JP5989301B2 - seasoning - Google Patents
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- JP5989301B2 JP5989301B2 JP2011003930A JP2011003930A JP5989301B2 JP 5989301 B2 JP5989301 B2 JP 5989301B2 JP 2011003930 A JP2011003930 A JP 2011003930A JP 2011003930 A JP2011003930 A JP 2011003930A JP 5989301 B2 JP5989301 B2 JP 5989301B2
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- Seasonings (AREA)
Description
本発明は、酢酸の刺激臭を低減させる調味料に関する。 The present invention relates to a seasoning that reduces the pungent odor of acetic acid.
日本の家庭では酸味を生かした調味料として主に食酢が用いられている。近年では食酢の有する食欲増進効果、減塩効果、疲労回復効果などの健康機能性が脚光を浴び、食酢を含有する飲料や調味料が販売されている。酸味を生かした代表的な調味料として、土佐酢、三杯酢、甘酢などの合わせ酢(以下、「調味酢」という)の他、ぽん酢やドレッシング等が知られており、これらは醤油と組み合わせて使用されている。食酢としては穀物酢、米酢、玄米酢、粕酢、黒酢等の他、リンゴ酢やワイン酢、バルサミコ酢等が市販されており、好みや用途に応じて市場で入手可能である。しかし、一般的な食酢は揮発性有機酸である酢酸の刺激臭(以下、「酢酸臭」という)を有し、食酢が苦手な消費者も依然として多く、酢酸臭の低減が求められている。 In Japanese homes, vinegar is mainly used as a seasoning that takes advantage of acidity. In recent years, health functions such as an appetite promoting effect, a salt reducing effect, and a fatigue recovery effect of vinegar have been highlighted, and beverages and seasonings containing vinegar have been sold. As typical seasonings that make use of sourness, combined vinegars such as Tosa vinegar, three cups vinegar, sweet vinegar (hereinafter referred to as “seasoned vinegar”), ponzu vinegar and dressing are known, and these are used in combination with soy sauce Has been. As vinegar, grain vinegar, rice vinegar, brown rice vinegar, rice bran vinegar, black vinegar and the like, as well as apple vinegar, wine vinegar, balsamic vinegar and the like are commercially available, and are available on the market according to taste and use. However, general vinegar has an irritating odor (hereinafter referred to as “acetic acid odor”) of acetic acid, which is a volatile organic acid, and many consumers are not good at vinegar, and reduction of acetic acid odor is required.
酢酸臭を低減する方法として、調味料においては、食用有機酸にソトロンを含有させる方法(例えば、特許文献1参照)、黒酢入りぽん酢に昆布のだし汁を含有させる方法(例えば、特許文献2参照)が開示されている。これらの方法では、ソトロンまたはソトロンを含有する原料を食酢に含有させることで独特の香りや色が付与される、黒酢に対してのみ効果がある等、適用範囲が限られてしまう課題が残され、刺激臭の低減効果も未だ不十分であった。 As a method for reducing acetic acid odor, in a seasoning, a method of containing sotron in an edible organic acid (for example, see Patent Document 1), a method of incorporating kelp dashi soup in black vinegared vinegar (for example, see Patent Document 2) ) Is disclosed. In these methods, there is a problem that the scope of application is limited, for example, by adding sotron or a raw material containing sotron to vinegar to give a unique scent or color, or to be effective only for black vinegar. In addition, the effect of reducing the irritating odor was still insufficient.
また、酢酸0.1〜10%を飲食品に含有させる際に、香気成分としてヘキサナールを添加することにより酢酸臭を低減させる方法(例えば、特許文献3参照)も報告されているが、オフフレーバーであるヘキサナールを使用するため独特の異臭を呈することがあり、また強い香りを有する醤油を同時に用いる調味酢、ドレッシングの用途では、より酢酸臭が際立つことがあるため低減効果が不十分であった。 In addition, a method of reducing acetic acid odor by adding hexanal as an aroma component when 0.1 to 10% of acetic acid is contained in a food or drink has been reported (for example, see Patent Literature 3). Because it uses hexanal, it may have a unique off-flavor, and in the use of seasoned vinegar and dressing that uses soy sauce with a strong scent at the same time, the effect of reduction was insufficient because the acetic acid odor might be more conspicuous .
また防腐目的として、穀物加工食品に酢酸0.01〜0.06%と共にα−エチルグルコシドを0.00001〜0.001%含有させることにより酢酸の酸臭を低減する方法(例えば、特許文献4参照)が開示されている。飲料においては、黒酢と共にスクラロースを含有させる方法(例えば、特許文献5参照)、酸味料と共にグルカンを含有させる方法(例えば、特許文献6参照)が開示されているが、飲料であるため含有される酢酸濃度が低く、より高い配合量で酢酸を含有させる調味料においては刺激臭の低減効果は不十分であった。 For the purpose of preserving, a method for reducing the acid odor of acetic acid by adding 0.00001 to 0.001% of α-ethylglucoside together with 0.01 to 0.06% of acetic acid in the processed grain food (for example, Patent Document 4) Reference). In beverages, a method of containing sucralose together with black vinegar (for example, see Patent Document 5) and a method of containing glucan together with a sour agent (for example, see Patent Document 6) are disclosed. The effect of reducing the irritating odor was insufficient in the seasoning containing low acetic acid concentration and containing acetic acid at a higher blending amount.
最近になって、糖類や柑橘果汁を添加することで酢酸の刺激を緩和させた調味酢や、とろみ状・ゼリー状にすることで酢酸の刺激を緩和させた調味酢も販売され、従来品に比べ酢酸臭は改善されていると考えられるが、食品として摂取できる酢酸の量・濃度も低下している他、粘度が高いなど一般の食品と物性が異なる等の課題が残されており、刺激臭の低減効果もなお改良の余地があった。 Recently, seasoned vinegar with reduced acetic acid stimulation by adding saccharides and citrus juice, and seasoned vinegar with reduced acetic acid stimulation by making it thick and jelly-like are also sold. Although the acetic acid odor is thought to have improved, the amount and concentration of acetic acid that can be ingested as a food has decreased, and there are still problems such as high viscosity and different physical properties from general foods. There was still room for improvement in the odor reduction effect.
