JP6112919B2 - Pretreatment material for taking alginate impression - Google Patents

Description

  The present invention relates to a pretreatment material used when an impression is taken using a dental alginate impression material.

  When a cast crown restoration process or a defect prosthesis process is required to restore a tooth or the like, first, a mold such as an abutment tooth is taken. Next, a model made of gypsum or the like is produced using the obtained mold. And a prosthesis is produced based on the model, and the produced prosthesis is attached to an abutment tooth or the like. The mold such as the abutment tooth is referred to as an impression, and a curable material for obtaining the impression is referred to as an impression material. As this impression material, an alginate impression material, an agar impression material, a silicone rubber impression material, a polysulfide rubber impression material, a polyether rubber impression material, or the like is used. Among them, the alginate impression material is most widely used because it is inexpensive and easy to handle.

  Alginate impression material has a characteristic that the cured product after curing is relatively soft and easily deforms due to stress generated at the stage of removing the impression material from the oral cavity after taking the impression. Compared to an ether rubber impression material, etc., it had the disadvantage of low impression accuracy. Therefore, in the past, when taking a precise impression using an alginate impression material, a method of applying an alginate impression after applying an agar impression material around the tooth to be precisely taken (agar, alginate) It is common to use a combined impression).

  The agar impression material is an elastic rubber-like solid at room temperature (20 ° C. to 30 ° C.), and when used, after being heated to 100 ° C. in advance, The one kept at a suitable temperature (50 ° C. to 60 ° C.) is used. When an agar impression material is set around the teeth in the mouth (30 ° C to 35 ° C), it will solidify in just a few minutes. When setting an agar impression material and taking an impression with an alginate impression material The timing is important. If the agar solidifies at the time of taking the alginate impression, it will not be possible to obtain a precise impression, and in that case, it will be necessary to start over from the beginning, and the burden on not only the operator but also the patient will be great. there were. In addition, even if the timing of solidification of the agar impression material and the timing of curing of the alginate impression material are slightly shifted, adhesion failure occurs between the alginate impression material and the agar impression material, and the cured impression product is removed from the oral cavity. When removing from the inside, the agar impression material cured product may be lifted. In this case, it is difficult to notice the failure immediately after the acquisition, and after making the plaster model using the acquired impression cured body and preparing the prosthesis such as a crown, the prosthesis is set in the patient. There is a possibility that troubles such as incompatibility occur and cause great damage to the operator and the patient.

  In this way, the combined impression is a method in which two uncured materials (an agar impression material and an alginate impression material) are superposed, and therefore it is necessary to press-contact at a time when both have sufficient fluidity. However, as described above, when the area where the impression is taken becomes wide, it can be said that it is very difficult for the surgeon to take an impression by matching the curing timing of each impression material to an appropriate area. .

  In order to overcome such problems, it has already been proposed that impression acquisition can be performed easily and accurately without failure by using a cartridge for agar impression material in which the temperature of the agar impression material can be visually confirmed ( Patent Document 1). However, in the method disclosed in Patent Document 1, although the temperature of the agar when the agar impression material is set on the tooth can be confirmed, it is still necessary to pay attention to the timing of curing after setting on the tooth. It was not a fundamental solution.

  On the other hand, a small amount of silicone impression material (or agar impression material) is pressed onto the teeth, and a polyethylene film having a bonding ability between the silicone impression material and the alginate impression material and a polyethylene / polyester film are cured on the cured product. A method of taking a second impression using an alginate impression material after being put on is proposed (Patent Document 2). However, the impression material applied to the tooth for the first time is itself a material that hardens in a short time if left unattended, so that a small amount of impression material can reach every corner of the tooth having a complicated shape. In order to apply, it is necessary to pay attention to the curing timing of the impression material, which is not a fundamental solution. Moreover, in order to properly set the film on the cured cured impression material for the first time so as not to cause gaps and wrinkles, the operator needs skill and further improvements are made from the viewpoint of operability. Was demanded.

JP-A-7-116177 JP 2009-106672 A

  The present invention proposes an impression acquisition method capable of acquiring a precise impression without the necessity of matching the curing timing of each impression material in a combined impression using an alginate impression material.

  The present inventors have intensively studied to overcome the above problems. As a result, it was found that the above problem can be solved by performing a combined impression using a pretreatment material containing an alginate, a surfactant, and water and having a viscosity in a specific range and an alginate impression material. .

