JP5994260B2 - Lid material - Google Patents

Description

  The present invention relates to a lid material that is easily opened by delamination between an intermediate layer and a seal layer, and a package using the same.

  2. Description of the Related Art Conventionally, containers having various forms have been developed for filling and packaging various foods and drinks, chemical products such as liquid detergents, cosmetics, pharmaceuticals, miscellaneous goods, industrial members, and the like.

  The lid material that seals the opening of the container is required to have both a sealing property that reliably protects the quality of the contents and an easy-opening property that can be easily opened when consumed, that is, an easy peel property. The

  As lid materials that satisfy this requirement, materials having various layer configurations have been proposed, and there are several types depending on the mechanism of opening.

  Among them, the delamination type lid material has a sealant composed of at least two layers of a seal layer and an intermediate layer adjacent to the seal layer, and the package sealed with the lid material is opened by an initial opening force. This is achieved by breaking the seal layer in the vicinity of the outer peripheral edge of the seal portion, then peeling between the seal layer and the intermediate layer, and then breaking the seal layer in the vicinity of the inner peripheral edge of the seal portion.

  The force required to open the delamination-type lid material, that is, the peel strength (peel strength) is determined by the interlayer adhesive strength between the seal layer and the intermediate layer, and the adhesive strength between the seal layer and the adherend of the container is Do not depend. Therefore, even if there are variations in the heat sealing conditions at the time of sealing, the peel strength is constant, so this type of lid material can exhibit stable easy-openability.

  As a delamination-type lid material, for example, in Patent Document 1, a sealant seal layer is made of a blend polymer of an ethylene-unsaturated carboxylic acid (or ester thereof) copolymer and polyethylene or polypropylene, and the seal layer. An intermediate layer adjacent to is made of an ethylene-unsaturated carboxylic acid (or ester thereof) copolymer.

  Further, Patent Document 2 is characterized in that the sealant seal layer is made of polyethylene, and the intermediate layer adjacent to the seal layer is made of a blend polymer of ethylene-methacrylic acid copolymer (EMAA) and polypropylene. A lid material is disclosed.

  The lid materials according to these patent documents have a layer made of a blend polymer of two types of resins having different extrusion temperature zones. When such a layer is adjusted to one of the extrusion temperature zones, the other resin Therefore, there is a problem in that a bad odor may be generated after film formation.

  In addition, in the delamination type lid material, if the seal layer is thickened, the initial opening resistance (strength) required when opening the package, that is, the force necessary to break the seal layer first increases. It is known that the opening does not proceed smoothly and the easy opening is impaired. Therefore, in this type of lid material, it is necessary to make the seal layer as thin as possible and to be several μm or less. However, in order to uniformly mold the thermoplastic resin forming the seal layer with such a thin thickness, thorough process control is essential, and the manufacturing cost is greatly increased.

JP-A-5-212835 JP 2002-283513 A

  The present invention solves the above-mentioned problems, and is a delamination-type lid material that has excellent sealing properties and easy-opening properties, is excellent in moldability, has a high degree of freedom in the manufacturing process, and is excellent in economy. It aims at providing the used package.

  As a result of various studies, the inventor has studied a combination of resins constituting the seal layer and the intermediate layer adjacent to the seal layer, and used a combination of specific types of resins, and further, in the resin forming the seal layer, It has been found that the above object can be achieved by adding an inorganic filler.

  That is, in a lid made of a laminate having a base layer, an intermediate layer, and a seal layer adjacent to the intermediate layer in this order, the intermediate layer is a layer made of EMAA, and the seal layer is made of polyethylene resin and It has been found that the above-mentioned lid material and a package using the same, which are layers composed of a resin composition containing an inorganic filler, achieve the above-mentioned object.

The present invention is characterized by the following points.
1. In a lid member made of a laminate having a base material layer, an intermediate layer, and a seal layer adjacent to the intermediate layer in this order, the intermediate layer is a layer made of EMAA, and the seal layer is made of a polyethylene resin and an inorganic filler The said cover material characterized by being a layer which consists of a resin composition containing this.
2. 2. The lid material according to 1 above, wherein the intermediate layer has a thickness of 10 to 100 μm, and the seal layer has a thickness of 1 to 30 μm.
3. The said inorganic filler is 1-30 micrometers in average particle diameter, and is contained in the said resin composition in the ratio of 10-60 mass%, The cover material of said 1 or 2 characterized by the above-mentioned.
4). The polyethylene resin is a high pressure method low density polyethylene (homopolymer of ethylene produced by the high pressure method, hereinafter referred to as “LDPE”) having a melt flow rate (MFR: 190 ° C., 2.16 kg load) of 15 to 80 g / 10 min. 4. The lid material according to any one of the above 1 to 3, wherein
5. The said intermediate | middle layer and a sealing layer are laminated | stacked on a base material layer by the coextrusion coating method, The lid | cover material in any one of said 1-4 characterized by the above-mentioned.
6). The lid material according to any one of 1 to 5 above, wherein the peeling from the sealed object heat-sealed through the sealing layer is performed by delamination between the sealing layer and the intermediate layer. .
7). The lid material according to any one of 1 to 6 above, and a container having a flange portion coated with a polyethylene resin on the surface, the lid material and the container, the surface of the sealing layer of the lid material being a container A package that is overlapped and heat-sealed to face the flange.