一方、トマトやワイン等に含有され、β−カロテンやリコペンを前駆体として生じる香気成分としてβ−ダマセノン、β―イオノン、6−メチル−5−ヘプテン−2−オールが知られている(例えば、非特許文献1参照)。
近年、調味料の風味を向上させる目的で、β−ダマセノンを節類抽出物入り調味料に含有させる方法(例えば、特許文献7参照)が開示されている他、β−イオノンを染毛剤のナフトール臭マスキング剤として使用する方法(例えば、特許文献8参照)、6−メチル−5−ヘプテン−2−オール(別名:スルカトール)を殺真菌組成物として使用する方法(例えば、特許文献9参照)が開示されているが、酢酸臭を低減させる目的で検討されたことは無かった。
On the other hand, β-damasenone, β-ionone, and 6-methyl-5-hepten-2-ol are known as aromatic components that are contained in tomatoes, wine, and the like and are produced using β-carotene and lycopene as precursors (for example, Non-patent document 1).
In recent years, for the purpose of improving the flavor of seasonings, there has been disclosed a method of adding β-damasenone to seasonings containing nodular extracts (see, for example, Patent Document 7), and β-ionone as a hair dye naphthol. A method using an odor masking agent (see, for example, Patent Document 8) and a method using 6-methyl-5-hepten-2-ol (also known as sulfatol) as a fungicidal composition (see, for example, Patent Document 9). Although disclosed, it has never been studied for the purpose of reducing the odor of acetic acid.
本発明は上記事情に鑑みてなされたものであり、酢酸臭を低減する調味料および該調味料を含有する配合調味料(酢酸含有調味料)を提供することにある。 This invention is made | formed in view of the said situation, and it is providing the seasoning which reduces an acetic acid odor, and the mixing | blending seasoning (acetic acid containing seasoning) containing this seasoning.
本発明者らは、上記課題を解決するため鋭意検討を重ねた結果、例えば調味酢やドレッシング等の、食酢と醤油を共に含有する調味料において、醤油の香りが酢酸の刺激臭を強めていることを見出した。そこで醤油の香りをマスキングする成分を探索した結果、驚くべきことにβ−ダマセノンおよび/またはβ−イオノンおよび/または6−メチル−5−ヘプテン−2−オールを一定濃度以上含有する際に、醤油の香りをマスキング可能であり、さらに前記成分を含有する調味料が、酢酸臭を低減することを見出した。
また、上記成分を含有する果汁や野菜汁を醤油に添加することで得られた調味料であっても、同様の酢酸臭低減効果が得られることを見出し、本発明を完成させた。
As a result of intensive studies to solve the above-mentioned problems, the present inventors, for example, seasonings containing both vinegar and soy sauce, such as seasoning vinegar and dressing, have a strong odor of acetic acid. I found out. Therefore, as a result of searching for a component masking the scent of soy sauce, surprisingly, when containing β-damasenone and / or β-ionone and / or 6-methyl-5-hepten-2-ol above a certain concentration, soy sauce It has been found that a seasoning containing the above components can reduce the odor of acetic acid.
Moreover, even if it was the seasoning obtained by adding the fruit juice and vegetable juice containing the said component to soy sauce, it discovered that the same acetic acid odor reduction effect was acquired, and completed this invention.
すなわち本発明は、
1)β−ダマセノンを5〜1300ppbおよび/またはβ−イオノンを5〜1000ppbおよび/または6−メチル−5−ヘプテン−2−オールを1000〜5000ppbの濃度で含有する調味料。
2)β−ダマセノン、β−イオノン、6−メチル−5−ヘプテン−2−オールが、野菜汁または果汁に由来することを特徴とする上記1)記載の調味料
3)野菜汁または果汁が、トマトに由来するものを含む、上記2)記載の調味料。
4)上記1)〜3)のいずれかに記載の調味料を含有し、β−ダマセノンを1〜280ppbおよび/またはβ−イオノンを1〜220ppbの濃度で含有することを特徴とする配合調味料。
に関する。
That is, the present invention
1) A seasoning containing β-damasenone at a concentration of 5 to 1300 ppb and / or β-ionone at a concentration of 5 to 1000 ppb and / or 6-methyl-5-hepten-2-ol at a concentration of 1000 to 5000 ppb.
2) The seasoning 3) vegetable juice or fruit juice according to 1) above, wherein β-damasenone, β-ionone, 6-methyl-5-hepten-2-ol is derived from vegetable juice or fruit juice. The seasoning as described in 2) above, which includes those derived from tomatoes.
4) A seasoning according to any one of 1) to 3) above, containing β-damasenone in a concentration of 1 to 280 ppb and / or β-ionone in a concentration of 1 to 220 ppb. .
About.
本発明によれば、消費者は食酢と醤油からなる調味料を使用する際に、従来までと同じ食酢量の配合で、従来の醤油では得られなかった酢酸臭に対する低減効果が得られる。本発明の調味料を配合した調味酢やドレッシングを用いることで、つけかけ用途、和え物など様々な食事の場面で、酢酸臭に咽ることなく酢酸含有調味料を使用することが可能となる。また本発明品は、醤油の強い香りが低減されているため、食酢を含有する調味料だけでなく、洋風のスープなどに添加すれば、醤油風味を感じさせることなく風味を向上させることが可能であり、洋風用途に適した調味料としても非常に有用である。 According to the present invention, when a consumer uses a seasoning comprising vinegar and soy sauce, the effect of reducing acetic acid odor, which cannot be obtained with conventional soy sauce, is obtained with the same vinegar content as before. By using the seasoning vinegar or dressing blended with the seasoning of the present invention, it becomes possible to use the acetic acid-containing seasoning in various meal scenes such as application, seasoning, etc. without phlegm. In addition, since the strong scent of soy sauce is reduced in the present invention product, it is possible to improve the flavor without feeling the soy sauce flavor if added to Western soups as well as seasonings containing vinegar It is also very useful as a seasoning suitable for Western-style applications.
以下、本発明を詳細に説明する。 Hereinafter, the present invention will be described in detail.
本発明は、酢酸臭を低減する調味料を得ることを目的とし、該調味料中にβ−ダマセノンおよび/またはβ−イオノンおよび/または6−メチル−5−ヘプテン−2−オールの各成分を特定濃度(ppb)含有させることを特徴とする。ここで、本発明における各成分の濃度(ppb)は、マイクログラム毎リットル(μg/l)である。 An object of the present invention is to obtain a seasoning that reduces the odor of acetic acid. In the seasoning, each component of β-damasenone and / or β-ionone and / or 6-methyl-5-hepten-2-ol is added. It is characterized by containing a specific concentration (ppb). Here, the concentration (ppb) of each component in the present invention is microliter per liter (μg / l).
