JP5948615B2 - Vacuum heat insulating material, and refrigerator, jar pot and house equipped with the same - Google Patents

Description

  The present invention relates to a vacuum heat insulating material in which a core material made of a fiber assembly is sealed under reduced pressure in a jacket material.

  In recent years, as a measure against global warming, which is a global environmental problem, there has been an active movement to promote energy saving, and for thermal and thermal equipment, there is a vacuum thermal insulation material that has excellent thermal insulation performance from the viewpoint of effective use of heat. It is becoming popular.

  A vacuum heat insulating material is a material in which a core material having a high gas phase volume ratio and a fine gap is inserted into a jacket material having a gas barrier property processed into a bag shape, and the core material is sealed under reduced pressure. is there.

  By making the gap diameter of the core material smaller than the mean free path of gas molecules under reduced pressure, the gas heat conduction component becomes small, and the influence of the convective heat transfer component can be ignored in a fine gap of about 1 mm. Become. Furthermore, since the influence of the radiation component is slight near room temperature, it is said that the heat conduction in the vacuum heat insulating material is dominated by the solid heat conduction component of the core material and the slightly remaining gas heat conduction component.

  The glass wool used as the core material must retain the void formed by the core material against the compressive load from the atmosphere. Therefore, the glass wool before being sealed under reduced pressure is very bulky because of its high gas phase volume ratio. . Moreover, since the rigidity is insufficient, it is very difficult to store the glass wool in the envelope material processed into a bag shape.

Therefore, in order to solve the above-mentioned problem, a state in which a laminate formed by alternately laminating a large number of metal foils having a low emissivity and silica-based inorganic fiber sheets is compressed in the laminating direction to a density that withstands atmospheric pressure against vacuum. A core material of a vacuum heat insulating material stitched with a thread made of a material having a low thermal conductivity has been proposed (see, for example, Patent Document 1).

  Hereinafter, the core material of the conventional vacuum heat insulating material will be described with reference to the drawings. FIG. 19 is a cross-sectional view illustrating a configuration of a core material of a conventional vacuum heat insulating material described in Patent Document 1.

  As shown in FIG. 19, the core material 1 of the conventional vacuum heat insulating material described in Patent Document 1 is formed by alternately laminating a large number of metal foils 2 and silica-based inorganic fibrous sheets 3 having a low thermal radiation rate. It is said that the laminated body 4 is stitched with a thread 5 made of a material having a low thermal conductivity in a state where the laminated body 4 is compressed in the laminating direction until it is pressured to atmospheric pressure against vacuum, and the handling property of the core material 1 can be improved. ing.

JP-A-8-121683

  However, in the configuration of Patent Document 1 described above, since the sewing method uses a hand stitch sewing machine that sews with one thread 5, the entanglement force between the thread 5 and the laminate 4 that is to be sewn is weak, and after sewing is performed. When a bulky inorganic fiber having a compression rate of 80% to 90% is sewn, the yarn 5 is unwound from the laminate 4 due to the repulsive force of the inorganic fiber, and sufficient rigidity is not given to the laminate 4.

  When this laminated body 4 is used as the core material 1 of the vacuum heat insulating material, the amount of deformation in the thickness direction of the core material 1 increases before and after the vacuum packaging, so that the flatness of the vacuum heat insulating material after the vacuum packaging is not sufficiently secured. In addition, it is difficult to ensure the flatness of the vacuum heat insulating material even in the process of inspecting the degree of internal vacuum of the vacuum heat insulating material by reducing the pressure of a part or the whole of the vacuum heat insulating material.

  An object of this invention is to provide the vacuum heat insulating material which ensured planarity in view of the said conventional subject.

In order to achieve the above object, the vacuum heat insulating material of the present invention has at least a plurality of core members made of a fiber assembly and having two heat transfer surfaces facing each other, and a jacket material covering the core member. A vacuum heat insulating material in which the core material is sealed under reduced pressure in the jacket material, the portion exposed to one of the heat transfer surfaces of the core material, the portion exposed to the other heat transfer surface, and the fiber assembly A yarn having a portion embedded in the body, wherein the yarn is a produced yarn not provided with a colorant and has a cross-sectional area larger than a cross-sectional area of the yarn, and the transmission of the fiber assembly. It has a large diameter part that remains on the hot surface and keeps the compressed state of the fiber assembly even after sewing, and the plurality of core members are stacked and compressed in the thickness direction by the tension of the yarn. .

By providing the large-diameter portion having a cross-sectional area larger than the cross-sectional area of the yarn, the large-diameter portion continues to maintain the compressed state of the fiber assembly even after sewing, so that rigidity is imparted to the fiber assembly. Since this fiber assembly is compressed in the thickness direction of the core material, the amount of deformation in the thickness direction of the fiber assembly becomes small before and after vacuum packaging. And since the said thread | yarn is a production | generation thread | yarn to which the coloring agent is not provided, the deformation amount with respect to the thickness direction of a fiber assembly can be made small, without generating organic gas under reduced pressure.

Since the vacuum heat insulating material of the present invention has a small amount of deformation in the thickness direction of the fiber assembly before and after vacuum packaging, the flatness of the vacuum heat insulating material is ensured without increasing the organic gas . Further, the flatness of the vacuum heat insulating material can be ensured also in the step of depressurizing a part or the whole of the vacuum heat insulating material and inspecting the internal vacuum degree of the vacuum heat insulating material.

