JP6093212B2 - Manufacturing method of steel material excellent in cold workability or machinability - Google Patents

Manufacturing method of steel material excellent in cold workability or machinability Download PDF

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JP6093212B2
JP6093212B2 JP2013054093A JP2013054093A JP6093212B2 JP 6093212 B2 JP6093212 B2 JP 6093212B2 JP 2013054093 A JP2013054093 A JP 2013054093A JP 2013054093 A JP2013054093 A JP 2013054093A JP 6093212 B2 JP6093212 B2 JP 6093212B2
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亮廣 松ヶ迫
亮廣 松ヶ迫
土田 武広
武広 土田
山下 浩司
浩司 山下
徹 今村
徹 今村
慎治 福岡
慎治 福岡
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Kobe Steel Ltd
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Description

本発明は、自動車用部品や軸受け、建設機械用部品等の各種部品の製造に用いられる冷間加工性又は被削性に優れた鋼材を製造する方法に関するものである。   The present invention relates to a method of manufacturing a steel material having excellent cold workability or machinability used for manufacturing various parts such as automobile parts, bearings, and construction machine parts.

自動車用部品や軸受け、建設機械用部品等の各種部品には高炭素鋼が使用されており、通常、熱間圧延材を冷間加工、切削加工などによって所定の形状に成形した後、焼入れ焼戻し処理を行って最終的な強度調整が行われて製造される。熱間圧延材の冷間加工性や被削性は、高炭素鋼中に析出している炭化物の形状に影響を受け、棒状の炭化物が存在していると、それらが割れの起点となり、冷間加工性や被削性が悪くなる。そこで熱間圧延材を冷間加工したり切削するにあたっては、熱間圧延材を焼鈍して炭化物を球状化する処理(球状化焼鈍)が施される。   High carbon steel is used for various parts such as automobile parts, bearings, and construction machine parts. Usually, hot rolled material is formed into a predetermined shape by cold working, cutting, etc., and then quenched and tempered. The final strength adjustment is performed by performing the process, and the manufacturing is performed. The cold workability and machinability of hot-rolled materials are affected by the shape of carbides precipitated in high-carbon steel. Interworkability and machinability deteriorate. Therefore, when cold-working or cutting the hot-rolled material, a process of spheroidizing the carbide by annealing the hot-rolled material (spheroidizing annealing) is performed.

一般に球状化焼鈍では、(1)鋼材をAc1点(約730℃)以上のやや高い温度(例えば760〜780℃)に1〜2時間加熱したのち、ゆっくり冷却する方法、(2)Ac1点の上下20〜30℃の間で加熱と冷却を繰り返す方法、(3)冷間加工後に温度680〜700℃に加熱するか、または焼入れ後に温度680〜700℃で焼戻しする方法、(4)変態点直上にあたる温度760〜780℃から温度700℃まで冷却し、この温度で約3時間程度保持してから空冷する方法などが採用されている。 In general, in spheroidizing annealing, (1) a method of slowly cooling a steel material to a slightly higher temperature (for example, 760 to 780 ° C.) of A c1 point (about 730 ° C.) for 1 to 2 hours, and (2) A c1 A method of repeating heating and cooling between 20-30 ° C. above and below the point, (3) a method of heating to a temperature of 680-700 ° C. after cold working, or a method of tempering at a temperature of 680-700 ° C. after quenching, (4) A method of cooling from a temperature of 760 to 780 ° C. immediately above the transformation point to a temperature of 700 ° C. and holding at this temperature for about 3 hours and then air cooling is adopted.

ところで軸受鋼などに使用される高炭素鋼としては、SUJ2鋼が代表的であり、このSUJ2鋼も球状化焼鈍して用いられている。SUJ2鋼はC量が0.95〜1.10%と高く、またCr含有量も1.30〜1.60%と高い。   By the way, as a high carbon steel used for bearing steel etc., SUJ2 steel is typical, and this SUJ2 steel is also used after spheroidizing annealing. SUJ2 steel has a high C content of 0.95 to 1.10% and a high Cr content of 1.30 to 1.60%.

一方、C量は高いままCr量を減らした鋼材についても球状化焼鈍が適用されている(特許文献1、2など)。特許文献1ではC:1.41%、Cr:0.64%の鋼材Dに対して、Ac1−100℃〜Ac1の第1保定温度まで加熱して30〜120分間保定し、次いでAc1+5℃以上の第2保定温度まで加熱した後冷却する球状化焼鈍方法が開示されている。特許文献2ではC:0.40〜0.80重量%、Cr:0.80重量%以下の軸受用鋼材について、下記(1)〜(3)の処理の後、(4)〜(5)の処理を1回以上繰り返し、その後冷却する球状化焼鈍方法が開示されている。 On the other hand, spheroidizing annealing is also applied to steel materials in which the amount of Cr is reduced while the amount of C is high (Patent Documents 1, 2, etc.). Patent Document 1 C: 1.41%, Cr: against 0.64% for steel D, and retention heated to 30 to 120 minutes until the first retention temperature of Ac 1 -100 ° C. to Ac 1, then Ac A spheroidizing annealing method is disclosed in which the steel is heated to a second holding temperature of 1 + 5 ° C. or higher and then cooled. In Patent Document 2, C: 0.40 to 0.80% by weight, Cr: 0.80% by weight or less of the steel for bearings, after the treatments (1) to (3) below, (4) to (5) A spheroidizing annealing method is disclosed in which the above treatment is repeated once or more and then cooled.

(1)A3点以上に加熱保持後急速冷却を行う。
(2)A3点+(5〜30)℃の温度範囲に再加熱保持する。
(3)A1点−(5〜30)℃の温度範囲で保持する。
(4)(A1点+5)〜(A3点+30)℃の温度範囲で保持する。
(5)A1点−(5〜30)℃の温度範囲で保持する。
(1) A Rapid cooling is performed after heating and holding at 3 points or more.
(2) A 3 point + (5-30) reheating kept at a temperature in the range of ° C..
(3) A 1 point-held at a temperature range of (5 to 30) ° C.
(4) Hold in a temperature range of (A 1 point + 5) to (A 3 point + 30) ° C.
(5) A 1 point-held in a temperature range of (5 to 30) ° C.

