいとの要望が国内外で高まっている。 The spiny properties of cheese are very attractive in terms of texture and appearance in cooking, but cheese can be added, or even a small amount of protein, to express this property It was necessary to use. On the other hand, in recent years, consideration for people with food allergies is one of the social missions, and in order to be able to enjoy meals without concern about the allergies, milk proteins that cause allergies or proteins that are further expanded contain more. In spite of not having done it, the demand for providing food which can taste the taste and texture of cheese-like is increasing at home and abroad.

タンパク質を低減しつつ、曳糸性を有するものとして特許文献1に増粘剤と酸処理デンプン、パーム油中融点画分、トータルミルクプロテイン等のタンパク質の使用が提案されている。タンパク質含量が10重量%以下である糸曳き性チーズ食品において、最もタンパク質含量の低いものとして本文中の実施例には2.0重量%の配合例しか記載されておらず、タンパク質を含有していない糸曳き性チーズ食品の品質の評価はされていない。また、特許文献2には馬鈴薯由来のデキストリンとカラギナン等の増粘多糖類、アラビアガム等の乳化剤を構成成分とし、実質的にタンパク質を含まないものが提示されているが、曳糸性を持ち合わせていない。チーズの多岐にわたる特性を発揮するには乳タンパク質が重要な役割を果たしており、乳タンパク質の機能を代替できるタンパク質も一切使用しないでチーズに期待される特性を全て満足させることは非常に困難であった。 Patent Document 1 proposes the use of a thickener and a protein such as acid-treated starch, a melting point fraction in palm oil, and total milk protein as having spinnability while reducing protein. In a stringy cheese food having a protein content of 10% by weight or less, only the 2.0% by weight formulation example is described in the examples in the text as the one with the lowest protein content and contains protein There is no assessment of the quality of a stringy cheese food. In addition, Patent Document 2 discloses dextrin derived from potato, thickening polysaccharide such as carrageenan, and emulsifier such as gum arabic as components and substantially contains no protein, but it has spinnability. Not. Milk protein plays an important role in exerting various properties of cheese, and it is very difficult to satisfy all the expected properties of cheese without using any protein that can replace the function of milk protein. The

特開2015−188387JP-A-2015-188387 特開2010−142181Unexamined-Japanese-Patent No. 2010-142181

本発明は実質的に乳タンパク質を含有しないにもかかわらず、チーズ特有の保形性及び食感を有し、切断、裁断、切削等の加工適性を持ち、加熱時には良好な溶融性と曳糸性を示すチーズ様加工食品を提供することを目的とする。更には乳成分をはじめとする食物アレルギーを引き起こす可能性のある原材料やタンパク質を含有しないチーズ様加工食品を提供することである。 Although the present invention contains substantially no milk protein, it has the shape-retaining property and texture unique to cheese, has processing suitability for cutting, cutting, cutting, etc., and has good meltability and string when heated. It aims at providing a cheese-like processed food that exhibits Another object of the present invention is to provide a cheese-like processed food which does not contain raw materials or proteins which may cause food allergy including milk components.

本発明者は特定の加工デンプンの組み合わせとすること、及び油脂と水を含有させ、微細化された無数の油滴粒子の周りを水により膨潤したデンプンが覆う乳化構造を有する加工食品とすることにより前記課題を解決できることを見出し、本発明を完成させるに至った。更には該食品の構成成分である油脂を、特定の物性を持つ油脂とすることで乳化構造の安定性を高め、常温で良好な保形性を保持しつつ加熱により良好な溶融性が見られ、表面に艶のある見栄えの良いチーズ様加工食品としたのである。 The inventor of the present invention is a combination of a specific modified starch, and a processed food having an emulsified structure in which fat and water and water are contained, and starch swollen by water is covered around innumerable oil droplet particles that have been refined It has been found that the problem can be solved by the present invention, and the present invention has been completed. Furthermore, the stability of the emulsified structure is enhanced by making the fats and oils that are the constituent components of the food into fats and oils having specific physical properties, and good meltability is observed by heating while maintaining good shape retention at normal temperature. It was made to be a cheese-like processed food with a glossy appearance on the surface.

すなわち本発明は、
(1)乳タンパク質含量が0.1質量%以下であって、酸化デンプン、ヒドロキシプロピルデンプン、上昇融点が30℃以上の油脂及び水を含有し、酸化デンプン総量中のアミロース含量が0.1〜23質量%で、実質的に乳タンパク質を含有せずとも加熱時にチーズ様の曳糸性を有するチーズ様加工食品、
(2)タンパク質含量が0.1質量%以下であって、実質的にタンパク質を含有せずとも加熱時にチーズ様の曳糸性を有する(1)に記載のチーズ様加工食品、
(3)酸化デンプンとヒドロキシプロピルデンプンの含有比が質量比として15:1〜2:1である(1)または(2)に記載のチーズ様加工食品、
(4)油脂のSFCが10℃で50〜95%、20℃で40〜85%である(1)〜(3)のいずれかに記載のチーズ様加工食品、
(5)実質的に乳由来原料を含有しない(1)〜(4)のいずれかに記載のチーズ様加工食品、
(6)形状がブロック状、スライス状、サイノメ状、短冊状、シュレッド状、粉状である(1)〜(5)のいずれかに記載のチーズ様加工食品を提供するものである。
That is, the present invention
(1) The content of milk protein is 0.1% by mass or less and contains oxidized starch, hydroxypropyl starch, fats and oils with an elevated melting point of 30 ° C. or higher, and water, and the amylose content in the total oxidized starch is 0.1 to 0.1 A cheese-like processed food which is 23% by mass and which has a cheese-like spinnability on heating without substantially containing milk protein,
(2) The cheese-like processed food according to (1), which has a protein content of 0.1% by mass or less and which has a cheese-like spinnability on heating without substantially containing protein.
(3) The processed cheese-like food according to (1) or (2), wherein the content ratio of oxidized starch to hydroxypropyl starch is 15: 1 to 2: 1 as a mass ratio.
(4) The cheese-like processed food according to any one of (1) to (3), wherein the SFC of fats and oils is 50 to 95% at 10 ° C and 40 to 85% at 20 ° C.
(5) The cheese-like processed food according to any one of (1) to (4), which contains substantially no milk-derived material.
(6) The cheese-like processed food according to any one of (1) to (5), which has a block shape, a slice shape, a sinome shape, a strip shape, a shred shape, or a powder shape.