Sectional drawing which shows the structure of the vacuum heat insulating material in Embodiment 1 of this invention. The top view which shows the heat-transfer surface of the core material used for the vacuum heat insulating material of the embodiment AA line sectional view of FIG. The top view which shows the heat-transfer surface of the core material used for the vacuum heat insulating material in Embodiment 2 of this invention BB sectional view of FIG. The top view which shows the heat-transfer surface of the core material used for the vacuum heat insulating material in Embodiment 3 of this invention CC sectional view of FIG. The top view which shows the heat-transfer surface of the core material used for the vacuum heat insulating material in Embodiment 4 of this invention DD sectional view of FIG. Sectional drawing which shows the structure of the vacuum heat insulating material in Embodiment 5 of this invention. The top view which shows the heat-transfer surface of the core material used for the vacuum heat insulating material of the embodiment EE sectional view of FIG. The top view which shows the heat-transfer surface of the core material used for the vacuum heat insulating material in Embodiment 6 of this invention FF sectional view of FIG. The top view which shows the heat-transfer surface of the core material used for the vacuum heat insulating material in Embodiment 7 of this invention GG sectional view of FIG. The top view which shows the heat-transfer surface of the core material used for the vacuum heat insulating material in Embodiment 8 of this invention HH line sectional view of FIG. Sectional drawing which shows the structure of the core material of the conventional vacuum heat insulating material shown by patent document 1

The first invention has at least a plurality of core members made of a fiber assembly and having two heat transfer surfaces facing each other, and a jacket member covering the core member, and the core member is placed in the jacket member A vacuum heat insulating material sealed under reduced pressure, wherein the yarn has a portion exposed to one of the heat transfer surfaces of the core member, a portion exposed to the other heat transfer surface, and a portion buried in the fiber assembly. The yarn is a generated yarn not provided with a colorant, has a cross-sectional area larger than the cross-sectional area of the yarn, stays on the heat transfer surface of the fiber assembly, and after the sewing, the fiber It has a large-diameter portion that keeps the compressed state of the assembly, and the plurality of core members are stacked and compressed in the thickness direction by the tension of the yarn.

By providing the large-diameter portion having a cross-sectional area larger than the cross-sectional area of the yarn, the large-diameter portion continues to maintain the compressed state of the fiber assembly even after sewing, so that rigidity is imparted to the fiber assembly. Since this fiber assembly is compressed in the thickness direction of the core material, it has the effect of reducing the deformation amount in the thickness direction of the fiber assembly before and after vacuum packaging. And since the said thread | yarn is a production | generation thread | yarn to which the coloring agent is not provided, the deformation amount with respect to the thickness direction of a fiber assembly can be made small, without generating organic gas under reduced pressure.

And by the said effect | action, since the deformation amount with respect to the thickness direction of a fiber assembly is small before and after vacuum packaging, the planarity of a vacuum heat insulating material is ensured, without increasing organic gas . Further, the flatness of the vacuum heat insulating material can be ensured also in the step of depressurizing a part or the whole of the vacuum heat insulating material and inspecting the internal vacuum degree of the vacuum heat insulating material.

  In addition, although it does not specify in particular regarding the kind of fiber, conventionally well-known materials, such as inorganic fiber, such as glass wool, rock wool, an alumina fiber, and a metal fiber, and a polyethylene terephthalate fiber, can be utilized. In addition, when using a metal fiber, the metal fiber which consists of a metal comparatively excellent in heat conductivity among metals is not preferable.

  Among them, it is desirable to use glass wool having high elasticity of the fiber itself, low thermal conductivity of the fiber itself, and industrially inexpensive. Furthermore, since the thermal conductivity of the vacuum heat insulating material tends to decrease as the fiber diameter of the fiber decreases, it is desirable to use a fiber having a smaller fiber diameter, but the fiber cost is expected to increase because it is not versatile. Therefore, the glass wool which consists of an aggregate | assembly with a comparatively cheap average fiber diameter of about 3 micrometers-6 micrometers generally used as a fiber for vacuum heat insulating materials is more desirable.

  The heat transfer surface in the present invention refers to a surface having the largest area and a surface facing the surface when a fiber assembly is used as a fiber heat insulator. Further, when the vacuum heat insulating material is disposed on a relatively high temperature surface or a relatively low temperature surface for heat insulation, the vacuum heat insulating material is opposed to the relatively high temperature surface or the relatively low temperature surface on which the vacuum heat insulating material is disposed. It refers to the surface of the material and its opposite surface. Moreover, when using it laminating | stacking a some fiber heat insulator, the surface of each vacuum heat insulating material perpendicular | vertical with respect to the lamination direction and the surface which opposes it are pointed out.

  The jacket material in the present invention plays a role of maintaining the vacuum degree of the vacuum heat insulating material, and is a resin film in which metal foil or metal atoms are vapor-deposited as a gas barrier film as an inner layer and a heat-welded film as an inner layer. A surface protective film is laminated as the outermost layer.

  The heat welding film is not particularly specified, but a thermoplastic resin such as a low density polyethylene film, a linear low density polyethylene film, a high density polyethylene film, a polypropylene film, a polyacrylonitrile film, or a mixture thereof is used. Can be used.

  Gas barrier films include metal foils such as aluminum foil and copper foil, base materials such as polyethylene terephthalate films and ethylene-vinyl alcohol copolymer films, metals such as aluminum and copper, and metal oxides such as alumina and silica. The film etc. which vapor-deposited the thing can be used.

  Moreover, as a surface protective film, conventionally well-known materials, such as a nylon film, a polyethylene terephthalate film, a polypropylene film, can be used.

  In order to suppress the increase of gas heat conduction component due to the invasion of gas and water vapor, the adsorbent supplementing the gas and water vapor entering the vacuum heat insulating material, such as zeolite and calcium oxide, is sealed under reduced pressure together with the core material. It is desirable.

  In addition, the vacuum insulation material manufacturing method is not particularly specified, but it is obtained by folding back one outer cover material and thermally welding the heat-welded films located at the ends of the opposite outer cover materials. The core material is inserted into the bag-shaped jacket material, and the heat-welded films located at the openings of the bag-shaped jacket material are thermally welded under reduced pressure, or the heat-welded films are opposed to each other. The core material is inserted into a bag-shaped outer cover material obtained by arranging a single outer cover material and heat-welding the heat-welded films located at the ends of each outer cover material. The method of heat-welding the heat welding films located in the vicinity of the opening part of a shape-like outer covering material can be utilized.

  The yarn in the present invention plays a role for compressing an aggregate of fibers. In addition, although the material of the thread is not particularly specified, natural fibers such as cotton and silk, polyethylene terephthalate, depending on the material constituting the fiber aggregate and the degree to which the fiber aggregate is compressed to a predetermined bulk density Synthetic yarns such as nylon, polyethylene, and polypropylene, and inorganic yarns such as long glass fibers and long metal fibers can be used.

  However, for the purpose of securing the heat insulating effect of the heat insulating material, the purpose of suppressing the organic gas generated under reduced pressure, and the purpose of providing a heat insulating material having higher rigidity, an organic material made of a synthetic resin such as polyethylene terephthalate or nylon is used. It is more desirable to use fibers.

