JP6061050B1 - Light control film and method of manufacturing light control film - Google Patents

Abstract

A VA-type light control film having a negative C plate layer can be further reduced in overall thickness. First and second laminated layers including first and second transparent electrodes 12F and 13C, first and second alignment layers 12G and 13D, and first and second linearly polarizing plates 12D and 13F. In the light control film 10 of the VA system in which the liquid crystal layer 14 is sandwiched between the bodies 12 and 13 and the amount of transmitted light is varied by driving by the first and second transparent electrodes 12F and 13C, the first laminate 12 is A transparent film material 12A functioning as a negative C plate layer, and the transparent film material 12A is provided with the first transparent electrode 12F, the first alignment layer 12G, and the first linearly polarizing plate 12D. One linearly polarizing plate 12D is a coating type linearly polarizing plate. [Selection] Figure 1

Description

  The present invention relates to a light control film that is attached to a window or the like of a passenger car to control the transmission of extraneous light.

  Conventionally, for example, various devices relating to a light control film that is attached to a window to control the transmission of external light have been proposed (Patent Documents 1 and 2). One such light control film uses liquid crystal. The light control film using the liquid crystal is produced by sandwiching a liquid crystal material with a transparent film material on which a transparent electrode is produced, and producing the liquid crystal cell with a linear polarizing plate. As a result, in this light control film, the orientation of the liquid crystal is changed by changing the electric field applied to the liquid crystal, thereby blocking or transmitting the extraneous light, and further changing the amount of transmitted light. To control.

  In such a light control film, a liquid crystal cell is configured using a flexible transparent film material. However, by controlling the amount of transmitted light by controlling the polarization plane of the transmitted light, the transparent film material has optical properties. A film with small anisotropy is applied. The linear polarizing plate sandwiching the liquid crystal cell is arranged by crossed Nicols or parallel Nicols, but in these arrangements, the transmitted light can be sufficiently shielded in the front direction, but the transmitted light is sufficient in the oblique direction. It cannot be shielded from light. Thus, it is conceivable to arrange a compensation film for optical compensation as required in the light control film.

  Various driving methods proposed for liquid crystal display panels can be applied to driving the liquid crystal cell. Specifically, for example, a driving method such as a TN (Twisted Nematic) method, an IPS (In-Place-Switching) method, or a VA (Virtual Alignment) method can be applied. In the VA system, a device for improving viewing angle characteristics by providing an optical compensation film using a negative C plate has been proposed.

  Among these driving methods, an IPS type FFS (fringe field switching) type liquid crystal display device is disclosed in Patent Document 3 as an O-type linear polarizing plate, which is a normal linear polarizing plate, and a coating-type polarizing plate. There has been proposed a device for improving characteristics when observing from an oblique direction by laminating E-type linearly polarizing plates and arranging them on the exit surface of the liquid crystal cell. Patent Document 4 and the like disclose the configuration of an E-type linearly polarizing plate.

  Here, in the light control film, for example, it is required to sufficiently reduce the transmittance at the time of light shielding by sticking to a window glass or the like to shield the external light. From the viewpoint of ensuring, driving by the VA method is conceivable. In this case, it is conceivable to improve the optical characteristics by providing an optical functional layer that functions as a negative C plate. Here, the VA method is a method of controlling the transmitted light by changing the alignment of the liquid crystal between vertical alignment and horizontal alignment. Generally, the liquid crystal layer is vertically aligned by vertically aligning the liquid crystal when no electric field is applied. A liquid crystal cell is formed by being sandwiched between alignment layers, and the liquid crystal material is horizontally aligned by application of an electric field.

  The light control film is desired to have a small overall thickness. That is, the light control film having a conventional configuration is formed by forming a transparent electrode or the like on a transparent film material having a thickness of about 100 μm so that the liquid crystal layer is formed with about 5 μm and sandwiching the liquid crystal layer. The perpendicular parallel polarizing plate is produced by sandwiching an optical functional layer having an optical function as a linear polarizing plate with a transparent film material having a thickness of several tens of μm. A compensation film used for optical compensation is a C film having a thickness of several tens of μm. A plate is applied. The light control film is produced by sequentially laminating these members with an adhesive layer having a thickness of about 20 μm. Accordingly, the light control film is produced with a thickness of 500 μm or more when it is possible to sufficiently shield the transmitted light in the oblique direction by the conventional configuration, and it is difficult to sufficiently secure even the flexibility. As a result, with respect to the thickness, the conventional light control film still has an insufficient problem for practical use.

