JP5962453B2 - Multilayer molded body with coating and method for coating multilayer molded body - Google Patents

Multilayer molded body with coating and method for coating multilayer molded body Download PDF

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JP5962453B2
JP5962453B2 JP2012253503A JP2012253503A JP5962453B2 JP 5962453 B2 JP5962453 B2 JP 5962453B2 JP 2012253503 A JP2012253503 A JP 2012253503A JP 2012253503 A JP2012253503 A JP 2012253503A JP 5962453 B2 JP5962453 B2 JP 5962453B2
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resin material
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JP2014100834A (en
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博隆 稲葉
博隆 稲葉
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Toyota Industries Corp
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Description

本発明は、被膜付き多層成形体および多層成形体の被膜方法に関する。   The present invention relates to a coated multilayer molded body and a method for coating a multilayer molded body.

近年、自動車のパノラマルーフやバックドア、クォータウィンドウ等の窓に、樹脂ウィンドウを採用することが多くなってきた。樹脂ウィンドウには、透明樹脂を板状に成形した後、その透明樹脂の一方の面に窓枠となる樹脂を射出成型する、いわゆる二色成形により作製されるものがある。二層成形は、たとえば、成形時に、窓枠の肉厚部で生じるヒケにより、外観が損なわれることを回避するため、窓枠と板状材を別個に射出成形をおこなう、といった目的で用いられる。なお、二層成形には、窓枠となる樹脂を板状の樹脂と異なる材質とした、いわゆる二色成形も含まれる。   In recent years, resin windows have been increasingly used for automobile panorama roofs, back doors, quarter windows and the like. Some resin windows are manufactured by so-called two-color molding, in which a transparent resin is molded into a plate shape, and then a resin that becomes a window frame is injection-molded on one surface of the transparent resin. The two-layer molding is used for the purpose of performing injection molding of the window frame and the plate-like material separately, for example, in order to avoid the appearance from being damaged due to sink marks generated in the thick part of the window frame during molding. . The two-layer molding includes so-called two-color molding in which the resin that becomes the window frame is made of a material different from the plate-like resin.

また、樹脂ウィンドウには、その表面に、ハードコート層や紫外線/赤外線カット層等の様々な機能を有する被膜を形成することも知られている。   It is also known that a film having various functions such as a hard coat layer and an ultraviolet / infrared cut layer is formed on the surface of the resin window.

樹脂ウィンドウの被膜には公知の多様な方法を用いることができる。ただし、スプレー塗布のように、液滴状の塗料を塗布する場合には、樹脂ウィンドウの表面に塗料の細かい凹凸が形成されやすく、見栄えが悪くなる上、被膜の機能低下を招くことも考えられる。   Various known methods can be used for coating the resin window. However, in the case of applying a droplet-like paint such as spray application, fine irregularities of the paint are easily formed on the surface of the resin window, the appearance is deteriorated, and the function of the film may be deteriorated. .

そのため、樹脂ウィンドウの被膜方法には、治具に立てかけた樹脂ウィンドウに上方から塗料を掛け流すフローコート法や、塗料の浴に樹脂ウィンドウを浸すディップ法などが適している。   Therefore, as a method for coating a resin window, a flow coat method in which a paint is poured from above onto a resin window standing on a jig, a dip method in which the resin window is immersed in a paint bath, and the like are suitable.

ただし、上述したフローコート法やディップ法であっても、二層成形による窓枠を有する樹脂ウィンドウに被膜を形成する際には、次のような課題が存在している。すなわち、窓枠となる樹脂が窓となる透明樹脂の上側に位置する領域の際に、樹脂から透明樹脂にスジ状に塗料が垂れて被膜に濃淡を生じさせてしまう現象(いわゆる、際ダレ)が生じるという問題があった。   However, even when the above-described flow coating method or dip method is used, there are the following problems when a film is formed on a resin window having a window frame by two-layer molding. In other words, when the resin that becomes the window frame is located on the upper side of the transparent resin that becomes the window, a phenomenon that the paint droops in a streaky manner from the resin to the transparent resin and causes the film to become shaded (so-called sag) There was a problem that occurred.

