JP6151993B2 - Method for decomposing amine nitrosates and method for recovering carbon dioxide in gas to be treated - Google Patents

Description

  The present invention relates to a method for decomposing amine nitrosates and a method for recovering carbon dioxide in a gas to be treated. More specifically, the present invention relates to a method for decomposing a nitroso compound derived from amines used for recovery of carbon dioxide in gas discharged from a combustion apparatus such as a boiler, and a carbon dioxide absorbing solution containing amines. The present invention relates to a method for recovering carbon dioxide in a gas to be treated with high efficiency by decomposing a nitrosate of amines that may be by-produced therein.

In a thermal power plant or the like, fossil fuel is burned, so a large amount of carbon dioxide (CO ₂ ) is generated. Carbon dioxide is one of the causes of global warming, and the suppression of its emission is being promoted in each country. As a method for recovering carbon dioxide, an absorption method using a liquid containing amines such as alkanolamine is known as the most practical method (see, for example, Patent Document 1).

In addition to CO ₂ , the combustion exhaust gas contains acidic gas components such as HCl (hydrogen chloride), NO _x (nitrogen oxide), and SO _x ; oxygen, nitrogen, water vapor, and the like. When this combustion exhaust gas is brought into contact with an absorbing solution containing amines, an acidic gas component in addition to CO ₂ is also absorbed by the absorbing solution. When the acid gas component is combined with amines, an inorganic acid salt is formed. For example, HCl forms a hydrochloride, NO _x forms a nitrate, and SO ₂ forms a sulfate. Further, when an organic acid such as formic acid, succinic acid, or acetic acid by-produced by decomposition of amines is combined with amines, an organic acid salt is formed. Such organic acid salts and inorganic acid salts are thermally stable salts (hereinafter, sometimes referred to as heat stable salts). Thermally stable salts corrode metals and reduce the ability to absorb CO ₂ . Such heat stable salts are removed by reclaiming or the like.

  While the absorption liquid containing amines is used to recover carbon dioxide from combustion exhaust gas, a part of the amines may be nitrosated. Since nitrosated products of amines have lower carbon dioxide absorption than amines and reduce the recovery efficiency of carbon dioxide, various studies have been conducted to remove the nitrosated products. For example, Patent Document 2 discloses a method of decomposing by heating nitrosamine.

  Many nitrosamines have a higher boiling point than the original amines. For example, the boiling point of N-nitrosodimethylamine produced by nitrosation of dimethylamine (boiling point 7.0 ° C.) is 151 to 154 ° C., and the boiling point of N-nitrosodiethylamine produced by nitrosation of diethylamine (boiling point 55.5 ° C.) is 177 ° C. In the thermal decomposition method of amine nitrosates, amines, which are the main components of the absorbing solution, are also thermally decomposed together, resulting in a large loss of amines. Also, thermally stable nitrosates of amines need to be heated at a temperature higher than that of conventional reclaimers and reboilers for thermal decomposition, so additional equipment may be required. .

Japanese Patent No. 3529855 WO2012 / 104137

The object of the present invention is to install nitrosated products of amines by-produced in the absorption liquid (hereinafter referred to as “nitroso compounds”) without installing new additional equipment and with almost no decomposition of amines having CO ₂ absorption ability. A) ”is sometimes provided to provide a method for efficiently decomposing a) to amines.

  As a result of studies to achieve the above object, the present inventors have completed the present invention including the following modes.

(1) heating a liquid to be treated containing a nitrosated product of amines in the presence of hydrohalic acid at a temperature not lower than the boiling point of water and not higher than the boiling point of the amines;
A method for decomposing amine nitrosates.
[2] The method for decomposing a nitrosated product of an amine according to [1], wherein the liquid to be treated further contains an amine.
[3] The method for decomposing amine nitrosates according to [2], wherein the amount of hydrogen halide is 100 mol parts or more with respect to 100 mol parts of the total amount of amino groups and nitroso groups.
[4] The method for decomposing amine nitrosates according to any one of [1] to [3], wherein the liquid to be treated is an aqueous amine solution used to absorb carbon dioxide in the combustion exhaust gas. .