特開平4−333527号公報JP-A-4-333527 特開平4−362123号公報JP-A-4-362123

前記SUJ2鋼などの高Cr合金鋼は、比較的安定して球状化焼鈍が可能であるのに対して、高いC量を保ったままでCrを減らした高C低Cr鋼では、球状化焼鈍を安定して行うことが難しい。例えば線材コイルを炉で処理して球状化焼鈍する場合、一部で球状化焼鈍に成功しても、球状化焼鈍に失敗する部分が発生することがあり、歩留まりが低下する。そして全ての場所で球状化焼鈍に成功するには炉の条件設定が極めてシビアになるという課題がある。前記特許文献1及び2の方法でも高C低Cr鋼を安定して球状化することは難しい。   High Cr alloy steels such as the SUJ2 steel can be spheroidized and annealed relatively stably, whereas high C low Cr steels with reduced Cr while maintaining a high C content are subject to spheroidizing annealing. It is difficult to do stably. For example, when a wire coil is processed in a furnace and subjected to spheroidizing annealing, even if the spheroidizing annealing is partially succeeded, a portion where the spheroidizing annealing fails may occur, resulting in a decrease in yield. And in order to succeed in spheroidizing annealing in all places, there is a problem that the condition setting of the furnace becomes very severe. It is difficult to stably spheroidize high C low Cr steel even by the methods of Patent Documents 1 and 2.

本発明は上記の様な事情に着目してなされたものであって、その目的は、鋼材の冷間加工性又は被削性を担保するために球状化焼鈍するに際して、対象鋼が高C低Cr鋼であっても安定して球状化焼鈍できる技術を確立することにある。   The present invention has been made paying attention to the above-mentioned circumstances, and its purpose is that when subjecting a steel material to spheroidizing annealing to ensure cold workability or machinability, the target steel has a high C low The purpose is to establish a technique that can stably spheroidize annealing even with Cr steel.

上記目的を達成し得た本発明の製造方法とは、C:0.7〜1.5%(質量%の意味。以下、同じ)、Cr:0.9%未満(0%を含まない)を含有する鋼材を球状化焼鈍して冷間加工性又は被削性に優れた鋼材を製造する方法であって、前記球状化焼鈍は、1段目熱処理と、これに続く2段目熱処理とから構成され、これら1段目熱処理及び2段目熱処理の条件は以下の通りである点にその要旨を有するものである。
(1)1段目熱処理
昇温速度:400℃/hr未満
加熱温度:A1点+10℃〜A1点+30℃でありかつ780℃未満
加熱保持時間:3〜8時間
冷却速度:A1点〜A1点−20℃の温度範囲を3℃/hr以下
冷却終了温度:A1点−35℃以下
(2)2段目熱処理
昇温速度:400℃/hr未満
加熱温度:A1点+5℃〜A1点+25℃でありかつ780℃未満
加熱保持時間:0.5〜2時間
冷却速度:A1点−15℃〜A1点−35℃の温度範囲を5℃/hr以下
The production method of the present invention that can achieve the above object is: C: 0.7 to 1.5% (meaning mass%, hereinafter the same), Cr: less than 0.9% (not including 0%) Is a method for producing a steel material excellent in cold workability or machinability by spheroidizing annealing, and the spheroidizing annealing includes a first stage heat treatment, followed by a second stage heat treatment, The conditions of these first-stage heat treatment and second-stage heat treatment are summarized as follows.
(1) First-stage heat treatment Temperature increase rate: less than 400 ° C./hr Heating temperature: A 1 point + 10 ° C. to A 1 point + 30 ° C. and less than 780 ° C. Heating holding time: 3-8 hours Cooling rate: A 1 point ~ A 1 point-20 ° C temperature range 3 ° C / hr or less Cooling end temperature: A 1 point -35 ° C or less (2) Second stage heat treatment Heating rate: less than 400 ° C / hr Heating temperature: A 1 point +5 ° C. to a 1 point + 25 ° C. and is and 780 ° C. lower than the heating holding time: 0.5 to 2 hours cooling rate: the temperature range of a 1 point -15 ° C. to a 1 point -35 ℃ 5 ℃ / hr or less

前記鋼材は、Si:0.001〜0.7%、Mn:0.1〜2.0%、Al:0.001〜0.1%を更に含有していてもよく、残部が鉄および不可避的不純物であってもよい。この不可避的不純物は、例えば、P:0.05%以下(0%を含まない)、S:0.001〜0.05%、N:0.015%以下(0%を含まない)などである。前記鋼材は、更に、Cu:0.25%以下(0%を含まない)、Ni:0.25%以下(0%を含まない)、Mo:0.25%以下(0%を含まない)およびB:0.01%以下(0%を含まない)よりなる群から選択される少なくとも1種を含有していてもよく、またTi:0.2%以下(0%を含まない)、Nb:0.2%以下(0%を含まない)およびV:0.5%以下(0%を含まない)よりなる群から選択される少なくとも1種を含有していてもよい。   The steel material may further contain Si: 0.001 to 0.7%, Mn: 0.1 to 2.0%, Al: 0.001 to 0.1%, the balance being iron and inevitable It may be an impurity. The inevitable impurities include, for example, P: 0.05% or less (not including 0%), S: 0.001 to 0.05%, N: 0.015% or less (not including 0%), etc. is there. The steel materials are further Cu: 0.25% or less (not including 0%), Ni: 0.25% or less (not including 0%), Mo: 0.25% or less (not including 0%) And B: may contain at least one selected from the group consisting of 0.01% or less (not including 0%), Ti: 0.2% or less (not including 0%), Nb : May contain at least one selected from the group consisting of 0.2% or less (not including 0%) and V: 0.5% or less (not including 0%).

本発明によれば、特定の2段階熱処理法を採用しているため、高C低Cr鋼であっても、安定して確実に球状化焼鈍することができ、歩留まりを高めることができる。   According to the present invention, since a specific two-stage heat treatment method is adopted, even a high C low Cr steel can be spheroidized and annealed stably and reliably, and the yield can be increased.

本発明者らは、前記課題を解決するために鋭意研究を重ねた結果、A1変態点よりも十分に低い温度まで冷却する過程を間に挟むようにして2段階に分けて熱処理を行い、かつ1段階目の熱処理の熱処理条件は比較的強く、そして2段階目の熱処理は比較的弱くなるようにしつつ一定の条件範囲内でコントロールすると、高C低Cr鋼であっても、安定して確実に球状化焼鈍することができることを見出し、本発明を完成した。以下、本発明法が対象とする鋼材について説明した後、本発明法について説明する。 As a result of intensive studies to solve the above problems, the present inventors conducted heat treatment in two stages so as to sandwich a process of cooling to a temperature sufficiently lower than the A 1 transformation point. The heat treatment conditions of the first stage heat treatment are relatively strong, and the second stage heat treatment is relatively weak and controlled within a certain range of conditions to ensure stable and reliable even for high C low Cr steels. The inventors have found that spheroidizing annealing can be performed and completed the present invention. Hereinafter, after explaining the steel material which this invention method makes object, this invention method is demonstrated.