  The lid material of the present invention is a delamination-type lid material, and is characterized by having a combination of a seal layer made of a resin composition containing a polyethylene resin and an inorganic filler and an intermediate layer made of EMAA. In the lid material of the present invention, the sealing layer forms the outermost surface on the side in contact with the adherend surface of the container, that is, the innermost layer surface of the package, is melted by heat sealing, and the adherend surface of the container It is a layer to be bonded. In addition, the intermediate layer is present adjacent to the seal layer, serves as a cushion during heat sealing, and seals the contents without generating a gap even when the container is uneven. It is a layer for.

  In the lid material of the present invention, each of the intermediate layer and the seal layer is made of one type of resin and does not contain a significant amount of different kinds of resins having different extrusion temperature zones. Therefore, the lid material of the present invention is excellent in moldability, does not generate off-flavors, and can be used for a wide range of contents such as foods and pharmaceuticals without limiting the packaging application.

  In the production of the lid of the present invention, a combination of a specific resin and a resin composition is used as an intermediate layer and a seal layer of a sealant, and these layers have a layer thickness of 10 to 100 μm, Co-extrusion is performed so that the layer thickness is 1 to 30 μm. As a result, a seal layer having a specific breaking strength (that is, a layer made of a resin composition containing a polyethylene resin and an inorganic filler) and an intermediate layer (that is, an EMAA layer) bonded to the seal layer with a specific interlayer adhesive strength are formed. As a result, the lid material of the present invention exhibits excellent easy-openability at the time of opening, while exhibiting high hermeticity that can withstand distortion caused during transportation and storage.

  In the lid material of the present invention, the seal layer is made of a resin composition containing polyethylene and an inorganic filler. This makes it possible to provide a thick seal layer without increasing the initial opening resistance, increase the sealing performance without impairing the easy opening, and eliminate the need for strict process control. Can be reduced.

  Furthermore, when the lid material according to the present invention heat-seals the lid material, for example, on the flange portion of the plastic molded container, for example, the seal includes a portion in which the flange portion of the plastic molded container protrudes in a convex shape or the like. In the case of the part, even if the lid material is heat-sealed with a ring seal, the sealing layer is not pierced and good sealability and easy-openability can be obtained.

  In addition, when the sealing area of the flange portion of the plastic molded container is small, even if the lid material is heat-sealed with a ring seal, the hermeticity does not become unstable, and it has a very good hermeticity. is there.

  That is, the lid material of the present invention is excellent in heat sealability and can sufficiently satisfy its sealability, and satisfies the requirements for protecting the quality of the contents, extending the storage period, etc. It has excellent openability so that the packaging bag can be easily opened at the time of consumption, and can be applied as a lid material for various plastic molded containers.

  Furthermore, EMAA, which forms the intermediate layer in the lid material of the present invention, has a carboxyl group derived from methacrylic acid in the molecular chain. Can be combined. For this reason, in the lid material of the present invention, even when a metal film or a vapor deposition film is used as the base material layer, a new adhesive layer is provided between the base material layer and the intermediate layer, It is not necessary to perform a surface treatment for increasing the thickness, and high interlayer adhesion can be obtained by laminating the intermediate layer and the seal layer directly on the base material layer by coextrusion coating.

  Therefore, the lid material of the present invention can be widely applied to the packaging of various contents such as foods and medicines because the components of the adhesive do not elute into the contents.

It is a schematic sectional drawing which shows the example about the layer structure of the laminated body which comprises the cover material of this invention. It is a schematic sectional drawing which shows the example about the layer structure of the laminated body which comprises the cover material of this invention. It is a schematic sectional drawing which shows the layer structure of the example about the package manufactured using the cover material of this invention.

The above-described present invention will be described in more detail below.
Hereinafter, the resin names used in the present invention are those commonly used in the industry.
In the present invention, the melt flow rate (MFR) is a value measured by a method based on JIS K6922 and is a value measured at 190 ° C. and a 2.16 kg load unless otherwise specified.

  In the present invention, the density is measured by a method based on JIS K7112.