[5] The amines according to any one of [1] to [4], wherein the hydrohalic acid is at least one selected from the group consisting of hydrochloric acid, hydrobromic acid, and hydroiodic acid. Method for decomposing nitrosates.
[6] The method for decomposing an amine nitrosate according to any one of [1] to [5], wherein the heating is performed at a pressure equal to or lower than atmospheric pressure; A method for decomposing a nitrosated product of an amine, wherein the pressure is adjusted so that the boiling point of the mixture with hydrohalic acid is 100 ° C or lower.
[7] The method for decomposing a nitrosated product of an amine according to any one of [1] to [6], wherein the amine is an alkanolamine.
[8] The method for decomposing a nitrosated product of an amine according to any one of [1] to [7], further comprising heating in the presence of an alkali component after heating in the presence of hydrohalic acid. .
[9] The liquid to be treated containing a nitrosated product of amines is heated to a pH of less than 3 and at a temperature not lower than the boiling point of water and not higher than the boiling point of the amines.
A method for decomposing amine nitrosates.

[10] A step of obtaining a CO ₂ rich absorbent by bringing a gas to be treated containing carbon dioxide into contact with a CO ₂ lean absorbent containing amines to absorb the carbon dioxide into the CO ₂ lean absorbent (I) ,
A step of heating the CO ₂ rich absorbent to desorb carbon dioxide and regenerating it into a CO ₂ lean absorbent (II),
Part of the regenerated CO ₂ lean absorbent is regenerated in steps (III) and (II) in the presence of hydrohalic acid at a temperature above the boiling point of water and below the boiling point of amines. A step (IV) of supplying the remainder of the CO ₂ lean absorbent and / or the CO ₂ lean absorbent heated in step (III) to the carbon dioxide absorption step (I),
A method for recovering carbon dioxide in a gas to be treated.
[11] The method for recovering carbon dioxide in the gas to be treated according to [10], further comprising a step (V) of heating the CO ₂ lean absorbent heated in the step (III) in the presence of an alkali component.

According to the method of the present invention, it is possible to efficiently decompose nitrosated products of amines by-produced in the absorption liquid without installing new additional equipment and almost no decomposition of amines having CO ₂ absorption ability. To amines.

It is a figure which shows one Embodiment of the apparatus for implementing the decomposition | disassembly method of a nitroso compound (A). It is a figure which shows one Embodiment of the apparatus for implementing the decomposition | disassembly method of a nitroso compound (A). It is a figure which shows one Embodiment of the reclaiming apparatus for enforcing the decomposition | disassembly method of a nitroso compound (A). It is a figure which shows one Embodiment of the apparatus for implementing the carbon dioxide collection method of this invention.

  In the method for decomposing a nitrosated product of an amine according to an embodiment of the present invention, a liquid to be treated containing the nitroso compound (A) is at least the boiling point of water and not more than the boiling point of the amine in the presence of hydrohalic acid. Heating at a temperature of

Examples of amines include primary amines, secondary amines, and tertiary amines.
Examples of the primary amine include monoalkanolamines such as monomethanolamine and monoethanolamine; alkylamines such as methylamine and ethylamine.
Secondary amines include dialkylamines such as dimethylamine, diethylamine, methylethylamine, t-butylethylamine and dibutylamine; dialkanolamines such as dimethanolamine and diethanolamine; N-methyl-N- (hydroxyethyl) amine, N N- such as -ethyl-N- (hydroxyethyl) amine, N-ethyl-N- (hydroxybutyl) amine, N-isopropyl-N- (hydroxyethyl) amine, N-methyl-N- (hydroxypropyl) amine Alkyl-N- (hydroxyalkyl) amine; cyclic amines such as heptamethyleneimine, piperazine, piperidine, morpholine, and the like.
Examples of the tertiary amine include trialkylamines such as trimethylamine and triethylamine, trialkanolamines such as trimethanolamine and triethanolamine; and cyclic amines such as quinuclidine and pyridine.
Of these, alkanolamines are preferable, and N-hydroxyalkylamine and N-alkyl-N-hydroxyalkylamine are more preferable.

The nitroso compound (A) contained in the liquid to be treated used in the present invention includes nitroso compounds [nitrosoalkanes] represented by RN = O generated by oxidation of primary amine (RNH ₂ ), primary amine (RNH ₂ ) or N-nitroso compounds [N-nitrosamines] represented by RNH-N = O or R ₂ NN = O produced by reaction of secondary amine (R ₂ NH) with nitrous acid, etc. . R is an N-substituent such as an alkyl group or a hydroxyalkyl group. The nitroso compound represented by RN = O may be mutated to an oxime when R is a primary alkyl group or a secondary alkyl group. In the present invention, these tautomers are also included in the nitroso compound (A). In addition, the nitrosoalkane may be a dimer, and in the present invention, this dimer is also included in the nitroso compound (A). N-nitrosamine represented by RNH-N = O is an unstable substance and decomposes at room temperature to be mutated to diazo hydroxide. In the present invention, this tautomer is also included in the nitroso compound (A).