1. 対象鋼
本発明は、高C低Cr鋼を対象とする。高C低Cr鋼には、球状化焼鈍を安定して行うという課題がある。前記高C低Cr鋼は、具体的にはCを0.7〜1.5%(質量%の意味。以下、同じ)、Crを0.9%未満(0%を含まない)含有する。
1. Target Steel The present invention is intended for high C low Cr steel. The high C low Cr steel has a problem of stably performing spheroidizing annealing. Specifically, the high C low Cr steel contains C in an amount of 0.7 to 1.5% (meaning mass%, hereinafter the same) and Cr less than 0.9% (not including 0%).

前記Cは、鋼材の強度(即ち、最終製品の強度)を確保するために必要な元素であり、冷間加工性や被削性に重要な影響を及ぼす。また炭化物を生じるため、球状化焼鈍方法の設計に当たっては必ず考慮しなければならない。C量は、好ましくは0.8%以上である。しかしCを過剰に含有すると、強度が高くなり過ぎて冷間加工性や被削性が悪くなるため、上限を設定した。C量は、好ましくは1.2%以下である。   The C is an element necessary for ensuring the strength of the steel material (that is, the strength of the final product), and has an important influence on cold workability and machinability. In addition, since carbide is generated, it must be taken into consideration when designing the spheroidizing annealing method. The amount of C is preferably 0.8% or more. However, if C is contained excessively, the strength becomes too high and cold workability and machinability deteriorate, so the upper limit was set. The amount of C is preferably 1.2% or less.

Crは球状化の難しさに影響を与える元素である。本発明ではこのCrを0.9%未満に低減した場合でも、安定して確実に球状化できることを目的として球状化焼鈍方法を設計するものであり、Cr量の特定は必須である。本発明によればCrが0.8%以下、又は0.6%以下、特に0.4%以下、更には0.3%以下であっても確実に球状化が可能であり、さらにはCr量は0.1%以下であってもよい。なおCrは、鋼材の焼入れ性を向上させ、最終製品の強度を高めるのに作用する元素である為、0.9%未満を満足する範囲で多く含有していてもよい。Cr量は、例えば、0.01%以上、好ましくは0.05%以上、さらに好ましくは0.1%以上であってもよい。   Cr is an element that affects the difficulty of spheroidization. In the present invention, even when this Cr is reduced to less than 0.9%, a spheroidizing method is designed for the purpose of stably and surely spheroidizing, and it is essential to specify the Cr amount. According to the present invention, even when Cr is 0.8% or less, or 0.6% or less, particularly 0.4% or less, and even 0.3% or less, spheroidization can be reliably performed. The amount may be 0.1% or less. Note that Cr is an element that acts to improve the hardenability of the steel material and increase the strength of the final product, and therefore may be contained in a large amount within a range satisfying less than 0.9%. For example, the Cr amount may be 0.01% or more, preferably 0.05% or more, and more preferably 0.1% or more.

本発明で焼鈍方法を設計するにあたって考慮すべき鋼材成分は上述したC量及びCr量であるが、実際に本発明の焼鈍方法に使用する鋼材は、通常、Si、Mn、Alを下記の範囲で更に含有する。また残部は特に限定されないが、鉄および不可避的不純物であってもよい。Si、Mn、Alの添加量及びその添加理由は以下の通りである。   The steel components to be considered in designing the annealing method in the present invention are the above-described C amount and Cr amount, but the steel materials actually used in the annealing method of the present invention usually have Si, Mn, and Al within the following ranges. In addition, it contains. The balance is not particularly limited, but may be iron and inevitable impurities. The addition amount of Si, Mn, and Al and the reason for the addition are as follows.

Siは、脱酸元素として、および固溶体硬化による最終製品の強度を増加させるために含有させることが好ましい元素である。Si量は、0.001%以上含有させることが好ましく、より好ましくは0.05%以上、更に好ましくは0.1%以上、特に好ましくは0.2%以上である。しかしSi量が0.7%を超えると、過度に強度が上昇して冷間加工性を劣化させることがある。従ってSi量は、0.7%以下とすることが好ましく、より好ましくは0.60%以下、更に好ましくは0.50%以下である。   Si is an element that is preferably contained as a deoxidizing element and to increase the strength of the final product by solid solution hardening. The Si content is preferably 0.001% or more, more preferably 0.05% or more, still more preferably 0.1% or more, and particularly preferably 0.2% or more. However, if the amount of Si exceeds 0.7%, the strength is excessively increased and cold workability may be deteriorated. Accordingly, the Si content is preferably 0.7% or less, more preferably 0.60% or less, and still more preferably 0.50% or less.

Mnは、焼入れ性を向上し、最終製品の強度を増加させるのに有効に作用する元素である。こうした作用を有効に発揮させるには、0.1%以上含有させることが好ましく、より好ましくは0.3%以上、更に好ましくは0.50%以上である。しかし過剰に含有すると強度が過度に上昇して冷間加工性が劣化することがある。従ってMn量は、2.0%以下とすることが好ましく、より好ましくは1.5%以下、更に好ましくは1.2%以下、特に好ましくは1.0%以下である。   Mn is an element that effectively acts to improve hardenability and increase the strength of the final product. In order to effectively exhibit such an action, the content is preferably 0.1% or more, more preferably 0.3% or more, and still more preferably 0.50% or more. However, when it contains excessively, intensity | strength rises excessively and cold workability may deteriorate. Accordingly, the Mn content is preferably 2.0% or less, more preferably 1.5% or less, still more preferably 1.2% or less, and particularly preferably 1.0% or less.

