JP6152332B2 - Non-woven fabric for preventing fold contact - Google Patents

Description

  The present invention relates to a fold adhesion preventing non-woven fabric which is a member for a liquid filter for efficiently removing particles contained in a liquid and obtaining a clean liquid.

  For example, in an oil filter element for an internal combustion engine, a filter element is known in which a filter part is formed by forming a hollow cylinder into a hollow cylinder after the sheet-like filter medium is folded in order to store more filter medium in a predetermined volume. It has been. In such a filter element, in order to maintain the shape of the folds, the filter medium is installed in a metal or plastic cylinder provided with many openings, but the filter medium and the cylinder are not fixed. When the liquid is passed, the filter medium is deformed by the pressure difference between the inside and outside of the filtration part, or when adjacent pleats are in close contact with each other, the pressure loss increases, and the life of the filter element may be extremely shortened.

  As a means for preventing such deformation of the filter medium and close contact between the pleats, a method of forming a convex portion by applying a resin hot melt resin on the surface of the fold-folded filter medium has been proposed (patent) Reference 1). However, since the portion to which the hot melt resin is applied does not pass, the area of the filter medium in that portion has to be sacrificed.

  In addition, a method of attaching a comb-shaped spacer corresponding to a pleat shape has been proposed (see Patent Document 2), but an adhesive is used to fix the spacer so that it does not shift due to vibration or the like. There is a problem that the process becomes complicated, such as application of an agent and drying.

JP 05-329314 A JP 11-42410 A

  An object of the present invention is to provide a pleat-adhesion-preventing nonwoven fabric that prevents deformation of the filter medium and adhesion between pleats without sacrificing the area of the filter medium.

  As a result of intensive studies to solve the above problems, the following invention has been found.

(1) A non-woven fabric obtained by mixing a heat-meltable fiber and a non-heat-meltable fiber. An adhesive layer having a ratio of 60:40 to 95: 5 and a heating layer having a mass ratio of heat-meltable fiber and non-heat-meltable fiber of 0: 100 to 40:60 are laminated and integrated, A pleat-adhesion-preventing nonwoven fabric characterized by being thermally bonded to a fold-folded liquid filter.

(2) the mass ratio of the heat-meltable fibers and non-thermally-meltable fiber is 95: 5 to 5: 95 in which (1) Symbol placement of fold contact prevention nonwoven.

( 3 ) The fold adhesion-preventing nonwoven fabric according to (1) or (2) , wherein the heating layer contains non-thermomeltable fibers fibrillated.

  The pleat adhesion preventing nonwoven fabric of the present invention is easily pleated by, for example, wrapping the entire outer periphery of a filter medium having a hollow cylindrical shape after fold folding, and heating the portion where the pleat adhesion prevention nonwoven cloth contacts the peak portion of the filter medium. Can be fixed. Since bonding is performed after the fold folding process, only the ridges of the filter medium are bonded without impairing the fold folding characteristics, and therefore, close contact between adjacent folds can be prevented without sacrificing the surface of the filter medium.

  Since the bonding area between the peak portion of the filter medium and the pleat adhesion preventing nonwoven fabric is extremely narrow, a member composed only of a hot-melt component has a large shape change at the time of melting, and it has been difficult to melt and fuse well. On the other hand, the pleat adhesion preventing nonwoven fabric (1) of the present invention is a nonwoven fabric obtained by mixing a heat-meltable fiber and a non-heat-meltable fiber, so that only the heat-meltable fiber is localized when thermally bonded to the filter medium. Since the nonwoven fabric shape is maintained by the non-heat-meltable fiber, it is difficult to melt and can be firmly bonded to the filter medium.

In the fold adhesion preventing nonwoven fabric ( 1 ) of the present invention, the use of a heat-meltable fiber having a melting point or a softening point of 280 ° C. or less improves thermal adhesiveness with a filter medium, and is excellent in the effect of preventing fold adhesion.

In the pleat adhesion preventing nonwoven fabric ( 2 ) of the present invention, by setting the mass ratio of the heat-meltable fiber and the non-heat-meltable fiber to 95: 5 to 5:95, the thermal adhesiveness with the filter medium is improved, and the fold adhesion It is excellent in the prevention effect and preferable.