本発明の曳糸性チーズ様加工食品は、常温ではブロック状のものをサイノメ状、短冊状等への形状に自在にカットでき、シュレッド状への裁断や粉状への粉砕も可能となる等形状の加工適性に優れ、それらをオーブンやトースター等の調理器具内で加熱すると溶融して曳糸性を発現するといったチーズに類似した特有の物性を持つことに加えて、本発明の構成成分は、ほぼ無味無臭なため様々な呈味成分や香料を含有させることでチーズ風味にとどまらず、バター風味やチョコレート風味、マヨネーズ風味等任意の風味を付けることでき、使用できる調理食品の範囲が格段に広がる。しかも、本発明品は実質的に乳タンパク質や乳成分を含有していないので食物アレルギーを心配する人に配慮した加工食品であり、加える風味成分のアレルゲンに留意することで食物が原因となるアレルギーを引き起こさない加工食品とすることも可能となる。 The spiny cheese-like processed food of the present invention can be freely cut into a block shape into a sinome shape, a strip shape or the like at normal temperature, and it becomes possible to cut it into shreds or pulverize it into a powder shape etc. In addition to having unique physical properties similar to cheese, such as being excellent in shape processing suitability and melting when heated in a cooker such as an oven or toaster to develop spinnability, the components of the present invention Because it is almost tasteless and odorless, it contains not only cheese flavor but also butter flavor, chocolate flavor, mayonnaise flavor and other flavors by containing various flavoring ingredients and flavors, and the range of usable cooked foods is remarkable. spread. Moreover, the product of the present invention is a processed food which is considered to be a person who is concerned about food allergy because it contains substantially no milk protein and milk component, and food allergy is caused by paying attention to the allergen of the flavor component to be added. It is also possible to make processed food that does not cause

本発明の曳糸性チーズ様加工食品は、乳タンパク質含量が0.1質量%以下であって、酸化デンプンとヒドロキシプロピルデンプン、上昇融点30℃以上の油脂及び水を含有し、酸化デンプン総量中のアミロース含量が0.1〜23質量%で、実質的に乳タンパク質を含有せずとも加熱時に曳糸性を有するチーズ様加工食品であり、酸化デンプンを含む水相部中に油脂が分散された構造を持つ食品である。 The spiny cheese-like processed food according to the present invention has a milk protein content of 0.1% by mass or less and contains oxidized starch and hydroxypropyl starch, fats and oils with an elevated melting point of 30 ° C. or higher, and water, among the total oxidized starches. Processed cheese-like processed food having an amylose content of 0.1 to 23% by mass and having spinnability on heating substantially without containing milk protein, and fats and oils are dispersed in an aqueous phase portion containing oxidized starch It is a food with a different structure.

「実質的に」とは、タンパク質が含まれていないか、分析上、わずか痕跡程度である状態をいう。本発明においてはナチュラルチーズやプロセスチーズはもちろんのこと、脱脂粉乳やホエーパウダー等の乳タンパク質を含有する原料やあるいは大豆タンパク質や小麦タンパク質等の植物性タンパク質の使用を必要としない。 "Substantially" refers to a state in which the protein is not contained or analytically only a trace. In the present invention, it is not necessary to use natural cheese and processed cheese as well as raw materials containing milk protein such as skimmed milk powder and whey powder, or use of vegetable protein such as soybean protein and wheat protein.

本発明の構成成分であるデンプンは、化学処理を施された加工デンプンに属するものである。その加工デンプンの1つである酸化デンプンはデンプンを次亜塩素酸ナトリウムで酸化処理して得られるものであり、その酸化処理の程度はカルボキシル基量で規定することができ、カルボキシル基量が多いほど酸化処理程度が進んだことを意味する。未処理のデンプンはカルボキシル基がほぼない。起源原料としては馬鈴薯由来、タピオカ由来、コーン由来、ワキシーコーン由来、サゴヤシ由来、米由来、エンドウ由来、甘藷由来のデンプンから選ばれた1種類以上の酸化デンプンを用いることができる。本発明にはいずれの起源のデンプンであってもよいが、良好な曳糸性と加熱溶融性、成形加工適性の物性を兼ね備えるためには、用いた酸化デンプン総量中のアミロース含量を0.1〜23質量%とし、馬鈴薯由来、タピオカ由来、ワキシーコーン由来の酸化デンプンを1種類以上用いることがより好ましい。ただし、乳以外にもアレルギー疾患を心配する人を対象とする場合は、対象となるアレルゲンを有する可能性のある植物由来の加工デンプンを選択しないことが必要である。具体的には小麦由来、米由来、エンドウ由来を用いないことである。 The starch which is a component of the present invention belongs to chemically processed modified starch. Oxidized starch, which is one of the modified starches, is obtained by oxidizing starch with sodium hypochlorite, and the degree of oxidation treatment can be defined by the amount of carboxyl groups, and the amount of carboxyl groups is large. It means that the degree of oxidation processing has advanced. Untreated starch is nearly free of carboxyl groups. As the raw material, one or more types of oxidized starch selected from starch, tapioca, corn, waxy corn, sago palm, rice, pea and sweet potato derived starch can be used. The present invention may be starch of any origin, but in order to have good spinnability, heat melting property, and physical properties of molding processability, the amylose content in the total amount of oxidized starch used is 0.1. It is more preferable to use one or more types of oxidized starches derived from potato, tapioca, and waxy corn at a concentration of -23% by mass. However, when targeting people who are concerned about allergic diseases other than milk, it is necessary not to select a modified starch derived from a plant which may have the target allergen. Specifically, wheat origin, rice origin and pea origin are not used.

本発明に用いるヒドロキシプロピルデンプンはデンプンを酸化プロピレンでエーテル化して得られ、デンプンのいくつかの水酸基がヒドロキシプロピル基でエーテル化されたものである。馬鈴薯由来、タピオカ由来、コーン由来、ワキシーコーン由来、小麦由来、サゴヤシ由来、米由来、エンドウ由来、甘藷由来を起源とするデンプンから選ばれた1種類以上のヒドロキシプロピルデンプンを用いることができる。本発明にはいずれの起源のデンプンであってもよいが、タピオカ由来がより好ましい。酸化デンプン同様、アレルギー疾患を心配する人を対象とする場合は、小麦由来、米由来、エンドウ由来を用いないことである。 The hydroxypropyl starch used in the present invention is obtained by etherifying starch with propylene oxide, and is one in which some hydroxyl groups of starch are etherified with hydroxypropyl group. One or more types of hydroxypropyl starch selected from starch derived from potato, tapioca, corn, waxy corn, wheat, sago palm, rice, pea and sweet potato origin can be used. It may be starch of any origin for the present invention, but tapioca origin is more preferred. As with oxidized starch, when targeting people concerned about allergic diseases, wheat origin, rice origin and pea origin should not be used.

本発明に用いる酸化デンプン及びヒドロキシプロピルデンプンの添加量は目的とする物性に応じて適宜調整することが可能であり、例えば酸化デンプン含量を5〜50質量%、10〜40質量%、15〜35質量%とすることができる。好ましい酸化デンプン含量は15〜30質量%であり、さらに好ましくは20〜30質量%である。また、ヒドロキシプロピルデンプン含量を1〜15質量%、1〜10質量%、2〜10質量%とすることができる。ヒドロキシプロピルデンプンの好ましい含量は2〜8質量%であり、さらに好ましくは3〜7質量%である。 The addition amount of the oxidized starch and the hydroxypropyl starch used in the present invention can be appropriately adjusted according to the target physical properties, and for example, the oxidized starch content is 5 to 50% by mass, 10 to 40% by mass, 15 to 35 It can be mass%. The preferred oxidized starch content is 15 to 30% by mass, more preferably 20 to 30% by mass. In addition, the hydroxypropyl starch content can be 1 to 15% by mass, 1 to 10% by mass, and 2 to 10% by mass. The preferred content of hydroxypropyl starch is 2 to 8% by mass, more preferably 3 to 7% by mass.

