JP5944290B2 - Compositions and cosmetics in which fading is prevented - Google Patents
Compositions and cosmetics in which fading is prevented Download PDFInfo
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- JP5944290B2 JP5944290B2 JP2012211747A JP2012211747A JP5944290B2 JP 5944290 B2 JP5944290 B2 JP 5944290B2 JP 2012211747 A JP2012211747 A JP 2012211747A JP 2012211747 A JP2012211747 A JP 2012211747A JP 5944290 B2 JP5944290 B2 JP 5944290B2
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- 238000005562 fading Methods 0.000 title claims description 77
- 239000000203 mixture Substances 0.000 title claims description 76
- 239000002537 cosmetic Substances 0.000 title claims description 35
- 239000000980 acid dye Substances 0.000 claims description 41
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 36
- 230000002378 acidificating effect Effects 0.000 claims description 35
- 239000000975 dye Substances 0.000 claims description 34
- 239000003814 drug Substances 0.000 claims description 26
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 19
- 239000004310 lactic acid Substances 0.000 claims description 18
- 235000014655 lactic acid Nutrition 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 15
- 229940079593 drug Drugs 0.000 claims description 13
- 235000013305 food Nutrition 0.000 claims description 13
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 claims description 7
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 7
- 150000004056 anthraquinones Chemical class 0.000 claims description 7
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 claims description 7
- 238000002845 discoloration Methods 0.000 claims description 5
- 239000002304 perfume Substances 0.000 claims description 2
- 239000003205 fragrance Substances 0.000 description 35
- 239000000049 pigment Substances 0.000 description 18
- 230000002265 prevention Effects 0.000 description 14
- 239000007788 liquid Substances 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- 239000000796 flavoring agent Substances 0.000 description 11
- 235000019634 flavors Nutrition 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000008213 purified water Substances 0.000 description 9
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 8
- -1 and the like Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000000284 extract Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 235000006708 antioxidants Nutrition 0.000 description 3
- 238000004649 discoloration prevention Methods 0.000 description 3
- JGUMTYWKIBJSTN-UHFFFAOYSA-N 2-ethylhexyl 4-[[4,6-bis[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 JGUMTYWKIBJSTN-UHFFFAOYSA-N 0.000 description 2
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 241000207199 Citrus Species 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000020971 citrus fruits Nutrition 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 2
- 150000003306 rutin derivatives Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BOCBOJPUWMTAJB-UHFFFAOYSA-N (2-butylphenyl) 2-hydroxybenzoate Chemical compound CCCCC1=CC=CC=C1OC(=O)C1=CC=CC=C1O BOCBOJPUWMTAJB-UHFFFAOYSA-N 0.000 description 1
- OIQXFRANQVWXJF-QBFSEMIESA-N (2z)-2-benzylidene-4,7,7-trimethylbicyclo[2.2.1]heptan-3-one Chemical compound CC1(C)C2CCC1(C)C(=O)\C2=C/C1=CC=CC=C1 OIQXFRANQVWXJF-QBFSEMIESA-N 0.000 description 1
- FBZQBGYPONNWCG-UHFFFAOYSA-N (4,5-dihydroxy-2,3-dimethoxyphenyl)-phenylmethanone Chemical compound COC1=C(O)C(O)=CC(C(=O)C=2C=CC=CC=2)=C1OC FBZQBGYPONNWCG-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- WHQOKFZWSDOTQP-UHFFFAOYSA-N 2,3-dihydroxypropyl 4-aminobenzoate Chemical compound NC1=CC=C(C(=O)OCC(O)CO)C=C1 WHQOKFZWSDOTQP-UHFFFAOYSA-N 0.000 description 1
- OSJVRHJQUTTZIN-UHFFFAOYSA-N 2-ethoxyethyl 2-methoxy-3-phenylprop-2-enoate Chemical compound CCOCCOC(=O)C(OC)=CC1=CC=CC=C1 OSJVRHJQUTTZIN-UHFFFAOYSA-N 0.000 description 1
- WSSJONWNBBTCMG-UHFFFAOYSA-N 2-hydroxybenzoic acid (3,3,5-trimethylcyclohexyl) ester Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C1=CC=CC=C1O WSSJONWNBBTCMG-UHFFFAOYSA-N 0.000 description 1
- LVYLCBNXHHHPSB-UHFFFAOYSA-N 2-hydroxyethyl salicylate Chemical compound OCCOC(=O)C1=CC=CC=C1O LVYLCBNXHHHPSB-UHFFFAOYSA-N 0.000 description 1
- ZSNLEVJATWJBLU-UHFFFAOYSA-N 2-tert-butyl-2-methoxy-1,3-diphenylpropane-1,3-dione Chemical compound C=1C=CC=CC=1C(=O)C(C(C)(C)C)(OC)C(=O)C1=CC=CC=C1 ZSNLEVJATWJBLU-UHFFFAOYSA-N 0.000 description 1
- ZUYVPAKYYMBQBT-UHFFFAOYSA-N 3,4-diethyl-2-hexoxyphenol Chemical compound CCCCCCOC1=C(O)C=CC(CC)=C1CC ZUYVPAKYYMBQBT-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- JMGZEFIQIZZSBH-UHFFFAOYSA-N Bioquercetin Natural products CC1OC(OCC(O)C2OC(OC3=C(Oc4cc(O)cc(O)c4C3=O)c5ccc(O)c(O)c5)C(O)C2O)C(O)C(O)C1O JMGZEFIQIZZSBH-UHFFFAOYSA-N 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 description 1
- 239000002211 L-ascorbic acid Substances 0.000 description 1
