JP6093729B2 - Styrene polymer functional film and method for producing the same - Google Patents

Description

The present invention relates to a styrenic polymer functional film and a method for producing the same.

As polymer functional membranes having various functions, ion exchange membranes, reverse osmosis membranes, forward osmosis membranes, gas separation membranes and the like are known.
For example, ion exchange membranes are used for electrodeionization (EDI), continuous electrodeionization (CEDI), electrodialysis (ED), reverse electrodialysis (EDR), and the like. .

  Various examples of production of ion exchange membranes have been reported so far, and the use of a chain transfer agent has been proposed in order to improve the film-forming property. For example, Patent Document 1 discloses a method for producing an ion exchange membrane made of a styrene monomer using 2,4-diphenyl-4-methyl-1-pentene as a chain transfer agent, and Patent Document 2 discloses a chain transfer agent. A method for producing a cation exchange membrane composed of a perfluorocarbon monomer / perfluoroolefin copolymer having a sulfo group, which uses a saturated hydrocarbon for the cation exchange membrane, has been proposed.

JP 2006-206633 A JP 2006-83342 A

Film formation is improved by using 2,4-diphenyl-4-methyl-1-pentene or saturated hydrocarbon as a chain transfer agent in the polymerization and curing reaction, but in particular, when a styrene monomer is used, polymerization is performed. It took a long time to cure, and improvement was necessary for mass production.
Moreover, conventional ion exchange membranes increase the electrical resistance of the membrane when the water permeability is lowered, and conversely, the water permeability increases when the electrical resistance of the membrane is lowered, further improving the performance of the polymer functional membrane. In order to achieve this, it is important to lower the water permeability and lower the electrical resistance of the membrane. Thereby, for example, a reduction in energy required for electrodialysis is expected.
Accordingly, it is an object of the present invention to develop a means for reducing the water permeability and the electrical resistance of the membrane in a well-balanced manner, thereby providing a styrenic polymer functional membrane having excellent ion exchange membrane performance and a method for producing the same. And Furthermore, an object of the present invention is to provide a method for producing a styrenic polymer functional film having a shortened polymerization curing time and suitable for mass production.

In order to reduce the water permeability and the electrical resistance of the membrane in a well-balanced manner, the present inventors have studied various styrene-based ion exchange membranes. In particular, as a result of finding a clue to the chain transfer agent having at least two action sites and further studying it, a product having a mercapto group as the action group has a good balance between the water permeability and the electrical resistance of the membrane. It has been found that it can be a means that can be lowered, and has been found to be effective in solving the problems of the present invention. In addition, the time required for the polymerization and curing can be shortened by polymerizing and curing the composition containing a chain transfer agent whose functional group is a mercapto group under specific polymerization conditions, and the improvement required for the above-mentioned mass production can be achieved. Found to get. The present invention has been made based on these findings.
That is, the object of the present invention has been achieved by the following means.

<1> A styrenic polymer having a structure represented by the following general formula (1) and a structure represented by the following general formula (2) and having an ion exchange capacity of 2.0 meq / g to 7.0 meq / g. Molecular functional membrane.

In the general formula (1), LL represents a single bond, an alkylene group which may have a substituent, —O—, —S—, —NR ^Z — or a linking group in which these are combined. LL ¹ and LL ² each independently represent — (CR ¹ R ² ) ₁ — or — (CR ¹ R ² ) ₁ —C (═O) O— in which the atom bonded to LL is an oxygen atom. R ¹ and R ² each independently represents a hydrogen atom or an alkyl group, and l represents 1 or 2. R ^Z represents a hydrogen atom or a substituent. However, if the terminal atom of the substituents of substituents and R ^Z in the LL is a sulfur atom, a sulfur atom having a bond incorporated in the polymer chain.

In the general formula (2), Ar represents an aryl group. L ¹ represents a single bond or a divalent linking group. n1 represents an integer of 0 to 10.
<2> The styrenic system according to <1>, in which the content of the structural portion represented by the general formula (1) is 0.01 parts by mass to 10 parts by mass with respect to the total 100 parts by mass of the polymer functional film. Polymer functional membrane.
<3> (A) A styrene monomer represented by the following general formula (HSM), (B) a crosslinking agent represented by the following general formula (CL), and (C) a chain represented by the following general formula (3). The styrenic polymer functional film according to <1> or <2>, which is obtained by polymerizing and curing a composition containing a transfer agent.

In the general formula (HSM), R ³ represents a halogen atom or —N ⁺ (R ⁴ ) (R ⁵ ) (R ⁶ ) (X ₁ ⁻ ). n2 represents an integer of 1 to 10. Here, R ^{4 to} R ⁶ each independently represents a linear or branched alkyl group or aryl group. R ⁴ and R ⁵ , or R ⁴ , R ⁵ and R ⁶ may be bonded to each other to form an aliphatic heterocycle. X ₁ ⁻ represents an organic or inorganic anion.

In general formula (CL), Ar represents an aryl group. L ¹ represents a single bond or a divalent linking group. n1 represents an integer of 0 to 10.

In the general formula (3), LLa represents ^a single bond, an alkylene group which may have a substituent, -O-, -S-, -NR ^Za -or a linking group in which these are combined. LL ¹ and LL ² each independently represent — (CR ¹ R ² ) ₁ — or — (CR ¹ R ² ) ₁ —C (═O) O— in which the atom bonded to LL ^a is an oxygen atom. R ¹ and R ² each independently represents a hydrogen atom or an alkyl group, and l represents 1 or 2. R ^Za represents a hydrogen atom or a substituent. However, if the terminal atom of the substituents of substituents and ^{R Za} of LL ^a is a sulfur atom, an SH.
<4> The styrenic polymer functional film according to <3>, wherein the composition further comprises (D) a polymerization initiator represented by the following general formula (PI-1) or (PI-2).

In General Formula (PI-1), R ⁷ represents a hydrogen atom, an alkyl group, an alkenyl group, an alkoxy group, or an aryloxy group, and R ⁸ and R ⁹ each independently represent a hydrogen atom, an alkyl group, an alkenyl group, an alkoxy group Represents a group or an aryloxy group, and R ⁸ and R ⁹ may be bonded to each other to form a ring.
In General Formula (PI-2), R ¹⁰ represents an alkyl group, an aryl group, an alkylthio group, or an arylthio group, and R ¹¹ represents an alkyl group, an aryl group, an alkylthio group, an arylthio group, or an acyl group. R ¹² represents an alkyl group or an aryl group.
<5> The content of the styrene monomer represented by the general formula (HSM) is 1 part by mass to 85 parts by mass with respect to 100 parts by mass of the total solid content of the composition <3> or <4 > A styrenic polymer functional film described in>.
<6> Any <3> to <5> in which the content of the crosslinking agent represented by the general formula (CL) is 10 parts by mass to 100 parts by mass with respect to 100 parts by mass of the total solid content of the composition. A styrenic polymer functional film according to claim 1.
<7> The content of the chain transfer agent represented by the general formula (3) is 0.01 parts by mass to 10 parts by mass with respect to 100 parts by mass of the total solid content of the composition. The styrenic polymer functional film according to any one of 6>.
<8> The styrenic polymer functional film according to any one of <3> to <7>, wherein the composition contains (F) a solvent.
<9> (F) The styrenic polymer functional film according to <8>, wherein the solvent is water or a water-soluble solvent.
<10> The styrenic polymer functional film according to any one of <1> to <9>, comprising a synthetic woven fabric or synthetic nonwoven fabric, a sponge-like film, or a film-like support having fine through-holes.
<11> The styrenic polymer functional film according to any one of <3> to <10>, wherein the polymerization curing reaction is performed by heating and / or energy beam irradiation.
<12> A method for producing a styrene-based polymer functional membrane, wherein the polymer functional membrane has an ion exchange capacity of 2.0 meq / g to 7.0 meq / g, and (A) the following general formula (HSM) (B) a composition containing a crosslinking agent represented by the following general formula (CL) and (C) a chain transfer agent represented by the following general formula (3). A method for producing a polymer functional membrane.

In the general formula (HSM), R ³ represents a halogen atom or —N ⁺ (R ⁴ ) (R ⁵ ) (R ⁶ ) (X ₁ ⁻ ). n2 represents an integer of 1 to 10. Here, R ^{4 to} R ⁶ each independently represents a linear or branched alkyl group or aryl group. R ⁴ and R ⁵ , or R ⁴ , R ⁵ and R ⁶ may be bonded to each other to form an aliphatic heterocycle. X ₁ ⁻ represents an organic or inorganic anion.

In general formula (CL), Ar represents an aryl group. L ¹ represents a single bond or a divalent linking group. n1 represents an integer of 0 to 10.

In the general formula (3), LLa represents ^a single bond, an alkylene group which may have a substituent, -O-, -S-, -NR ^Za -or a linking group in which these are combined. LL ¹ and LL ² each independently represent — (CR ¹ R ² ) ₁ — or — (CR ¹ R ² ) ₁ —C (═O) O— in which the atom bonded to LL ^a is an oxygen atom. R ¹ and R ² each independently represents a hydrogen atom or an alkyl group, and l represents 1 or 2. R ^Za represents a hydrogen atom or a substituent. However, if the terminal atom of the substituents of substituents and ^{R Za} of LL ^a is a sulfur atom, an SH.

In the present specification, “to” is used to mean that the numerical values described before and after it are included as a lower limit value and an upper limit value.
In each general formula, unless otherwise specified, when there are a plurality of groups having the same sign, these may be the same or different from each other, and similarly, when there are repetitions of a plurality of partial structures, These repetitions mean both the same repetition and a mixture of different repetitions within the specified range.
Each group defined in each general formula may further have a substituent unless otherwise specified. For example, in the case of an alkyl group or an aryl group, an alkyl group or a substituent that may have a substituent. Means an aryl group which may have
Furthermore, the geometrical isomer which is the substitution mode of the double bond in each general formula is not limited to the E-form or the Z-form unless otherwise specified, even if one of the isomers is described for convenience of display. Or a mixture thereof.