本発明に用いる酸化デンプンとヒドロキシプロピルデンプンの総量は加工食品の総質量の10〜50質量%がよく、酸化デンプンに対してヒドロキシプロピルデンプンの含量を少なくし、酸化デンプンとヒドロキシプロピルデンプンの含有比を質量比として15:1〜2:1とするのがよい。好ましくは酸化デンプンとヒドロキシプロピルデンプンの総質量が本発明の加工食品中の20〜35質量%で、酸化デンプンとヒドロキシプロピルデンプンの含有比が質量比として10:1〜4:1である。 The total amount of oxidized starch and hydroxypropyl starch used in the present invention is preferably 10 to 50% by mass of the total mass of the processed food, which reduces the content of hydroxypropyl starch to oxidized starch, and the content ratio of oxidized starch and hydroxypropyl starch It is good to make 15: 1 to 2: 1 as mass ratio. Preferably, the total mass of oxidized starch and hydroxypropyl starch is 20 to 35% by mass in the processed food of the present invention, and the content ratio of oxidized starch to hydroxypropyl starch is 10: 1 to 4: 1 as a mass ratio.

酸化デンプンと名称が類似している酸処理デンプンは、デンプンを塩酸や硫酸等の酸性水溶液に浸漬し、糊化温度以下で半日ないし数日間放置した後、中和、水洗、ろ過、乾燥を行って製造される加工デンプンであり、酸化デンプンと同様に低粘度で冷却によりゲル化能が増大する性質を持っているが、タンパク質を含有せず酸処理デンプン主体で構成したチーズ様加工食品では、ピザ用ナチュラルチーズのように良好な曳糸性や加熱溶融性等の物性を兼ね備えることは困難である。 Acid-treated starch whose name is similar to oxidized starch is soaked in an acidic aqueous solution such as hydrochloric acid or sulfuric acid, left for half a day to several days below the gelatinization temperature, then neutralized, washed with water, filtered and dried. The processed starch is a low-viscosity similar to oxidized starch and has the property of increasing its gelling ability upon cooling, but in a cheese-like processed food composed of an acid-treated starch and containing no protein, It is difficult to have physical properties such as good spinnability and heat melting properties as natural cheese for pizza.

本発明に用いる油脂は食用に使用される油脂であり、上昇融点が30℃以上のものであれば特に制限はなく、パーム油、カカオ脂等の植物油脂や大豆硬化油、なたね硬化油等の植物硬化油、豚脂、牛脂等の動物油脂またはこれらの硬化油、魚油等水産動物油脂の硬化油等が例示でき、これら油脂の分別油やエステル交換油であってもよい。また、これらの油脂から選ばれた2種以上の油脂の混合油脂、さらにその分別油やエステル交換油であってもよい。より好ましい曳糸性チーズ様加工食品の物性のためには上昇融点が30℃以上で10℃のSFCが50〜95%、20℃のSFCが40〜85%である油脂とするのがよい。また、油脂添加量として本発明の加工食品に対して10〜40質量%がよく、好ましくは15〜35質量%、より好ましくは20〜30質量%である。 The fats and oils used in the present invention are fats and oils used for food, and there is no particular limitation as long as the rising point is 30 ° C. or more, and vegetable fats and oils such as palm oil and cacao butter, hydrogenated soybean oil, coconut oil and the like Examples of hydrogenated vegetable oils, animal fats and oils such as pork fat and beef tallow, and hydrogenated oils thereof, and hydrogenated oils of fish and oil such as fish oil may be exemplified, and fractionated oils and transesterified oils of these fats and oils may be used. Moreover, the mixed oil of 2 or more types of fats and oils selected from these fats and oils, and also the fractionated oil and transesterified oil may be sufficient. For physical properties of a more preferable spiny cheese-like processed food, it is preferable to use an oil and fat having a 50 to 95% SFC with a 10 ° C rising melting point and a 40 to 85% SFC at 20 ° C. Moreover, 10-40 mass% is good with respect to the processed foodstuffs of this invention as fats and oils addition amount, Preferably it is 15-35 mass%, More preferably, it is 20-30 mass%.

本発明の曳糸性チーズ様加工食品の含有する水分量は、含有させる水溶性成分を溶解することができる量であればよく、目的とする加工食品の物性に応じて適宜調整すればよい。水溶性成分の一部が不溶となれば曳糸性効果が十分に発揮できず、またザラついた食感となり好ましくない。含有する水分量が多すぎると流動物となってしまい、切断、裁断等の加工ができず、加熱時の曳糸性が非常に弱いものとなる。水分量は酸化デンプンとヒドロキシプロピルデンプンを合わせた質量の1.4〜1.8倍とすることが好ましく、その他に水溶性成分を含有させる場合にはそのものらを溶解できる水分量を余分に加えるとよい。 The water content contained in the spiny cheese-like processed food of the present invention may be an amount capable of dissolving the water-soluble component to be contained, and may be appropriately adjusted according to the physical properties of the target processed food. If part of the water-soluble component is insoluble, the spinous effect can not be sufficiently exhibited, and the texture becomes rough, which is not preferable. If the amount of water contained is too large, it becomes a fluid, and processing such as cutting and cutting can not be performed, and the spinnability at the time of heating becomes very weak. The amount of water is preferably 1.4 to 1.8 times the total mass of oxidized starch and hydroxypropyl starch, and in the case of containing other water-soluble components, an extra amount of water capable of dissolving itself is added It is good.

本発明の曳糸性チーズ様加工食品には発明の効果に影響を与えない範囲内において、呈味成分や風味成分を加えることができる。例えば、塩や砂糖等の糖類や甘味料及び化学調味料、ココアパウダーやコーヒーパウダー、イチゴやマスカット等の各種果汁、チーズ香料やバター香料等の各種香料等が挙げられる。このような呈味成分や風味成分を加えることでチーズ様の食感や加熱時の曳糸性を持ちつつ、チーズ風味はもちろんのこと多岐にわたる風味を付与した加工食品とすることができる。また、着色料や日持ち向上剤も使用することができる。アレルギーに配慮した加工食品とするには、アレルゲンを含有しない原料を選択すればよい。 Taste ingredients and flavor ingredients can be added to the spiny cheese-like processed food of the present invention as long as the effects of the invention are not affected. For example, saccharides such as salt and sugar, sweeteners and chemical seasonings, cocoa powder and coffee powder, various fruit juices such as strawberries and muscat, various flavors such as cheese flavor and butter flavor, and the like can be mentioned. By adding such taste and taste components, it is possible to obtain processed food having a cheese-like texture and spinnability at the time of heating, as well as cheese flavor and various other flavors. Also, coloring agents and preservatives can be used. In order to make processed food in consideration of allergy, it is sufficient to select a raw material that does not contain an allergen.

