JP5973205B2 - Processed powder for cosmetics and cosmetics containing the same - Google Patents

Description

  The present invention relates to a cosmetic powder obtained by coating a powder of a solid UV absorber solid at 25 ° C. and a surfactant solid at 25 ° C. More specifically, the cosmetic has a high UV protection effect and excellent usability. It relates to powder for use. Moreover, this invention relates to the cosmetics which mix | blend the cosmetic powder.

Conventionally, UV absorbers, UV scattering agents, and the like are blended in cosmetics having UV protection effects. Cinnamic acid type, benzoic acid ester type, salicylic acid type, benzophenone type, dibenzoylmethane type UV absorber, triazine type UV absorber, etc. are blended as UV absorbers, and the properties are liquid to solid It is various. Among them, dibenzoylmethane-based and triazine-based ultraviolet absorbers are attracting attention because they have a high molar extinction coefficient and can absorb ultraviolet rays having a wider wavelength (see, for example, Patent Document 1). Dibenzoylmethane-based and triazine-based UV absorbers are attractive materials that protect against ultraviolet rays, but their properties are solid, so when blended into cosmetics, they can be dissolved and dispersed with other oil components. It was necessary to consider the properties, and there were cases where blending was difficult. There was a problem that the UV protection effect could not be fully exhibited if it could not be dissolved or dispersed uniformly in the cosmetic.
Therefore, studies have been made on the combination of an ultraviolet absorber and powder. For example, a method in which powder and a hardly soluble ultraviolet absorber are mixed under heating and then cooled and coated, a method of coating by a mechanochemical method (for example, Patent Document 2), or a method of compounding in a supercritical fluid (for example, Patent Document 3) has been studied.

JP-A-9-188666 International Publication No. WO 98/09610 JP 2008-115270 A

  However, in the method of simply mixing the poorly soluble UV absorber and the powder, when the powder is coated with the solid UV absorber, the powder aggregates or the UV absorber is localized and evenly distributed. When the phenomenon of not being coated occurs, it may cause problems such as poor spread when used as cosmetics and unevenness of the cosmetic film, and it may not be possible to demonstrate the UV protection effect more efficiently. there were. In addition, the method of compounding in a supercritical fluid has a problem that high temperature and high pressure are required for production, and a cosmetic method in which a solid UV absorber is uniformly coated on a powder by a simpler method. It was desired to obtain powder for use

  In view of this situation, as a result of intensive studies, the present inventor has conducted a surface treatment with a solid oil-soluble UV absorber that is solid at 25 ° C. and a solid surfactant at 25 ° C. By improving the dispersibility of the absorbent and further suppressing the aggregation between the powders, the localization of the oil-soluble ultraviolet absorbent in the treated powder is prevented, and the powder is uniformly treated on the surface. As a result, it has been found that a treatment powder for cosmetics having a high UV protection effect and excellent usability can be obtained, and the present invention has been completed.

That is, the present invention
The following components (a) and (b);
(A) An oil-soluble ultraviolet absorbent that is solid at 25 ° C. (b) A treated powder for cosmetics that is surface-treated with a solid surfactant at 25 ° C.

  (2) Further, the oil-soluble ultraviolet absorber solid at 25 ° C. of the component (a) is dioctylbutamide triazone, 4-tert-butyl-4′-methoxy-dibenzoylmethane, 2,4,6- Tris [4- (2-ethylhexyloxycarbonyl) anilino] -1,3,5-triazine, diethylaminohydroxybenzoylhexylbenzoate, 2,4-bis {[4- (2-ethyl-hexyloxy) -2-hydroxy] A cosmetic powder for cosmetics according to (1), characterized in that it is one or more selected from -phenyl} -6- (4-methoxyphenyl)-(1,3,5) -triazine. Is.

  (3) One or more selected from surfactants that are solid at 25 ° C. of the component (b) selected from phospholipids, sorbitan stearate, sorbitan sesquistearate, sorbitan palmitate, and sorbitan sesquipalmitate The cosmetic powder for cosmetics according to (1) or (2) is provided.

  (4) Further, the cosmetic-treated powder according to any one of (1) to (3), wherein the cosmetic-treated powder contains titanium oxide and / or zinc oxide. It is to provide.

  (5) Further, the components (a) and (b) are dissolved in a volatile solvent, mixed with powder and then subjected to surface treatment by drying and removing the volatile solvent. (4) The processed powder for cosmetics according to any one of (4) is provided.

  (6) Moreover, the cosmetics characterized by mix | blending the processing powder for cosmetics of said (1)-(5) are provided.

  (7) The cosmetic according to (6) is provided, wherein the cosmetic is in a powder form.

