JP6122405B2 - HYDROGEN GENERATOR, METHOD FOR PRODUCING HYDROGEN GENERATOR, METHOD FOR PRODUCING HIGH CONCENTRATION HYDROGEN WATER, AND HIGH CONCENTRATION HYDROGEN WATER THEREOF - Google Patents
HYDROGEN GENERATOR, METHOD FOR PRODUCING HYDROGEN GENERATOR, METHOD FOR PRODUCING HIGH CONCENTRATION HYDROGEN WATER, AND HIGH CONCENTRATION HYDROGEN WATER THEREOF Download PDFInfo
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Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Description
この発明は、水素発生技術に関連するものであり、特に、水素水の製造に用いる水素発生剤、および、それを利用した高濃度水素水を製造、提供する分野は勿論のこと、その輸送、保管、組み立ておよび設置に必要となる設備、器具類を提供、販売する分野から、それら資材や機械装置、部品類に必要となる素材、例えば、木材、石材、各種繊維類、プラスチック、各種金属材料等を提供する分野、それらに組み込まれる電子部品やそれらを集積した制御関連機器の分野、各種計測器の分野、当該設備、器具を動かす動力機械の分野、そのエネルギーとなる電力やエネルギー源である電気、オイルの分野といった一般的に産業機械と総称されている分野、更には、それら設備、器具類を試験、研究したり、それらの展示、販売、輸出入に係わる分野、将又、それらの使用の結果やそれを造るための設備、器具類の運転に伴って発生するゴミ屑の回収、運搬等に係わる分野、それらゴミ屑を効率的に再利用するリサイクル分野などの外、現時点で想定できない新たな分野までと、関連しない技術分野はない程である。 The present invention relates to hydrogen generation technology, in particular, a hydrogen generating agent used for the production of hydrogen water, and the field of producing and providing high-concentration hydrogen water using the same, as well as its transportation, Materials necessary for storage, assembly and installation, and equipment and instruments necessary for storage, assembly and installation, materials required for such materials, machinery and parts, such as wood, stone, various fibers, plastics, various metal materials Etc., the electronic components incorporated in them, the field of control-related equipment that integrates them, the field of various measuring instruments, the field of power equipment that moves the equipment and instruments, and the power and energy sources that serve as the energy Fields generally referred to as industrial machinery, such as the field of electricity and oil, as well as testing and researching those facilities and equipment, as well as exhibiting, selling, importing and exporting them. Fields, generals, and results of their use, facilities for making them, fields related to the collection and transportation of garbage generated by the operation of equipment, and recycling fields that efficiently reuse these garbage In addition, there are no technical fields that are not related to new fields that are currently unimaginable.
（着目点）
水素水は、水に水素分子を含み、人体内の活性酸素を減少させ、老化予防、腸内環境の改善、血液をサラサラにするダイエット、デトックス、美容、記憶力アップなど様々な効能を有するものとして広く知られ、電解水素水生成器や水素水サーバーの外、アルミパウチやペットボトル、アルミ缶などに詰めたもの、または、水素発生型スティックなど、多様な商品が販売、利用されている。
(Points of interest)
Hydrogen water contains hydrogen molecules in water, reduces active oxygen in the human body, has various effects such as aging prevention, improvement of intestinal environment, smooth blood, diet, detox, beauty, memory improvement, etc. A wide variety of products such as hydrogen pouches, plastic bottles, aluminum cans, etc., or hydrogen generation sticks are sold and used in addition to electrolyzed hydrogen water generators and hydrogen water servers.
電解水素水生成器は、水タンクや水素生成部などを有し、電源のある適切な場所に設置する必要がある上、高価なことも手伝って誰もが気軽に購入して利用できるものではなく、水素水サーバーも適切な設置場所を要し、保管中の水素水中から水素が抜けてしまう虞があり、ペットボトルなどに詰められた水素水も水素が抜けてしまう虞があり、さらには、水自体を保管、輸送しなければならず、保管・輸送コストが嵩むといった問題もであり、こうした実情の中、水素発生型スティックのように、ボトルなどの容器に充填した水に該スティックを投入するだけで水素水を得ることができるタイプのものが、経済的にも有利で気軽に購入・利用することができるという理由から好評を博してきており、一層、幅広い市場を獲得するには、水素をより効率的且つ経済的に発生可能とする水素発生剤の開発が待望視されている。 An electrolytic hydrogen water generator has a water tank, a hydrogen generator, etc., and it must be installed in a suitable place with a power source. In addition, it is expensive and can be easily purchased and used by anyone. The hydrogen water server also requires an appropriate installation location, there is a risk that hydrogen will escape from the hydrogen water being stored, hydrogen water packed in PET bottles etc. may also escape hydrogen, However, the water itself must be stored and transported, and storage and transport costs increase. Under such circumstances, the stick is applied to water filled in a container such as a hydrogen-generating stick. The type that can obtain hydrogen water just by charging it has gained popularity because it is economically advantageous and can be purchased and used easily. To acquire a wider market ,hydrogen More efficient and development of hydrogen generating agent to economically feasible generation is awaited vision.
（従来の技術）
こうした状況を反映し、その打開策となるような提案もこれまでに散見されない訳ではない。
例えば、下記する特許文献１（１）に提案されているものに代表されるように、原水と接触することで水素を発生させ水素溶液をつくる水素発生剤としてのアルミニウム、亜鉛、ニッケル、またはコバルトの中、何れか一つ以上と、金属イオン封鎖能とｐＨ調整能を有する一剤とを接触して含有する水素発生系を隔離体に収容し、前記金属イオン封鎖能とｐＨ調整能を有する一剤が、金属イオンの吸着と共に、水素イオンを放出する物質、または加水分解を受け水酸化金属を生成する化合物の中、少なくとも何れか一方を含み、前記金属イオンの吸着と共に、水素イオンを放出する物質、または加水分解を受け水酸化金属を生成する化合物は、水素イオン型陽イオン交換樹脂、ミョウバン、または水酸化マグネシウムの中、少なくとも何れか一つを含むものとし、原水で水素発生反応を促進することにより、マグネシウムイオン（あるいは、水素発生の際に水素発生剤より溶出する陽イオンなど副生成物）が増加することなく、かつ、原水のｐＨも変えることのない、高濃度または過飽和水素溶液を得ることができ、こうした器具を用いれば、家庭や職場、街中、店頭などといった場所を問わず、任意の飲料の香味を変化させることなく、簡単に高濃度水素飲料を製造できるものとした非破壊的高濃度水素溶液の製造器具がある。
(Conventional technology)
Reflecting this situation, proposals that can be used to overcome this situation are not unheard of.