  Specific examples of the nitroso compound (A) include N-nitrosodiethanolamine, N-nitrosoheptamethyleneimine, N-nitrosodimethylamine, N-nitrosodiethylamine, N-nitrosomethylhydroxyethylamine, N-ethyl-N- (2- Hydroxyethyl) nitrosamine, N-tert-butyl-N-ethylnitrosamine, N-nitrosodibutylamine, N-ethyl-N- (4-hydroxybutyl) nitrosamine, N-butyl-N- (4-hydroxybutyl) nitrosamine, N-nitrosomorpholine etc. are mentioned. Of these, the nitroso compound (A) that is dissolved or mixed in water is preferably used as the decomposition target of the method according to the present invention.

  As the liquid to be treated containing such a nitroso compound (A), an aqueous amine solution (hereinafter sometimes referred to as an absorbing liquid) used for absorbing carbon dioxide in combustion exhaust gas is preferably used. The absorbing liquid is an aqueous solution containing at least amines as main components and a nitroso compound (A) as impurities.

  Since the boiling point of the nitroso compound (A) is often higher than the boiling point of the amines, the decomposition method of the present invention is performed after concentrating the nitroso compound (A) by distilling off the amines from the liquid to be treated. It is preferable. If the amount of amines in the liquid to be treated is small, the amount of hydrohalic acid consumed by the reaction with the amines is reduced, and the amount of hydrohalic acid added for decomposition can be reduced. In addition, amines that are unnecessarily decomposed by heating to decompose the nitroso compound (A) can be reduced. It is also preferable to reduce the amount of water in the liquid to be treated. This is because, as will be described later, nitrile halide produced as a by-product reacts with water to produce nitrous acid, and this nitrous acid may nitrosate amines again.

Examples of the hydrohalic acid used in the present invention include at least one selected from the group consisting of hydrochloric acid, hydrobromic acid, and hydroiodic acid. The amount of hydrohalic acid is preferably 100 mol parts or more relative to 100 mol parts of the total amount of amino groups and nitroso groups as the amount of hydrogen halide. The amount of nitroso group includes the amount of tautomers. By making the amount of hydrogen halide larger than the total amount of amino groups and nitroso groups, the amines regenerated from the nitroso compound (A) react with the hydrogen halide to form a heat-stable salt, and the nitroso compound Unnecessary thermal decomposition of amines regenerated from (A) can be prevented.
Further, the pH of the liquid to be treated is preferably less than 5, more preferably less than 3, and even more preferably less than 2.

  The decomposition of the nitroso compound (A) is performed by heating to a temperature not lower than the boiling point of water and not higher than the boiling point of the amines. The details of the decomposition process of the nitroso compound (A) according to the present invention are not clear, but it is assumed that it is decomposed by a chemical reaction as shown in the following formula, for example. By this decomposition, the nitroso compound (A) can be regenerated to the original amines.

  The YNO nitrosyl halide produced as a by-product in this decomposition reaction produces nitrous acid as a by-product by reaction with water. Heating above the boiling point of water vaporizes the water, reducing the opportunity for reaction between water and nitrile halide and suppressing the production of nitrous acid. In addition, halogenated nitrosyl has a boiling point, for example, nitrosyl chloride is −6.4 ° C., which is often lower than amines. Therefore, by adjusting the heating temperature for decomposing the nitroso compound (A), the nitrosyl halide is reduced. It can be removed by vaporization.

  Of the amines contained in the liquid to be treated, those that have reacted with hydrogen halide to form a heat-stable salt are not decomposed even by heating to decompose the nitroso compound (A). However, the heat-stable non-chlorinated amines are somewhat decomposed by heating for decomposing the nitroso compound (A). Therefore, the heating temperature is preferably as low as possible. In order to easily balance the vaporization of water, the decomposition of amines and the promotion of decomposition of the nitroso compound (A), the pressure is set to a pressure below atmospheric pressure, preferably the boiling point of water suppresses the thermal decomposition of amines. It is preferable to heat by lowering the pressure to a sufficient temperature or lower, more preferably to a pressure at which the boiling point of the mixture of amines containing nitrosated amines and hydrohalic acid is 100 ° C. or lower.