さらに、本発明の加工食品の物性に変化を加えるために増粘安定剤を使用してもよく、例えばグアーガム、キサンタンガム、アラビアガム、カラギナン、ローカストビーンガム、タマリンドシードガム、タラガム、デキストリン、ペクチン、寒天、セルロース、CMC、食物繊維、ポリアクリル酸ナトリウム等が挙げられる。また、本発明の加工食品中の油脂の分散を良くするために乳化剤を使用することも可能である。例えば、レシチンやグリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、プロピレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル、酢酸モノグリセリド、酒石酸モノグリセリド、コハク酸モノグリセリド、クエン酸モノグリセリド、ジアセチル酒石酸モノグリセリド、乳酸モノグリセリド、ポリオキシエチレンソルビタン脂肪酸エステル等が挙げられる。いずれも発明の効果に影響をきたさない範囲内で使用ができる。 Furthermore, thickening stabilizers may be used to alter the physical properties of the processed food of the invention, such as guar gum, xanthan gum, gum arabic, carrageenan, locust bean gum, tamarind seed gum, cod gum, dextrin, pectin, Agar, cellulose, CMC, dietary fiber, sodium polyacrylate and the like can be mentioned. It is also possible to use an emulsifying agent to improve the dispersion of the fats and oils in the processed food of the present invention. For example, lecithin and glycerin fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, acetic acid monoglyceride, tartaric acid monoglyceride, succinic acid monoglyceride, citric acid monoglyceride, diacetyl tartaric acid monoglyceride, lactic acid monoglyceride, polyoxy acid Ethylene sorbitan fatty acid ester etc. are mentioned. Both can be used within the range which does not affect the effect of the invention.

本発明のチーズ様加工食品の製造としては、酸化デンプン、ヒドロキシプロピルデンプン、水を主原料として、必要に応じて食塩、風味成分、酸味料、乳化剤、日持ち向上剤等の副原料を混合溶解した水相部に油脂を添加し、混合乳化させる。乳化の温度は乳化の効率と殺菌の効果が発揮できることから80℃以上、望ましくは85〜95℃で混合物の粘度を下げた状態で行うのがよい。 In the production of the cheese-like processed food of the present invention, secondary materials such as sodium chloride, flavor components, acidulants, emulsifiers, and shelf life improvers are mixed and dissolved as necessary with oxidized starch, hydroxypropyl starch and water as main ingredients. Add fats and oils to the water phase and mix and emulsify. The temperature of emulsification is preferably 80 ° C. or more, preferably 85 to 95 ° C., in a state where the viscosity of the mixture is lowered, because the efficiency of emulsification and the effect of sterilization can be exhibited.

混合物の乳化機としては、ステファン型乳化機、表面掻取型乳化機、ケトル型乳化機またはスパイラル型乳化機等、通常のプロセスチーズの乳化に用いられる乳化機を使用することができる。また、乳化混合物の粘度が低い場合にはホモミキサーやプロペラミキサーを具備した混合乳化タンクであってもよい。加熱や温度の保持のためにジャケットタイプがよく、この時に直接蒸気の通気が可能な加圧耐用容器であれば短時間で加熱が行えるためより望ましい。乳化物の冷却方法としては、そのまま容器に移し替えて冷蔵庫等で保管することや容器をクーリングトンネルに通して連続式に行う方法が挙げられ、パーフェクターやオンレーター等の掻取式連続熱交換装置での冷却であってもよい。 As an emulsifying machine for the mixture, an emulsifying machine used for emulsifying ordinary process cheese, such as a Stefan-type emulsifying machine, a surface scratching-type emulsifying machine, a kettle emulsifying machine or a spiral emulsifying machine can be used. When the viscosity of the emulsified mixture is low, it may be a mixed emulsification tank equipped with a homomixer or a propeller mixer. A jacket type is preferable for heating and holding the temperature, and at this time, if it is a pressurized durable container capable of direct aeration of steam, it is more desirable because heating can be performed in a short time. As a method of cooling the emulsion, there is a method of transferring the container as it is and storing it in a refrigerator or the like, or a method of continuously carrying the container by passing it through a cooling tunnel. It may be cooling in the device.

(パーム核極度硬化油の調製)
1リットルのオートクレーブにパーム核油(ヨウ素価18.0)100質量部、ニッケル触媒(堺化学工業株式会社製 SO−750R)0.3質量部を添加し、水素圧0.2MPa、回転数750rpmで攪拌しながら、180℃で水素添加反応を行い、油脂のヨウ素価が0.5に低下するまで反応を続けた。その後、活性白土を対油0.3質量部添加して脱色、脱臭をして表1に示す分析値を有する油脂1を得た。
(Preparation of palm kernel extreme curing oil)
100 parts by mass of palm kernel oil (iodine value 18.0) and 0.3 parts by mass of nickel catalyst (SO-750R manufactured by Sakai Chemical Industry Co., Ltd.) are added to a 1 liter autoclave, hydrogen pressure 0.2 MPa, rotation speed 750 rpm While stirring with stirring, the hydrogenation reaction was performed at 180 ° C., and the reaction was continued until the iodine value of the oil decreased to 0.5. Thereafter, 0.3 parts by mass of activated clay was added to oil to carry out decolorization and deodorization to obtain Fat 1 having the analysis values shown in Table 1.

(エステル交換油の調製)
パーム核極度硬化油60質量部とパームオレイン40質量部を混合した油脂に、0.2質量部のナトリウムメトキシドを加え、80℃で60分混合攪拌してランダムエステル交換反応を行い、反応後、水洗して触媒を除去した。次に脱色、脱臭して表1に示す分析値を有する油脂2を得た。
(Preparation of transesterified oil)
0.2 parts by mass of sodium methoxide is added to a mixture of 60 parts by mass of palm kernel extreme curing oil and 40 parts by mass of palm olein, mixed and stirred at 80 ° C. for 60 minutes for random transesterification, and after reaction The catalyst was removed by washing with water. Next, it was decolorized and deodorized to obtain a fat and oil 2 having the analysis values shown in Table 1.

(その他油脂)
その他油脂として、パーム油(ヨウ素価51.2、油脂3)、パームステアリン(ヨウ素価31.5、油脂4)、大豆油(ヨウ素価130.8、油脂5)、パームオレイン(ヨウ素価57.5、油脂6)、パーム核極度硬化油70質量部とパームオレイン30質量部を混合した油脂(ヨウ素価17.6、油脂7)、バターから抽出したバターオイル(ヨウ素価31.7、油脂8)を用いて実施例、比較例を行った。実施例、比較例に使用した油脂1〜8の詳細な情報は表1に示した。
(Other oils and fats)
Other fats and oils include palm oil (iodine value 51.2, fat and oil 3), palm stearin (iodine value 31.5, fat and oil 4), soybean oil (iodine value 130.8, fat and oil 5), palm olein (iodine value 57. 5. Fats and oils 6), Fats and oils obtained by mixing 70 parts by mass of extremely hardened palm kernel oil and 30 parts by mass of palm olein (iodine number 17.6, fats and oils 7), butter oil extracted from butter (iodine number 31.7, fats and oils 8 Examples and comparative examples were performed using. Detailed information of the oils and fats 1 to 8 used in Examples and Comparative Examples is shown in Table 1.