In the fold adhesion-preventing nonwoven fabric ( 1 ) of the present invention, an adhesive layer having a mass ratio of the heat-meltable fiber and the non-heat-meltable fiber of 60:40 to 95: 5, A heating layer having a mass ratio of 0: 100 to 40:60 is laminated and integrated. By placing an adhesive layer with a high ratio of hot melt fibers and excellent adhesion to the filter medium on the filter medium side, while heating from the heating layer side with a high ratio of non-heat melt fibers and excellent thermal dimensional stability The thermal adhesiveness with the filter medium is improved, and the effect of preventing fold adhesion is excellent, which is preferable.

The nonwoven fabric for preventing pleat adhesion according to the present invention may be designed by printing a product name or color as an exterior material for a filter element. In the fold adhesion-preventing nonwoven fabric ( 3 ) of the present invention, a more homogeneous fiber network can be obtained by containing fibrillated dense non-heat-meltable fibers in the heating layer to be printed, and the printing ink can be applied. The meat property is improved and the printability is excellent, which is preferable.

  Hereinafter, the fold adhesion preventing nonwoven fabric of the present invention will be described in detail. The pleat adhesion preventing nonwoven fabric of the present invention is a nonwoven fabric obtained by mixing a heat-meltable fiber and a non-heat-meltable fiber, in order to prevent adhesion between the pleats by heat bonding to a fold-folded filter medium for a liquid filter. belongs to. By heating at an arbitrary temperature, the heat-meltable fibers are locally melted, exhibiting adhesiveness with the filter medium, and non-heat-bondable fibers that are not heat-melted during heat bonding have a non-woven shape. Since it maintains, it is hard to melt | fuse and implement | achieves favorable adhesiveness with a filter medium.

  The heat-meltable fiber in the present invention is not particularly limited as long as it is a fiber that melts by heating at the time of heat bonding with the filter medium, but has a melting point or a softening point of 280 ° C. or less in order to achieve good heat bond with the filter medium. It is preferably a fiber. Such fibers include polyester fibers such as stretched polyethylene terephthalate, unstretched polyethylene terephthalate, polybutylene terephthalate and copolymers thereof, polyamide fibers such as nylon 6 and nylon 66, olefin fibers such as polyethylene and polypropylene, poly Examples thereof include vinylidene chloride fiber, polyvinyl chloride fiber, and polystyrene fiber. Polyester fiber, polyamide fiber, and polyolefin fiber are preferable because they are easily made into fine fibers. The polymers constituting these fibers can also be used in the form of homopolymers, modified polymers, blends, copolymers, and the like. You may use not only the fiber which consists of a single component but the composite fiber which consists of a several component. Moreover, the fiber which has irregular cross sections, such as T type, Y type, and a triangle, can also be contained.

  The fiber diameter of the heat-meltable fiber is preferably 1 to 25 μm, more preferably 3 to 20 μm, and still more preferably 5 to 15 μm. If the fiber diameter is too small, the liquid permeability may be impaired. On the other hand, if the fiber diameter is too large, the formation becomes uneven and may be easily melted during thermal bonding. In the present invention, the “fiber diameter” refers to a fiber diameter having a value converted to the diameter of a perfect circle having the same cross-sectional area when the cross section of the fiber is elliptical or polygonal.

  The fiber length of the heat-meltable fiber is preferably 1 to 10 mm, particularly preferably 3 to 7 mm. If the fiber length is too short, sufficient mechanical strength may not be obtained. If the fiber length is too long, the formation becomes uneven and may be easily melted during thermal bonding.