本発明は、上述の課題を解決するためになされたものであり、塗料の際ダレの抑制が図られた被膜付き多層成形体および多層成形体の被膜方法を提供することを目的とする。   The present invention has been made to solve the above-described problems, and an object of the present invention is to provide a multilayer molded body with a coating and a coating method for the multilayer molded body in which sagging is suppressed during coating.

本発明に係る被膜付き多層成形体は、少なくとも、板状の第1の樹脂材と、第1の樹脂材の一方面において第1の樹脂材の周囲を囲む枠状の第2の樹脂材とで構成され、且つ、第1の樹脂材の一方面において第1の樹脂材と第2の樹脂材の縁部とを一体的に覆う被膜が形成された被膜付き多層成形体であって、第2の樹脂材の縁部が、被膜の外縁位置から第2の樹脂材と第1の樹脂材との境界位置までの間に屈曲部がない非屈曲面で構成されている。   The multilayer molded body with a coating according to the present invention includes at least a plate-like first resin material, and a frame-like second resin material surrounding the first resin material on one surface of the first resin material, A multi-layer molded body with a coating, in which a coating integrally covering the first resin material and the edge of the second resin material is formed on one surface of the first resin material, The edge part of 2 resin material is comprised by the non-bending surface without a bending part between the outer edge position of a film, and the boundary position of a 2nd resin material and a 1st resin material.

発明者らは、被膜の外縁位置から第2の樹脂材と第1の樹脂材との境界位置までの間に屈曲部があると、被膜形成時に、その屈曲部に塗料溜まりが生じて、屈曲部に溜まった塗料が時間差で流れ落ちることが、際ダレの一因であるとの知見を得た。そこで、本発明に係る被膜付き多層成形体においては、被膜の外縁位置から第2の樹脂材と第1の樹脂材との境界位置までの間に屈曲部がない非屈曲面で、第2の樹脂材の縁部を構成することで、塗料が溜まりにくく、際ダレが効果的に抑制される。   The inventors have found that when there is a bent portion between the outer edge position of the film and the boundary position between the second resin material and the first resin material, a paint pool is formed in the bent portion when the film is formed, and the bent It was found that the paint accumulated in the part was caused by the time difference and was one of the causes of dripping. Therefore, in the multilayer molded body with a coating according to the present invention, the second bent portion has no bent portion between the outer edge position of the coating and the boundary position between the second resin material and the first resin material. By configuring the edge of the resin material, the paint is difficult to accumulate, and dripping is effectively suppressed.

また、第2の樹脂材の縁部における非屈曲面が湾曲面である態様であってもよい。非屈曲面が湾曲面であれば、塗料が溜まりにくく、際ダレが効果的に抑制される。   Further, the non-bending surface at the edge of the second resin material may be a curved surface. If the non-bending surface is a curved surface, the paint is difficult to accumulate, and dripping is effectively suppressed.

本発明に係る多層成形体の被膜方法は、少なくとも、板状の第1の樹脂材と、第1の樹脂材の一方面において第1の樹脂材の周囲を囲む枠状の第2の樹脂材とで構成された多層成形体の、第1の樹脂材の一方面に、第1の樹脂材と第2の樹脂材の縁部とを一体的に覆う被膜を形成する、多層成形体の被膜方法であって、被膜となるべき塗料を塗布する際、塗料が第2の樹脂材の上側の縁部から第1の樹脂材に向かって流れ落ちるように塗布し、且つ、第2の樹脂材と第1の樹脂材との境界位置までの間に屈曲部がない位置から塗布を開始する。   The method for coating a multilayer molded body according to the present invention includes at least a plate-like first resin material and a frame-like second resin material surrounding the periphery of the first resin material on one surface of the first resin material. The multilayer molded body is formed by forming a film integrally covering the first resin material and the edge of the second resin material on one surface of the first resin material of the multilayer molded body constituted by In the method, when applying the coating material to be a film, the coating material is applied so as to flow down from the upper edge of the second resin material toward the first resin material, and the second resin material and Application is started from a position where there is no bent portion up to the boundary position with the first resin material.

このような多層成形体の被膜方法においては、被膜となるべき塗料の塗布が開始される位置から第2の樹脂材と第1の樹脂材との境界位置までの間に屈曲部がないため、第2の樹脂材の上側の縁部から第1の樹脂材に向かって流れ落ちるように塗布される塗料が溜まりにくく、際ダレが効果的に抑制される。   In such a multilayer molded body coating method, since there is no bent portion between the position where the coating of the coating material to be coated starts and the boundary position between the second resin material and the first resin material, The coating applied so as to flow down from the upper edge of the second resin material toward the first resin material is unlikely to accumulate, and dripping is effectively suppressed.