  In addition, when the term “compound” is used at the end in this specification, or when a specific compound is indicated by its name or formula, in addition to the compound itself, a dissociative partial structure in the chemical structural formula If it has, it is used in the meaning including its salt and its ion. Further, in this specification, when the term “group” is added to the end of the description, or when a specific compound is referred to by its name, the group or compound may have an arbitrary substituent. Meaning.

According to the present invention, means for reducing the water permeability and the electrical resistance of the membrane in a well-balanced manner has been developed. As a result, it has become possible to reduce the energy required for electrodialysis and the like. By this means, it has become possible to provide a styrenic polymer functional membrane having excellent ion exchange membrane performance and a method for producing the same. In addition, it is possible to provide a method for producing a styrenic polymer functional film having a shortened polymerization curing time and suitable for mass production.

The flow path of the apparatus for measuring the water permeability of a film | membrane is typically represented.

<< Polymer functional film >>
The styrenic polymer functional membrane of the present invention (in this specification, the styrenic polymer functional membrane may be referred to as “polymer functional membrane” or simply “membrane”) It can be used to perform osmosis, forward osmosis, gas separation and the like. Hereinafter, a preferred embodiment of the present invention will be described by taking as an example the case where the polymer functional membrane has a function as an anion exchange membrane.

<Product of water permeability and electrical resistance of membrane>
Both the water permeability and the electrical resistance of the membrane are preferably low.
In the present invention, a decrease in water permeability and a decrease in electrical resistance of the membrane are reduced in a balanced manner. As an evaluation standard for this purpose, it is effective to compare the product value of the water permeability and the electrical resistance of the membrane.
The value [(Ω · cm ² ) · (mL / m ² / Pa / hr)] of the product of the water permeability and the electrical resistance of the membrane is preferably as low as possible. In the present invention, it is preferably less than 15 × 10 ⁻⁵ , more preferably less than 12 × 10 ⁻⁵ , and particularly preferably less than 10 × 10 ⁻⁵ . The lower limit is not particularly limited, but 3 × 10 ⁻⁵ or more is practical.

  In the present invention, even if the same crosslinking agent is used, the product of the water permeability and the electrical resistance of the membrane is lowered by using the chain transfer agent represented by the general formula (3) of the present invention. This is an effective means for reducing the product of the water permeability and the electrical resistance of the membrane.

In addition, a water permeability can be measured by the method performed in the Example.
The electrical resistance of the film can be measured by the method described in, for example, Membrane Science, 319, 217-218 (2008), Masayuki Nakagaki, Membrane Experimental Method, pages 193-195 (1984).

<Selective permeability>
The selective permeability of anions such as Cl 2 ⁻ of the polymer functional membrane (anion exchange membrane) of the present invention is preferably more than 0.90, more preferably more than 0.93, more than 0.95, It is particularly preferable that the value approaches 1.0.

<Swelling rate>
The swelling ratio (rate of dimensional change due to swelling) of the functional polymer film of the present invention in water is preferably less than 30%, more preferably less than 15%, and particularly preferably less than 8%. The swelling rate can be controlled by selecting polymerization curing conditions in the polymerization curing stage.

<Measurement of selective permeability and swelling ratio in water>
For example, Membrane Science, 319, 217 to 218 (2008), Masayuki Nakagaki, Membrane Experimental Method, pages 193 to 195 (1984) are the same as the electrical resistance of the membrane. It can be measured by the method described.

<Thickness of film>
The polymer functional membrane of the present invention is preferably an anion exchange membrane.
When it has a support body, the thickness of the film | membrane of this invention is 30-250 micrometers including a support body, 40-200 micrometers is more preferable, 50-150 micrometers is especially preferable.

<Mass average molecular weight>
The mass average molecular weight of the polymer constituting the polymer functional film of the present invention is several hundred thousand or more because three-dimensional crosslinking is formed, and cannot be measured substantially. Generally considered as infinite.

<Structure of polymer functional film>
The polymer functional film of the present invention has at least a structure represented by the following general formula (1) and a structure represented by the following general formula (2).

  First, the structure represented by the general formula (1) will be described.

In the general formula (1), LL represents a single bond, an alkylene group which may have a substituent, —O—, —S—, —NR ^Z — or a linking group in which these are combined. LL ¹ and LL ² each independently represent — (CR ¹ R ² ) ₁ — or — (CR ¹ R ² ) ₁ —C (═O) O— in which the atom bonded to LL is an oxygen atom. R ¹ and R ² each independently represents a hydrogen atom or an alkyl group, and l represents 1 or 2. R ^Z represents a hydrogen atom or a substituent. However, if the terminal atom of the substituents of substituents and R ^Z in the LL is a sulfur atom, a sulfur atom having a bond incorporated in the polymer chain constituting the polymer functional film.

1-12 are preferable and, as for carbon number of the alkylene group in LL, 1-8 are more preferable. For example, methylene, ethylene, propylene, isopropylene, tetramethylene, hexamethylene, octamethylene, decamethylene, and dodecamethylene are mentioned.
Substituents on R ^Z is may be a monovalent substituent polyvalent substituent groups. However, in the case of a polyvalent substituent, the terminal of the substituent (the atom having a bond other than that bonded to the nitrogen atom) is a sulfur atom, that is, -S-). The monovalent substituent is preferably an alkyl group or an aryl group, and the polyvalent substituent is preferably a divalent substituent. The divalent substituent, - alkylene -S -, - arylene -S- are preferred, - alkylene -S- is more _{preferable, - (CH 2) 2 -S} -, - (CH 2) 3 -S- Is more preferable, and — (CH ₂ ) ₂ —S— is particularly preferable.

The number of carbon atoms of the substituents in R ^Z is preferably 1 to 12, more preferably 1 to 10, even more preferably 1-6.

Alkylene group which may have a substituent in LL, -O -, - S -, - NR ^Z - is the linking group combined, for example, alkylene -O- alkylene, alkylene -S- alkylene, - alkylene -NR Z ^- alkylene. Examples of these alkylene ethylene, propylene are preferred, and ethylene is more preferable.

Examples of the substituent that alkylene may have include a substituent group α described later, and among them, an alkyl group and a hydroxy group are exemplified. Here, the substituent may be a polyvalent substituent. For example, —CH ₂ C (═O) O— (CR ¹ R ² ) ₁ —X, —CH ₂ O—CH ₂ C [CH ₂ C (= O) O— (CR ¹ R ² ) ₁ —X] ₃ may be mentioned and is preferable. ^Wherein, R 1, ^{R 2} and l have the same meanings as ^R 1, ^{R 2} and l in LL ¹ and LL ^2, and their preferable ranges are also the same. X represents a hydrogen atom, SH or S-.

^{1 in} LL ¹ and LL ² represents 1 or 2, and R ¹ and R ² each independently represents a hydrogen atom or an alkyl group. Here, 1-10 are preferable, as for carbon number of an alkyl group, 1-6 are more preferable, 1 or 2 is further more preferable, and 1 is especially preferable.
R ¹ and R ² are preferably a hydrogen atom or methyl, and most preferably a hydrogen atom.

  l represents 1 or 2, but 2 is preferred.

  The structure represented by the general formula (1) is preferably a structure represented by the following general formula (1A).

In General Formula (1A), R ^Z represents —S— or — ^* CR ^3a R ^4a R ^5a . ^{* Indicates} a carbon atom bonded to a carbon atom of methylene. R ^3a , R ^4a and R ^5a are each independently an unsubstituted alkyl group, —CH ₂ OH, — ^** CH ₂ (OC═O) _m (CR ^1a R ^2a ) _n S— or — ^** CH ₂ OCH represents a ^{_{2 C [CH 2 (OC =}} O) m (CR 1a R 2a) n S-] 3. ^** indicates a carbon atom bonded to ^* C. However, when R ^Z is not —S—, all of R ^{3a to} R ^5a are not an unsubstituted alkyl group or —CH ₂ OH. R ^1a and R ^2a each independently represents a hydrogen atom, an alkyl group or a hydroxy group. However, when n is 2 or more, R ^1a and R ^2a on the carbon atom bonded to the sulfur atom are a hydrogen atom or an alkyl group. m represents 0 or 1, and n represents an integer of 1 to 12.

The alkyl group in R ^1a and R ^2a is synonymous with the alkyl group in the general formula (1), and the preferred range is the same, but ethyl is particularly preferred.
n is preferably 2 to 6, and 4 is particularly preferable.

  Next, the structure represented by the following general formula (2) will be described.

In the general formula (2), Ar represents an aryl group. L ¹ represents a single bond or a divalent linking group. n1 represents an integer of 0 to 10.

  6-12 are preferable, as for the aryl group in Ar, 6-10 are more preferable, and 6-8 are more preferable. The aryl group may have a substituent, and examples of the substituent include any substituent selected from the substituent group α described below. The aryl group is preferably a phenyl group.

The divalent linking group in L ¹ is an alkylene group, an alkenylene group, an arylene group, a divalent heterocyclic group, —O—, —SO ² —, —SO—, —NR ^Z — or a group in which these are combined. Represents. Here, R ^Z represents a hydrogen atom or a substituent.

1-12 are preferable and, as for carbon number of an alkylene group, 1-4 are more preferable, for example, a methylene, ethylene, propylene, hexamethylene, and octamethylene are mentioned.
2-12 are preferable and, as for carbon number of an alkenylene group, 2-4 are more preferable, for example, ethenylene and propenylene are mentioned.
1-12 are preferable, as for carbon number of a bivalent heterocyclic group, 1-10 are more preferable, and 2-8 are more preferable. The hetero atom constituting the hetero ring is preferably an oxygen atom, a sulfur atom or a nitrogen atom, and may be an aromatic ring or an aliphatic ring. The heterocycle is preferably a 5- or 6-membered ring, and examples thereof include a furan ring, a thiophene ring, an oxazole ring, a thiazole ring, a triazole ring, a pyridine ring, a piperidine ring, and a piperazine ring.