本発明は、簡便には醤油に、β−ダマセノンおよび/またはβ−イオノンおよび/または6−メチル−5−ヘプテン−2−オールを添加することで得られる。一方で、醤油へ、上記の各成分を含有する果汁および/または野菜汁を添加することにより、各成分を所望の量含有させた調味料とすることもできる。例えば、生醤油または火入れ醤油に、β−ダマセノンおよび/またはβ−イオノンおよび/または6−メチル−5−ヘプテン−2−オールを本発明の濃度(ppb)範囲になるまで果汁および/または野菜汁を添加することで、本発明の調味料を得ることができる。 The present invention can be conveniently obtained by adding β-damasenone and / or β-ionone and / or 6-methyl-5-hepten-2-ol to soy sauce. On the other hand, by adding fruit juice and / or vegetable juice containing each of the above components to soy sauce, it is possible to obtain a seasoning containing each component in a desired amount. For example, fresh soy sauce or fired soy sauce is mixed with β-damasenone and / or β-ionone and / or 6-methyl-5-hepten-2-ol until the concentration (ppb) range of the present invention is reached. The seasoning of this invention can be obtained by adding.
本発明における「果汁」とは、果実を破砕して搾汁または裏ごし等をし、皮、種子等を除去したものをいう。果汁は、濃縮していないストレート果汁だけでなく、2〜10倍になるまで水分を除去して濃縮したもの(以下、「濃縮果汁」という)も好適に用いることができ、3〜8倍に濃縮したものがより好ましい。糖度計や屈折計によって測定されるBrix(糖度)は6〜80%(w/w)であることが好ましく、20〜70%(w/w)であることが特に好ましい。果汁の濃度が薄すぎると、上記香気成分の含有量が低下するため好ましくない。 The “fruit juice” in the present invention refers to a product obtained by crushing fruit and squeezing or squeezing the fruit and removing the skin, seeds and the like. As for the fruit juice, not only the straight fruit juice that has not been concentrated, but also the one obtained by removing water and concentrating until it becomes 2 to 10 times (hereinafter referred to as “concentrated fruit juice”) can be suitably used. What was concentrated is more preferable. The Brix (sugar content) measured by a saccharimeter or refractometer is preferably 6 to 80% (w / w), particularly preferably 20 to 70% (w / w). If the concentration of the fruit juice is too thin, the content of the aroma component is lowered, which is not preferable.
本発明における「野菜汁」とは、野菜を搾汁したもの、または破砕後裏ごし等したものをいう。野菜汁は、濃縮していないストレートタイプだけでなく、2〜10倍になるまで水分を除去して濃縮したもの(以下、「濃縮野菜汁」という)も好適に用いることができる。果汁と同様に、糖度計や屈折計によって測定されるBrix(糖度)は6〜80%(w/w)であることが好ましく、20〜70%(w/w)であることが特に好ましい。 The “vegetable juice” in the present invention refers to a product obtained by squeezing a vegetable, or a product that has been crushed and ground. The vegetable juice is not limited to a straight type that is not concentrated, but can also be suitably used after removing water until it is 2 to 10 times concentrated (hereinafter referred to as “concentrated vegetable juice”). As with fruit juice, the Brix (sugar content) measured by a saccharimeter or refractometer is preferably 6 to 80% (w / w), particularly preferably 20 to 70% (w / w).
果汁・野菜汁の濃縮方法としては、制限無く公知の加熱による濃縮、真空濃縮、凍結濃縮、膜濃縮などが用いられる。 As a method for concentrating fruit juice and vegetable juice, known methods such as concentration by heating, vacuum concentration, freeze concentration, and membrane concentration are used without limitation.
濃縮した果汁・野菜汁を適宜希釈し、色素やパルプ分を除く遠心分離や精密膜ろ過などを実施して得られた透過液を、さらに濃縮して得られる搾汁濃縮液は、酢酸臭を低減する前記各香気成分を多く含有するため特に好ましい。 The juice concentrate obtained by further diluting the concentrated fruit juice / vegetable juice and carrying out centrifugal separation or precision membrane filtration to remove pigments and pulp content, This is particularly preferable because it contains a large amount of each fragrance component to be reduced.
生醤油または火入れ醤油に対する果汁および/または野菜汁および/または濃縮果汁および/または濃縮野菜汁の添加量は10〜80%(w/w)であることが好ましく、20〜70%(w/w)であることが特に好ましい。10%未満であれば通常の醤油と品質に差がなく、酢酸臭低減効果が向上せず好ましくない。また80%を超えると果実感が強くなり、調味料としての風味のバランスが損なわれるため好ましくない。 The addition amount of fruit juice and / or vegetable juice and / or concentrated fruit juice and / or concentrated vegetable juice to fresh soy sauce or hot soy sauce is preferably 10 to 80% (w / w), and 20 to 70% (w / w). Is particularly preferred. If it is less than 10%, there is no difference in quality from ordinary soy sauce, and the effect of reducing acetic acid odor is not improved, which is not preferable. On the other hand, if it exceeds 80%, the fruit feeling becomes strong and the balance of flavor as a seasoning is impaired, which is not preferable.
果汁の原料となる「果実」としては、例えばトマト、ブドウ、柑橘類、スイカ等が挙げられるが、好ましくはトマトである。これらの果実は、1種または2種以上を組み合わせて用いることができる。また、必要に応じて、塩類、糖類、香料、酸味料等を添加したものでもよい。 Examples of the “fruit” used as the raw material for fruit juice include tomato, grape, citrus fruit, watermelon and the like, and tomato is preferred. These fruits can be used alone or in combination of two or more. Moreover, what added salts, saccharides, a fragrance | flavor, a sour agent, etc. may be used as needed.
野菜汁の原料となる「野菜」としては、カボチャ、にんじん、ほうれん草、ピーマン、キャベツ、アスパラガス等が挙げられる。これらの野菜は、1種または2種以上を組み合わせて用いることができる。また、必要に応じて、塩類、糖類、香料、酸味料等を添加したものでもよい。 Examples of “vegetables” that are used as raw materials for vegetable juice include pumpkin, carrot, spinach, peppers, cabbage, and asparagus. These vegetables can be used alone or in combination of two or more. Moreover, what added salts, saccharides, a fragrance | flavor, a sour agent, etc. may be used as needed.