<I> Layer structure of a laminated body constituting a lid member and a package manufactured using the same FIG. 1 is a schematic cross-sectional view showing an example of a layer structure of a laminated body constituting a lid member of the present invention. .
As shown in FIG. 1, the laminate constituting the lid of the present invention comprises a sealant 1 and a base material layer 4, and the sealant 1 comprises a seal layer 2 comprising a resin composition containing a polyethylene resin and an inorganic filler. And an intermediate layer 3 made of EMAA. In order to seal the container using the lid material of the present invention, the adhesive surface P on the seal layer 2 side is overlapped so as to face the adherend surface of the container and heat sealed.

  In another aspect, as shown in FIG. 2, the laminate constituting the lid material of the present invention includes, as the base material layer 4, a base film 4 a made of paper or a resin film, and a gas barrier made of aluminum foil or the like. A multilayer laminated film having the conductive film 4b can also be used.

FIG. 3 is a schematic cross-sectional view showing an example of the layer structure of a package manufactured using the lid material of the present invention.
As shown in FIG. 3, the adhesive surface P on the seal layer 2 side of the lid material A of the present invention is opposed to the attachment surface Q of the flange portion 13 of the opening portion of the container 11 filled with the contents 12. The package B of the present invention is manufactured by overlapping and heat-sealing. The adherend surface Q of the flange portion 13 is coated with a polyethylene resin, and is fused with the polyethylene resin forming the seal layer 2 to exhibit excellent seal stability and foreign matter sealability.

<II> Base material layer In the present invention, as the base material layer, an arbitrary base material that retains strength necessary for a lid, heat resistance at the time of sealing, dead hold property, flatness, etc., depending on the packaging application. Can be used. Examples of the substrate suitably used in the present invention include various papers such as imitation paper, clay coated paper, kraft paper, paperboard, synthetic paper, polyester resin film, polyamide resin film, polyolefin resin film, and the like. These various resin films, vapor-deposited films having a vapor-deposited layer such as metal oxide, metal films such as aluminum foil, other various barrier films, light-shielding films, and multilayer laminated films obtained by laminating these films. Lamination of the film can be performed by any method.

The layer thickness of the base material layer can be appropriately determined by those skilled in the art depending on the packaging application.
Moreover, what is necessary is just to give various surface treatments, such as a corona discharge process, a chemical | medical agent process, and an ozone process, or to coat an anchor coat agent and an adhesive agent on the intermediate | middle layer lamination surface of a base material layer.
Furthermore, on the surface opposite to the intermediate layer lamination surface of the base material layer, an additional layer, for example, an arbitrary printed picture layer such as a character and a picture, and a surface protective layer for protecting the layer can be provided as desired. .

<III> Intermediate layer In the lid material of the present invention, the intermediate layer follows the unevenness of the adherend surface when heat-sealing the lid material, and at the same time functions as a cushion layer to supplement the sealing performance. It also functions as an adhesive layer between the sealing layer and the base material layer laminated.

  In the present invention, the intermediate layer is a layer made of EMAA. EMAA used preferably has an MFR of 2 to 30 g / 10 min, more preferably 6 to 15 g / 10 min. If the MFR is less than 2 g / 10 min, co-extrusion with the seal layer cannot be performed. On the other hand, if it is larger than 30 g / 10 minutes, the neck-in becomes large and narrow width and uneven thickness are likely to occur. In particular, by co-extruding EMAA with an MFR of 6 to 15 g / 10 min with the resin composition forming the seal layer, the intermediate layer and the seal layer are laminated with suitable adhesive strength, and excellent easy-openability can get.

  The ratio of the structural unit derived from ethylene and the structural unit derived from methacrylic acid in EMAA can be arbitrarily determined by those skilled in the art depending on the type of the base material layer and the use of the lid. Since the ratio of the structural unit derived from methacrylic acid is large and the number of carboxyl groups contained in the structural unit is large, the polarity is increased, so that the adhesive strength with the metal is increased. Moreover, the odor of resin is suppressed, so that there are many ratios of the structural unit derived from ethylene.

  In the lid material of the present invention, the thickness of the intermediate layer is preferably 10 to 100 μm, more preferably 25 to 60 μm. When the thickness of the intermediate layer is less than 10 μm, it cannot follow the unevenness of the adherend surface, for example, the joint formed by pasting the paste margin of the paper container, and does not function as a cushion layer. On the other hand, when the layer thickness exceeds 100 μm, it becomes difficult to form a film with a uniform film thickness.

<IV> Seal Layer In the lid material of the present invention, the seal layer is a layer that forms the outermost surface on the side in contact with the adherend surface of the container, that is, the innermost layer of the package, and is melted by heat sealing. Then, it adheres to the polyethylene resin layer coated on the adherend surface of the container.
In the present invention, the seal layer is made of a resin composition containing a polyethylene resin and an inorganic filler.