  The non-heat-meltable fiber in the present invention is not particularly limited as long as it is a fiber that does not melt by heating when thermally bonded to the filter medium. As such fibers, wood pulp such as conifer pulp, hardwood pulp, straw pulp, bamboo pulp, linter pulp, hemp pulp, natural cellulose fibers such as kenaf pulp, regenerated cellulose fibers such as rayon, lyocell, cupra, acetate, triacetate, Semi-synthetic fibers such as promix, glass, microglass, inorganic fibers such as alumina, silica, zirconia, rock wool, wholly aromatic polyamide, wholly aromatic polyester, polyacrylonitrile, polyimide, polyketone, vinylon, urethane, phenol Organic synthetic fibers such as Cellulosic fibers, wholly aromatic polyamide fibers, and polyacrylonitrile fibers are preferred because they can be easily refined and refined. The polymers constituting these fibers can also be used in the form of homopolymers, modified polymers, blends, copolymers, and the like. You may use not only the fiber which consists of a single component but the composite fiber which consists of a some component. Further, the fiber may be fibrillated as long as it does not impair liquid permeability and air permeability. Furthermore, pulp fibers obtained from waste paper, waste paper, and the like can also be used. Moreover, the fiber which has irregular cross sections, such as T type, Y type, and a triangle, can also be contained.

  The fiber diameter of the non-thermomeltable fiber is preferably 1 to 25 μm, more preferably 3 to 20 μm, and further preferably 5 to 15 μm. If the fiber diameter is too small, the liquid permeability may be impaired. On the other hand, if the fiber diameter is too large, the formation becomes uneven and may be easily melted when thermally bonded to the filter medium.

  The fiber length of the non-heat-meltable fiber is preferably 1 to 10 mm, particularly preferably 3 to 7 mm. If the fiber length is too short, the fiber may fall off from the papermaking wire. If the fiber length is too long, the formation becomes uneven and may be easily melted during thermal bonding with the filter medium.

  In the fold adhesion-preventing nonwoven fabric of the present invention, the mass ratio of the heat-meltable fiber and the non-heat-meltable fiber is preferably 95: 5 to 5:95, more preferably 90:10 to 30:70, More preferably, it is 80: 20-40: 60. If the mass ratio of the hot-melt fiber is too large, it may be easily melted, and if it is too small, the thermal adhesiveness with the filter medium may be insufficient.

  In the fold adhesion-preventing nonwoven fabric of the present invention, the mass ratio of the heat-meltable fiber and the non-heat-meltable fiber is 60:40 to 95: 5, and the mass ratio of the heat-melt fiber and the non-heat-meltable fiber. It is preferable that a heating layer of 0: 100 to 40:60 is laminated and integrated. By increasing the ratio of hot-melt fibers in the adhesive layer in contact with the filter medium, while increasing the melting component adhering to the filter medium, by increasing the ratio of non-heat-meltable fibers in the heating layer to which the heating jig is applied Since the thermal dimensional stability of the nonwoven fabric is improved, the thermal adhesiveness with the filter medium is improved, and the fold adhesion preventing effect is excellent, which is preferable. The mass ratio of the heat-meltable fiber and the non-heat-meltable fiber in the adhesive layer is more preferably 70:30 to 90:10, and still more preferably 80:20 to 90:10. Moreover, the mass ratio of the heat-meltable fiber and the non-heat-meltable fiber in the heating layer is more preferably 5:95 to 35:65, and still more preferably 10:90 to 30:70.

  The pleat adhesion preventing nonwoven fabric of the present invention is preferable because the heating layer contains non-heat-meltable fibers that are fibrillated, so that the ink-inking property is improved and the printability is excellent. Examples of the fibrillated non-heat-meltable fibers used in the present invention include cellulose fibers such as natural cellulose and regenerated cellulose, aramid fibers such as wholly aromatic polyamides, polyester fibers such as wholly aromatic polyesters, polyimide fibers, and polyamideimides. Examples thereof include fibers, polyketone fibers, polyether ether ketone fibers, polybenzimidazole fibers, poly-p-phenylenebenzobisthiazole fibers, polytetrafluoroethylene fibers, and acrylic fibers. Among these, cellulose fibers that are easily fibrillated, aramid fibers such as para-type wholly aromatic polyamide, and acrylic fibers such as a copolymer of acrylonitrile and an acrylate ester are preferable. Moreover, these may be used independently and may use 2 or more types together.