  The treated powder for cosmetics of the present invention is an oil-soluble ultraviolet absorber uniformly coated on the powder, and has high dispersibility in the cosmetic. By blending it, the UV protection effect is high and light. The present invention relates to a cosmetic that is excellent in feeling of use such as spreading and that provides a uniform cosmetic film.

Hereinafter, the present invention will be described in detail.
The component (a) used in the present invention is a solid oil-soluble UV absorbent that is solid at 25 ° C. so as to protect the skin from UV rays, and is solid at 25 ° C. and oil-soluble. Although not particularly limited, 2- [4- (diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester, ethyl paraaminobenzoate, benzophenone-1, benzophenone-3, benzophenone-6, benzophenone-9, 2, 4, 6 -Tris [4- (2-ethylhexyloxycarbonyl) anilino] -1,3,5-triazine, dioctylbutamide triazone, 4-tert-butyl-4'-methoxy-dibenzoylmethane, 2,4-bis { [4- (2-Ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl)-(1,3,5)- Triazine and the like, can be used more than those one or two. Among these, dioctylbutamide triazone, 4-tert-butyl-4′-methoxy-dibenzoylmethane, 2,4,6-tris [4- (2-ethylhexyloxycarbonyl) anilino] -1,3,5- Triazine, diethylaminohydroxybenzoylhexyl benzoate, 2,4-bis {[4- (2-ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl)-(1,3,5) -Triazine is preferred because of its high ultraviolet protection effect when the powder is surface-treated.
As a commercial product, 2,4,6-tris [4- (2-ethylhexyloxycarbonyl) anilino] -1,3,5-triazine is UVINUL
Examples of T-150 (manufactured by BASF) and dioctylbutamide triazone include UVASORB HEB (manufactured by 3V GROUP).

  The treatment amount of the component (a) used in the cosmetic powder for cosmetics of the present invention is 0.01 to 30 parts by mass with respect to 100 parts by mass of the surface-treated powder, and is excellent in light elongation and UV protection effect. If it is 0.1-15 mass parts, since those effects are especially remarkable, it is still more preferable.

The component (b) used in the present invention, which is a solid surfactant at 25 ° C., is used together with the component (a) in the processing of the powder, thereby improving the dispersibility of the component (a) and absorbing ultraviolet rays. It is added to enhance the effect and improve the uniformity of the cosmetic film when the surface-treated powder is added to the cosmetic, and is not particularly limited as long as it is solid at 25 ° C. Nonionic surfactants such as amphoteric surfactants such as lipids, sorbitan stearate, sorbitan sesquistearate, sorbitan palmitate, sorbitan sesquipalmitate, polyoxyethylene hydrogenated castor oil, polyethylene glycol monostearate, polyethylene glycol monopalmitate Agent, stearic acid, palmitic acid, 12 hydroxystearic acid, polyoxyethylene cetylate Anionic surfactants such as alkali metal salts of luric acid and N-acyl amino acid salts, and cationic surfactants such as alkylammonium chloride can be used, and one or more of these can be used. Among them, phospholipid, sorbitan stearate, sorbitan sesquistearate, sorbitan palmitate, and sorbitan sesquipalmitate are preferable because the dispersion of component (a) can be improved. Among the phospholipids, hydrogenated phospholipid is preferable from the viewpoint of dispersibility of the oil-soluble ultraviolet absorber. The content of phosphatidylcholine contained in the phospholipid is preferably 50% by mass (hereinafter simply referred to as “%”) or more, more preferably 70% or more.
In addition, in order to obtain a light stretch spread and a uniform decorative film, the melting point of the component (b) is preferably 45 ° C to 100 ° C. It is more preferable from the viewpoint of ease.

  The amount of the component (b) used in the present invention is not particularly limited, but 1 to 200 parts by mass with respect to 100 parts by mass of the component (a) is excellent in the dispersibility of the component (a) and excellent in the ultraviolet protection effect. If it is 5-50 mass parts, since the dispersibility of a component (a) is especially favorable and it is excellent also in the uniformity of a decorative film, it is still more preferable. In addition, 0.01 to 10 parts by mass is preferable for 100 parts by mass of the surface-treated powder because a light stretch spread and a uniform decorative film can be obtained. Is more preferable because it is particularly remarkable.

  In order to treat uniformly on the surface of the powder, the component (a) used in the present invention and the component (b) used in the present invention should be heated and melted to the melting point of both of them and not phase separated when mixed. Further, when transparently dissolved, it is preferable that the effect is remarkably exhibited in forming a broader spread and a uniform decorative film. For example, 2,4,6-tris [4- (2-ethylhexyloxycarbonyl) anilino] -1,3,5-triazine and sorbitan sesquistearate or 4-tert-butyl-4'-methoxy-dibenzoylmethane A combination of phospholipid (phosphatidylcholine) and the like is preferable.