また、フローコート法により塗料を塗布する態様であってもよい。フローコート法によれば、第2の樹脂材の上側の縁部に塗料を掛け流すことで、塗料が第1の樹脂材に向かって流れ落ちる。   Moreover, the aspect which apply | coats a coating material by the flow coat method may be sufficient. According to the flow coat method, the coating material flows down toward the first resin material by pouring the coating material on the upper edge of the second resin material.

本発明によれば、塗料の際ダレの抑制が図られた被膜付き多層成形体および多層成形体の被膜方法が提供される。   ADVANTAGE OF THE INVENTION According to this invention, the coating method of the multilayer molded object with a film by which suppression of dripping at the time of a coating was aimed at and the multilayer molded object is provided.

図1は、本発明の実施形態に係るパノラマルーフを示した概略模式図である。FIG. 1 is a schematic diagram showing a panoramic roof according to an embodiment of the present invention. 図2は、図1に示すパノラマルーフのII−II線断面図である。FIG. 2 is a cross-sectional view of the panoramic roof shown in FIG. 1 taken along the line II-II. 図3は、従来技術に係る窓枠材の断面図である。FIG. 3 is a cross-sectional view of a window frame material according to the prior art. 図4は、図2とは異なる態様の窓枠材を示した断面図である。FIG. 4 is a cross-sectional view showing a window frame member in a mode different from that in FIG.

以下、添付図面を参照して、本発明の好適な実施形態について詳細に説明する。なお、説明において、同一要素又は同一機能を有する要素には、同一符号を用いることとし、重複する説明は省略する。   Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. In the description, the same reference numerals are used for the same elements or elements having the same function, and redundant description is omitted.

図1は、本発明の実施形態に係る二色成形体である自動車のパノラマルーフ1を示した図であり、パノラマルーフ1が図示しない治具に立て掛けられた状態を示した図である。   FIG. 1 is a view showing a panorama roof 1 of an automobile which is a two-color molded body according to an embodiment of the present invention, and is a view showing a state where the panorama roof 1 is leaned against a jig (not shown).

パノラマルーフ1は、透明樹脂で構成される板状の窓材(第1の樹脂材)10と、黒色樹脂で構成される枠状の窓枠材(第2の樹脂材)20とを備えている。このパノラマルーフ1は、窓材10となる透明樹脂の一方の面に、窓枠材20となる黒色樹脂を射出成型して得られる、いわゆる(多層成形体の一種である)二色成形体である。   The panorama roof 1 includes a plate-like window material (first resin material) 10 made of a transparent resin and a frame-like window frame material (second resin material) 20 made of a black resin. Yes. This panoramic roof 1 is a so-called two-color molded body (which is a kind of multilayer molded body) obtained by injection molding a black resin to be a window frame material 20 on one surface of a transparent resin to be a window material 10. is there.

図1に示すように、窓枠材20は、窓材10の車室側の面10aにおいて、窓材10の周囲を囲むように配置されている。より具体的には、窓枠材20は、矩形状の2つの開口が左右に並ぶ形状を有しており、それらの各開口から窓材10が露出している。   As shown in FIG. 1, the window frame member 20 is arranged so as to surround the periphery of the window member 10 on the surface 10 a on the passenger compartment side of the window member 10. More specifically, the window frame member 20 has a shape in which two rectangular openings are arranged side by side, and the window member 10 is exposed from each of the openings.

パノラマルーフ1には、図2に示すように、耐候性や耐久性、耐擦傷性等の機能を有するハードコート層(被膜)30が形成されている。ハードコート層30は、窓枠材20の開口から露出する窓材10の車室側の面10aと、窓枠材20の開口周りの縁部22とを、一体的に覆っている。   As shown in FIG. 2, a hard coat layer (film) 30 having functions such as weather resistance, durability, and scratch resistance is formed on the panorama roof 1. The hard coat layer 30 integrally covers the cabin-side surface 10 a of the window member 10 exposed from the opening of the window frame member 20 and the edge 22 around the opening of the window frame member 20.

