JP5911549B1 - Taste improving agent for high-intensity sweeteners using salamander extract - Google Patents
Taste improving agent for high-intensity sweeteners using salamander extract Download PDFInfo
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- JP5911549B1 JP5911549B1 JP2014217986A JP2014217986A JP5911549B1 JP 5911549 B1 JP5911549 B1 JP 5911549B1 JP 2014217986 A JP2014217986 A JP 2014217986A JP 2014217986 A JP2014217986 A JP 2014217986A JP 5911549 B1 JP5911549 B1 JP 5911549B1
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- JP
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- Prior art keywords
- salamander
- supercritical fluid
- taste
- intensity sweetener
- improving agent
- Prior art date
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- 239000000284 extract Substances 0.000 title claims abstract description 45
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- 229960001367 tartaric acid Drugs 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
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- Proteomics, Peptides & Aminoacids (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Chemical & Material Sciences (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
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- General Preparation And Processing Of Foods (AREA)
- Confectionery (AREA)
- Medicinal Preparation (AREA)
Abstract
【課題】 高甘味度甘味料特有の不快な後味や呈味を、ごく少量の添加量で効果的に抑制する高甘味度甘味料の呈味改善剤を提供することである。【解決手段】 サンショウを超臨界流体で抽出して得られる抽出物を有効成分とする高甘味度甘味料の呈味改善剤である。【選択図】 なしPROBLEM TO BE SOLVED: To provide a taste improving agent for a high sweetness sweetener that effectively suppresses an unpleasant aftertaste and taste peculiar to a high sweetness sweetener with a very small addition amount. SOLUTION: This is a taste improving agent for high-intensity sweeteners containing as an active ingredient an extract obtained by extracting a salamander with a supercritical fluid. [Selection figure] None
Description
本発明は、高甘味度甘味料の呈味改善剤に関するものである。詳しくは、高甘味度甘味料の不快な後味を改善する、すなわち不快な甘味の後残りを減少させる呈味改善剤に関するものである。 The present invention relates to a taste improving agent for high-intensity sweeteners. Specifically, the present invention relates to a taste improver that improves the unpleasant aftertaste of a high-intensity sweetener, that is, reduces the remaining after-unpleasant sweetness.
近年の健康指向の高まりやダイエットに対する関心からアスパルテーム、ステビア、アセスルファムK、スクラロース、ネオテームなどの低カロリーの高甘味度甘味料を使用した飲食品や口腔衛生品が増加している。
このような高甘味度甘味料は、ショ糖の数十倍から数千倍の甘味度を有するという優れた性能を持つ反面、飲食時に不快な苦味、エグ味及び収斂味を与える他、甘味が長く持続するため味の切れが悪く、結果として呈味の質がショ糖に比して劣り、消費者に不快な甘味感を与えるという欠点を有している。
そのため、低カロリーとして有用な高甘味度甘味料を各種飲食物に幅広く適用するに際しては、そうした呈味の改善が最大の課題となっている。
特に、甘味が長く持続する甘味の後引き、後残りの問題は、苦味やエグ味よりも解決が困難であり、以下に例示するように、種々の技術が提案されて来たが、いずれも十分な改善効果をもたらすものではなかった。
Due to the recent increase in health orientation and interest in dieting, foods and oral hygiene products using low-calorie high-intensity sweeteners such as aspartame, stevia, acesulfame K, sucralose and neotame are increasing.
Such a high-intensity sweetener has an excellent performance of having a sweetness several tens to several thousand times that of sucrose, but gives an unpleasant bitter taste, a delicious taste and an astringent taste when eating and drinking. Since it lasts for a long time, the taste is poor, and as a result, the taste quality is inferior to that of sucrose, which gives consumers an unpleasant sweet taste.
Therefore, when a high-intensity sweetener useful as a low calorie is widely applied to various foods and drinks, the improvement of such taste is the biggest issue.
In particular, after-sweetness and long-lasting sweetness is difficult to solve than bitterness and egg taste, and various techniques have been proposed as exemplified below. It did not bring about a sufficient improvement effect.