  The fibrillated non-heat-meltable fiber used in the present invention preferably has a Canadian standard freeness in the range of 0 to 700 ml. If the freeness is less than 0 ml, the liquid permeability may be impaired. On the other hand, if the freeness exceeds 700 ml, the effect of improving the printability may be insufficient.

  In the present invention, in order to obtain fibrillated non-heat-meltable fibers, for example, short fibers are dispersed in water at an appropriate concentration, and this is sheared by a refiner, a beater, a mill, a grinding device, or a high-speed rotary blade. Rotating blade type homogenizer that gives force, double cylindrical high speed homogenizer that generates a shearing force between a cylindrical inner blade that rotates at high speed and a fixed outer blade, ultrasonic crushing that is refined by ultrasonic impact It may be finely processed by adjusting conditions such as blade shape, flow rate, number of treatments, treatment speed, treatment concentration, etc.

The basis weight of the fold contact prevention nonwoven fabric of the present invention is not particularly limited, is preferably from 20 to 200 g / ^{m 2,} more preferably 30 to 150 g / ^{m 2,} more preferably 35~100g / ^{m 2.} If it is less than 20 g / m ² , the thermal adhesiveness with the filter medium may be impaired. On the other hand, if it exceeds 200 g / m ² , the liquid permeability may be impaired.

  The thickness of the pleat adhesion preventing nonwoven fabric of the present invention is not particularly limited, but is preferably 40 to 500 μm, more preferably 70 to 450 μm, and further preferably 130 to 400 μm. If it is less than 40 μm, the thermal adhesiveness with the filter medium may be impaired, while if it exceeds 500 μm, the liquid permeability may be impaired.

In the present invention, the basis weight of the adhesive layer is preferably 10 g / ^{m 2} or more, 20 g / ^{m 2} or more preferably, 30 g / ^{m 2} or more is more preferable. If the basis weight of the adhesive layer is less than 10 g / m ² , the thermal adhesiveness with the filter medium may not be improved. On the other hand, the basis weight of the heating layer is preferably 5 g / ^{m 2} or more, more preferably 10 g / ^{m 2} or more, further preferably 15 g / ^{m 2} or more. When the basis weight of the heating layer is less than 5 g / m ² , the thermal dimensional stability may not be improved. The total basis weight of the adhesive layer and the heating layer is preferably 200 g / m ² or less. If it exceeds 200 g / m ² , the liquid permeability may be impaired.

  In the present invention, the thickness of the adhesive layer is preferably 30 to 490 μm, more preferably 50 to 430 μm, and still more preferably 80 to 350 μm. If it is less than 30 μm, the thermal adhesiveness with the filter medium may not be improved, while if it exceeds 490 μm, the liquid permeability may be impaired. Moreover, it is preferable that the thickness of a heating layer is 10-470 micrometers, 20-400 micrometers is more preferable, 50-320 micrometers is further more preferable. If the thickness is less than 10 μm, the thermal dimensional stability may not be improved, while if it exceeds 470 μm, the liquid permeability may be impaired.

  In the pleat adhesion preventing nonwoven fabric of the present invention, a thermoplastic resin can be included as necessary as long as the characteristics are not impaired. Examples of the thermoplastic resin include acrylic, vinyl acetate, epoxy, synthetic rubber, urethane, polyester, and vinylidene chloride latex, polyvinyl alcohol, starch, and phenol resin. These may be used alone or in combination of two or more.

  In the fold adhesion preventing nonwoven fabric of the present invention, additives such as a crosslinking agent, a water repellent, a dispersant, a yield improver, a paper strength agent, and a dye can be appropriately blended as long as the properties are not impaired.

  Examples of the fold-adhesion-preventing nonwoven fabric of the present invention include dry nonwoven fabrics produced by methods such as electrostatic spinning, spunbonding, melt blowing, needle punching, and spunlace, and wet nonwoven fabrics produced by a paper machine. As the wet nonwoven fabric, for example, a paper machine in which a paper net such as a long net, a circular net, or a slanted wire type is installed alone, or two or more of the same or different types from these paper nets are installed online. Manufactured with a combination paper machine. The wet paper produced by the paper machine is dried with a dryer. After drying, a thermoplastic resin is contained and dried with an air dryer, a cylinder dryer, a suction drum dryer, an infrared dryer or the like. When a dry nonwoven fabric and a wet nonwoven fabric are laminated and used, the wet nonwoven fabric and dry nonwoven fabric produced by a paper machine may be laminated by a paper machine, or may be laminated by using a separate processing machine.