For example, as represented by the following proposed in Patent Document 1 (1), aluminum, zinc, nickel, or cobalt as a hydrogen generator that generates hydrogen solution by generating hydrogen by contact with raw water Among them, a hydrogen generating system containing one or more of them and one agent having a sequestering ability and a pH adjustment ability is contained in a separator, and has the sequestering ability and the pH regulation ability. One agent contains at least one of a substance that releases hydrogen ions together with adsorption of metal ions, or a compound that generates metal hydroxide upon hydrolysis, and releases hydrogen ions together with adsorption of the metal ions. The compound to be hydrolyzed to produce metal hydroxide is at least one of hydrogen ion cation exchange resin, alum, and magnesium hydroxide. By promoting the hydrogen generation reaction with raw water, magnesium ions (or by-products such as cations eluted from the hydrogen generator during hydrogen generation) do not increase, and the pH of the raw water High concentration or supersaturated hydrogen solution can be obtained without any change, and with such equipment, it is easy to change the flavor of any beverage at home, at work, in the city, in stores, etc. In addition, there is a non-destructive high concentration hydrogen solution production tool that can produce a high concentration hydrogen beverage.
また、特許文献１（２）に見られるような、水中に投入することで水を分解し還元して、還元水素水に変化させる還元水素水生成剤であって、表面が徐酸化処理されたＭｇナノ粒子を主成分としたものは、それを用いて還元水素水に溶解するＭｇ成分は、人体に悪影響を及ぼさない微量なものであり、一般に得ることができる水を、飲用時に即座に還元水素水に変化させることができるものなどが散見される。 In addition, as shown in Patent Document 1 (2), a reducing hydrogen water generator that decomposes and reduces water by being introduced into water to convert it into reduced hydrogen water, and the surface is subjected to gradual oxidation treatment. The main component of Mg nanoparticles is the Mg component that dissolves in the reduced hydrogen water using it, which is a trace amount that does not adversely affect the human body. Generally, water that can be obtained is immediately reduced at the time of drinking. Some things can be changed to hydrogen water.
しかし、前者特許文献１（１）に示されているような非破壊的高濃度水素溶液の製造器具類は、水素発生剤としてアルミニウム、亜鉛、ニッケルまたはコバルトの中、何れか一つ以上、および、金属イオン封鎖剤として、例えば、スルホン酸基を交換基とする酸性陽イオン交換樹脂またはカルボン酸基を交換基とする酸性陽イオン交換樹脂を含む、水素イオン型陽イオン交換樹脂や、ミョウバン、酸化（または水酸化）マグネシウムなどを用いるものとしているが、それらは何れも、それのみでは固形状に成形することが困難なため、不織布の袋に漏出しないよう確りと包装した上、多孔（透水性）容器などの隔離体に収容するものとしなければならず、漏出防止のため、水素水生成剤、金属イオン封鎖剤などの粒径に制限を受けてしまうという欠点がある。 However, the non-destructive high-concentration hydrogen solution production instrument as shown in the former Patent Document 1 (1) is one or more of aluminum, zinc, nickel or cobalt as a hydrogen generator, and As the sequestering agent, for example, an acid cation exchange resin having an sulfonic acid group as an exchange group or an acid cation exchange resin having an carboxylic acid group as an exchange group, a hydrogen ion cation exchange resin, alum, Although it is assumed that magnesium oxide (or hydroxide) is used, all of them are difficult to be molded into a solid form by themselves, so that they are securely packaged so as not to leak into a non-woven bag, and porous (water permeable) If the particle size of the hydrogen water generating agent, sequestering agent, etc. is limited to prevent leakage, There is a cormorant drawbacks.
また、後者特許文献１（２）に代表する還元水素水生成剤などは、通常の飲料水を飲用時、即座に還元水素水に変化させることができるという効果を得るためにＭｇナノ粒子を用いるものとしているが、Ｍｇナノ粒子は、極めて活性が高く、大気中に取り出すと空気と反応し燃焼してしまうという危険性があり、１％Ｏ２−Ａｒ以下の雰囲気中に数時間以上放置し、Ｍｇナノ粒子表面に薄い酸化被膜を形成・安定化させるという工程を要し、酸化被膜を形成するまでのＭｇナノ粒子を取り扱う危険性を残すものであり、安全に生産するには、より厳重な管理態勢が不可欠となり、生産コストを高騰させてしまう虞があった。
（問題意識）
上述したとおり、従前までに提案のあるこれら各種非破壊的高濃度水素溶液の製造器具類などは、水素水生成剤や金属イオン封鎖剤に、互いを塊状に成形可能とする機能を有しておらず、隔離体に漏出しないよう収容するためには、夫々の粒径を漏出しない大きさに設定せざるを得ず、水素の発生速度を高めるのが難しいという欠点を有し、また、従前までのＭｇナノ粒子を用いた還元水素水生成剤などは、その活性の高さが製造工程の安全確保を困難なものにしてしまうという欠点が残るものであり、安全な生産態勢を確保し、取扱い性を高め、生産コストを削減可能とする上、長期間に渡って高濃度の水素を発生可能とする経済性を兼ね備えた新規な水素発生剤、およびその製造技術開発の可能性を痛感するに至ったものである。
(Awareness of problems)
As described above, these various non-destructive high concentration hydrogen solution production tools that have been proposed in the past have a function that enables a hydrogen water generating agent and a metal ion sequestering agent to be formed into a mass. In order to store the particles so as not to leak into the separator, each particle size must be set to a size that does not leak, and it is difficult to increase the hydrogen generation rate. The reduced hydrogen water generating agent using Mg nanoparticles up to the defect remains that the high activity makes it difficult to ensure the safety of the manufacturing process, ensuring a safe production system, We are impressed with the possibility of developing a novel hydrogen generator and its manufacturing technology that can be handled and reduced in production costs, and has the economy of being able to generate high concentrations of hydrogen over a long period of time. Has been reached.
（発明の目的）
そこで、この発明は、生産効率を高め、利用し易い形状・寸法のものとし、より高濃度の水素水を迅速に製造し、しかも、より長期間に渡り、高濃度水素水を安定して製造可能とする経済性を兼ね備えた新たな水素発生技術の開発はできないものかとの判断から、逸速くその開発、研究に着手し、長期に渡る試行錯誤と幾多の試作、実験とを繰り返してきた結果、今回、遂に新規な構造の水素発生剤、その新規な水素発生剤の製造方法、新規な高濃度水素水の製造方法、および、それらによる新規な高濃度水素水を実現化することに成功したものであり、以下では、図面に示すこの発明を代表する実施例と共に、その構成を詳述することとする。
(Object of invention)
Therefore, the present invention increases the production efficiency, has a shape and size that is easy to use, and quickly manufactures high concentration hydrogen water, and stably manufactures high concentration hydrogen water for a longer period of time. Judging whether it is possible to develop a new hydrogen generation technology that has the economics of enabling it, the results of the rapid start of its development and research, repeated trial and error over many years, and many trials and experiments This time, we have finally succeeded in realizing a hydrogen generator having a novel structure, a method for producing the new hydrogen generator, a method for producing a new high-concentration hydrogen water, and a new high-concentration hydrogen water using them. In the following, the configuration thereof will be described in detail together with an embodiment representative of the present invention shown in the drawings.