実施例、比較例に使用した酸化デンプン及びヒドロキシプロピルデンプン、酸処理デンプン、ヒドロキシプロピルリン酸架橋デンプン、未加工デンプンの由来原料は以下の通りである。酸化デンプン1:馬鈴薯、酸化デンプン2:サゴヤシ、酸化デンプン3:ワキシーコーン、酸化デンプン4:タピオカ、酸化デンプン5:コーン、ヒドロキシプロピルデンプン1:タピオカ、ヒドロキシプロピルデンプン2:馬鈴薯、酸処理デンプン:サゴヤシ、ヒドロキシプロピリン酸架橋デンプン:コーン、未加工デンプン:サゴヤシ。
本発明に使用した酸化デンプンのアミロース含量及びカルボキシル基量は由来原料ごとに分類して表2に示し、表3〜表5に示した酸化デンプンの中のアミロース含量は表2の値をもとに算出した。
The origins of oxidized starch and hydroxypropyl starch, acid-treated starch, hydroxypropyl phosphate cross-linked starch, and raw starch used in Examples and Comparative Examples are as follows. Oxidized starch 1: potato, oxidized starch 2: sago palm, oxidized starch 3: waxed corn, oxidized starch 4: tapioca, oxidized starch 5: corn, hydroxypropyl starch 1: tapioca, hydroxypropyl starch 2: potato, acid treated starch: sago palm , Hydroxypropyric acid crosslinked starch: corn, raw starch: sago palm.
The amylose content and carboxyl group content of the oxidized starch used in the present invention are classified according to the origin and shown in Table 2, and the amylose content in the oxidized starch shown in Tables 3 to 5 is based on the values in Table 2. Calculated to

以下に実施例を挙げ、本発明をさらに詳しく説明するが、本発明は、これらに限定されるものではない。尚、本発明の実施例における評価方法は下記の通りである。上昇融点については、基準油脂分析試験法2.2.4.2−1996にて、SFCについては、基準油脂分析試験法2.2.9−2013固体脂含量(NMR法)にて分析を行った。 EXAMPLES The present invention will be described in more detail by way of the following examples, but the present invention is not limited thereto. In addition, the evaluation method in the Example of this invention is as follows. The rising melting point is analyzed by the standard fat and oil analysis test method 2.2.4.2-1996, and the SFC is analyzed by the standard fat and oil analysis test method 2.2.9-2013 solid fat content (NMR method) The

Figure 2018174712
Figure 2018174712

Figure 2018174712
Figure 2018174712

曳糸性チーズ様加工食品の品質評価
(曳糸性)
曳糸性の評価方法は、シュレッド状(縦35mm×横5mm×厚さ2mm)に成形した曳糸性チーズ様加工食品10g分をアルミ箔の上に乗せ、100V、810Wのオーブンで3分間加熱した後、測定装置として、株式会社山電製「クリープメータ レオナー(RE−3305S)」、測定プランジャーとして、同社規定の円盤型プランジャーNo.37(直径11.3mm、厚さ1mm)を使用して下記の条件で測定した。
円盤型プランジャーの先端が曳糸性チーズ様加工食品と接触するようにセットし、曳糸性チーズ様加工食品を10mm/secのテーブルスピードで下方向に移動させ、プランジャーの先端から曳糸性チーズ様加工食品が剥離した時点で移動を停止した。アルミ箔上の曳糸性チーズ様加工食品の表面とプランジャーの先端との距離を測定し、3回測定した平均を曳糸性の長さとした。プランジャーから剥離せずに装置の測定限界(77mm)に達した場合は77mm以上とした。なお曳糸性評価判定は下記に示す基準とした。
◎:60mm以上 ○:20mm以上60mm未満 ×:20mm未満
(加熱溶融性)
加熱溶融性の評価方法は以下の条件で評価した。シュレッド状(縦35mm×横5mm×厚さ2mm)に成形した曳糸性チーズ様加工食品10g分をアルミ箔の上に乗せ、100V、810Wのオーブンで加熱し、溶融性が良好なものから以下の基準にて3段階で評価した。
◎:3〜5分で溶融し、かつ程よい流動性が見られる
○:3〜5分で溶融するが、流動性は見られない
×:5分経過して加熱してもほとんど溶融しない
(成形加工適性)
成形加工適性は以下の2つの方法によって評価した。
(1) カット適性
5℃で3日間冷蔵保管した曳糸性チーズ様加工食品を室温下、ナイフで切断した時の切り易さについて以下の基準で評価した。
◎:曳糸性チーズ様加工食品がナイフに付着することなく切れ、ナイフがほとんど汚れない
○:曳糸性チーズ様加工食品がナイフに付着するが、ナイフとチーズ様食品は容易に分離する
×:曳糸性チーズ様加工食品がナイフに付着し、ナイフとチーズ様食品が容易に分離しない
(2) 硬度
直径50mm、深さ25mmのカップに曳糸性チーズ様加工食品を30g入れ、5℃で3日間冷蔵保管した。株式会社山電製「クリープメータ レオナー(RE−3305S)」に該サンプルをセットし、プランジャーNo.5(5mm×22mm)、試料台速度を5mm/secに設定し、プランジャーを挿入した時の応力(gf)を読みとった。硬度は以下の基準で評価した。
◎:1000gf以上
○:500gf以上1000gf未満
×:500gf未満
(30℃での油脂の分離)
シュレッド状(縦35mm×横5mm×厚さ2mm)に成形した曳糸性チーズ様加工食品5g分を30℃に静置させ、以下の基準で評価した。
〇:4時間経過しても曳糸性チーズ様加工食品の表面に油滴(=オイルオフ)が見られない
×:1時間以上4時間未満で曳糸性チーズ様加工食品の表面に油滴が見られる
(食感の評価)
ダイス状(縦20mm×横20mm×厚さ20mm)に成形した20℃の曳糸性チーズ様加工食品を食べた時の感触を、以下の基準で評価した。
○:チーズ特有の弾力感、粘りを感じる
×:チーズ特有の弾力感、粘りを感じない
Quality evaluation of spiny cheese-like processed food (spinability)
The method of evaluating spinnability is as follows: 10 g of spiny cheese-like processed food shaped in a shred shape (35 mm long × 5 mm wide × 2 mm thick) is placed on an aluminum foil and heated for 3 minutes in an oven of 100 V and 810 W After that, as a measuring device, use the creep meter "Creeper (RE-3305S)" made by Sanden Co., Ltd., and the disk type plunger No. 37 (diameter 11.3 mm, thickness 1 mm) specified by the company as a measurement plunger. It measured on condition of the following.
The tip of the disc-shaped plunger is set so as to be in contact with the spiny cheese-like processed food, and the spiny cheese-like processed food is moved downward at a table speed of 10 mm / sec. Movement was stopped when the processed cheese-like processed food peeled off. The distance between the surface of the thread-like cheese-like processed food on aluminum foil and the tip of the plunger was measured, and the average of three measurements was taken as the length for thread-likeness. When it reached the measurement limit (77 mm) of the device without peeling from the plunger, it was 77 mm or more. The spinnability evaluation evaluation was based on the following criteria.
:: 60 mm or more ○: 20 mm or more and less than 60 mm ×: less than 20 mm (heat melting property)
The evaluation method of heat melting property was evaluated on condition of the following. Place 10 g of a spiny cheese-like processed food shaped like shreds (35 mm long × 5 mm wide × 2 mm thick) on aluminum foil, heat in an oven at 100 V and 810 W, and have good meltability and less It evaluated in three steps on the basis of.
◎: It melts in 3 to 5 minutes, and moderate fluidity is observed ○: melts in 3 to 5 minutes, but fluidity is not observed ×: hardly melts even after heating for 5 minutes (forming Processing aptitude)
The molding processability was evaluated by the following two methods.
(1) Cutability A stringed cheese-like processed food stored refrigerated at 5 ° C. for 3 days was evaluated for ease of cutting when cut with a knife at room temperature according to the following criteria.
曳: Spinach cheese-like processed food cuts without sticking to the knife, and the knife hardly stains ○ ○: Spinach-like cheese-like processed food adheres to the knife, but the knife and the cheese-like food separate easily × : Spiny cheese-like processed food adheres to the knife, and the knife and cheese-like food do not separate easily (2) Hardness of 50 mm diameter, 25 mm deep Put 30 g of spiny cheese-like processed food in a cup, 5 ° C Stored refrigerated for 3 days. When the sample is set in “Creep meter Reoner (RE-3305S)” manufactured by Sanden Co., Ltd., plunger No. 5 (5 mm × 22 mm), sample table speed set to 5 mm / sec, and plunger inserted Stress (gf) was read. The hardness was evaluated based on the following criteria.
:: 1000 gf or more
○: 500 gf or more and less than 1000 gf
X: less than 500 gf (separation of fats and oils at 30 ° C.)
A portion of 5 g of a stringy cheese-like processed food formed into a shred shape (35 mm long × 5 mm wide × 2 mm thick) was allowed to stand at 30 ° C., and evaluated according to the following criteria.
○: No oil droplets (= oil off) are found on the surface of the spiny cheese-like processed food even after 4 hours x: Oil droplets on the surface of the spiny cheese-like processed food in 1 hour or more and less than 4 hours Can be seen (evaluation of food texture)
The feel when eating a 20 ° C. twisty cheese-like processed food formed into a die shape (20 mm long × 20 mm wide × 20 mm thick) was evaluated based on the following criteria.
○: Elasticity unique to cheese, feel sticky ×: Elasticity unique to cheese, do not feel sticky