  Furthermore, although the shape of the yarn is not particularly specified, it has a monofilament composed of a single yarn, a twisted yarn composed of a plurality of yarns, a wooly yarn obtained by subjecting the twisted yarn to a bulky process, and elasticity. A rubber-like thread, a thread that shrinks when heated, a member to which a product tag in which a synthetic resin is molded into an I shape, and the like can be used.

  Further, a general sewing thread is coated with an oil agent on the surface of the thread for the purpose of improving the sliding of the thread during sewing and for preventing the thread breakage in the twisting process. When this oil-coated yarn is applied to a fiber heat insulator, it causes generation of organic gas under reduced pressure. Therefore, it is preferable that the amount of oil is as small as possible. In addition, since the above-mentioned monofilament does not have a twisting process, the adhesion amount of the oil agent is 0.1% to 0.3% in weight ratio, which is smaller than that of the twisted thread. Therefore, it is more desirable to apply a monofilament to the present invention.

  Furthermore, a coloring agent is given to a general sewing thread in view of design properties. When the yarn to which the colorant is applied is applied to the fiber heat insulator, as in the case of the above-described oil agent, an organic gas is generated under reduced pressure, and thus a generated yarn to which no colorant is applied is more desirable.

The large-diameter portion in the present invention are those provided in the yarn, and refers to a moiety having a larger cross-sectional area than the cross-sectional area of the yarn was embedded in the fiber aggregate. The type and shape of the large-diameter part are not particularly specified. A formed thread, a thread anchored to another member, or a thread entangled with another member can be considered.

The front Kitai diameter are those formed by a knot.

The front Kitai diameter is looped to the yarn, and is formed by passing said yarn in said wheel.

The front Kitai diameter are those which are formed by the air ring of the yarn.

As a result , since the empty ring that becomes the large diameter portion has a plurality of thread knots, even if a part of the large diameter portion is buried in the fiber assembly for some reason, the other large diameter portion is the fiber assembly. In order to continue to maintain the compressed state of the body, it has an effect of imparting rigidity to the fiber assembly.

  The empty ring in the present invention refers to a thread seam formed without a fiber assembly. In addition, an empty ring is a fiber assembly formed by a lock stitch, a single ring stitch, or a double ring stitch.

The front Kitai diameter portion is obtained by forming the section by entangling the yarn.

The front Kitai diameter is one that the yarn is formed by a through or confounding anchoring member.

Also, the previous SL anchoring member is for fixing the yarn.

The front Symbol anchoring member is rod-shaped, or sheet, or those wherein the button-like shape.
The front Symbol anchoring member is one that is non-woven fabric.
The thickness of the pre-Symbol anchoring member is obtained by less and 1 mm.

Here, an effect that anchoring member relative to fiber維集coalescence to serve wedge, stiffness is imparted to the fiber assembly becomes stronger.

  The anchoring member in the present invention plays a role of fixing the yarn. Although the thread fixing method is not particularly specified, the thread is entangled with the mooring member, or the thread is arranged so as to penetrate the mooring member, and is larger than the through hole of the mooring member. A method of forming the diameter portion with a thread is conceivable.

  Although the shape of the anchoring member is not particularly specified, various shapes such as a bar shape such as a wire, a sheet shape such as a film or a non-woven fabric, and a button shape having a hole are conceivable. However, the thickness of the mooring member is preferably within 1 mm for the purpose of ensuring the flatness of the vacuum heat insulating material and the purpose of suppressing damage to the jacket material.

Moreover, the use of non-woven fabric as the anchoring member, since the yarn is easily entangled nonwoven fabric can be reduced Ri by the size of the large diameter portion. In addition, since the effect | action which compresses a fiber assembly as a whole will be acquired if a film and a sheet | seat are provided in the whole heat-transfer surface, the effect which becomes easy to ensure the planarity of a vacuum heat insulating material will be acquired.

The front Kitai diameter portion, and is formed by connecting the ends of a plurality of said yarns arranged in isolation from each other.

The front Kitai diameter portion, the yarn is sewn by meandering, and is formed by connecting the ends of the yarn.

The front Kiito is parallel stitch, or is obtained by semi-reverse stitching.

In the second invention, particularly in the first invention, the fiber assembly is a fiber heat insulator.
The third invention is a refrigerator provided with the vacuum heat insulating material of the first or second invention.
The 4th invention is a jar pot provided with the vacuum heat insulating material of the 1st or 2nd invention especially.
Moreover, the 5th invention is the house provided with the vacuum heat insulating material of the 1st or 2nd invention especially.
In the sixth aspect of the invention, particularly in the first aspect of the invention, the large diameter portion is difficult to move in the thickness direction within the fiber assembly.

  Hereinafter, embodiments of the present invention will be described with reference to the drawings. However, the same components as those of the above-described embodiments will be denoted by the same reference numerals, and detailed description thereof will be omitted. The present invention is not limited to the embodiments.

(Embodiment 1)
FIG. 1 is a cross-sectional view showing a configuration of a vacuum heat insulating material in Embodiment 1 of the present invention, FIG. 2 is a plan view showing a heat transfer surface of a core material used in the vacuum heat insulating material of the same embodiment, and FIG. It is sectional drawing at the time of cut | disconnecting the core material used for the vacuum heat insulating material of embodiment at the position of the AA line of FIG. 2, and seeing the cross section from the direction of the arrow.

  As shown in FIGS. 1 to 3, the vacuum heat insulating material 6 of the present embodiment includes a core material 9 having two heat transfer surfaces 8 made of a fiber assembly 7, a moisture adsorbing material 12, and a core material. 9 and a covering material 10 covering the moisture adsorbing material 12, and the core material 9 is sealed in the covering material 10 under reduced pressure. The core material 9 includes a yarn 5 having a portion exposed on one heat transfer surface 8, a portion exposed on the other heat transfer surface 8, and a portion buried in the fiber assembly 7. A plurality of large-diameter portions 11 having a size that is difficult to move in the thickness direction in the fiber assembly 7 are exposed to the heat transfer surface 8 across a portion embedded in the fiber assembly 7. The large diameter portion 11 is formed by tying the yarn 5. The fiber assembly 7 is compressed in the thickness direction by the tension of the yarn 5.