- 235000000069 L-ascorbic acid Nutrition 0.000 description 1
- 229930182559 Natural dye Natural products 0.000 description 1
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 241000219995 Wisteria Species 0.000 description 1
- YRXGUZPUZBCGST-UHFFFAOYSA-N [2-(hydroxymethoxy)phenyl]-phenylmethanone Chemical compound OCOC1=CC=CC=C1C(=O)C1=CC=CC=C1 YRXGUZPUZBCGST-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- XNEFYCZVKIDDMS-UHFFFAOYSA-N avobenzone Chemical compound C1=CC(OC)=CC=C1C(=O)CC(=O)C1=CC=C(C(C)(C)C)C=C1 XNEFYCZVKIDDMS-UHFFFAOYSA-N 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 235000012745 brilliant blue FCF Nutrition 0.000 description 1
- 235000021466 carotenoid Nutrition 0.000 description 1
- 150000001747 carotenoids Chemical class 0.000 description 1
- 229940114081 cinnamate Drugs 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 235000013345 egg yolk Nutrition 0.000 description 1
- 210000002969 egg yolk Anatomy 0.000 description 1
- UVCJGUGAGLDPAA-UHFFFAOYSA-N ensulizole Chemical compound N1C2=CC(S(=O)(=O)O)=CC=C2N=C1C1=CC=CC=C1 UVCJGUGAGLDPAA-UHFFFAOYSA-N 0.000 description 1
- 229960000655 ensulizole Drugs 0.000 description 1
- IVTMALDHFAHOGL-UHFFFAOYSA-N eriodictyol 7-O-rutinoside Natural products OC1C(O)C(O)C(C)OC1OCC1C(O)C(O)C(O)C(OC=2C=C3C(C(C(O)=C(O3)C=3C=C(O)C(O)=CC=3)=O)=C(O)C=2)O1 IVTMALDHFAHOGL-UHFFFAOYSA-N 0.000 description 1
- IAJNXBNRYMEYAZ-UHFFFAOYSA-N ethyl 2-cyano-3,3-diphenylprop-2-enoate Chemical compound C=1C=CC=CC=1C(=C(C#N)C(=O)OCC)C1=CC=CC=C1 IAJNXBNRYMEYAZ-UHFFFAOYSA-N 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229960002389 glycol salicylate Drugs 0.000 description 1
- 229960004881 homosalate Drugs 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 1
- LZXXNPOYQCLXRS-UHFFFAOYSA-N methyl 4-aminobenzoate Chemical compound COC(=O)C1=CC=C(N)C=C1 LZXXNPOYQCLXRS-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000978 natural dye Substances 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 229960001679 octinoxate Drugs 0.000 description 1
- 229960003921 octisalate Drugs 0.000 description 1
- FMJSMJQBSVNSBF-UHFFFAOYSA-N octocrylene Chemical group C=1C=CC=CC=1C(=C(C#N)C(=O)OCC(CC)CCCC)C1=CC=CC=C1 FMJSMJQBSVNSBF-UHFFFAOYSA-N 0.000 description 1
- 229960000601 octocrylene Drugs 0.000 description 1
- WCJLCOAEJIHPCW-UHFFFAOYSA-N octyl 2-hydroxybenzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1O WCJLCOAEJIHPCW-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- 229960000969 phenyl salicylate Drugs 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229940100498 polysilicone-15 Drugs 0.000 description 1
- 229920002282 polysilicones-15 Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical compound O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 1
- FDRQPMVGJOQVTL-UHFFFAOYSA-N quercetin rutinoside Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC=2C(C3=C(O)C=C(O)C=C3OC=2C=2C=C(O)C(O)=CC=2)=O)O1 FDRQPMVGJOQVTL-UHFFFAOYSA-N 0.000 description 1
- WPPDXAHGCGPUPK-UHFFFAOYSA-N red 2 Chemical compound C1=CC=CC=C1C(C1=CC=CC=C11)=C(C=2C=3C4=CC=C5C6=CC=C7C8=C(C=9C=CC=CC=9)C9=CC=CC=C9C(C=9C=CC=CC=9)=C8C8=CC=C(C6=C87)C(C=35)=CC=2)C4=C1C1=CC=CC=C1 WPPDXAHGCGPUPK-UHFFFAOYSA-N 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- IKGXIBQEEMLURG-NVPNHPEKSA-N rutin Chemical compound O[C@@H]1[C@H](O)[C@@H](O)[C@H](C)O[C@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](OC=2C(C3=C(O)C=C(O)C=C3OC=2C=2C=C(O)C(O)=CC=2)=O)O1 IKGXIBQEEMLURG-NVPNHPEKSA-N 0.000 description 1
- ALABRVAAKCSLSC-UHFFFAOYSA-N rutin Natural products CC1OC(OCC2OC(O)C(O)C(O)C2O)C(O)C(O)C1OC3=C(Oc4cc(O)cc(O)c4C3=O)c5ccc(O)c(O)c5 ALABRVAAKCSLSC-UHFFFAOYSA-N 0.000 description 1
- 235000005493 rutin Nutrition 0.000 description 1
- 229960004555 rutoside Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- JAOZKJMVYIWLKU-UHFFFAOYSA-N sodium 7-hydroxy-8-[(4-sulfonaphthalen-1-yl)diazenyl]naphthalene-1,3-disulfonic acid Chemical compound C1=CC=C2C(=C1)C(=CC=C2S(=O)(=O)O)N=NC3=C(C=CC4=CC(=CC(=C43)S(=O)(=O)O)S(=O)(=O)O)O.[Na+] JAOZKJMVYIWLKU-UHFFFAOYSA-N 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 235000020238 sunflower seed Nutrition 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
Landscapes
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Medicinal Preparation (AREA)
- Cosmetics (AREA)
Description
本発明は、食品、化粧品、医薬品及び医薬部外品に好適に用いることができる退色防止組成物に関する。また、本発明は、上記退色防止組成物を用いた化粧品に関する。 The present invention relates to an anti-fading composition that can be suitably used for foods, cosmetics, pharmaceuticals, and quasi drugs. Moreover, this invention relates to the cosmetics using the said discoloration prevention composition.
食品、化粧品、医薬品及び医薬部外品などに用いられる各種の組成物では、外観色を付与するために、色素が用いられている。 In various compositions used for foods, cosmetics, pharmaceuticals, quasi drugs, and the like, pigments are used to impart an appearance color.