As the polyethylene resin, any polyethylene such as low density, medium density or high density polyethylene can be used, and a homopolymer, copolymer or graft polymer can be used, but preferably the density is 0.900 to 0.930 g. / cm ³ of low density polyethylene, in particular LDPE with an MFR of 15-80 g / 10 min, more preferably 15-40 g / 10 min.

  By using this LDPE, a high and stable seal strength with the adherend surface of the container and a suitable peel strength with the intermediate layer can be obtained. When the MFR of LDPE is less than 15 g / 10 minutes, the breaking strength of the sealing layer is increased, so that the initial opening resistance required when opening the package, that is, the force necessary to break the sealing layer first. Large, easy-openability is impaired. On the other hand, when the MFR of LDPE is larger than 80 g / 10 minutes, the film forming property is inferior.

  As inorganic fillers, titanium oxide, potassium titanate, barium sulfate, zinc oxide, zinc white, aluminum powder, alumina, aluminum hydroxide, magnesium oxide, magnesium hydroxide, boron nitride, molybdenum disulfide, antimony trioxide, cerium oxide , Heavy calcium carbonate, light calcium carbonate, natural silica, synthetic silica, glass, shirasu, kaolin, clay, talc, mica, wollastonite, sepiolite, ferrite, zonolite, montmorillonite, hydrotalcite, zeolite, tungsten, Examples include stainless steel, lead powder, iron powder, Teflon powder, graphite, charcoal, bamboo charcoal, activated carbon, activated clay, resin balloon, carbon fiber, catechin, etc. You can choose.

The shape of the inorganic filler is not particularly limited, and may be any of a spherical shape, a rod shape, a needle shape, a flat plate shape, a bead shape, a hollow shape, and a combination thereof.
Among the inorganic fillers according to the present invention, a spherical shape is preferable from the viewpoints of suppressing variation in peelability and sealing strength.

  Moreover, as an average particle diameter of an inorganic filler, from a peelable and film forming viewpoint, it becomes like this. Preferably it is 1-30 micrometers, More preferably, it is 5-15 micrometers. When the average particle size of the inorganic filler is less than 1 μm, the easy peeling effect is lost, and when it is greater than 30 μm, the film thickness is larger than the film thickness, which adversely affects the film forming property. In the present invention, the average particle size of the inorganic filler is the particle size at an integrated value of 50% in the particle size distribution measured by the laser diffraction scattering method.

Moreover, 10-60 mass%, More preferably, 15-50 mass%, More preferably, 15-30 mass% of an inorganic filler is mix | blended in the resin composition which forms a sealing layer. If the blending ratio of the inorganic filler is less than 10% by mass, the effect of suppressing the increase in initial opening resistance caused by increasing the thickness of the seal layer cannot be obtained sufficiently. On the other hand, if it is more than 60% by mass, sufficient seal strength cannot be obtained.
The inorganic filler can be easily and uniformly dispersed in the polyethylene resin using a mixer or a blender.

  In the lid material of the present invention, the seal layer has a thickness of 1 to 30 μm, for example, 1 to 20 μm, preferably 3 μm or more, more preferably 5 μm or more. If the thickness of the sealing layer is less than 1 μm, it is difficult to form a uniform film, and sufficient sealing performance as the sealing layer cannot be provided. If it is thicker than 30 μm, even if an inorganic filler is blended, the initial opening resistance becomes too large and the easy-opening property is impaired.

  Furthermore, if the sealing layer is thinner than 3 μm, even if it does not contain an inorganic filler, the initial opening resistance is suppressed to a range that can be easily opened by hand, but strict process control is essential for film formation, Manufacturing costs are greatly increased. Moreover, it is not preferable because the seal to the container having the line seal protrusion flange becomes unstable.

  In the present invention, it is also possible to provide the seal layer with a thickness of 5 μm or more. The seal layer having such a layer thickness can be stably formed without requiring strict process control, and can provide high sealing performance.

<V> Manufacture of Laminate Constructing Cover Material In the manufacture of the laminate composing the cover material of the present invention, the sealant composed of the intermediate layer and the seal layer is obtained by replacing the resin and resin composition as materials of each layer with T Using a die coextrusion machine or a coextrusion inflation film forming machine, the film is formed by coextrusion. Here, the laminated body which comprises the cover material of this invention is manufactured by forming the coextruded film which consists of an intermediate | middle layer and a sealing layer, and dry-laminating this with the film which forms a base material layer. Can do.