（発明の構成）
図面に示すこの発明を代表する実施例からも明確に理解されるように、この発明の水素発生剤は、基本的に次のような構成から成り立っている。
即ち、水に接して水素を発生する金属材料からなる水素発生原料と、水との接触状態を調整可能とする食用油および天然油の何れか少なくとも一種からなる封鎖用油脂とを、その混合重量比率を、３：７ないし１：９の割合となるようにし、水素溶出速度調整機能を付与可能なポリエチレングレコールが適量添加、均質に混合され、所定形状に成形、固形化されてなるものとした構成を要旨とする水素発生剤である。
(Structure of the invention)
As can be clearly understood from the embodiments representing the present invention shown in the drawings, the hydrogen generating agent of the present invention basically comprises the following constitution.
That is, a mixed weight of a hydrogen generating raw material made of a metal material that generates hydrogen in contact with water, and a sealing oil and fat made of at least one of edible oil and natural oil that can adjust the contact state with water The ratio is set to a ratio of 3: 7 to 1: 9, and an appropriate amount of polyethylene glycol capable of providing a hydrogen elution rate adjusting function is added, mixed homogeneously, molded into a predetermined shape , and solidified. This is a hydrogen generating agent having the structure as described above.
（関連する発明１）
上記した水素発生剤に関連し、この発明には、その製造方法をも包含している。
即ち、水素発生原料に封鎖用油脂を、３：７ないし１：９の混合重量比率にて混合し、１００℃以下の室温下にて均質に攪拌した上、−１５ないし５℃に冷却して所定形状に成形、固形化するようにしてなるものとした構成からなる水素発生剤の製造方法である。
(Related invention 1)
In relation to the above-described hydrogen generating agent, the present invention also includes a production method thereof.
That is, oil for sealing is mixed with the hydrogen generating raw material at a mixing weight ratio of 3: 7 to 1: 9, stirred uniformly at room temperature of 100 ° C. or lower, and cooled to −15 to 5 ° C. This is a method for producing a hydrogen generating agent having a configuration that is formed and solidified into a predetermined shape.
（関連する発明２）
上記した水素発生剤に関連し、この発明には、その水素発生剤を利用した高濃度水素水の製造方法も包含している。
即ち、所定量の水に対し、この発明の基本をなす水素発生剤か、上記した関連する発明で得られる水素発生剤かの何れかを適宜割合で投入し、長期間に渡り、水素を高濃度に発生するようにしてなる、この発明の水素発生剤を利用した高濃度水素水の製造方法である。
(Related invention 2)
In relation to the hydrogen generating agent described above, the present invention also includes a method for producing high-concentration hydrogen water using the hydrogen generating agent.
That is, with respect to a predetermined amount of water, either a hydrogen generator that forms the basis of the present invention or a hydrogen generator obtained by the related invention described above is added in an appropriate ratio, and hydrogen is increased over a long period of time. This is a method for producing high-concentration hydrogen water using the hydrogen generator of the present invention, which is generated at a concentration.
これは、より具体的に示すと、水３５０ｃｃに対し、この発明の基本をなす水素発生剤か、上記した関連する発明で得られる水素発生剤かの何れかを１．５ｇの割合で投入し、１ヶ月以上に渡り、９００〜１０００ｐｐｂの水素量を発生するようにしてなる、この発明の水素発生剤を利用した高濃度水素水の製造方法ということができる。 More specifically, it is charged at a rate of 1.5 g of either the hydrogen generator that forms the basis of the present invention or the hydrogen generator obtained in the related invention described above with respect to 350 cc of water. In addition, it can be said to be a method for producing high-concentration hydrogen water using the hydrogen generating agent of the present invention, which generates a hydrogen amount of 900 to 1000 ppb for one month or more.
（関連する発明３）
上記した水素発生剤に関連し、この発明には、その水素発生剤を利用した高濃度水素水も包含している。
即ち、この発明の製造方法によって高濃度水素水を製造した上、それらから水素発生剤が取り除かれ、ボトルやタンクなど密閉包装されるか、または、コップ類に充填提供されるかした構成からなる、上記した製造方法による高濃度水素水が充填または提供される容器入りの高濃度水素水である。
(Related invention 3)
In relation to the hydrogen generating agent described above, the present invention also includes high-concentration hydrogen water using the hydrogen generating agent.
That is, the high-concentration hydrogen water is produced by the production method of the present invention, and the hydrogen generator is removed from the high-concentration hydrogen water, and the bottle or tank is hermetically packaged or filled into a cup. The high-concentration hydrogen water in a container filled or provided with the high-concentration hydrogen water by the above-described production method.
以上のとおり、この発明の水素発生剤によれば、従前までのものとは違い、上記したとおりの固有の特徴ある構成から、水素発生原料に封鎖用油脂を混合することにより、安全且つ取扱い易いサイズの塊状体に加工してあるから、微粒子状のものに比較して格段に安全に、無駄無く包装・出荷することができる上、水や水溶液などに投入し易いなど取扱い性に秀でるという特徴を有し、迅速に高濃度水素水を製造することができ、しかも封鎖用油脂が過剰な水素生成を抑制し、より長期間に渡って高い水素発生機能を一定に保つことができるものとなり、利用後は、水や水溶液などに残留することなく確実に分離することができ、その分離作業を格段に効率的に行え、より安全で経済的に利用できるものになるという大きな効果を発揮するものである。 As described above, according to the hydrogen generating agent of the present invention, unlike the conventional ones, it is safe and easy to handle by mixing the sequestering fats and oils with the hydrogen generating raw material from the characteristic features as described above. Since it is processed into a large-sized block, it can be packaged and shipped much more safely and without waste than the fine particles, and it is easy to put into water or aqueous solution, and it has excellent handling characteristics. It is possible to quickly produce high-concentration hydrogen water, and the sequestering fats and oils can suppress excessive hydrogen generation, and can maintain a high hydrogen generation function for a longer period of time, After use, it can be reliably separated without remaining in water, aqueous solution, etc., the separation work can be performed much more efficiently, and it has the great effect that it can be used more safely and economically. It is.