L ¹ is preferably a single bond, an alkylene group, an arylene group, a divalent heterocyclic group, —O— or —SO ² —.

  The alkylene group, alkenylene group, arylene group, and divalent heterocyclic group may have a substituent, and examples of the substituent include any substituent selected from the substituent group α described below.

  n1 is preferably 0 or 1, particularly preferably 0.

<Content of specific structure>
In this invention, 0.01 mass part-10 mass parts are preferable, and, as for content of the structure part represented by the said General formula (1) with respect to all 100 mass parts of a polymeric functional film, 0.05 mass part 10 mass parts is more preferable, 0.05 mass parts-5 mass parts is still more preferable, 0.2 mass parts-4 mass parts is especially preferable.
Moreover, in this invention, 10 mass parts-100 mass parts are preferable, and, as for content of the structure part represented by the said General formula (2) with respect to 100 mass parts of all the polymer functional films, 10 mass parts-90 mass parts. Mass parts are more preferable, and 10 parts by mass to 80 parts by mass are particularly preferable.

Here, the substituent group α will be described.
The substituent group α is a group of substituents composed of the following substituents.

(Substituent group α)
As the substituent group α, an alkyl group (preferably an alkyl group having 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, particularly preferably 1 to 10 carbon atoms, such as methyl, ethyl, isopropyl, and t-butyl. , N-octyl, 2-ethylhexyl, n-decyl, n-hexadecyl), a cycloalkyl group (preferably having 3 to 30 carbon atoms, more preferably 3 to 20 carbon atoms, and particularly preferably 3 to 10 carbon atoms). Group, for example, cyclopropyl, cyclopentyl, cyclohexyl, etc.), an alkenyl group (preferably an alkenyl group having 2 to 30 carbon atoms, more preferably 2 to 20 carbon atoms, particularly preferably 2 to 10 carbon atoms). For example, vinyl, allyl, 2-butenyl, 3-pentenyl, etc.), alkynyl groups (preferably An alkynyl group having 2 to 30 primes, more preferably 2 to 20 carbons, particularly preferably 2 to 10 carbons, and examples thereof include propargyl and 3-pentynyl, and aryl groups (preferably 6 to 6 carbons). 30, more preferably an aryl group having 6 to 20 carbon atoms, particularly preferably 6 to 12 carbon atoms, such as phenyl, p-methylphenyl, naphthyl, anthranyl, etc.), amino group (amino group, alkyl group) An amino group and an arylamino group, preferably an amino group having 0 to 30 carbon atoms, more preferably 0 to 20 carbon atoms, particularly preferably 0 to 10 carbon atoms, such as amino, methylamino, dimethylamino, Diethylamino, dibenzylamino, diphenylamino, ditolylamino, etc.), alkoxy groups (preferably An alkoxy group having 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, and particularly preferably 1 to 10 carbon atoms, and examples thereof include methoxy, ethoxy, butoxy, 2-ethylhexyloxy and the like. Group (preferably an aryloxy group having 6 to 30 carbon atoms, more preferably 6 to 20 carbon atoms, particularly preferably 6 to 12 carbon atoms, and examples thereof include phenyloxy, 1-naphthyloxy, 2-naphthyloxy and the like. And a heterocyclic oxy group (preferably a heterocyclic oxy group having 2 to 30 carbon atoms, more preferably 2 to 20 carbon atoms, particularly preferably 2 to 12 carbon atoms, such as pyridyloxy, pyrazyloxy, pyrimidyloxy, Quinolyloxy, etc.)

An acyl group (preferably an acyl group having 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, particularly preferably 1 to 12 carbon atoms, and examples thereof include acetyl, benzoyl, formyl, pivaloyl, etc.), alkoxy A carbonyl group (preferably an alkoxycarbonyl group having 2 to 30 carbon atoms, more preferably 2 to 20 carbon atoms, particularly preferably 2 to 12 carbon atoms, such as methoxycarbonyl and ethoxycarbonyl), aryloxy A carbonyl group (preferably an aryloxycarbonyl group having 7 to 30 carbon atoms, more preferably 7 to 20 carbon atoms, particularly preferably 7 to 12 carbon atoms, such as phenyloxycarbonyl), an acyloxy group ( Preferably 2-30 carbons, more preferably 2-20 carbons, especially preferred. Or an acyloxy group having 2 to 10 carbon atoms such as acetoxy and benzoyloxy), an acylamino group (preferably having 2 to 30 carbon atoms, more preferably 2 to 20 carbon atoms, and particularly preferably carbon number). 2-10 acylamino groups such as acetylamino and benzoylamino).

An alkoxycarbonylamino group (preferably an alkoxycarbonylamino group having 2 to 30 carbon atoms, more preferably 2 to 20 carbon atoms, particularly preferably 2 to 12 carbon atoms, such as methoxycarbonylamino), aryl Oxycarbonylamino group (preferably an aryloxycarbonylamino group having 7 to 30 carbon atoms, more preferably 7 to 20 carbon atoms, particularly preferably 7 to 12 carbon atoms, and examples thereof include phenyloxycarbonylamino group). , Alkyl or arylsulfonylamino group (preferably having 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, particularly preferably 1 to 12 carbon atoms, and examples thereof include methanesulfonylamino and benzenesulfonylamino). Sulfamoyl group (sulfamoyl group) An alkyl or aryl sulfamoyl group, preferably a sulfamoyl group having 0 to 30 carbon atoms, more preferably 0 to 20 carbon atoms, and particularly preferably 0 to 12 carbon atoms, such as sulfamoyl, methylsulfamoyl, Dimethylsulfamoyl, phenylsulfamoyl, etc.),

A carbamoyl group (including a carbamoyl group, an alkyl or arylcarbamoyl group, preferably a carbamoyl group having 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, and particularly preferably 1 to 12 carbon atoms, such as carbamoyl, methylcarbamoyl , Diethylcarbamoyl, phenylcarbamoyl, etc.), an alkylthio group (preferably an alkylthio group having 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, particularly preferably 1 to 12 carbon atoms, such as methylthio, Ethylthio etc.), an arylthio group (preferably an arylthio group having 6 to 30 carbon atoms, more preferably 6 to 20 carbon atoms, particularly preferably 6 to 12 carbon atoms, such as phenylthio). A heterocyclic thio group (preferably having 2 to 3 carbon atoms) More preferably a heterocyclic thio group having 2 to 20 carbon atoms, particularly preferably 2 to 12 carbon atoms, such as pyridylthio, 2-benzimidazolylthio, 2-benzoxazolylthio, 2-benzthiazolylthio and the like. ),

An alkyl or arylsulfonyl group (preferably an alkyl or arylsulfonyl group having 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, and particularly preferably 1 to 12 carbon atoms, and examples thereof include mesyl and tosyl). An alkyl or arylsulfinyl group (preferably an alkyl or arylsulfinyl group having 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, particularly preferably 1 to 12 carbon atoms, such as methanesulfinyl, benzenesulfinyl, etc. Ureido group (preferably a ureido group having 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, particularly preferably 1 to 12 carbon atoms, and examples thereof include ureido, methylureido, and phenylureido. ), Phosphoric acid amide groups (preferably carbon A phosphoric acid amide group having 1 to 30, more preferably 1 to 20 carbon atoms, particularly preferably 1 to 12 carbon atoms, such as diethyl phosphoric acid amide and phenyl phosphoric acid amide)), hydroxy group, mercapto A group, a halogen atom (for example, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, more preferably a fluorine atom),

A cyano group, a sulfo group, a carboxyl group, an oxo group, a nitro group, a hydroxamic acid group, a sulfino group, a hydrazino group, an imino group, and a heterocyclic group (preferably having a carbon number of 1 to 30, more preferably a heterocyclic group having 1 to 12 carbon atoms) A ring group, and the ring-constituting hetero atom is preferably, for example, a nitrogen atom, an oxygen atom, or a sulfur atom. Specifically, for example, imidazolyl, pyridyl, quinolyl, furyl, thienyl, piperidyl, morpholino, benzoxazolyl, benzimidazolyl , Benzthiazolyl, carbazolyl group, azepinyl group, etc.), silyl group (preferably a silyl group having 3 to 40 carbon atoms, more preferably 3 to 30 carbon atoms, particularly preferably 3 to 24 carbon atoms, Trimethylsilyl, triphenylsilyl, etc.), silyloxy groups (preferably Ku 3 to 40 carbon atoms, more preferably 3 to 30 carbon atoms, particularly preferably a silyloxy group having 3 to 24 carbon atoms, for example trimethylsilyloxy, etc. triphenylsilyl oxy and the like.) And the like.

These substituents may be further substituted with any one or more substituents selected from the above substituent group α.
In the present invention, when one structural site has a plurality of substituents, these substituents are connected to each other to form a ring, or condensed with a part or all of the above structural sites to form an aromatic group. A ring or an unsaturated heterocyclic ring may be formed.

<< Constituent Components of Polymer Functional Film >>
The polymer functional film of the present invention has at least a structure represented by the general formula (1) and a structure represented by the general formula (2). In the present invention, the polymer functional film preferably comprises (A) a styrene-based monomer represented by the following general formula (HSM), (B) a crosslinking agent represented by the following general formula (CL), and the above general It contains (C) a chain transfer agent that forms the structure represented by formula (1) as an essential component, and is further represented by (D) general formula (PI-1) or (PI-2) as necessary. A composition containing (E) a polymerization initiator represented by formula (AI) and (F) a solvent (hereinafter referred to as “polymer functional film-forming composition”). It is formed by a polymerization curing reaction.
Hereinafter, the components constituting the polymer functional film of the present invention will be described in detail.