JP 03-47392 A Japanese Patent Laid-Open No. 08-184273 JP 2011-59266 A JP-T 8-511109

  This invention is made | formed in view of such a condition, and it enables it to make the whole thickness still thinner regarding the light control film by the VA system provided with the negative C plate layer.

  The present inventor has intensively studied to solve the above problems, and has come to the idea that a film material that functions as a negative C plate is applied to a base material, and an E-type linear polarizing plate is provided on the base material. The present invention has been completed.

  Specifically, the present invention provides the following.

(1) a first laminate including a first transparent electrode, a first alignment layer, and a first linearly polarizing plate;
A second laminate comprising a second transparent electrode, a second alignment layer, a second linearly polarizing plate;
In the dimming film by the VA method in which the liquid crystal layer is sandwiched by and the amount of transmitted light is varied by driving with the first and second transparent electrodes,
The first laminate is
It has a transparent film material that functions as a negative C plate layer,
The transparent film material is provided with the first transparent electrode, the first alignment layer, and the first linear polarizing plate,
The light control film in which the first linear polarizing plate is an E-type linear polarizing plate.

  According to (1), the transparent film material that functions as a negative C plate layer is provided with a transparent electrode, an alignment layer, and a linearly polarizing plate on the transparent film material that functions as a negative C plate layer. It can be used without separately providing a base material, and the entire thickness can be reduced. The thickness can also be reduced by applying an E-type linearly polarizing plate.

(2) In (1),
The first laminate is
The first transparent electrode and the first alignment layer are sequentially provided on the liquid crystal layer side of the transparent film material,
The light control film in which the said 1st linearly-polarizing plate was provided in the opposite side to the said liquid-crystal layer side of the said transparent film material.

  According to (2), the overall thickness can be further reduced with respect to the light control film by the VA system including the negative C plate layer by a more specific configuration with respect to the first laminate.

(3) In (2),
The second laminate is
It has a transparent film material that functions as a negative C plate layer,
The second transparent electrode and the second alignment layer are sequentially provided on the liquid crystal layer side of the transparent film material,
The second linear polarizing plate is provided on the side opposite to the liquid crystal layer side of the transparent film material,
The light control film in which the second linear polarizing plate is an E-type linear polarizing plate.

(4) In (2),
The second laminate is
The second transparent electrode, the second linearly polarizing plate, and the second alignment layer are sequentially provided on the liquid crystal layer side of the transparent film material,
The light control film in which the second linear polarizing plate is an E-type linear polarizing plate.

  According to (3) or (4), the overall thickness can be further reduced with respect to the light control film by the VA method including the negative C plate layer by a more specific configuration with respect to the second laminate.

(5) In the manufacturing method of the light control film by VA system,
A first laminate production step of producing a first laminate comprising a first transparent electrode, a first alignment layer, and a first linearly polarizing plate;
A second laminate production step of producing a second laminate comprising a second transparent electrode, a second alignment layer, and a second linearly polarizing plate;
A laminating step of laminating the first and second laminates with a liquid crystal layer interposed therebetween,
The first laminate manufacturing step includes
The first transparent electrode and the first alignment layer are sequentially formed on one surface of a transparent film material functioning as a negative C plate layer, and the first surface by a coating mold is formed on the other surface of the transparent film material. The manufacturing method of the light control film which produces 1 linearly-polarizing plate.

  According to (5), the transparent film material that functions as the negative C plate layer is provided with the transparent electrode, the alignment layer, and the linearly polarizing plate on the transparent film material that functions as the negative C plate layer. It can be used without separately providing a base material, and the entire thickness can be reduced. The thickness can also be reduced by applying an E-type linearly polarizing plate.

  According to the present invention, the overall thickness of the VA-type light control film having a negative C plate layer can be further reduced.