加えて、封鎖用油脂を食用油および天然油の何れか少なくとも一種からなるものとした、この発明の水素発生剤は、飲料水やその他の飲料類などに投入した場合にも、食品としての安全性を損ねることが無く、安心して利用できるものとなり、水素発生原料と封鎖用油脂との混合重量比率を、３：７ないし１：９望ましくは２：８としたもの、および、水素発生原料と封鎖用油脂との混合体積比率を、３：７ないし１：９望ましくは２：８としたものは、水分に接した場合の水素発生量を充分に高めることができ、しかもその充分な水素濃度を長期間に渡り維持・延命化することができるものとなる。 In addition, the hydrogen generating agent according to the present invention, in which the oil or fat for blocking is made of at least one of edible oil and natural oil, is safe as food even when it is put into drinking water or other beverages. The hydrogen generating raw material and the sequestering fat are mixed in a weight ratio of 3: 7 to 1: 9, preferably 2: 8, and the hydrogen generating raw material. When the mixing volume ratio with the oil for blocking is 3: 7 to 1: 9, preferably 2: 8, the amount of hydrogen generated when in contact with moisture can be sufficiently increased, and the sufficient hydrogen concentration Can be maintained over a long period of time.
ポリエチレングレコールを適量添加したこの発明の水素発生剤は、封鎖用油脂の水素発生抑制機能に加え、さらに、水素溶出速度調整機能を付与可能なものとし、短時間中に過剰な水素を発生してしまうのを抑制し、一段と均質且つ長期的に水素を安定発生可能なものとし、また、炭酸ガス溶出剤を適量添加したこの発明の水素発生剤は、それを用いて製造した高濃度水素水に炭酸ガスを含むものとすることができ、それを飲料としたり、美容液としたりすることによって、高濃度水素による効能に加え、炭酸ガスに由来する、血圧の低下、心臓への負担の低減、新陳代謝の向上、エネルギー代謝の増加、利尿作用など様々な効用が期待できるものとなる。 The hydrogen generator of the present invention to which an appropriate amount of polyethylene glycol has been added is capable of providing a hydrogen elution rate adjustment function in addition to the hydrogen generation suppression function of the oil for sealing, and generates excessive hydrogen in a short time. The hydrogen generator of the present invention to which hydrogen can be stably generated in a more homogeneous and long-term manner, and an appropriate amount of a carbon dioxide eluent is added is a highly concentrated hydrogen water produced using the hydrogen generator. In addition to the effects of high-concentration hydrogen, by reducing the blood pressure, reducing the burden on the heart, and metabolism Various effects such as improvement of energy, increase of energy metabolism, diuretic action can be expected.
ボタン状、球状、小ブロック状、小板状、棒状、短棒状およびパイプ状などの中、少なくとも何れか１つの形状に成形、固形化してなる、この発明の水素発生剤は、従来型の造粒機や製丸機などを用いて、効率的に生産可能なものとすることができるから、経済的に生産可能な上、取扱い性や計量、包装、輸送などの作業性に秀れ、微粒子状の水素発生原料のままの状態に比較して格段に安全に利用可能なものとすることができる。 The hydrogen generating agent of the present invention, which is formed and solidified into at least one of a button shape, a spherical shape, a small block shape, a small plate shape, a rod shape, a short rod shape, and a pipe shape, has a conventional structure. Since it can be efficiently produced using a granulator or a round machine, it can be produced economically, and it has excellent workability such as handling, weighing, packaging, and transportation. Compared to the state of the raw hydrogen generating raw material, it can be used much more safely.
多孔質塊状に成形、固形化してなるこの発明の水素発生剤は、内部まで通水可能なものとなり、より効率的に水素を発生可能なものとすることができるから、水素発生原料の混合率を一段と低く設定した場合にも、高濃度水素水を長期間に渡って製造可能な能力を発揮できるものとすることができる。 The hydrogen generating agent of the present invention formed into a porous lump and solidified is capable of passing water to the inside and can generate hydrogen more efficiently. Even when set to a much lower value, the ability to produce high-concentration hydrogen water over a long period of time can be exhibited.
この発明の水素発生剤の製造方法によると、１００℃以下の室温下にて均質に攪拌した上、−１５ないし５℃に冷却し所定形状に成形、固形化するようにしたから、水素発生原料に封鎖用油脂をより均質に混合することができ、しかも取扱いし易いサイズ・形状に、迅速且つ効率的に成形加工することができるものとなり、高濃度水素水をより安定して長期間に渡り、製造可能な水素発生剤を格段に経済的に提供可能なものとすることができる。 According to the method for producing a hydrogen generating agent of the present invention, since the mixture is uniformly stirred at a room temperature of 100 ° C. or lower, cooled to −15 to 5 ° C., formed into a predetermined shape and solidified, the hydrogen generating raw material The oil and fat for sealing can be mixed more homogeneously, and can be processed quickly and efficiently into a size and shape that is easy to handle, and high-concentration hydrogen water can be more stably used over a long period of time. Therefore, it is possible to provide a hydrogen generator that can be produced much more economically.
この発明の水素発生剤を利用した高濃度水素水の製造方法によれば、所定量の水に対し、水素発生剤を適宜割合で投入するだけで、簡便に高濃度水素水を製造可能なものとすることができ、例えば、水３５０ｃｃに対し、水素発生剤を１．５ｇの割合で投入するだけで、約１ヶ月以上に渡り、９００〜１０００ｐｐｂの水素量を発生するものとなり、格段に経済的に高濃度水素水を得ることができる。 According to the method for producing high-concentration hydrogen water using the hydrogen generator of the present invention, high-concentration hydrogen water can be easily produced by simply adding the hydrogen generator in an appropriate ratio to a predetermined amount of water. For example, by adding a hydrogen generator at a rate of 1.5 g per 350 cc of water, a hydrogen amount of 900 to 1000 ppb is generated for about one month or more. In addition, high concentration hydrogen water can be obtained economically.