Alは、脱酸元素として作用すると共に、鋼材中に存在する固溶NをAlNとして固定し、冷間加工性を向上させる元素である。こうした作用を有効に発揮させるには、Al量は0.001%以上とすることが好ましく、より好ましくは0.005%以上、更に好ましくは0.01%以上である。しかしAl量が過剰になると、鋼材中にAl23が過剰に生成し、冷間加工性が劣化することがある。従ってAl量は、0.1%以下であることが好ましく、より好ましくは0.08%以下、更に好ましくは0.05%以下である。 Al is an element that acts as a deoxidizing element, fixes solid solution N present in the steel as AlN, and improves cold workability. In order to effectively exert such effects, the Al content is preferably 0.001% or more, more preferably 0.005% or more, and still more preferably 0.01% or more. However, when the amount of Al is excessive, Al 2 O 3 is excessively generated in the steel material, and cold workability may be deteriorated. Accordingly, the Al content is preferably 0.1% or less, more preferably 0.08% or less, and still more preferably 0.05% or less.

上記不可避的不純物としては、例えば、P、SおよびNを例示できる。これらの制限理由と、その許容し得る含有量は、例えば、以下の通りである。
Pは、鋼材中に不可避的に含まれる元素であり、粒界偏析を起こすと延性劣化の原因となる。従ってP量は、0.05%以下(0%を含まない)であることが好ましく、より好ましくは0.04%以下、更に好ましくは0.03%以下である。
Examples of the inevitable impurities include P, S, and N. The reasons for these limitations and the allowable contents thereof are as follows, for example.
P is an element inevitably contained in the steel material, and when grain boundary segregation occurs, it causes ductile deterioration. Therefore, the P content is preferably 0.05% or less (excluding 0%), more preferably 0.04% or less, and still more preferably 0.03% or less.

Sは、鋼材中に不可避的に含まれる元素であり、鋼材中にMnSとして存在し、延性を劣化させて冷間加工性を悪化させることがある。従ってS量は、0.05%以下であることが好ましく、より好ましくは0.04%以下、更に好ましくは0.03%以下である。
一方、Sは、鋼材の被削性を向上させる作用も有する。従ってS量は、0.001%以上であることが好ましく、より好ましくは0.002%以上、更に好ましくは0.003%以上である。
S is an element inevitably contained in the steel material, and is present as MnS in the steel material, which may deteriorate ductility and cold workability. Accordingly, the S amount is preferably 0.05% or less, more preferably 0.04% or less, and still more preferably 0.03% or less.
On the other hand, S also has the effect | action which improves the machinability of steel materials. Therefore, the S amount is preferably 0.001% or more, more preferably 0.002% or more, and further preferably 0.003% or more.

Nは、鋼材中に不可避的に含まれる元素であり、鋼材中に固溶Nとして存在すると、歪み時効による硬度上昇および延性低下を招き、冷間加工性を劣化させることがある。従ってN量は、0.015%以下(0%を含まない)であることが好ましく、より好ましくは0.013%以下、更に好ましくは0.010%以下である。   N is an element inevitably contained in the steel material. When N is present as solid solution N in the steel material, the hardness increases due to strain aging and the ductility decreases, and cold workability may be deteriorated. Accordingly, the N content is preferably 0.015% or less (excluding 0%), more preferably 0.013% or less, and still more preferably 0.010% or less.

上記鋼材は更に、(1)Cu、Ni、MoおよびBなど、および/または(2)Ti、NbおよびVなどを含んでもよい。
(1)の場合、Cu:0.25%以下(0%を含まない)、Ni:0.25%以下(0%を含まない)、Mo:0.25%以下(0%を含まない)およびB:0.01%以下(0%を含まない)よりなる群から選択される少なくとも1種を含有させる。これらの元素は、いずれも鋼材の焼入れ性を向上させて最終製品の強度を高めるのに有効に作用する元素であり、単独で含有させてもよく、2種以上含有させてもよい。前記作用を確実に発揮させる観点から、Cuは0.01%以上、Niは0.01%以上、Moは0.01%以上、Bは0.001%以上含有させることが好ましく、より好ましくは、Cuは0.03%以上、Niは0.03%以上、Moは0.03%以上、Bは0.0015%以上である。しかし過剰に含有すると、強度が高くなり過ぎて、冷間加工性が劣化することがある。従って前記範囲よりもその上限を限定してもよく、例えば、Cuは0.15%以下、Niは0.15%以下、Moは0.2%以下、Bは0.008%以下とするのが好ましい。
The steel material may further include (1) Cu, Ni, Mo, and B, and / or (2) Ti, Nb, V, and the like.
In the case of (1), Cu: 0.25% or less (not including 0%), Ni: 0.25% or less (not including 0%), Mo: 0.25% or less (not including 0%) And B: at least one selected from the group consisting of 0.01% or less (not including 0%) is contained. These elements are elements that effectively act to improve the hardenability of the steel material and increase the strength of the final product, and may be contained alone or in combination of two or more. From the viewpoint of surely exhibiting the above-mentioned action, it is preferable to contain Cu 0.01% or more, Ni 0.01% or more, Mo 0.01% or more, and B 0.001% or more, more preferably Cu is 0.03% or more, Ni is 0.03% or more, Mo is 0.03% or more, and B is 0.0015% or more. However, when it contains excessively, intensity | strength will become high too much and cold workability may deteriorate. Therefore, the upper limit may be limited more than the above range. For example, Cu is 0.15% or less, Ni is 0.15% or less, Mo is 0.2% or less, and B is 0.008% or less. Is preferred.

(2)の場合、Ti:0.2%以下(0%を含まない)、Nb:0.2%以下(0%を含まない)、およびV:0.5%以下(0%を含まない)よりなる群から選択される少なくとも1種を含有させる。これらの元素はいずれも、鋼材中に存在するNと結合して窒化物を形成し、固溶Nを低減することにより、変形抵抗を低下させて冷間加工性を向上させる元素であり、これらの元素は単独で、または2種以上を含有させることが好ましい。こうした作用を有効に発揮させるには、Tiは0.02%以上、Nbは0.02%以上、Vは0.05%以上含有させることが好ましく、より好ましくは、Tiは0.04%以上、Nbは0.05%以上、Vは0.08%以上である。しかし過剰に含有すると、形成される窒化物が変形抵抗を高め、冷間加工性を劣化させることがある。従って前記範囲よりもその上限を限定してもよく、例えば、Tiは0.1%以下、Nbは0.1%以下、Vは0.25%以下とするのが好ましい。   In the case of (2), Ti: 0.2% or less (not including 0%), Nb: 0.2% or less (not including 0%), and V: 0.5% or less (not including 0%) And at least one selected from the group consisting of: These elements are all elements that combine with N present in the steel material to form nitrides and reduce solute N, thereby reducing deformation resistance and improving cold workability. These elements are preferably used alone or in combination of two or more. In order to effectively exert such an effect, it is preferable that Ti is 0.02% or more, Nb is 0.02% or more, and V is 0.05% or more, more preferably, Ti is 0.04% or more. , Nb is 0.05% or more, and V is 0.08% or more. However, when it contains excessively, the nitride formed may increase deformation resistance and may deteriorate cold workability. Therefore, the upper limit may be limited more than the above range. For example, it is preferable that Ti is 0.1% or less, Nb is 0.1% or less, and V is 0.25% or less.