果実と野菜には、β−ダマセノンおよび/またはβ−イオノンおよび/または6−メチル−5−ヘプテン−2−オールが含有されていることが好ましい。または前駆物質であるβ−カロテンが含有されていてもよい。 The fruits and vegetables preferably contain β-damasenone and / or β-ionone and / or 6-methyl-5-hepten-2-ol. Alternatively, β-carotene which is a precursor may be contained.
β−ダマセノンの調味料中の濃度は、5〜1300ppbであることが好ましく、55〜1300ppbの範囲であることが特に好ましい。調味料中のβ−ダマセノン濃度が1ppb未満の場合は、酢酸臭低減効果は十分ではない。5ppb以上の場合に、濃口醤油と比較して酢酸臭低減効果が向上し、54ppbを超えると、調味料に使用した原料の影響を受けずに、顕著な酢酸臭低減効果の向上が見られる。1300ppbを超えると成分の香りが強くなり、香りのバランスを損なうため好ましくない。β−ダマセノンを添加する際には、市販の純品のほか、β−ダマセノンを含有する食用可能な原料(例えば、果汁、野菜汁、酒、果実酒、香料、香辛料等)を用いてもよい。 The concentration of β-damerone in the seasoning is preferably 5 to 1300 ppb, and particularly preferably in the range of 55 to 1300 ppb. When the concentration of β-damasenone in the seasoning is less than 1 ppb, the effect of reducing acetic acid odor is not sufficient. In the case of 5 ppb or more, the effect of reducing acetic acid odor is improved as compared with thick soy sauce, and when it exceeds 54 ppb, the effect of reducing acetic acid odor is significantly improved without being affected by the raw materials used for the seasoning. If it exceeds 1300 ppb, the scent of the component becomes strong and the balance of the scent is impaired. In addition to commercially available pure products, edible raw materials (for example, fruit juice, vegetable juice, liquor, fruit liquor, fragrance, spice, etc.) containing β-damagenone may be used when adding β-damagenone. .
β−イオノンの調味料中の濃度は、5〜1000ppbであることが好ましい。調味料中のβ−イオノン濃度が1ppb未満の場合は、酢酸臭低減効果は十分ではない。1ppb以上の場合に、濃口醤油と比較して顕著に酢酸臭低減効果が向上し、5ppb以上ではさらに顕著な酢酸臭低減効果の向上が見られる。1000ppbを超えると成分の香りが強くなり、香りのバランスを損なうため好ましくない。β−イオノンを添加する際には、市販の純品のほか、β−イオノンを含有する食用可能な原料(例えば、果汁、野菜汁、酒、果実酒、香料、香辛料等)を用いてもよい。 The concentration of β-ionone in the seasoning is preferably 5 to 1000 ppb. When the β-ionone concentration in the seasoning is less than 1 ppb, the effect of reducing acetic acid odor is not sufficient. In the case of 1 ppb or more, the effect of reducing acetic acid odor is remarkably improved as compared with the thick soy sauce, and in the case of 5 ppb or more, the effect of reducing acetic acid odor is further improved. If it exceeds 1000 ppb, the scent of the component becomes strong and the scent balance is impaired, which is not preferable. When β-ionone is added, in addition to commercially pure products, edible raw materials containing β-ionone (for example, fruit juice, vegetable juice, sake, fruit liquor, flavor, spice, etc.) may be used. .
6−メチル−5−ヘプテン−2−オールの調味料中の濃度は、1000〜5000ppbであることが好ましい。6−メチル−5−ヘプテン−2−オール濃度が1000ppb未満の場合は、酢酸臭低減効果は十分ではない。1000ppb以上の場合に、濃口醤油と比較して顕著に酢酸臭低減効果が向上する。5000ppbを超えると成分の香りが強くなり、香りのバランスを損なうため好ましくない。6−メチル−5−ヘプテン−2−オールを添加する際には、市販の純品のほか、6−メチル−5−ヘプテン−2−オールを含有する食用可能な原料(例えば、果汁、野菜汁、酒、果実酒、香料、香辛料等)を用いてもよい。 The concentration of 6-methyl-5-hepten-2-ol in the seasoning is preferably 1000 to 5000 ppb. When the 6-methyl-5-hepten-2-ol concentration is less than 1000 ppb, the effect of reducing acetic acid odor is not sufficient. In the case of 1000 ppb or more, the effect of reducing acetic acid odor is remarkably improved as compared with concentrated soy sauce. If it exceeds 5000 ppb, the scent of the component becomes strong and the balance of the scent is impaired, which is not preferable. When adding 6-methyl-5-hepten-2-ol, in addition to commercially pure products, edible raw materials containing 6-methyl-5-hepten-2-ol (for example, fruit juice, vegetable juice) , Liquor, fruit liquor, fragrance, spice, etc.).
生醤油および火入れ醤油は、制限無く日本農林規格で定められる「しょうゆ」を用いればよい。例えば、日本農林規格で定められる、こいくちしょうゆ、うすくちしょうゆ、たまりしょうゆ、しろしょうゆ等で用いられている原料の配合比率により得られた醤油麹を食塩水と共に仕込み、発酵・熟成・圧搾を経て、生醤油が得られる。この生醤油は加熱殺菌を行っていないため、麹菌由来の酵素や、醤油酵母、醤油乳酸菌などが含有されている。生醤油は、火入れと呼ばれる加熱殺菌工程を経る。火入れは公知の醤油製成過程で行なわれている加熱条件を用いればよい。加熱によって澱が生じることがあるため、数日間静置した後、澱から上清を分離して火入れ醤油が得られる。 For the soy sauce and raw soy sauce, "soy sauce" defined by Japanese Agricultural Standards may be used without limitation. For example, the soy sauce cake obtained from the blending ratio of ingredients used in the Japanese agricultural and forestry standards, such as koikuchi soy sauce, thin soy sauce, tamari soy sauce, white soy sauce, etc. After that, raw soy sauce is obtained. Since this raw soy sauce is not heat-sterilized, it contains enzymes derived from Aspergillus oryzae, soy sauce yeast, soy sauce lactic acid bacteria, and the like. Raw soy sauce undergoes a heat sterilization process called burning. The heating may be performed under the heating conditions that are performed in a known soy sauce production process. Since starch may be generated by heating, after standing for several days, the supernatant is separated from the starch to obtain a soy sauce.