Moreover, when a base material layer consists of a resin film, three layers, a base material layer, an intermediate | middle layer, and a sealing layer, can also be formed into a film by coextrusion.
Alternatively, the laminate may be produced by directly laminating the intermediate layer and the seal layer on the film forming the base material layer by a coextrusion coating method.

  In the present invention, since the intermediate layer is made of EMAA that can be strongly and stably bonded to paper or metal, when the substrate layer is paper, or a metal film such as aluminum foil, or a metal or inorganic oxide Even when a barrier film made of a vapor deposition film or the like is included, the intermediate layer and the seal layer can be laminated directly on the base material layer by coextrusion coating. Here, it is not necessary to newly provide an adhesive layer between the base material layer and the intermediate layer or to perform a surface treatment for increasing the adhesive force.

<VI> Production of Lid and Packaging The lid of the present invention is produced by punching the laminate obtained as described above according to the shape of the flange provided around the opening of the container. The

  In actual manufacturing, in addition to being manufactured as a single-sheet lid material punched in advance according to the shape of the opening of the container, the wound lid material is supplied to the filling seal device to fill the contents. In many cases, it is manufactured by a method of punching into individual shapes in-line after heat-sealing to the flange at the periphery of the opening of the container, and any method can be used.

The package of the present invention can be manufactured by superposing the surface of the sealing layer of the lid material so as to face the flange portion of the container filled with the contents and heat-sealing. Here, the flange portion of the container is coated with polyethylene resin.
Examples of the contents enclosed in the package of the present invention include various foods and drinks, chemical products such as liquid detergents, cosmetics, pharmaceuticals, miscellaneous goods, industrial members, and the like, but are not limited thereto.

In addition, as the container, containers having various shapes such as various square shapes, round shapes, pyramid shapes, conical shapes and the like can be used depending on the purpose, application, and the like, and the attachment surface of the flange portion As long as is coated with a polyethylene resin, the other portions may be made of any material.
In the present invention, the heat sealing method between the lid member and the container can be performed by a known method such as a bar seal, a rotary roll seal, a belt seal, an impulse seal, a high frequency seal, an ultrasonic seal, and the like. .

  Next, the present invention will be described in more detail with reference to specific examples.

[Example 1]
The clay-coated paper and the aluminum foil were laminated by a sandwich lamination method through LDPE having an MFR of 8 g / 10 min and a melting point of 105 ° C. to obtain a base film.

  Next, a polyurethane-based anchor coating agent was coated on the aluminum foil side surface of the base film obtained above by a gravure roll coating method to form an anchor coating agent layer.

  On the other hand, 70 parts by mass of LDPE having an MFR of 45 g / 10 minutes and a melting point of 105 ° C. and an inorganic filler-containing masterbatch (MFR 45 g / 10 minutes, LDPE having a melting point of 105 ° C., natural silica (average particle size 5 μm) content of 40% by mass) are 30 masses. The resin composition which comprises a part and a sealing layer was prepared. The natural silica content in the resin composition was 12% by mass.

  Next, on the surface of the anchor coating agent layer on the substrate film obtained above, MFR 9 g / 10 minutes forming an intermediate layer, EMAA having a melting point of 99 ° C. (Nucle (R) N0908N manufactured by Mitsui DuPont Polychemical Co., Ltd.) and The above-mentioned resin composition for forming the seal layer was laminated by coextrusion coating so that the layer thickness was 40 μm for the intermediate layer and 10 μm for the seal layer, to produce a laminate constituting the lid material of the present invention. The extrusion temperature of the intermediate layer was 280 ° C., the extrusion temperature of the seal layer was 250 ° C., and the die temperature was 260 ° C. The extrusion line speed was 80 m / min.

The layer structure of the obtained laminate was as follows: clay coated paper (basis weight 110 g / m ² ) / LDPE layer (layer thickness 10 μm) / aluminum foil (thickness 9 μm) / anchor coating agent layer ( Dry layer thickness 1 μm) / intermediate layer (layer thickness 40 μm) / sealing layer (layer thickness 10 μm).

  Next, this laminated body was punched out in a shape having a circular shape of 100 mm in diameter and provided with a knob piece on a part of the outer periphery to produce the lid material of the present invention.

  Prepare the obtained lid and a paper cup (200 cc, 82 mm in diameter) coated with 20 μm thick LDPE on the innermost surface so that the surface of the sealing layer of the lid faces the flange on the periphery of the opening of the container Then, using a ring sealer, heat sealing was performed under the conditions of a sealing temperature of 160 ° C., a pressure of 100 kPa, and a time of 1 second to produce a package.

[Example 2]
In the same manner as in Example 1, a base film having a layer configuration of clay coated paper / LDPE layer / aluminum foil was obtained.