That is, the pretreatment material for obtaining an alginate impression of the present invention comprises (A) β-D mannuronic acid and α-L guluronic acid as a unit structure, and the mole of β-D mannuronic acid relative to α-L gluronic acid. Alginate in which the ratio of alginate having an M / G ratio in the range of 0.4 to 0.7 is 90% by mass or more of the entire alginate, (B) Hydrophilic / lipophilic balance (HLB) Is a polyglycerin fatty acid ester having a viscosity of 2.0 to 6.0, (C) water, and has a viscosity in the range of 5 to 80 Pa · s at 23 ° C.

  Another embodiment of the present invention is an impression kit comprising the pretreatment material for obtaining an alginate impression and an alginate impression material.

  By using the pretreatment material for alginate impression acquisition according to the present invention, it is possible to easily acquire a precise impression even in parts having complicated shapes such as crowns and necks by performing an alginate combined impression. It becomes. In addition, since the pretreatment material for taking an alginate impression of the present invention does not cure by itself, and cures when it comes into contact with the alginate impression material to be pressed thereafter, the curing timing of the two types of impression materials is set. There is no need to match. Therefore, even when taking impressions of a large number of teeth with a wide range of impression objects, it is possible to easily obtain a precise impression without failure, which is extremely promising.

It is a figure which shows the molecular structure of the MM block comprised by combining (beta) -D-mannuronic acid (M) continuously. It is a figure which shows the molecular structure of the GG block comprised by alpha-L-guluronic acid (G) combining continuously. It is a schematic diagram explaining an example of the association part (Egg Box Junction) where the GG block chains in the alginic acid molecule are associated so as to embrace calcium ions. It is a schematic diagram shown about a pair of metal mold | die used for evaluation of impression precision. It is a schematic diagram explaining the evaluation method of impression accuracy.

  The pretreatment material for taking an alginate impression of the present invention contains (A) an alginate, (B) a surfactant, and (C) water, and has a viscosity in the range of 5 to 80 Pa · s at 23 ° C. It is characterized by.

  The greatest feature of the pretreatment material for taking an alginate impression of the present invention is that it has a viscosity in a specific range, and a gelation reagent (calcium ion) necessary for the alginate to harden by the gelation reaction. The present invention is to use a paste-like composition containing no released calcium sulfate or the like as a pretreatment material for obtaining an alginate impression material.

  Since the pretreatment material alone does not harden, the appropriate viscosity is maintained even after the pretreatment material is applied to the tooth for which an impression is to be taken. The pre-treatment material flows in variously, and the impression accuracy can be greatly improved.

  In addition, the pretreatment material of the present invention comes into contact with the subsequent alginate impression material, so that the calcium ions in the alginate impression material are transferred to the pretreatment material, and curing starts. There is no need to adjust timing. Therefore, after the pretreatment material is set on the teeth, the subsequent alginate impression can be obtained with a sufficient margin.

  Moreover, the strength of the pretreatment material after curing is improved by using an alginate having a specific M / G ratio as an alginate and a polyglycerin fatty acid ester having a specific HLB as a surfactant. A more accurate combined impression can be obtained.

  The reason for this is not clear, but by blending a polyglycerin fatty acid ester having a specific HLB, from a gelling reaction agent (such as calcium sulfate) in the alginate impression material that comes into contact with the pretreatment material during the combined impression. The released calcium ions are quickly transferred and diffused into the more hydrophilic pretreatment material, and further, the alginate having a specific M / G ratio is blended to be supplied into the pretreatment material. This is considered to be because the gelation reaction with calcium ions proceeds efficiently to form a firm gel at an early stage.

  When the M / G ratio is low, α-L-guluronic acid (rather than the ratio of the flat MM block (see FIG. 1) formed by continuously bonding β-D-mannuronic acid (M) The proportion of bowl-shaped GG blocks (see FIG. 2) configured by continuously combining G) is relatively large. For this reason, when the alginic acid molecule gels in the presence of calcium ions, as illustrated in FIG. 3, the GG block chains in the alginic acid molecules are associated with each other so as to embed calcium ions (Egg Box). Junction) is easily formed. For this reason, in the hardened | cured material using the alginate with a low M / G ratio, it is thought that the hardened | cured material which has strong gel strength can be obtained in presence of a small amount of calcium ions as mentioned above. In addition, in the alginic acid molecule shown as a string-like line in FIG. 3, the code | symbol G means a GG block chain | strand and another part means an MM block chain | strand. Black circles mean calcium ions.