It is sectional drawing which shows the light control film which concerns on 1st Embodiment of this invention. It is a flowchart which shows the manufacturing process of the light control film of FIG. It is a flowchart which shows the upper side laminated body preparation process in the manufacturing process of FIG. It is a flowchart which shows the lower side laminated body preparation process in the manufacturing process of FIG. It is sectional drawing which shows the light control film which concerns on 2nd Embodiment of this invention.

[First Embodiment]
FIG. 1 is a cross-sectional view for explaining the light control film according to the first embodiment of the present invention. The light control film 10 is a light control film by a VA system, and is configured by sandwiching a liquid crystal layer 14 between a lower laminate 12 and an upper laminate 13 which are film-shaped first and second laminates.

  In the lower laminate 12, a negative C plate layer 12A is formed of a transparent film material such as a TAC (triacetyl cellulose) film material, and hard coat layers 12B and 12C are provided on both surfaces of the negative C plate layer 12A. The lower laminate 12 is provided with a first linear polarizing plate 12D following the hard coat layer 12C, and further with a hard coat layer 12E. On the other hand, on the liquid crystal layer 14 side, the first transparent electrode 12F and the first alignment layer 12G are provided following the hard coat layer 12B.

  Further, in the upper laminate 13, the negative C plate layer 13A is similarly formed of a transparent film material, and the hard coat layer 13B, the second transparent electrode 13C, the second transparent electrode 13C, and the like are sequentially formed on the negative C plate layer 13A on the liquid crystal layer 14 side. Two alignment layers 13D are provided, and a hard coat layer 13E and a second linearly polarizing plate 13F are provided on the side opposite to the liquid crystal layer.

  Here, the hard coat layers 12B, 12C, 13B, and 13E are produced with a thickness of about 5 μm, and the hard coat layer 12E is produced with a thickness of about 10 μm. The negative C plate layers 12A and 13A have a thickness of about 100 μm, and the transparent electrodes 12F and 13C are formed of ITO having a thickness of 50 nm.

  The linearly polarizing plates 12D and 13F are optical functional layers that function as E-type linearly polarizing plates. Here, as described in Patent Documents 3 and 4, the E-type linearly polarizing plate is a linearly polarizing plate including a polarizing layer formed by alignment of dye molecules. The polarizing layers of the linearly polarizing plates 12D and 13F have an absorption axis in a direction perpendicular to the arrangement direction of the dye molecules, the extraordinary refractive index is smaller than the ordinary refractive index, and extraordinary rays are used. This is a polarizing layer having a larger transmittance than ordinary light.

  The E-type polarizing layer is prepared by applying a coating liquid containing the dye molecules related to the polarizing layer to produce a coating film, and then applying mechanical stress (shearing force) to the coating layer to remove the dye molecules. Various preparation methods can be applied, such as applying stress while applying a coating liquid. Thereby, it is comprised so that the whole thickness can be made thin.

  That is, in the light control film of the conventional configuration, the transmitted light of the liquid crystal layer incident on the linear polarizing plate needs to prevent the polarization plane controlled by the liquid crystal layer from being impaired, and thus has a small optical anisotropy. It is necessary to apply a transparent film material to the substrate, it is difficult to apply a highly versatile film material to the substrate, and it is difficult to reduce the overall thickness.

  However, in this embodiment, a transparent film material is applied to the negative C plate layers 12A and 13A, and the linear polarizing plates 12D and 13F and the transparent electrodes 12F and 13C are provided using the transparent film material as a base material. Thus, a base material made of a transparent film material having a small optical anisotropy can be omitted, and the entire thickness can be reduced accordingly.

  In addition, by applying a transparent film material to the negative C plate layers 12A and 13A in this way, and using the transparent film material as a base material, the coating type linearly polarizing plates 12D and 13F are directly arranged, The thickness of the linear polarizing plate can also be reduced, and as a result, the overall thickness can be reduced.

  Actually, according to the configuration of FIG. 1, the thickness of the linear polarizing plates 12D and 13F is about 1 μm, so that the entire light control film 10 can have a thickness of about 200 μm. The thickness can be significantly reduced.

  Here, various optical films functioning as a negative C plate layer can be applied to the negative C plate layers 12A and 13A.