高甘味度甘味料の甘味の残存性の難点を解消するため、グルコン酸もしくはリンゴ酸等の有機酸やその塩を使用する方法(特許文献1)、高甘味度甘味料とルチン、ヘスペリジン等の天然物を組み合わせる方法(特許文献2、3)、ガラクトマンナン分解物、ビートオリゴ糖等の糖類を高甘味度甘味料の味質改善に用いる方法(特許文献4、5)、さとうきび由来のバガス抽出物や酵素処理イチョウ葉エキス等の植物由来の抽出物を高甘味度甘味料に配合する方法(特許文献6、7)、キナ酸を甘味改善剤として用いる方法(特許文献8)、溶媒抽出したサンショウ抽出物等の感覚刺激物質とキナ酸とバニラポリフェノールの三成分を組み合わせた呈味改善剤 (特許文献9)など各種方法が提案されている。
しかしながら、このような既存の方法では、高甘味度甘味料の不快な後味を低減させるために、改善剤を多量に添加する必要があり、その結果、改善剤に起因する味や香りが、かえって飲食品本来の香味を損なうことになり、それを防止するため別の添加剤が必要になるといった問題点を有していた。
しかしながら、昨今の食の安全の風潮に鑑みれば、食品用添加剤の量や数を安易に増加することは一般消費者にとっては決して好ましいことではない。
In order to eliminate the difficulty of remaining sweetness of high-intensity sweeteners, a method using an organic acid such as gluconic acid or malic acid or a salt thereof (Patent Document 1), a high-intensity sweetener and rutin, hesperidin, etc. Method of combining natural products (Patent Documents 2 and 3), Method of using saccharides such as galactomannan degradation products and beet oligosaccharides to improve the quality of high-intensity sweeteners (Patent Documents 4 and 5), bagasse extraction from sugarcane Or plant-derived extracts such as enzyme-treated ginkgo biloba extract (Patent Documents 6 and 7), a method using quinic acid as a sweetness improving agent (Patent Document 8), solvent extraction Various methods such as a taste improving agent (Patent Document 9) combining a sensory stimulant such as a salamander extract and three components of quinic acid and vanilla polyphenol have been proposed.
However, in such an existing method, in order to reduce the unpleasant aftertaste of the high-intensity sweetener, it is necessary to add a large amount of an improving agent, and as a result, the taste and aroma caused by the improving agent are rather reduced. The original flavor of food and drink was impaired, and another additive was required to prevent it.
However, in view of the recent trend of food safety, it is not preferable for general consumers to easily increase the amount and number of food additives.
本発明は上記事情に鑑みてなされたものであり、飲食品又は口腔衛生製品の本来の風味を変えることなく、高甘味度甘味料特有の不快な後味や呈味を1種類の添加剤によって、ごく少量の添加量で効果的に抑制する高甘味度甘味料の呈味改善剤を提供することを課題とする。 The present invention has been made in view of the above circumstances, without changing the original flavor of food and drink or oral hygiene products, the unpleasant aftertaste and taste peculiar to high-intensity sweeteners, with a single additive, It is an object of the present invention to provide a taste improving agent for high-intensity sweeteners that can be effectively suppressed with a very small amount of addition.
本発明者らは上記課題を解決すべく鋭意研究を重ねた結果、サンショウを超臨界流体で抽出して得られる抽出物が、高甘味度甘味料の不快な後味や呈味を少ない添加量で効果的に抑制できることを見出し、本発明の完成に至った。 As a result of intensive studies to solve the above-mentioned problems, the present inventors have found that an extract obtained by extracting salamander with a supercritical fluid has a small amount of unpleasant aftertaste and taste of high-intensity sweeteners. Thus, the present invention has been completed.
すなわち、本発明の要旨は以下のとおりである。
(1)サンショウを超臨界流体で抽出して得られる抽出物を有効成分とする高甘味度甘味料の呈味改善剤。
(2)超臨界流体が、圧力7.4〜60MPa、温度20〜100℃の領域における超臨界状態二酸化炭素であり、超臨界流体の使用量がサンショウの1〜20倍容量であり、抽出時間が1〜6時間である上記の呈味改善剤。
(3)超臨界流体抽出時に、濃度が5〜99.5(w/w)%のエタノール水溶液をサンショウの0.05〜2倍容量で共存させる上記の呈味改善剤。
(4)サンショウが、サンショウの乾燥した実である上記の呈味改善剤。
(5)高甘味度甘味料が、アスパルテーム、ステビア、スクラロース、アセスルファムK又はネオテームである上記の呈味改善剤。
(6)サンショウを超臨界流体で抽出して得られる抽出物を含む高甘味度甘味料の呈味改善用の香料組成物。
(7)香料組成物100質量部に対して、サンショウの超臨界流体抽出物が0.0005〜10質量部含まれる上記の香料組成物。
That is, the gist of the present invention is as follows.
(1) A taste improver for a high-intensity sweetener comprising an extract obtained by extracting salamander with a supercritical fluid as an active ingredient.
(2) The supercritical fluid is supercritical carbon dioxide in the region of pressure 7.4-60 MPa and temperature 20-100 ° C., and the amount of supercritical fluid used is 1-20 times the volume of salamander, extraction Said taste improving agent whose time is 1 to 6 hours.
(3) The taste improver described above, wherein an aqueous ethanol solution having a concentration of 5 to 99.5 (w / w)% coexists in a volume of 0.05 to 2 times that of a salamander during supercritical fluid extraction.
(4) The taste improver according to the above, wherein the salamander is dried fruit of salamander.
(5) The said taste improving agent whose high sweetness degree sweetener is aspartame, stevia, sucralose, acesulfame K, or neotame.
(6) A fragrance composition for improving the taste of a high-intensity sweetener comprising an extract obtained by extracting salamander with a supercritical fluid.
(7) The fragrance composition as described above, wherein 0.0005 to 10 parts by mass of a supercritical fluid extract of salam is included with respect to 100 parts by mass of the fragrance composition.