Hereinafter, each component which comprises the pretreatment material for alginate impression collection of this embodiment is demonstrated in detail.
(A) Alginate As the alginate that can be used in the pretreatment material for taking an alginate impression of the present invention, any known alginate that is used in a conventional alginate impression material can be used without particular limitation. Examples of the alginate include i) alkali metal alginate such as sodium alginate and potassium alginate, ii) ammonium alginate such as ammonium alginate and triethanolamine alginate, and the like. Among these alginates, it is preferable to use an alkali metal alginate from the viewpoints of availability, ease of handling, physical properties of the cured product, and the like. Among the alginate, β / D mannuronic acid and α-L guluronic acid are included as a unit structure, and the M / G ratio which is the molar ratio of β-D mannuronic acid to α-L guluronic acid is 0.00. The use of an alginate in the range of 4 to 0.7 is most preferable from the viewpoint of the strength of the pretreated material cured product as described above.

  Moreover, two or more types of alginate can be mixed and used.

  Here, the upper limit of the M / G ratio of the alginate is generally about 2.5, and the alginate in which the M / G ratio is in the range of 0.4 to 0.7 and the M / G ratio is 0. When an alginate exceeding 0.7 is mixed and used, an alginate having an M / G ratio in the range of 0.4 to 0.7 and an alginate having an M / G ratio exceeding 0.7 It is preferable that the content ratio of the alginate whose M / G ratio is in the range of 0.4 to 0.7 with respect to the total amount is 90% by mass or more, and more preferably 93% by mass or more. Preferably, it is 95 mass% or more.

  The content of alginate with respect to the total amount of the pretreatment material for impression collection is not particularly limited, but the pretreatment material for alginate impression collection of the present invention has a viscosity at 23 ° C. from the viewpoint of operability during the combined impression. It is necessary to adjust to a range of 5 to 80 Pa · s, more preferably 30 to 60 Pa · s.

  The viscosity of the pretreatment material in the present invention can be determined as follows.

An appropriate amount of pretreatment material is placed on a cone plate viscometer (for example, CS rheometer CVO120HR manufactured by BOHLIN), measurement is started at a shear rate of 0.1 / s, and the viscosity 66 seconds after the start of measurement is read. The viscosity of the treated material (η23 _0.1 / Pa · s (pascal sec)) was used. The viscosity is measured under the conditions that the cone diameter is 2 cm and the cone inclination angle is 1 °.

  The viscosity may be adjusted as appropriate depending on the amount of the alginate used. In general, the content of the alginate in the pretreatment material is in the range of 1 to 10% by mass. It is preferable. By setting the content of the alginate in the kneaded material to 1% by mass or more, it becomes easy to ensure the gel strength of the cured product. Moreover, it becomes easy to ensure the operativity at the time of apply | coating a pretreatment material to a tooth | gear by making content of alginate in a pretreatment material into 10 mass% or less.

  If the viscosity of the pretreatment material is less than 5 Pa · s, it may cause a decrease in impression accuracy, such as dripping the pretreatment material when the pretreatment material is applied to the teeth. In addition, when the viscosity of the pretreatment material exceeds 80 Pa · s, the fluidity is insufficient after the pretreatment material is applied to the tooth, and the portion having a complicated shape such as the crown or the neck Since the paste does not flow in every corner, the impression accuracy is reduced.

  The molecular weight of the alginate is not particularly limited, but from the viewpoint of gel strength and operability, a molecular weight in which the viscosity of the aqueous solution containing 1% by mass of the alginate is in the range of 20 mPa · s to 1000 mPa · s is preferable. It is preferable to select as appropriate.

(B) Surfactant As the surfactant that can be used in the pretreatment material for obtaining an alginate impression of the present invention, any known surfactant can be used without particular limitation. Anionic surfactants, cationic surfactants Any of an agent, an amphoteric surfactant, and a nonionic surfactant can be used.

  Examples of the anionic surfactant include alkyl sulfonates, alkyl benzene sulfonates, and alkyl ether carboxylates. Examples of the cationic surfactant include alkylamine salts and quaternary ammonium salts. Examples of amphoteric surfactants include aminocarboxylates. Nonionic surfactants include polyoxyethylene alkyl ether, polyoxyethylene alkylphenyl ether, polyoxyethylene-polyoxypropylene block polymer, polyoxyethylene glycerin fatty acid ester, polyoxyglycerin fatty acid ester, sorbitan fatty acid ester, sucrose Examples include esters, polyoxydiethylene alkylamines, block polymers of polysiloxanes and polyoxyethylenes, and the like.