A method for recovering carbon dioxide in a gas to be treated according to an embodiment of the present invention comprises contacting a gas to be treated containing carbon dioxide with a CO ₂ lean absorbing solution containing amines to convert the carbon dioxide into CO ₂ lean. is absorbed in the absorbing liquid, to obtain a CO ₂ rich absorbent solution (I), the step of carbon dioxide by heating the CO ₂ rich absorbent solution desorbed to play CO ₂ lean absorbing solution (II), is reproduced A part of the CO ₂ lean absorbing solution was regenerated in steps (III) and (II) in which heating was performed in the presence of hydrohalic acid above the boiling point of water and below the boiling point of amines. A step (IV) of supplying the remainder of the CO ₂ lean absorbing solution and / or the CO ₂ lean absorbing solution heated in the step (III) to the carbon dioxide absorbing step (I).

The method for recovering carbon dioxide in the gas to be treated according to an embodiment of the present invention can be performed by, for example, an apparatus as shown in FIG.
In the present invention, step (I), step (II) and step (IV) are usually performed continuously and simultaneously.
Step (I): The gas 11 to be treated is supplied to the bottom 3 of the absorption tower 1 by the blower 12, rises in the packed bed 2, and is discharged as a treated gas 4 from the top. The gas to be treated 11 may have a pressure equal to or higher than normal pressure, or may be normal pressure. The temperature of the gas to be treated 11 is preferably 100 ° C. or lower. A CO ₂ lean absorbing liquid containing amines is poured from the nozzle 6 onto the top of the packed bed 2 and comes into contact with the gas to be treated in the packed bed 2 to absorb carbon dioxide in the gas to be treated, and the bottom of the absorption tower Accumulate at 10. The liquid accumulated in the bottom 10 is rich in carbon dioxide and is called a CO ₂ rich absorption liquid.

Step (II): The CO ₂ rich absorbent extracted from the bottom 10 is heated by the heat exchanger 22 and poured from the nozzle 14 onto the top of the packed bed 15 of the regeneration tower (desorption tower) 13. The poured liquid descends through the packed bed 15 and accumulates at the bottom of the desorption tower. As will be described later, the liquid accumulated at the bottom of the desorption tower has a low carbon dioxide content and is called a CO ₂ lean absorbing liquid. A reboiler 23 is installed at the bottom of the tower. Steam vaporized by the reboiler ascends the packed bed 2 and heats the CO ₂ rich absorbent that descends the packed bed 2 to desorb carbon dioxide. The desorbed carbon dioxide is removed by mist in the water washing section 26 and discharged from the top of the desorption tower. Further, water is recovered by the separator 17, carbon dioxide is sent to the next step through the pipe 18, and the recovered water is supplied to the water washing section 26 of the desorption tower or the nozzle 9 at the top of the absorption tower.

Step (IV): The CO ₂ lean absorbent stored at the bottom of the desorption tower is cooled by the heat exchanger 22 and returned to the absorption tower 1.

In the present invention, step (III) may be carried out continuously at all times, but it is preferred from the viewpoint of energy saving that the step (III) is carried out when the CO ₂ absorption capacity of the absorbing solution is reduced. The decrease in the CO ₂ absorption capacity of the absorbing solution is caused by an increase in the amount of heat-stable salt and / or nitroso compound (A) in the absorbing solution, as already described. The amount of the heat stable salt and the nitroso compound (A) in the absorbing solution can be measured by a known method.

Step (III): When the valve 30 is opened, water vapor is sent to the heat transfer tube of the reclaiming device 24. The CO ₂ lean absorbent extracted from the bottom of the desorption tower 13 is heated by the heat transfer tube of the reclaiming device 24. The amines and water contained in the CO ₂ lean absorbent are vaporized and returned to the desorption tower. The heat stable salt and nitroso compound (A) are concentrated. Hydrohalic acid is supplied to the concentrated liquid, and the concentrated liquid is heated in the presence of hydrohalic acid. In this way, the nitroso compound (A) is regenerated into amines before nitrosation. The heating temperature is not lower than the boiling point of water and not higher than the boiling point of the amines. The pressure during heating is preferably not more than atmospheric pressure. The regenerated amines are vaporized and returned to the desorption tower. The amines that cannot be returned react with hydrohalic acid to form heat stable salts.
Step (V): If the heat-stable salt remains in the CO ₂ lean absorbent heated in step (III), remove it from the reclaiming device 24 as sludge, or use an alkali component (for example, alkali metal hydroxide, Heat-stable salt is regenerated to amines by adding and heating an alkali metal carbonate. The regenerated amines can be vaporized and returned to the desorption tower.