生醤油または火入れ醤油に果汁を添加して得られる調味料は、果汁由来のβ−ダマセノンおよび/またはβ−イオノンおよび/または6−メチル−5−ヘプテン−2−オールの各成分がバランスよく配合され、酢酸臭低減効果が高く、風味のバランスに優れ、果汁由来の香りや酸味、甘味の感じられる調味料となりうる。これらの成分が含有されているかは、定法に従ってガスクロマトグラフ法により定量することで確認することができる。 The seasoning obtained by adding fruit juice to raw soy sauce or fired soy sauce is a well-balanced blend of β-damasenone and / or β-ionone and / or 6-methyl-5-hepten-2-ol derived from fruit juice In addition, it has a high effect of reducing acetic acid odor, has an excellent balance of flavor, and can be a seasoning that has a fragrance, sourness, and sweetness derived from fruit juice. Whether these components are contained can be confirmed by quantifying by gas chromatography according to a conventional method.
果汁を添加した生醤油または火入れ醤油は、定法に従って圧搾濾過され、一般成分分析、香気成分分析を行い、成分を調整する。この際pHや塩分、エタノール濃度、グルタミン酸濃度、クエン酸濃度、香気成分濃度を適宜調整してもよい。好ましくはpHが3.5〜5.0、塩分が8.0〜18.0%となるように調整する。 Fresh soy sauce or fired soy sauce to which fruit juice has been added is squeezed and filtered in accordance with a conventional method, and general component analysis and aroma component analysis are performed to adjust the components. At this time, pH, salinity, ethanol concentration, glutamic acid concentration, citric acid concentration, and aroma component concentration may be appropriately adjusted. Preferably, the pH is adjusted to 3.5 to 5.0 and the salt content is adjusted to 8.0 to 18.0%.
成分調整後は、殺菌または除菌を行う。殺菌の場合は、75〜120℃で5秒〜60分の加熱を行い、澱を沈めた後、上清を調味料として得る。除菌の場合は公知のMF膜によるろ過等を行い、ろ過物を調味料として得る。 After component adjustment, sterilization or sterilization is performed. In the case of sterilization, heating is performed at 75 to 120 ° C. for 5 seconds to 60 minutes to sink the starch, and then the supernatant is obtained as a seasoning. In the case of sterilization, filtration with a known MF membrane or the like is performed to obtain a filtrate as a seasoning.
本発明の調味料は、日本農林規格の「しょうゆ」と同様の使い方ができ、また任意の飲食品に配合することができる。例えば、調味酢、ドレッシング、つゆ、たれ、和風だし、洋風だし、中華だし、ソース等の配合調味料や、スープ等に添加して用いることができる。 The seasoning of the present invention can be used in the same manner as Japanese soy sauce “soy sauce” and can be blended in any food or drink. For example, it can be used by adding to seasoning vinegar, dressing, soup, sauce, Japanese-style soup, Western-style soup, Chinese soup, sauces and other blended seasonings, soup and the like.
本明細書における調味酢とは、主たる原料として食酢および砂糖類を用い、果汁、醤油、食塩、その他の調味料を加えたものであって、主として寿司、酢の物および漬物に用いるものをいう。例えば、二杯酢、三杯酢、土佐酢、甘酢、ぽん酢等が挙げられる。 The seasoned vinegar in this specification means vinegar and sugar as main raw materials, and fruit juice, soy sauce, salt and other seasonings added, and is mainly used for sushi, vinegar and pickles. For example, two cup vinegar, three cup vinegar, Tosa vinegar, sweet vinegar, ponzu vinegar and the like can be mentioned.
調味酢に用いる食酢としては、例えば穀物酢、米酢、玄米酢、粕酢、黒酢等の他、リンゴ酢やワイン酢、バルサミコ酢等が挙げられる。 Examples of vinegar used for seasoning vinegar include cereal vinegar, rice vinegar, brown rice vinegar, rice bran vinegar, black vinegar, and apple vinegar, wine vinegar, balsamic vinegar, and the like.
本明細書におけるドレッシングとは、食用植物油脂と醸造酢または柑橘類の果汁を主原料として、食塩、砂糖類、香辛料、醤油などを加えて調製し、水中油滴型に乳化するか、または分離した状態の調味料、さらにこれに酢漬け野菜等を加えたものであり、日本農林規格で定められたドレッシングおよびドレッシングタイプ調味料(ノンオイルドレッシング)と同一の概念である。 Dressing in this specification is prepared by adding edible vegetable oil and fat and brewed vinegar or citrus fruit juice as main ingredients, adding salt, sugar, spices, soy sauce, etc., emulsified into oil-in-water droplets, or separated. The seasoning of the state, and further vinegared vegetables and the like are added, and it is the same concept as the dressing and dressing type seasoning (non-oil dressing) defined by the Japanese Agricultural Standards.
以下、実施例により本発明をさらに具体的に説明する。ただし、本発明の技術的範囲は、それらの例により何ら限定されるものではない。 Hereinafter, the present invention will be described more specifically with reference to examples. However, the technical scope of the present invention is not limited by these examples.
<各種成分の火入れ醤油への添加>
火入れ醤油として、市販の濃口醤油(キッコーマン社製、丸大豆使用)を用いた(対照品)。この醤油(対照品)にβ−ダマセノン、β−イオノン、6−メチルー5−ヘプテン−2−オールをそれぞれ添加・混合し、試験品1−1〜1−18を調製した。
<Addition of various ingredients to soy sauce for burning>
Commercially available dark soy sauce (Kikkoman Co., Ltd., using round soybeans) was used as a burning soy sauce (control product). Β-Damacenone, β-ionone, and 6-methyl-5-hepten-2-ol were added to and mixed with this soy sauce (control product) to prepare test products 1-1 to 1-18.