  The powder to be surface-treated in the present invention is not particularly limited as long as it is a powder usually used in cosmetics, and has a spherical shape, a plate shape, a needle shape, etc., a fog shape, a fine particle, a pigment grade, etc. The particle structure such as porous and nonporous is not particularly limited, and examples thereof include inorganic powders, glitter powders, organic powders, pigment powders, and composite powders. Specifically, titanium oxide, black titanium oxide, cerium oxide, conger, ultramarine, bengara, yellow iron oxide, black iron oxide, zinc oxide, aluminum oxide, anhydrous silicic acid, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate , Calcium sulfate, chromium oxide, chromium hydroxide, carbon black, aluminum silicate, magnesium silicate, magnesium aluminum silicate, mica, synthetic mica, sericite, talc, kaolin, silicon carbide, barium sulfate, bentonite, smectite, nitriding Inorganic powders such as boron, luminescent powder such as bismuth oxychloride, titanium oxide coated mica, iron oxide coated mica, iron oxide coated mica titanium, organic pigment coated mica titanium, aluminum powder, nylon powder, polymethyl methacrylate Pa Acrylonitrile-methacrylic acid copolymer powder, vinylidene chloride-methacrylic acid copolymer powder, polyethylene powder, polystyrene powder, organopolysiloxane elastomer powder, polymethylsilsesquioxane powder, polyurethane powder, wool powder, silk powder, Organic powders such as crystalline cellulose and N-acyl lysine, organic tar pigments, pigment powders such as organic pigment lake pigments, fine particle titanium oxide coated mica titanium, fine particle zinc oxide coated mica titanium, barium sulfate coated mica titanium, Examples include composite powders such as titanium oxide-containing silica and zinc oxide-containing silica, and one or more of these can be used.

Among these, it is preferable to include titanium oxide and zinc oxide in the surface-treated powder because a surface-treated powder having a higher ultraviolet protection effect can be obtained.
The amount of titanium oxide and zinc oxide contained in the cosmetic powder for cosmetics of the present invention is not particularly limited, but is preferably 1 to 100%, preferably 10 to 100% in the powder from the viewpoint of obtaining an ultraviolet protection effect. And the effect is further improved.

In this invention, it does not specifically limit as a method of processing these powder surfaces, Usually a well-known processing method is used. Specifically, a method of directly mixing with powder (dry processing method), a method using a solvent such as ethanol, isopropyl alcohol, n-hexane, light isoparaffin, benzene, toluene, etc. (wet method), a gas phase method, a mechanochemical Law.
A particularly preferred embodiment is a wet method, more specifically, a method in which the component (a) and the component (b) are dissolved in a volatile solvent by heating and then mixed with the powder, and the solvent is removed by drying. It is done. This method is preferable because the treatment on the powder surface becomes more uniform, and the uniformity of the decorative film and the UV protection effect are further enhanced.

  The treated powder for cosmetics of the present invention can be treated with other treatment agents, for example, silicone compounds, fluorine compounds and the like within a range not impeding the present invention.

In addition to the components described above, the cosmetic powder for cosmetics of the present invention is usually a component used in cosmetics, an ultraviolet absorber other than component (a), a surfactant other than component (b), an oil agent, The present invention includes oil gelling agents, water-soluble components such as water-soluble polymers and alcohols, oil-soluble film forming agents such as trimethylsiloxysilicic acid, paraoxybenzoic acid derivatives, preservatives such as phenoxyethanol, vitamins, cosmetic ingredients, and fragrances. It can mix | blend suitably in the range which does not impair the effect.
In addition, in the cosmetic compounded with the cosmetic powder for cosmetics of the present invention, these components can be appropriately blended within the range not impairing the effects of the present invention, in the same manner as the cosmetic powder for cosmetics. The powder that has not been subjected to the surface treatment of the present invention can be appropriately blended within a range that does not impair the effects of the present invention.

  UV absorbers other than component (a) include salicylic acid series such as 2-ethylhexyl salicylate, PABA series such as ethyl paradihydroxypropylbenzoate, 2- {4- (diethylamino) -2-hydroxybenzoyl} benzoyl hexyl , Cinnamic acid such as paramethoxycinnamic acid-2-ethylhexyl, 2-2′-methylene-bis- {6- (2H-benzotriazol-2-yl) -4- (1,1,3,3, -tetra Methylbutyl) phenol}, phenylbenzimidazolesulfonic acid and the like, and one or more of them can be used. Moreover, a component (a) can be contained in the range which does not prevent the effect of this invention.