  Here, the in-plane main refractive index is nx (slow axis direction), ny is (fast axis direction), and the refractive index in the thickness direction is nz. The negative C plate is a negative uniaxial retardation optical element whose refractive index distribution satisfies nz <nx = ny. Thus, the negative C plate has a function of changing the optical characteristics in the oblique direction, and is used to bring the characteristics viewed from the oblique direction closer to the characteristics viewed from the front direction.

  As a film material constituting the negative C plate, in addition to a stretched transparent film material such as TAC (triacetyl cellulose), a cholesteric liquid crystal cured product laminated on an alignment layer can be applied. In addition, the transparent film material in the present invention means a film-like material that is transparent in the visible light region, and includes not only a resin film but also a liquid crystal cured product.

  ITO is applied to the transparent electrodes 12F and 13C. As the linearly polarizing plates 12D and 13F, an E-type linearly polarizing plate that is a coating type polarizing plate is applied, and more specifically, for example, the configuration disclosed in Japanese Patent Application Laid-Open No. 8-511109 can be applied. It is formed by a coating film of a dichroic organic dye that exhibits optical anisotropy.

  As the alignment layers 12G and 13D, although a photo-alignment layer is applied, various configurations such as an alignment layer formed by rubbing treatment and an alignment layer prepared by forming a fine line-shaped uneven shape can be applied.

  In the light control film 10, a columnar spacer 15 that maintains the thickness of the liquid crystal layer 24 is formed on the alignment layer 12G of the lower laminate 12, but is provided on the hard coat layer 12B. Also good. Moreover, you may provide in the side of the upper laminated body 13, and you may provide in both the lower laminated body 12 and the upper laminated body 13.

  In the light control film 10, a sealing agent is arranged in a frame shape surrounding the liquid crystal layer 14, and leakage of liquid crystal related to the liquid crystal layer 14 is prevented by this sealing agent, and further, the upper laminate 13 and the lower laminate 12 are formed. It is held together. Here, as the sealing agent, various materials capable of preventing the liquid crystal from leaking and capable of holding the upper laminate 13 and the lower laminate 12 together can be applied. In this embodiment, for example, an epoxy resin is used. A thermosetting resin, an ultraviolet curable resin using an acrylic resin, a curable resin curable by heat and ultraviolet light, or the like is used.

  FIG. 2 is a flowchart for explaining the manufacturing process of the light control film 10. In the manufacturing process of the light control film, the upper laminate 13 and the lower laminate 12 are produced in the upper laminate production step SP2 and the lower laminate production step SP3, respectively. Further, in the lamination step SP4, the upper laminate 13 and the lower laminate 12 are laminated with the liquid crystal layer 24 interposed therebetween, and then integrated with a sealant to produce the light control film 10.

  FIG. 3 is a flowchart showing in detail the upper laminate manufacturing process SP2. In this upper laminate manufacturing process SP2 (SP11), in the electrode manufacturing process SP12, a transparent film 13C made of ITO is formed by sputtering or the like on the transparent film material related to the negative C plate layer 13A obtained by manufacturing the hard coat layers 13B and 13E. Is produced. In the subsequent linear polarizing plate manufacturing step SP13, the coating liquid for the linear polarizing plate 13F is applied and then dried, whereby the linear polarizing plate 13F is manufactured. In addition, the linear polarizing plate manufacturing step SP13 applies the shearing force to the coating film by stretching the coating film with a blade or the like at the time of applying the coating liquid or after preparing the coating film. The dye relating to the linearly polarizing plate 13F is oriented in the above-described direction, whereby the linearly polarizing plate 13F is produced so as to function as a linearly polarizing plate. Then, this manufacturing process produces alignment layer 13D by applying and drying the coating liquid concerning alignment layer 13D in alignment layer preparation process SP14, and hardening by irradiation of the ultraviolet-ray by a linearly polarized light subsequently. .