  In the present embodiment, a plurality (six in FIG. 2) of threads 5 are sewn in parallel with each other at a predetermined interval and parallel to the longitudinal direction of the core material 9. And the large diameter part 11 is formed by the ball knot of the thread | yarn 5 for every part exposed to the heat-transfer surface 8. FIG. In the yarn 5, the portions penetrating through the fiber assembly 7 are distributed almost evenly, and the portions exposed to the heat transfer surface 8 are arranged perpendicular to the longitudinal direction of the core material 9.

  In the present embodiment, polyethylene terephthalate having a fineness of 205 dtex is used as the yarn 5, a ring is formed at the end of the yarn 5, and the large diameter portion 11 is formed by passing the yarn 5 through the ring. After passing the other end of the yarn 5 through a fiber assembly 7 (thickness 150 mm) made of glass wool having a basis weight of 2,400 g / m 2, a ring is formed on the heat transfer surface 8 of the fiber assembly 7, The large-diameter portion 11 was formed on the thread 5 by passing the thread through the ring. By repeating this operation, the core material 9 having the shape shown in FIGS. 2 and 3 was obtained.

  Since the thickness of the core material 9 was 15 mm and the handling was good, it was determined that the compression effect of the fiber assembly 7 in the present embodiment was sufficient.

  Next, the core material 9 was inserted into the bag-shaped outer cover material 10 together with the moisture adsorbing material 12 made of calcium oxide, and the vacuum heat insulating material 6 was obtained by sealing the interior of the outer cover material 10 under reduced pressure. When the thickness of the vacuum heat insulating material 6 was measured, it was 9.8 mm, and no deformation such as undulation was observed on the heat transfer surface of the vacuum heat insulating material 6, so that the flatness was judged to be good.

  In the core material 9 configured as described above, the large-diameter portion 11 having a cross-sectional area larger than that of the yarn 5 remains on the heat transfer surface 8 of the fiber assembly, and maintains the compressed state of the fiber assembly 7 even after sewing. In order to continue, the fiber assembly 7 is given rigidity. Accordingly, since the vacuum heat insulating material 6 using the fiber assembly 7 is compressed in the thickness direction, the amount of deformation in the thickness direction of the fiber assembly 7 is reduced before and after vacuum packaging, and the plane of the vacuum heat insulating material 6 is reduced. Sex is secured. Further, the flatness of the vacuum heat insulating material 6 can be ensured also in the step of depressurizing a part or the whole of the vacuum heat insulating material 6 and inspecting the internal vacuum degree of the vacuum heat insulating material 6.

  Furthermore, as compared with the main sewing method using the upper and lower two threads, the number of threads buried in the fiber assembly 7 is reduced, and the incidental effect that the thermal bridge is reduced occurs.

(Embodiment 2)
4 is a plan view showing the heat transfer surface of the core material used in the vacuum heat insulating material in Embodiment 2 of the present invention, and FIG. 5 shows the core material used in the vacuum heat insulating material of the same embodiment in FIG. It is sectional drawing at the time of cut | disconnecting in the position of B line and seeing the cross section from the direction of the arrow.

  As shown in FIGS. 4 and 5, the vacuum heat insulating material 6 of the present embodiment has two heat transfer surfaces 8 made of a fiber assembly 7 and facing each other, like the vacuum heat insulating material 6 of the first embodiment. The core material 9 includes a core material 9, a moisture adsorbing material 12, and a jacket material 10 that covers the core material 9 and the moisture adsorbing material 12. The core material 9 is sealed in the jacket material 10 under reduced pressure. The core material 9 includes a yarn 5 having a portion exposed on one heat transfer surface 8, a portion exposed on the other heat transfer surface 8, and a portion buried in the fiber assembly 7. The large-diameter portion 11 having a size that is difficult to move in the thickness direction in the fiber assembly 7 is exposed to the heat transfer surface 8 with a portion buried in the fiber assembly 7 interposed therebetween. The fiber assembly 7 is compressed in the thickness direction by the tension of the yarn 5.

  In this embodiment, a nylon resin having a diameter of 0.5 mm is used as the thread 5 and is bent using a jig called a tag gun so that the other end of the thread 5 is a straight line. A fiber assembly 7 (thickness 150 mm) made of 400 g / m 2 of glass wool was penetrated from one heat transfer surface 8 to the other heat transfer surface 8. By repeating this operation so as to form a staggered pattern on the heat transfer surface 8 of the core material 9, the core material 9 having the shape shown in FIGS. 4 and 5 was obtained.

  Since the thickness of the core material 9 was 20 mm and the handling was good, it was determined that the compression effect of the fiber assembly 7 in the present embodiment was sufficient.

  Next, the core material 9 was inserted into the bag-shaped outer cover material 10 together with the moisture adsorbing material 12 made of calcium oxide, and the vacuum heat insulating material 6 was obtained by sealing the interior of the outer cover material 10 under reduced pressure. When the thickness of the vacuum heat insulating material 6 was measured, it was 10 mm, and no deformation such as undulation was observed on the heat transfer surface of the vacuum heat insulating material 6, so that the flatness was judged to be good.

  In the core material 9 configured as described above, the large-diameter portion 11 having a cross-sectional area larger than that of the yarn 5 remains on the heat transfer surface 8 of the fiber assembly, and maintains the compressed state of the fiber assembly 7 even after sewing. In order to continue, the fiber assembly 7 is given rigidity. Accordingly, since the vacuum heat insulating material 6 using the fiber assembly 7 is compressed in the thickness direction, the amount of deformation in the thickness direction of the fiber assembly 7 is reduced before and after vacuum packaging, and the plane of the vacuum heat insulating material 6 is reduced. Sex is secured. Further, the flatness of the vacuum heat insulating material 6 can be ensured also in the step of depressurizing a part or the whole of the vacuum heat insulating material 6 and inspecting the internal vacuum degree of the vacuum heat insulating material 6.

  Furthermore, as compared with the main sewing method using the upper and lower two threads, the number of threads buried in the fiber assembly 7 is reduced, and the incidental effect that the thermal bridge is reduced occurs.

(Embodiment 3)
6 is a plan view showing the heat transfer surface of the core material used for the vacuum heat insulating material in Embodiment 3 of the present invention, and FIG. 7 shows the core material used for the vacuum heat insulating material of the same embodiment in FIG. It is sectional drawing at the time of cut | disconnecting in the position of C line and seeing the cross section from the direction of the arrow.