この発明の高濃度水素水の製造方法によって製造した高濃度水素水は、水素発生剤を取り除き、ボトルやタンクなどに密閉包装してなるものとすることにより、保存、輸送、店頭陳列、携帯、備蓄などに有利なものとなり、幅広い利用が可能となり、また、コップ類に充填することによって、店頭販売や飲食店における利用に有利なものとすることができ、より具体的には、各種瓶詰め、各種缶詰め、各種パウチ、各種パック、その外の各種密閉包装を施したものとすることができる外、各種水素水生成器やタンク式サーバーなどに利用することが可能であり、しかも高濃度水素水自体は、高濃度水素が、人体の活性酸素を減少させ、老化予防、腸内環境の改善、血液をサラサラにするダイエット、デトックス、美容、記憶力アップなど様々な効能を有する上、滅菌、消臭の能力が高く、ポリエチレングレコールや炭酸ガス溶出剤などを混合したものは、それらがもつ機能を追加して発揮可能なものとすることができるから、水素水飲料に留まらず、美容液、洗浄液、浄化液、消臭剤、滅菌剤、整髪料、その他の広範に渡る用途に有効に利用することができるという秀れた効果を奏する。 The high-concentration hydrogen water produced by the method for producing high-concentration hydrogen water according to the present invention removes the hydrogen generating agent and is hermetically packaged in bottles, tanks, etc., for storage, transportation, store display, carrying, It becomes advantageous for stockpiling and can be used widely, and by filling into cups, it can be advantageous for over-the-counter sales and use in restaurants. More specifically, various bottling, It can be used for various canned products, various pouches, various packs, and various other sealed packagings. It can also be used for various hydrogen water generators and tank-type servers. In itself, high-concentration hydrogen reduces the active oxygen of the human body, prevents aging, improves the intestinal environment, smoothens blood, diet, detox, beauty, memory improvement, etc. In addition to its efficacy, it has high sterilization and deodorization capabilities, and a mixture of polyethylene glycol or carbon dioxide gas eluent can be added to the functions of those. It has an excellent effect that it can be effectively used not only in beverages but also in beauty liquids, cleaning liquids, cleaning liquids, deodorants, sterilizing agents, hair styling agents, and other various uses.
上記したとおりの構成からなるこの発明の実施に際し、その最良もしくは望ましい形態について説明を加えることにする。
水素発生原料は、氷点ないし沸点の温度条件下にて水に接し、水素を発生する性質を持ち、接触した水中に水素分子を生成し、高濃度の水素水に変える機能を担い、アルカリ金属、アルカリ土類金属などとすることができ、例えば、金属Ｍｇ、金属Ｎａ、金属Ａｌ、金属Ｃａなどとするのが望ましく、水は、水素水を生成する対象となる機能を担い、水または水溶液ということができ、飲料とする場合には、飲料水、または、飲料可能な各種水溶液としなければならず、天然水、ミネラルウォーター、浄水、蒸留水、純水などの外、ジュース、果汁入り飲料、炭酸飲料、緑茶、珈琲、紅茶、その他、あらゆる飲料とすることが可能である。
In implementing the present invention having the above-described configuration, the best or desirable mode will be described.
The hydrogen generation raw material has the property of generating hydrogen molecules in contact with water under freezing or boiling temperature conditions, generating hydrogen molecules in the water in contact with it, and converting it into high-concentration hydrogen water. Alkaline earth metal can be used, for example, metal Mg, metal Na, metal Al, metal Ca and the like are desirable. Water is responsible for generating hydrogen water, and is referred to as water or an aqueous solution. In the case of a beverage, it must be in the form of drinking water or various drinkable aqueous solutions, natural water, mineral water, purified water, distilled water, pure water, etc., juice, juice-containing beverages, Carbonated beverages, green tea, coffee, black tea, and other beverages can be used.
封鎖用油脂は、水素発生原料との混在によって水素発生原料の水との接触状態を調整可能とすると共に、所定形状に成形、固形化可能とする機能を担い、食用油および天然油の何れか少なくとも一種からなるものとしなければならず、より具体的には、ヒマシ油、大豆油、パラフィンなどとするのが望ましく、油の種類を変えることによって固まり方が異なるから、封鎖機能を高めたり、弱めたりすることが可能である。 The sequestration fat is capable of adjusting the contact state with the water of the hydrogen generation raw material by mixing with the hydrogen generation raw material, and has a function of making it possible to form and solidify into a predetermined shape, either edible oil or natural oil It must be composed of at least one type, more specifically, castor oil, soybean oil, paraffin, etc., and because the way of solidification varies depending on the type of oil, enhance the sealing function, It can be weakened.
水素発生原料と封鎖用油脂との混合比率は、混合重量比率を３：７ないし１：９望ましくは２：８とすべきであり、表現を変えて示すと、混合体積比率を、３：７ないし１：９望ましくは２：８としたものとするのが良く、水素発生原料を、３割を超えて混合すると、封鎖用油脂による封鎖機能が充分に得られず、長期間に渡り水素を充分に発生する機能を保つことができなくなる虞があり、１割以下にすると水素を発生する機能そのものが低下してしまう虞がある。 The mixing ratio between the hydrogen generating raw material and the oil for sealing should be a mixing weight ratio of 3: 7 to 1: 9, preferably 2: 8. In other words, the mixing volume ratio is 3: 7. Or 1: 9, preferably 2: 8. If the hydrogen generating raw material is mixed in an amount exceeding 30%, the sealing function by the sealing oil and fat cannot be sufficiently obtained, and the hydrogen is not generated for a long time. There is a possibility that the function that sufficiently generates cannot be maintained, and when the ratio is 10% or less, the function of generating hydrogen itself may be deteriorated.
ポリエチレングレコールは、封鎖用油脂が水素発生原料の水との接触状態を調整可能とする機能を助け、水素発生原料の溶出速度を調整する機能を担い、より具体的には、不活性のポリエチレングレコールを用いるのが望ましく、炭酸ガス溶出剤は、水中に炭酸ガスを溶出させる機能を担い、より具体的には、例えば、重曹、ビタミンＣ、有機酸などとすることができる。 Polyethylene glycol helps the sealing oil and fat to adjust the contact state of the hydrogen generating raw material with water, and functions to adjust the elution rate of the hydrogen generating raw material. It is desirable to use glycol, and the carbon dioxide eluent has a function of eluting carbon dioxide in water, and more specifically, for example, sodium bicarbonate, vitamin C, organic acid, and the like.
水素発生剤の所定形状は、適宜形状に成形、固形化したものとすることができ、例えば、ボタン状、球状、小ブロック状、小板状、棒状、短棒状およびパイプ状などの中、少なくとも何れか１つの形状に成形、固形化してなるものとすることができ、より効率的に生産するには、押し出し成形品とするのが望ましく、また、多孔質塊状やポーラス構造などに成形、固形化してなるものとすることができ、透水性のカプセルや濾過膜などに包装し、透水性の包装諸共、水中に投入可能なものとすることができる。 The predetermined shape of the hydrogen generating agent can be formed into an appropriate shape and solidified, for example, at least in a button shape, a spherical shape, a small block shape, a small plate shape, a rod shape, a short rod shape, a pipe shape, etc. It can be molded into any one shape and solidified, and for more efficient production, it is desirable to make it an extrusion molded product, and it is molded and solidified into a porous mass or porous structure. And can be packaged in a water-permeable capsule, a filtration membrane, or the like, and both the water-permeable packaging can be put into water.