<(A) Styrene monomer>
The said component (A) used for the composition for polymeric functional film formation in this invention is a styrene-type monomer represented with the following general formula (HSM).

In the general formula (HSM), R ³ represents a halogen atom or —N ⁺ (R ⁴ ) (R ⁵ ) (R ⁶ ) (X ₁ ⁻ ). n2 represents an integer of 1 to 10. Here, R ^{4 to} R ⁶ each independently represents a linear or branched alkyl group or aryl group. R ⁴ and R ⁵ , or R ⁴ , R ⁵ and R ⁶ may be bonded to each other to form an aliphatic heterocycle. X ₁ ⁻ represents an organic or inorganic anion.

_{Here, - (CH 2) n2 -R} 3 may be divided into groups represented by groups and the following formula represented by the following general formula (ALX) (ALA).

Formula (ALX), in (ALA), ^{X 4} represents a halogen ^atom, R 4 to R ⁶ and _{X 1} ^- is ^R in the general formula (HSM) 4 ~R ⁶ and _{X 1} ^- and have the same meanings, The preferred range is also the same. n3 is synonymous with n2 in the general formula (HSM), and the preferred range is also the same.

Examples of the halogen atom represented by R ³ in the general formula (HSM) and X ⁴ in the general formula (ALX) include a fluorine atom, a chlorine atom, a bromine atom and an iodine atom. A fluorine atom, a chlorine atom and a bromine atom are preferable, and a chlorine atom A bromine atom is more preferable, and a chlorine atom is particularly preferable.
N2 in the general formula (HSM), n3 in the general formula (ALX) and general formula (ALA) are preferably 1 or 2, and particularly preferably 1.

In the general formulas (HSM) and (ALA), the alkyl group and aryl group in R ^{4 to} R ⁶ are preferably in the preferred range of the alkyl group and aryl group in Ra, Rb, Rc and Rd of the general formula (2).

The ring formed by combining R ⁴ and R ⁵ with each other is preferably a 5- or 6-membered ring, and examples thereof include a pyrrolidine ring, a piperidine ring, a morpholine ring, a thiomorpholine ring, and a piperazine ring.
Examples of the ring formed by combining R ⁴ , R ⁵ and R ⁶ with each other include a quinuclidine ring and a triethylenediamine ring (1,4-diazabicyclo [2.2.2] octane ring).

X ₁ ⁻ in the general formulas (HSM) and (ALA) has the same meaning as X ₁ ⁻ and X ₂ ⁻ in the general formula (2), and the preferred range is also the same.

  Of the groups represented by the general formula (ALX) or (ALA), the group represented by the general formula (ALA) is preferable.

Hereinafter, in the general formula (HSM), the styrene monomer in the case where — (CH ₂ ) _n2 —R ³ is a group represented by the general formula (ALA) may be referred to as a styrene monomer (SM). Here, although the specific example of a styrene-type monomer (SM) is shown, this invention is not limited to these.

  The monofunctional styrene monomer (SM) compound can be synthesized by the method described in JP-A No. 2000-229917 or JP-A No. 2000-212306 or a method analogous thereto. Moreover, it is also possible to obtain as a commercial item from Sigma-Aldrich.

  In the polymer functional film of the present invention, a combination of two or more monofunctional styrene monomers (SM) may be used.

In the general formula (HSM), when — (CH ₂ ) _n2 —R ³ represents a group represented by the general formula (ALX), a tertiary amine compound which is a quaternary ammonium agent is reacted after polymerization and curing reaction. It is preferable to react the polymer functional membrane to an anion exchange membrane.

In the present specification, hereinafter, in the general formula (HSM), a styrene monomer in the case where — (CH ₂ ) _n2 —R ³ represents a group represented by the general formula (ALX) is referred to as a styrene monomer (HSM). . Here, although the specific example of a styrene-type monomer (HSM) is shown, this invention is not limited to these.

  In the present invention, the content of the styrenic monomer represented by the general formula (HSM) is preferably 1 part by mass to 85 parts by mass with respect to 100 parts by mass of the total solid content of the polymer functional film forming composition. 10 mass parts-85 mass parts are more preferable, and 20 mass parts-80 mass parts are especially preferable.

In the present invention, the polymer functional film-forming composition may contain a styrene monomer other than the styrene monomer represented by the general formula (HSM). Specific examples of the styrene monomer other than the styrene monomer represented by the general formula (HSM) include styrene and styrene oxide.
For 100 parts by mass of the total solid content of the composition for forming a functional polymer film, a styrene monomer other than the styrene monomer represented by the general formula (HSM) and the styrene monomer represented by the general formula (HSM) The total content is preferably 1 part by mass to 85 parts by mass, more preferably 10 parts by mass to 85 parts by mass, and particularly preferably 20 parts by mass to 80 parts by mass.

  A tertiary amine compound which is a quaternary ammonium agent is represented by the following general formula (AA).

In the general formula ^(AA), R 4 ~R ⁶ has the same meaning respectively ^R 4 to R ⁶ in the general formula (ALA), and the preferred range is also the same.

  Next, although the specific example of the tertiary amine compound which is a quaternary ammonium agent is shown, this invention is not limited to these.

There are no particular restrictions on the reaction conditions when the tertiary amine compound, which is a quaternary ammonium agent, is reacted with the polymerized and cured film, but the reaction is usually performed by immersing the polymerized and cured film in a tertiary amine compound solution. . The amine compound solution concentration at this time is preferably 0.01 mol / L to 5.00 mol / L, more preferably 0.05 mol / L to 3.00 mol / L, and 0.10 mol / L to 1. 00 mol / L is particularly preferred.
The temperature at which the polymerized and cured film is immersed in the tertiary amine compound solution is preferably 0 to 100 ° C, more preferably 10 to 80 ° C, and particularly preferably 20 to 60 ° C.
The time for immersing the polymerized and cured film in the tertiary amine compound solution is preferably 0.5 to 24 hours, more preferably 1 to 18 hours, and particularly preferably 2 to 12 hours.

<(B) Crosslinking agent represented by general formula (CL)>
In order to form the structure represented by the general formula (2) of the polymer functional film of the present invention, (B) a crosslinking agent represented by the following general formula (CL) is used.

In general formula (CL), Ar represents an aryl group. L ¹ represents a single bond or a divalent linking group. n1 represents an integer of 0 to 10.

  Specific examples of the crosslinking agent represented by the general formula (CL) are shown below, but the present invention is not limited thereto.

  The crosslinking agent represented by the general formula (CL) is commercially available and can be synthesized by a method based on a conventional method.

  In the polymer functional film of the present invention, (B) two or more kinds of crosslinking agents represented by the general formula (CL) may be used in combination.

  In this invention, content of the crosslinking agent represented by the said (B) general formula (CL) is 10 mass parts-100 mass parts with respect to 100 mass parts of total solid of the composition for polymeric functional film formation. Is preferable, 10 mass parts-90 mass parts is more preferable, and 10 mass parts-80 mass parts is especially preferable.

  In the composition for forming a functional polymer film in the present invention, the molar ratio of (A) the styrene monomer represented by the general formula (HSM) and (B) the crosslinking agent represented by the general formula (CL) is: (A) Component mole / (B) Component mole is preferably 1 / 0.1 to 1/55, more preferably 1 / 0.14 to 1/55, and particularly preferably 1 / 0.3 to 1/55. .

In the present invention, the crosslink density of the polymer formed by reacting the styrene monomer represented by (A) the general formula (HSM) and the crosslinker represented by (B) the general formula (CL) is 0.4. ˜2 mmol / g is preferable, 0.5 to 2 mmol / g is more preferable, and 1.0 to 2 mmol / g is particularly preferable.
When the crosslinking density is within the above range, the membrane water content is decreased, the water permeability is decreased, and the membrane resistance is also small.

<(C) Chain transfer agent>
The chain transfer agent (C) used in the composition for forming a functional polymer film in the present invention is not particularly limited, but a chain transfer agent represented by the following general formula (3) is preferable.

In the general formula (3), LLa represents ^a single bond, an alkylene group which may have a substituent, -O-, -S-, -NR ^Za -or a linking group in which these are combined. LL ¹ and LL ² each independently represent — (CR ¹ R ² ) ₁ — or — (CR ¹ R ² ) ₁ —C (═O) O— in which the atom bonded to LL is an oxygen atom. R ¹ and R ² each independently represents a hydrogen atom or an alkyl group, and l represents 1 or 2. R ^Za represents a hydrogen atom or a substituent. However, if the terminal atom of the substituents of substituents and ^{R Za} of LL ^a is a sulfur atom, an SH.

In the general formula (3), LL ¹ and LL ² have the same meanings LL ¹ and LL ² respectively in the general formula (1), and the preferred range is also the same.
LL ^a, when terminal atom of the substituents of the substituents and R ^Za of LL ^a is a sulfur atom, other than a SH has the same meaning as LL in formula (1), and the preferred range is also the same.

  Therefore, the chain transfer agent represented by the general formula (3) is preferably a chain transfer agent represented by the following general formula (3A).

In General Formula (3A), R ^Za represents —SH or — ^* CR ^3b R ^4b R ^5b . ^{* Indicates} a carbon atom bonded to a carbon atom of methylene. R ^3b , R ^4b and R ^5b are each independently an unsubstituted alkyl group, —CH ₂ OH, — ^** CH ₂ (OC═O) _m (CR ^1a R ^2a ) _n SH or — ^** CH ₂ OCH ₂ C [CH ₂ (OC═O) _m (CR ^1a R ^2a ) _n SH] ₃ is represented. ^** indicates a carbon atom bonded to ^* C. However, when R ^Za is not —SH, all of R ^{3b to} R ^5b are not an unsubstituted alkyl group or —CH ₂ OH. R ^1a and R ^2a each independently represents a hydrogen atom, an alkyl group or a hydroxy group. However, when n is 2 or more, R ^1a and R ^2a on the carbon atom bonded to the sulfur atom are a hydrogen atom or an alkyl group. m represents 0 or 1, and n represents an integer of 1 to 12.