(8)高甘味度甘味料100質量部に対して、サンショウの超臨界流体抽出物を0.001〜10質量部添加する、高甘味度甘味料の呈味改善方法。
(9)呈味改善が、高甘味度甘味料を飲食した後の不快な甘味の後残りを減少させることである上記の呈味改善方法。
(10)高甘味度甘味料と、前記呈味改善剤とを含有する高甘味度甘味料含有組成物。
(11)高甘味度甘味料と、上記の香料組成物とを含有する高甘味度甘味料含有組成物。(12)高甘味度甘味料が、アスパルテーム、ステビア、スクラロース、アセスルファムK及びネオテームからなる群より選ばれる1種又は2種以上である上記の高甘味度甘味料含有組成物。
(13)上記の呈味改善剤、上記の香料組成物または上記の高甘味度甘味料含有組成物を含有する飲食品又は口腔衛生製品。
(8) A method for improving the taste of high-intensity sweeteners, wherein 0.001 to 10 parts by mass of a supercritical fluid extract of salamander is added to 100 parts by mass of high-intensity sweeteners.
(9) The method for improving taste according to the above, wherein the taste improvement is to reduce the remaining after unpleasant sweetness after eating or drinking a high-intensity sweetener.
(10) A high-intensity sweetener-containing composition comprising a high-intensity sweetener and the taste improver.
(11) A high-intensity sweetener-containing composition comprising a high-intensity sweetener and the above-described flavor composition. (12) The high-intensity sweetener-containing composition described above, wherein the high-intensity sweetener is one or more selected from the group consisting of aspartame, stevia, sucralose, acesulfame K and neotame.
(13) Food / beverage products or oral hygiene products containing the taste improver, the fragrance composition, or the high-sweetness sweetener-containing composition.
本発明の高甘味度甘味料の呈味改善剤は、高甘味度甘味料に特有の不快な後味や呈味をごく少量の添加量で効果的に抑制することができるので、呈味改善剤が飲食品又は口腔衛生製品の本来の風味を変えることがない。
従って、適用の範囲が拡大し、それはこれまで味覚の点で適用範囲に限界があった高甘味度甘味料の適用対象の拡大をもたらす点で大きな意義を有する。
また、本発明の呈味改善剤は、古来より食用に供されているサンショウを原料とする点、抽出溶媒が残存しない超臨界流体(特に二酸化炭素は無味、無臭、無害)である点で安全性にも優れる。
The taste improving agent for high-intensity sweeteners of the present invention can effectively suppress unpleasant aftertaste and taste unique to high-intensity sweeteners with a very small addition amount. Does not change the original flavor of food or drink products or oral hygiene products.
Therefore, the range of application is expanded, which has a great significance in that the application range of high-intensity sweeteners, which has been limited in the range of application in terms of taste, has been expanded.
In addition, the taste improver of the present invention is based on a salamander that has been used for food since ancient times, and is a supercritical fluid in which no extraction solvent remains (particularly carbon dioxide is tasteless, odorless, harmless). Excellent safety.
〔1〕呈味改善剤
(1)呈味改善剤の原料
本発明に係る呈味改善剤は上述したように、呈味改善の有効成分として、サンショウの超臨界流体による抽出物を含有する。
サンショウ(山椒;Japanese pepper;学名Zanthoxylum piperitum)は、ミカン科サンショウ属に属する落葉低木で、数種の品種がある。本発明に用いるサンショウには特に品種の限定はない。
サンショウの若芽や葉は、日本料理や香辛料に用いられ、乾燥した実は辛味香辛料や生薬(健胃や駆虫)として用いられる。本発明では、サンショウの植物体のうちいずれの部分であっても原料として使用可能であるが、特に乾燥した実が抽出効率に優れる点で好ましい。
[1] Taste improving agent (1) Raw material for taste improving agent As described above, the taste improving agent according to the present invention contains an extract of a salmon supercritical fluid as an active ingredient for improving taste. .
Salamander (Japanese pepper; scientific name Zanthoxylum piperitum) is a deciduous shrub belonging to the genus Salamander and has several varieties. There is no particular limitation on the variety of salamanders used in the present invention.
Salamander shoots and leaves are used in Japanese cuisine and spices, and dried fruits are used as spicy spices and herbal medicines (healthy stomach and anthelmintic). In the present invention, any portion of the plant body of the salamander can be used as a raw material, but in particular, dried fruit is preferable in terms of excellent extraction efficiency.
(2)呈味改善剤の製造方法、剤形等
本発明の呈味改善剤は、サンショウを超臨界流体を用いて抽出することによって得ることができる。
超臨界流体による抽出とは、加圧下に液状となったガス、亜臨界ないし超臨界状態での流体による抽出を意味するものであるが、好ましい形態として液状二酸化炭素による抽出、亜臨界ないし超臨界状態の二酸化炭素による抽出が挙げられ、超臨界状態二酸化炭素による抽出が特に好ましい。
(2) Production method, dosage form, etc. of taste improver The taste improver of the present invention can be obtained by extracting salamander using a supercritical fluid.