水素発生剤の製造方法は、水素発生原料に封鎖用油脂を、３：７ないし１：９望ましくは２：８の混合比率にて混合し、１００℃以下の室温下にて均質に攪拌した上、−１５ないし５℃に冷却し所定形状に成形、固形化してなるものとしなければならず、１００℃を超えると水素発生原料が酸化してしまう虞があり、充分な品質の水素発生剤を得ることができなくなり、攪拌後に−１５ないし５℃に冷却し所定形状に成形する工程では、−１５℃を超えてさらに冷やすと、硬化して成形が困難になる虞があり、５℃を超えると硬化し難くなり、成形後に形状を維持するのが困難になる虞があり、また、水素発生剤の製造方法は、水素発生原料に封鎖用油脂を混合する工程中に、適量のポリエチレングレコールや適量の炭酸ガス溶出剤を混合、均質に攪拌するようにしたものとすることができる。 The production method of the hydrogen generating agent is that the sequestering fats and oils are mixed with the hydrogen generating raw material in a mixing ratio of 3: 7 to 1: 9, preferably 2: 8, and stirred uniformly at room temperature of 100 ° C. or lower. It must be cooled to -15 to 5 ° C, molded into a predetermined shape and solidified, and if it exceeds 100 ° C, the hydrogen generating raw material may be oxidized. In the step of cooling to −15 to 5 ° C. after the stirring and forming into a predetermined shape after stirring, if it is further cooled above −15 ° C., it may be hardened and molding may be difficult, and the temperature exceeds 5 ° C. It is difficult to harden and maintain the shape after molding, and the method for producing the hydrogen generating agent is an appropriate amount of polyethylene glycol during the process of mixing the oil for sealing with the hydrogen generating raw material. Or a proper amount of carbon dioxide eluent It may be provided with so as to stir the quality.
高濃度水素水の製造方法は、所定量の水に対し、この発明の上記した水素発生剤、または、この発明の水素発生剤の製造方法によって製造した水素発生剤の、何れか１つの水素発生剤を適宜割合で投入し、長期間に渡って水素を高濃度に発生するようにしてなるものであり、より具体的には、水３５０ｃｃに対し、この発明の製造方法によって製造した水素発生剤の、何れか１つの水素発生剤を１．５ｇの割合で投入し、約１ヶ月以上に渡り、９００〜１０００ｐｐｂの水素量を発生するようにしてなるものとすることができ、水に対する水素発生剤の投入量を増加させれば、水素発生量は多くなり、減らせば減少することとなり、必要や好みなどに応じて、水に対する水素発生剤の投入割合を適宜設定することが可能である。 The method for producing high-concentration hydrogen water is to generate any one of the above-described hydrogen generator of the present invention or the hydrogen generator produced by the method of producing the hydrogen generator of the present invention for a predetermined amount of water. The agent is added at an appropriate ratio so that hydrogen is generated at a high concentration over a long period of time. More specifically, hydrogen is produced by the production method of the present invention for 350 cc of water. Any one of the hydrogen generating agents is added at a rate of 1.5 g, and the amount of hydrogen of 900 to 1000 ppb can be generated over about one month or more. Increasing the amount of hydrogen generator added will increase the amount of hydrogen generated and decrease it if reduced. The ratio of hydrogen generator to water can be set appropriately according to need and preference. is there.
高濃度水素水は、この発明の高濃度水素水の製造方法によって製造したものであり、水素発生剤を取り除き、ボトルやタンクなどに密閉包装し、または、コップ類に充填してなるものとすることができ、水中に混在する水素が抜けないよう、アルミニウムパウチやアルミニウムボトルなどに密封したものとするのが良い。
以下では、図面に示すこの発明を代表する実施例と共に、その構造について詳述することとする。
High-concentration hydrogen water is produced by the method for producing high-concentration hydrogen water according to the present invention, and is obtained by removing the hydrogen generating agent and hermetically packaging in bottles, tanks, etc., or filling cups. It should be sealed in an aluminum pouch or aluminum bottle so that hydrogen mixed in the water does not escape.
In the following, the structure of the present invention will be described in detail together with an embodiment representative of the present invention shown in the drawings.
図面は、この発明の水素発生剤、水素発生剤の製造方法、高濃度水素水の製造方法、および、それらによる高濃度水素水の技術的思想を具現化した代表的な一実施例を示すものである。
水に接して水素を発生する水素発生原料に、水との接触状態を調整可能とする封鎖用油脂を混合し、所定形状に成形、固形化してなるものとした、この発明の基本をなす水素発生剤は、この発明に包含する水素発生剤の製造方法により、水素発生原料に封鎖用油脂を、３：７ないし１：９望ましくは２：８の混合比率にて混合し、１００℃以下の室温下にて均質に攪拌した上、−１５ないし５℃に冷却し所定形状に成形、固形化するようにしてなるものである。
以下では、この発明の水素発生剤の製造方法の一例に従い、順次、この発明の水素発生剤の一例の構成につき示すこととする。
Hydrogen which forms the basis of the present invention, which is formed by mixing a hydrogen generating raw material which generates hydrogen in contact with water with a fat for sealing capable of adjusting the contact state with water, and molding and solidifying the oil into a predetermined shape. According to the method for producing a hydrogen generating agent included in the present invention, the generating agent is prepared by mixing a sequestering fat and oil with a hydrogen generating raw material in a mixing ratio of 3: 7 to 1: 9, preferably 2: 8. The mixture is stirred uniformly at room temperature, cooled to −15 to 5 ° C., and formed into a predetermined shape and solidified.
Below, according to an example of the manufacturing method of the hydrogen generator of this invention, it shall show sequentially about the structure of an example of the hydrogen generator of this invention.
室温下にて、金属Ｍｇ、金属Ｎａ、金属Ａｌの少なくとも１種からなる水素発生原料と、ヒマシ油、大豆油、パラフィンの少なくとも１種からなる封鎖用油脂とを、混合重量比率２：８として混合し、１００℃以下の室温下にて均質になるまで攪拌した上、−１５ないし５℃に冷却し、造粒機に投入し、押し出し成型によって直径４ｍｍ、長さ８ｍｍの円柱状に成形、固形化するようにしたものである。 At room temperature, a hydrogen generation raw material composed of at least one of metal Mg, metal Na, and metal Al and a sealing fat / oil composed of at least one of castor oil, soybean oil, and paraffin were mixed at a weight ratio of 2: 8. Mix, stir until homogenous at room temperature of 100 ° C. or lower, cool to −15 to 5 ° C., put into a granulator, and shape by extrusion to form a cylinder with a diameter of 4 mm and a length of 8 mm. It is made to solidify.
