JP5955416B2 - Bamboo powder-containing molded body, vehicle interior material and building material, and method for producing bamboo powder-containing molded body - Google Patents

Bamboo powder-containing molded body, vehicle interior material and building material, and method for producing bamboo powder-containing molded body Download PDF

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JP5955416B2
JP5955416B2 JP2014554023A JP2014554023A JP5955416B2 JP 5955416 B2 JP5955416 B2 JP 5955416B2 JP 2014554023 A JP2014554023 A JP 2014554023A JP 2014554023 A JP2014554023 A JP 2014554023A JP 5955416 B2 JP5955416 B2 JP 5955416B2
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bamboo powder
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lactic acid
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JPWO2014103034A1 (en
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俊博 竹鼻
俊博 竹鼻
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NHK Spring Co Ltd
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    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
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    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
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    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/02Manufacture of substantially flat articles, e.g. boards, from particles or fibres from particles

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Description

本発明は、竹粉含有成形体、車両用内装材及び建築用材料、並びに竹粉含有成形体の製造方法に関する。   The present invention relates to a bamboo powder-containing molded body, a vehicle interior material and a building material, and a method for producing a bamboo powder-containing molded body.

地球環境への配慮や植物の有効活用を図るため、原料の一部として植物由来の粉末等を配合して成形した各種部材が提案されている。例えば、原料の一部として竹を利用したトレー容器、合成板、空気入りタイヤが提案されている(特開2005−329688号公報、特開2008−030380号公報、特開2011−012110号公報参照)。   In order to consider the global environment and effectively use plants, various members formed by blending plant-derived powders as part of the raw materials have been proposed. For example, tray containers using bamboo as part of raw materials, synthetic boards, and pneumatic tires have been proposed (see Japanese Patent Application Laid-Open Nos. 2005-329688, 2008-030380, and 2011-012110). ).

成形体の原料の一部として竹を利用する場合、一般的には、維管束の繊維方向(竹の長手方向)に繊維化したものや、竹を炭化して粉化したものが用いられている。
竹を維管束の繊維方向に繊維化したものであれば、強度を高める効果が得られるが、線維化に大きなエネルギーが必要である。また、竹の繊維状物を用いるとささくれ等が発生する恐れがある。
When bamboo is used as a part of the raw material of the molded body, generally, fiberized in the fiber direction of the vascular bundle (longitudinal direction of bamboo) or carbonized and powdered bamboo is used. Yes.
If bamboo is fiberized in the fiber direction of the vascular bundle, the effect of increasing the strength can be obtained, but a large amount of energy is required for fibrosis. In addition, when bamboo fiber is used, there is a risk of occurrence of poultry.

一方、竹を炭化して粉末状にした竹粉では強度効果がほとんど得られない。また、例えば、竹を摩砕して得た粉状体をバインダーと配合して複合化するに際しても、押出、射出成形で大きなエネルギーが必要である。   On the other hand, the strength effect is hardly obtained with bamboo powder obtained by carbonizing bamboo into powder. Also, for example, when blending a powdery body obtained by grinding bamboo with a binder, a large amount of energy is required for extrusion and injection molding.

ところで、自動車や家の中では臭いがこもり易く、各種、脱臭剤や芳香剤が使用されている。例えば竹を炭化した竹炭や、竹粉に有機酸やビタミンCを塗布して脱臭機能を付与したものがあるが、その形態や用途は限られている。   By the way, odors tend to be trapped in automobiles and homes, and various deodorizers and fragrances are used. For example, there are bamboo charcoal obtained by carbonizing bamboo, and those obtained by applying a deodorizing function by applying organic acid or vitamin C to bamboo powder, but its form and use are limited.

本発明は、少ないエネルギーで製造することができ、安全で、かつ、脱臭及び強度効果が得られる竹粉含有成形体及びその製造方法並びにそれを用いた車両用内装材及び建築用材料を提供することを目的とする。   The present invention provides a bamboo powder-containing molded article that can be produced with less energy, is safe, and that can provide deodorization and strength effects, a method for producing the same, a vehicle interior material and a building material using the same. For the purpose.

上記目的を達成するため、以下の発明が提供される。
本発明の第1の側面によれば、維管束に由来する孔を有し、乳酸菌発酵させた鱗片状の竹粉を含む竹粉含有成形体が提供される。
前記鱗片状の竹粉が厚さ方向に層状に重なっていることが好ましく、また、バインダーを含むことが好ましい。
In order to achieve the above object, the following invention is provided.
According to the 1st side surface of this invention, the bamboo-powder containing molded object which has the hole derived from a vascular bundle and contains the scale-like bamboo powder fermented by lactic acid bacteria is provided.
The scaly bamboo powder is preferably layered in the thickness direction, and preferably contains a binder.

本発明の第2の側面によれば、維管束に由来する孔を有し、乳酸菌発酵させた鱗片状の竹粉及び水を含む竹粉分散液を用い、抄造法により、前記乳酸菌発酵させた鱗片状の竹粉を含むシート状物を形成するシート状物形成工程と、前記シート状物から水分を除去して1次成形体とする1次成形工程と、を含む竹粉含有成形体の製造方法が提供される。
前記竹粉分散液は、さらにバインダーを含むことが好ましい。また、前記1次成形体をホットプレスして2次成形体とする2次成形工程をさらに含むことができる。
According to the second aspect of the present invention, the lactic acid bacterium is fermented by a papermaking method using a bamboo powder dispersion containing scale-like bamboo powder and water that has pores derived from vascular bundles and is fermented with lactic acid bacteria. A bamboo powder-containing molded body comprising: a sheet-like material forming step for forming a sheet-like material containing scaly bamboo powder; and a primary molding step for removing moisture from the sheet-like material to form a primary molded body. A manufacturing method is provided.
The bamboo powder dispersion preferably further contains a binder. Further, the method may further include a secondary molding step in which the primary molded body is hot-pressed to form a secondary molded body.

本発明によれば、少ないエネルギーで製造することができ、安全で、かつ、脱臭及び強度効果が得られる竹粉含有成形体及びその製造方法並びにそれを用いた車両用内装材及び建築用材料が提供される。   ADVANTAGE OF THE INVENTION According to this invention, the bamboo powder containing molded object which can be manufactured with little energy, is safe, and can obtain a deodorizing and strength effect, its manufacturing method, and the interior material for vehicles, and the building material using the same Provided.