色素を含む組成物では、日光等の紫外線や蛍光灯等の光線により、分解反応や酸化還元反応が進行することがある。このため、色素を含む組成物が退色することがある。具体的には、色素を含む組成物が変色したり、色素を含む組成物の色の濃淡が変わったりする。特に、酸性色素を含む組成物では、紫外線や光線によって、著しい退色が生じることがある。食品、化粧品、医薬品及び医薬部外品に用いられる組成物では、退色は大きな問題となることがある。 In a composition containing a dye, a decomposition reaction or an oxidation-reduction reaction may proceed due to ultraviolet rays such as sunlight or light from a fluorescent lamp. For this reason, the composition containing a pigment may fade. Specifically, the composition containing the dye changes color, or the color density of the composition containing the dye changes. In particular, in a composition containing an acidic dye, significant fading may occur due to ultraviolet rays or light. In compositions used in foods, cosmetics, pharmaceuticals and quasi drugs, fading can be a major problem.
従来、退色を抑えるための方法として、紫外線吸収剤、抗酸化剤、ｐＨ緩衝剤又は各種の抽出物を用いる方法が知られている。 Conventionally, as a method for suppressing fading, a method using an ultraviolet absorber, an antioxidant, a pH buffer or various extracts is known.
具体的には、下記の特許文献１には、ヒマワリの種子又はその搾油粕から水又は含水アルコールで抽出される成分と、Ｌ−アスコルビン酸又はその塩類とを含む退色防止剤が開示されている。下記の特許文献２には、ヤマモト科植物抽出物を用いる色素の安定化法が開示されている。下記の特許文献３には、脱脂卵黄の加水分解物と、水溶性抗酸化剤とを含むカロチノイド系色素の退色防止剤が開示されている。下記の特許文献４には、カムカム果汁及び／又はカムカム抽出物と、有機系紫外線吸収剤及び／又は無機系紫外線散乱剤とを含む退色防止組成物が開示されている。下記の特許文献５には、酵素処理ルチンと藤茶抽出物とを含むルチン誘導体組成物が開示されており、該ルチン誘導体組成物を色素の退色防止及び変色防止に用いることが記載されている。 Specifically, the following Patent Document 1 discloses an anti-fading agent comprising a component extracted from sunflower seeds or oiled lees thereof with water or hydrous alcohol, and L-ascorbic acid or salts thereof. . Patent Document 2 below discloses a pigment stabilization method using a Yamamoto plant extract. Patent Document 3 below discloses a carotenoid pigment discoloration inhibitor containing a hydrolyzed product of defatted egg yolk and a water-soluble antioxidant. Patent Document 4 below discloses a discoloration prevention composition containing cam cam juice and / or cam cam extract, and an organic ultraviolet absorber and / or an inorganic ultraviolet scattering agent. Patent Document 5 below discloses a rutin derivative composition containing an enzyme-treated rutin and a wisteria tea extract, and describes that the rutin derivative composition is used for preventing fading and discoloration of a pigment. .
特許文献１〜５に記載のように、色素を含む組成物の退色を抑える数多くの試みが検討されている。しかしながら、従来の退色防止組成物及び退色防止方法では、紫外線や光線によって、色素を含む組成物の退色を十分に抑制できないことがある。特に、組成物が香料を含まない場合には、退色を抑制できたとしても、組成物が香料を含む場合には、退色を十分に抑制できないことがある。特に、香料を用いかつ色素として酸性色素を用いた場合には、香料と酸性色素とを含む組成物の退色が特に生じやすいという問題がある。 As described in Patent Documents 1 to 5, many attempts have been made to suppress fading of a composition containing a pigment. However, in the conventional fading prevention composition and the fading prevention method, the fading of the composition containing the pigment may not be sufficiently suppressed by ultraviolet rays or light. In particular, when the composition does not contain a fragrance, even if the color fading can be suppressed, the color fading may not be sufficiently suppressed when the composition contains a fragrance. In particular, when a fragrance is used and an acidic pigment is used as a pigment, there is a problem that fading of a composition containing the fragrance and the acidic pigment is particularly likely to occur.
本発明の目的は、香料を用いているにも関わらず、かつ色素として酸性色素を用いているにも関わらず、紫外線や光線による退色を抑えることができる退色防止組成物、並びに該退色防止組成物を用いた化粧品を提供することである。 An object of the present invention is to provide an anti-fading composition capable of suppressing fading due to ultraviolet rays or light, regardless of whether a fragrance is used or an acidic pigment as a pigment, and the anti-fading composition. It is to provide cosmetics using products.
本発明の広い局面によれば、香料と、紫外線吸収剤と、乳酸と、酸性色素とを含む、退色防止組成物が提供される。 According to a broad aspect of the present invention, there is provided a fading prevention composition comprising a fragrance, an ultraviolet absorber, lactic acid, and an acidic dye.
本発明に係る退色防止組成物のある特定の局面では、該退色防止組成物は、乳酸塩を実質的に含まない。 In a specific aspect of the anti-fading composition according to the present invention, the anti-fading composition is substantially free of lactate.
本発明に係る退色防止組成物のある特定の局面では、前記酸性色素が、アゾ系酸性色素、トリフェニルメタン系酸性色素又はアントラキノン系酸性色素である。 In a specific aspect of the anti-fading composition according to the present invention, the acidic dye is an azo acid dye, a triphenylmethane acid dye, or an anthraquinone acid dye.
本発明に係る退色防止組成物のある特定の局面では、該退色防止組成物は、溶剤をさらに含む。 On the specific situation with the fading prevention composition which concerns on this invention, this fading prevention composition further contains a solvent.
本発明に係る退色防止組成物は、食品、化粧品、医薬品又は医薬部外品に好適に用いられる。 The anti-fading composition according to the present invention is suitably used for foods, cosmetics, pharmaceuticals or quasi drugs.
本発明の広い局面によれば、容器と、前記容器内に充填されている化粧料とを備え、前記化粧料が、上述した退色防止組成物を含有する、化粧品が提供される。 According to a wide aspect of the present invention, there is provided a cosmetic comprising a container and a cosmetic filled in the container, wherein the cosmetic contains the above-described fading preventing composition.
本発明に係る退色防止組成物では、香料と紫外線吸収剤と乳酸と酸性色素とが組み合わされているので、香料を用いているにも関わらず、かつ色素として酸性色素を用いているにも関わらず、紫外線や光線による退色を抑えることができる。 In the anti-fading composition according to the present invention, since a fragrance, an ultraviolet absorber, lactic acid, and an acidic dye are combined, although the fragrance is used, an acidic dye is used as the dye. Therefore, fading due to ultraviolet rays or light can be suppressed.