  As shown in FIGS. 6 and 7, the vacuum heat insulating material 6 of the present embodiment has two heat transfer surfaces 8 made of a fiber assembly 7 and facing each other, like the vacuum heat insulating material 6 of the first embodiment. The core material 9 includes a core material 9, a moisture adsorbing material 12, and a jacket material 10 that covers the core material 9 and the moisture adsorbing material 12. The core material 9 is sealed in the jacket material 10 under reduced pressure. The core material 9 includes a yarn 5 having a portion exposed on one heat transfer surface 8, a portion exposed on the other heat transfer surface 8, and a portion buried in the fiber assembly 7. In the vicinity, a large-diameter portion 11 having a size that is difficult to move in the thickness direction in the fiber assembly 7 is exposed on the heat transfer surface 8 with a portion embedded in the fiber assembly 7 interposed therebetween. The large diameter portion 11 is formed by tying the yarn 5. The fiber assembly 7 is compressed in the thickness direction by the tension of the yarn 5.

In the present embodiment, a plurality (six in FIG. 6) of threads 5 are half-reversely sewn in parallel to the longitudinal direction of the core material 9 while being separated from each other by a predetermined distance. And the large diameter part 11 is formed in the part exposed to the heat-transfer surface 8 of the both ends vicinity of the thread | yarn 5 by the ball knot of the thread | yarn 5. FIG. In addition, as for the thread | yarn 5, the location which penetrates the inside of the fiber assembly 7 is made to distribute substantially equally in a grid pattern.

  In the present embodiment, nylon having a fineness of 110 dtex is used as the yarn 5, a ring is formed at the end of the yarn 5, and the large diameter portion 11 is formed by passing the yarn through the ring. After the other end of the yarn 5 is penetrated from one heat transfer surface 8 of the fiber aggregate 7 (thickness 150 mm) made of glass wool having a basis weight of 2,400 g / m 2 to the other heat transfer surface 8, the fiber aggregate 7 The thread | yarn 5 was penetrated from the different location on the same heat-transfer surface 8 to the heat-transfer surface 8 which opposes. After repeating this operation, finally, a ring is formed with the thread 5, and the large diameter portion 11 is formed by passing the thread 5 through the ring, and the core material 9 having the shape shown in FIGS. 6 and 7 is obtained. It was.

  Since the thickness of the core material 9 was 23 mm and the handling was good, it was determined that the compression effect of the fiber assembly 7 in the present embodiment was sufficient.

  Next, the core material 9 was inserted into the bag-shaped outer cover material 10 together with the moisture adsorbing material 12 made of calcium oxide, and the vacuum heat insulating material 6 was obtained by sealing the interior of the outer cover material 10 under reduced pressure. When the thickness of the vacuum heat insulating material 6 was measured, it was 11 mm, and no deformation such as undulation was observed on the heat transfer surface of the vacuum heat insulating material 6, so that the flatness was judged to be good.

  In the core material 9 configured as described above, the large-diameter portion 11 having a cross-sectional area larger than that of the yarn 5 remains on the heat transfer surface 8 of the fiber assembly, and maintains the compressed state of the fiber assembly 7 even after sewing. In order to continue, the fiber assembly 7 is given rigidity. Accordingly, since the vacuum heat insulating material 6 using the fiber assembly 7 is compressed in the thickness direction, the amount of deformation in the thickness direction of the fiber assembly 7 is reduced before and after vacuum packaging, and the plane of the vacuum heat insulating material 6 is reduced. Sex is secured. Further, the flatness of the vacuum heat insulating material 6 can be ensured also in the step of depressurizing a part or the whole of the vacuum heat insulating material 6 and inspecting the internal vacuum degree of the vacuum heat insulating material 6.

  Furthermore, as compared with the main sewing method using the upper and lower two threads, the number of threads buried in the fiber assembly 7 is reduced, and the incidental effect that the thermal bridge is reduced occurs.

(Embodiment 4)
FIG. 8 is a plan view showing the heat transfer surface of the core material used in the vacuum heat insulating material according to Embodiment 4 of the present invention, and FIG. 9 shows the core material used in the vacuum heat insulating material of the same embodiment in FIG. It is sectional drawing at the time of cut | disconnecting in the position of D line and seeing the cross section from the direction of the arrow.

  As shown in FIGS. 8 and 9, the vacuum heat insulating material 6 of the present embodiment has two heat transfer surfaces 8 made of fiber assemblies 7 and facing each other, like the vacuum heat insulating material 6 of the first embodiment. The core material 9 includes a core material 9, a moisture adsorbing material 12, and a jacket material 10 that covers the core material 9 and the moisture adsorbing material 12. The core material 9 is sealed in the jacket material 10 under reduced pressure. The core material 9 includes a yarn 5 having a portion exposed on one heat transfer surface 8, a portion exposed on the other heat transfer surface 8, and a portion buried in the fiber assembly 7. In the vicinity, a large-diameter portion 11 having a size that is difficult to move in the thickness direction in the fiber assembly 7 is exposed on the heat transfer surface 8 with a portion embedded in the fiber assembly 7 interposed therebetween. The large diameter portion 11 is formed by tying the yarn 5. The fiber assembly 7 is compressed in the thickness direction by the tension of the yarn 5.

In the present embodiment, polyethylene terephthalate having a fineness of 135 dtex is set as a thread 5 on a single-ring stitch sewing machine, and a nonwoven fabric sheet 13 made of polyethylene terephthalate as an anchoring member is sewn to form an empty ring. Next, a fiber assembly 7 (thickness 150 mm) made of glass wool having a basis weight of 2,400 g / m 2 while the nonwoven fabric sheet 13 and the yarn 5 are continuous.
) Was sewn, and finally only a thread was entangled to form an empty ring. By repeating this operation, the core material 9 having the shape shown in FIGS. 8 and 9 was obtained.

  Since the thickness of the core material was 18 mm and the handling was good, it was determined that the compression effect of the fiber assembly 7 in the present embodiment was sufficient.

  Next, the core material 9 was inserted into the bag-shaped outer cover material 10 together with the moisture adsorbing material 12 made of calcium oxide, and the vacuum heat insulating material 6 was obtained by sealing the interior of the outer cover material 10 under reduced pressure. When the thickness of the vacuum heat insulating material 6 was measured, it was 10.4 mm, and no deformation such as undulation was observed on the heat transfer surface of the vacuum heat insulating material 6, so that the flatness was judged to be good.