鱗片状の竹粉を製造する方法の一例を示す概略図である。It is the schematic which shows an example of the method of manufacturing scaly bamboo powder. 維管束に由来する孔を有する鱗片状の竹粉(乳酸菌発酵前)を示した画像である。It is the image which showed the scaly bamboo powder (before lactic-acid-bacteria fermentation) which has the hole originating in a vascular bundle. 竹の維管束内で増殖した乳酸菌を示す画像例である。It is an example of an image which shows the lactic acid bacteria which proliferated in the vascular bundle of a bamboo. 本発明に係る竹粉含有成形体の製造工程の一例を示す概略図である。It is the schematic which shows an example of the manufacturing process of the bamboo powder containing molded object which concerns on this invention. 抄造法により鱗片状の竹粉が層状に重なった成形体(1次成形体)の一例を示す画像である。It is an image which shows an example of the molded object (primary molded object) in which the scaly bamboo powder piled up in layers by the papermaking method. 竹を摩砕して得た竹粉を示した画像である。It is the image which showed the bamboo powder obtained by grinding bamboo.

以下、本発明に係る竹粉含有成形体及びその製造方法について具体的に説明する。   Hereinafter, the bamboo powder-containing molded article and the method for producing the same according to the present invention will be specifically described.

<竹粉含有成形体>
本発明に係る竹粉含有成形体(適宜、「成形体」と称する)は、維管束に由来する孔を有し、乳酸菌発酵させた鱗片状の竹粉(適宜、「乳酸菌発酵させた鱗片状の竹粉」又は「乳酸菌発酵させた竹粉」と称する場合がある)を含んで構成されており、乳酸菌発酵させた鱗片状の竹粉のほかに補強材料としてバインダーを含むことが好ましい。以下、本発明に係る竹粉含有成形体の構成成分について説明する。
<Bamboo powder-containing molded body>
The bamboo powder-containing molded product according to the present invention (suitably referred to as “molded product”) has a scale derived bamboo powder having pores derived from vascular bundles and fermented with lactic acid bacteria (appropriately, “scalar shaped fermented with lactic acid bacteria” It may be referred to as “bamboo powder” or “bamboo powder fermented with lactic acid bacteria”), and it is preferable to include a binder as a reinforcing material in addition to the flaky bamboo powder fermented with lactic acid bacteria. Hereinafter, the components of the bamboo powder-containing molded body according to the present invention will be described.

(乳酸菌発酵させた鱗片状の竹粉)
本発明の成形体に含まれる竹粉は、鱗片状(厚みが薄い板状体、鱗状、Flake状)であり、厚さ方向に維管束に由来する孔を有し、乳酸菌発酵させたものである。本発明で用いる鱗片状の竹粉の大きさは、厚さが好ましくは100〜1000μm、より好ましくは 300〜600μmあり、平面視した場合の径(幅)が好ましくは50〜3000μmであり、より好ましくは100〜800μmである。
(Scaly bamboo powder fermented with lactic acid bacteria)
The bamboo powder contained in the molded body of the present invention is a scale-like (thin plate-like body, scale-like, Flake-like) having pores derived from vascular bundles in the thickness direction and fermented with lactic acid bacteria. is there. The scale-like bamboo powder used in the present invention has a thickness of preferably 100 to 1000 μm, more preferably 300 to 600 μm, and a diameter (width) when viewed in plan is preferably 50 to 3000 μm. Preferably it is 100-800 micrometers.

乳酸菌発酵させるための鱗片状の竹粉は、竹を繊維と交差する方向で切削、好ましくは竹の維管束に対して略直角に切削(スライス)して得ることができる。例えば、図1に示すように、複数の円形のこぎり刃を重ねて配置した切削手段10を回転させ、竹の端面を切削手段10に押し当てて切削しながら竹12の維管束の方向(長手方向)に進行させる。これにより竹12の長手方向に伸びる維管束が垂直に切断され、図2に示すように維管束に由来する孔を有する鱗片状の竹粉を連続的に製造することができる。このような方法によれば、竹の竹齢に無関係に竹粉化することができ、また、竹やぶなどから切り出した竹をそのまま切削して加工することもできるため、少ないエネルギーにより一回の加工で例えば500μm程度の大きさの鱗片状の竹粉を効率的に得ることができる。   The scaly bamboo powder for fermenting lactic acid bacteria can be obtained by cutting (slicing) bamboo in a direction intersecting with the fibers, preferably at a substantially right angle to the bamboo vascular bundle. For example, as shown in FIG. 1, the direction of the vascular bundle of the bamboo 12 (longitudinal direction) is rotated while rotating the cutting means 10 in which a plurality of circular saw blades are stacked and pressing the end face of the bamboo against the cutting means 10. ). As a result, the vascular bundle extending in the longitudinal direction of the bamboo 12 is cut vertically, and as shown in FIG. 2, scaly bamboo powder having holes derived from the vascular bundle can be continuously produced. According to such a method, bamboo can be made into powder regardless of the age of the bamboo, and it is also possible to cut and process bamboo cut out from bamboo bamboo, etc., so that it can be processed once with less energy Thus, for example, scaly bamboo powder having a size of about 500 μm can be efficiently obtained.

本発明で用いる鱗片状の竹粉を製造するための切削手段としては、例えば、特開2003−236403号公報に記載されている竹粉製造装置を用いることができる。市販品としては、例えば、丸大鉄工(株)竹粉製造機「PANDA」を用いることができる。   As a cutting means for producing the scale-like bamboo powder used in the present invention, for example, a bamboo powder production apparatus described in JP-A-2003-236403 can be used. As a commercial item, for example, Marudai Iron Works Co., Ltd. bamboo powder manufacturing machine “PANDA” can be used.

なお、前述したように竹の維管束に対して略直角に切削(スライス)した場合、切削粉は通常は全て鱗片状の竹粉となるが、鱗片状以外の竹粉も若干混入する可能性もある。鱗片状以外の竹粉が混入したものを用いてもよいが、使用する竹粉のうち90質量%以上が乳酸菌発酵させた鱗片状の竹粉であることが好ましい。   As described above, when cutting (slicing) at a substantially right angle to the bamboo vascular bundle, the cutting powder is usually all scaly bamboo powder, but some bamboo powder other than scaly may be mixed in. There is also. A mixture of bamboo powder other than scaly may be used, but 90% by mass or more of the bamboo powder used is preferably scaly bamboo powder fermented with lactic acid bacteria.