  The present invention will be described more specifically with reference to the following examples. In addition, this invention is not limited by these Examples.

  The apparatus used in the examples is merely an example, and does not limit the scope of implementation. For example, similar results can be obtained by using other equipment such as a mantle heater or a ribbon heater for heating the liquid, a round bottom flask as a container, and a Liebig tube as a cooling pipe.

The amount of the nitroso compound was measured with a GC (gas chromatograph) -TEA (thermal energy analysis) apparatus (TEA-800 manufactured by Ellutia).
The amount of the amine compound was measured with an ion chromatograph (ICS-1500, manufactured by DIONEX). The amount of the amine compound includes an amount obtained by converting amine chloride into an amine compound by weight.

Example 1
It implemented using the apparatus shown in FIG.
Diethanolamine (C ₄ H ₁₁ NO ₂ , DEA, molecular weight 105 g / mol, boiling point 268.8 ° C (according to Showa Chemical MSDS)) 8.5 parts by mass (80.95 parts by mole), moisture 1.499 parts by weight, and nitrosodiethanolamine (C ₄ H ₁₀ N A mixed solution of 0.001 part by mass (0.007 mol part) of ₂ O ₃ , NDEA, molecular weight 134 g / mol) was prepared.

To the flask 103, the mixed solution was added, and hydrochloric acid (hydrogen chloride concentration 36% by mass) 8.62 parts by mass (85.11 mol parts) was added thereto. The pH of the preparation was less than 1.
The flask 103 was immersed in an oil bath 101 in which silicone oil 102 adjusted to a temperature of 140 ° C. was stored, and the prepared solution was heated for 30 minutes. The flask 103 is connected to the cooling pipe 105 via a connecting pipe 107. The upper part of the flask 103 and the connecting pipe 107 are heated by the heater 106 so as not to condense. The gas evaporated in the flask 103 was condensed in a cooling pipe 105 in which 20 ° C. cooling water 108 circulated, and the condensate 109 was collected in a collection bottle (not shown).

The amount of the nitroso compound contained in the condensate 109 and the amount of the nitroso compound contained in the liquid remaining in the flask 103 were measured, and the total was calculated. The total amount of nitroso compounds was below the detection limit. That is, the nitroso compound was completely decomposed.
Further, the amount of amine compound contained in the condensate 109 and the amount of amine compound contained in the liquid remaining in the flask 103 were measured, and the total was calculated. The total amount of the amine compound did not change from the amount of the amine compound contained in the preparation solution. That is, the amine compound did not decompose.

Comparative Example 1
The same procedure as in Example 1 was performed except that 8.62 parts by mass of water was added instead of hydrochloric acid. The total amount of the amine compound and the nitroso compound was not changed from the amount of the amine compound and the amount of the nitroso compound contained in the preparation solution. The nitroso compound did not decompose at all.

Comparative Example 2
The same procedure as in Example 1 was performed except that the apparatus shown in FIG. 2 (heating at 280 ° C. with a mantle heater 206 instead of heating with the oil bath 101) was used. The total amount of nitroso compounds was below the detection limit. Moreover, the total amount of amine compounds was reduced to about 70%. That is, although the nitroso compound was completely decomposed, the amine compound useful for CO ₂ absorption was also decomposed simultaneously with the decomposition of the nitroso compound.

Example 2
The same procedure as in Example 1 was performed except that the temperature of the silicone oil 102 was changed to 110 ° C. and the heating time was changed to 1 hour. The total amount of nitroso compounds was almost below the detection limit. That is, the nitroso compound was almost completely decomposed. The total amount of the amine compound was not changed from the amount of the amine compound contained in the preparation solution. That is, the amine compound did not decompose.

Comparative Example 3
The same procedure as in Example 1 was performed except that the temperature of the silicone oil 102 was changed to 90 ° C. and the heating time was changed to 1 hour. The total amount of the amine compound and the nitroso compound was not changed from the amount of the amine compound and the amount of the nitroso compound contained in the preparation solution. The nitroso compound did not decompose at all.