  On the other hand, 20 parts by mass of LDPE having an MFR of 55 g / 10 minutes and a melting point of 105 ° C. and an inorganic filler-containing master batch (MFR 55 g / 10 minutes, content of natural silica (average particle size 10 μm) in LDPE having a melting point of 105 ° C. of 45% by mass) are 80 masses. The resin composition which comprises a part and a sealing layer was prepared. The natural silica content in the resin composition was 36% by mass.

  Then, MFR 9 g / 10 minutes forming an intermediate layer directly on the surface of the aluminum foil on the base film obtained above, EMAA having a melting point of 99 ° C. (Nucle (R) N0908N manufactured by Mitsui DuPont Polychemical), The above resin composition for forming the seal layer was laminated by coextrusion coating so that the layer thickness was 30 μm for the intermediate layer and 8 μm for the seal layer, to produce a laminate constituting the lid material of the present invention. The extrusion temperature of the intermediate layer was 280 ° C., the extrusion temperature of the seal layer was 250 ° C., and the die temperature was 260 ° C. The extrusion line speed was 80 m / min.

The layer structure of the obtained laminate was as follows: clay-coated paper (basis weight 110 g / m ² ) / LDPE layer (layer thickness 10 μm) / aluminum foil (thickness 9 μm) / intermediate layer (layer thickness) 30 μm) / sealing layer (layer thickness 8 μm).
Then, using this laminate, the lid material and package of the present invention were produced in the same manner as in Example 1.

[Example 3]
In the same manner as in Example 1, a base film having a layer configuration of clay coated paper / LDPE layer / aluminum foil was obtained.

  On the other hand, 70 parts by mass of LDPE having an MFR of 20 g / 10 min and a melting point of 106 ° C. and an inorganic filler-containing master batch (MFR 20 g / 10 min, content of natural silica (average particle size 5 μm) in LDPE having a melting point of 106 ° C. of 40% by mass) are 30 masses. The resin composition which comprises a part and a sealing layer was prepared. The natural silica content in the resin composition was 12% by mass.

  Then, MFR 9 g / 10 minutes forming an intermediate layer directly on the surface of the aluminum foil on the base film obtained above, EMAA having a melting point of 99 ° C. (Nucle (R) N0908N manufactured by Mitsui DuPont Polychemical), The above resin composition for forming the seal layer was laminated by coextrusion coating so that the layer thickness was 35 μm for the intermediate layer and 10 μm for the seal layer, to produce a laminate constituting the lid material of the present invention. The extrusion temperature of the intermediate layer was 280 ° C., the extrusion temperature of the seal layer was 250 ° C., and the die temperature was 260 ° C. The extrusion line speed was 80 m / min.

The layer structure of the obtained laminate was as follows: clay-coated paper (basis weight 110 g / m ² ) / LDPE layer (layer thickness 10 μm) / aluminum foil (thickness 9 μm) / intermediate layer (layer thickness) 35 μm) / sealing layer (layer thickness 10 μm).
Then, using this laminate, the lid material and package of the present invention were produced in the same manner as in Example 1.

[Example 4]
In the same manner as in Example 1, a base film having a layer configuration of clay coated paper / LDPE layer / aluminum foil was obtained.

  On the other hand, 70 parts by mass of LDPE having an MFR of 55 g / 10 minutes and a melting point of 105 ° C. and an inorganic filler-containing master batch (MFR 55 g / 10 minutes, content of calcium carbonate (average particle size 30 μm) in LDPE having a melting point of 105 ° C. of 40% by mass) are 30 masses. The resin composition which comprises a part and a sealing layer was prepared. The calcium carbonate content in the resin composition was 12% by mass.

  Then, MFR 9 g / 10 minutes forming an intermediate layer directly on the surface of the aluminum foil on the base film obtained above, EMAA having a melting point of 99 ° C. (Nucle (R) N0908N manufactured by Mitsui DuPont Polychemical), The above resin composition for forming the seal layer was laminated by coextrusion coating so that the layer thickness was 30 μm for the intermediate layer and 8 μm for the seal layer, to produce a laminate constituting the lid material of the present invention. The extrusion temperature of the intermediate layer was 280 ° C., the extrusion temperature of the seal layer was 250 ° C., and the die temperature was 260 ° C. The extrusion line speed was 80 m / min.

The layer structure of the obtained laminate was as follows: clay-coated paper (basis weight 110 g / m ² ) / LDPE layer (layer thickness 10 μm) / aluminum foil (thickness 9 μm) / intermediate layer (layer thickness) 30 μm) / sealing layer (layer thickness 8 μm).
Then, using this laminate, the lid material and package of the present invention were produced in the same manner as in Example 1.