若い竹をそのまま粉化すると、カビ等が発生し工業材料としては使えなかったが、維管束に由来する孔を有する鱗片状の竹粉とした上でサイレージ化することにより、少ないエネルギーによって保管することができる。
切削によって得た鱗片状の竹粉を乳酸菌発酵させる方法としては、竹に土着の乳酸菌を利用する方法又はサイレージ用乳酸菌を添加する方法が挙げられる。例えば、切削後の鱗片状の竹粉を真空パックすることで乳酸菌発酵(サイレージ化)が始まる。発酵時の温度は25℃〜45℃程度が好ましい。なお、乳酸菌は嫌気性雰囲気下で増殖するため、真空パックに限らず、酸素を含まない雰囲気下に置けばよい。乳酸菌発酵により、図3に示すように竹の維管束内で1μm程度の球状の乳酸菌を見つけることができる。
サイレージ化(乳酸菌発酵)を制御することにより、有機酸の生成も制御でき、脱臭効果も制御することができる。
When young bamboo is pulverized as it is, mold etc. is generated and it cannot be used as an industrial material, but it is stored with less energy by making it into flaky bamboo powder with holes derived from vascular bundles and silageizing it. be able to.
Examples of the method of fermenting the flaky bamboo powder obtained by cutting with lactic acid bacteria include a method of using indigenous lactic acid bacteria or a method of adding silage lactic acid bacteria to bamboo. For example, lactic acid bacteria fermentation (silage formation) starts by vacuum-packing scaly bamboo powder after cutting. The temperature during fermentation is preferably about 25 ° C to 45 ° C. Since lactic acid bacteria grow in an anaerobic atmosphere, they are not limited to vacuum packs, and may be placed in an atmosphere that does not contain oxygen. By lactic acid bacteria fermentation, spherical lactic acid bacteria of about 1 μm can be found in the vascular bundle of bamboo as shown in FIG.
By controlling silageation (fermentation of lactic acid bacteria), the production of organic acids can be controlled, and the deodorizing effect can also be controlled.

本発明の成形体に含まれる乳酸菌発酵させた鱗片状の竹粉の含有量は成形体の用途等に応じて決めればよい。乳酸菌発酵させた鱗片状の竹粉の含有量によって成形体の強度、脱臭性、通気性、重量などを調整することができる。例えば、乳酸菌発酵させた鱗片状の竹粉の含有量が多いほど脱臭性能を高くすることができる。
本発明の成形体において乳酸菌発酵させた鱗片状の竹粉が配合されている形態は特に限定されないが、曲げ強度が必要な時、厚さ方向に層状に重なっていることが好ましい。乳酸菌発酵させた鱗片状の竹粉が積層して一体的な状態となっていることで強度効果が得られるとともに、積層された鱗片状の竹粉は厚さ方向に貫通する孔に多数の乳酸菌を保持することができ、高い脱臭性能を有する成形体とすることができる。
The content of the scale-like bamboo powder fermented with lactic acid bacteria contained in the molded body of the present invention may be determined according to the usage of the molded body. The strength, deodorizing property, air permeability, weight, etc. of the molded product can be adjusted by the content of the scale-like bamboo powder fermented with lactic acid bacteria. For example, the deodorizing performance can be increased as the content of scale-like bamboo powder fermented with lactic acid bacteria increases.
The form in which the scale-like bamboo powder fermented with lactic acid bacteria is blended in the molded article of the present invention is not particularly limited, but when bending strength is required, it is preferable to overlap in the thickness direction. The layered bamboo flakes fermented with lactic acid bacteria are combined into an integrated state to provide a strength effect, and the laminated flake-shaped bamboo powder has numerous lactic acid bacteria in the holes penetrating in the thickness direction. Can be made, and it can be set as the molded object which has high deodorizing performance.

(バインダー)
バインダーは、主に成形体の強度を補強するために用いられるが、バインダーの添加により、成形体の強度のほか、密度や脱臭性も調整することができ、設計自由度を大きくすることができる。
(binder)
The binder is mainly used to reinforce the strength of the molded body, but by adding the binder, the density and deodorizing properties can be adjusted in addition to the strength of the molded body, and the degree of freedom in design can be increased. .

本発明で用いることができるバインダーとしては、鱗片状の竹粉と混ざり合うことで成形しやすく、成形体の強度を向上させることができ、かつ、竹を劣化させない温度(成形時間にもよるが、例えば250℃以下)で加工することができるものを用いればよい。例えば、鱗片状の竹粉と結合して一体となる繊維状又は粒子状の有機材料が好ましく、具体的には熱可塑性繊維、パルプを含む天然繊維、熱硬化性粉体等が挙げられる。   As a binder that can be used in the present invention, it is easy to mold by mixing with scaly bamboo powder, the strength of the molded body can be improved, and the temperature at which bamboo does not deteriorate (depending on the molding time). For example, what can be processed at 250 ° C. or lower) may be used. For example, a fibrous or particulate organic material combined with scale-like bamboo powder is preferable. Specific examples include thermoplastic fibers, natural fibers including pulp, and thermosetting powder.

バインダーとして用いることができる熱可塑性樹脂としては、例えば、ポリビニル系:アクリロニトリル−ブタジエン−スチレン樹脂、ポリ塩化ビニル、ポリスチレン、ポリ塩化ビニリデン、ポリフッ化ビニリデン、ポリ酢酸ビニル、ポリオレフィン系:ポリプロピレン、ポリエチレン、ポリエステル系:アクリル樹脂、ポリエチレンテレフタレート、ポリアミド系:ポリアミド6,11,12、熱可塑性ポリウレタン系などが挙げられ、熱可塑性樹脂又は熱可塑性エラストマー等の被覆層を有する繊維状物を用いてもよい。
繊維状物の繊維長さは好ましくは0.5〜20mmであり、より好ましくは1〜10mmであり、線維径は好ましくは10〜300μmであり、より好ましくは20〜200μmである。
Examples of the thermoplastic resin that can be used as the binder include polyvinyl: acrylonitrile-butadiene-styrene resin, polyvinyl chloride, polystyrene, polyvinylidene chloride, polyvinylidene fluoride, polyvinyl acetate, polyolefins: polypropylene, polyethylene, and polyester. System: acrylic resin, polyethylene terephthalate, polyamide system: polyamide 6, 11, 12, thermoplastic polyurethane system, and the like may be used, and a fibrous material having a coating layer such as a thermoplastic resin or a thermoplastic elastomer may be used.
The fiber length of the fibrous material is preferably 0.5 to 20 mm, more preferably 1 to 10 mm, and the fiber diameter is preferably 10 to 300 μm, more preferably 20 to 200 μm.

また、バインダーとして用いることができる熱硬化性樹脂としては、フェノール樹脂、メラミン樹脂、エポキシ樹脂、不飽和ポリエステル樹脂などが挙げられる。
バインダーとして用いられる粉状物の粒径は好ましくは5〜20μmであり、より好ましくは2〜10μmである。
Moreover, as a thermosetting resin which can be used as a binder, a phenol resin, a melamine resin, an epoxy resin, an unsaturated polyester resin, etc. are mentioned.
The particle size of the powdery material used as the binder is preferably 5 to 20 μm, more preferably 2 to 10 μm.