  EXAMPLES Hereinafter, the present invention will be specifically described with reference to examples, but the present invention is not limited to the examples. In the examples, all parts and percentages are by mass unless otherwise specified.

{Preparation of filter medium 1 for liquid filter}
After water is poured into a 2 m ³ dispersion tank, 30% by mass of unbeaten softwood pulp fibers, a fiber diameter of 15 μm, a fiber length of 5 mm, the core is polyethylene terephthalate, and the sheath is a copolyester (softening point 75 ° C.) 70% by mass of the core-sheath type composite fiber was blended and dispersed for 5 minutes at a dispersion concentration of 0.2% by mass to prepare a slurry for making a support layer.

  Next, 25% by mass of unbeaten softwood pulp fiber fiber, fiber diameter 7 μm, fiber length 5 mm, drawn polyethylene terephthalate fiber 25% by mass, fiber diameter 15 μm, fiber length 5 mm, the core is polyethylene terephthalate, and the sheath is copolymerized polyester ( 50% by mass of a polyester core-sheath composite fiber having a softening point of 75 ° C. was blended, and a slurry for forming a filter medium layer was prepared in the same manner as the support layer slurry.

Using a combination paper machine in which a long net and a circular net are installed on-line, a web is formed so that the dry weight of the support layer is 50 g / m ² with the long net, and the dry weight of the filter medium layer is 20 g with the circular net. After forming the web so that it becomes / m ² and making the two webs before drying, drying and integration while pressing the touch roll at a pressure of 400 N / cm ² with a cylinder dryer having a surface temperature of 130 ° C. Thus, a filter material 1 for a liquid filter was produced.

{Preparation of filter medium 2 for liquid filter}
Water was added to a 2 m ³ dispersion tank, blended with 50% by mass of cotton linter pulp fibers and 50% by mass of softwood pulp fibers, and dispersed at a dispersion concentration of 0.2% by mass for 5 minutes to prepare a papermaking slurry.

A web was formed using a circular paper machine so as to have a dry mass of 140 g / m ² , and dried with a cylinder dryer having a surface temperature of 130 ° C. to prepare a filter base paper. Subsequently, the filter base paper was impregnated with a phenol resin by a size press method so that the solid content was 20% by mass, and a filter medium 2 for a liquid filter was produced.

<Hot melt fiber 1>
The heat-meltable fiber 1 was a drawn polyethylene terephthalate fiber (melting point 260 ° C.) having a fiber diameter of 5 μm and a fiber length of 5 mm.

<Hot melt fiber 2>
The heat-meltable fiber 2 was a drawn polyethylene terephthalate fiber (melting point 260 ° C.) having a fiber diameter of 10 μm and a fiber length of 5 mm.

<Hot melt fiber 3>
The polyester core-sheath composite fiber having a fiber diameter of 15 μm, a fiber length of 5 mm, polyethylene terephthalate (melting point 253 ° C.) and a sheath polyester copolymer (softening point 75 ° C.) was used as the heat-meltable fiber 3.

<Hot melt fiber 4>
A polyphenylene sulfide fiber (melting point 285 ° C.) having a fiber diameter of 15 μm and a fiber length of 5 mm was used as the heat-meltable fiber 4.

<Non-heat-meltable fiber 1>
Unbeaten softwood pulp fiber was designated as non-heat-meltable fiber 1.

<Non-heat-meltable fiber 2>
The non-heat-meltable fiber 2 was a rayon fiber having a fiber diameter of 10 μm and a fiber length of 5 mm.

<Non-heat-meltable fiber 3>
An acrylic fiber having a fiber diameter of 5 μm and a fiber length of 5 mm was used as the non-thermomeltable fiber 3.