  Surfactants other than component (b) are those that are liquid to paste at 25 ° C. and are glycerin fatty acid esters and their alkylene glycol adducts, polyglycerin fatty acid esters and their alkylene glycol adducts, propylene glycol fatty acid esters and their Nonionic such as alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, sorbitol fatty acid ester and its alkylene glycol adduct, polyalkylene glycol fatty acid ester, polyoxyalkylene-modified silicone, polyoxyalkylene alkyl co-modified silicone, etc. Surfactants, alkylbenzene sulfate, alkyl sulfonate, α-olefin sulfonate, dialkyl sulfosuccinate, α-sulfurate Phonated fatty acid salt, acylmethyl taurate, N-methyl-N-alkyl taurate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, poly Anionic surfactants such as oxyethylene alkylphenyl ether phosphates, N-acyl-N-alkyl amino acid salts, positive amines such as alkylamine salts, polyamines and alkanoylamine fatty acid derivatives, alkylammonium salts, and alicyclic ammonium salts Examples thereof include ionic surfactants, amphoteric surfactants such as N, N-dimethyl-N-alkyl-N-carboxymethylammonium betaine, and the like, and one or more of them can be used. Moreover, a component (b) can be contained in the range which does not prevent the effect of this invention.

  Examples of oils include paraffin wax, ceresin wax, ozokerite, microcrystalline wax, montan wax, fisher trops wax, polyethylene wax, liquid paraffin, squalane, petrolatum, polyisobutylene, polybutene and other hydrocarbons, carnauba wax, beeswax, etc. , Natural waxes such as lanolin wax and candelilla, glyceryl 2-ethylhexanoate, pentaerythritol ester of rosin acid, cetyl isooctanoate, isopropyl myristate, diglyceryl triisostearate, dipentaerythritol fatty acid ester, diiso malate Esters such as stearyl, dimer linoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), stearic acid, behenic acid Fatty acids such as 12-hydroxystearic acid, higher alcohols such as cetanol, stearyl alcohol, and behenyl alcohol, lanolin derivatives such as lanolin fatty acid isopropyl, lanolin alcohol, N-laureuil L-glutamic acid di (cholesteryl, behenyl, octyldodecyl), etc. These amino acid derivatives, fluorine-based oils such as perfluoropolyether, perfluorodecane, and perfluorooctane can be used, and one or more of these can be used.

  As the oil gelling agent, any one can be used as long as it is usually used in cosmetics. Examples thereof include dextrin fatty acid ester, sucrose fatty acid ester, starch fatty acid ester, hydroxystearic acid, calcium stearate, and the like. Or 2 or more types can be used.

  The aqueous component may be any component that is soluble in water, for example, lower alcohols such as ethyl alcohol and propyl alcohol, propylene glycol, 1,3-butylene glycol, dipropylene glycol, and 1,2-pentane. Diols, glycols such as polyethylene glycol, glycerols such as glycerin, diglycerin, polyglycerin, plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender, rose, etc. Cellulose derivatives such as methylcellulose, hydroxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, carboxymethylcellulose, sodium alginate, carragina Natural polymers such as quince seed gum, agar, gelatin, xanthan gum, locust bean gum, pectin, gellan gum, polyvinyl alcohol, carboxy vinyl polymer, alkyl-added carboxy vinyl polymer, sodium polyacrylate, sodium polymethacrylate, Synthetic polymers such as polyacrylic acid glycerin ester and polyvinylpyrrolidone can be used, and one or more of these can be used.

  The cosmetic treatment powder in the cosmetic of the present invention can be used singly or in combination of two or more, and the blending amount is not particularly limited, but is preferably 5 to 100% from the viewpoint of obtaining a sufficient UV protection effect, If it is 20 to 100%, the effect is improved, and it is more preferable.

  The cosmetic of the present invention may be any of powder, water, oil-in-water, water-in-oil, oil, and the like, and can be prepared by a conventional method with other components used as necessary. It can be implemented in various forms such as powder, liquid, emulsion, cream, solid, gel, and paste. Among these, since it is easy to obtain the lightness of spreading and a high UV protection effect, powder form is preferable. The cosmetic of the present invention can be applied to products such as emulsions and creams, sunscreens, makeup bases, foundations, concealers, white powders, blushers, eye shadows, lipsticks, etc., especially sunscreens, makeup bases, foundations. Those used for white powder and the like are preferable.