Extraction with a supercritical fluid means extraction with a gas in a liquid state under pressure, a fluid in a subcritical or supercritical state, but as a preferred form, extraction with liquid carbon dioxide, subcritical or supercritical Extraction with carbon dioxide in the state can be mentioned, and extraction with supercritical carbon dioxide is particularly preferred.
より具体的に言えば、超臨界流体は、好ましくは圧力7.4〜60MPa、特に好ましくは8〜20.5MPaであり、温度20〜100℃、特に好ましくは30〜80℃の領域における超臨界状態二酸化炭素である。
また、超臨界流体の使用量は、サンショウ植物体、特に乾燥したサンショウの実の1〜20倍容量、特に1〜15倍容量が好ましい。また、抽出時間は、1〜6時間、特に1.5〜3時間が好ましい。
さらに、抽出効率を上げるため、上記超臨界流体抽出の際にエントレーナー(助溶媒)を共存させることが好ましい。そうしたエントレーナーとしては、エタノール水溶液が食品に使用できる観点から好適である。そのエタノール濃度は5〜99.5(w/w)%、好ましくは30〜70(w/w)%である。また、エントレーナーの使用量は原料のサンショウ植物体、特に乾燥したサンショウの実の0.05〜2倍、好ましくは0.5〜1.5倍量である。
More specifically, the supercritical fluid preferably has a pressure of 7.4 to 60 MPa, particularly preferably 8 to 20.5 MPa, and a supercritical temperature in the range of 20 to 100 ° C., particularly preferably 30 to 80 ° C. State carbon dioxide.
Moreover, the usage-amount of a supercritical fluid has a 1-20 times capacity | capacitance, especially 1-15 times the capacity | capacitance of a salamander plant body, especially the dried salamander's fruit. The extraction time is preferably 1 to 6 hours, particularly preferably 1.5 to 3 hours.
Furthermore, in order to increase the extraction efficiency, it is preferable that an entrainer (cosolvent) coexists in the supercritical fluid extraction. As such an entrainer, an ethanol aqueous solution is preferable from the viewpoint that it can be used for food. The ethanol concentration is 5 to 99.5 (w / w)%, preferably 30 to 70 (w / w)%. Further, the amount of the entrainer used is 0.05 to 2 times, preferably 0.5 to 1.5 times the amount of the raw salamander plant body, especially the dried salamander.
抽出後、粗抽出液を固液分離して得られる抽出原液をそのまま呈味改善剤として使用することも可能であるが、必要に応じてさらにろ過等の精製を行って不純物を除去することもできる。
また、本発明の超臨界流体サンショウ抽出物の成分濃度を低くしたい場合は、抽出原液を溶剤で希釈した形態の液剤としてもよい。その場合の溶剤としては、例えば、エタノール、グリセリン、プロピレングリコール、トリアセチン、中鎖脂肪酸トリグリセリド、ベンジルアルコール等が挙げられる。
After extraction, it is possible to use the extracted stock solution obtained by solid-liquid separation of the crude extract as it is as a taste improver, but it is also possible to remove impurities by further purification such as filtration if necessary. it can.
In addition, when it is desired to reduce the component concentration of the supercritical fluid salamander extract of the present invention, the extraction stock solution may be diluted with a solvent. Examples of the solvent in this case include ethanol, glycerin, propylene glycol, triacetin, medium chain fatty acid triglyceride, benzyl alcohol and the like.
上述のサンショウ抽出物が単独で存在する液剤形態の呈味改善剤は、本発明の好適な形態の一例ではあるが、これに限定されるものではなく、本発明の趣旨を逸脱しない範囲において、付加的成分を添加する、あるいは他の有効成分と組み合わせて合剤にする等、種々変形して実施可能である。
例えば、公知の各種天然香料や合成香料と組み合わせて香料組成物にすることが例示される。
また、酸化防止剤(ビタミンC、ビタミンEなど)や糖類、甘味料、冷感剤、乳化増粘安定剤、pH調整剤と組み合わせた組成物として使用することもできる。
さらに、本呈味改善剤は、液剤以外の剤形、例えば凍結乾燥または加熱乾燥などの処理を行って固形剤として使用することも可能である。さらに、賦形剤(デキストリン等)を
添加し噴霧乾燥により粉末状あるいは顆粒状、さらには錠剤にすることも可能であり、用途に応じて種々の剤形を採用することができる。
The above-described taste improving agent in liquid form in which the salamander extract is present alone is an example of a preferred form of the present invention, but is not limited thereto, and does not depart from the spirit of the present invention. It can be carried out with various modifications such as adding an additional component or combining it with other active ingredients.
For example, it is exemplified that a fragrance composition is combined with various known natural fragrances and synthetic fragrances.
Moreover, it can also be used as a composition combined with antioxidants (vitamin C, vitamin E, etc.), saccharides, sweeteners, cooling agents, emulsion thickening stabilizers, and pH adjusters.
Furthermore, the present taste improving agent can be used as a solid agent after treatment with a dosage form other than a liquid, for example, freeze drying or heat drying. Furthermore, an excipient (such as dextrin) can be added to form a powder, granules, or a tablet by spray drying, and various dosage forms can be employed depending on the application.