[Example 5]
In the same manner as in Example 1, a base film having a layer configuration of clay coated paper / LDPE layer / aluminum foil was obtained.

  On the other hand, 70 mass parts of LDPE having an MFR of 55 g / 10 min and a melting point of 105 ° C. and an inorganic filler-containing master batch (MFR 55 g / 10 min, LDPE having an melting point of 105 ° C., content of natural silica (average particle size 10 μm) of 50 mass%) are 30 mass The resin composition which comprises a part and a sealing layer was prepared. The natural silica content in the resin composition was 15% by mass.

  Then, MFR 9 g / 10 minutes forming an intermediate layer directly on the surface of the aluminum foil on the base film obtained above, EMAA having a melting point of 99 ° C. (Nucle (R) N0908N manufactured by Mitsui DuPont Polychemical), The above resin composition for forming the seal layer was laminated by coextrusion coating so that the layer thickness was 30 μm for the intermediate layer and 8 μm for the seal layer, to produce a laminate constituting the lid material of the present invention. The extrusion temperature of the intermediate layer was 280 ° C., the extrusion temperature of the seal layer was 250 ° C., and the die temperature was 260 ° C. The extrusion line speed was 80 m / min.

The layer structure of the obtained laminate was as follows: clay-coated paper (basis weight 110 g / m ² ) / LDPE layer (layer thickness 10 μm) / aluminum foil (thickness 9 μm) / intermediate layer (layer thickness) 30 μm) / sealing layer (layer thickness 8 μm).

  Then, using this laminate, the lid material and package of the present invention were produced in the same manner as in Example 1.

[Example 6]
In the same manner as in Example 1, a base film having a layer configuration of clay coated paper / LDPE layer / aluminum foil was obtained.

  Meanwhile, MFR 55 g / 10 minutes, LDPE 30 parts by mass with a melting point of 105 ° C., and inorganic filler-containing master batch (MFR 55 g / 10 minutes, melting point 105 ° C. LDPE, natural silica (average particle size 20 μm) content 30% by mass) 70 mass The resin composition which comprises a part and a sealing layer was prepared. The natural silica content in the resin composition was 21% by mass.

  Then, MFR 9 g / 10 minutes forming an intermediate layer directly on the surface of the aluminum foil on the base film obtained above, EMAA having a melting point of 99 ° C. (Nucle (R) N0908N manufactured by Mitsui DuPont Polychemical), The above resin composition for forming the seal layer was laminated by coextrusion coating so that the layer thickness was 30 μm for the intermediate layer and 8 μm for the seal layer, to produce a laminate constituting the lid material of the present invention. The extrusion temperature of the intermediate layer was 280 ° C., the extrusion temperature of the seal layer was 250 ° C., and the die temperature was 260 ° C. The extrusion line speed was 80 m / min.

The layer structure of the obtained laminate was as follows: clay-coated paper (basis weight 110 g / m ² ) / LDPE layer (layer thickness 10 μm) / aluminum foil (thickness 9 μm) / intermediate layer (layer thickness) 30 μm) / sealing layer (layer thickness 8 μm).
Then, using this laminate, the lid material and package of the present invention were produced in the same manner as in Example 1.

[Example 7]
In the same manner as in Example 1, a base film having a layer configuration of clay coated paper / LDPE layer / aluminum foil was obtained.

  On the other hand, 50 mass parts of LDPE having an MFR of 55 g / 10 minutes and a melting point of 105 ° C. and an inorganic filler-containing master batch (MFR 55 g / 10 minutes, LDPE having a melting point of 105 ° C., content of natural silica (average particle size 10 μm) 40 mass%) 50 mass The resin composition which comprises a part and a sealing layer was prepared. The natural silica content in the resin composition was 20% by mass.

  Then, MFR 9 g / 10 minutes forming an intermediate layer directly on the surface of the aluminum foil on the base film obtained above, EMAA having a melting point of 99 ° C. (Nucle (R) N0908N manufactured by Mitsui DuPont Polychemical), The above resin composition forming the seal layer was laminated by coextrusion coating so that the layer thickness was 60 μm for the intermediate layer and 8 μm for the seal layer, to produce a laminate constituting the lid material of the present invention. The extrusion temperature of the intermediate layer was 280 ° C., the extrusion temperature of the seal layer was 250 ° C., and the die temperature was 260 ° C. The extrusion line speed was 80 m / min.

The layer structure of the obtained laminate was as follows: clay-coated paper (basis weight 110 g / m ² ) / LDPE layer (layer thickness 10 μm) / aluminum foil (thickness 9 μm) / intermediate layer (layer thickness) 30 μm) / sealing layer (layer thickness 8 μm).
Then, using this laminate, the lid material and package of the present invention were produced in the same manner as in Example 1.