2. 製造方法
2.1 球状化焼鈍
本発明は、安定した球状化焼鈍が困難な上記のような高C低Cr鋼であっても、確実に球状化焼鈍してその冷間加工性と被削性を改善する発明である。本発明の製造方法で採用する球状化焼鈍法は、2段階に分けて熱処理を行う点に特徴があり、1段階目の熱処理を比較的強く設計し、2段階目の熱処理は比較的弱く設計している。1段階目の熱処理についてより詳細に説明すると、以下の通りである。
2. 2. Manufacturing Method 2.1 Spheroidizing Annealing The present invention is surely spheroidizing annealing and cold workability and machinability of the above-described high C low Cr steel, which is difficult to stably spheroidizing annealing. It is an invention that improves the above. The spheroidizing annealing method employed in the manufacturing method of the present invention is characterized in that the heat treatment is performed in two stages, the first stage heat treatment is designed to be relatively strong, and the second stage heat treatment is designed to be relatively weak. doing. A more detailed description of the first stage heat treatment is as follows.

2.1.1 1段目熱処理
1段目の熱処理では、まず鋼材を昇温速度:400℃/hr未満で加熱する。この加熱は、A1点+10℃以上、A1点+30℃以下の温度(ただし、780℃未満)まで行い、この温度で3〜8時間保持する。次いで冷却を開始し、この冷却では、A1点以下、A1点−20℃以上の温度範囲を3℃/hr以下の速度で徐冷する。冷却はA1点−35℃以下まで実施する。この1段目の熱処理で、元々のパーライト組織をある程度の球状化組織とし、また粒界セメンタイトも大幅に低減できる。そのため、続く2段目の熱処理で、全ての部位で確実に球状化組織を得ることができる。なおA1点は、オーステナイト+セメンタイトの相からオーステナイト+セメンタイト+フェライトの相への変態温度であり、総合熱力学計算ソフトウエア(Thermo−Calc。CRC総合研究所から購入可能。データベースはTTLFE)に、鋼材の化学成分組成を入力して求まる値である。
2.1.1 First-stage heat treatment In the first-stage heat treatment, first, the steel material is heated at a heating rate of less than 400 ° C./hr. This heating is performed to a temperature of A 1 point + 10 ° C. or higher and A 1 point + 30 ° C. or lower (however, less than 780 ° C.), and held at this temperature for 3 to 8 hours. Next, cooling is started, and in this cooling, a temperature range of A 1 point or lower and A 1 point −20 ° C. or higher is gradually cooled at a rate of 3 ° C./hr or lower. Cooling is carried out to A 1 point -35 ° C. or lower. By this first heat treatment, the original pearlite structure is made into a certain degree of spheroidized structure, and the grain boundary cementite can be greatly reduced. Therefore, a spheroidized structure can be reliably obtained at all sites by the subsequent second-stage heat treatment. The point A 1 is the transformation temperature from the austenite + cementite phase to the austenite + cementite + ferrite phase, which can be purchased from comprehensive thermodynamic calculation software (Thermo-Calc. CRC Research Institute, database is TTLFE). The value obtained by inputting the chemical composition of the steel material.

1段目の熱処理で鋼材の昇温速度を前記範囲に設定したのは、これを超えると、温度がオーバーシュートしやすくなって、加熱温度、時間に影響を与えるためである。昇温速度は、好ましくは300℃/hr以下、より好ましくは200℃/hr以下である。なお昇温速度が遅すぎると生産効率が低下する。よって昇温速度は、例えば、5℃/hr以上、好ましくは10℃/hr以上、より好ましくは20℃/hr以上である。   The reason why the rate of temperature rise of the steel material is set in the above range in the first heat treatment is that if the temperature is exceeded, the temperature tends to overshoot and the heating temperature and time are affected. The temperature rising rate is preferably 300 ° C./hr or less, more preferably 200 ° C./hr or less. If the temperature raising rate is too slow, the production efficiency is lowered. Therefore, the rate of temperature rise is, for example, 5 ° C./hr or more, preferably 10 ° C./hr or more, more preferably 20 ° C./hr or more.

1段目の加熱温度および加熱時間を前記範囲に設定したのは、この加熱で未固溶のパーライトと網状セメンタイトを消滅させ、かつセメンタイトが若干残存する様にするためである。加熱温度が低すぎたり、加熱時間が短すぎたりすると、未固溶のパーライトまたは網状セメンタイトが残存し、球状化が不十分な部分が発生する。逆に加熱温度が高すぎたり、加熱時間が長すぎたりすると、セメンタイトが溶けすぎ、その後の冷却でパーライトが発生しやすくなる結果、球状化が不十分な部分が発生する。前記加熱温度は、好ましくはA1点+12℃〜A1点+28℃、より好ましくはA1点+15℃〜A1点+25℃である。また該加熱温度は、好ましくは770℃以下、より好ましくは765℃以下である。前記加熱時間は、好ましくは4〜7時間である。 The reason why the heating temperature and the heating time in the first stage are set in the above-mentioned range is that the undissolved pearlite and reticulated cementite are eliminated by this heating, and some cementite remains. If the heating temperature is too low or the heating time is too short, undissolved pearlite or reticulated cementite remains, and a part with insufficient spheroidization occurs. On the other hand, if the heating temperature is too high or the heating time is too long, the cementite is excessively melted, and pearlite is likely to be generated by the subsequent cooling. As a result, a portion with insufficient spheroidization occurs. The heating temperature is preferably A 1 point + 12 ° C. to A 1 point + 28 ° C., more preferably A 1 point + 15 ° C. to A 1 point + 25 ° C. Moreover, this heating temperature becomes like this. Preferably it is 770 degrees C or less, More preferably, it is 765 degrees C or less. The heating time is preferably 4 to 7 hours.