このようなハードコート層30は、たとえばフローコート法を用いた塗料の塗布によって形成することができる。以下、フローコート法を用いてハードコート層30を形成する方法について説明する。   Such a hard coat layer 30 can be formed, for example, by applying a paint using a flow coat method. Hereinafter, a method of forming the hard coat layer 30 using the flow coat method will be described.

ハードコート層30を形成する際には、図1に示したように、パノラマルーフ1を治具に略垂直に立て掛けた状態で、ホース40から、ハードコート層30となるべき塗料50を掛け流す。   When forming the hard coat layer 30, as shown in FIG. 1, the paint 50 to be the hard coat layer 30 is poured from the hose 40 in a state where the panorama roof 1 is leaned substantially vertically on the jig. .

このとき、塗料50は、ホース40から、窓枠材20の上側の縁部22の上述した外縁位置P(正確には外縁位置に対応する位置)に向かって放出される。すると、塗料50は、外縁位置Pから塗料50の塗布が開始され、縁部22の下方に位置する窓材10に向かって塗料50が流れ落ちる。その結果、ホース40から放出された塗料50は、窓枠材20の縁部22と窓材10とを一体的に覆うように塗布され、この塗料50が乾燥することで、上述したハードコート層30が形成される。   At this time, the paint 50 is discharged from the hose 40 toward the above-described outer edge position P of the upper edge portion 22 of the window frame member 20 (precisely, a position corresponding to the outer edge position). Then, the coating material 50 starts to be applied from the outer edge position P, and the coating material 50 flows down toward the window member 10 located below the edge portion 22. As a result, the paint 50 discharged from the hose 40 is applied so as to integrally cover the edge 22 of the window frame material 20 and the window material 10, and the paint 50 is dried, whereby the hard coat layer described above is applied. 30 is formed.

そして、窓枠材20の縁部22においては、ハードコート層30の外縁位置Pから窓枠材20と窓材10との境界位置Qまでの間の面22aが、屈曲部がない非屈曲面として湾曲面で構成されている。   And in the edge part 22 of the window frame material 20, the surface 22a between the outer edge position P of the hard-coat layer 30 and the boundary position Q of the window frame material 20 and the window material 10 is a non-bending surface without a bending part. As a curved surface.

発明者らは、窓材と窓枠材との境界に生じる塗料の際ダレの抑制に関し、鋭意研究の末、以下のような知見を得た。   The inventors have obtained the following knowledge as a result of diligent research regarding the suppression of dripping at the boundary between the window material and the window frame material.

すなわち、図3に示す従来技術に係る窓枠材120のように、その縁部122において、ハードコート層30の外縁位置Pから窓枠材120と窓材10との境界位置Qまでの間に屈曲部124があると、上述したハードコート層30の形成時に、屈曲部124に塗料溜まり32が生じやすい。そして、塗料溜まり32に溜まった塗料は、表面張力等の影響である程度の時間塗料溜まり32に留まり、他の塗料よりも遅れて時間差で流れ落ちる。この時間差で流れ落ちる塗料により、塗料の流下量の均一性が乱され、その結果、塗料の濃淡を生じることが際ダレの一因となる。   That is, like the window frame material 120 according to the prior art shown in FIG. 3, at the edge 122, between the outer edge position P of the hard coat layer 30 and the boundary position Q between the window frame material 120 and the window material 10. When the bent portion 124 is present, the paint pool 32 is likely to be generated in the bent portion 124 when the hard coat layer 30 described above is formed. The paint accumulated in the paint reservoir 32 remains in the paint reservoir 32 for a certain period of time due to the influence of surface tension and the like, and flows down with a time difference later than other paints. The paint flowing down with this time difference disturbs the uniformity of the flow rate of the paint, and as a result, the density of the paint is a factor in dripping.

そこで、発明者らは、窓枠材20の縁部22を非屈曲面22aで構成することを新たに見出した。それにより、塗料50が溜まる屈曲部が存在しないため、当然に、塗料溜まりは生じにくく、塗料50がスムースに窓枠材20の縁部22から流れ落ちるため、際ダレが効果的に抑制される。   Therefore, the inventors have newly found that the edge portion 22 of the window frame member 20 is constituted by a non-bending surface 22a. Accordingly, since there is no bent portion in which the paint 50 is accumulated, naturally, the paint accumulation is hardly generated, and the paint 50 smoothly flows down from the edge portion 22 of the window frame member 20, so that drooping is effectively suppressed.