<各種成分を添加した火入れ醤油の官能評価>
酢酸臭低減効果を評価するため、三杯酢を調製し、官能評価に用いた。三杯酢は下記の材料を混合し用意した。
材料:
対照品または試験品 10ml
穀物酢(酸度4.2%) 30ml
砂糖 12g
上記材料を混合し終えた時点での容量は47.5mlであった。
官能評価は、訓練され識別能力を有するパネル5名による評点法で行った。酢酸臭低減効果および香りの総合評価について、上記のように用意した対照品と試験品を含有する三杯酢の香りを嗅ぎ、比較を行った。評点は下記の基準に従った。
(酢酸臭低減効果)
1:対照品のほうが、かなり効果が高い
2:対照品のほうが、やや効果が高い
3:効果は同等
4:試験品のほうが、やや効果が高い
5:試験品のほうが、かなり効果が高い
(香りの総合評価)
1:対照品のほうが、とても好ましい
2:対照品のほうが、やや好ましい
3:同等
4:試験品のほうが、やや好ましい
5:試験品のほうが、とても好ましい
<Sensory evaluation of soy sauce with various ingredients added>
In order to evaluate the acetic acid odor reduction effect, three cups of vinegar were prepared and used for sensory evaluation. Three cups of vinegar were prepared by mixing the following ingredients.
material:
Control or test product 10ml
Grain vinegar (acidity 4.2%) 30ml
12g sugar
The volume when the above materials were mixed was 47.5 ml.
The sensory evaluation was performed by a scoring method using five trained and discriminating panels. About the acetic acid odor reduction effect and the comprehensive evaluation of fragrance, the scent of three cups of vinegar containing the control product and the test product prepared as described above was sniffed and compared. The score was according to the following criteria.
(Acetic acid odor reduction effect)
1: The control product is much more effective 2: The control product is slightly more effective 3: The effect is equivalent 4: The test product is slightly more effective 5: The test product is much more effective
(Comprehensive evaluation of fragrance)
1: Control product is more preferable 2: Control product is slightly preferable 3: Equivalent 4: Test product is slightly preferable 5: Test product is more preferable
表1の官能評価結果より、火入れ醤油において、β−ダマセノンは5ppb以上、β−イオノンは5ppb以上、6−メチルー5−ヘプテン−2−オールは1000ppb以上を含有させることで、酢酸臭低減効果の向上が見られた(試験品1−2〜6、1−8〜14)。β−ダマセノンが1ppb、または、β−イオノンが1ppbの添加時には、酢酸臭低減効果の顕著な向上は見られなかった(試験品1−1、1−7)。試験品を配合した三杯酢においては、β−ダマセノンは1.1ppb以上、β−イオノンは1.1ppb以上、6−メチルー5−ヘプテン−2−オールは211ppb以上の濃度が含有されていれば、酢酸臭が低減されることが示された。
また、β−ダマセノンとβ−イオノンが共に含有されるときには、さらに酢酸臭低減効果が高まった(試験品1−15〜18)。β−ダマセノンが1000ppb含有される際に、β−イオノン濃度が200ppb以上になると、成分由来の香りの相乗効果により成分由来の香りが強くなり、酢酸臭低減効果の向上はみられるものの、香りの総合評価において評価が減少傾向となった(試験品1−17〜18)。
β−ダマセノンは1000ppb、β−イオノンは1000ppbを超えて含有させると、成分由来の香りが強くなり、酢酸臭低減効果の向上はみられるものの、香りの総合評価において評価が減少傾向となった。それぞれ5000ppb以上を含有させると、香りの総合評価が下がった(試験品1−5〜6、1−11〜12)。
From the sensory evaluation results in Table 1, in the soy sauce that is fired, by adding 5 ppb or more for β-damasenone, 5 ppb or more for β-ionone, and 1000 ppb or more for 6-methyl-5-hepten-2-ol, Improvement was observed (test products 1-2 to 6, 1-8 to 14). When β-damasenone was added at 1 ppb or β-ionone was added at 1 ppb, no significant improvement in the effect of reducing acetic acid odor was observed (test products 1-1, 1-7). In three cups of vinegar mixed with the test product, β-damasenone is 1.1 ppb or more, β-ionone is 1.1 ppb or more, and 6-methyl-5-hepten-2-ol is 211 ppb or more. It was shown that the odor was reduced.
Moreover, when both β-damasenone and β-ionone were contained, the effect of reducing acetic acid odor was further enhanced (test products 1-15 to 18). When β-damasenone is contained at 1000 ppb, if the β-ionone concentration is 200 ppb or more, the scent derived from the component becomes stronger due to the synergistic effect of the scent derived from the component, and the effect of reducing acetic acid odor is improved, but the scent In the comprehensive evaluation, the evaluation showed a decreasing trend (test products 1-17 to 18).
When β-damasenone was added in an amount exceeding 1000 ppb and β-ionone was added in an amount exceeding 1000 ppb, the fragrance derived from the components became strong and the effect of reducing the acetic acid odor was improved, but the evaluation of the fragrance overall evaluation tended to decrease. When each contained 5000 ppb or more, the overall evaluation of fragrance was lowered (test products 1-5 to 6 and 11 to 12).
<醤油麹の調製>
大豆10kgは温水中に浸漬し、吸水させた後、加圧条件下で蒸煮した。小麦10kgは炒熬した後、割砕した。大豆・小麦を混合後、麹菌を接種し、通風製麹装置によって製麹を行い、3日後に醤油麹を得た。
<Preparation of soy sauce cake>
10 kg of soybeans were immersed in warm water and absorbed, and then steamed under pressurized conditions. 10 kg of wheat was fried and then cracked. After mixing soybeans and wheat, koji molds were inoculated, and koji was produced with a ventilating koji apparatus, and soy sauce koji was obtained after 3 days.
<生醤油の調製>
醤油諸味は、発酵・熟成後の食塩濃度が16.0%となるように食塩水と水を加え、定法に従い醤油乳酸菌を加えよく混合し、乳酸発酵を行った。続いて定法に従い耐塩性の醤油酵母(Zygosaccharomyces rouxii)を添加し、諸味品温を25℃に保持しながら酵母発酵を行った後、3ヶ月間発酵・熟成させた。諸味を圧搾・ろ過して「生醤油」を得た。
<Preparation of raw soy sauce>
For soy sauce moromi, salt solution and water were added so that the salt concentration after fermentation and ripening would be 16.0%, and soy sauce lactic acid bacteria were added and mixed well according to a conventional method, followed by lactic acid fermentation. Subsequently, according to a conventional method, salt-resistant soy sauce yeast (Zygosaccharomyces rouxii) was added, and yeast fermentation was carried out while maintaining the moromi product temperature at 25 ° C., followed by fermentation and aging for 3 months. The moromi was pressed and filtered to obtain “raw soy sauce”.