  Hereinafter, the present invention will be described in more detail with reference to examples. Note that these do not limit the present invention.

Examples 1-2 and Comparative Examples 1-3: Processed powder for cosmetics Processed powder for cosmetics having the composition shown in Table 1 was prepared by the following production method. Moreover, the ultraviolet-ray protective effect was evaluated by the following evaluation method and evaluation criteria. The results are also shown in Table 1.

(Production method)
A: Components 1 and 2 are mixed.
B: Component 9 is added to components 3 to 8, and heated and dissolved at 70 ° C.
C: A is added to B and mixed.
D: C is heated to 80 ° C. and component 9 isopropyl alcohol is dried under reduced pressure.
E: D is pulverized with a pulverizer.

〔Evaluation method〕
UV protection effect 40 mg of each sample was applied on a 5 cm × 8 cm square surgical tape (model number: 1526 manufactured by Sumitomo 3M) with a puff of the treated powder for cosmetics of the example and the comparative example, and SPF Analyzer System UV-1000S ( The transmittance of 350 nm, which is the UVA region, was calculated from the average value of 15 measurements per sample (N = 3) and determined using the following four-step criteria.

4-step criteria (evaluation): (judgment)
The UVA transmittance is less than 10%, and the blocking effect is very good:
The UVA transmittance is 10% or more and less than 15%, and the blocking effect is good: ○
The UVA transmittance is 15% or more and less than 20%, and the blocking effect is slightly inferior: Δ
The UVA transmittance is 20% or more, and the blocking effect is inferior: ×

  As the cosmetic treatment powders of Examples 1 and 2 of the present invention, those having a high ultraviolet protection effect were obtained. On the other hand, in Comparative Example 1 in which no surfactant was used, the UV absorber was not uniformly treated on the surface, and the UV protection effect was poor. Moreover, the comparative example 2 which used the liquid surfactant instead of solid was also inferior in the ultraviolet protective effect because the uniformity of the ultraviolet absorber was insufficient. In Comparative Example 3 in which solid oil was used in place of the surfactant, the powders aggregated, and the ultraviolet absorber was not uniformly treated and was inferior in the ultraviolet protection effect.

Examples 3 to 8: Treated powder for cosmetics Treated powder for cosmetics having the composition shown in Table 2 was prepared by the following production method and used as a cosmetic powder.

(Production method)
A: Components 1 to 9 are mixed.
B: The component 15 is added to the components 10-14, and it heat-dissolves at 70 degreeC.
C: A is added to B and mixed.
D: C is heated to 80 ° C. and component 15 isopropyl alcohol is dried under reduced pressure.
E: D is pulverized with a pulverizer.

Examples 9 to 10 and Comparative Examples 4 to 6: White powder White powder was prepared by the composition shown in Table 3 and the following production method. In addition, the following evaluation methods and evaluation criteria were used to evaluate the lightness of spreading, uniformity of the decorative film, and UV protection effect. The results are also shown in Table 3.

(Production method)
A: Components 1 to 20 are mixed.
B: Components 21 to 23 are added to A and mixed.
C: B is pulverized with a pulverizer.
D: C was filled in a resin container to obtain a powdery white powder.

[Evaluation Method 1]
Twenty cosmetic panel specialists used the white powders of the examples and comparative examples shown in Table 3 for each item of “lightness of spread” and “uniformity of makeup film”. Each of them was evaluated in five stages according to the following evaluation criteria, given a score for each sample, and the average score of all the panels was determined according to the following criteria.
Evaluation criteria:
[Evaluation Result]: [Score]
Very good: 5 points Good: 4 points Normal: 3 points Somewhat bad: 2 points Bad: 1 point Judgment criteria:
[Average score]: [Judgment]
4.5 or more: ◎
3.5 or more and less than 4.5: ○
1.5 or more and less than 3.5: △
Less than 1.5: ×

[Evaluation Method 2]
Ultraviolet ray protection effect The transmittance of 350 nm was calculated using the same method as the cosmetic powders of Examples 1 and 2, and the determination was made using the following four-step criteria.
(G) Four-step criteria (evaluation): (judgment)
The UVA transmittance is less than 20%, and the blocking effect is very good:
The UVA transmittance is 20% or more and less than 30%, and the blocking effect is good: ○
The UVA transmittance is 30% or more and less than 40%, and the blocking effect is slightly inferior: Δ
The UVA transmittance is 40% or more, and the blocking effect is inferior: ×