香料組成物にする場合に組み合わせる香料成分としては、例えば、アセトフェノン、ベンズアルデヒド、フェニルアセトアルデヒド、シンナムアルデヒド、アニスアルデヒド、イオノン、イソ吉草酸イソアミル、イソ吉草酸エチル、アセト酢酸エチル、レブリン酸エチル、ピルビン酸エチル、インドール、ノナラクトン、デカラクトン、ウンデカラクトン、ドデカラクトン、エチルバニリン、マルトール、エチルマルトール、フラネオール、ソトロン、ピネン、リモネン、ミルセン、テルピノレン、リナロール、ゲラニオール、シトロネロール、メントール、シネオール、メントフラン、リモネンオキサイド、ピネンオキサイド、リナロールオキサイド、シトラール、メントン、カルボン、プレゴン、ピペリトン、酢酸リナリル、酢酸メンチル、酢酸テルピニル等の香料ケミカル;柑橘等のフルーツ系精油;アップル、パイナップル、グレープ等の回収フレーバー;ミルク、バター、チーズ、ヨーグルト等の乳系香料;アニス、ウイキョウ、オールスパイス、カモミール、ペパーミントテイル、カルダモン、カンゾウ、クミン、クローブ、キャラウェイ、コリアンダー、セイボリー、サルビア、シソ、シナモン、ジンジャー、セロリー、スペアミント、タイム、タラゴン、ディル、ニガヨモギ、ニンジン、バジル、ヒソップ、ラベンダー、レモングラス、ローズマリー、ローレル等の香辛料の精油または抽出物等が挙げられる。 Examples of the fragrance component to be combined in the case of a fragrance composition include acetophenone, benzaldehyde, phenylacetaldehyde, cinnamaldehyde, anisaldehyde, ionone, isoamyl isovalerate, ethyl isovalerate, ethyl acetoacetate, ethyl levulinate, pyruvate Ethyl, indole, nonalactone, decalactone, undecalactone, dodecalactone, ethyl vanillin, maltol, ethyl maltol, furaneol, sotron, pinene, limonene, myrcene, terpinolene, linalool, geraniol, citronellol, menthol, cineol, mentfuran, limonene oxide , Pinene oxide, linalool oxide, citral, menthone, carvone, pregon, piperitone, linalyl acetate, menth acetate Perfume chemicals such as terpinyl acetate; Fruit-based essential oils such as citrus; Recovered flavors such as apple, pineapple and grape; Milk-based flavors such as milk, butter, cheese and yogurt; Anise, fennel, allspice, chamomile, peppermint tail, Cardamom, daylily, cumin, clove, caraway, coriander, savory, salvia, perilla, cinnamon, ginger, celery, spearmint, thyme, tarragon, dill, sagebrush, carrot, basil, hyssop, lavender, lemongrass, rosemary, laurel Examples include spice essential oils or extracts.
香料成分を含有する香料組成物中のサンショウ超臨界流体抽出物の配合量としては、香料組成物100質量部に対してサンショウ超臨界流体抽出物の質量は0.0005〜10質量部が好ましく、0.001〜4質量部が特に好ましく、最も好ましくは0.003〜3.0質量部(香料組成物中に30〜30,000ppm)である。
香料組成物には、サンショウ超臨界流体抽出物がごく僅かの量しか含まれていないため、香料組成物中の香料成分の香気に悪影響を及ぼさないことも本発明の利点である。
As a compounding quantity of the salamander supercritical fluid extract in the fragrance composition containing the fragrance component, the mass of the salamander supercritical fluid extract is 0.0005 to 10 parts by mass with respect to 100 parts by mass of the fragrance composition. The amount is preferably 0.001 to 4 parts by mass, and most preferably 0.003 to 3.0 parts by mass (30 to 30,000 ppm in the fragrance composition).
It is also an advantage of the present invention that the perfume composition contains only a slight amount of salamander supercritical fluid extract and therefore does not adversely affect the aroma of the perfume ingredients in the perfume composition.
呈味改善剤組成物を調製する際に使用できる乳化増粘安定剤としては、例えば寒天、アルギン酸、カラギーナン、グアーガム、ペクチン、キサンタンガム、ジェランガムなどが挙げられる。また、pH調整剤としては、例えば塩酸、水酸化ナトリウム、クエン酸、クエン酸ナトリウム、リンゴ酸、リンゴ酸ナトリウム、乳酸、乳酸ナトリウム、酒石酸、酒石酸ナトリウムなどが挙げられる。 Examples of the emulsion thickening stabilizer that can be used in preparing the taste improver composition include agar, alginic acid, carrageenan, guar gum, pectin, xanthan gum, and gellan gum. Examples of the pH adjuster include hydrochloric acid, sodium hydroxide, citric acid, sodium citrate, malic acid, sodium malate, lactic acid, sodium lactate, tartaric acid, and sodium tartrate.