<比率を変えた果汁混合醤油の調製>
火入れ醤油である市販の濃口醤油(キッコーマン社製、丸大豆使用)に対して、果汁としてトマト搾汁濃縮液(日本デルモンテ社製、イスラエル産、Brix60%)を、醤油:果汁の比が95:5、80:20、60:40、40:60、20:80(いずれも体積比)となるようにそれぞれ混合し果汁混合醤油を調製した。同様にして、上記生醤油に対して、トマト搾汁濃縮液を醤油:果汁の比が80:20、60:40(いずれも体積比)となるようにそれぞれ混合し果汁混合生醤油を調製した。
<Preparation of mixed fruit juice with different ratio>
Concentrated soy sauce (manufactured by Nihon Del Monte Co., Ltd., Israel, Brix 60%) as a fruit juice against a commercially available soy sauce (made by Kikkoman Co., Ltd., using round soybeans) as a soy sauce, soy sauce: fruit juice ratio is 95: 5, 80:20, 60:40, 40:60, 20:80 (all volume ratios) were mixed to prepare fruit juice mixed soy sauce. Similarly, tomato juice concentrate was mixed with the raw soy sauce so that the ratio of soy sauce: fruit juice was 80:20, 60:40 (both volume ratios), respectively, to prepare fruit mixed raw soy sauce. .
<果汁混合醤油、果汁混合生醤油の火入れおよびろ過>
果汁混合醤油および果汁混合生醤油は、火入れを80℃達温30分間行い、1〜2日間、4℃にて静置した。沈殿が生じた場合は上清を回収し、試験品2−1〜2−7を得た。
<Fire-filling and filtration of fruit juice mixed soy sauce and fruit mixed raw soy sauce>
The fruit juice mixed soy sauce and the fruit juice mixed raw soy sauce were heated at 80 ° C. for 30 minutes and allowed to stand at 4 ° C. for 1-2 days. When precipitation occurred, the supernatant was recovered to obtain test products 2-1 to 2-7.
<成分調整>
各種試験品の調製終了時点での食塩濃度はそれぞれ試験品2−1:15.7%、試験品2−2:15.1% 、試験品2−3:13.1%、試験品2−4:10.9%、試験品2−5:8.6%、試験品2−6:14.8% 、試験品2−7:13.2%(いずれもw/v)であった。官能評価時には、対照品と同じ食塩濃度16.0%(w/v)となるように食塩を添加した。
<Ingredient adjustment>
The salt concentrations at the end of the preparation of the various test products are as follows: Test product 2-1: 15.7%, Test product 2-2: 15.1%, Test product 2-3: 13.1%, Test product 2- 4: 10.9%, test product 2-5: 8.6%, test product 2-6: 14.8%, test product 2-7: 13.2% (all w / v). At the time of sensory evaluation, sodium chloride was added so that the same sodium chloride concentration as the control product was 16.0% (w / v).
<成分分析>
醤油の一般成分は、しょうゆ試験法(財団法人、日本醤油研究所編、昭和60年(1985年)3月1日発行)記載の方法に従い分析を行った。
<Component analysis>
The general components of soy sauce were analyzed according to the method described in the soy sauce test method (founded by Japan Soy Sauce Research Institute, published on March 1, 1985).
<香気成分分析>
β−ダマセノン、β−イオノン、6−メチル−5−ヘプテン−2−オールはヘッドスペースGC−MSを用いた標準添加法にて分析定量した。試料として対照品または試験品10mlをバイアル瓶に2本ずつ入れた。既知濃度の上記成分を1本の試料入りバイアル瓶に入れ、上記成分未添加の試料入りバイアル瓶と合わせて用意した。ヘッドスペースサンプラ(Agilent Technologies社製、G1888)にそれぞれセットし、分析を行った。
<Aroma component analysis>
β-Damacenone, β-ionone, and 6-methyl-5-hepten-2-ol were analyzed and quantified by a standard addition method using headspace GC-MS. As a sample, 10 ml of a control product or a test product was placed in each vial. The above-mentioned components having known concentrations were put in one sample-containing vial and prepared together with the above-described sample-added sample-containing vial. Each headspace sampler (Agilent Technologies, G1888) was set and analyzed.
分析条件は下記のようにして行った。
測定機器:Agilent Technologies社製、6890N GC + 5973MSD
カラム: DB−WAX(Agilent Technologies社製、60m×内径0.25mm×膜厚0.5μm)
昇温条件: 40℃、3分保持後、3℃/分の速度で220℃まで昇温
注入モード: スプリットレスモード
キャリアガス: ヘリウム、流速1.5ml/分
測定モード: SIMモード
The analysis conditions were as follows.
Measuring instrument: Agilent Technologies, 6890N GC + 5973MSD
Column: DB-WAX (manufactured by Agilent Technologies, 60 m × inner diameter 0.25 mm × film thickness 0.5 μm)
Temperature rise conditions: 40 ° C., hold for 3 minutes, then heat up to 220 ° C. at a rate of 3 ° C./minute Injection mode: Splitless mode Carrier gas: Helium, flow rate 1.5 ml / minute Measurement mode: SIM mode
検出された標品ピークの面積値から検量線を作成し、濃度を算出した。前記3成分の検出下限濃度は1ppb以下であった。対照品は、いずれの成分も検出下限以下であった。 A calibration curve was created from the area value of the detected standard peak, and the concentration was calculated. The detection lower limit concentration of the three components was 1 ppb or less. In the control product, all components were below the lower limit of detection.
対照品および試験品の一般成分分析結果、香気成分含量を表4に示す。食塩濃度は成分調整後の値を示した。 Table 4 shows the results of general component analysis and aroma component contents of the control product and the test product. The salt concentration showed the value after component adjustment.