以下、本発明を詳細に説明する。 Hereinafter, the present invention will be described in detail.
本発明に係る退色防止組成物は、（Ａ）香料と、（Ｂ）紫外線吸収剤と、（Ｃ）乳酸と、（Ｄ）酸性色素とを含む。 The anti-fading composition according to the present invention comprises (A) a fragrance, (B) an ultraviolet absorber, (C) lactic acid, and (D) an acidic dye.
本発明に係る退色防止組成物では、上述した成分（Ａ）〜（Ｄ）が組み合わされているので、香料を用いているにも関わらず、更に用いている色素が（Ｄ）酸性色素であるにも関わらず、日光等の紫外線や蛍光灯等の光線による退色を抑えることができる。すなわち、本発明に係る退色防止組成物や、本発明に係る退色防止組成物を用いた食品、化粧品、医薬品及び医薬部外品に、紫外線や光線が照射されても、変色を生じ難くし、かつ色の濃淡を変化し難くすることができる。本発明は、（Ａ）香料と（Ｄ）酸性色素とを含む組成において、退色防止性を高めたことに特徴を有する。また、本発明では、（Ａ）香料を含む組成において、（Ｄ）酸性色素としてある特定の酸性色素Ｄ１を用いる場合に、特定の酸性色素Ｄ１とともに（Ｂ），（Ｃ）成分を組み合わせることにより、特定の酸性色素Ｄ１とともに（Ｂ），（Ｃ）成分を組み合わせていない場合と比べて、退色を抑えることができる。 In the anti-fading composition according to the present invention, since the components (A) to (D) described above are combined, the dye further used is the (D) acidic dye despite the use of the fragrance. Nevertheless, fading due to ultraviolet rays such as sunlight and light rays such as fluorescent lamps can be suppressed. That is, the anti-fading composition according to the present invention and foods, cosmetics, pharmaceuticals and quasi-drugs using the anti-fading composition according to the present invention are less likely to cause discoloration even when irradiated with ultraviolet rays or light. In addition, it is possible to make it difficult to change the color shading. The present invention is characterized in that fading prevention is enhanced in a composition containing (A) a fragrance and (D) an acidic dye. In the present invention, in the composition containing (A) the fragrance, when (D) a specific acidic dye D1 is used as the acidic dye, the (B) and (C) components are combined with the specific acidic dye D1. As compared with the case where the components (B) and (C) are not combined with the specific acidic dye D1, fading can be suppressed.
（Ａ）香料と（Ｂ）紫外線吸収剤と（Ｃ）乳酸と（Ｄ）酸性色素とを均一に混合するために、本発明に係る退色防止組成物は、（Ｅ）溶剤を含むことが好ましい。 In order to uniformly mix (A) the fragrance, (B) the ultraviolet absorber, (C) lactic acid, and (D) the acidic dye, the anti-fading composition according to the present invention preferably includes (E) a solvent. .
以下、本発明に係る退色防止組成物に用いられる各成分を具体的に説明する。 Hereafter, each component used for the fading prevention composition which concerns on this invention is demonstrated concretely.
（（Ａ）香料）
（Ａ）香料は、付与したい香調に応じて適宜選定される。（Ａ）香料の香調としては、シトラス系、グリーン系、フローラル系、フルーティ系及びフゼア系等が挙げられる。これらのいずれの香調の香料を用いてもよい。また、これら以外の香調の香料を用いてもよい。（Ａ）香料は特に限定されない。（Ａ）香料は、１種のみが用いられてもよく、２種以上が併用されてもよい。
((A) fragrance)
(A) A fragrance | flavor is suitably selected according to the fragrance tone to give. (A) Citrus type, green type, floral type, fruity type, fuze type, etc. are mentioned as a fragrance tone of a fragrance | flavor. Any of these perfumes may be used. Moreover, you may use the fragrance | flavor of fragrance | flavor other than these. (A) A fragrance | flavor is not specifically limited. (A) Only 1 type may be used for a fragrance | flavor and 2 or more types may be used together.
食品、化粧品、医薬品及び医薬部外品などの用途に応じて、（Ａ）香料の配合量は適宜調整される。上記退色防止組成物１００質量％中、（Ａ）香料の含有量は、好ましくは０．０１質量％以上、より好ましくは０．０５質量％以上、好ましくは２０質量％以下、より好ましくは１０質量％以下である。（Ａ）香料の含有量が上記下限以上及び上記上限以下であると、香りを適度に調整でき、退色防止効果がより一層効果的に得られる。 The blending amount of (A) the fragrance is appropriately adjusted according to the use such as food, cosmetics, pharmaceuticals and quasi drugs. In 100% by mass of the anti-fading composition, the content of the fragrance (A) is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, preferably 20% by mass or less, more preferably 10% by mass. % Or less. (A) When content of a fragrance | flavor is more than the said minimum and below the said upper limit, a fragrance can be adjusted moderately and the fading prevention effect will be obtained much more effectively.