〔2〕高甘味度甘味料
本発明の呈味改善剤が改善対象とする高甘味度甘味料は、ショ糖の数百倍から数千倍の高い甘味を有する天然物由来又は合成の甘味料をいい、ステビア(Stevia)、甘草抽出物、ソーマチン(Thaumatin)、グリチルリチン、グリチルリチン酸2ナトリウム、グリチルリチン酸アンモニウム、サッカリン、サッカリンナトリウム、アスパルテーム、アセスルファムK(Acesulfame K)、スクラロース(Sucralose)、アリテーム(Alitame)、ネオテーム(Neotame)等を例示することができる。
本発明の呈味改善剤は、高甘味度甘味料の種類には制限されずに使用できるが、特にアスパルテーム、ステビア、スクラロース、アセスルファムK、ネオテームの呈味改善に使用することが自然な甘味質を表現できる点で好ましい。
[2] High-intensity sweetener The high-intensity sweetener targeted by the taste improver of the present invention is derived from a natural product having a high sweetness several hundred to several thousand times that of sucrose, or a synthetic sweetener. Stevia, licorice extract, thaumatin, glycyrrhizin, disodium glycyrrhizinate, ammonium glycyrrhizinate, saccharin, sodium saccharine, aspartame, acesulfame K, sucralose, Alitame Neotame etc. can be illustrated.
The taste-improving agent of the present invention can be used without being limited to the kind of high-intensity sweetener, but it is a natural sweetness that is particularly useful for improving the taste of aspartame, stevia, sucralose, acesulfame K, neotame. Is preferable in that it can be expressed.
本発明の呈味改善剤は、高甘味度甘味料に少量添加することにより、高甘味度甘味料に特有の不快な後味や呈味が効果的に抑制された高甘味度甘味料含有組成物として供することができる。
高甘味度甘味料含有組成物とする場合は、高甘味度甘味料および本発明の呈味改善剤の他、各種糖類、有機酸、澱粉、デキストリンなど、通常使用される分散剤、賦形剤などを適宜含むことができる。
本発明の呈味改善剤を高甘味度甘味料に添加する場合は、高甘味度甘味料100質量部に対し、サンショウ超臨界抽出物0.001〜10質量部が通常であり、0.005〜5質量部が好ましく、より望ましくは0.023〜2.3質量部である。
The taste-improving agent of the present invention is a high-intensity sweetener-containing composition in which an unpleasant aftertaste and taste unique to a high-intensity sweetener are effectively suppressed by adding a small amount to the high-intensity sweetener. Can serve as.
When a high-sweetness sweetener-containing composition is used, in addition to the high-sweetness sweetener and the taste improver of the present invention, various commonly used dispersants and excipients such as various sugars, organic acids, starches, and dextrins Etc. can be included as appropriate.
When the taste improver of the present invention is added to a high-intensity sweetener, 100 to 10 parts by mass of the high-intensity sweetener is usually 0.001 to 10 parts by mass of a salmon supercritical extract. 005 to 5 parts by mass is preferable, and more desirably 0.023 to 2.3 parts by mass.
また、本発明の呈味改善剤は、高甘味度甘味料を含有している飲食品や口腔衛生製品に少量添加することで、高甘味度甘味料に特有の不快な後味や呈味が効果的に抑制され、飲食品や口腔衛生製品の呈味を改善することもできる。
本発明の呈味改善剤を添加し得る飲食品または口腔衛生製品は特に限定されない。飲食品としては、例えばコーヒー、紅茶、スポーツドリンク、乳飲料などの飲料;キャンディ、錠菓、チューインガムなどの菓子類;ゼリー、チルドデザートなどの冷菓;ヨーグルトなどの乳製品;等が挙げられる。また、ペットフード等のペット用の飼料も飲食品に含まれる。
また、口腔衛生製品としては、例えば歯磨き、洗口液、口中清涼剤、シート状フィルムなどが挙げられる。
また、本発明の呈味改善剤を、高甘味度甘味料を含有している飲食品や口腔衛生製品に添加する場合は、飲食品や口腔衛生製品の種類や剤形によって異なるが、該飲食品や口腔衛生製品中の呈味改善成分含量として、0.0001〜5質量%が通常であり、0.001〜2質量%が好ましい。
In addition, the taste improver of the present invention is effective for an unpleasant aftertaste and taste unique to high-intensity sweeteners by adding a small amount to foods and beverages and oral hygiene products containing high-intensity sweeteners. And can improve the taste of food and drink products and oral hygiene products.
The food or drink or oral hygiene product to which the taste improving agent of the present invention can be added is not particularly limited. Examples of the food and drink include beverages such as coffee, tea, sports drinks, and dairy drinks; confectionery such as candy, tablet confectionery, and chewing gum; frozen confectionery such as jelly and chilled dessert; and dairy products such as yogurt; Pet foods such as pet food are also included in the food and drink.
Examples of oral hygiene products include toothpaste, mouthwash, mouth freshener, and sheet-like film.
In addition, when the taste improver of the present invention is added to a food or drink or oral hygiene product containing a high-intensity sweetener, it varies depending on the type or dosage form of the food or drink or oral hygiene product. As a taste improving component content in goods and oral hygiene products, 0.0001-5 mass% is normal, and 0.001-2 mass% is preferable.