  FIG. 4 is a flowchart showing in detail the lower laminate manufacturing process SP3. In this lower laminate manufacturing step SP3 (SP21), in the electrode manufacturing step SP22, the transparent film 12F made of ITO is formed by sputtering on the transparent film material related to the negative C plate layer 13A formed by forming the hard coat layers 12B and 12C. Is produced. Subsequently, in the linear polarizing plate manufacturing step SP23, this manufacturing process is performed in the same manner as the linear polarizing plate manufacturing step SP13, after applying the coating liquid for the linear polarizing plate 12D and then drying, whereby the linear polarizing plate 12D is formed. Produced. Subsequently, in this manufacturing process, the alignment layer 12G is formed by applying the coating liquid related to the alignment layer 12G, drying, and exposing in the alignment layer manufacturing process SP24. Further, in the spacer manufacturing step SP25, a spacer 15 is manufactured by applying a photoresist material to the entire surface, drying, exposing, and developing. In these upper laminate production process and lower laminate production process, the linear polarizing plate production process may be provided after the alignment layer production process or before the transparent electrode production process. .

[Detailed configuration of spacer]
Here, in this embodiment, the spacer 15 is formed in a columnar shape or a truncated cone shape. Further, in this embodiment, the Vickers hardness value Xs of the spacer 15 and the Vickers hardness value Xf of the portion where the tip of the spacer 15 abuts are Vickers hardness value 2 or more and Vickers hardness value 6 or less, and Xs <Xf. Thus, the reliability related to the spacer is further improved as compared with the related art.

  That is, when Xf <Xs, the tip of the spacer 15 penetrates into the opposing surface due to the pressing force during use, and as a result, the cell gap becomes non-uniform or local alignment failure occurs. In a severe case, the end of the spacer 15 breaks through the opposite laminated body, and the liquid crystal material leaks. However, by satisfying Xs <Xf, it is possible to reduce the situation where the tip of the spacer penetrates into the opposite surface due to the pressing force during use, etc., thereby making the cell gap non-uniform and local orientation. Generation | occurrence | production of a defect can be reduced and also the leakage of liquid crystal material can be avoided effectively.

  When the Vickers hardness value is smaller than 2, the spacer is crushed by the external pressure and the cell gap is reduced or the desired cell gap cannot be obtained. However, in this embodiment, the Vickers hardness value is 2 or more. The situation can be reduced. Further, when the Vickers hardness value is more than 6, the substrate is easily damaged, and cracks are generated when the whole is bent. In this embodiment, the Vickers hardness value is 6 or less, so that the substrate is damaged. And the occurrence of cracks when the whole is bent can be reduced. By these, the reliability regarding a spacer can be improved further compared with the past.

  Table 1 is a chart showing test results used for confirmation of the configuration related to the spacer. The light control films of Test Examples 1 to 6 in Table 1 are configured identically except that the configurations regarding the spacer and the alignment layer with which the spacer contacts are different. More specifically, in the light control films of Test Examples 1 to 6, the spacer 15 is provided only on the lower laminate 12, and the Vickers hardness value Xs of the spacer 15 is set according to the heat treatment conditions related to the spacer 15. did.

  That is, the spacer 15 is applied after the coating liquid related to the spacer 15 is dried, and then a portion where the spacer 15 is produced is selectively exposed by mask exposure using an exposure apparatus. Note that this is a case of a positive type photoresist. On the contrary, in the case of a negative type photoresist, a part other than the part for producing the spacer 15 is selectively exposed. After that, the spacer 15 is selectively removed at an unexposed or exposed portion by development processing, and processing such as rinsing is performed, and processing such as drying is performed as necessary.

  In this exposure process, exposure may be performed in a so-called half-cure state by heating in advance or in a heated environment. In the development process, after rinsing or the like is performed, the heat treatment is performed. May accelerate the reaction. The hardness value Xs of the spacer 15 can be set by selecting a photoresist material related to the spacer 15, setting the heating temperature and time in the exposure process and the development process, and setting the exposure light amount and the exposure time.

  In this embodiment, the Vickers hardness value Xs of the spacer 15 in Test Examples 1, 5, and 6 is set to 1.8, 4.2, and 4.2, respectively, by setting the heating temperature and time in the exposure process and the development process. The Vickers hardness value Xs of the spacer 15 in Test Examples 2, 3, and 4 was set to 2.2, 3.7, and 4.2, respectively. The spacer 15 was produced in a cylindrical shape having a diameter of 15 μm and a height of 5 μm.