本発明の成形体におけるバインダーの含有量は、成形体の用途等に応じて決めればよい。高い強度が要求されない場合は、バインダーを含まず、乳酸菌発酵させた鱗片状の竹粉で成形体を構成してもよいが、バインダーを加えることで成形しやすく、強度を高めることができる。
本発明の成形体を、例えば車両用内装材や建築用材料として用いることができるハードボードとする場合は、強度確保のため、成形体中のバインダーの含有量は5質量%以上とすることが好ましく、10質量%以上とすることがより好ましい。一方、脱臭性確保のため、成形体中の乳酸菌発酵させた鱗片状の竹粉の含有量は65質量%以上とすることが好ましく、80質量%以上とすることがより好ましい。
成形体中の乳酸菌発酵させた鱗片状の竹粉の含有量とバインダーの含有量の比率(質量比)は90:10〜65:35とすることが好ましく、80:20〜70:30とすることがより好ましい。
What is necessary is just to determine the content of the binder in the molded object of this invention according to the use etc. of a molded object. When high strength is not required, the molded body may be composed of scaly bamboo powder fermented with lactic acid bacteria without including a binder, but by adding a binder, it is easy to mold and the strength can be increased.
When the molded body of the present invention is a hard board that can be used as, for example, a vehicle interior material or a building material, the content of the binder in the molded body may be 5% by mass or more in order to ensure strength. Preferably, it is more preferably 10% by mass or more. On the other hand, in order to ensure deodorization, the content of the flaky bamboo powder fermented with lactic acid bacteria in the molded body is preferably 65% by mass or more, and more preferably 80% by mass or more.
The ratio (mass ratio) of the content of the flaky bamboo powder fermented with lactic acid bacteria and the content of the binder in the molded body is preferably 90:10 to 65:35, and 80:20 to 70:30. It is more preferable.

(その他の成分)
本発明の成形体は、成形体に要求される特性や成形体の製造容易性などを考慮して他の成分を含んでもよく、例えば、難燃剤、密度調整剤(充填剤)、分散剤、消泡剤などが挙げられる。
(Other ingredients)
The molded article of the present invention may contain other components in consideration of the properties required for the molded article and the ease of production of the molded article. For example, flame retardants, density adjusting agents (fillers), dispersants, Examples include antifoaming agents.

本発明の竹粉含有成形体は、乳酸菌発酵により、生成した有機酸が付着した鱗片状の竹粉を含んで構成されているため、有機酸によりアンモニア等の脱臭(反応)機能を発揮することがき、また、鱗片状の竹粉に形成されている多孔質内への吸着によっても脱臭が行われると考えられる。   The bamboo powder-containing molded body of the present invention is composed of scale-like bamboo powder to which the organic acid produced by lactic acid bacteria fermentation is attached, and therefore exhibits a deodorizing (reaction) function such as ammonia with the organic acid. It is thought that deodorization is also carried out by adsorption into the porous material formed in the postcard and scaly bamboo powder.

<竹粉含有成形体の製造方法>
本発明の竹粉含有成形体を製造する方法は特に限定されないが、抄造法を利用して好適に製造することができる。すなわち、本発明の竹粉含有成形体の製造方法は、維管束に由来する孔を有し、乳酸菌発酵させた鱗片状の竹粉及び水を含む竹粉分散液を用い、抄造法により、前記乳酸菌発酵させた鱗片状の竹粉を含むシート状物を形成するシート状物形成工程と、前記シート状物から水分を除去(脱水及び乾燥)して1次成形体とする1次成形工程と、を含んでいる。また、シート状以外の成形体とする場合、あるいは、強度を高める場合は、1次成形体をホットプレスして2次成形体とする2次成形工程をさらに含むことができる。
<Method for producing bamboo powder-containing molded body>
Although the method for producing the bamboo powder-containing molded product of the present invention is not particularly limited, it can be suitably produced using a papermaking method. That is, the method for producing a bamboo powder-containing molded article of the present invention uses a bamboo powder dispersion liquid containing scale-shaped bamboo powder fermented with lactic acid bacteria and water, having pores derived from vascular bundles, and a papermaking method. A sheet-like material forming step for forming a sheet-like material containing scale-like bamboo powder fermented with lactic acid bacteria, and a primary molding step for removing water (dehydrating and drying) from the sheet-like material to obtain a primary molded body; , Including. Moreover, when setting it as molded objects other than a sheet form, or when raising an intensity | strength, the secondary shaping | molding process which hot-presses a primary molded object and makes it a secondary molded object can further be included.

以下、本発明の竹粉含有成形体の製造方法の各工程について説明する。図4は本発明に係る竹粉含有成形体の製造方法の一例を概略的に示している。   Hereinafter, each process of the manufacturing method of the bamboo powder containing molded object of this invention is demonstrated. FIG. 4 schematically shows an example of a method for producing a bamboo powder-containing molded body according to the present invention.

(シート状物形成工程)
まず、維管束に由来する孔を有し、乳酸菌発酵させた鱗片状の竹粉及び水を含む竹粉分散液を用い、抄造法により、前記乳酸菌発酵させた鱗片状の竹粉を含むシート状物を形成する。
(Sheet formation process)
First, using a bamboo powder dispersion containing flaky lactic acid bacteria fermented flaky bamboo powder and water having a pore derived from the vascular bundle, a sheet-form containing the lactic acid bacteria fermented flaky bamboo powder Form things.

竹粉分散液は、切削後の鱗片状の竹粉を乳酸菌発酵させた後、乾燥(絶乾状態:例えば115℃×1時間以上の条件で乾燥)させた後に水を添加し、混合することで得ることができる。水と竹粉との配合比は、鱗片状の竹粉が水中で分散した状態を保つことができればよく、例えば、水100質量部に対し、0.1〜10質量部の竹粉を添加する。鱗片状の竹粉が水中で安定して分散させた状態を保つため、竹粉分散液に界面活性剤を添加してもよい。
竹粉分散液は、製造する成形体の強度を向上させるため、前記したバインダー(マトリックス)を含むことが好ましい。乳酸菌発酵させた鱗片状の竹粉とバインダーの配合比(質量基準)は、目的とする成形体の用途等に応じて決めればよい。
さらに、目的とする成形体の用途に応じて、難燃剤などの他の成分を添加してもよい。
Bamboo powder dispersion is obtained by fermenting flaky bamboo powder after cutting and then drying (absolutely dry condition: for example, drying at 115 ° C. × 1 hour or more) and then adding water and mixing. Can be obtained at The mixing ratio of water and bamboo powder is only required to maintain a state in which scaly bamboo powder is dispersed in water. For example, 0.1 to 10 parts by mass of bamboo powder is added to 100 parts by mass of water. . In order to keep the scale-like bamboo powder stably dispersed in water, a surfactant may be added to the bamboo powder dispersion.
The bamboo powder dispersion preferably contains the above-described binder (matrix) in order to improve the strength of the molded article to be produced. What is necessary is just to determine the compounding ratio (mass reference | standard) of the scale-like bamboo powder fermented with lactic acid bacteria, and a binder according to the use etc. of the target molded object.
Furthermore, you may add other components, such as a flame retardant, according to the use of the target molded object.