また、水素発生原料に封鎖用油脂を混合する工程中に、ポリエチレングレコールおよび炭酸ガス溶出剤の少なくとも何れか一方の適量を添加し、１００℃以下の室温下にて均質になるまで攪拌するようにしたものとすることができる。 In addition, during the process of mixing the oil for sealing with the hydrogen generating raw material, an appropriate amount of at least one of polyethylene glycol and carbon dioxide eluent is added and stirred at room temperature of 100 ° C. or lower until homogeneous. It can be made.
（実施例１の作用・効果）
以上のとおりの構成からなるこの発明の水素発生剤は、水素発生原料が封鎖用油脂と混合することにより、水や水溶液などに投入した際の水分との接触率を封鎖用油脂の種類および混合率に応じて抑制するものとなり、混合重量比率２：８として混合したものは、最も長期間に渡り、効率的に水素を発生するものとなり、特に、直径４ｍｍ、長さ８ｍｍの円柱状に成形、固形化したものは、取扱いし易く、そのまま水中に投入しても、水素水から分離し易く、不織布製の袋などに包装するだけで、容易に小分け包装することができ、微粒子のものと異なり、漏出を確実に防止できるという効果が得られる。
(Operation / Effect of Example 1)
The hydrogen generating agent of the present invention having the above-described configuration is obtained by mixing the hydrogen generating raw material with the sealing oil and fat, thereby determining the contact ratio with water when it is put into water or an aqueous solution. If the mixture is mixed at a mixing weight ratio of 2: 8, hydrogen will be generated efficiently over the longest period, and in particular, it will be formed into a cylindrical shape with a diameter of 4 mm and a length of 8 mm. The solidified product is easy to handle and can be easily separated from hydrogen water even if it is put into water as it is. In contrast, the effect of reliably preventing leakage can be obtained.
この発明が包含している水素発生剤の製造方法は、水素発生原料と封鎖用油脂とを混合し、１００℃以下の室温下にて均質に攪拌するようにしたから、水素発生原料の酸化および発火を安全に防止することができる上、封鎖用油脂の劣化を阻止し、高い品質を確保でき、さらに、−１５ないし５℃に冷却し所定形状に成形、固形化するようにしたから、封鎖用油脂を迅速、且つ確実に所望の形状に成形することができ、格段に効率的な生産を可能にするものとなる。 In the method for producing a hydrogen generating agent included in the present invention, the hydrogen generating raw material and the oil for sealing are mixed and stirred uniformly at a room temperature of 100 ° C. or lower. In addition to being able to safely prevent ignition, it is possible to prevent deterioration of the oil and fat for sealing, to ensure high quality, and to cool to -15 to 5 ° C and to form and solidify into a predetermined shape. Oils and fats can be quickly and surely formed into a desired shape, thereby enabling extremely efficient production.
この発明の水素発生剤による水素発生能力は、次のとおりである。
この発明の高濃度水素水の製造方法に従い、浄水３５０ｃｃに対し、１．５ｇの水素発生剤を投入して得た、この発明の高濃度水素水は、水素量が約９００〜１０００ｐｐｂ、酸化還元電位が約−７００ｍＶを示し、約１ヶ月以上に渡って水素を発生することを確認した。
The hydrogen generation capability of the hydrogen generator of the present invention is as follows.
According to the manufacturing method of the hydrogen-rich water of the present invention, with respect to water purification 350 cc, obtained by introducing hydrogen generating agent 1.5g, hydrogen-rich water, the amount of hydrogen of about 900 to 1000 ppb in the present invention, The oxidation-reduction potential was about −700 mV, and it was confirmed that hydrogen was generated over about 1 month.
さらに、この発明の水素発生剤の有効性を確認するため、その滅菌効果について、以下のとおり試験を行った。
農業用水３５０ｃｃに対して当該水素発生剤０．５ｇを投入し、時間経過に伴う雑菌量の変化を測定するものであり、該水素発生剤０．５ｇの投入により、該農業用水の水素濃度は、９００〜１０００ｐｐｂを示し、図１に示すように、３０分後、１時間後、２時間後、２０時間後、４８時間後の夫々に、簡易測定紙１（柴田科学株式会社製）を入れ、一般細菌群数を測定した結果によると、２時間経過した後には、菌の斑点が見られなくなり、７時間以内で雑菌は略０に近くなるという結果が得られ、除菌効果の有効性を確認することができた。
Furthermore, in order to confirm the effectiveness of the hydrogen generating agent of the present invention, the sterilization effect was tested as follows.
0.5 g of the hydrogen generator is added to 350 cc of agricultural water, and the change in the amount of germs over time is measured. By adding 0.5 g of the hydrogen generator, the hydrogen concentration of the agricultural water is Indicates 900 to 1000 ppb, and as shown in FIG. 1, simple measurement paper 1 (manufactured by Shibata Kagaku Co., Ltd.) after 30 minutes, 1 hour, 2 hours, 20 hours and 48 hours. According to the results of the measurement of the number of general bacterial groups, after 2 hours, the bacterial spots are not seen, and within 7 hours, the result is that the bacteria are almost zero, and the sterilization effect is improved. The effectiveness could be confirmed.
所定量の水に対し、請求項１ないし８何れか一項記載の水素発生剤を適宜割合で投入し、長期間に渡って水素を高濃度に発生するようにしてなる、この発明の基本をなす水素発生剤を利用した高濃度水素水の製造方法は、水３５０ｃｃに対し、前記実施例１に示した水素発生剤を１．５ｇの割合で投入し、約１ヶ月以上に渡り、９００〜１０００ｐｐｂの水素量を発生するようにしてなるものとすることができ、該水素発生剤を取り除き、ボトルやタンクなどに密閉包装し、または、コップ類に充填することにより、この発明の高濃度水素水を得るものとする。 The hydrogen generating agent according to any one of claims 1 to 8 is added in an appropriate ratio with respect to a predetermined amount of water to generate hydrogen at a high concentration over a long period of time. A method for producing high-concentration hydrogen water using a formed hydrogen generator is to introduce the hydrogen generator shown in Example 1 at a rate of 1.5 g with respect to 350 cc of water. It can be configured to generate a hydrogen amount of ˜1000 ppb , and by removing the hydrogen generating agent and hermetically packaging in bottles and tanks, or filling into cups, Concentrated hydrogen water shall be obtained.