（（Ｂ）紫外線吸収剤）
（Ｂ）紫外線吸収剤としては、パラアミノ安息香酸、パラアミノ安息香酸メチル、パラアミノ安息香酸グリセリル、パラジメチルアミノ安息香酸アミル、パラジメチルアミノ安息香酸オクチル、サリチル酸エチレングリコール、サリチル酸フェニル、サリチル酸オクチル、サリチル酸ブチルフェニル、サリチル酸ホモメンチル、パラメトキシケイ皮酸オクチル、メトキシケイ皮酸エトキシエチル、ジメトキシケイ皮酸モノエチルヘキサン酸グリセリル、ヒドロキシメトキシベンゾフェノン、ジヒドロキシジメトキシベンゾフェノン、オクチルトリアゾン、メトキシケイヒ酸エチルヘキシル、ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル、オクトクリレン、ポリシリコン−１５、ビスエチルヘキシルオキシフェノールメトキシフェニルトリアジン、オキシベンゾン−３、２，４，６−トリス［４−（２−エチルヘキシルオキシカルボニル）アニリノ］−１，３，５−トリアジン、ｔ−ブチルメトキシジベンゾイルメタン、ベンゾトリアゾール、ベンジリデンカンファー、トリメトキシケイヒ酸メチルビス（トリメチルシロキシ）シリルイソペンチル、及びフェニルベンズイミダゾールスルホン酸等が挙げられる。これら以外の紫外線吸収剤を用いてもよい。
((B) UV absorber)
(B) As an ultraviolet absorber, paraaminobenzoic acid, methyl paraaminobenzoate, glyceryl paraaminobenzoate, amyl paradimethylaminobenzoate, octyl paradimethylaminobenzoate, ethylene glycol salicylate, phenyl salicylate, octyl salicylate, butylphenyl salicylate , Homomenthyl salicylate, octyl paramethoxycinnamate, ethoxyethyl methoxycinnamate, glyceryl monoethyl hexanoate dimethoxycinnamate, hydroxymethoxybenzophenone, dihydroxydimethoxybenzophenone, octyl triazone, ethylhexyl methoxycinnamate, diethylaminohydroxybenzoylbenzoic acid Hexyl, Octocrylene, Polysilicone-15, Bisethylhexyloxyphenol methoxypheny Triazine, oxybenzone-3, 2,4,6-tris [4- (2-ethylhexyloxycarbonyl) anilino] -1,3,5-triazine, t-butylmethoxydibenzoylmethane, benzotriazole, benzylidene camphor, trimethoxy Examples thereof include methyl bis (trimethylsiloxy) silylisopentyl cinnamate and phenylbenzimidazole sulfonic acid. You may use ultraviolet absorbers other than these.
（Ｂ）紫外線吸収剤は、ＵＶ−Ａ領域（３２０〜４００ｎｍの波長領域）に吸収能を有するものであっても、ＵＶ−Ｂ領域（２８０〜３２０ｎｍの吸収波長）に吸収能を有するものであってもよく、特に限定されない。退色をより一層効果的に防止する観点から、ＵＶ−Ａ領域（３２０〜４００ｎｍの波長領域）に吸収能を有する紫外線吸収剤がより好ましい。 (B) The ultraviolet absorber has absorption ability in the UV-B region (absorption wavelength of 280 to 320 nm) even if it has absorption ability in the UV-A region (wavelength region of 320 to 400 nm). There may be, and it is not specifically limited. From the viewpoint of more effectively preventing fading, an ultraviolet absorber having an absorption ability in the UV-A region (wavelength region of 320 to 400 nm) is more preferable.
食品、化粧品、医薬品及び医薬部外品などの用途に応じて、（Ｂ）紫外線吸収剤の配合量は適宜調整される。上記退色防止組成物１００質量％中、（Ｂ）紫外線吸収剤の含有量は、好ましくは０．００１質量％以上、より好ましくは０．００５質量％以上、好ましくは５質量％以下、より好ましくは１質量％以下である。（Ｂ）紫外線吸収剤の含有量が上記下限以上及び上記上限以下であると、退色防止効果がより一層効果的に得られる。 The blending amount of the (B) ultraviolet absorber is appropriately adjusted according to the use such as food, cosmetics, pharmaceuticals and quasi drugs. In 100% by mass of the anti-fading composition, the content of the (B) ultraviolet absorber is preferably 0.001% by mass or more, more preferably 0.005% by mass or more, preferably 5% by mass or less, more preferably. 1% by mass or less. (B) When content of a ultraviolet absorber is more than the said minimum and below the said upper limit, the discoloration prevention effect is obtained more effectively.
（（Ｃ）乳酸）
上記退色防止組成物では、乳酸塩ではなく、（Ｃ）乳酸を用いる。組成物中で（Ａ），（Ｂ），（Ｄ）成分とともに（Ｃ）乳酸が含まれていることにより、退色防止性能がかなり向上する。
((C) lactic acid)
In the anti-fading composition, (C) lactic acid is used instead of lactate. By containing (C) lactic acid together with the components (A), (B), and (D) in the composition, the fading prevention performance is significantly improved.
本発明に係る上記退色防止組成物は、乳酸塩を実質的に含まないことが好ましい。これにより、退色防止効果をさらに向上させることが可能となる。尚、本発明における「実質的に乳酸塩を含有しない」とは、「別途、乳酸塩を含有させることはしない」という意味であり、乳酸と各配合成分中に含まれる成分により形成される微量の乳酸塩までをも除外するものではない。 The anti-fading composition according to the present invention preferably contains substantially no lactate. Thereby, it becomes possible to further improve the fading prevention effect. In the present invention, “substantially does not contain lactate” means “not to contain lactate separately”, and is a trace amount formed by components contained in lactic acid and each component. It does not exclude even the lactate.
食品、化粧品、医薬品及び医薬部外品などの用途に応じて、（Ｃ）乳酸の配合量は適宜調整される。上記退色防止組成物１００質量％中、（Ｃ）乳酸の含有量は、好ましくは０．００１質量％以上、より好ましくは０．００５質量％以上、好ましくは２質量％以下、より好ましくは１質量％以下である。 The blending amount of (C) lactic acid is appropriately adjusted according to uses such as foods, cosmetics, pharmaceuticals, and quasi drugs. In 100% by mass of the anti-fading composition, the content of (C) lactic acid is preferably 0.001% by mass or more, more preferably 0.005% by mass or more, preferably 2% by mass or less, more preferably 1% by mass. % Or less.
（（Ｄ）酸性色素）
色素としては、酸性色素、塩基性色素及び天然色素等が存在する。これらの色素の中で、本発明に係る退色防止組成物は、（Ｄ）酸性色素を含む。（Ｄ）酸性色素は、１種のみが用いられてもよく、２種以上が併用されてもよい。
((D) acidic dye)
Examples of the dye include acidic dyes, basic dyes, and natural dyes. Among these pigments, the anti-fading composition according to the present invention includes (D) an acidic pigment. (D) Only 1 type may be used for an acidic pigment | dye and 2 or more types may be used together.