As is apparent from the results in Table 2, the white powders of Examples 9 to 10 of the present invention were excellent in all items of “lightness of spreading”, “uniformity of the cosmetic film”, and “ultraviolet ray protection effect”. It was a powdery cosmetic.
On the other hand, in Comparative Example 4 in which the component (a) at 25 ° C. and no solid UV absorber was blended, the powder aggregated into a lumpy shape, and “lightness of spread” and “uniformity of the cosmetic film” It was inferior to. Moreover, it was inferior to the “ultraviolet ray protection effect”.
Further, in Comparative Example 5 in which a liquid surfactant was blended in place of the solid surfactant at 25 ° C. as component (b), the adhesiveness to the skin was too strong, and a “feeling of spreading” was not felt. It was particularly inferior to "lightness".
Furthermore, in Comparative Example 6 in which a wax was blended in place of the solid surfactant at 25 ° C. as component (b), the adhesion to the skin was too strong and the dispersibility of the UV absorber was poor, resulting in color unevenness. Both the “lightness of spread and spread” and “uniformity of the decorative film” were inferior. Moreover, the “ultraviolet ray protection effect” was also inferior.
Further, in Comparative Example 7 in which the surface of the powder and the ultraviolet absorbent were not treated on the powder surface at 25 ° C., but simply mixed, the ultraviolet absorbent was localized in the cosmetic, and “uniformity of the cosmetic film” , "UV protection effect" was inferior.

Example 11: Water-in-oil type emulsified base (component) (%)
1. Treatment powder for cosmetics of Example 1 8
2. Red 226 0.15
3. Stearic acid (5%) treated yellow iron oxide 0.5
4). Methyltrimethicone 20
5. Organopolysiloxane graft polyoxyalkylene modified silicone * 1 3
6). Sorbitan sesquiisostearate 1
7). Isotridecyl isononanoate 5
8). Diisostearyl malate 3
9. Glyceryl triisostearate 4
10. Lauroyl glutamate di (phytosteryl /
Octyldodecyl) 2
11 Silicone composite spherical powder * 2 3
12 Methyl methacrylate cross polymer * 3 2
13. Dimethyl distearyl ammonium hectorite 1
14 Methylparaben 0.1
15. Ethyl alcohol 5
16. Glycerin 3
17. Rosemary extract 0.1
18. Purified water remaining amount 19. Perfume proper amount20. Sodium chloride 1
21. Methylenebisbenzotriazolyltetramethylbutylphenol 2
* 1: KF-6038 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 2: KSP-100 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 3: Matsumoto Microsphere M-305 (Matsumoto Yushi Seiyaku Co., Ltd.)

(Production method)
A: Components 1-3, 11-13 are dispersed in components 4-10.
B: Components 14 to 20 are mixed and dissolved.
C: Component 21 is dispersed in B.
D: C was added to A to emulsify, and the mixture was filled in a container to obtain a water-in-oil base.
The water-in-oil type emulsified base of Example 11 of the present invention was excellent in all items of “lightness of spreading”, “uniformity of cosmetic film”, and “ultraviolet ray protection effect”.

Example 12: Powder foundation (component) (%)
1. Treatment powder for cosmetics of Example 4 5
2. Treatment powder for cosmetics of Example 5 10
3. Silicone-treated titanium oxide (particle diameter 0.25 μm) 5
4). Silicone-treated zinc oxide (particle size 0.5 μm) 5
5. Octyltriethoxysilane-treated sericite 25
6). Nylon powder (particle size 10μm) 5
7). Boron nitride 5
8). 8. remaining amount of talc Silicone elastomer powder * 4 1
10. Magnesium stearate 1
11 Methyl methacrylate cross polymer * 3 4
12 Methylparaben 0.2
13. Paramethoxycinnamic acid-2-ethylhexyl 3
14 PEG-10 hydrogenated castor oil 0.5
15. Squalane 3
16. Di-2-ethylhexyl succinate 3
17. Orange oil 0.1
18. Astaxanthin 0.001
19. Perfume proper amount * 4: Trefil E-506C (manufactured by Toray Dow Corning)

(Production method)
A: Components 1 to 12 are mixed with a Henschel mixer.
B: Components 13 to 19 are mixed with A.
C: B is pulverized with a pulverizer.
D: C was filled in a resin pan and pressure molded to obtain a powder foundation.
The powder foundation of Example 12 of the present invention was excellent in all items of “lightness of spreading”, “uniformity of cosmetic film”, and “ultraviolet ray protection effect”.