  On the other hand, in the alignment layer 13D of the upper laminate 13 which is a surface with which this spacer abuts, it was prepared by rubbing treatment instead of the photo-alignment layer. That is, a polyimide film was prepared by applying a coating liquid, drying and curing, and this polyimide film was prepared by rubbing. Moreover, the Vickers hardness value Xf was set by the setting of the heating temperature at the time of hardening at the time of producing this polyimide film and the heating time. Note that the Vickers hardness value Xf may be adjusted by performing another heat treatment after the rubbing treatment. Thus, in Test Examples 1, 5, and 6, the Vickers hardness value Xf was set to 4.9, 6.7, and 3.6, and in Test Examples 2, 3, and 4, the Vickers hardness value Xf was set to 4.9. .

  In this experiment, a load corresponding to 0.8 MPa was applied in a state where the light control film was placed on a smooth surface having high hardness by a surface plate, and then the cell gap was measured to determine the decrease in the cell gap. The weighting time is 24 hours. After weighting in this way, the upper laminate and the lower laminate are peeled off and the spacer is observed with a microscope to check for collapse of the spacer (spacer collapse), and the part where the spacer contacts is observed with a microscope. The penetration of the spacer tip (film penetration) was observed.

  Here, for observation with this microscope, a front view, a perspective view, and a cross-section are observed using a method such as SEM, and the deformation of the spacer is visually confirmed. When the deformation of the spacer is confirmed, according to the situation, “ The presence or absence of “cell gap reduction, spacer crushing” was judged as “Good”. Therefore, in Table 1, “◯” indicates a case where no abnormality related to the corresponding item is observed, and “X” indicates a case where abnormality regarding the corresponding item is observed.

  Similarly, if the part where the spacer abuts is perspective using a technique such as SEM, if a dent (recess) is confirmed, “film penetration” is determined as x, and if no recess is observed, “film penetration” Was rated as ○.

  Further, in the state where the laminates 12 and 13 were laminated and a load corresponding to 0.1 MPa was applied, the relative positions of the laminates 12 and 13 were displaced by 0.1 cm / sec, and the occurrence of scratches was confirmed visually. Here, when scratches are confirmed in more than half of the multiple samples, “scratch (film)” is indicated by “x”, and conversely, scratches are not confirmed in more than half of the multiple samples. In this case, “scratch (film)” is indicated by “◯”.

  Further, in the state of the light control film, it was wound around a cylindrical mandrel having a diameter of 2 mm in accordance with the bending test of JIS K5600-5-1 to confirm the occurrence of cracks. In this test, when cracks are confirmed in the substrate in more than half of the multiple samples, “crack (film)” is indicated by “x”, and conversely, in more than half of the multiple samples, the substrate In the case where the occurrence of cracks is not confirmed, “crack (film)” is indicated by “◯”.

  In the measurement results of Table 1, in Test Example 1, due to insufficient spacer hardness, cell gap reduction and spacer crushing are observed, and in Test Example 5, the Vickers hardness value Xf of the spacer facing surface exceeds 6. Thus, generation of cracks was observed, and further, cell gap reduction and spacer collapse were observed. In Test Example 6, since the Vickers hardness value Xs of the spacer was larger than the Vickers hardness value Xf of the opposing surface, the substrate was observed to be damaged, and the penetration of the spacer tip was also confirmed. However, in Test Examples 2, 3, and 4, these phenomena were not observed, and this confirmed that the reliability related to the spacer could be further improved as compared with the conventional case.

[Second Embodiment]
FIG. 5 is a cross-sectional view showing a light control film according to a second embodiment of the present invention. The light control film 20 is configured the same as the light control film 10 according to the first embodiment except that the configuration related to the upper laminate 23 is different. In FIG. 5, the hard coat layer is omitted.

  Here, in the light control film 20, the negative C plate layer 12 </ b> A is provided only on the side of the lower laminate 12 that is one side of the liquid crystal layer 14. Thus, a highly versatile transparent film material is applied to the base material 23A in the upper laminate 23, and the transparent electrode 13C and the linearly polarizing plate 13F are provided on the base material 23A. Further, by providing the transparent electrode 13C and the linear polarizing plate 13F on the liquid crystal layer 14 side of the base material 23A, a material having high versatility can be applied to the base material 23A. Specifically, in this embodiment, PET (polyethylene) is used. A terephthalate) film material is applied.