（Ｄ）酸性色素としては、アゾ系酸性色素、キサンテン系酸性色素、トリフェニルメタン系酸性色素、アントラキノン系酸性色素、ピラゾロン系酸性色素、フタロシアニン系酸性色素及びインジゴイド系酸性色素等が挙げられる。 Examples of the acid dye (D) include azo acid dyes, xanthene acid dyes, triphenylmethane acid dyes, anthraquinone acid dyes, pyrazolone acid dyes, phthalocyanine acid dyes, and indigoid acid dyes.
なかでも、本発明の上記組成の採用により、退色をより一層抑制可能であることから、（Ｄ）酸性色素は、アゾ系酸性色素、トリフェニルメタン系酸性色素又はアントラキノン系酸性色素であることが好ましい。また、アゾ系酸性色素、トリフェニルメタン系酸性色素及びアントラキノン系酸性色素は汎用性にも優れている。（Ｄ）酸性色素は、アゾ系酸性色素であることが好ましく、トリフェニルメタン系酸性色素であることが好ましく、アントラキノン系酸性色素であることも好ましい。 Among these, since the fading can be further suppressed by employing the above composition of the present invention, the (D) acidic dye may be an azo acid dye, a triphenylmethane acid dye, or an anthraquinone acid dye. preferable. Also, azo acid dyes, triphenylmethane acid dyes and anthraquinone acid dyes are excellent in versatility. (D) The acid dye is preferably an azo acid dye, preferably a triphenylmethane acid dye, and preferably an anthraquinone acid dye.
食品、化粧品、医薬品及び医薬部外品などの用途に応じて、（Ｄ）酸性色素の配合量は適宜調整される。上記退色防止組成物１００質量％中、（Ｄ）酸性色素の含有量は、好ましくは０．００００００１質量％以上、より好ましくは０．０００００１質量％以上、好ましくは０．１質量％以下、より好ましくは０．０１質量％以下である。（Ｄ）酸性色素の含有量が上記下限以上及び上記上限以下であると、退色防止効果がより一層効果的に得られる。 The amount of the (D) acidic pigment is appropriately adjusted according to the use such as food, cosmetics, pharmaceuticals and quasi drugs. In 100% by mass of the anti-fading composition, the content of the (D) acidic dye is preferably 0.0000001% by mass or more, more preferably 0.000001% by mass or more, preferably 0.1% by mass or less, more preferably. Is 0.01 mass% or less. (D) When the content of the acidic dye is not less than the above lower limit and not more than the above upper limit, the anti-fading effect can be obtained more effectively.
（（Ｅ）溶剤）
（Ａ）香料と（Ｂ）紫外線吸収剤と（Ｃ）乳酸と（Ｄ）酸性色素とを均一に混合するために、本発明に係る退色防止組成物は、（Ｅ）溶剤を含むことが好ましい。（Ｅ）溶剤は、１種のみが用いられてもよく、２種以上が併用されてもよい。
((E) solvent)
In order to uniformly mix (A) the fragrance, (B) the ultraviolet absorber, (C) lactic acid, and (D) the acidic dye, the anti-fading composition according to the present invention preferably includes (E) a solvent. . (E) As for a solvent, only 1 type may be used and 2 or more types may be used together.
（Ｅ）溶剤としては、水及びアルコールが挙げられる。上記アルコールとしては、メタノール、エタノール、プロパノール及びブタノール等が挙げられる。上記アルコールは、炭素数４以下のアルコールであることが好ましく、炭素数２以下のアルコ−ルであることがより好ましい。上記アルコールは、１種のみが用いられてもよく、２種以上が併用されてもよい。 (E) As a solvent, water and alcohol are mentioned. Examples of the alcohol include methanol, ethanol, propanol, and butanol. The alcohol is preferably an alcohol having 4 or less carbon atoms, and more preferably an alcohol having 2 or less carbon atoms. As for the said alcohol, only 1 type may be used and 2 or more types may be used together.
食品、化粧品、医薬品及び医薬部外品などの用途に応じて、更に（Ａ）香料と（Ｂ）紫外線吸収剤と（Ｃ）乳酸と（Ｄ）酸性色素との種類及び配合量に応じて、（Ｅ）溶剤の配合量は適宜調整される。上記退色防止組成物１００質量％中、（Ｅ）溶剤の含有量は好ましくは１質量％以上、より好ましくは１０質量％以上、好ましくは９９．９８７９９９質量％以下、より好ましくは９９質量％以下である。（Ｅ）溶剤の含有量が上記下限以上及び上記上限以下であると、配合成分の混合性がより一層高くなり、退色防止効果がより一層効果的に得られる。また、（Ｅ）溶剤を用いる場合に、上記退色防止組成物１００質量％中、（Ａ）香料と（Ｂ）紫外線吸収剤と（Ｃ）乳酸と（Ｄ）酸性色素との合計の含有量は、好ましくは０．０１２００１質量％以上、より好ましくは０．１質量％以上、好ましくは３０質量％以下、より好ましくは２５質量％以下である。 Depending on the use of food, cosmetics, pharmaceuticals and quasi-drugs, depending on the type and amount of (A) fragrance, (B) UV absorber, (C) lactic acid and (D) acidic pigment, (E) The compounding quantity of a solvent is adjusted suitably. In 100% by mass of the anti-fading composition, the content of the solvent (E) is preferably 1% by mass or more, more preferably 10% by mass or more, preferably 99.987999% by mass or less, more preferably 99% by mass or less. is there. (E) When the content of the solvent is not less than the above lower limit and not more than the above upper limit, the mixing properties of the blending components are further enhanced, and the anti-fading effect can be obtained more effectively. When (E) the solvent is used, the total content of (A) the fragrance, (B) the ultraviolet absorber, (C) lactic acid, and (D) the acidic dye in 100% by mass of the anti-fading composition is as follows: Preferably, it is 0.012001 mass% or more, More preferably, it is 0.1 mass% or more, Preferably it is 30 mass% or less, More preferably, it is 25 mass% or less.