  Among these, the use of a polyglycerin fatty acid ester having an HLB (hydrophilic / lipophilic balance) in the range of 2.0 to 6.0 is most preferable from the viewpoint of the strength of the cured pretreatment material as described above.

  Here, the HLB value is a value calculated by the Griffin method (WC Griffin, J. Soc. Cosmists., Chemists., 1, 311 (1949)) represented by the following mathematical formula.

HLB = 20 × (molecular weight of hydrophilic group part) / (molecular weight of surfactant)
The polyglycerol fatty acid ester is obtained by esterifying one or two or more hydroxyl groups of polyglycerol with a fatty acid. The HLB of the polyglycerol fatty acid ester is comprehensively determined by the number of glycerin monomers, the number of esterified hydroxyl groups, and the type of constituent fatty acid. In general, as the number of glycerin monomers increases, the number of esterified hydroxyl groups decreases, and the number of constituent fatty acids decreases, the HLB tends to increase. The constituent fatty acid may be a saturated fatty acid or an unsaturated fatty acid. Generally, the constituent fatty acid has 15 to 22 carbon atoms, specifically, pentadecylic acid, palmitic acid, margaric acid, stearic acid, oleic acid, nonadecanoic acid, tuberculostearic acid, arachidic acid, eic acid, behenic acid, etc. Of these, those having 16 to 20 carbon atoms are more preferred, and stearic acid and oleic acid having 18 carbon atoms are most preferred from the viewpoint of dispersibility in the pretreatment material for impression-taking.

  The polyglycerin constituting the polyglycerin fatty acid ester is a dimer to a 12-mer, that is, diglycerin, triglycerin, tetraglycerin, pentaglycerin, hexaglycerin, heptaglycerin, octaglycerin, nonaglycerin, decaglycerin. Undecaglycerin and dodecaglycerin are preferable, and octamerin, nonaglycerin, and decaglycerin of octamer to 10mer are more preferable from the viewpoint of dispersibility in the pretreatment material for obtaining an impression.

  In addition, the number of esterified hydroxyl groups in the polyglycerin is appropriately selected in order to obtain a desired HLB, although it depends on the number of glycerin monomers, and generally 1 to 8 substitutions are used. Specific examples of polyglycerin fatty acid esters having an HLB of 2.0 to 6.0 that are particularly preferably used in the present invention include pentaglycerin monopentadecylate, pentaglycerin monopalmitate, triglycerin monomalga. Phosphate ester, diglycerol monostearate ester, diglycerol monooleate ester, diglycerol monoisostearate ester, tetraglycerol monostearate ester, tetraglycerol monooleate ester, hexaglycerol tristearate ester, decaglycerol pentastearin Acid ester, decaglycerin pentaisostearate, decaglycerin pentaoleate, decaglycerin pentanonadecanoate, decaglycerate Acre esters, deca glyceryl tri behenic acid ester and the like.

  Among the polyglycerin fatty acid esters described above, decaglycerin pentastearic acid ester (HLB = 3.5) in the range of HLB = 3.0 to 4.0 from the viewpoint of dispersibility of the pretreatment material for impression taking. It is particularly preferable to use decaglycerin pentaisostearate (HLB = 3.5) and decaglycerin pentaoleate (HLB = 3.5).

  Moreover, you may use surfactant in combination of 2 or more types.

  Although it does not specifically limit regarding the compounding quantity of surfactant, (A) The inside of the range of 10 mass parts-500 mass parts is preferable with respect to 100 mass parts of alginate, The inside of the range of 50 mass parts-100 mass parts is preferable. More preferred.

(C) Water The water used for the pretreatment material for obtaining an impression of the present invention contains calcium ions eluted from the gelling agent in the alginate impression material in the pretreatment material when contacting the alginate impression material. And the function of promoting the gelation reaction by the alginate and calcium ions in the pretreatment material and the function of adjusting the viscosity of the pretreatment material to an appropriate range.

  As water used for the pretreatment material for impression acquisition of the present invention, tap water, ion-exchanged water, distilled water and the like can be used. The amount of water used is preferably used in the range of 100 parts by mass to 10000 parts by mass, and in the range of 500 parts by mass to 3000 parts by mass with respect to 100 parts by mass of the alginate in the pretreatment material for obtaining an impression. It is more preferable to use within.