^{R 1a,} R ^2a, m and n are ^{R 1a, R 2a,} respectively m and n synonymous in formula (1A), and their preferable ranges are also the same.
R ^Za , R ^3b , R ^4b and R ^5b are the same as those in the general formula except that R ^Z , R ^3a , R ^4a and R ^5a in the general formula (1A) are —SH when the terminal atom is a sulfur atom. It is synonymous with R ^Z , R ^3a , R ^4a and R ^5a in (1A), and the preferred range is also the same.

  Specific examples of the chain transfer agent represented by the general formula (3) are shown below, but the present invention is not limited thereto.

  In the present invention, the content of the chain transfer agent represented by the general formula (3) (C) is 0.01 parts by mass to 100 parts by mass of the total solid content of the composition for forming a functional polymer film. 10 mass parts is preferable, 0.05 mass part-10 mass parts are more preferable, 0.05 mass part-5 mass parts are more preferable, 0.2 mass part-4 mass parts are especially preferable.

<(D) Polymerization initiator>
The composition for forming a functional polymer film in the present invention preferably contains (D) a polymerization initiator represented by the general formula (PI-1) or (PI-2).

In General Formula (PI-1), R ⁷ represents a hydrogen atom, an alkyl group, an alkenyl group, an alkoxy group, or an aryloxy group, and R ⁸ and R ⁹ each independently represent a hydrogen atom, an alkyl group, an alkenyl group, an alkoxy group Represents a group or an aryloxy group, and R ⁸ and R ⁹ may be bonded to each other to form a ring.
In General Formula (PI-2), R ¹⁰ represents an alkyl group, an aryl group, an alkylthio group, or an arylthio group, and R ¹¹ represents an alkyl group, an aryl group, an alkylthio group, an arylthio group, or an acyl group. R ¹² represents an alkyl group or an aryl group.

R ⁷ is preferably a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, or an aryloxy group having 6 to 12 carbon atoms, and an alkyl group or an alkenyl group , An alkoxy group, and an aryloxy group may have a substituent, and examples of the substituent include any substituent selected from the substituent group α.
The aryl of the aryloxy group is preferably phenyl.
R ⁷ is preferably a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms. In the case of an alkoxy group, methoxy and 2-hydroxyethoxy are preferable, and in the case of an alkyl group, a phenyl group. Is preferably a methyl group substituted with —C (═O) —C (R ⁸ ) (R ⁹ ) (OH) substituted for the phenyl group to form a methylene bis-form as a whole molecule. .

R ⁸ and R ⁹ are preferably an alkyl group, an alkenyl group, an alkoxy group or an aryloxy group, an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, carbon An aryloxy group of several 6 to 10 is preferable, an alkyl group is more preferable, and methyl is particularly preferable. The alkyl group, alkenyl group, alkoxy group and aryloxy group may have a substituent, and examples of the substituent include any substituent selected from the substituent group α.
The ring formed by combining R ⁸ and R ⁹ with each other is preferably a 5- or 6-membered ring, more preferably a cyclopentane ring or a cyclohexane ring.

The alkyl group in R ^{10 to} R ¹² is preferably an alkyl group having 1 to 8 carbon atoms, the aryl group in R ^{7 to} R ⁹ is preferably an aryl group having 6 to 16 carbon atoms, and the aryl group has a substituent. May be. Examples of the substituent include any substituent selected from the substituent group α, and an alkyl group and an alkoxy group are preferable.

The alkylthio group or arylthio group in R ¹⁰ and R ¹¹ is preferably an alkylthio group having 1 to 12 carbon atoms and an arylthio group having 6 to 12 carbon atoms.
The acyl group in R ¹¹ is preferably an alkylcarbonyl group or an arylcarbonyl group, more preferably an alkylcarbonyl group having 2 to 12 carbon atoms, or an arylcarbonyl group having 7 to 17 carbon atoms. R ¹¹ is preferably an arylcarbonyl group, particularly preferably a phenylcarbonyl group which may have a substituent. The acyl group may have a substituent, and examples of the substituent include any substituent selected from the substituent group α.

  The polymerization initiator represented by the general formula (PI-1) is preferable to the polymerization initiator represented by the general formula (PI-2).

  Specific examples of the polymerization initiator represented by the general formula (PI-1) or (PI-2) are shown below, but the present invention is not limited thereto.

  The polymerization initiator represented by the general formula (PI-1) or (PI-2) can be obtained from BASF Japan Ltd.

  In this invention, content of the polymerization initiator represented by said (D) general formula (PI-1) or (PI-2) with respect to 100 mass parts of total solid of the composition for polymeric functional film formation. Is preferably 0.1 to 20 parts by mass, more preferably 0.1 to 10 parts by mass, and particularly preferably 0.5 to 5 parts by mass.

  The composition for forming a functional polymer film in the present invention preferably further contains (E) a polymerization initiator represented by the following general formula (AI).

In General Formula (AI), R ^{13 to} R ¹⁶ each independently represents an alkyl group, and Y represents ═O or ═N—Ri. Re to Ri each independently represent a hydrogen atom or an alkyl group. Re and Rf, Rg and Rh, Re and Ri, and Rh and Ri may be bonded to each other to form a ring.

The alkyl group for R ^{13 to} R ¹⁶ preferably has 1 to 8 carbon atoms, more preferably 1 to 4 carbon atoms, and particularly preferably methyl.
Re to Ri are preferably a hydrogen atom or an alkyl group having 1 to 8 carbon atoms.
The ring formed by combining Re and Rf, Rg and Rh, Re and Ri, and Rh and Ri is preferably a 5- or 6-membered ring.
The ring formed by bonding Re and Ri and Rh and Ri is preferably an imidazoline ring, and the ring formed by bonding Re and Rf and Rg and Rh is a pyrrolidine ring or piperidine ring. Piperazine ring, morpholine ring, and thiomorpholine ring are preferable.

  Y is preferably ═N—Ri.

  Specific examples of the polymerization initiator represented by the general formula (AI) are shown below, but the present invention is not limited thereto.

  The polymerization initiator represented by the general formula (AI) can be obtained from Wako Pure Chemical Industries, Ltd., the exemplary compound (AI-1) is VA-061, and the exemplary compound (AI-2) is VA-044. The exemplified compound (AI-3) is VA-046B, the exemplified compound (AI-4) is V-50, the exemplified compound (AI-5) is VA-067, the exemplified compound (AI-6) is VA-057, Compound (AI-7) is commercially available as VA086 (both trade names).

  In the present invention, the content of the polymerization initiator represented by (E) the general formula (AI) is 0.1 to 20 parts by mass with respect to 100 parts by mass of the total solid content of the polymer functional film forming composition. Is preferable, 0.1-10 mass parts is more preferable, and 0.5-5 mass parts is especially preferable.

(F) Solvent The composition for forming a functional polymer film in the present invention may contain (F) a solvent.
In this invention, 5-60 mass parts is preferable with respect to 100 mass parts of all compositions, and, as for content of the (F) solvent in the said composition for polymeric functional film formation, 10-40 mass parts is more preferable. .
By setting the content of the solvent within this range, a uniform film can be produced without increasing the viscosity of the polymer functional film-forming composition. In addition, the occurrence of pinholes (fine defect holes) can be suppressed.

(F) A solvent having a solubility in water of 5% by mass or more is preferably used, and a solvent that is freely mixed in water is preferable. For this reason, a solvent selected from water and a water-soluble solvent is preferred. As the water-soluble solvent, alcohol solvents, ether solvents that are aprotic polar solvents, amide solvents, ketone solvents, sulfoxide solvents, sulfone solvents, nitrile solvents, and organic phosphorus solvents are particularly preferable. . Water and alcohol solvents are preferred. Examples of alcohol solvents include methanol, ethanol, isopropanol, n-butanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol and the like. Among alcohol solvents, ethanol, isopropanol, n-butanol, and ethylene glycol are more preferable, and isopropanol is particularly preferable. These can be used alone or in combination of two or more. Water alone or a combination of water and a water-soluble solvent is preferred, and water alone or a combination of water and at least one alcohol solvent is more preferred. In the combined use of water and a water-soluble solvent, 0.1 to 10% of isopropanol is preferable with respect to 100% by mass of water, more preferably 0.5 to 5%, and still more preferably 1.0 to 2.0%.
Examples of aprotic polar solvents include dimethyl sulfoxide, dimethyl imidazolidinone, sulfolane, N-methylpyrrolidone, dimethylformamide, acetonitrile, acetone, dioxane, tetramethylurea, hexamethylphosphorotriamide, pyridine, propionitrile, Preferred examples of the solvent include butanone, cyclohexanone, tetrahydrofuran, tetrahydropyran, ethylene glycol diacetate, and γ-butyrolactone. Among them, dimethylsulfoxide, N-methylpyrrolidone, dimethylformamide, dimethylimidazolidinone, sulfolane, acetone or acetonitrile, and tetrahydrofuran are preferable. preferable. These can be used alone or in combination of two or more.

(G) Polymerization inhibitor In order to provide stability to the coating liquid at the time of forming a film | membrane in the composition for polymeric functional film formation in this invention, it is also preferable that a polymerization inhibitor is included.
As a polymerization inhibitor, a well-known polymerization inhibitor can be used, and a phenol compound, a hydroquinone compound, an amine compound, a mercapto compound, etc. are mentioned.
Examples of the phenol compound include hindered phenols (phenols having a t-butyl group in the ortho position, typically 2,6-di-t-butyl-4-methylphenol) and bisphenols. Specific examples of the hydroquinone compound include monomethyl ether hydroquinone. Specific examples of the amine compound include N-nitroso-N-phenylhydroxylamine and N, N-diethylhydroxylamine. Specific examples of the aliphatic heterocyclic compound include 4-hydroxy-2,2,6,6-tetramethylpiperidine 1-oxyl.
These polymerization inhibitors may be used singly or in combination of two or more.
The content of the polymerization inhibitor is preferably 0.01 to 5 parts by mass, more preferably 0.01 to 1 part by mass with respect to 100 parts by mass of the total solid content in the polymer functional film-forming composition. 0.01-0.5 mass part is further more preferable.