竹粉分散液を容器内で撹拌混合し(図4(A))、抄造法により、鱗片状の竹粉を漉して乳酸菌発酵させた鱗片状の竹粉を含むシート状物を形成する(図4(B))。
抄造は、和紙などを製造する技術であり、紙を製造する際、紙の原料となる繊維を水を含む分散液から繊維をすくい取る方法、あるいは、繊維を水から濾別する方法が挙げられる。手抄きと機械抄きに大別されるが、本発明はいずれも適用することができる。
The bamboo powder dispersion is stirred and mixed in a container (FIG. 4 (A)), and a sheet-like material containing scale-like bamboo powder that is fermented with lactic acid bacteria by straining the scale-like bamboo powder by a papermaking method is formed (FIG. 4). 4 (B)).
Papermaking is a technique for producing Japanese paper, and when producing paper, a method of scooping fibers from a dispersion containing water or a method of filtering fibers from water is used. . Although broadly divided into hand-making and machine-making, any of the present invention can be applied.

乳酸菌発酵させた鱗片状の竹粉を含む分散液を原料として抄造によりシート状物を形成することで、乳酸菌発酵させた鱗片状の竹粉が厚さ方向に層状に重なったシート状物を得ることができる。水を媒体とした抄造法によりシート状物を形成するため、製造エネルギーが少なく、大型のシート状物を形成することもできる。
また、抄造法によれば、少ないバインダー(マトリックス)でシート状物を製造することができ、特に乳酸菌発酵させた鱗片状の竹粉と繊維状のバインダーでは、よく絡み合うことで、強度が顕著に向上する。
目付量は、成形体に求められる強度と密度に応じて決めればよいが、成形体としての強度を得るため0.2g/cm以上とすることが好ましい。
By forming a sheet-like material by papermaking using a dispersion containing scale-like bamboo powder fermented with lactic acid bacteria, a sheet-like material in which the scale-like bamboo powder fermented with lactic acid bacteria is layered in the thickness direction is obtained. be able to. Since the sheet-like material is formed by a papermaking method using water as a medium, the production energy is small and a large-sized sheet-like material can be formed.
In addition, according to the papermaking method, a sheet-like material can be produced with a small amount of binder (matrix). In particular, the scale-like bamboo powder fermented with lactic acid bacteria and the fibrous binder are intertwined with each other, so that the strength is remarkable. improves.
The basis weight may be determined according to the strength and density required of the molded body, but is preferably 0.2 g / cm 3 or more in order to obtain the strength as the molded body.

本発明における抄造は、例えば、バッチ用として手抄き機を用いてもよいし、長尺用として連続機を用いてもよい。手抄き機として、例えば、印刷朝陽会「新版 製紙・印刷の計測機器」 p.178−179 (2002)に記載されている「TAPPI式手すき機」、「角型シートマシン」などを用いることができる。また、連続機として、CMC出版「機能性不織布の開発」 p.232−233 (2004)に記載されている「傾斜ワイヤー型長網(短網)抄紙機」、「円網抄紙機」などを用いることができる。
また、抄紙機を用いず、例えば、竹粉含有分散液を筒状容器内で撹拌混合した後、竹粉を沈降させてフィルターで漉すことでシート状物を得ることもできる。
In the paper making in the present invention, for example, a hand machine may be used for batch use, or a continuous machine may be used for long use. As a hand-drawing machine, for example, the printing Chao-kai “New measuring machine for papermaking and printing” p. 178-179 (2002), "TAPPI type handrail machine", "square sheet machine", etc. can be used. Also, as a continuous machine, CMC publication “Development of functional nonwoven fabric” p. “Inclined wire type long net (short net) paper machine” and “circular net paper machine” described in 232-233 (2004) can be used.
Further, without using a paper machine, for example, after a bamboo powder-containing dispersion is stirred and mixed in a cylindrical container, the bamboo powder is allowed to settle and sieved with a filter to obtain a sheet-like material.

(1次成形工程)
抄造法により、乳酸菌発酵させた鱗片状の竹粉を含むシート状物を形成した後、シート状物から水分を除去して1次成形体とする。
例えば、容器内から乳酸菌発酵させた鱗片状の竹粉を含むシート状物30を取出し(図4(C))、両面からプレス機22により圧縮して脱水する(図4(D))。脱水後のシート状物に水分が残留する場合は、乾燥させて残留水分を蒸発させることが好ましい。なお、シート状物の両面からプレスして脱水する際、プレスとともに加熱して乾燥させてもよい。
乾燥手段は特に限定されず、例えば、温風又は熱風を当ててもよいし、ヒータによって加熱してもよいし、高温又は低湿の乾燥室内に放置してもよいし、自然乾燥してもよい。
抄造法により形成した乳酸菌発酵させた鱗片状の竹粉を含むシート状物から水分を除去することで1次成形体31を得ることができる(図4(E))。
図5は1次成形工程後の成形体を示しており、鱗片状の竹粉が厚さ方向に層状に重なっている。
(Primary molding process)
After forming a sheet-like material containing scaly bamboo powder fermented with lactic acid bacteria by a papermaking method, moisture is removed from the sheet-like material to obtain a primary molded body.
For example, the sheet-like material 30 containing scaly bamboo powder fermented with lactic acid bacteria is taken out from the container (FIG. 4C), and compressed from both sides by the press 22 and dehydrated (FIG. 4D). When moisture remains in the sheet-like material after dehydration, it is preferable to dry it and evaporate the remaining moisture. When dehydrating by pressing from both sides of the sheet-like material, it may be heated and dried together with the press.
The drying means is not particularly limited, and for example, warm air or hot air may be applied, it may be heated by a heater, left in a high temperature or low humidity drying chamber, or may be naturally dried. .
The primary molded body 31 can be obtained by removing water from the sheet-like material containing the scale-like bamboo powder fermented by lactic acid bacteria formed by the papermaking method (FIG. 4E).
FIG. 5 shows the molded body after the primary molding step, and scaly bamboo powder is layered in the thickness direction.