1段目の冷却速度を前記範囲に設定したのは、微細な再生パーライトの発生を抑制するためである。微細な再生パーライトが発生すると2段目の加熱時に溶けすぎて、その後の冷却でパーライトが発生しやすくなり、球状化が不十分な部分が発生する。冷却速度は、好ましくは2℃/hr以下である。また該冷却速度の下限は適宜設定できるが、例えば、0.1℃/hr以上、好ましくは0.5℃/hr以上であってもよく、また1℃/hr以上であってもよい。   The reason why the cooling rate of the first stage is set in the above range is to suppress the generation of fine reproduction pearlite. When fine regenerated pearlite is generated, it is excessively melted during the second stage of heating, and pearlite is likely to be generated by subsequent cooling, and a portion with insufficient spheroidization is generated. The cooling rate is preferably 2 ° C./hr or less. The lower limit of the cooling rate can be set as appropriate, but may be, for example, 0.1 ° C./hr or more, preferably 0.5 ° C./hr or more, or 1 ° C./hr or more.

1段目の冷却終了温度を前記範囲に設定したのは、オーステナイトが残ったまま2段目の加熱に入ることを防止するためである。オーステナイトが残ったまま2段目の加熱に入ると、セメンタイトが溶けすぎ、その後の冷却でパーライトが発生しやすくなって、球状化が不十分な部分が発生する。冷却終了温度は、A1点−37℃以下であってもよく、A1点−40℃以下であってもよい。なお冷却終了温度の下限は特に設定されないが、生産効率の観点から、例えば、A1点−100℃以上、好ましくはA1点−50℃以上程度であってもよい。 The reason why the first stage cooling end temperature is set in the above range is to prevent the second stage heating from entering while the austenite remains. If the second stage of heating is entered with austenite remaining, the cementite is excessively melted, and pearlite is likely to be generated by the subsequent cooling, and a portion with insufficient spheroidization occurs. The cooling end temperature may be A 1 point −37 ° C. or lower, or A 1 point −40 ° C. or lower. The lower limit of the cooling end temperature is not particularly set, but may be, for example, A 1 point −100 ° C. or higher, preferably A 1 point −50 ° C. or higher, from the viewpoint of production efficiency.

2.1.2 2段目熱処理
2段目の熱処理では、1段目の冷却終了後、鋼材を昇温速度:400℃/hr未満で加熱する。この加熱は、A1点+5℃以上、A1点+25℃以下の温度(ただし、780℃未満)まで行い、この温度で0.5〜2時間保持する。次いで冷却を開始し、この冷却では、A1点−15℃以下、A1点−35℃以上の温度範囲を5℃/hr以下の速度で徐冷する。前記1段目の熱処理の後、これよりも比較的弱い2段目の熱処理を行うことで、パーライトの再生を防止しつつ、球状化が困難な部位でも確実に球状化できる。
2.1.2 Second-stage heat treatment In the second-stage heat treatment, after completion of the first-stage cooling, the steel material is heated at a heating rate of less than 400 ° C./hr. This heating is performed to a temperature of A 1 point + 5 ° C. or higher and A 1 point + 25 ° C. or lower (however, less than 780 ° C.) and held at this temperature for 0.5 to 2 hours. Next, cooling is started, and in this cooling, the temperature range of A 1 point −15 ° C. or lower and A 1 point −35 ° C. or higher is gradually cooled at a rate of 5 ° C./hr or lower. By performing the second-stage heat treatment, which is relatively weaker than the first-stage heat treatment, it is possible to reliably spheroidize even at a site where spheroidization is difficult while preventing regeneration of pearlite.

2段目の熱処理で鋼材の昇温速度を前記範囲に設定したのは、これを超えると、温度がオーバーシュートしやすくなって、加熱温度、時間に影響を与えるためである。昇温速度は、好ましくは300℃/hr以下、より好ましくは200℃/hr以下である。なお昇温速度が遅すぎると生産効率が低下する。よって昇温速度は、例えば、5℃/hr以上、好ましくは10℃/hr以上、より好ましくは20℃/hr以上である。   The reason why the temperature increase rate of the steel material is set in the above range in the second heat treatment is that if the temperature is exceeded, the temperature tends to overshoot and the heating temperature and time are affected. The temperature rising rate is preferably 300 ° C./hr or less, more preferably 200 ° C./hr or less. If the temperature raising rate is too slow, the production efficiency is lowered. Therefore, the rate of temperature rise is, for example, 5 ° C./hr or more, preferably 10 ° C./hr or more, more preferably 20 ° C./hr or more.

2段目の加熱温度および加熱時間を前記範囲に設定したのは、この加熱で未固溶のパーライトを消滅させる一方で、セメンタイトを多く残存させるためである。加熱温度が低すぎたり、加熱時間が短すぎたりすると、未固溶のパーライトが残存する部分が発生し、球状化が不十分な部分が発生する。逆に加熱温度が高すぎたり、加熱時間が長すぎたりするとセメンタイトが溶けすぎる部分が発生し、その後の冷却でパーライトが発生しやすくなり、球状化が不十分な部分が発生する。前記加熱温度は、好ましくはA1点+7℃〜A1点+23℃、より好ましくはA1点+10℃〜A1点+20℃である。また該加熱温度は、好ましくは760℃以下、より好ましくは755℃以下である。前記加熱時間は、好ましくは1.0〜2時間である。 The reason why the heating temperature and the heating time of the second stage are set in the above-mentioned range is that undiluted pearlite is eliminated by this heating while a large amount of cementite remains. When the heating temperature is too low or the heating time is too short, a portion where undissolved pearlite remains is generated, and a portion with insufficient spheroidization is generated. On the other hand, if the heating temperature is too high or the heating time is too long, a portion in which cementite is excessively dissolved is generated, and pearlite is easily generated by subsequent cooling, and a portion in which spheroidization is insufficient is generated. The heating temperature is preferably A 1 point + 7 ° C. to A 1 point + 23 ° C., more preferably A 1 point + 10 ° C. to A 1 point + 20 ° C. Moreover, this heating temperature becomes like this. Preferably it is 760 degrees C or less, More preferably, it is 755 degrees C or less. The heating time is preferably 1.0 to 2 hours.

2段目の冷却速度を前記範囲に設定したのは、再生パーライトの発生を抑制するためである。再生パーライトが発生すると、球状化が不十分となる。冷却速度は、好ましくは4.5℃/hr以下、より好ましくは4.0℃/hr以下である。また該冷却速度の下限は適宜設定できるが、例えば、0.5℃/hr以上、好ましくは1.0℃/hr以上であってもよく、また2℃/hr以上であってもよい。   The reason why the cooling rate of the second stage is set in the above range is to suppress the generation of regenerated pearlite. When regenerated perlite is generated, the spheroidization becomes insufficient. The cooling rate is preferably 4.5 ° C./hr or less, more preferably 4.0 ° C./hr or less. The lower limit of the cooling rate can be set as appropriate. For example, it may be 0.5 ° C./hr or higher, preferably 1.0 ° C./hr or higher, or 2 ° C./hr or higher.