[Other ingredients]
In addition to the components (A) to (G), the composition for forming a functional polymer film in the present invention includes a plasticizer, a reinforcing agent for imparting flexibility to the film, a surfactant, and a polymer dispersant. And an anti-crater agent and the like.

[Surfactant]
In order to adjust film physical properties, various polymer compounds can be added to the composition for forming a functional polymer film in the present invention. High molecular compounds include acrylic polymers, polyurethane resins, polyamide resins, polyester resins, epoxy resins, phenol resins, polycarbonate resins, polyvinyl butyral resins, polyvinyl formal resins, shellac, vinyl resins, acrylic resins, rubber resins. Waxes and other natural resins can be used. Two or more of these may be used in combination.
Further, nonionic surfactants, cationic surfactants, organic fluoro compounds, and the like can be added to adjust liquid properties.

  Specific examples of the surfactant include alkylbenzene sulfonate, alkylnaphthalene sulfonate, higher fatty acid salt, sulfonate of higher fatty acid ester, sulfate ester of higher alcohol ether, sulfonate of higher alcohol ether, higher alkyl Anionic surfactants such as alkyl carboxylates of sulfonamides, alkyl phosphates, polyoxyethylene alkyl ethers, polyoxyethylene alkyl phenyl ethers, polyoxyethylene fatty acid esters, sorbitan fatty acid esters, ethylene oxide adducts of acetylene glycol, Nonionic surfactants such as ethylene oxide adducts of glycerin and polyoxyethylene sorbitan fatty acid esters, and other amphoteric interfaces such as alkyl betaines and amide betaines Sexual agents, silicone surface active agent, including a fluorine-based surfactant, can be appropriately selected from surfactants and derivatives thereof are known.

[Polymer dispersant]
The composition for forming a functional polymer film in the present invention may contain a polymer dispersant.
Specific examples of the polymer dispersant include polyvinyl pyrrolidone, polyvinyl alcohol, polyvinyl methyl ether, polyethylene oxide, polyethylene glycol, polypropylene glycol, and polyacrylamide. Among them, polyvinyl pyrrolidone is also preferably used.

[Anti-crater]
Anti-crater agent is also called surface conditioner, leveling agent or slip agent, and prevents unevenness on the film surface. For example, organic modified polysiloxane (mixture of polyether siloxane and polyether), polyether modified poly Examples thereof include compounds having a structure of siloxane copolymer or silicon-modified copolymer.
Examples of commercially available products include, for example, Tego Glide 432, 110, 110, 130, 406, 410, 411, 415, 420, 435, 440, 450, and the like manufactured by Evonik Industries. 482, A115, B1484, and ZG400 (all are trade names).
The crater inhibitor is preferably 0 to 10 parts by weight, more preferably 0 to 5 parts by weight, and more preferably 1 to 2 parts by weight with respect to 100 parts by weight of the total solid content in the polymer functional film-forming composition. preferable.

  In addition to the above, the composition for forming a functional polymer film in the present invention may contain, for example, a viscosity improver and a preservative, if necessary.

<Support>
Many techniques can be used to provide the membrane of the present invention having particularly good mechanical strength. For example, a support can be used as the membrane reinforcing material, and a porous support can be preferably used. This porous support can constitute a part of the membrane by applying and / or impregnating the polymer functional film-forming composition, followed by polymerization and curing reaction.
Examples of the porous support as the reinforcing material include a synthetic woven fabric or synthetic nonwoven fabric, a sponge film, a film having fine through holes, and the like. The material forming the porous support of the present invention is, for example, polyolefin (polyethylene, polypropylene, etc.), polyacrylonitrile, polyvinyl chloride, polyester, polyamide and copolymers thereof, or, for example, polysulfone, polyethersulfone, Polyphenylene sulfone, polyphenylene sulfide, polyimide, polyetherimide, polyamide, polyamideimide, polyacrylonitrile, polycarbonate, polyacrylate, cellulose acetate, polypropylene, poly (4-methyl-1-pentene), polyvinylidene fluoride, polytetra A porous membrane based on fluoroethylene, polyhexafluoropropylene, polychlorotrifluoroethylene and their copolymers Door can be. Of these, polyolefins are preferred in the present invention.
Commercially available porous supports and reinforcement materials are commercially available from, for example, Japan Vilene, Freudenberg Filtration Technologies (Novatex material) and Separ AG.
In the case where the porous support and the reinforcing material are subjected to a polymerization and curing reaction by energy beam irradiation, the wavelength region of the energy beam is not obstructed, that is, it is required to pass the irradiation of the wavelength used for polymerization and curing. In the case of thermal polymerization curing, it is not necessary to consider this point. Moreover, it is preferable that the porous reinforcing material can be penetrated by the polymer functional film-forming composition.

  The porous support preferably has hydrophilicity. In order to impart hydrophilicity to the support, general methods such as corona treatment, ozone treatment, sulfuric acid treatment, and silane coupling agent treatment can be used.

[Method for producing polymer functional film]
Next, the manufacturing method of the polymeric functional film of this invention is demonstrated.
The method for producing a polymer functional film of the present invention comprises (A) a styrene monomer represented by the general formula (HSM), (B) a crosslinking agent represented by the general formula (CL), and (C) the general formula ( The polymer functional film-forming composition containing the chain transfer agent represented by 3) is polymerized and cured to form a film.

The polymer functional film-forming composition further comprises (D) a polymerization initiator represented by the general formula (PI-1) or (PI-2), (E) a polymerization represented by the general formula (AI). It is preferable to contain an initiator.
The composition for forming a functional polymer film further includes (F) a solvent, and the content of the solvent is 5 to 60 masses with respect to 100 parts by mass of the total composition for forming a functional polymer film. Part.
The solvent (F) is preferably water or a water-soluble solvent, and is preferably subjected to a polymerization and curing reaction after applying and / or impregnating the polymer functional film-forming composition onto a support. Further, the polymerization and curing reaction is preferably a polymerization and curing reaction in which the polymer functional film-forming composition is polymerized by irradiation with energy rays or irradiation with energy rays and heating. Furthermore, heating is preferably performed on a film formed by energy beam irradiation.

Hereinafter, an example of the manufacturing method of the polymeric functional film of this invention is demonstrated in detail.
The polymer functional membrane of the present invention can be prepared in batch (batch mode) using a fixed support, but the membrane is prepared in continuous mode using a moving support (continuous mode). ). The support may be in the form of a roll that is continuously rewound. In the case of a continuous method, a support is placed on a belt that is continuously moved, and a process of forming a film by continuously applying a coating liquid that is a polymer functional film forming composition and polymerizing and curing is continuously performed. Can be done. However, only one of the coating process and the film forming process may be performed continuously.
Separately from the support, a temporary support (after the completion of the polymerization and curing reaction, after the polymerization and curing reaction is completed) until the polymerization and curing reaction is completed by coating and / or impregnating the porous functional support with the composition for forming a functional polymer film of the present invention. The film may be peeled off from the support).
Such a temporary support does not need to consider material permeation, and includes any metal plate such as a polyethylene terephthalate (PET) film or an aluminum plate that can be fixed for film formation. It does n’t matter.
In addition, the composition for forming a functional polymer film in the present invention can be applied and / or impregnated on a porous support, and polymerized and cured without using a support other than the porous support.

  The composition for forming a polymer functional film in the present invention can be prepared by various methods such as curtain coating, extrusion coating, air knife coating, slide coating, nip roll coating, forward roll coating, reverse roll coating, dip coating, kiss coating, and rod. The porous support can be applied and / or impregnated by bar coating or spray coating. Multiple layers can be applied simultaneously or sequentially. For simultaneous multi-layer application, curtain coating, slide coating, slot die coating and extrusion coating are preferred.

  For the production of the functional polymer film in a continuous manner, the composition for forming the functional polymer film is continuously applied to the moving support, more preferably, the composition application part for forming the functional polymer film. An irradiation source for polymerizing and curing the polymer functional film-forming composition, a film winding part for collecting the formed film, and a support as the polymer functional film-forming composition application part And a means for moving the irradiation source to the film winding unit.

In this production example, (i) the functional polymer film-forming composition according to the present invention is applied to and / or impregnated into a porous support, and (ii) the polymeric functional film-forming composition is irradiated with energy rays. In this case, in addition to this, the polymer functional film of the present invention is prepared through a process of further polymerizing and curing reaction by heating, and (iii) removing the film from the support if desired.
In (ii), heating may be performed before energy beam irradiation, may be performed simultaneously with energy beam irradiation, or may be performed on a film formed by energy beam irradiation. Furthermore, the above (ii) may be a polymerization curing reaction by heating, but a polymerization curing reaction by energy ray irradiation is preferred.
The time required for the polymerization curing reaction is not particularly limited, but is preferably less than 20 minutes, more preferably less than 15 minutes, and particularly preferably less than 8 minutes. The lower limit is not particularly limited, but 30 seconds or more is practical.