  That is, in the light control film having a conventional configuration, the transmitted light of the liquid crystal layer incident on the linearly polarizing plate must not impair the polarization plane controlled by the liquid crystal layer. It is necessary to use a small transparent film material, and it is difficult to apply a highly versatile film material. However, when the linearly polarizing plate 13F functioning as a linearly polarizing plate is provided on the liquid crystal layer 14 side of the base material 23A as in this embodiment, the transmitted light of the liquid crystal layer 14 is variously polarized by the base material 23A. However, the light transmitted through the linearly polarizing plate 13F can be prevented from affecting the polarization plane, and thus a film material having a large optical anisotropy such as a PET film is applied to the base material 23A. It is also possible to use a transparent film material with high versatility.

  In this embodiment, even when a negative C plate layer is provided only on one side of the liquid crystal layer 14, the configuration on this one side can be simplified and the thickness can be reduced. On the other side, by providing a coating-type linear polarizing plate on the substrate liquid crystal layer side, a transparent film material having high versatility can be applied to the substrate to simplify the overall configuration and reduce the thickness. it can.

[Other Embodiments]
The specific configuration suitable for the implementation of the present invention has been described in detail above, but the present invention is combined with the above-described embodiments and further modified in various ways without departing from the spirit of the present invention. can do.

  That is, in the above-described embodiment, the case where the spacer is formed by the column shape using the photoresist is described. However, the present invention is not limited to this, and a so-called bead spacer may be applied.

10, 20 Light control film 12 Lower laminate (first laminate)
12A negative C plate layer 12B, 12C, 12E, 13B, 13E hard coat layer 12D first linear polarizing plate 12F first transparent electrode 12G first alignment layer 13A negative C plate layer 13F second linear polarizing plate 13C second 2 transparent electrodes 13D 2nd alignment layer 13, 23 Upper side laminated body (2nd laminated body)
14 Liquid crystal layer 15 Spacer

Claims (6)

A first laminate including a first transparent electrode, a first alignment layer, and a first linearly polarizing plate;
A second laminate comprising a second transparent electrode, a second alignment layer, a second linearly polarizing plate;
In the dimming film by the VA method in which the liquid crystal layer is sandwiched by and the amount of transmitted light is varied by driving with the first and second transparent electrodes,
The first laminate is
It has a transparent film material that functions as a negative C plate layer,
The transparent film material is provided with the first transparent electrode, the first alignment layer, and the first linear polarizing plate,
The light control film, wherein the first linear polarizing plate and the second linear polarizing plate are E-type linear polarizing plates. The transparent film material is a transparent resin film.
The light control film of Claim 1. The first laminate is
The first transparent electrode and the first alignment layer are sequentially provided on the liquid crystal layer side of the transparent film material,
Wherein the opposite side to the liquid crystal layer side, the light control film of claim 1 or claim 2 wherein the first linear polarizer is provided in the transparent film material. The second laminate is
It has a transparent film material that functions as a negative C plate layer,
The second transparent electrode and the second alignment layer are sequentially provided on the liquid crystal layer side of the transparent film material,
The opposite side of the liquid crystal layer side of the transparent film material, the second linear polarizing plate that is provided
Dimming film according to 請 Motomeko 3. The second laminate is
The liquid crystal layer side of the transparent film material, the second transparent electrode, the second linear polarizer, the second alignment layer that are sequentially provided
Dimming film according to 請 Motomeko 3. In the manufacturing method of the light control film by VA system,
A first laminate production step of producing a first laminate comprising a first transparent electrode, a first alignment layer, and a first linearly polarizing plate;
A second laminate production step of producing a second laminate comprising a second transparent electrode, a second alignment layer, and a second linearly polarizing plate;
A laminating step of laminating the first and second laminates with a liquid crystal layer interposed therebetween,
The first laminate manufacturing step includes
The first transparent electrode and the first alignment layer are sequentially formed on one surface of a transparent film material functioning as a negative C plate layer, and the first surface by a coating mold is formed on the other surface of the transparent film material. 1 linear polarizing plate ,
The second laminate manufacturing step includes
The second transparent electrode and the second alignment layer are sequentially formed on one surface of the transparent film material, and the second linear polarizing plate by a coating mold is formed on the other surface of the transparent film material. A method for producing a light control film.

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