(実施例1)ヒドロキシプロピルデンプン:タピオカ
水相部として食塩を1.5質量部、水を45.5質量部添加して昇温し、50℃に達した後、酸化デンプン1(アミロース含量:21質量%、カルボキシル基量:1.1質量%)を26.0質量部、ヒドロキシプロピルデンプン1を5.0質量部添加し、プロペラミキサー(1,300rpm)で混合攪拌して溶解させた。デンプンがしっかり膨潤糊化した後、油脂1を22.0質量部添加し乳化させ85℃まで混合攪拌した。85℃に到達後、そのままの回転数で1分間攪拌保持した。加熱乳化したチーズ様乳化物を容器に充填し、5℃の冷蔵庫で3日間冷却して曳糸性チーズ様加工食品を得た。このものについて曳糸性や加熱溶融性、成形加工適性等を評価した。
該曳糸性チーズ様加工食品のタンパク質含量は0.0質量%、酸化デンプンの中のアミロース含量は21.0質量%、酸化デンプン/ヒドロキシプロピルデンプン比は5.2、5℃における硬度は1,800gfであり、曳糸性及び810W、3分間加熱した際の加熱溶融性、成形加工適性とも良好な物性であった。品質評価結果は表3に示した。
(Example 1) Hydroxypropyl starch: 1.5 parts by mass of sodium chloride and 45.5 parts by mass of water as tapioca aqueous phase are added and heated to reach 50 ° C. Oxidized starch 1 (amylose content: 26.0 parts by mass of 21% by mass, carboxyl group content: 1.1% by mass, and 5.0 parts by mass of hydroxypropyl starch 1 were added and dissolved by mixing and stirring with a propeller mixer (1,300 rpm). After the starch was firmly swollen and gelatinized, 22.0 parts by mass of Fat 1 was added, emulsified, and mixed and stirred to 85 ° C. After reaching 85 ° C., stirring was maintained for 1 minute at the same rotational speed. The heated and emulsified cheese-like emulsion was filled in a container and cooled in a refrigerator at 5 ° C. for 3 days to obtain a twist-like cheese-like processed food. The spinnability, heat melting property, molding processability, etc. of this product were evaluated.
The protein content of the spiny cheese-like processed food is 0.0% by mass, the amylose content in oxidized starch is 21.0% by mass, the oxidized starch / hydroxypropyl starch ratio is 5.2, the hardness at 5 ° C. is 1 , 800 gf, spinnability, heat melting property when heated at 810 W for 3 minutes, and molding processability were both good physical properties. The quality evaluation results are shown in Table 3.

(実施例2) ヒドロキシプロピルデンプン:馬鈴薯
表3に示した配合により、実施例1と同様の手順で曳糸性チーズ様加工食品を製造した。実施例1と同様の評価を行ったところ、曳糸性及び加熱溶融性、成形加工適性とも良好な物性であった。品質評価結果は表3に示した。
Example 2 Hydroxypropyl Starch: Potato According to the composition shown in Table 3, a spiny cheese-like processed food was produced in the same manner as in Example 1. The same evaluation as in Example 1 was carried out, and it was found that the spinnability, the heat melting property, and the molding processability were both good physical properties. The quality evaluation results are shown in Table 3.

(実施例3〜10) 酸化デンプンの組み合わせ
表3に示した配合により、実施例1〜2において酸化デンプンの由来や、酸化デンプンの組み合わせを変えた以外は同様の手順で製造し、曳糸性チーズ様加工食品を得た。品質評価結果は表3に示した。
(Examples 3 to 10) According to the combinations shown in Table 3 according to combinations of oxidized starches, the same procedure is followed except for changing the origin of oxidized starch or the combination of oxidized starches in Examples 1 to 2, Cheese-like processed food was obtained. The quality evaluation results are shown in Table 3.