（他の成分）
上記退色防止組成物には、可溶化剤、酸化防止剤、ｐＨ調整剤及び各種の抽出物を配合してもよい。また、これら以外の成分も必要に応じて、適宜配合可能である。上記退色防止組成物には、可溶化剤を含むことが好ましい。
(Other ingredients)
You may mix | blend a solubilizer, antioxidant, a pH adjuster, and various extracts with the said fading prevention composition. Moreover, components other than these can also be mix | blended suitably as needed. The fading prevention composition preferably contains a solubilizer.
（退色防止組成物の他の詳細）
上記退色防止組成物は、食品、化粧品、医薬品又は医薬部外品に好適に用いることができる。上記退色防止組成物は、食品、化粧品、医薬品及び医薬部外品などに用いられる適宜の有効成分と混合されて用いられてもよい。化粧料では、香料が用いられることが多い。また、化粧料では、退色は特に大きな問題になりやすい。また、化粧料は、美観を考慮して、透明又は半透明の容器内に充填されることがある。透明又は半透明の容器内に充填された化粧料は、日光の紫外線や蛍光灯の光線に晒される。従って、退色防止効果に優れている上記退色防止組成物は、化粧料により好適に用いることができる。
(Other details of anti-fading composition)
The anti-fading composition can be suitably used for foods, cosmetics, pharmaceuticals or quasi drugs. The anti-fading composition may be used by mixing with an appropriate active ingredient used for foods, cosmetics, pharmaceuticals, quasi drugs and the like. In cosmetics, fragrances are often used. In cosmetics, fading tends to be a particularly serious problem. Moreover, cosmetics may be filled in a transparent or translucent container in view of aesthetics. The cosmetic filled in a transparent or translucent container is exposed to sunlight ultraviolet rays or fluorescent light rays. Accordingly, the anti-fading composition having an excellent anti-fading effect can be suitably used for cosmetics.
上記退色防止組成物を含有する化粧料などは、（Ａ）香料と、（Ｂ）紫外線吸収剤と、（Ｃ）乳酸と、（Ｄ）酸性色素とを含有する。 Cosmetics containing the anti-fading composition contain (A) a fragrance, (B) an ultraviolet absorber, (C) lactic acid, and (D) an acidic dye.
上記退色防止組成物を含有する化粧料の性状としては、液状、ジェル状、クリーム状及び泡状等が挙げられる。液状には、ペースト状が含まれる。液状であっても退色防止効果が十分に得られることから、上記化粧料は、液状であることが好ましい。 Examples of the properties of the cosmetic containing the anti-fading composition include liquid, gel, cream and foam. The liquid form includes a paste. Since the anti-fading effect can be sufficiently obtained even when it is liquid, the cosmetic is preferably liquid.
（化粧品）
本発明に係る化粧品は、容器と、該容器内に充填されている化粧料とを備える。該化粧料が、上記退色防止組成物を含有する。すなわち、上記化粧料は、（Ａ）香料と、（Ｂ）紫外線吸収剤と、（Ｃ）乳酸と、（Ｄ）酸性色素とを含む。上記容器は、透明又は半透明の容器であってもよい。半透明の容器では、該容器を介して、容器内の物質を視認可能である。上記容器は、ガラス容器であってもよい。
(Cosmetics)
The cosmetic according to the present invention includes a container and a cosmetic filled in the container. The cosmetic contains the anti-fading composition. That is, the cosmetic contains (A) a fragrance, (B) an ultraviolet absorber, (C) lactic acid, and (D) an acidic pigment. The container may be a transparent or translucent container. In a translucent container, the substance in the container can be visually recognized through the container. The container may be a glass container.
以下、本発明を実施例に基づいて更に詳細に説明する。本発明は以下の実施例にのみ限定されない。なお、配合量の単位は、特記しない限り「質量部」である。 Hereinafter, the present invention will be described in more detail based on examples. The present invention is not limited only to the following examples. The unit of the blending amount is “part by mass” unless otherwise specified.
実施例及び比較例では、下記の成分を用いた。 In the examples and comparative examples, the following components were used.
（Ａ）香料
１）シトラス系香料
２）フルーティ系香料
３）フゼア系香料
(A) Fragrance 1) Citrus flavor 2) Fruity flavor 3) Fuze flavor
（Ｂ）紫外線吸収剤
１）紫外線吸収剤１（ＤＳＭ ニュートリションジャパン社製「ｐａｒｓｏｌ１７８９」）
２）紫外線吸収剤２（ＢＡＳＦ社製「ＵＶＩＮＵＬ Ｄ−５０」）
(B) Ultraviolet absorber 1) Ultraviolet absorber 1 ("Parsol 1789" manufactured by DSM Nutrition Japan)
2) UV absorber 2 ("UVINUL D-50" manufactured by BASF)
（Ｃ）乳酸
１）乳酸
(C) Lactic acid 1) Lactic acid
（Ｄ）酸性色素
１）赤２（アゾ系酸性色素）含有液（酸性色素０．０１質量％と精製水を９９．９９質量％とを含む）
２）赤１０２（アゾ系酸性色素）含有液（酸性色素０．０１質量％と精製水を９９．９９質量％とを含む）
３）赤２０１（アゾ系酸性色素）含有液（酸性色素０．０１質量％と精製水を９９．９９質量％とを含む）
４）赤２２７（アゾ系酸性色素）含有液（酸性色素０．０１質量％と精製水を９９．９９質量％とを含む）
５）赤５０４（アゾ系酸性色素）含有液（酸性色素０．０１質量％と精製水を９９．９９質量％とを含む）
６）青１（トリフェニルメタン系酸性色素）含有液（酸性色素０．０１質量％と精製水を９９．９９質量％とを含む）
７）黄５（アゾ系酸性色素）含有液（酸性色素０．０１質量％と精製水を９９．９９質量％とを含む）
８）紫４０１（アントラキノン系酸性色素）含有液（酸性色素０．０１質量％と精製水を９９．９９質量％とを含む）
(D) Acid dye 1) Red 2 (azo acid dye) -containing liquid (including 0.01% by weight of acid dye and 99.99% by weight of purified water)
2) Red 102 (azo acid dye) -containing liquid (containing 0.01% by weight of acid dye and 99.99% by weight of purified water)
3) Red 201 (azo acid dye) -containing liquid (containing 0.01% by weight of acid dye and 99.99% by weight of purified water)
4) Red 227 (azo acid dye) -containing liquid (containing 0.01% by weight of acid dye and 99.99% by weight of purified water)
5) Red 504 (azo acid dye) -containing liquid (containing 0.01% by weight of acid dye and 99.99% by weight of purified water)
6) Blue 1 (triphenylmethane acid dye) -containing liquid (containing 0.01% by weight of acid dye and 99.99% by weight of purified water)
7) Yellow 5 (azo acid dye) -containing liquid (containing 0.01% by weight of acid dye and 99.99% by weight of purified water)
8) Purple 401 (anthraquinone acid dye) -containing liquid (containing 0.01% by weight of acid dye and 99.99% by weight of purified water)
（Ｅ）溶剤
１）９５質量％エタノール
２）精製水
(E) Solvent 1) 95% by mass ethanol 2) Purified water
（他の成分）
可溶化剤（日光ケミカルズ社製「ＮＩＫＫＯＬ ＰＥＮ−４６３０」）
(Other ingredients)
Solubilizer ("NIKKOL PEN-4630" manufactured by Nikko Chemicals)
（実施例１〜１８、参考例１〜３６及び比較例１〜２７） (Examples 1-18, Reference Examples 1-36 and Comparative Examples 1-27)
下記の表１〜６に示す各成分を下記の表１〜６に示す含有量で配合し、混合し、退色防止組成物を得た。なお、香料を用いていない退色防止組成物は、参考例とした。 The components shown in Tables 1 to 6 below were blended in the amounts shown in Tables 1 to 6 and mixed to obtain a fading prevention composition. In addition, the fading prevention composition which does not use the fragrance | flavor was made into the reference example.