(2次成形工程)
水分を除去したシート状物は1次成形体として利用することもできるが、強度をさらに高める場合、あるいはシート状以外の成形体とする場合は、1次成形体31をホットプレスして2次成形体32とすることができる(図4(F))。
脱水・乾燥後、所定の型に入れてホットプレスにより圧縮成形することで、強度が高まるとともに所望の形状に成形することができる。なお、2次成形工程を行う場合は、成形容易性及び強度の向上の観点から、竹粉分散液に、バインダー、好ましくは熱可塑性樹脂、より好ましくは熱可塑性の繊維状バインダーを予め含ませて竹粉とバインダーを含むシート状物を形成することが好ましい。
(Secondary molding process)
The sheet-like material from which moisture has been removed can be used as a primary molded body. However, when the strength is further increased, or when a molded body other than a sheet is to be formed, the primary molded body 31 is hot-pressed to obtain a secondary body. It can be set as the molded body 32 (FIG. 4F).
After dehydration and drying, it is put into a predetermined mold and compression-molded by hot pressing, whereby the strength can be increased and the desired shape can be formed. In the case of performing the secondary molding step, from the viewpoint of improving molding ease and strength, the bamboo powder dispersion is preliminarily containing a binder, preferably a thermoplastic resin, more preferably a thermoplastic fibrous binder. It is preferable to form a sheet-like material containing bamboo powder and a binder.

2次成形工程における条件(温度、圧力、時間など)は、製造すべき成形体の形態、バインダーの種類、バインダーの配合量等に応じて決めればよく、2次成形工程におけるホットプレス条件は、バインダーの融点、流動性等に応じて決めればよい。例えば、熱可塑性バインダーを含む場合は、加熱後、型で圧縮成形が可能である。   The conditions (temperature, pressure, time, etc.) in the secondary molding step may be determined according to the form of the molded article to be produced, the type of binder, the blending amount of the binder, etc. The hot press conditions in the secondary molding step are: What is necessary is just to determine according to melting | fusing point of a binder, fluidity | liquidity, etc. For example, when a thermoplastic binder is included, it can be compressed with a mold after heating.

上記工程を経て、乳酸菌発酵させた鱗片状の竹粉及びバインダーを含む2次成形体32を得ることができる。上記方法では、抄造法によりシート状物を得るため、例えば大きなボードを製造することもできる。なお、2次成形体の形状は用途に応じて決めればよい。
本発明の竹粉含有成形体は、上記のように乳酸菌発酵させた鱗片状の竹粉を用い、水を媒体とした抄造法によりシート状物を得て、乾燥、圧縮等により成形体を製造することができるため、省エネルギーで、カーボンニュートラルに近い成形体を得ることができる。
Through the above steps, a secondary molded body 32 containing scale-like bamboo powder fermented with lactic acid bacteria and a binder can be obtained. In the above method, for example, a large board can be manufactured in order to obtain a sheet-like material by a papermaking method. In addition, what is necessary is just to determine the shape of a secondary molded object according to a use.
The bamboo powder-containing molded article of the present invention is a scale-like bamboo powder fermented with lactic acid bacteria as described above, and a sheet-like material is obtained by a papermaking method using water as a medium, and the molded article is produced by drying, compression, etc. Therefore, it is possible to obtain a molded body close to carbon neutral with energy saving.

また、本発明では、厚さ方向に孔を有し、乳酸菌発酵させた鱗片状の竹粉を用いて成形体を製造するため、脱臭性能を有することができるほか、単に粉状の竹粉を用いる場合に比較して曲げ強度を大きくすることができる。例えば、鱗片状の竹粉を65質量%以上99質量%以下、バインダーを1質量%以上35質量%以下で含むことで、以下の曲げ強度、板厚、及び密度を有する2次成形体を製造することができる。
曲げ強度:20(MPa)以上
板厚:0.5(mm)以上
密度:0.2(g/cm)以上
In addition, in the present invention, since a molded body is produced using scale-like bamboo powder having pores in the thickness direction and fermented with lactic acid bacteria, it can have deodorizing performance, and simply powdery bamboo powder can be used. The bending strength can be increased as compared with the case of using. For example, a secondary molded body having the following bending strength, plate thickness, and density is produced by including scaly bamboo powder in an amount of 65% by mass to 99% by mass and a binder in an amount of 1% by mass to 35% by mass. can do.
Bending strength: 20 (MPa) or more Plate thickness: 0.5 (mm) or more Density: 0.2 (g / cm 3 ) or more

以下に実施例について説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、以下の説明において、特に断りのない限り、配合量(含有量、添加量)に関する「部」、「%」は全て質量基準である。   Examples will be described below, but the present invention is not limited to these examples. In the following description, unless otherwise specified, “part” and “%” relating to the blending amount (content, addition amount) are based on mass.

<実施例1>
−竹粉分散液の調製−
丸大鉄工(株)製の竹粉製造機「PANDA」を用い、竹を維管束に対して直角に切削(スライス)して鱗片状の竹粉(切削粉)を得た。竹粉の平均厚さは400μmであり、平均幅は600μmであった。
<Example 1>
-Preparation of bamboo powder dispersion-
Using bamboo powder manufacturing machine “PANDA” manufactured by Marudai Iron Works Co., Ltd., bamboo was cut (sliced) at right angles to the vascular bundle to obtain scaly bamboo powder (cut powder). The average thickness of the bamboo powder was 400 μm and the average width was 600 μm.

得られた鱗片状の竹粉を真空パックして大気中に、45℃以上にならないところに放置することで乳酸菌発酵を行った。   Lactic acid bacteria fermentation was performed by vacuum-packing the obtained scaly bamboo powder and leaving it in the atmosphere at a temperature not exceeding 45 ° C.

乳酸菌発酵させた鱗片状の竹粉と熱可塑性バインダー繊維(材質:ポリプロピレン、サイズ:2.4dtex×5mm)を水に配合した。具体的には、乳酸菌発酵させた鱗片状の竹粉と熱可塑性バインダー繊維との配合比(質量比)は、竹粉:熱可塑性PP(ポリプロピレン)バインダー繊維=80:20とし、また、水1000質量部に対して竹粉と繊維を合わせて8.3質量部(希釈率:120倍)を撹拌混合して竹粉分散液A1を得た   Scale-like bamboo powder fermented with lactic acid bacteria and thermoplastic binder fiber (material: polypropylene, size: 2.4 dtex × 5 mm) were blended in water. Specifically, the blending ratio (mass ratio) between the flaky bamboo powder fermented with lactic acid bacteria and the thermoplastic binder fiber is bamboo powder: thermoplastic PP (polypropylene) binder fiber = 80: 20, and water 1000 A bamboo powder dispersion A1 was obtained by mixing 8.3 parts by mass (dilution rate: 120 times) of bamboo powder and fibers with respect to parts by mass and stirring and mixing them.

−シート状物形成工程−
竹粉分散液A1を用いて以下のようにして抄造法によりシート状物A1を作製した。
水30Lに竹粉と繊維を合わせて250g含む分散液(希釈率:120倍)を撹拌機で1分間撹拌し、250メシュ付きの容器に移して水をろ過(脱水)後、真空引きする。その時間は、およそ30秒とした。
-Sheet formation process-
A sheet-like material A1 was produced by a papermaking method using the bamboo powder dispersion A1 as follows.
A dispersion containing 250 g of bamboo powder and fibers in 30 L of water (dilution rate: 120 times) is stirred with a stirrer for 1 minute, transferred to a vessel with a 250 mesh, filtered (dehydrated), and then evacuated. The time was about 30 seconds.