このようにパノラマルーフ1においては、上述したとおり、際ダレが効果的に抑制されているため、際ダレを何らかの部材で覆い隠す必要がなく、意匠の自由度が高くなっている。そのため、パノラマルーフの樹脂化が促進されて、自動車の軽量化が進み、それは環境負荷の低減につながる。   Thus, in panorama roof 1, since drooping is effectively suppressed as described above, it is not necessary to cover the drooping with any member, and the degree of freedom of design is high. For this reason, the use of a panoramic roof as a resin has been promoted, and the weight of automobiles has been reduced, leading to a reduction in environmental burden.

図4は、上述した窓枠材20とは異なる態様の窓枠材20Aを示した図である。   FIG. 4 is a view showing a window frame member 20A having a different form from the window frame member 20 described above.

窓枠材20Aの縁部22においては、ハードコート層30の外縁位置Pから窓枠材20Aと窓材10との境界位置Qまでの間の非屈曲面22aが、平坦面で形成されている。具体的には、非屈曲面22aは、窓材10の表面10aに対し、縁に向かって次第に薄くなるように傾斜した傾斜面となっている。   At the edge portion 22 of the window frame member 20A, a non-bent surface 22a between the outer edge position P of the hard coat layer 30 and the boundary position Q between the window frame member 20A and the window member 10 is formed as a flat surface. . Specifically, the non-bending surface 22a is an inclined surface that is inclined with respect to the surface 10a of the window member 10 so as to become gradually thinner toward the edge.

窓枠材20Aのように、縁部22の非屈曲面22aが平坦面であっても、窓枠材20の縁部22の湾曲した非屈曲面22a同様、塗料50が溜まる屈曲部が存在しないため、塗料溜まりは生じにくく、際ダレが効果的に抑制される。   Like the window frame member 20A, even if the non-bent surface 22a of the edge 22 is a flat surface, there is no bent portion where the paint 50 is accumulated, like the curved non-bent surface 22a of the edge 22 of the window frame member 20. Therefore, paint accumulation is less likely to occur, and dripping is effectively suppressed.

ただし、パノラマルーフ1は二色成形体であり、窓枠材20、20Aは射出成形により形成されるため、薄い部分があるとそこには樹脂が入り込みにくい。そのため、射出成形の成形性の観点からは、非屈曲面22aの先端部分に薄い部分が生じる窓枠材20Aよりも、窓枠材20のほうが好ましい。   However, the panorama roof 1 is a two-color molded body, and the window frame members 20 and 20A are formed by injection molding. Therefore, if there is a thin portion, it is difficult for the resin to enter there. Therefore, from the viewpoint of moldability of injection molding, the window frame material 20 is more preferable than the window frame material 20A in which a thin portion is generated at the tip portion of the non-bent surface 22a.

なお、本発明は上記実施形態に限定されるものではなく、様々な変形が可能である。   In addition, this invention is not limited to the said embodiment, A various deformation | transformation is possible.

たとえば、被膜は、ハードコート層に限らず、紫外線カット層や赤外線カット層等の被膜であってもよい。   For example, the film is not limited to a hard coat layer, and may be a film such as an ultraviolet cut layer or an infrared cut layer.

また、被膜の形成は、フローコート法による塗料の塗布に限らず、ディップ法による塗料の塗布であってもよい。ディップ法であっても、引き上げた際に、フローコート法同様、塗料が窓枠材20から窓材10に流れ落ちるために、塗料が溜まる屈曲部が存在しないようにすることで、際ダレが効果的に抑制される。   The formation of the film is not limited to the application of the paint by the flow coat method, but may be the application of the paint by the dip method. Even when the dip method is used, when the paint is pulled up, since the paint flows down from the window frame material 20 to the window material 10 as in the case of the flow coating method, there is no bending portion where the paint accumulates, and this is effective. Is suppressed.

さらに、二色成形体は、パノラマルーフに限らず、バックドアやクォータウィンドウ等の樹脂ウィンドウであってもよく、また、窓枠材の開口が一つ又は三つ以上の樹脂ウィンドウであってもよい。   Furthermore, the two-color molded body is not limited to a panoramic roof, and may be a resin window such as a back door or a quarter window, or may have one or three or more resin windows. Good.