<Fibrilized non-heat-meltable fiber>
Non-fibrillated lyocell monofilament (Cortles) was processed using a double disc refiner to produce fibrillated fibers with a Canadian freeness of 300 ml. It was set as the fibrillated non-heat-meltable fiber.

"Preparation of slurry for papermaking"
After introducing water into a 2 m ³ dispersion tank, the raw materials were blended in the ratios shown in Table 1, and dispersed at a dispersion concentration of 0.2% by mass for 5 minutes to prepare a papermaking slurry.

(Example (reference example) 1-3 and comparative example 1)
The papermaking slurries 1 to 4 were formed into a web so as to have a dry mass of 70 g / m ² using a circular paper machine and dried with a cylinder dryer having a surface temperature of 130 ° C. 3 and Comparative Example 1 were obtained.

  The filter medium 1 for liquid filter is fold-folded, and the nonwoven fabric A to D for preventing pleat adhesion so that both ends are overlapped by about 5 mm on the outer peripheral surface of the liquid filter 1 having a hollow cylindrical shape as a whole so that the filter medium surface is outside. And heat-bonding the overlapping end portions and the portion where the pleat adhesion preventing nonwoven fabric is in contact with the peak portion of the filter medium using a soldering iron heated to 280 ° C., Examples 1 to 3 shown in Table 3 and comparison The filter element of Example 1 was obtained.

(Examples (Reference Examples) 4 to 7 and Comparative Example 2)
The papermaking slurries 5-9 were formed using a circular paper machine so that the dry mass was 70 g / m ² , dried with a cylinder dryer having a surface temperature of 130 ° C., and Examples 4 to 4 shown in Table 2 7 and Comparative Example 2 were obtained.

  Using the filter medium 2 for liquid filters and the nonwoven fabrics E to I for preventing pleat adhesion, heat-bonded to the filter medium in the same manner as in Examples 1 to 3 and Comparative Example 1, and Examples 4 to 7 and Comparative Example 2 shown in Table 3 Filter element was obtained.

(Examples 8 to 10)
Using a combination paper machine in which a long net and a circular net are installed online, a web is formed on the slurry 1, 4-6, 10, 11 for paper making so that the dry mass is 50 g / m ^2. After forming the web so as to have a dry mass of 20 g / m ² with a circular net and laminating both webs before drying, the touch roll was pressed with a cylinder dryer having a surface temperature of 130 ° C. at a pressure of 400 N / cm ² . While pressurizing, drying and integration were performed to obtain pleat adhesion preventing nonwoven fabrics J to L shown in Table 2.

  A non-woven fabric for preventing pleat adhesion so that a layer made of a long mesh is disposed on the filter medium side as an adhesive layer on the outer peripheral surface of the liquid filter 2 formed into a hollow cylindrical shape by folding the filter medium 2 for a liquid filter. J to L were wound and thermally bonded to the filter medium in the same manner as in Examples 1 to 3 and Comparative Example 1 to obtain filter elements of Examples 8 to 10 shown in Table 3.

(Comparative Example 3)
By punching, an aperture was provided in a polyethylene terephthalate (PET) film having a thickness of 250 μm so that the aperture diameter was 1 mmφ and the aperture area ratio was 25%, and a porous film A was produced. The porous film A was wound around the outer peripheral surface of the liquid filter 2 having a hollow cylindrical shape by folding the filter medium 2 for the liquid filter so that both ends overlap each other by about 5 mm, and only the overlapping both ends were heated to 280 ° C. A filter element of Comparative Example 3 shown in Table 3 was obtained by heat bonding using a soldering iron.

  The following evaluations were performed on the pleat adhesion preventing nonwoven fabrics and filter elements obtained in Examples and Comparative Examples, and the results are shown in Tables 2 and 3.

Test 1 (basis weight)
The basis weight was measured according to JIS P8124.

Test 2 (thickness)
The thickness was measured in accordance with JIS P 8118.