[Additive]
In addition to the components described above, various additives can be blended in the pretreatment material for taking an alginate impression of the present embodiment as necessary. Examples of the additive include a fragrance, a coloring amount, an antibacterial agent, an antiseptic, a pH adjuster, and the like, and any one or a plurality of additives selected from these may be blended as necessary. Can do.

[Usage of pretreatment material for impression acquisition]
Although the adjustment method of the pretreatment material for alginate impression collection of this embodiment is not specifically limited, For example, it can adjust as follows. That is, (A) an alginate, (B) a surfactant, and (C) water may be weighed and kneaded until a uniform paste is obtained.

  Moreover, although the manufacturing method of the above-mentioned pretreatment material for alginate impression collection is not particularly limited, it can be manufactured using a known stirring mixer that can be used for paste manufacturing. Here, as the stirring mixer, for example, a rotating container type mixing and kneading machine such as a ball mill, a ribbon mixer, a kneader, an internal mixer, a screw kneader, a Henschel mixer, a universal mixer, a Ladige mixer, a butterfly mixer, etc. A fixed container type mixing kneader having a horizontal axis or a vertical axis can be used.

  It is preferable to prepare a large amount of the pretreatment material for impression collection of the present embodiment in advance and store it in a sealed container such as an aluminum pack because it can be stored for a long period of time. Furthermore, if a pre-treatment material used in a single combined impression is sealed and filled in a syringe-type sealed container that can discharge paste from the tip, it is possible to improve operability as well as long-term storage. It is.

  Although the usage method of the pretreatment material for alginate impression collection of this embodiment is not specifically limited, For example, it can be used as follows. That is, immediately before taking an impression using an alginate impression material, after applying the pretreatment material of this embodiment so as to wrap the teeth to be taken, take the alginate impression material on the impression taking tray, The impression acquisition part to which is applied may be pressed and left until the impression material is cured (usually 2 to 5 minutes), and then the impression may be removed from the teeth.

[Amount of pretreatment material for impression acquisition]
The coating amount (thickness) of the pretreatment material of the present invention is not particularly defined as long as it does not depart from the spirit of the present invention, but a gel of alginate in the pretreatment material and calcium ions transferred from the alginate impression material From the viewpoint of the chemical reaction, the coating thickness of the pretreatment material is preferably within 1 cm, and more preferably within 0.5 cm 2. When the coating thickness of the pretreatment material exceeds 1 cm, the gelation reaction efficiency between the alginate in the pretreatment material and the calcium ions transferred from the alginate impression material decreases, and the gel strength of the lowermost layer tends to be insufficient. It is in.

[Alginate impression material]
As the alginate impression material that can be used in combination with the pretreatment material for obtaining an alginate impression of the present invention, a commercially available known alginate impression material can be used without any limitation.

  Alginate impression materials are classified into two types, powder type and paste type, from the state of packaging. Powder type alginate impression materials include alginate such as potassium alginate and sodium alginate; gelling reagents such as calcium sulfate dihydrate, calcium sulfate hemihydrate, calcium sulfate anhydrous; trisodium phosphate, sodium pyrophosphate, etc. Gel mixture regulator; Filler such as diatomaceous earth; powder mixture mainly composed of inorganic compounds such as zinc oxide, magnesium oxide, potassium titanium fluoride, etc. These are used for impression taking by kneading a specified amount of impression material powder and water into a paste. On the other hand, the paste type impression material is a base paste in which the alginate and the filler are previously made into a uniform paste solution containing water, a gelation reaction material, a gelation modifier, a filler, an inorganic compound, Is a paste made with a hydrophobic solvent, and is used for taking an impression after taking a specified amount of both before use and kneading and mixing to make a uniform paste. Any of the above powder types and paste types can be used as a combination impression together with the pretreatment material for obtaining an alginate impression of the present embodiment.

[Impression taking kit]
The impression kit of this embodiment is a kit in which the pretreatment material for taking an alginate impression of the present invention and the above-described alginate impression material of either powder type or paste type are combined.

The present invention will be described below in more detail with reference to examples. However, the present invention is not limited to the following examples.
[Abbreviations of raw materials]
Abbreviations of various raw materials used in the preparation of pretreatment materials for alginate impressions in Examples and Comparative Examples described below are as follows.