[Polymerization by heating]
(1) When heating before irradiation with energy rays The heating temperature is preferably 40 to 120 ° C, more preferably 50 to 100 ° C, and particularly preferably 60 to 90 ° C.
The heating time is preferably 10 seconds to 6 hours, more preferably 10 seconds to 3 hours, and particularly preferably 10 seconds to 1 hour.
(2) When heating simultaneously with the energy irradiation line The heating temperature is preferably 40 to 120 ° C, more preferably 50 to 100 ° C, and particularly preferably 60 to 90 ° C. The heating time is not particularly limited, and is not less than the total time of the heating time until the porous support containing the polymer functional film-forming composition reaches the superheating temperature and the time when the subsequent energy rays are irradiated. I just need it.
(3) When heating after irradiation with energy rays The heating temperature is preferably 40 to 120 ° C, more preferably 50 to 100 ° C, and particularly preferably 60 to 90 ° C.
The heating time is preferably 1 minute to 12 hours, more preferably 1 minute to 8 hours, and particularly preferably 1 minute to 6 hours.
(4) When polymerizing and curing by heating without energy irradiation The heating temperature is preferably 40 to 95 ° C, more preferably 50 to 85 ° C, and particularly preferably 60 to 80 ° C.
The heating temperature is preferably 1 minute to 48 hours, more preferably 1 minute to 12 hours, and particularly preferably 1 minute to 4 hours.

[Energy beam irradiation]
In the manufacturing unit, the polymer functional film-forming composition application unit is provided at a position upstream of the irradiation source, and the irradiation source is positioned upstream of the collection unit.
In order to have sufficient fluidity when applied with a high-speed coater, the viscosity at 35 ° C. of the composition for forming a functional polymer film in the present invention is preferably less than 4000 mPa · s, preferably 1 to 1000 mPa · s. More preferably, 1 to 500 mPa.s. s is most preferred. In the case of slide bead coating, the viscosity at 35 ° C. is preferably 1 to 100 mPa · s.

  In the high-speed coating machine, the coating liquid that is the composition for forming a functional polymer film in the present invention can be applied to a support that moves at a speed exceeding 15 m / min, for example, a speed exceeding 20 m / min, It can also be applied at a speed exceeding 400 m / min.

  In particular, when a support is used to increase the mechanical strength, before applying the polymer functional film-forming composition of the present invention to the surface of the support, the support is treated with, for example, the wettability of the support. In order to improve adhesion, it may be subjected to corona discharge treatment, glow discharge treatment, flame treatment, ultraviolet irradiation treatment, and the like.

  During the polymerization curing reaction, (A) a styrene monomer represented by the general formula (HSM) and (B) a crosslinking agent represented by the general formula (CL) are polymerized to form a polymer. The polymerization curing reaction can be carried out by irradiation with energy rays and heating under the condition that the polymerization curing occurs quickly enough to form a film within 5 minutes.

In the polymerization curing of the polymer functional film-forming composition in the present invention, the polymer functional film-forming composition is applied or impregnated on a support, preferably within 60 seconds, more preferably within 15 seconds, In particular, it starts within 5 seconds, most preferably within 3 seconds.
Polymerization curing energy beam irradiation is preferably less than 20 minutes, more preferably less than 15 minutes, particularly preferably less than 10 minutes, and most preferably less than 8 minutes. In the continuous method, irradiation is continuously performed, and the polymerization curing reaction time is determined in consideration of the speed at which the polymer functional film-forming composition moves through the irradiation beam.

  When high intensity ultraviolet rays (UV light) are used in the polymerization curing reaction, a considerable amount of heat is generated, and therefore the lamp of the light source and / or the support / film is cooled with cooling air or the like to prevent overheating. Is preferred. When a significant dose of infrared light (IR light) is irradiated with the UV beam, the UV light is irradiated using an IR reflective quartz plate as a filter.

  It is preferable to use ultraviolet rays for the polymerization curing reaction. The suitable wavelength is preferably matched with the absorption wavelength and wavelength of any photoinitiator included in the composition for forming a functional polymer film. For example, UV-A (400 to 320 nm), UV-B ( 320-280 nm) and UV-C (280-200 nm).

  Suitable UV sources include mercury arc lamps, carbon arc lamps, low pressure mercury lamps, medium pressure mercury lamps, high pressure mercury lamps, swirling plasma arc lamps, metal halide lamps, xenon lamps, tungsten lamps, halogen lamps, lasers and UV light emitting diodes. is there. Medium pressure or high pressure mercury vapor type UV lamps are particularly preferred. In addition, additives such as metal halides may be present to modify the emission spectrum of the lamp. Particularly suitable are lamps having an emission maximum between 200 and 450 nm.

The energy output of the irradiation source is preferably 1 to 100 mW / cm ² , preferably ² to 50 mW / cm ² , but may be higher or lower as long as a desired exposure dose can be realized. Absent. The polymerization hardening of the film is adjusted according to the exposure strength. The exposure dose is preferably measured by the High Energy UV Radiometer (UV Power Pack ^™ manufactured by EIT-Instrument Markets) in the UV-A range indicated by the apparatus, and is preferably at least 40 mJ / cm ² or more, more preferably 500 or more. 50,000 mJ / cm ² , most preferably 3000 to 30,000 mJ / cm ² . The exposure time can be freely selected, but is preferably short and particularly preferably less than 1 minute.

  When the application speed is high, a plurality of light sources may be used to obtain a necessary exposure dose. In this case, the plurality of light sources may have the same or different exposure intensity.

Here, when R ³ is a halogen atom in the general formula (HSM), the composition for polymer functional film formation is subjected to a polymerization and curing reaction, and then represented by the general formula (AA) which is a quaternary ammonium agent. The tertiary amine compound is reacted.

<< Use of polymer functional film >>
The polymer functional membrane of the present invention can be used for electrodesalting as an anion exchange membrane, continuous electrodesalting, electrodialysis, reverse electrodialysis, gas separation, and the like. It can also be used in medical applications, and recently it can also be used in solid polymer electrolyte fuel cells.

  EXAMPLES Hereinafter, although this invention is demonstrated in detail based on an Example, this invention is not limited to these Examples. Unless otherwise specified, “part” and “%” are based on mass.

(Synthesis of pyridinium styrenesulfonate, PySS)

  100 g of sodium styrenesulfonate, 52 g of pyridine hydrochloride, 52 g of N-methyl-2-pyrrolidone and 0.30 g of 2,6-di-t-butyl-4-methylphenol (all manufactured by Wako Pure Chemical Industries, Ltd.) were mixed. And stirred at 60 ° C. for 6 hours. Stir at room temperature for a further 18 hours and remove the resulting NaCl by filtration. Reprecipitation was performed using a poor solvent to obtain 60 g of pyridinium styrenesulfonate (PySS).

Example 1
(Creation of anion exchange membrane)
The coating solution of the composition for forming a polymer functional film having the composition (unit: g) shown in Table 1 below was manually applied to an aluminum plate at a speed of about 5 m / min using a 150 μm wire winding rod. Subsequently, a non-woven fabric (FO-2223-10 manufactured by Freudenberg, thickness: 100 μm) was impregnated with the coating solution. Excess coating solution was removed using a rod around which no wire was wound. The temperature of the coating solution at the time of coating was about 25 ° C. (room temperature). By using a UV exposure machine (Fusion UV Systems, Model Light Hammer 10, D-valve, conveyor speed 9.5 m / min, 100% strength), the coating liquid-impregnated support is polymerized and cured to cause anion. An exchange membrane was prepared. The exposure amount was 1,000 mJ / cm ² in the UV-A region. The polymerization curing time was 60 to 2000 seconds. The exposure time was 60 to 2000 seconds. The resulting membrane was removed from the aluminum plate and stored in 0.1 M NaCl solution for at least 12 hours.

Example 2, Comparative Examples 1 and 2
In the production of the anion exchange membrane of Example 1, the anion exchange membranes of Example 2 and Comparative Examples 1 and 2 were produced in the same manner as in Example 1 except that the composition was changed to the composition described in Table 1 below. .

Example 3 and Comparative Example 3
In the preparation of the anion exchange membrane of Example 1, the composition was changed to the composition shown in Table 1 below, and after the polymerization curing reaction, the membrane was immersed in a 30% aqueous solution of trimethylamine for 24 hours in the same manner as in Example 1. Anion exchange membranes of Example 3 and Comparative Example 3 were prepared.

(Performance evaluation of anion exchange membrane)
The following items were evaluated about the anion exchange membrane created in Examples 1-3 and Comparative Examples 1-3.

[Measurement of ion exchange capacity]
It was measured by the method described in Masayuki Nakagaki / ed., Membrane Experimental Method, page 194, Kitami Shobo (1984) (ISBN-978-4-906126-09-5).

[Electrical resistance of membrane (Ω · cm ² )]
Wipe both sides of the membrane immersed in 0.5M NaCl aqueous solution for about 2 hours with dry filter paper, and sandwich it in a two-chamber cell (effective membrane area 1 cm ² , using Ag / AgCl reference electrode (made by Metrohm) as the electrode) Both chambers are filled with 100 mL of NaCl solution of the same concentration, placed in a constant temperature water bath at 25 ° C. and left to reach equilibrium, and after the liquid temperature in the cell reaches 25 ° C. correctly, an AC bridge (frequency 1, the electric resistance _{r 1} was measured by 000Hz). measurement NaCl concentration was 0.5M, were measured in order from a low concentration solution. then remove the film, the electrical resistance _{r 2} between two electrodes only as 0.5M NaCl solution The electric resistance r of the film was determined as r ₁ -r ₂ .

  In Table 1, “electrical resistance of the film” is abbreviated as “film resistance”.

[Water permeability (mL / m ² / Pa / hr)]
The water permeability of the membrane was measured by an apparatus having a flow path 10 shown in FIG. In FIG. 1, reference numeral 1 represents a membrane, and reference numerals 3 and 4 represent flow paths for a feed solution (pure water) and a draw solution (4M NaCl), respectively. Moreover, the arrow of a code | symbol 2 shows the flow of the water isolate | separated from the feed solution.
400 mL of the feed solution and 400 mL of the draw solution were brought into contact with each other through the membrane (membrane contact area 18 cm ² ), and each solution was flowed at a flow rate of 0.11 cm / sec in the direction of the arrow 5 with a peristaltic pump. The rate at which the water in the feed solution penetrates the draw solution through the membrane was analyzed by measuring the mass of the feed solution and the draw solution in real time, and the water permeability was determined.