Example 13: Oil-in-water emulsion sunscreen (component) (%)
1. Treated powder for cosmetics of Example 15 15
2. Dimethylpolysiloxane * 5 8
3. Organopolysiloxane graft polyoxyalkylene modified silicone * 1 1
4). Tri (capryl / capric) glyceryl 3
5. 2-methoxyhexyl paramethoxycinnamate 5
6). Liquid paraffin 1
7). Stearic acid 1.5
8). Oleic acid PEG-20 acid sorbitan 1
9. Cetostearyl alcohol 0.5
10. Phospholipid 0.3
11 Phenoxyethanol 0.3
12 Ethyl alcohol 5
13.1,3-Butylene glycol 5
14 Triethanolamine 1.5
15. Purified water remaining amount 16. Carboxyvinyl polymer (1% aqueous solution) 20
17. Acetylated sodium hyaluronate (1% aqueous solution) 1
* 5: KF-96 (2CS) (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 3 are bead-milled and mixed uniformly.
B: Components 4 to 10 are heated and dissolved at 70 ° C., and A is mixed.
C: Components 11 to 17 are mixed and dissolved.
D: B was added to C and emulsified, and the mixture was filled in an oil-in-water emulsion sunscreen.
The oil-in-water emulsified sunscreen of Example 13 of the present invention was excellent in all items of “lightness of spread”, “uniformity of cosmetic film”, and “ultraviolet ray protection effect”.

Example 14: Oily solid concealer (component) (%)
1. Treated powder for cosmetics of Example 3 25
2. Treatment powder for cosmetics of Example 6 5
3. Treatment powder for cosmetics of Example 7 5
4). Diglyceryl triisostearate 5
5. Methylphenyl polysiloxane * 6 4
6). Cetyl polyether-modified silicone * 7 1
7). Decamethylcyclopentasiloxane 5
8). Cross-linked methylpolysiloxane /
Decamethylcyclopentasiloxane mixture * 8 10
9. 10. Glyceryl tri-2-ethylhexanoate Octyl palmitate 3
11 Paramethoxycinnamic acid-2-ethylhexyl 3
12 Ascorbyl tetrahexyldecanoate 1
13. Sorbitan sesquioleate 1
14 Diglyceryl diisostearate 3
15. Phospholipid 0.5
16. Microcrystalline wax 4
17. Carnauba wax * 9 2
18. Methylparaben 0.2
19. Nylon powder (particle size 6μm) 5
20. Silicone-treated mica titanium * 10 3
* 6: SH556 (Toray Dow Corning)
* 7: ABIL EM-90 (Evonik Goldschmidt)
* 8: KSG-15 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 9: Refined carnauba wax No. 1 (manufactured by Nippon Natural Products)
* 10: SA-Timilon Super Gold (manufactured by Miyoshi Kasei Kogyo Co., Ltd.)

(Production method)
A: Components 1 to 6 are roller-processed and mixed uniformly.
B: Components 10 to 18 are heated and dissolved at 90 ° C.
C: A and components 7 to 9, 19, and 20 are mixed with B.
D: C was dissolved at 90 ° C., poured into a metal pan and filled to obtain an oily solid concealer.
The oil-based solid concealer of Example 14 of the present invention was excellent in all items of “lightness of spreading”, “uniformity of cosmetic film”, and “ultraviolet ray protection effect”.

Example 15: Stick-shaped lipstick (ingredient) (%)
1. Treated powder for cosmetics of Example 2 2
2. Treatment powder for cosmetics of Example 6 4
3. Red No. 202 1.2
4). Yellow No. 4 0.8
5. Black iron oxide 0.1
6). Titanium oxide coated synthetic phlogopite * 11 3
7). Fluorine compound-treated mica titanium * 12 2
8). Silicic anhydride * 13 0.5
9. Glyceryl tri-2-ethylhexanoate 15
10. Diisostearyl malate 10
11 Paramethoxycinnamic acid-2-ethylhexyl 3
12 13. Diglyceryl triisostearate remaining amount Heavy liquid isoparaffin 20
14 Vaseline 3
15. Ethylene / propylene copolymer * 14 6
16. Polyethylene wax * 15 4
17. Ceramide 2 0.05
18. Methylparaben 0.1
19.2,6-Di-tert-butyl-p-cresol 0.05
20. Fragrance 0.3
* 11: HELIOS R100S (Topy Industries, Ltd.)
* 12: FLAMENCO RED (manufactured by BASF) treated with 3% perfluorooctyltriethoxysilane * 13: AEROSIL R976S (manufactured by AEROSIL)
* 14: EP-700 (manufactured by Baker Petrolite)
* 15: PERFORMALENE 655 (manufactured by Baker Petrolite)

(Production method)
A: Components 9 to 17 are dissolved by heating at 110 ° C.
B: Components 1 to 8 are added to A and mixed uniformly.
C: Components 18 to 20 are mixed with B.
D: C was dissolved at 90 ° C., poured into a mold and filled to obtain a stick-shaped lipstick.
The stick-shaped lipstick of Example 15 of the present invention was excellent in all items of “lightness of spreading”, “uniformity of cosmetic film”, and “ultraviolet ray protection effect”.