<官能評価>
官能評価は、訓練され識別能力を有するパネル5名による評点法で行った。対照品または試験品を用いて調製した三杯酢、ドレッシングについて比較を行った。評点は下記の基準に従った。
(酢酸臭低減効果)
1:対照品のほうが、かなり効果が高い
2:対照品のほうが、やや効果が高い
3:効果は同等
4:試験品のほうが、やや効果が高い
5:試験品のほうが、かなり効果が高い
(風味の総合評価)
1:対照品のほうが、とても好ましい
2:対照品のほうが、やや好ましい
3:同等
4:試験品のほうが、やや好ましい
5:試験品のほうが、とても好ましい
<Sensory evaluation>
The sensory evaluation was performed by a scoring method using five trained and discriminating panels. Comparison was made on three cups of vinegar and dressing prepared using the control or test product. The score was according to the following criteria.
(Acetic acid odor reduction effect)
1: The control product is much more effective 2: The control product is slightly more effective 3: The effect is equivalent 4: The test product is slightly more effective 5: The test product is much more effective
(Comprehensive evaluation of flavor)
1: Control product is more preferable 2: Control product is slightly preferable 3: Equivalent 4: Test product is slightly preferable 5: Test product is more preferable
<三杯酢の官能評価>
三杯酢は、トマト搾汁濃縮液に由来する糖分を算出し、砂糖の配合量を変えることで糖分が同濃度となるように、表2に示す配合で調製した。調製した三杯酢の香りや、直接喫食した際の、酢酸臭低減効果および風味について評価した。
<Sensory evaluation of three cups of vinegar>
Three cups of vinegar were prepared with the composition shown in Table 2 so that the sugar content derived from the tomato juice concentrate was calculated and the sugar content was the same by changing the amount of sugar. The fragrance of the prepared three cups of vinegar, the effect of reducing acetic acid odor and the flavor when eating directly were evaluated.
<ドレッシングの官能評価>
ドレッシングも、トマト搾汁濃縮液に由来する糖分を算出し、砂糖の配合量を変えることで糖分が同濃度となるように、表3に示す配合で調製した。レタスを3cm間隔に切ったものを20g用意し、調製したドレッシングを5ml添加した。ドレッシング自体の香りや、サラダとして直接喫食した際の、酢酸臭低減効果および風味について評価した。
<Sensory evaluation of dressing>
The dressing was also prepared with the formulation shown in Table 3 so that the sugar content derived from the tomato juice concentrate was calculated and the sugar content would be the same by changing the sugar content. 20 g of lettuce cut at 3 cm intervals was prepared, and 5 ml of the prepared dressing was added. The aroma of the dressing itself, the effect of reducing acetic acid odor and the flavor when eating directly as a salad were evaluated.
表4に示す結果より、果汁であるトマト搾汁濃縮液の混合比率が高い程、一般成分ではグルタミン酸値が上昇した。香気成分では、β−ダマセノンが54〜1299ppb、β−イオノンが3〜95ppb、6−メチル−5−ヘプテン−2−オールが8〜112ppbとなり、果汁比率の増加に応じて香気成分が増加していることが分かる。 From the results shown in Table 4, the higher the mixing ratio of the concentrated tomato juice concentrate, the higher the glutamic acid value of the general components. In the fragrance component, β-damasenone is 54 to 1299 ppb, β-ionone is 3 to 95 ppb, 6-methyl-5-hepten-2-ol is 8 to 112 ppb, and the fragrance component is increased as the juice ratio increases. I understand that.
表4の官能評価結果より、対照品と比較して試験品2−2〜2−7を使用した際に、三杯酢の酢酸臭を顕著に低減し、風味の好ましさが向上していることが分かる。このとき、三杯酢中のβ−ダマセノンは57〜273ppb、β−イオノンは6〜20ppb、6−メチル−5−ヘプテン−2−オールは6〜24ppbとなった。 From the sensory evaluation results in Table 4, when using test samples 2-2 to 2-7 compared to the control product, the acetic acid odor of three cups of vinegar is significantly reduced, and the taste preference is improved. I understand. At this time, β-damasenone in three cups of vinegar was 57 to 273 ppb, β-ionone was 6 to 20 ppb, and 6-methyl-5-hepten-2-ol was 6 to 24 ppb.
ドレッシングでも、対照品と比較して試験品2−2〜2−7を使用した際に、酢酸臭を顕著に低減し、風味の好ましさが向上していることが分かる。このとき、三杯酢中のβ−ダマセノンは47〜228ppb、β−イオノンは5〜17ppb、6−メチル−5−ヘプテン−2−オールは5〜20ppbとなった。 It can be seen that also in dressing, when the test products 2-2 to 2-7 were used as compared with the control product, the odor of acetic acid was remarkably reduced and the taste preference was improved. At this time, β-damasenone in three cups of vinegar was 47 to 228 ppb, β-ionone was 5 to 17 ppb, and 6-methyl-5-hepten-2-ol was 5 to 20 ppb.
試験品2−1は、β−ダマセノンを54ppb、β−イオノンを3ppb、6−メチル−5−ヘプテン−2−オールを8ppb含有していたが、酢酸臭低減効果は見られたものの、顕著な風味の好ましさの向上は見られなかった。これは上記3香気成分以外の、トマト果汁由来成分の影響であると考えられる。 Although the test product 2-1 contained 54 ppb of β-damasenone, 3 ppb of β-ionone, and 8 ppb of 6-methyl-5-hepten-2-ol, although the effect of reducing acetic acid odor was observed, it was remarkable. There was no improvement in flavor preference. This is considered to be an effect of components derived from tomato juice other than the above three aroma components.
以上の結果より、トマト搾汁濃縮液を醤油に添加することにより、β−ダマセノン、β−イオノン、6−メチル−5−ヘプテン−2−オールの濃度が増加し、酢酸臭低減効果を向上した調味料が得られた。このような調味料は、調味酢やドレッシングに配合することで酢酸臭低減効果を示し、風味も優れていることが示された。 From the above results, by adding the tomato juice concentrate to soy sauce, the concentration of β-damasenone, β-ionone, 6-methyl-5-hepten-2-ol was increased, and the effect of reducing acetic acid odor was improved. A seasoning was obtained. It was shown that such a seasoning showed an acetic acid odor reduction effect by blending with seasoning vinegar or dressing, and an excellent flavor.
Claims (6)
醤油および5〜1000ppbのβ−イオノンを含有し、および/または
1000〜5000ppbの6−メチル−5−ヘプテン−2−オールを含有する
調味料。 Contains soy sauce and 200-1300 ppb β-damercenone, and / or contains soy sauce and 5-1000 ppb β-ionone, and / or 1000-5000 ppb 6-methyl-5-hepten-2-ol seasoning.
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