  In the core material 9 configured as described above, the large-diameter portion 11 having a cross-sectional area larger than that of the yarn 5 remains on the heat transfer surface 8 of the fiber assembly, and maintains the compressed state of the fiber assembly 7 even after sewing. In order to continue, the fiber assembly 7 is given rigidity. Accordingly, since the vacuum heat insulating material 6 using the fiber assembly 7 is compressed in the thickness direction, the amount of deformation in the thickness direction of the fiber assembly 7 is reduced before and after vacuum packaging, and the plane of the vacuum heat insulating material 6 is reduced. Sex is secured. Further, the flatness of the vacuum heat insulating material 6 can be ensured also in the step of depressurizing a part or the whole of the vacuum heat insulating material 6 and inspecting the internal vacuum degree of the vacuum heat insulating material 6.

  Furthermore, as compared with the main sewing method using the upper and lower two threads, the number of threads buried in the fiber assembly 7 is reduced, and the incidental effect that the thermal bridge is reduced occurs.

(Embodiment 5)
FIG. 10 is a cross-sectional view showing the configuration of the vacuum heat insulating material in Embodiment 5 of the present invention, FIG. 11 is a plan view showing the heat transfer surface of the core material used in the vacuum heat insulating material of the same embodiment, and FIG. It is sectional drawing at the time of cut | disconnecting the core material used for the vacuum heat insulating material of embodiment in the position of the EE line | wire of FIG. 11, and seeing the cross section from the direction of the arrow.

  As shown in FIGS. 10 to 12, the vacuum heat insulating material 6 of the present embodiment includes a core material 9 including two heat transfer surfaces 8 made of a fiber assembly 7, a moisture adsorbing material 12, and a core material. 9 and a covering material 10 covering the moisture adsorbing material 12, and the core material 9 is sealed in the covering material 10 under reduced pressure. The core material 9 includes a yarn 5 having a portion exposed to one heat transfer surface 8, a portion exposed to the other heat transfer surface 8, and a portion buried in the fiber assembly 7, and the fiber assembly 7. The fiber assembly 7 is compressed in the thickness direction by the tension of the yarn 5 and is connected in an annular shape so as to be exposed to the two heat transfer surfaces 8 that pass through the inside and face each other.

  In the present embodiment, the single thread 5 meanders so that most of the portion parallel to the longitudinal direction of the core material 9 is the majority, and finally returns to the starting point perpendicular to the longitudinal direction of the core material 9. Sewing on the course. Then, the ends of the yarn 5 are connected to form an annular shape.

  In the present embodiment, low density polyethylene having a fineness of 120 dtex is set as a thread 5 on a hand stitch sewing machine, and a fiber assembly 7 (thickness 150 mm) made of glass wool having a basis weight of 2,400 g / m 2 is shown in FIG. Then, the core material 9 having the shape shown in FIG. 12 was obtained by binding and sewing so that the portions penetrating through the fiber assembly 7 were distributed almost evenly, and finally binding both ends of the yarn 5.

  Since the thickness of the core material 9 was 25 mm and the handling was good, it was determined that the compression effect of the fiber assembly 7 in the present embodiment was sufficient.

Next, the core material 9 was inserted into the bag-shaped outer cover material 10 together with the moisture adsorbing material 12 made of calcium oxide, and the vacuum heat insulating material 6 was obtained by sealing the interior of the outer cover material 10 under reduced pressure. When the thickness of the vacuum heat insulating material 6 was measured, it was 11 mm, and no deformation such as undulation was observed on the heat transfer surface of the vacuum heat insulating material 6, so that the flatness was judged to be good.

  The core material 9 configured as described above compresses the fiber assembly 7 when the yarn 5 is tied in a ring shape, and maintains the compressed state of the fiber assembly 7 even after the yarn 5 is tied in a ring shape. In order to keep it held, rigidity is imparted to the fiber assembly 7. Since the fiber assembly 7 is compressed in the thickness direction, the amount of deformation in the thickness direction of the fiber assembly 7 is reduced after vacuum packaging, so that the flatness of the vacuum heat insulating material 6 is ensured. Further, the flatness of the vacuum heat insulating material 6 can be ensured also in the step of depressurizing a part or the whole of the vacuum heat insulating material 6 and inspecting the internal vacuum degree of the vacuum heat insulating material 6.

  Furthermore, as compared with the main sewing method using the upper and lower two threads, the number of threads buried in the fiber assembly 7 is reduced, and the incidental effect that the thermal bridge is reduced occurs.

(Embodiment 6)
FIG. 13 is a plan view showing the heat transfer surface of the core material used for the vacuum heat insulating material in Embodiment 6 of the present invention, and FIG. 14 shows the core material used for the vacuum heat insulating material of the same embodiment in FIG. It is sectional drawing at the time of cut | disconnecting in the position of F line and seeing the cross section from the direction of the arrow.

  As shown in FIGS. 13 and 14, the vacuum heat insulating material 6 of the present embodiment includes a core material 9 having two heat transfer surfaces 8 made of a fiber assembly 7 and facing each other, a moisture adsorbing material 12, and a core material. 9 and a covering material 10 covering the moisture adsorbing material 12, and the core material 9 is sealed in the covering material 10 under reduced pressure. The core material 9 includes a plurality of yarns 5 each having a portion exposed to one heat transfer surface 8, a portion exposed to the other heat transfer surface 8, and a portion buried in the fiber assembly 7. The yarn 5 penetrates the inside of the fiber assembly 7 from one heat transfer surface 8 and is exposed to the other heat transfer surface 8, and then penetrates the inside of the fiber assembly 7 from the other heat transfer surface 8. One end of the yarn 5 exposed on the heat surface 8 and remaining on one heat transfer surface 8 without penetrating the fiber assembly 7 and the fiber assembly 7 passing twice through the one end The other end of the yarn 5 exposed on the hot surface 8 is connected to form a ring of the yarn 5, and the fiber assembly 7 is compressed in the thickness direction by the tension of the yarn 5.