(実施例11) 酸化デンプン/ヒドロキシプロピルデンプン比:3.1
水相部として食塩を2.5質量部、クエン酸を0.15質量部、アミノ酸を0.2質量部、酵母エキスを0.15質量部、水を46.8質量部添加して昇温し、50℃に達した後、酸化デンプン1(アミロース含量:21質量%、カルボキシル基量:1.1質量%)を22.0質量部、ヒドロキシプロピルデンプン1を7.0質量部添加し、プロペラミキサー(1,300rpm)で混合攪拌して溶解させた。デンプンがしっかり膨潤糊化した後、油脂2を21.0質量部添加し、乳化させ85℃まで混合攪拌した。85℃に到達後、チーズ香料を0.2質量部添加してそのままの回転数で1分間攪拌保持した。加熱乳化したチーズ様乳化物を容器に充填し、5℃の冷蔵庫で3日間冷却して曳糸性チーズ様加工食品を得た。品質評価結果は表4に示した。
Example 11 Oxidized Starch / Hydroxypropyl Starch Ratio: 3.1
As the aqueous phase, 2.5 parts by mass of sodium chloride, 0.15 parts by mass of citric acid, 0.2 parts by mass of amino acid, 0.15 parts by mass of yeast extract, 46.8 parts by mass of water are added to raise the temperature And after reaching 50 ° C., 22.0 parts by mass of oxidized starch 1 (amylose content: 21% by mass, carboxyl group content: 1.1% by mass) and 7.0 parts by mass of hydroxypropyl starch 1 are added, The mixture was mixed and dissolved by a propeller mixer (1,300 rpm). After the starch was firmly swollen and gelatinized, 21.0 parts by mass of the oil and fat 2 was added, emulsified, and mixed and stirred to 85 ° C. After reaching 85 ° C., 0.2 parts by mass of cheese flavor was added and kept stirring for 1 minute at the same rotational speed. The heated and emulsified cheese-like emulsion was filled in a container and cooled in a refrigerator at 5 ° C. for 3 days to obtain a twist-like cheese-like processed food. The quality evaluation results are shown in Table 4.

(実施例12) 酸化デンプン/ヒドロキシプロピルデンプン比:13.0
表4に示した配合により、実施例11と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表4に示した。
(Example 12) Oxidized starch / hydroxypropyl starch ratio: 13.0
According to the composition shown in Table 4, a spiny cheese-like processed food was produced in the same procedure as in Example 11. The quality evaluation results are shown in Table 4.

(実施例13〜16)他の油脂の使用:パーム油、パームステアリン、配合油脂、バターオイル
表4に示した配合により、実施例11と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表4に示した。
(Examples 13 to 16) Use of other fats and oils: Palm oil, palm stearin, blended fats and oils, butter oil A spiny cheese-like processed food was produced in the same procedure as in Example 11 according to the composition shown in Table 4. . The quality evaluation results are shown in Table 4.

(実施例17)乳以外のタンパク質使用:大豆タンパク質
表4に示した配合により、実施例11と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表4に示した。
(Example 17) Use of protein other than milk: soy protein According to the composition shown in Table 4, a spiny cheese-like processed food was produced in the same procedure as in Example 11. The quality evaluation results are shown in Table 4.

(実施例18)増粘剤使用:アラビアガム
表4に示した配合により、実施例11と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表4に示した。
Example 18 Use of Thickener: According to the composition shown in Table 4, gum arabic-like processed food in the same manner as in Example 11 was prepared. The quality evaluation results are shown in Table 4.

(実施例19)チーズ風味以外の加工食品:チョコレート風味
水相部として砂糖を6.0質量部、水を44.3質量部添加して昇温し、50℃に達した後、酸化デンプン1(アミロース含量:21質量%、カルボキシル基量:1.1質量%)を19.0質量部、酸化デンプン2(アミロース含量:25質量%、カルボキシル基量:0.4質量%)を4.0%、ヒドロキシプロピルデンプン1を4.0質量部添加し、プロペラミキサー(1,300rpm)で混合攪拌して溶解させた。デンプンがしっかり膨潤糊化した後、ココアパウダーを10.0質量部添加し、デンプンとよく馴染むように混合攪拌した。そこに油脂1を12.5質量部添加し、乳化させ85℃まで混合攪拌した。85℃に到達後、チョコレート香料を0.2質量部添加してそのままの回転数で1分間攪拌保持した。加熱乳化したチョコレート様乳化物を容器に充填し、5℃の冷蔵庫で3日間冷却して曳糸性チョコレート様加工食品を得た。品質評価結果は表4に示した。
(Example 19) Processed food other than cheese flavor: 6.0 parts by mass of sugar and 44.3 parts by mass of water as a chocolate-flavored aqueous phase, heated to 50 ° C., and then oxidized starch 1 19.0 parts by mass of (amylose content: 21% by mass, carboxyl group content: 1.1% by mass), oxidized starch 2 (amylose content: 25% by mass, carboxyl group content: 0.4% by mass) 4.0 % And 4.0 parts by mass of hydroxypropyl starch 1 were added and dissolved by mixing and stirring with a propeller mixer (1,300 rpm). After the starch was firmly swollen and gelatinized, 10.0 parts by mass of cocoa powder was added and mixed and stirred so as to be well compatible with the starch. 12.5 mass parts of fats and oils 1 were added there, and it emulsified, mixed and stirred to 85 degreeC. After reaching 85 ° C., 0.2 parts by mass of a chocolate flavor was added and kept stirring for 1 minute at the same rotational speed. The heated and emulsified chocolate-like emulsion was filled in a container and cooled in a refrigerator at 5 ° C. for 3 days to obtain a spindling chocolate-like processed food. The quality evaluation results are shown in Table 4.

(実施例20)乳化剤使用:ポリグリセリン脂肪酸エステル
表4に示した配合により、実施例11と同様の手順でチーズ様加工食品を製造した。品質評価結果は表4に示した。
(Example 20) Emulsifier use: Polyglycerin fatty acid ester According to the composition shown in Table 4, a cheese-like processed food was produced in the same manner as in Example 11. The quality evaluation results are shown in Table 4.

Figure 2018174712
Figure 2018174712

Figure 2018174712
Figure 2018174712

(比較例1)酸化デンプン以外のデンプン:酸処理デンプン
水相部として食塩を1.5質量部、水を45.5質量部添加して昇温し、50℃に達した後、酸処理デンプンを26.0質量部、ヒドロキシプロピルデンプン1を5.0質量部添加し、プロペラミキサー(1,300rpm)で混合攪拌して溶解させた。デンプンがしっかり膨潤糊化した後、油脂1を22.0質量部添加し乳化させ85℃まで混合攪拌した。85℃に到達後、そのままの回転数で1分間攪拌保持した。加熱乳化したチーズ様乳化物を容器に充填し、5℃の冷蔵庫で3日間冷却して曳糸性チーズ様加工食品を得た。品質評価結果は表5に示した。
(Comparative Example 1) Starch other than oxidized starch: 1.5 parts by mass of sodium chloride and 45.5 parts by mass of water as the acid-treated starch aqueous phase, heated to 50 ° C., and then acid-treated starch 26.0 parts by mass and 5.0 parts by mass of hydroxypropyl starch 1 were added and dissolved by mixing and stirring with a propeller mixer (1,300 rpm). After the starch was firmly swollen and gelatinized, 22.0 parts by mass of Fat 1 was added, emulsified, and mixed and stirred to 85 ° C. After reaching 85 ° C., stirring was maintained for 1 minute at the same rotational speed. The heated and emulsified cheese-like emulsion was filled in a container and cooled in a refrigerator at 5 ° C. for 3 days to obtain a twist-like cheese-like processed food. The quality evaluation results are shown in Table 5.