1. Alginate Alg-1: Potassium alginate M / G ratio = 1.6, 1% by mass aqueous solution viscosity 500 mPa · s
Alg-2: Sodium alginate M / G ratio = 1.6, 1 mass% aqueous solution viscosity 500 mPa · s
Alg-3: Potassium alginate M / G ratio = 0.4, 1 mass% aqueous solution viscosity 500 mPa · s
Alg-4: Potassium alginate M / G ratio = 0.5, 1 mass% aqueous solution viscosity 500 mPa · s
Alg-5: Potassium alginate M / G ratio = 0.7, 1% by mass aqueous solution viscosity 500 mPa · s
Alg-6: Potassium alginate M / G ratio = 0.5, 1 mass% aqueous solution viscosity 950 mPa · s
Alg-7: Potassium alginate M / G ratio = 0.5, 1 mass% aqueous solution viscosity 30 mPa · s

2. Surfactant SDS: Sodium dodecyl sulfate POEMPE: Polyethylene methyl phenyl ether DGMRE: Decaglycerin monolaurate (HLB = 15.5)
DGTOE: Decaglycerin trioleate (HLB = 7.0)
HGSE: hexaglycerin tristearate (HLB = 2.5)
DGSE: Decaglycerin pentastearate (HLB = 3.5)
DGOE: Decaglycerin pentaoleate (HLB = 3.5)
DIGMOE: Diglycerin monooleate (HLB = 5.5)

3. Alginate impression material product A: Paste type alginate impression material (Tokuyama Dental Co., Ltd.) using “Tokuyama AP-1 paste” for both hardener and base material
Product B: Powder type alginate impression material (manufactured by Tokuyama Dental)
Product C: Competitor product of powder type alginate impression material Product D: Competitor product of powder type alginate impression material

4). Agar impression material E: Commercially available agar impression material F: Commercially available agar impression material G: Commercially available agar impression material

[Evaluation method]
The evaluation methods of “viscosity”, “impression accuracy”, and “impression surface evaluation” for the samples of Examples and Comparative Examples described later are as follows.

(1) Viscosity measurement A suitable amount of pretreatment material is placed on a cone plate viscometer (CS rheometer CVO120HR manufactured by BOHLIN), and viscosity measurement is started while maintaining at 23 ° C., at a shear rate of 0.1 / s. The viscosity 66 seconds after the start of measurement was η23 _0.1 / Pa · s (Pascal Sec). The measurement conditions for the viscosity were a cone diameter of 2 cm and a cone inclination angle of 1 °.

(2) Impression accuracy When the impression accuracy was evaluated, a pair of molds shown in FIG. 4 was used. Here, as shown in FIG. 4, the pair of molds used for the evaluation of impression accuracy includes a first mold 10 and a second mold 20. The first mold 10 has two concave portions 12R and 12L, and the second mold 20 has two convex portions 22R and 22L. Further, as shown in FIG. 4, the first mold 10 and the second mold 20 are configured so that the concave portion 12R and the convex portion 22R and the concave portion 12L and the convex portion 22L coincide with each other. In the case where the second mold 20 and the second mold 20 are fitted, both have a dimensional accuracy that can be fitted with substantially no gap. The shapes and dimensions of the protrusions 22R and 22L are assumed to be a bridge crown, and the height H of the protrusions 22R and 22L is 10 mm, and the width W of the top is 8 mm.

  After applying the adjusted pretreatment material for each alginate impression of the present invention so as to wrap the convex portions 22R and 22L of the second mold 20 so that the coating thickness is within the range of 1 mm to 5 mm, the stock is processed. Press the button on the watch to start measuring time.

  Next, when the alginate impression material used for the combined impression is a paste type, a base paste and a curing agent paste prepared in advance are used with an alginate impression material automatic mixer AP mixer II (manufactured by Tokuyama Dental Co., Ltd.). Kneaded. Also, if it is a powder type alginate impression material, the powder component is mixed in advance until it becomes a uniform powder. Kneaded until the shape.

  Thereafter, the alginate kneaded material was poured into a resin tray having a size capable of completely accommodating the second mold 20, and the surface was smoothed. And, the time after applying the pretreatment material for alginate impression to the second mold 20 became a desired time (after 15 seconds, after 30 seconds, after 1 minute, after 2 minutes, after 5 minutes). At that time, the second mold 20 was brought into pressure contact with the kneaded material disposed in the resin tray so that the surface provided with the convex portions 22R and 22L faced downward. In this state, the kneaded product was allowed to stand for 3 minutes to cure, and then the second mold 20 was removed to obtain an impression.