2.2 球状化焼鈍前工程
本発明の鋼材を製造するに当たり、球状化焼鈍前の工程は特に限定されず、例えば、通常の鋼材の製造方法に従えばよい。例えば、所定の成分に調整した鋼材を鋳造し、必要に応じて分塊圧延した後、熱間圧延した鋼材を使用することができる。また他の方法によって得られた鋼材であっても、炭化物の球状化がなされていない鋼材であれば、いずれであっても使用できる。
2.2 Step before spheroidizing annealing In manufacturing the steel material of the present invention, the step before spheroidizing annealing is not particularly limited, and for example, a normal method for manufacturing a steel material may be followed. For example, a steel material that has been adjusted to have a predetermined component is cast, and if necessary, the steel material that is hot-rolled after being subjected to split rolling can be used. Moreover, even if it is the steel material obtained by the other method, as long as it is the steel material in which the spheroidization of the carbide | carbonized_material is not made, any can be used.

上記のようにして球状化焼鈍された鋼材は、冷間加工性や被削性に優れている。そのため、冷間加工(特に冷間鍛造)、切削加工などによって簡便に所定の形状に成形できる。この成形体は、焼入れ焼戻し処理などの最終的な強度調整を行い、鋼部品となる。本発明は、軸受けなどの自動車用部品、建設機械用部品等の各種部品を製造するのに極めて有用である。   The steel material spheroidized and annealed as described above is excellent in cold workability and machinability. Therefore, it can be easily formed into a predetermined shape by cold working (particularly cold forging) or cutting. This formed body is subjected to final strength adjustment such as quenching and tempering, and becomes a steel part. The present invention is extremely useful for manufacturing various parts such as automobile parts such as bearings and construction machine parts.

以下、実施例を挙げて本発明をより具体的に説明するが、本発明はもとより下記実施例によって制限を受けるものではなく、前・後記の趣旨に適合し得る範囲で適当に変更を加えて実施することも勿論可能であり、それらはいずれも本発明の技術的範囲に包含される。   EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited by the following examples, but may be appropriately modified within a range that can meet the purpose described above and below. Of course, it is possible to implement them, and they are all included in the technical scope of the present invention.

実験例
下記表1に示す成分組成の鋼材(鋼種A〜I)を熱間圧延することでφ15mmの線材コイル(1トン)を一鋼種当たり21個製造した。3段(層)積み型のバッチ式加熱炉に、一段(層)当たり7個(3段(層)の合計で21個)の線材コイルを挿入し、下記表2に示す条件で1段目(1回目)の熱処理を行った後、2段目(2回目)の熱処理を行った。
Experimental Example 21 steel wires (1 ton) having a diameter of 15 mm were produced per steel type by hot rolling steel materials (steel types A to I) having the composition shown in Table 1 below. Insert seven wire coils per stage (layer) into a three-stage (layer) stacking batch furnace, and the first stage under the conditions shown in Table 2 below. After performing the (first) heat treatment, the second (second) heat treatment was performed.

熱処理終了後、21個の線材コイルから偏りなく6個の線材コイルを選択し、評価用のコイルとした。1つのコイルについて、端部からサンプルを採取し、横断面のD/8位置(Dは直径)を一周に亘って観察し、観察部におけるLC(Lamellar Content:ラメラ量)番号及びCN(carbide network:炭化物網)番号の最大値をASTM A892−88に従って求めた。この評価を選択した6つのコイル全てにおいて実施し、最も大きい番号を、その鋼種のLC番号、CN番号とした。結果を表2に示す。なおLCは、層状セメンタイトの割合を示すパラメータであり、数値が小さいほど層状セメンタイトが少なく、球状化度がよいことを意味する。CNは、粒界のセメンタイト(主に初析セメンタイト)の割合を示すパラメータであり、数値が小さいほど粒界のセメンタイトが少なく、球状化度が良いことを示す。これらLC及びCNの両方が小さいときは、良好な球状化組織が得られていると評価でき、従って冷間加工性および被削性が向上していると判断できる。   After the heat treatment, six wire coils were selected without deviation from the 21 wire coils, and used as evaluation coils. For one coil, a sample is taken from the end, and the D / 8 position (D is the diameter) of the cross section is observed over the entire circumference, and the LC (Lamellar Content) number and CN (carbide network) in the observation part are observed. : Carbide net) The maximum number was determined according to ASTM A892-88. This evaluation was performed on all six selected coils, and the largest number was the LC number and CN number of the steel type. The results are shown in Table 2. LC is a parameter indicating the ratio of layered cementite. The smaller the value, the less layered cementite and the better the degree of spheroidization. CN is a parameter indicating the proportion of cementite (mainly pro-eutectoid cementite) at grain boundaries, and the smaller the value, the less the cementite at grain boundaries and the better the degree of spheroidization. When both LC and CN are small, it can be evaluated that a good spheroidized structure is obtained, and therefore it can be determined that the cold workability and machinability are improved.