Example 16: Powdered foundation (component) (%)
1. Sericite 15
2. Synthetic phlogopite * 16 10
3. Iron-doped titanium oxide (particle size 0.27 μm) 12
4). Fine zinc oxide (particle diameter 15 nm) 5
5. 5. Talc remaining amount Lauroyl lysine 3
7). Plate-like barium sulfate (particle diameter 15 μm) 5
8). 8. remaining amount of talc Silicone composite spherical powder * 17 10
10. PET powder (particle diameter 6 μm) 5
11 Methyl methacrylate cross polymer * 3 10
12 Yellow iron oxide 1.5
13. Bengala 0.4
14 Black iron oxide 0.3
15. Methylparaben 0.2
16. Hydrogenated phospholipid 0.6
17. 2-Methoxyparacinnamic acid 2-ethylhexyl 2
18. 2- [4- (Diethylamino) -2-hydroxybenzoyl]
Benzoic acid hexyl ester 1
19.2,4-bis {[4- (2-ethyl-hexyloxy) -2-
Hydroxy] -phenyl} -6- (4-methoxyphenyl)-
(1,3,5) -Triazine 3
20. Lauroyl glutamate di (phytosteryl / behenyl /
Octyldodecyl 0.5
21. Oil-soluble rose extract 0.2
* 16: PDM-8W (Topy Industries, Ltd.)
* 17: KSP-101 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 14 are mixed uniformly.
B: 65 parts by mass of isopropyl alcohol is added to 7.5 parts by mass of components 15 to 21 and heated and dissolved at 70 ° C.
C: A is mixed with B.
D: C is heated to 80 ° C. and isopropyl alcohol is dried under reduced pressure.
E: D is pulverized with a pulverizer.
F: E was filled in a resin container to obtain a powdery foundation.
The powdery foundation of Example 16 of the present invention was excellent in all items of “lightness of spreading”, “uniformity of cosmetic film”, and “ultraviolet ray protection effect”.

Claims (6)

The following components (a) and (b);
(A) Dioctylbutamide triazone, 4-tert-butyl-4′-methoxy-dibenzoylmethane, 2,4,6-tris [4- (2-ethylhexyloxycarbonyl) anilino] -1,3,5- Triazine, diethylaminohydroxybenzoylhexyl benzoate, 2,4-bis {[4- (2-ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl)-(1,3,5) -One or two or more kinds of oil-soluble UV absorbers solid selected at 25 ° C selected from triazine (b) one selected from phospholipid, sorbitan stearate, sorbitan sesquistearate, sorbitan palmitate, sorbitan sesquipalmitate surface treated met cosmetic treatment powder in a solid surfactant or in two or more 25 ° C. After dissolving component (a) and component (b) in one or more volatile solvents selected from ethanol, isopropyl alcohol, n-hexane, light isoparaffin, benzene and toluene, and mixing with powder Treated powder for cosmetics that has been surface-treated by drying and removing volatile solvents .   The treated powder for cosmetics according to claim 1, wherein the surface-treated powder contains titanium oxide and / or zinc oxide.   A cosmetic comprising the treated powder for cosmetics according to claim 1 or 2.   The cosmetic according to claim 3, wherein the cosmetic is in a powder form. The following components (a) and (b);
(A ) Dioctylbutamide triazone, 4-tert-butyl-4′-methoxy-dibenzoylmethane, 2,4,6-tris [4- (2-ethylhexyloxycarbonyl) anilino] -1,3,5- Triazine, diethylaminohydroxybenzoylhexyl benzoate, 2,4-bis {[4- (2-ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl)-(1,3,5) -One or two or more kinds of oil-soluble UV absorbers solid selected at 25 ° C selected from triazine ( b) one selected from phospholipid, sorbitan stearate, sorbitan sesquistearate, sorbitan palmitate, sorbitan sesquipalmitate Or two or more surfactants that are solid at 25 ° C.
Or a component (a) and a component (b) selected from ethanol, isopropyl alcohol, n-hexane, light isoparaffin, benzene and toluene. A method for producing a processed powder for cosmetics, wherein the powder is dissolved in two or more volatile solvents, mixed with the powder, and then subjected to surface treatment by drying and removing the volatile solvent . 6. The method for producing a cosmetic powder for treatment according to claim 5, wherein the surface-treated powder contains titanium oxide and / or zinc oxide .