  Next, a cemented gypsum for making an impression mold (GC FUJI FUJI LOCK) is poured into the impression collection part of the cured product after the impression is taken, and then a sealed container with water on the bottom. The gypsum was cured by leaving it in a moisturizing box kept at a humidity of 80% or more for 1 hour.

  Then, as shown in FIG. 5, the surface of the plaster model 30 on which the convex portions 32R and 32L are provided and the surface of the first mold 10 on which the concave portions 12R and 12L are provided are fitted together. In the state, the length of the gap formed between the plaster model 30 and the first mold 10 was measured using a microscope (Laser microscope armor VK-8700 manufactured by KEYENCE). As shown in FIG. 2, the gap length is measured as follows: (1) Between the bottom surface of the concave portion 12L and the top surface of the convex portion 32L facing the bottom surface, two points near both ends (FIG. 2). (Positions indicated by reference signs A and B in the middle), (2) In the region between the convex portion 32R and the convex portion 32L, the surface of the first mold 10 and the surface of the plaster model 30 facing this surface Between the two points (positions indicated by reference numerals C and D in FIG. 2), and (3) between the bottom surface of the concave portion 12R and the top surface of the convex portion 32R facing the bottom surface. Measurements were made at two points near the both ends (positions indicated by symbols E and F in FIG. 2). Then, the average value of the six gap lengths measured at points A to F was obtained as “impression accuracy”. In FIG. 5, when the second mold 20 is used instead of the plaster model 30, the “impression accuracy” obtained in the same manner as described above is 5.0 μm.

  “15 seconds later”, “30 seconds later”, “1 minute later”, “2 minutes later”, and “5 minutes later” shown in the “Impression accuracy” column of the table described later are for the alginate impression of the present invention. The results from applying the pretreatment material to performing the combined impression using the alginate impression material are 15 seconds, 30 seconds, 1 minute, 2 minutes, and 5 minutes. It is shown.

(3) Impression surface evaluation After applying the adjusted pretreatment material for alginate impression of the present invention so as to wrap the convex portions 22R and 22L of the second mold 20, the button of the stopwatch is pressed, Time measurement started.

  Next, when the alginate impression material used for the combined impression is a paste type, a base paste and a curing agent paste prepared in advance are used with an alginate impression material automatic mixer AP mixer II (manufactured by Tokuyama Dental Co., Ltd.). Kneaded. Also, if it is a powder type alginate impression material, the powder component is mixed in advance until it becomes a uniform powder. Kneaded until the shape.

  Thereafter, the alginate kneaded material was poured into a resin tray having a size capable of completely accommodating the second mold 20, and the surface was smoothed. And, the time after applying the pretreatment material for alginate impression to the second mold 20 became a desired time (after 15 seconds, after 30 seconds, after 1 minute, after 2 minutes, after 5 minutes). At that time, the second mold 20 was brought into pressure contact with the kneaded material disposed in the resin tray so that the surface provided with the convex portions 22R and 22L faced downward. In this state, the kneaded product was allowed to stand for 3 minutes to cure, and then the second mold 20 was removed to obtain an impression.

Next, the impression acquisition surface of the cured product after the impression was acquired and the impression acquisition portion of the second mold 20 were visually observed, and the appearance of the impression surface was evaluated according to the following evaluation criteria.
Impression surface evaluation criteria:
○: No pre-treatment material or alginate impression material cured body remains in the impression acquisition part of the second mold 20, and the impression surface of the cured product after the impression acquisition is in a glossy and smooth state. is there.
Δ: Some of the pre-treated material cured body remains in the impression acquisition portion of the second mold 20, and the impression surface of the cured product after the impression acquisition has a glossy and rough surface (rough surface) Is occurring).
X: The pretreatment material and the alginate impression material are not adhered at all, and all of the pretreatment material cured product remains in the impression acquisition portion of the second mold 20.

  In addition, “after 15 seconds”, “after 30 seconds”, “after 1 minute”, “after 2 minutes”, and “after 5 minutes” shown in the “impression surface evaluation” column of the table to be described later are those of the present invention. When applying the pretreatment material for alginate impression and performing the combined impression using the alginate impression material after 15 seconds, 30 seconds, 1 minute, 2 minutes, and 5 minutes The results are shown.