（退色防止性の評価）
得られた退色防止組成物に波長３００〜７００ｎｍの紫外線及び可視光を３０時間照射した。紫外線、可視光を照射していない退色防止組成物と、紫外線及び可視光を照射した退色防止組成物との色調及び色の濃淡を目視で確認した。退色防止性を下記の基準で判定した。
(Evaluation of anti-fading property)
The obtained anti-fading composition was irradiated with ultraviolet rays and visible light having a wavelength of 300 to 700 nm for 30 hours. The color tone and color shade of the anti-fading composition not irradiated with ultraviolet light and visible light and the anti-fading composition irradiated with ultraviolet light and visible light were visually confirmed. The anti-fading property was determined according to the following criteria.
［退色防止性の判定基準］
Ａ：隣接比較で色の差異を識別できない
Ｂ：隣接比較で色の差異を識別できるが、離間比較では色の差異を識別できない
Ｃ：隣接比較及び離間比較において色の差異を識別できるが、紫外線の照射後に色調に変化はなく色の濃さに大きな差異はない
Ｄ：隣接比較及び離間比較において色の差異を識別でき、紫外線の照射後に色調が変化している
Ｅ：隣接比較及び離間比較において色の差異を識別でき、紫外線の照射後に無色又はほぼ無色になっている
Ｆ：退色防止組成物の調整直後（紫外線及び可視光の照射前）に無色になっている
[Judgment criteria for anti-fading properties]
A: Color difference cannot be identified by adjacent comparison B: Color difference can be identified by adjacent comparison, but color difference cannot be identified by separation comparison C: Color difference can be identified by adjacent comparison and separation comparison, but ultraviolet rays No change in color tone and no significant difference in color density after irradiation of D. Color difference can be identified in adjacent comparison and separation comparison, and color change after irradiation of ultraviolet light E: In adjacent comparison and separation comparison Color difference can be identified, and it is colorless or almost colorless after UV irradiation. F: Colorless immediately after the preparation of the anti-fading composition (before UV and visible light irradiation)
組成及び評価結果を下記の表１〜６に示す。 The compositions and evaluation results are shown in Tables 1 to 6 below.
実施例１と比較例１〜３との対比、実施例２と比較例４〜６との対比、実施例３と比較例７〜９との対比、実施例４と比較例１０〜１２との対比、実施例５と比較例１３〜１５との対比、実施例６と比較例１６〜１８との対比、実施例７と比較例１９〜２１との対比、実施例８と比較例２２〜２４との対比、実施例９と比較例２５〜２７との対比により、（Ａ）香料を含む組成において、（Ｄ）酸性色素としてある特定の酸性色素を用いる場合に、特定の酸性色素とともに（Ｂ），（Ｃ）成分を組み合わせることにより、特定の酸性色素とともに（Ｂ），（Ｃ）成分を組み合わせていない場合と比べて、退色を抑えることができることがわかる。 Comparison between Example 1 and Comparative Examples 1 to 3, Comparison between Example 2 and Comparative Examples 4 to 6, Comparison between Example 3 and Comparative Examples 7 to 9, Comparison between Example 4 and Comparative Examples 10 to 12 Comparison, comparison between Example 5 and Comparative Examples 13-15, comparison between Example 6 and Comparative Examples 16-18, comparison between Example 7 and Comparative Examples 19-21, Example 8 and Comparative Examples 22-24 In comparison with Example 9 and Comparative Examples 25 to 27, in the composition containing (A) the fragrance, (D) when a specific acidic dye is used as the acidic dye, together with the specific acidic dye (B It can be seen that by combining the components (C) and (C), fading can be suppressed as compared with the case where the components (B) and (C) are not combined with a specific acidic dye.
Claims (4)
乳酸塩を実質的に含まず、
前記酸性色素が、アゾ系酸性色素、トリフェニルメタン系酸性色素又はアントラキノン系酸性色素である、退色が防止された組成物。 And perfume, and an ultraviolet absorber, and lactic acid, an acidic dye seen including,
Substantially free of lactate,
A composition in which fading is prevented, wherein the acidic dye is an azo acid dye, a triphenylmethane acid dye or an anthraquinone acid dye .
前記化粧料が、請求項１〜３のいずれか１項に記載の退色が防止された組成物を含有する、化粧品。 A container, and a cosmetic filled in the container,
It said cosmetic contains a composition discoloration is prevented according to any one of claims 1 to 3 cosmetics.
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