以下、実施例および比較例により本発明をさらに詳しく説明するが、本発明はこれらによりなんら限定されるものではない。
〔製造例1〕(サンショウの水による抽出物)
サンショウ乾燥実50gに、水250gを加えて室温下で1時間抽出したのち、抽出液を固液分離し、175g(Brix2.0)の抽出液を得た。
EXAMPLES Hereinafter, although an Example and a comparative example demonstrate this invention further in detail, this invention is not limited at all by these.
[Production Example 1] (Extract from salamander with water)
After adding 250 g of water to 50 g of dried dried salam and extracting at room temperature for 1 hour, the extract was subjected to solid-liquid separation to obtain 175 g (Brix 2.0) of the extract.
〔製造例2〕(サンショウの超臨界二酸化炭素による抽出物)
サンショウ乾燥実180gに50(w/w)%エタノールを180g添加し、撹拌混合した後すぐに抽出槽に仕込み、圧力10MPa、温度40℃の超臨界二酸化炭素を連続的に2時間半供給して抽出を行った。
超臨界二酸化炭素は、原料であるサンショウ乾燥実に対して7.1倍容量使用した。
抽出槽から流出する抽出物含有超臨界二酸化炭素は、圧力4MPa、温度25℃に保った分離槽に移し、抽出物を二酸化炭素から分離し、74gの抽出液を得た。
得られた抽出液を−5℃で一晩静置し、その後珪藻土ろ過を行い、本発明の呈味改善剤を得た。
得られた本発明の呈味改善剤はサンショウ特有のフローラルノートの少ない溶液であった。
[Production Example 2] (Extract of salamander with supercritical carbon dioxide)
180g of 50% (w / w)% ethanol was added to 180g of dried salamander, and after stirring and mixing, it was immediately charged into the extraction tank, and supercritical carbon dioxide at a pressure of 10MPa and a temperature of 40 ° C was continuously supplied for 2.5 hours. And extracted.
The supercritical carbon dioxide was used in a volume 7.1 times that of the dried raw salamander.
The extract-containing supercritical carbon dioxide flowing out from the extraction tank was transferred to a separation tank maintained at a pressure of 4 MPa and a temperature of 25 ° C., and the extract was separated from the carbon dioxide to obtain 74 g of an extract.
The obtained extract was allowed to stand at −5 ° C. overnight, followed by diatomaceous earth filtration to obtain a taste improver of the present invention.
The obtained taste improving agent of the present invention was a solution with few floral notes peculiar to salamanders.
〔分析例1〕
サンショウ水抽出物とサンショウ超臨界二酸化炭素抽出物を各0.2gずつガスクロマトグラフィー(GC)用バイアル瓶に精秤し、そこに内部標準物質(2−octanol;0.405w/v%のエタノール溶液)を5μL添加し、下記の条件でGC−MS分析を行い、フローラルノートを示す代表的な香気成分とサンショールの含有量をそれぞれ定量した。
高甘味度甘味料の不快な後味を改善する呈味改善剤は、改善剤自体に特有の香気がなく、呈味に影響するサンショールなどの成分が多いことが望まれる。
そこで、特有の香気として、サンショウ特有のフローラルノートに寄与するシトロネラール、酢酸シトロネリル、酢酸ゲラニルを測定した。
また、呈味に影響を及ぼす成分として、サンショール及びヒドロキシサンショールを測定した。
[Analysis Example 1]
A 0.2 g portion of each of the salamander water extract and the salamander supercritical carbon dioxide extract was precisely weighed into a gas chromatography (GC) vial, and the internal standard substance (2-octanol; 0.405 w / v%) was added there. Of ethanol solution) was added, and GC-MS analysis was performed under the following conditions to quantify the contents of typical aroma components and sun shoals showing floral notes.
It is desired that the taste improving agent for improving the unpleasant aftertaste of the high-intensity sweetener does not have a characteristic aroma in the improving agent itself and has many components such as sun shawl that affects the taste.
Therefore, citronellal, citronellyl acetate, and geranyl acetate contributing to floral notes peculiar to salamander were measured as specific aromas.
In addition, sun shawl and hydroxy sun shawl were measured as components affecting the taste.
<分析条件>
GC-MS:
Instrument Agilent 7890B & 5977A
Injection Vol 1.0μL
Carrier gas He (1.0mL/min)
Inlet 250℃, Split ratio 30:1
Column DB-1 (0.25mm i.d. x 30m x film thickness 0.25μm)
Oven temp 80℃-260℃, 3℃/min.
<Analysis conditions>
GC-MS:
Instrument Agilent 7890B & 5977A
Injection Vol 1.0μL
Carrier gas He (1.0mL / min)
Inlet 250 ℃, Split ratio 30: 1
Column DB-1 (0.25mm id x 30m x film thickness 0.25μm)
Oven temp 80 ℃ -260 ℃, 3 ℃ / min.