−成形工程−
残ったシート状物(竹粉+繊維)A1を容器から取り出し、脱水プレスにて脱水(3MPaで2分)した。それを、110℃×4時間乾燥し、1次成形体を得た。
乾燥後、ホットプレス機により成形した。ホットプレス条件は、150℃、2分間、3MPaとした。これにより、実施例1の成形体A1を得た。
-Molding process-
The remaining sheet (bamboo powder + fiber) A1 was taken out of the container and dehydrated with a dehydration press (3 MPa, 2 minutes). It was dried at 110 ° C. for 4 hours to obtain a primary molded body.
After drying, it was molded by a hot press machine. The hot press conditions were 150 MPa, 2 minutes, and 3 MPa. This obtained the molded object A1 of Example 1. FIG.

<実施例2>
−シート状物形成工程−
実施例1の竹粉分散液A1の調製において、乳酸菌発酵させた鱗片状の竹粉と熱可塑性バインダー繊維との配合比(質量比)を、乳酸菌発酵させた竹粉:熱可塑性バインダー繊維=70:30としたこと以外は実施例1と同様にして竹粉分散液A2を調製し、竹粉分散液A2を用いて実施例1と同様に抄造法によりシート状物A2を作製した。
<Example 2>
-Sheet formation process-
In the preparation of the bamboo powder dispersion A1 of Example 1, the blending ratio (mass ratio) of the flaky bamboo-fermented bamboo powder and the thermoplastic binder fiber is the same as the bamboo powder fermented with the lactic acid bacteria: thermoplastic binder fiber = 70. : A bamboo powder dispersion A2 was prepared in the same manner as in Example 1 except that it was set to 30, and a sheet-like material A2 was prepared by a papermaking method in the same manner as in Example 1 using the bamboo powder dispersion A2.

−成形工程−
シート状物A2を用い、実施例1の成形工程と同様にして成形体A2を製造した。
-Molding process-
Using the sheet A2, a molded body A2 was produced in the same manner as in the molding process of Example 1.

<比較例1>
−竹粉分散液の調製−
石臼方式の摩砕機を用い、竹を摩砕してすり潰し状の竹粉(摩砕粉)を得た。図6に摩砕粉を示す。
得られた摩砕粉を実施例1と同様にして真空パックし、実施例1と同様の条件下で放置 した。竹粉として上記の摩砕粉を用いたこと、また、成形工程におけるホットプレス条件を表1に示すように変更したこと以外は実施例1と同様にして竹粉分散液B1を調製した。
<Comparative Example 1>
-Preparation of bamboo powder dispersion-
Using a stone mill grinder, the bamboo was ground to obtain a ground bamboo powder (ground powder). FIG. 6 shows the ground powder.
The obtained ground powder was vacuum packed in the same manner as in Example 1 and allowed to stand under the same conditions as in Example 1. A bamboo powder dispersion B1 was prepared in the same manner as in Example 1 except that the above-mentioned ground powder was used as the bamboo powder and the hot press conditions in the molding process were changed as shown in Table 1.

−シート状物形成工程−
実施例1のシート状物形成工程において、竹粉分散液A1の代わりに竹粉分散液B1を用いたこと以外は実施例1と同様にして抄造法によりシート状物B1を作製した。
-Sheet formation process-
In the sheet-like material forming step of Example 1, sheet-like material B1 was produced by a papermaking method in the same manner as in Example 1 except that bamboo powder dispersion B1 was used instead of bamboo powder dispersion A1.

−成形工程−
実施例1の成形工程において、シート状物A1の代わりにシート状物B1を用いたこと以外は実施例1の成形工程と同様にして成形体B1を製造した。
-Molding process-
In the molding step of Example 1, a molded body B1 was produced in the same manner as in the molding step of Example 1, except that the sheet B1 was used instead of the sheet A1.

<実施例3>
−シート状物形成工程−
実施例1の竹粉分散液A1を用いて実施例1と同様に抄造法によりシート状物A3を作製した。
−成形工程−
シート状物A3を用い、実施例1の成形工程において、ホットプレスの圧力を1MPaに変更したこと以外は実施例1と同様にして成形体A3を製造した。
<Example 3>
-Sheet formation process-
Using the bamboo powder dispersion A1 of Example 1, a sheet A3 was produced by the papermaking method in the same manner as in Example 1.
-Molding process-
Using the sheet-like material A3, a molded body A3 was produced in the same manner as in Example 1 except that in the molding step of Example 1, the pressure of the hot press was changed to 1 MPa.

<実施例4>
−シート状物形成工程−
実施例2の竹粉分散液A2を用いて実施例1と同様に抄造法によりシート状物A4を作製した。
−成形工程−
シート状物A4を用い、実施例1の成形工程において、ホットプレスの圧力を1MPaに変更したこと以外は実施例1と同様にして成形体A4を製造した。
<Example 4>
-Sheet formation process-
Using the bamboo powder dispersion A2 of Example 2, a sheet A4 was produced by the papermaking method in the same manner as in Example 1.
-Molding process-
Using the sheet-like material A4, a molded body A4 was produced in the same manner as in Example 1 except that in the molding step of Example 1, the pressure of the hot press was changed to 1 MPa.

<比較例2>
−シート状物形成工程−
実施例1のシート状物形成工程において、竹粉分散液A1の代わりに竹粉分散液B2(すり潰し状の竹粉:PPバインダー繊維=70:30)を用いたこと、また、成形工程におけるホットプレス条件を表1に示すように変更したこと以外は実施例1と同様にして抄造法によりシート状物B2を作製した。
<Comparative example 2>
-Sheet formation process-
In the sheet-like material forming process of Example 1, bamboo powder dispersion B2 (ground bamboo powder: PP binder fiber = 70: 30) was used instead of bamboo powder dispersion A1, and hot in the molding process. A sheet-like material B2 was produced by a papermaking method in the same manner as in Example 1 except that the pressing conditions were changed as shown in Table 1.

[評価]
実施例及び比較例で得られた成形体について、以下の評価を行った。
[Evaluation]
The following evaluation was performed about the molded object obtained by the Example and the comparative example.

(曲げ強さ)
成形体の曲げ強さをJIS A5905に準じて測定した。
(Bending strength)
The bending strength of the molded body was measured according to JIS A5905.

(密度)
成形体の重量と体積から密度を求めた。
(density)
The density was determined from the weight and volume of the molded body.