（実施例２の作用・効果）
以上のとおりの構成からなるこの発明の高濃度水素水の有効性を確認するため、その消臭効果について、以下のような幾つかの試験を行った。
下記表１の消臭性試験結果１に示すように、人間が発生する体臭に対する消臭効果を測定した結果、イソ吉草酸およびノネナールを９０％以上分解することを確認した。
消臭性試験方法：（一社）繊維評価技術協議会 ＳＥＫマーク繊維製品認証基準 準用２１、消臭性試験（ガスクロマトグラフ法）
ガス初発濃度 ：イソ吉草酸 約３８ｐｐｍ
ノネナール 約１４ｐｐｍ
試験試料 ：ガスクロマトグラフ法 ５０ｍｌ
測定時間 ：２時間後
(Operation / Effect of Example 2)
In order to confirm the effectiveness of the high-concentration hydrogen water of the present invention having the above-described configuration, the following tests were conducted with respect to the deodorizing effect.
As shown in Table 1 below, Table 1 shows the results of measuring the deodorizing effect on body odor generated by humans. As a result, it was confirmed that isovaleric acid and nonenal were decomposed by 90% or more.
Deodorization test method: (one company) Textile Evaluation Technology Council SEK Mark Textile Product Certification Criteria 21, Deodorization Test (Gas Chromatograph Method)
Initial gas concentration: Isovaleric acid approx. 38ppm
Nonenal about 14ppm
Test sample: Gas chromatography 50ml
Measurement time: 2 hours later
さらに、下記表２の消臭性試験結果２に示すように、動物（犬）が発生する臭に対する消臭効果を測定した結果、アンモニア、酢酸およびインドール（糞の分解臭）を９０％以上分解することを確認した。
消臭性試験方法：（一社）繊維評価技術協議会 ＳＥＫマーク繊維製品認証基準 準用２１、消臭性試験（検知管法、ガスクロマトグラフ法）
ガス初発濃度 ：アンモニア １００ｐｐｍ
酢酸 ３０ｐｐｍ
インドール 約３３ｐｐｍ
試験試料 ：検知管法 ５０ｍｌ、ガスクロマトグラフ法 ５０ｍｌ
測定時間 ：２時間後
Furthermore, as shown in Table 2 below, the deodorization test result 2 shows that the deodorizing effect on the odor generated by animals (dogs) was measured. As a result, ammonia, acetic acid and indole (degraded odor of feces) were decomposed by 90% or more. Confirmed to do.
Deodorization test method: (one company) Textile Evaluation Technology Council SEK Mark Textile Product Certification Criteria 21, Application for deodorization (detection tube method, gas chromatograph method)
Initial gas concentration: Ammonia 100ppm
Acetic acid 30ppm
Indole about 33ppm
Test sample: Detector tube method 50 ml, gas chromatograph method 50 ml
Measurement time: 2 hours later
（結 び）
叙述の如く、この発明の水素発生剤、水素発生剤の製造方法、高濃度水素水の製造方法、および、それらによる高濃度水素水は、その新規な構成によって所期の目的を遍く達成可能とするものであり、しかも製造も容易で、従前からの水素水生成技術に比較し、水素発生剤の生産性、およびその取扱い性を大幅に向上し、低廉化して遥かに経済的なものとすることができる上、高濃度水素水の生産性を大幅に改善し得るものとなることから、従前までは微粒子状の水素発生剤が、安全性や取扱い性を低下させてしまっていたが、こうした課題の解決によって水素水製造・流通・販売業界は固よりのこと、従来品よりも取扱い易く、長期的に利用できて経済的な水素発生剤、および高濃度水素水の提供を希望する企業や店舗、一般家庭などにおいても高く評価され、広範に渡って利用、普及していくものになると予想される。
(Conclusion)
As described above, the hydrogen generator of the present invention, the method of producing the hydrogen generator, the method of producing high-concentration hydrogen water, and the high-concentration hydrogen water by them can be used to achieve the intended purpose. Compared to conventional hydrogen water generation technology, it greatly improves the productivity and handling of hydrogen generators, making it cheaper and making it much more economical. In addition, the productivity of high-concentration hydrogen water can be greatly improved, and so far, particulate hydrogen generators have reduced safety and handling. By solving problems, the hydrogen water production, distribution, and sales industries are more solid, easier to handle than conventional products, long-term and economical hydrogen generators, and companies that want to provide high-concentration hydrogen water For stores, general households, etc. Been highly valued, use over a wide range, it is expected to be those that continue to spread.
１ 簡易測定紙
1 Simple measuring paper
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| JP2014163251A JP6122405B2 (en) | 2014-08-09 | 2014-08-09 | HYDROGEN GENERATOR, METHOD FOR PRODUCING HYDROGEN GENERATOR, METHOD FOR PRODUCING HIGH CONCENTRATION HYDROGEN WATER, AND HIGH CONCENTRATION HYDROGEN WATER THEREOF |
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| JP7016073B2 (en) * | 2017-04-14 | 2022-02-04 | 有限会社 アクアサイエンス | Hydrogen generation shower |
| CN108815607A (en) * | 2018-04-02 | 2018-11-16 | 云南中京国建投资有限公司 | A kind of gut washout method and apparatus |
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| GB8723034D0 (en) * | 1987-10-01 | 1988-03-23 | Dowty Maritime Systems Ltd | Gas generating devices |
| JP4363631B2 (en) * | 2003-05-27 | 2009-11-11 | 株式会社 エピア | Bottle with taste improver |
| JP2006143637A (en) * | 2004-11-18 | 2006-06-08 | Yamagata Three Top:Kk | Dissolving granule and method for producing dissolving granule |
| CN101304943B (en) * | 2005-11-10 | 2012-06-27 | 株式会社黑罗麦托 | Hydrogen generating agent and use thereof |
| US8057939B2 (en) * | 2005-12-06 | 2011-11-15 | Honeywell International Inc. | Electrical power generator |
| JP2009126736A (en) * | 2007-11-22 | 2009-06-11 | Hiromaito Co Ltd | Hydrogen-generating agent and its usage |
| CA2720533C (en) * | 2008-04-02 | 2016-02-16 | Cedar Ridge Research, Llc | Aluminum-alkali hydroxide recyclable hydrogen generator |
| WO2013031895A1 (en) * | 2011-08-31 | 2013-03-07 | 独立行政法人 国立高等専門学校機構 | Hydrogen water filled product, manufacturing method therefor, and manufacturing device therefor |
| JP5734457B2 (en) * | 2011-11-29 | 2015-06-17 | 芝野 哲也 | Bath preparation, external preparation for skin, reducing agent for water, method for producing reduced water, reducing water and method for reducing object |
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