Comparative Example 4
The same procedure as in Example 2 was performed except that 8.62 parts by mass of water was added instead of hydrochloric acid. The total amount of the amine compound and the nitroso compound was not changed from the amount of the amine compound and the amount of the nitroso compound contained in the preparation solution. The nitroso compound did not decompose at all.

Example 3
It implemented by the same method as Example 2 except having added 14.2 mass parts (84.24 mol parts) of hydrobromic acid (hydrogen bromide concentration 48 mass%) instead of hydrochloric acid. The total amount of nitroso compounds was below the detection limit. That is, the nitroso compound was completely decomposed. The total amount of the amine compound was not changed from the amount of the amine compound contained in the preparation solution. That is, the amine compound did not decompose.

Example 4
It implemented by the same method as Example 2 except having added 19.1 mass parts (85.11 mol parts) of hydroiodic acid (concentration of hydrogen iodide 57 mass%) instead of hydrochloric acid. The total amount of nitroso compounds was below the detection limit. That is, the nitroso compound was completely decomposed. The total amount of the amine compound was not changed from the amount of the amine compound contained in the preparation solution. That is, the amine compound did not decompose.

Example 5
The same procedure as in Example 1 was carried out except that N-din-butylamine was used instead of diethanolamine and N-nitrosodin-butylamine (boiling point 237 ° C.) was used instead of nitrosodiethanolamine. The total amount of nitroso compounds was below the detection limit. That is, the nitroso compound was completely decomposed. The total amount of the amine compound was not changed from the amount of the amine compound contained in the preparation solution. That is, the amine compound did not decompose.

Example 6
Use N-ethylaminoethanol instead of diethanolamine, and N-ethyl-N- (2-hydroxyethyl) nitrosamine (vapor pressure of 3 mmHg at 103 ° C) instead of nitrosodiethanolamine, and the temperature of silicone oil 102 to 103 ° C The same method as in Example 1 was carried out except that the change was made. The total amount of nitroso compounds was below the detection limit. That is, the nitroso compound was completely decomposed. The total amount of the amine compound was not changed from the amount of the amine compound contained in the preparation solution. That is, the amine compound did not decompose.

Example 7
Piperazine (divalent amine compound, molecular weight 86 g / mol) 1.0 part by mass (11.63 mol part), water 8.999 parts by mass, and 1-nitrosopiperazine (molecular weight 115 g / mol, boiling point 265 ° C.) 0.001 part by mass (0.009 mol part) A mixed solution was prepared.
The same procedure as in Example 1 was performed except that the mixed solution used in Example 1 was changed to the above mixed solution, and the amount of hydrochloric acid (hydrogen chloride concentration: 36 mass%) was changed to 2.53 parts by mass (25.0 mol parts). The total amount of nitroso compounds was below the detection limit. That is, the nitroso compound was completely decomposed. The total amount of the amine compound was not changed from the amount of the amine compound contained in the preparation solution. That is, the amine compound did not decompose.

Example 8
Compared except that the recovery bottle connected to the cooler 105 is connected to an aspirator (Yamato WP-15) and continuously evacuated to change the pressure in the flask 103 to 50 kPa absolute and the temperature of the cooling water to 4 ° C. Performed in the same manner as Example 3. At this time, the boiling point of water was about 82 ° C. The total amount of nitroso compounds was almost below the detection limit. That is, the nitroso compound was almost completely decomposed. The total amount of the amine compound was not changed from the amount of the amine compound contained in the preparation solution. That is, the amine compound did not decompose. It was confirmed that the decomposition of the nitroso compound was promoted by lowering the pressure to the atmospheric pressure or lower even at a low temperature at which the decomposition of the nitroso compound did not proceed under atmospheric pressure (see Comparative Example 3).

Example 9
A mixed liquid of 9.999 parts by mass of water and 0.001 parts by mass (0.007 mol parts) of nitrosodiethanolamine was prepared.
The same procedure as in Example 1 was performed except that the mixed solution used in Example 1 was changed to the above mixed solution, and the amount of hydrochloric acid (hydrogen chloride concentration: 36% by mass) was changed to 0.0112 parts by mass (0.11 mol part). The total amount of nitroso compounds was below the detection limit. That is, the nitroso compound was completely decomposed. On the other hand, an amine compound that was not contained in the preparation solution was detected. It was confirmed that the amine compound was produced by decomposition of the nitroso compound.