(脱臭性能)
臭覚測定法を用い、臭気強度(官能評価)で各成形体の脱臭性能を評価した。
A:2≦A<3
B:3≦B<4
C:4≦C≦5
(Deodorization performance)
Using the olfactory measurement method, the deodorizing performance of each molded body was evaluated by odor intensity (sensory evaluation).
A: 2 ≦ A <3
B: 3 ≦ B <4
C: 4 ≦ C ≦ 5

実施例及び比較例で製造した成形体の原料、ホットプレス条件、評価結果について表1にまとめた。   Table 1 summarizes the raw materials, hot press conditions, and evaluation results of the compacts produced in the examples and comparative examples.

表1に示すように、乳酸菌発酵させた鱗片状の竹粉を用いた実施例では、鱗片状以外の竹粉を用いた場合に比べて曲げ強さ及び脱臭性能が高いことがわかる。   As shown in Table 1, in Examples using scale-like bamboo powder fermented with lactic acid bacteria, it can be seen that bending strength and deodorization performance are higher than when bamboo powder other than scale-like is used.

本発明は、その要旨を逸脱しない範囲で種々変更して実施できる。また、本発明の権利範囲が上記各実施形態に限定されないことは言うまでもない。   The present invention can be implemented with various modifications without departing from the scope of the invention. Needless to say, the scope of rights of the present invention is not limited to the above embodiments.

本発明に係る竹粉含有成形体は、乳酸菌発酵させた鱗片状の竹粉とバインダーを含めた成形体とすることで、自然発酵の匂い(芳香性)をもつボードを得ることができ、車両用内装材(例えば背面ボード等)、建築用材料(例えば無音響室の壁面材料等)として好適に適用することができるが、これらに限定されない。例えば鱗片状の竹粉の含有量を高めた成形体であれば、脱臭性能を有するフィルター、緩衝材などにも適用することができる。   The bamboo powder-containing molded body according to the present invention is a molded body including scale-shaped bamboo powder fermented with lactic acid bacteria and a binder, so that a board having a natural fermentation odor (fragrance) can be obtained. It can be suitably applied as an interior material (for example, a back board) or a building material (for example, a wall material of an acoustic room), but is not limited thereto. For example, if it is a molded object in which the content of scaly bamboo powder is increased, it can also be applied to filters, cushioning materials and the like having deodorizing performance.

Claims (8)

維管束に由来する孔を有し、乳酸菌発酵させた鱗片状の竹粉を含む竹粉含有成形体。   A bamboo powder-containing molded article having scale-like bamboo powder having pores derived from vascular bundles and fermented with lactic acid bacteria. 前記鱗片状の竹粉が厚さ方向に層状に重なっている請求項1に記載の竹粉含有成形体。   The bamboo powder-containing molded article according to claim 1, wherein the scaly bamboo powder is layered in the thickness direction. さらにバインダーを含む請求項1又は請求項2に記載の竹粉含有成形体。   Furthermore, the bamboo-powder containing molded object of Claim 1 or Claim 2 containing a binder. 請求項1〜請求項3のいずれか一項に記載の竹粉含有成形体からなる車両用内装材。   The vehicle interior material which consists of a bamboo-powder containing molded object as described in any one of Claims 1-3. 請求項1〜請求項3のいずれか一項に記載の竹粉含有成形体からなる建築用材料。   The building material which consists of a bamboo-powder containing molded object as described in any one of Claims 1-3. 維管束に由来する孔を有し、乳酸菌発酵させた鱗片状の竹粉及び水を含む竹粉分散液を用い、抄造法により、前記乳酸菌発酵させた鱗片状の竹粉を含むシート状物を形成するシート状物形成工程と、
前記シート状物から水分を除去して1次成形体とする1次成形工程と、
を含む竹粉含有成形体の製造方法。
A sheet-like material containing a scale-like bamboo powder fermented by lactic acid bacteria by a paper-making method using a bamboo powder dispersion containing pores derived from vascular bundles and fermented lactic acid bacteria-like bamboo powder and water A sheet-like material forming step to be formed;
A primary molding step of removing moisture from the sheet to obtain a primary molded body;
The manufacturing method of the bamboo powder containing molded object containing this.
前記竹粉分散液が、さらにバインダーを含む請求項6に記載の成形体の製造方法。   The method for producing a molded body according to claim 6, wherein the bamboo powder dispersion further contains a binder. 前記1次成形体をホットプレスして2次成形体とする2次成形工程をさらに含む請求項6又は請求項7に記載の竹粉含有成形体の製造方法。   The method for producing a bamboo powder-containing molded body according to claim 6 or 7, further comprising a secondary molding step in which the primary molded body is hot pressed to form a secondary molded body.
JP2014554023A 2012-12-28 2012-12-28 Bamboo powder-containing molded body, vehicle interior material and building material, and method for producing bamboo powder-containing molded body Expired - Fee Related JP5955416B2 (en)

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JP6999880B2 (en) * 2017-08-29 2022-01-19 株式会社タケックス・ラボ How to make particle board, bamboo chips for particle board and how to make particle board
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JPH04307203A (en) * 1991-04-04 1992-10-29 Nidea:Kk Working method of bamboo, bamboo working device for executing same method, bamboo blank worked through same method and molded form using same bamboo blank
JPH06293008A (en) * 1992-12-22 1994-10-21 Fuyo Kogyo Kk Manufacture of particle board made of bamboo
JP2008023769A (en) * 2006-07-19 2008-02-07 Kagoshima Univ Heat-insulation and moisture-absorption/release sheet formed of bamboo vascular bundle sheath
JP2008307884A (en) * 2007-05-17 2008-12-25 Nishi Nippon Gijutsu Kaihatsu Kk Bamboo fiber molding and bamboo fiber molding-carbonized material
JP2012040701A (en) * 2010-08-13 2012-03-01 Kyushu Institute Of Technology Bamboo fiber, method of manufacturing the same, and method of manufacturing composite material using the bamboo fiber
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Publication number Priority date Publication date Assignee Title
JPH04307203A (en) * 1991-04-04 1992-10-29 Nidea:Kk Working method of bamboo, bamboo working device for executing same method, bamboo blank worked through same method and molded form using same bamboo blank
JPH06293008A (en) * 1992-12-22 1994-10-21 Fuyo Kogyo Kk Manufacture of particle board made of bamboo
JP2008023769A (en) * 2006-07-19 2008-02-07 Kagoshima Univ Heat-insulation and moisture-absorption/release sheet formed of bamboo vascular bundle sheath
JP2008307884A (en) * 2007-05-17 2008-12-25 Nishi Nippon Gijutsu Kaihatsu Kk Bamboo fiber molding and bamboo fiber molding-carbonized material
JP2012040701A (en) * 2010-08-13 2012-03-01 Kyushu Institute Of Technology Bamboo fiber, method of manufacturing the same, and method of manufacturing composite material using the bamboo fiber
JP3176586U (en) * 2012-03-21 2012-06-28 特定非営利活動法人グリーンネットワーク Lactic acid fermented bamboo powder production equipment

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