[Comparative Example 1]
Clay-coated paper (basis weight 110 g / m ² ) / LDPE layer (layer thickness) in the same manner as in Example 2 except that the sealing layer does not contain natural silica and consists of only LDPE having an MFR of 55 g / 10 min and a melting point of 105 ° C. A laminate having a layer structure of 10 μm) / aluminum foil (thickness 9 μm) / intermediate layer (layer thickness 30 μm) / sealing layer (layer thickness 8 μm) was obtained.
Then, using this laminate, a lid and a package were produced in the same manner as in Example 1.

[Comparative Example 2]
The clay-coated paper (tsubo A laminate having a layer configuration of 110 g / m ² ) / LDPE layer (layer thickness 10 μm) / aluminum foil (thickness 9 μm) / intermediate layer (layer thickness 35 μm) / sealing layer (layer thickness 10 μm) was obtained.
Then, using this laminate, a lid and a package were produced in the same manner as in Example 1.

[Comparative Example 3]
Clay-coated paper (basis weight 110 g / m ² ) / LDPE layer (layer thickness 10 μm) in the same manner as in Example 3 except that natural silica having an average particle diameter of 40 μm was used instead of natural silica having an average particle diameter of 5 μm. ) / Aluminum foil (thickness 9 μm) / intermediate layer (layer thickness 35 μm) / seal layer (layer thickness 10 μm). Film cracking occurred during film formation.

[Evaluation]
About the packaging body obtained in Examples 1-7 and Comparative Examples 1-3, the easy-opening property, the unsealing feeling, and the unsealing appearance were evaluated by the following references | standards. The results are shown in Table 1.
(Evaluation of easy opening)
According to the burst strength test of the container defined in JIS Z0238, the pressure (unit: kPa) at the time of burst (the heat seal part was opened and air leakage occurred) was measured.
(Evaluation of opening feeling and opening appearance)
About each package, the touch at the time of opening was determined, and the external appearance of the seal part after opening was evaluated visually.

  As is clear from the results shown in Table 1, the laminates of Examples 1 to 7 showed moderate sealing properties and good easy-opening properties. Moreover, after peeling, a beautiful peeling surface was obtained by peeling between the seal layer / intermediate layer.

  On the other hand, since the laminated body of Comparative Example 1 had a thick seal layer and did not contain an inorganic filler, it was difficult to open and the lid material was torn and remained in the opening. Moreover, since the MFR of LDPE which forms a sealing layer was large, the laminated body of the comparative example 2 did not progress smoothly of a sealing layer, but required big force for opening. Moreover, since the average particle diameter of the inorganic filler contained in the sealing layer was large in the laminate of Comparative Example 3, film cracking occurred during film formation.

1. Sealant2. 2. Seal layer Intermediate layer 4. Base material layer 4a. Base film 4b. 10. Gas barrier film Container 12. Contents 13. Flange A, A ₁ . Lid B. Package P.P. Adhesive surface of lid material Q. Adhered surface of flange

Claims (6)

In the cover material composed of the base material layer, the intermediate layer, and the laminate having the sealing layer adjacent to the intermediate layer in this order,
The intermediate layer is a layer made of an ethylene-methacrylic acid copolymer,
The seal layer is a layer made of a resin composition containing a polyethylene resin and an inorganic filler,
The layer thickness of the intermediate layer is 10 to 100 μm, the layer thickness of the seal layer is 1 to 30 μm,
The intermediate layer and the seal layer are each made of one kind of resin,
And the said filler is characterized by the average particle diameter of this inorganic filler being 1-30 micrometers.   The said inorganic filler is contained in the said resin composition in the ratio of 10-60 mass%, The cover material of Claim 1 characterized by the above-mentioned.   The lid according to claim 1 or 2, wherein the polyethylene resin is a high-pressure low-density polyethylene having a melt flow rate (MFR: 190 ° C, 2.16 kg load) of 15 to 80 g / 10 min. Wood.   The said intermediate | middle layer and a sealing layer are laminated | stacked on a base material layer by a coextrusion coating method, The manufacturing method of the cover material of any one of Claims 1-3 characterized by the above-mentioned.   The peeling from the to-be-sealed body heat-sealed through the said sealing layer is performed by the delamination of the said sealing layer and the said intermediate | middle layer, The any one of Claims 1-3 characterized by the above-mentioned. Cover material.   It consists of a lid | cover material of any one of Claims 1-3 and 5 and the container which has a flange part which coat | covered the polyethylene resin on the surface, This lid | cover material and this container are made into the sealing layer of this lid | cover material A package that is laminated and heat-sealed so that the surface of the container faces the flange of the container.

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