Example 10
The reclaiming apparatus shown in FIG. 3 was used.
The liquid 13 having the same composition as the prepared liquid prepared in Example 1 was put into the reclaiming container 308 through the supply port 311, and the liquid 13 was heated by supplying steam 301 at 140 ° C. to the heat transfer tube 309. During heating, the gas from the exhaust port 312 was cooled to 20 ° C. to recover the condensate. The liquid remaining in the reclaiming container 308 after reclaiming was extracted from the outlet 310.
The amount of the nitroso compound contained in the condensate and the amount of the nitroso compound contained in the solution extracted from the outlet 310 were measured and the total was calculated. The total amount of nitroso compounds was below the detection limit. That is, the nitroso compound was completely decomposed.
Further, the amount of the amine compound contained in the condensed liquid and the amount of the amine compound contained in the liquid extracted from the outlet 310 were measured and the total was calculated. The total amount of the amine compound was not changed from the amount of the amine compound contained in the preparation solution. That is, the amine compound did not decompose. It was confirmed that the nitroso compound could be decomposed by the reclaiming device.

101 oil bath, 102 silicone oil, 103 flask, 105 condenser,
106 heater, 107 connecting pipe, 108 cooling water, 109 condensate, 206 mantle heater,
308 reclaiming vessel, 309 heat transfer tube, 301 water vapor, 302 drain,
310 Fluid outlet, 311 Fluid supply port, 312 Exhaust port

Claims (10)

In the presence of hydrohalic acid in an amount such that the amount of hydrogen halide is 100 mol parts or more with respect to 100 mol parts of the total amount of amino groups and nitroso groups , the liquid to be treated containing nitrosates of amines is treated with water. Heating at a temperature above the boiling point of the amine and below the boiling point of the amines,
A method for decomposing amine nitrosates.   The method for decomposing a nitrosated product of amines according to claim 1, wherein the liquid to be treated further contains amines. The method for decomposing amine nitrosates according to claim 1 or 2 , wherein the liquid to be treated is an aqueous amine solution used to absorb carbon dioxide in combustion exhaust gas. The method for decomposing a nitrosated product of an amine according to any one of claims 1 to 3 , wherein the hydrohalic acid is at least one selected from the group consisting of hydrochloric acid, hydrobromic acid, and hydroiodic acid. . It said heating is carried out at a pressure of below atmospheric pressure, according to claim 1 in the degradation process of nitroso compound of amines according to any one of 4, including at least amines to nitroso compound of amines with hydrogen halide A method for decomposing a nitrosated product of an amine, wherein the pressure is adjusted so that the boiling point of the acid mixture is 100 ° C or lower. The method for decomposing a nitrosated product of an amine according to any one of claims 1 to 5 , wherein the amine is an alkanolamine. The method for decomposing amine nitrosates according to any one of claims 1 to 6 , further comprising heating in the presence of an alkali component after heating in the presence of hydrohalic acid. Heating the liquid to be treated containing a nitrosated product of amines to a pH of less than 3 with hydrohalic acid at a temperature not lower than the boiling point of water and not higher than the boiling point of the amines.
A method for decomposing amine nitrosates. A step (I) of obtaining a CO ₂ rich absorbent by contacting a gas to be treated containing carbon dioxide with a CO ₂ lean absorbent containing amines to absorb carbon dioxide in the CO ₂ lean absorbent;
A step of heating the CO ₂ rich absorbent to desorb carbon dioxide and regenerating it into a CO ₂ lean absorbent (II),
Halogenation of a portion of the CO ₂ lean absorbing solution that is regenerated and containing nitrosated amines such that the amount of hydrogen halide is 100 mol parts or more with respect to 100 mol parts of the total amount of amino groups and nitroso groups in the presence of hydrochloric acid, at a temperature below the boiling point of and amines in water above the boiling point, heating to Ru to decompose the nitroso compound step (III), and step (II) CO ₂ lean absorbent reproduced by Supplying the remainder of the liquid and / or the CO ₂ lean absorbing liquid heated in step (III) to the carbon dioxide absorbing step (I) (IV),
A method for recovering carbon dioxide in a gas to be treated. The method for recovering carbon dioxide in the gas to be treated according to claim 9 , further comprising a step (V) of heating the CO ₂ lean absorbent heated in the step (III) in the presence of an alkali component.

Images