Reference example 1
(A) 100 g of Alg-1 as an alginate, (B) 80 g of DGOE as a surfactant, (C) 1820 g of distilled water as water, and a small kneader (Aiko mixer manufactured by Aiko Sangyo Co., Ltd.) The pretreatment material 1 was prepared by kneading for 1 hour.

  After the viscosity of the adjusted pretreatment material 1 was measured, the impression surface evaluation and the impression accuracy were evaluated using the pretreatment material 1 and the alginate impression material “product A”.

Reference Example 2, Examples 3-12, Reference Examples 3-7, Examples 18-28
Except that the pretreatment material and the alginate impression material were changed to the contents shown in Table 3, the viscosity of the pretreatment material was measured, the impression surface was evaluated, and the impression accuracy was evaluated in the same manner as in Reference Example 1 . .

Comparative Examples 1 to 8
Except for changing the pretreatment material and the alginate impression material to the contents shown in Table 4, the viscosity of the pretreatment material was measured, the impression surface was evaluated, and the impression accuracy was evaluated in the same manner as in Reference Example 1 . .

Tables 1 and 2 show the compositions and viscosities of the pretreatment materials of Reference Examples 1 and 2, Examples 3 to 12, Reference Examples 3 to 7, Examples 18 to 28, and Comparative Examples 1 to 8. In addition, Table 3 and Table 3 show the evaluation results of impression surface evaluation and impression accuracy of Reference Examples 1 and 2, Examples 3 to 12, Reference Examples 3 to 7, Examples 18 to 28, and Comparative Examples 1 to 8. 4 shows.

Examples 3 to 12 and Examples 18 to 28 were carried out so as to satisfy all the requirements of the present invention, but in any case, they were not affected by the standing time after applying the pretreatment material. The pretreatment material and the alginate impression material are sufficiently adhered, and a good impression taking surface is obtained. Also, good results are obtained in impression accuracy. Further, (A) an alginate having an M / G ratio in the range of 0.4 to 0.7 as an alginate, and (B) a polyglycerol fatty acid having an HLB of 2.0 to 6.0 as a surfactant. When an ester is used, the calcium ion in the alginate impression material is quickly transferred to the pretreatment material, and the reaction efficiency with the alginate is improved and a firm gel is formed. Impression accuracy is obtained.

  On the other hand, Comparative Examples 1 to 3 are cases where a combined impression was performed using a commercially available agar impression material instead of using the pretreatment material for alginate impression of the present invention. A good impression-taking surface can be obtained 15 to 30 seconds after application, but the agar impression material is already cured before the combined impression is made using the alginate impression material after 1 minute or more. Therefore, it is not possible to obtain a sufficient impression taking surface. Even when the combined impression is performed 15 seconds to 30 seconds after the application of the agar impression material, the impression accuracy is reduced as compared with the case where the pretreatment material of the present invention is used.

  Comparative Examples 4 to 7 are cases where all the essential components of the pretreatment material for alginate impression of the present invention are blended, but the viscosity of the pretreatment material does not satisfy the requirements of the present invention, but the viscosity is 80 Pa. -If it exceeds s, the pretreatment material cannot flow into the details of the model (corner corners) and the like, resulting in bubble marks and the like, and the impression accuracy is greatly reduced. Also, if the viscosity is less than 5 Pa · s, the pretreatment material will flow down from the model after application, so the pretreatment material cannot be properly placed on the model, and the impression accuracy will be greatly reduced. doing.

  Comparative Example 8 is a case where a combined impression was performed using a pretreatment material that does not contain (B) a surfactant, which is an essential component of the present invention, but the familiarity between the pretreatment material and the alginate impression material Insufficient, when contacted with the alginate impression material, a sufficient amount of calcium ions is not supplied into the pretreatment material, resulting in insufficient gel strength of the pretreatment material cured product, resulting in a significant decrease in impression accuracy. Yes.

Claims (2)

(A) The M / G ratio which is β-D mannuronic acid and α-L guluronic acid as a unit structure and which is the molar ratio of β-D mannuronic acid to α-L guluronic acid is 0.4 to 0.7. The alginate in which the ratio of the alginate within the range is 90% by mass or more of the entire alginate, and (B) a polyglycerin fatty acid ester having a hydrophilic / lipophilic balance (HLB) of 2.0 to 6.0. A pretreatment material for taking an alginate impression, comprising a surfactant and (C) water and having a viscosity in the range of 5 to 80 Pa · s at 23 ° C. An impression kit comprising the pretreatment material for obtaining an alginate impression according to claim 1 and an alginate impression material.

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