The obtained results are summarized in Table 1 below.
Here, in Table 1, the materials used are indicated by the following abbreviations.

[Materials used and their abbreviations]
(Styrene monomer represented by the general formula (HSM))
Styrene monomer having an ionic group VBTMAC: exemplified compound SM-1 of (A), vinylbenzyltrimethylammonium chloride (manufactured by Sigma-Aldrich)
PySS: pyridinium styrenesulfonate intermediate of styrene monomer having ionic group CMS: exemplified compound HSM-1 of (A), chloromethylstyrene (manufactured by Tokyo Chemical Industry Co., Ltd.)
-Styrene monomer without ionic groups St: Styrene (Wako Pure Chemical Industries, Ltd.)
St-Ox: Styrene oxide (manufactured by Tokyo Chemical Industry Co., Ltd.)

(Crosslinking agent represented by general formula (CL))
DVB: divinylbenzene (manufactured by Tokyo Chemical Industry Co., Ltd.)

(Chain transfer agent)
Chain transfer agent (C) Bifunctional thiol: Dithioerythritol (manufactured by Tokyo Chemical Industry Co., Ltd.)
Comparative chain transfer agent CTA-1: 2,4-diphenyl-4-methyl-1-pentene (manufactured by Tokyo Chemical Industry Co., Ltd.)

(D) Polymerization initiator Irgacure 2959 (trade name, manufactured by BASF Japan Ltd.), exemplary compound PI-1-2
Irgacure 184 (trade name, manufactured by BASF Japan Ltd.), exemplary compound PI-1-5

(F) Solvent NMP: N-methylpyrrolidone (Wako Pure Chemical Industries, Ltd.)

(G) Polymerization inhibitor 4OH TEMPO: 4-hydroxy-2,2,6,6-tetramethylpiperidin-1-oxyl (manufactured by Tokyo Chemical Industry Co., Ltd.)
(Plasticizer)
DOP: Dioctyl phthalate (Tokyo Chemical Industry Co., Ltd.)
(Reinforcing agent for imparting flexibility to the membrane)
HNBR: Nitrile butadiene rubber (trade name: Zetpol 2010, manufactured by Nippon Zeon)
(Immersion liquid)
TMA 30% aqueous solution: trimethylamine 30% aqueous solution

The polymer functional membranes of Examples 1 to 3 have a structure represented by the general formula (1) and a structure represented by the general formula (2) defined in the present invention. On the other hand, although the polymeric functional film of Comparative Examples 1-3 has a structure represented by General formula (2), it does not have a structure represented by General formula (1).
As is clear from Table 1, from the comparison of Example 1 and Comparative Example 1, Example 2 and Comparative Example 2, and Example 3 and Comparative Example 3, in Example, the membrane resistance and water permeability were compared with those of Comparative Example. It turns out that is low in a well-balanced manner.
From this result, by using the polyfunctional mercapto compound represented by the general formula (3), the values of water permeability and membrane resistance can be reduced in a well-balanced manner.
Further, from the comparison between Example 1 and Comparative Example 1, Example 2 and Comparative Example 2, and Example 3 and Comparative Example 3, in Example, the time required for polymerization and curing is significantly shortened with respect to Comparative Example. You can see that

DESCRIPTION OF SYMBOLS 1 Membrane 2 The arrow which shows that the water in a feed solution osmose | permeates a draw solution through a film | membrane 3 The flow path of a feed solution 4 The flow path of a draw solution 10 The flow direction of a liquid 10 The flow path of a water permeability measuring apparatus

Claims (12)

It has a structure represented by the structure and the following general formula represented by the following general formula (1) (2), a styrene-based polymer functional ion exchange capacity of 2.0meq / g~7.0meq / g film.

In the general formula (1), LL represents a single bond, an alkylene group which may have a substituent, —O—, —S—, —NR ^Z — or a linking group in which these are combined. LL ¹ and LL ² each independently represent — (CR ¹ R ² ) ₁ — or — (CR ¹ R ² ) ₁ —C (═O) O— in which the atom bonded to LL is an oxygen atom. R ¹ and R ² each independently represents a hydrogen atom or an alkyl group, and l represents 1 or 2. R ^Z represents a hydrogen atom or a substituent. However, if the terminal atom of the substituents of substituents and R ^Z in the LL is a sulfur atom, a sulfur atom having a bond incorporated in the polymer chain.

In the general formula (2), Ar represents an aryl group. L ¹ represents a single bond or a divalent linking group. n1 represents an integer of 0 to 10. 2. The styrenic polymer according to claim 1, wherein the content of the structural part represented by the general formula (1) is 0.01 parts by mass to 10 parts by mass with respect to 100 parts by mass of the polymer functional film. Functional membrane. (A) a styrene monomer represented by the following general formula (HSM), (B) a crosslinking agent represented by the following general formula (CL), and (C) a chain transfer agent represented by the following general formula (3). The styrenic polymer functional film according to claim 1 or 2, which is obtained by subjecting a composition to be polymerized and cured.

In the general formula (HSM), R ³ represents a halogen atom or —N ⁺ (R ⁴ ) (R ⁵ ) (R ⁶ ) (X ₁ ⁻ ). n2 represents an integer of 1 to 10. Here, R ^{4 to} R ⁶ each independently represents a linear or branched alkyl group or aryl group. R ⁴ and R ⁵ , or R ⁴ , R ⁵ and R ⁶ may be bonded to each other to form an aliphatic heterocycle. X ₁ ⁻ represents an organic or inorganic anion.

In general formula (CL), Ar represents an aryl group. L ¹ represents a single bond or a divalent linking group. n1 represents an integer of 0 to 10.

In the general formula (3), LLa represents ^a single bond, an alkylene group which may have a substituent, -O-, -S-, -NR ^Za -or a linking group in which these are combined. LL ¹ and LL ² each independently represent — (CR ¹ R ² ) ₁ — or — (CR ¹ R ² ) ₁ —C (═O) O— in which the atom bonded to LL ^a is an oxygen atom. R ¹ and R ² each independently represents a hydrogen atom or an alkyl group, and l represents 1 or 2. R ^Za represents a hydrogen atom or a substituent. However, if the terminal atom of the substituents of substituents and ^{R Za} of LL ^a is a sulfur atom, an SH. The styrenic polymer functional film according to claim 3, wherein the composition further comprises (D) a polymerization initiator represented by the following general formula (PI-1) or (PI-2).

In General Formula (PI-1), R ⁷ represents a hydrogen atom, an alkyl group, an alkenyl group, an alkoxy group, or an aryloxy group, and R ⁸ and R ⁹ each independently represent a hydrogen atom, an alkyl group, an alkenyl group, an alkoxy group Represents a group or an aryloxy group, and R ⁸ and R ⁹ may be bonded to each other to form a ring.
In General Formula (PI-2), R ¹⁰ represents an alkyl group, an aryl group, an alkylthio group, or an arylthio group, and R ¹¹ represents an alkyl group, an aryl group, an alkylthio group, an arylthio group, or an acyl group. R ¹² represents an alkyl group or an aryl group. The content of the styrenic monomer represented by the general formula (A) (ASM) is 1 part by mass to 85 parts by mass with respect to 100 parts by mass of the total solid content of the composition. Styrenic polymer functional film. The total solid content 100 parts by weight of the composition, the (B) any one of the general formula according to claim 3 to 5 content of the crosslinking agent represented by (CL) is 10 parts by weight to 100 parts by weight The styrenic polymer functional film described in the item. The content of the chain transfer agent represented by the general formula (3) (C) is 0.01 parts by mass to 10 parts by mass with respect to 100 parts by mass of the total solid content of the composition. The styrenic polymer functional film according to any one of the above. The styrenic polymer functional film according to any one of claims 3 to 7, wherein the composition contains (F) a solvent. The styrenic polymer functional film according to claim 8, wherein the solvent (F) is water or a water-soluble solvent. The styrenic polymer functional film according to any one of claims 1 to 9, comprising a synthetic woven fabric or synthetic nonwoven fabric, a sponge-like film, or a film-like support having fine through-holes. The styrenic polymer functional film according to any one of claims 3 to 10, wherein the polymerization curing reaction is performed by heating and / or irradiation with energy rays. A method for producing a styrenic polymer functional membrane, wherein the polymer functional membrane has an ion exchange capacity of 2.0 meq / g to 7.0 meq / g, and is represented by (A) the following general formula (HSM): A polymer that undergoes a polymerization and curing reaction with a composition containing a styrene monomer, (B) a cross-linking agent represented by the following general formula (CL), and (C) a chain transfer agent represented by the following general formula (3) A method for producing a functional film.

In the general formula (HSM), R ³ represents a halogen atom or —N ⁺ (R ⁴ ) (R ⁵ ) (R ⁶ ) (X ₃ ⁻ ). n2 represents an integer of 1 to 10. Here, R ^{4 to} R ⁶ each independently represents a linear or branched alkyl group or aryl group. R ⁴ and R ⁵ , or R ⁴ , R ⁵ and R ⁶ may be bonded to each other to form an aliphatic heterocycle. X ₃ ⁻ represents an organic or inorganic anion.

In general formula (CL), Ar represents an aryl group. L ¹ represents a single bond or a divalent linking group. n1 represents an integer of 0 to 10.

In the general formula (3), LLa represents ^a single bond, an alkylene group which may have a substituent, -O-, -S-, -NR ^Za -or a linking group in which these are combined. LL ¹ and LL ² each independently represent — (CR ¹ R ² ) ₁ — or — (CR ¹ R ² ) ₁ —C (═O) O— in which the atom bonded to LL ^a is an oxygen atom. R ¹ and R ² each independently represents a hydrogen atom or an alkyl group, and l represents 1 or 2. R ^Za represents a hydrogen atom or a substituent. However, if the terminal atom of the substituents of substituents and ^{R Za} of LL ^a is a sulfur atom, an SH.

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