また、本発明は、上記実施形態の二色成形体(二層成形体)に限定されず、板状窓材と窓枠材とを別個に射出成形する多層成形の樹脂ウィンドウ(すなわち、多層成形体)に適用することができる。たとえば、板状窓材と窓枠材とが同材質の樹脂ウィンドウに適用することも可能である。また、板状窓材自体が二層以上の構造を有する、あるいは、窓枠材に厚みを増すために二層以上の構造を採用した三層以上の樹脂ウィンドウに適用することも可能である。   Further, the present invention is not limited to the two-color molded body (two-layer molded body) of the above-described embodiment, and is a multilayer molded resin window (that is, multilayer molded) in which a plate-like window material and a window frame material are separately injection-molded. Body). For example, the plate-like window material and the window frame material can be applied to a resin window made of the same material. Further, the plate-like window material itself may have a structure of two or more layers, or may be applied to a resin window of three or more layers adopting a structure of two or more layers in order to increase the thickness of the window frame material.

1…パノラマルーフ、10…窓材、20、20A…窓枠材、22…縁部、22a…非屈曲部、30…ハードコート層、50…塗料。   DESCRIPTION OF SYMBOLS 1 ... Panorama roof, 10 ... Window material, 20 and 20A ... Window frame material, 22 ... Edge part, 22a ... Unbent part, 30 ... Hard-coat layer, 50 ... Paint.

Claims (4)

少なくとも、板状の第1の樹脂材と、前記第1の樹脂材の一方面において前記第1の樹脂材の周囲を囲む枠状の第2の樹脂材とで構成され、且つ、前記第1の樹脂材の前記一方面において前記第1の樹脂材と前記第2の樹脂材の縁部とを一体的に覆う被膜が形成された被膜付き多層成形体であって、
前記第2の樹脂材の縁部が、前記被膜の外縁位置から前記第2の樹脂材と前記第1の樹脂材との境界位置までの間に屈曲部がない非屈曲面で構成されている、被膜付き多層成形体。
At least a plate-shaped first resin material and a frame-shaped second resin material surrounding the first resin material on one surface of the first resin material, and the first resin material A multi-layer molded body with a coating in which a coating that integrally covers the first resin material and the edge of the second resin material is formed on the one surface of the resin material,
The edge part of the second resin material is constituted by a non-bent surface having no bent part between the outer edge position of the coating and the boundary position between the second resin material and the first resin material. Multi-layer molded body with coating.
前記第2の樹脂材の縁部における非屈曲面が湾曲面である、請求項1に記載の被膜付き多層成形体。   The multilayer molded body with a film according to claim 1, wherein the non-bending surface at the edge of the second resin material is a curved surface. 少なくとも、板状の第1の樹脂材と、前記第1の樹脂材の一方面において前記第1の樹脂材の周囲を囲む枠状の第2の樹脂材とで構成された多層成形体の、前記第1の樹脂材の前記一方面に、前記第1の樹脂材と前記第2の樹脂材の縁部とを一体的に覆う被膜を形成する、多層成形体の被膜方法であって、
前記被膜となるべき塗料を塗布する際、前記塗料が前記第2の樹脂材の上側の縁部から前記第1の樹脂材に向かって流れ落ちるように塗布し、且つ、前記第2の樹脂材と前記第1の樹脂材との境界位置までの間に屈曲部がない位置から塗布を開始する、多層成形体の被膜方法。
A multilayer molded body composed of at least a plate-shaped first resin material and a frame-shaped second resin material surrounding the first resin material on one surface of the first resin material, A method of coating a multilayer molded body, wherein a film that integrally covers the first resin material and an edge of the second resin material is formed on the one surface of the first resin material,
When applying the coating material to be the film, the coating material is applied so as to flow down from the upper edge of the second resin material toward the first resin material, and the second resin material and A method for coating a multilayer molded body, wherein coating is started from a position where there is no bent portion between the first resin material and the boundary position.
フローコート法により前記塗料を塗布する、請求項3に記載の多層成形体の被膜方法。   The method for coating a multilayer molded article according to claim 3, wherein the paint is applied by a flow coating method.
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