Figure 0006093212
Figure 0006093212

Figure 0006093212
Figure 0006093212

No.13は1段目熱処理の加熱条件が強すぎた為に必要以上にセメンタイトが溶ける部分が発生し、その後の冷却でパーライトが発生しやすくなってLC番号が悪化した。No.14は1段目熱処理の加熱条件が弱すぎた為にパーライト又は網状セメンタイトが残存する部分が発生し、球状化が不十分となってCN番号が悪化した。No.15は1段目熱処理の冷却速度が速すぎるために微細な再生パーライトを生じる部分が発生し、LC番号が悪化した。No.16は1段目熱処理の冷却終了温度が高すぎてオーステナイトのままの部分を残したまま2段目の加熱に入ってしまうため、この2段目熱処理でセメンタイトが溶けすぎ、その後の冷却で再生パーライトが発生しやすくなってLC番号が悪化した。No.17は1段目熱処理の加熱条件及び2段目熱処理の加熱条件が共に弱いために球状化焼鈍ができない部分が発生し、LC番号、CN番号が共に悪化した。No.18は2段目熱処理の加熱条件が強すぎるためにセメンタイトが溶けすぎる部分が発生し、その後の冷却で再生パーライトとなるためLC番号が悪化した。No.19は2段目熱処理の加熱条件が弱すぎるために未固溶のパーライトが残存する部分が生じ、LC番号が悪化した。No.20は2段目熱処理の冷却速度が速すぎる為に再生パーライトとなる部分が発生し、LC番号が悪化した。No.21はCr含有量が多い従来鋼であって本熱処理条件の対象鋼ではないため、LC番号とCN番号が共に悪化した。
これらに対してNo.1〜12では、高C低Cr鋼を対象として適切な条件で2段階の熱処理を実施しているため、LC番号とCN番号が共に1になった。
No. In No. 13, since the heating conditions of the first stage heat treatment were too strong, a portion in which cementite was dissolved more than necessary was generated, and pearlite was easily generated by subsequent cooling, resulting in a deterioration of the LC number. No. In No. 14, since the heating conditions of the first stage heat treatment were too weak, a portion where pearlite or reticulated cementite remained was generated, resulting in insufficient spheroidization and worsening of the CN number. No. In No. 15, the cooling rate of the first-stage heat treatment was too high, so that a portion where fine regenerated pearlite was generated was generated, and the LC number was deteriorated. No. In No. 16, the cooling end temperature of the first stage heat treatment is too high and the second stage heat is entered while leaving the austenite portion, so that the cementite is melted too much by this second stage heat treatment and regenerated by subsequent cooling. Perlite was easily generated and the LC number was deteriorated. No. In No. 17, since the heating conditions of the first stage heat treatment and the heating conditions of the second stage heat treatment were both weak, a portion where spheroidizing annealing could not be performed occurred, and both the LC number and CN number deteriorated. No. In No. 18, the heating condition of the second stage heat treatment was too strong, so that a portion in which cementite was too dissolved was generated, and the LC number deteriorated because it became regenerated pearlite by subsequent cooling. No. For No. 19, the heating condition of the second stage heat treatment was too weak, so that a part where undissolved pearlite remained was generated, and the LC number was deteriorated. No. In No. 20, the cooling rate of the second-stage heat treatment was too high, so that a portion that became regenerated pearlite was generated, and the LC number deteriorated. No. Since No. 21 is a conventional steel with a high Cr content and not the target steel under the heat treatment conditions, both the LC number and the CN number deteriorated.
No. In Nos. 1 to 12, the LC number and the CN number were both 1 because the two-stage heat treatment was performed under the appropriate conditions for the high C low Cr steel.

Claims (3)

C:0.7〜1.5%(質量%の意味。以下、同じ)、Cr:0.9%未満(0%を含まない)、Si:0.001〜0.7%、Mn:0.1〜2.0%、およびAl:0.001〜0.1%を含有し、残部が鉄および不可避的不純物であり、前記不可避的不純物として、P:0.05%以下(0%を含まない)、S:0.001〜0.05%、N:0.015%以下(0%を含まない)を含み、パーライト組織を含む鋼材を球状化焼鈍して冷間加工性又は被削性に優れた鋼材を製造する方法であって、前記球状化焼鈍は、1段目熱処理と、これに続く2段目熱処理とから構成され、これら1段目熱処理及び2段目熱処理の条件は以下の通りである冷間加工性又は被削性に優れた鋼材の製造方法。
(1)1段目熱処理
昇温速度:400℃/hr未満
加熱温度:A1点+10℃〜A1点+30℃でありかつ780℃未満
加熱保持時間:3〜8時間
冷却速度:A1点〜A1点−20℃の温度範囲を3℃/hr以下
冷却終了温度:A1点−35℃以下
(2)2段目熱処理
昇温速度:400℃/hr未満
加熱温度:A1点+5℃〜A1点+25℃でありかつ780℃未満
加熱保持時間:0.5〜2時間
冷却速度:A1点−15℃〜A1点−35℃の温度範囲を5℃/hr以下
C: 0.7 to 1.5% (meaning mass%; hereinafter the same) , Cr: less than 0.9% (not including 0%) , Si: 0.001 to 0.7 %, Mn: 0.1 to 2.0%, and Al: 0.001 to 0.1% , the balance is iron and inevitable impurities, P: 0.05% or less (0% as the inevitable impurities) ), S: 0.001 to 0.05%, N: 0.015% or less (not including 0%), and spheroidizing and annealing a steel material including a pearlite structure, A method for producing a steel material having excellent machinability, wherein the spheroidizing annealing is composed of a first-stage heat treatment followed by a second-stage heat treatment, and conditions for the first-stage heat treatment and the second-stage heat treatment. Is a method for producing a steel material having excellent cold workability or machinability as follows.
(1) First-stage heat treatment Temperature increase rate: less than 400 ° C./hr Heating temperature: A 1 point + 10 ° C. to A 1 point + 30 ° C. and less than 780 ° C. Heating holding time: 3-8 hours Cooling rate: A 1 point ~ A 1 point-20 ° C temperature range 3 ° C / hr or less Cooling end temperature: A 1 point -35 ° C or less (2) Second stage heat treatment Heating rate: less than 400 ° C / hr Heating temperature: A 1 point +5 ° C. to a 1 point + 25 ° C. and is and 780 ° C. lower than the heating holding time: 0.5 to 2 hours cooling rate: the temperature range of a 1 point -15 ° C. to a 1 point -35 ℃ 5 ℃ / hr or less
前記鋼材が更に、
Cu:0.25%以下(0%を含まない)、
Ni:0.25%以下(0%を含まない)、
Mo:0.25%以下(0%を含まない)および
B :0.01%以下(0%を含まない)よりなる群から選択される少なくとも1種を含む請求項に記載の製造方法。
The steel material is further
Cu: 0.25% or less (excluding 0%),
Ni: 0.25% or less (excluding 0%),
The manufacturing method according to claim 1 , comprising at least one selected from the group consisting of Mo: 0.25% or less (excluding 0%) and B: 0.01% or less (not including 0%).
前記鋼材が更に、
Ti:0.2%以下(0%を含まない)、
Nb:0.2%以下(0%を含まない)および
V :0.5%以下(0%を含まない)よりなる群から選択される少なくとも1種を含む請求項1または2に記載の製造方法。
The steel material is further
Ti: 0.2% or less (excluding 0%),
The production according to claim 1 or 2 , comprising at least one selected from the group consisting of Nb: 0.2% or less (not including 0%) and V: 0.5% or less (not including 0%). Method.
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