Test 3 (printing test)
0.6 cc of indigo ink (manufactured by DIC Corporation, trade name: TRANS-G) is attached to a printing roll of an RI printing machine (manufactured by IHI Machine System Co., Ltd., RI-1 type). After carrying out and drying overnight, the reflection density of the printed part was measured with a reflection densitometer (Macbeth, product name: Macbeth TR924), and the printability was evaluated. In the evaluation of the present invention, the higher the reflection density, the better the printability and the better. In addition, about the pleat adhesion | attachment prevention nonwoven fabric J, K, and L which laminated | stacked the contact bonding layer and the heating layer, it printed on the surface of the heating layer.

Test 4 (filtration rate)
Eleven kinds of JIS test powders were diluted in water at a concentration of 0.05% by mass to obtain test liquids. Using a filter element, 20 liters of the test liquid was filtered 10 times while the differential pressure was periodically changed to ΔP = 5 to 50 kPa, and the filtration rate was measured from the filtration time.

Test 5 (Life test)
The filter element was set in a filter set part of an electric discharge machine using a wire with a diameter of 0.32 mm for rough machining, and the time until the filter pressure reached 300 kPa when continuously cut was measured.

  As is clear from Table 3, the filter elements of Examples 1 to 10 using pleat adhesion preventing nonwoven fabrics A to C, E to H, and J to L formed by mixing hot melt fibers and non-heat melt fibers are as follows. The filtration rate was good, and a long life result was shown.

  On the other hand, the filter elements of Comparative Examples 1 to 3 using the pleat adhesion preventing nonwoven fabrics D and I that do not mix the heat-meltable fiber and the non-heat-meltable fiber and the porous film A have a slow filtration speed and a very long life. The result was short. When the filter element after the life test was visually confirmed, the liquid filter was greatly deformed, and many locations where the pleats were in close contact with each other were confirmed.

  Example 6 using the pleat adhesion preventing nonwoven fabric G in which the melting point of the hot melt fiber exceeds 280 ° C., Example 7 using the fold adhesion preventing nonwoven fabric H in which the heat meltable fiber exceeds 95% by mass, and In the filter element of Example 3 using the pleat-adhesion-preventing nonwoven fabric C having a heat-meltable fiber content of less than 5% by mass, the filtration rate was higher than that of the filter elements produced in Examples 1, 2, 4, 5, and 8-10. The result was slightly slower and the life was slightly shortened. When the filter element after the life test was visually confirmed, peeling of the heat-bonded portion was slightly observed and the liquid filter was slightly deformed, but adhesion between the pleats was not confirmed.

  From comparison between Examples 1 to 7 and Examples 8 to 10, the adhesive layer having a mass ratio of the heat-meltable fiber and the non-heat-meltable fiber of 60:40 to 95: 5, the heat-meltable fiber, and the non-heat The filter elements of Examples 8 to 10 produced using the pleat adhesion preventing nonwoven fabrics J to L formed by laminating and integrating the heating layers having a mass ratio of the meltable fiber of 0: 100 to 40:60 have a lifetime. Especially excellent for a long time. Furthermore, the pleat adhesion preventing nonwoven fabric L produced in Example 10 and containing a fibrillated non-thermomeltable fiber in the heating layer has a high reflection density in the printed portion, excellent printability, and more preferable results. It was.

  The present invention relates to a fold adhesion preventing non-woven fabric which is a member for a liquid filter for efficiently removing particles contained in a liquid and obtaining a clean liquid.

Claims (3)

A non-woven fabric formed by mixing a heat-meltable fiber and a non- heat-meltable fiber, the melting point or softening point of the heat-meltable fiber is 280 ° C. or less, and the mass ratio of the heat-meltable fiber and the non-heat-meltable fiber is 60 : An adhesive layer of 40 to 95: 5 and a heating layer of 0: 100 to 40:60 mass ratio of the heat-meltable fiber and the non-heat-meltable fiber are laminated and integrated, and fold-folded A fold-adhesion-preventing nonwoven fabric, which is used by thermally bonding to a liquid filter. Heat-meltable fibers and non-thermal mass ratio of fusible fibers 95: 5 to 5:95 in which claim 1 Symbol placement of fold contact prevention nonwoven. The fold adhesion-preventing nonwoven fabric according to claim 1 or 2 , wherein the heating layer contains non-thermomeltable fibers fibrillated.