(比較例2)酸化デンプン以外のデンプン:ヒドロキシプロピルリン酸架橋デンプン
表5に示した配合により、酸処理デンプンをヒドロキシプロピルリン酸架橋デンプンに代えた以外は比較例1と同様の手順で曳糸性チーズ様加工食品を製造しようとしたが、水相部が高粘度となり、油相部と乳化せずチーズ様加工食品は得られなかった。品質評価結果は表5に示した。
Comparative Example 2 Starch Other than Oxidized Starch: Hydroxypropyl Phosphate Cross-Linked Starch The same procedure as Comparative Example 1 was followed except that the acid-treated starch was replaced with hydroxypropyl phosphate cross-linked starch according to the composition shown in Table 5. It was tried to produce processed cheese-like processed food, but the viscosity of the water phase became high, and it did not emulsify with the oil phase, and no cheese-like processed food was obtained. The quality evaluation results are shown in Table 5.

(比較例3)酸化デンプン以外のデンプン:酸化デンプン+未加工デンプン
表5に示した配合により、比較例1と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表5に示した。
Comparative Example 3 Starch Other than Oxidized Starch: Oxidized Starch + Raw Starch According to the composition shown in Table 5, a spiny cheese-like processed food was produced in the same procedure as Comparative Example 1. The quality evaluation results are shown in Table 5.

(比較例4)アミロース含量:23.0質量%以上
表5に示した配合により、比較例1と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表5に示した。
(Comparative Example 4) Amylose content: 23.0% by mass or more According to the composition shown in Table 5, a spiny cheese-like processed food was produced in the same procedure as Comparative Example 1. The quality evaluation results are shown in Table 5.

(比較例5〜6)油脂の変更:大豆油、パームオレイン
表5に示した配合により、比較例1と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表5に示した。
(Comparative Examples 5 to 6) Modification of Fats and Oils: Soybean oil, palm olein According to the composition shown in Table 5, a spiny cheese-like processed food was produced in the same procedure as Comparative Example 1. The quality evaluation results are shown in Table 5.

(比較例7)酸化デンプン/ヒドロキシプロピルデンプン含有比:下限以下(1.0)
表5に示した配合により、比較例1と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表5に示した。
Comparative Example 7 Oxidized Starch / Hydroxypropyl Starch Content Ratio: Below the Lower Limit (1.0)
According to the composition shown in Table 5, a spiny cheese-like processed food was produced in the same procedure as Comparative Example 1. The quality evaluation results are shown in Table 5.

(比較例8)酸化デンプン/ヒドロキシプロピルデンプン含有比:上限以上(26.0)
表5に示した配合により、比較例1と同様の手順で曳糸性チーズ様加工食品を製造した。品質評価結果は表5に示した。
(Comparative example 8) Oxidized starch / hydroxypropyl starch content ratio: More than upper limit (26.0)
According to the composition shown in Table 5, a spiny cheese-like processed food was produced in the same procedure as Comparative Example 1. The quality evaluation results are shown in Table 5.

Figure 2018174712
Figure 2018174712

すなわち本発明は、
(1)乳由来タンパク質含量が0.1質量%以下であって、酸化デンプンを15〜30質量%、ヒドロキシプロピルデンプンを2〜8質量%含みそれらの総量は加工食品の総質量の20〜35質量%であり、酸化デンプンとヒドロキシプロピルデンプンの含有比が15:1〜2:1であり、上昇融点30℃以上の油脂を10〜40質量%、及び水を含有し、酸化デンプン総量中のアミロース含量が0.1〜23質量%で、実質的に乳由来タンパク質を含有せずとも加熱時に曳糸性を有するチーズ様加工食品、
(2)タンパク質含量が0.1%以下で実質的にタンパク質を含有しない(1)に記載のチーズ様加工食品、
(3)油脂のSFCが10℃で50〜95%、20℃で40〜85%である(1)または)に記載のチーズ様加工食品、
(4)実質的に乳由来原料を含有しない(1)〜()のいずれかに記載のチーズ様加工食品、
(5)形状がブロック状、スライス状、サイノメ状、短冊状、シュレッド状、粉状である(1)〜()のいずれかに記載のチーズ様加工食品を提供するものである。
That is, the present invention
(1) The milk- derived protein content is 0.1% by mass or less, containing 15 to 30% by mass of oxidized starch and 2 to 8% by mass of hydroxypropyl starch, and the total amount thereof is 20 to 20 % of the total mass of processed food It is 35 mass%, content ratio of oxidized starch to hydroxypropyl starch is 15: 1 to 2: 1, 10 to 40 mass% of fats and oils with rising melting point of 30 ° C. or more , and water, in total oxidized starch A cheeselike processed food having an amylose content of 0.1 to 23% by mass and having spinnability on heating substantially without containing milk- derived protein,
(2) The cheese-like processed food according to (1), wherein the protein content is 0.1% or less and substantially free of protein.
(3) The cheese-like processed food according to (1) or ( 2 ), wherein the SFC of fats and oils is 50 to 95% at 10 ° C and 40 to 85% at 20 ° C.
(4) The cheese-like processed food according to any one of (1) to ( 3 ), which contains substantially no milk-derived material.
(5) The cheese-like processed food according to any one of (1) to ( 4 ), which has a block shape, a slice shape, a sinome shape, a strip shape, a shred shape, or a powder shape.

Claims (6)

乳タンパク質含量が0.1質量%以下であって、酸化デンプン、ヒドロキシプロピルデンプン、上昇融点30℃以上の油脂及び水を含有し、酸化デンプン総量中のアミロース含量が0.1〜23質量%で、実質的に乳タンパク質を含有せずとも加熱時に曳糸性を有するチーズ様加工食品。 Milk protein content is 0.1 mass% or less and contains oxidized starch, hydroxypropyl starch, fats and oils with rising melting point of 30 ° C or more and water, and amylose content in the total amount of oxidized starch is 0.1 to 23 mass% , A cheese-like processed food which is substantially free of milk proteins and has spinnability upon heating. タンパク質含量が0.1%以下で実質的にタンパク質を含有しない請求項1に記載のチーズ様加工食品。 The cheese-like processed food according to claim 1, wherein the protein content is 0.1% or less and substantially free of protein. 酸化デンプンとヒドロキシプロピルデンプンの含有比が15:1〜2:1である請求項1または2に記載のチーズ様加工食品。 The processed cheese-like food according to claim 1 or 2, wherein the content ratio of oxidized starch to hydroxypropyl starch is 15: 1 to 2: 1. 油脂のSFCが10℃で50〜95%、20℃で40〜85%である請求項1〜3のいずれかに記載のチーズ様加工食品。 The processed cheese-like food according to any one of claims 1 to 3, wherein the SFC of the fat or oil is 50 to 95% at 10 ° C and 40 to 85% at 20 ° C. 実質的に乳由来原料を含有しない請求項1〜4のいずれかに記載のチーズ様加工食品。 The cheese-like processed food according to any one of claims 1 to 4, which contains substantially no milk-derived material. 形状がブロック状、スライス状、サイノメ状、短冊状、シュレッド状、粉状である請求項1〜5のいずれかに記載のチーズ様加工食品。 The cheese-like processed food according to any one of claims 1 to 5, wherein the shape is a block, slice, sinome, strip, shred, or powder.
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