  It should be noted that the yarn 5 exposed on the heat transfer surface 8 forms a plurality of broken lines (five in FIG. 13) parallel to the longitudinal direction of the core material 9, and the portion penetrating through the yarn 5 fiber assembly 7 is almost the same. The portions that are evenly distributed in a grid pattern and exposed to the heat transfer surface 8 are arranged vertically in the longitudinal direction of the core member 9. The large diameter portion 11 formed by tying the yarn 5 is exposed only on one heat transfer surface 8.

  In the present embodiment, nylon having a fineness of 110 dtex is used as the yarn 5, and the yarn 5 is used from one heat transfer surface 8 of the fiber heat insulator 7 (thickness 150 mm) made of glass wool having a basis weight of 2,400 g / m 2 to the other. After passing through the heat transfer surface 8, it penetrates from one place on the other heat transfer surface 8 to the one heat transfer surface 8 and binds both ends of the yarn 5 to the shape shown in FIG. The core material 9 which becomes the shape was obtained.

  Since the thickness of the core material was 22 mm and the handling was good, it was determined that the compression effect of the fiber assembly 7 in the present embodiment was sufficient.

  Next, the core material 9 was inserted into the bag-shaped outer cover material 10 together with the moisture adsorbing material 12 made of calcium oxide, and the vacuum heat insulating material 6 was obtained by sealing the interior of the outer cover material 10 under reduced pressure. When the thickness of the vacuum heat insulating material 6 was measured, it was 9.7 mm, and no deformation such as undulation was observed on the heat transfer surface of the vacuum heat insulating material 6, so that the flatness was judged to be good.

The core material 9 configured as described above compresses the fiber assembly 7 when the yarn 5 is tied in a ring shape, and maintains the compressed state of the fiber assembly 7 even after the yarn 5 is tied in a ring shape. In order to keep it held, rigidity is imparted to the fiber assembly 7. Since the fiber assembly 7 is compressed in the thickness direction, the amount of deformation in the thickness direction of the fiber assembly 7 is reduced after vacuum packaging, so that the flatness of the vacuum heat insulating material 6 is ensured. Further, the flatness of the vacuum heat insulating material 6 can be ensured also in the step of depressurizing a part or the whole of the vacuum heat insulating material 6 and inspecting the internal vacuum degree of the vacuum heat insulating material 6.

  Furthermore, as compared with the main sewing method using the upper and lower two threads, the number of threads buried in the fiber assembly 7 is reduced, and the incidental effect that the thermal bridge is reduced occurs.

(Embodiment 7)
15 is a plan view showing the heat transfer surface of the core material used for the vacuum heat insulating material in Embodiment 7 of the present invention, and FIG. 16 shows the core material used for the vacuum heat insulating material of the same embodiment in FIG. It is sectional drawing at the time of cut | disconnecting in the position of G line and seeing the cross section from the direction of the arrow.

  As shown in FIGS. 15 and 16, the vacuum heat insulating material 6 of the present embodiment includes a core material 9 including two heat transfer surfaces 8 made of a fiber assembly 7, a moisture adsorbing material 12, and a core material. 9 and a covering material 10 covering the moisture adsorbing material 12, and the core material 9 is sealed in the covering material 10 under reduced pressure. The core material 9 includes a plurality of yarns 5 each having a portion exposed to one heat transfer surface 8, a portion exposed to the other heat transfer surface 8, and a portion buried in the fiber assembly 7. The yarn 5 penetrates the inside of the fiber assembly 7 from one heat transfer surface 8 and is exposed to the other heat transfer surface 8, and then penetrates the inside of the fiber assembly 7 from the other heat transfer surface 8. One end of the yarn 5 exposed on the heat surface 8 and remaining on one heat transfer surface 8 without penetrating the fiber assembly 7 and the fiber assembly 7 passing twice through the one end The other end of the yarn 5 exposed on the hot surface 8 is connected to form a ring of the yarn 5, and the fiber assembly 7 is compressed in the thickness direction by the tension of the yarn 5.

  It should be noted that the yarn 5 exposed on the heat transfer surface 8 forms a plurality of broken lines (five in FIG. 13) parallel to the longitudinal direction of the core material 9, and the portion penetrating through the yarn 5 fiber assembly 7 is almost the same. A portion that is uniformly distributed in a zigzag shape and exposed to the heat transfer surface 8 is exposed only to the heat transfer surface 8 of the core material 9 in a zigzag shape, and a large diameter portion 11 formed by tying the yarn 5 is one side. Only the heat transfer surface 8 is exposed.

  In the present embodiment, nylon having a fineness of 110 dtex is used as the yarn 5, and the yarn 5 is used from one heat transfer surface 8 of the fiber heat insulator 7 (thickness 150 mm) made of glass wool having a basis weight of 2,400 g / m 2 to the other. After passing through the heat transfer surface 8, it penetrates from one location on the other heat transfer surface 8 to the one heat transfer surface 8 and binds both ends of the yarn 5 to the shape shown in FIG. The core material 9 which becomes a shape was obtained.

  Since the thickness of the core material 9 was 18 mm and the handling was good, it was determined that the compression effect of the fiber assembly 7 in the present embodiment was sufficient.

  Next, the core material 9 was inserted into the bag-shaped outer cover material 10 together with the moisture adsorbing material 12 made of calcium oxide, and the vacuum heat insulating material 6 was obtained by sealing the interior of the outer cover material 10 under reduced pressure. When the thickness of the vacuum heat insulating material 6 was measured, it was 10.1 mm, and no deformation such as undulation was observed on the heat transfer surface of the vacuum heat insulating material, so that the flatness was judged to be good.

  The core material 9 configured as described above compresses the fiber assembly 7 when the yarn 5 is tied in a ring shape, and maintains the compressed state of the fiber assembly 7 even after the yarn 5 is tied in a ring shape. In order to keep it held, rigidity is imparted to the fiber assembly 7. Since the fiber assembly 7 is compressed in the thickness direction, the amount of deformation in the thickness direction of the fiber assembly 7 is reduced after vacuum packaging, so that the flatness of the vacuum heat insulating material 6 is ensured. Further, the flatness of the vacuum heat insulating material 6 can be ensured also in the step of depressurizing a part or the whole of the vacuum heat insulating material 6 and inspecting the internal vacuum degree of the vacuum heat insulating material 6.

  Furthermore, as compared with the main sewing method using the upper and lower two threads, the number of threads buried in the fiber assembly 7 is reduced, and the incidental effect that the thermal bridge is reduced occurs.

(Embodiment 8)
FIG. 17 is a plan view showing a heat transfer surface of the core material used for the vacuum heat insulating material in Embodiment 8 of the present invention, and FIG. 18 shows the core material used for the vacuum heat insulating material of the same embodiment in FIG. It is sectional drawing at the time of cut | disconnecting in the position of H line and seeing the cross section from the direction of the arrow.

  As shown in FIGS. 17 and 18, the vacuum heat insulating material 6 of the present embodiment includes a core material 9 including two heat transfer surfaces 8 made of a fiber assembly 7, a moisture adsorbing material 12, and a core material. 9 and a covering material 10 covering the moisture adsorbing material 12, and the core material 9 is sealed in the covering material 10 under reduced pressure. Further, the core material 9 has a plurality (seven in FIG. 17) having a portion exposed on one heat transfer surface 8, a portion exposed on the other heat transfer surface 8, and a portion buried in the fiber assembly 7. A plurality of (seven in FIG. 17) yarns 5 are provided, and are sewn together in parallel with the longitudinal direction of the core material 9, separated from each other by a predetermined distance, and at the end in the longitudinal direction of the core material 9. The ends of adjacent yarns 5 are connected to form a ring, and a plurality of rings of the yarn 5 are provided. The fiber assembly 7 is compressed in the thickness direction by the tension of the yarn 5.

  In the present embodiment, a yarn made of polyethylene terephthalate having a fineness of 205 dtex and a fiber assembly 7 made of glass wool (thickness 150 mm) having a basis weight of 2,400 g / m 2 were set on a hand stitch sewing machine. Next, the thread is sewn so as to be linear, and a plurality of threads located on the same side of the fiber assembly 7 are connected as shown in FIGS. 17 and 18 so that the thread 5 is bound in an annular shape. The material 9 was obtained. Since the thickness of the core material 9 was 21 mm and the handling was good, it was determined that the compression effect of the fiber assembly 7 in the present embodiment was sufficient.

  Next, the core material 9 was inserted into the bag-shaped outer cover material 10 together with the moisture adsorbing material 12 made of calcium oxide, and the vacuum heat insulating material 6 was obtained by sealing the interior of the outer cover material 10 under reduced pressure. When the thickness of the vacuum heat insulating material 6 was measured, it was 10.4 mm, and no deformation such as undulation was observed on the heat transfer surface of the vacuum heat insulating material 6, so that the flatness was judged to be good.

  The core material 9 configured as described above compresses the fiber assembly 7 when the yarn 5 is tied in a ring shape, and maintains the compressed state of the fiber assembly 7 even after the yarn 5 is tied in a ring shape. In order to keep it held, rigidity is imparted to the fiber assembly 7. Since the fiber assembly 7 is compressed in the thickness direction, the amount of deformation in the thickness direction of the fiber assembly 7 is reduced after vacuum packaging, so that the flatness of the vacuum heat insulating material 6 is ensured. Further, the flatness of the vacuum heat insulating material 6 can be ensured also in the step of depressurizing a part or the whole of the vacuum heat insulating material 6 and inspecting the internal vacuum degree of the vacuum heat insulating material 6.

  Furthermore, as compared with the main sewing method using the upper and lower two threads, the number of threads buried in the fiber assembly 7 is reduced, and the incidental effect that the thermal bridge is reduced occurs.

(Comparative example)
A polyethylene terephthalate having a fineness of 135 dtex was set as a thread on a hand stitch sewing machine, a fiber assembly (thickness 150 mm) made of glass wool having a basis weight of 2,400 g / m 2 was sewn, and a core material was obtained. However, since the thread was released immediately after sewing, the thickness of the core material was restored to 85 mm and it was difficult to handle. Therefore, it was determined that the compression effect of the fiber assembly was insufficient in this comparative example.

Next, the core material was inserted into a bag-shaped jacket material together with a moisture adsorbing material made of calcium oxide, and the vacuum jacket was obtained by sealing the inside of the jacket material under reduced pressure. When the thickness of this vacuum heat insulating material is measured, it is 9
. Although it was 5 mm, it was judged that ensuring of flatness was not sufficient because the heat transfer surface of the vacuum heat insulating material was wavy.

Since the vacuum heat insulating material of the present invention has a small amount of deformation in the thickness direction of the fiber assembly before and after vacuum packaging, the flatness of the vacuum heat insulating material is ensured without increasing the organic gas . Further, the flatness of the vacuum heat insulating material can be ensured also in the step of depressurizing a part or the whole of the vacuum heat insulating material and inspecting the internal vacuum degree of the vacuum heat insulating material. Therefore, the vacuum heat insulating material of the present invention can be used in any application to which a vacuum heat insulating material can be applied, such as a refrigerator, a jar pot, a rice cooker, a vending machine, and a house.

5 Yarn 6 Vacuum Insulating Material 7 Fiber Assembly 8 Heat Transfer Surface 9 Core Material 10 Outer Material 11 Large Diameter Part 13 Nonwoven Sheet (Mooring Member)

Claims (6)

At least a plurality of core members made of a fiber assembly and having two heat transfer surfaces facing each other;
A jacket material covering the core material,
A vacuum heat insulating material in which the core material is vacuum-sealed in the outer jacket material,
A yarn having a portion exposed to one of the heat transfer surfaces of the core, a portion exposed to the other heat transfer surface, and a portion buried in the fiber assembly;
The yarn is a produced yarn not provided with a colorant ,
Has a larger cross sectional area than the cross-sectional area before Symbol yarns, the remain in the heat transfer surface of the fiber assembly also has a large diameter portion which continues to hold the compressed state of the fiber aggregate after sewing,
A vacuum heat insulating material in which the plurality of core members are stacked and compressed in the thickness direction by the tension of the yarn. The fiber aggregate, the vacuum heat insulating material according to claim 1 is a fiber insulation. The refrigerator provided with the vacuum heat insulating material of Claim 1 or 2 . Pots having a vacuum heat insulating material according to claim 1 or 2. Housing provided with a vacuum heat insulating material according to claim 1 or 2. The vacuum heat insulating material according to claim 1, wherein the large diameter portion has a size that is difficult to move in the thickness direction in the fiber assembly.