以上の分析結果から、サンショウを超臨界二酸化炭素で抽出すると、従来使用されてきた水による抽出物に比べ、フローラルノートの香気成分の含有量が少なく、サンショール等の呈味を感じさせる成分が多く抽出されることが分かった。 From the above analysis results, when extracting salam with supercritical carbon dioxide, the amount of aroma components in floral notes is less than that of water-based extracts that have been used in the past, and components that make you feel the taste of sansholes, etc. It was found that a lot was extracted.
〔シュガーレスチューインガム〕
ガムベース25質量部、キシリトール38.7〜39.0質量部、マルチトール18.7質量部、還元パラチノース15質量部、アスパルテーム1.2質量部、アセスルファムK0.1質量部を混合し、ミントフレーバー1質量部及び各素材を添加し、ローラーにより均一に混錬した。その後、常法に従って、圧展成形し、板状のシュガーレスチューインガムを調製した。
[Sugarless chewing gum]
Mixing 25 parts by weight of gum base, 38.7-39.0 parts by weight of xylitol, 18.7 parts by weight of maltitol, 15 parts by weight of reduced palatinose, 1.2 parts by weight of aspartame, 0.1 parts by weight of acesulfame K, mint flavor 1 A mass part and each raw material were added, and it knead | mixed uniformly with the roller. Then, in accordance with a conventional method, it pressure-molded and prepared the plate-shaped sugar-less chewing gum.
表2の処方により調製したシュガーレスチューインガムに、キナ酸(ナカライテスク株式会社製)、サンショウ水抽出物(製造例1)、サンショウ超臨界二酸化炭素抽出物(製造例2)をそれぞれ添加して、実施例1〜4、比較例1〜3のサンプル7種を調製した。
サンプル7種のうち、サンショウ水抽出物の添加品、並びにサンショウ超臨界二酸化炭素抽出物添加品に関しては、分析例1に従って、フローラルノートの香気成分(シトロネラール、酢酸シトロネリル、酢酸ゲラニル)と呈味に影響する成分(サンショール及びヒドロキシサンショール)の含有量の定量分析を行った。その結果を表2に示す。
To sugarless chewing gum prepared according to the formulation in Table 2, quinic acid (manufactured by Nacalai Tesque Co., Ltd.), salamander extract (Manufacturing Example 1), and salamander supercritical carbon dioxide extract (Manufacturing Example 2) were added. 7 samples of Examples 1 to 4 and Comparative Examples 1 to 3 were prepared.
Of the seven types of samples, the additive for the salamander extract and the additive for the supercritical carbon dioxide extract are presented as floral note aroma components (citronellal, citronellyl acetate, geranyl acetate) according to Analysis Example 1. Quantitative analysis of the content of components affecting the taste (sansholes and hydroxysansholes) was performed. The results are shown in Table 2.
上記のサンプル7種について、10名のパネルにより呈味改善効果に関する官能評価を行った。
官能評価は以下の評価基準を用いて比較例及び実施例の不快な甘味の後残り、嗜好性に関する各項目を点数で評価し、各パネルの評価点を平均した。結果を表3に示す。
The sensory evaluation regarding a taste improvement effect was performed about 10 types of said samples by the panel of 10 persons.
The sensory evaluation was performed after the unpleasant sweetness of the comparative examples and examples using the following evaluation criteria, and each item relating to palatability was evaluated by a score, and the evaluation score of each panel was averaged. The results are shown in Table 3.
<評価基準>
(不快な甘味の後残り)
非常に強い:5点
強い: 4点
中程度: 3点
弱い: 2点
非常に弱い:1点
(嗜好性)
非常に高い:5点
高い: 4点
中程度: 3点
低い: 2点
非常に低い:1点
<Evaluation criteria>
(Remaining after unpleasant sweetness)
Very strong: 5 points Strong: 4 points Medium: 3 points Weak: 2 points Very weak: 1 point (preference)
Very high: 5 points High: 4 points Medium: 3 points Low: 2 points Very low: 1 point
サンショウ超臨界二酸化炭素抽出物を添加したものは、キナ酸添加と比較して不快な甘味の後残りが弱く、嗜好性が高かった。 What added the salmon supercritical carbon dioxide extract had a weak rest after unpleasant sweetness and high palatability compared with the addition of quinic acid.
〔シュガーレスキャンディ〕
表4のシュガーレスキャンディを調製した。
鍋に還元麦芽糖水飴400質量部、水30質量部、アセスルファムK0.15質量部、スクラロース0.05質量部を入れ、徐々に加熱して完全に溶解させ、これを常法により155℃になるまで煮詰めた。
これに比較例4はレモンフレーバーを0.3質量部、比較例5はレモンフレーバーを0.3質量部にさらにサンショウ水抽出物(製造例1)を0.1質量部、実施例5はレモンフレーバーを0.3質量部にさらにサンショウ超臨界二酸化炭素抽出物(製造例2)を0.001質量部加え、混合した後デポジットによりキャンディを成型した。
[Sugarless candy]
The sugarless candy of Table 4 was prepared.
Put 400 parts by weight of reduced maltose starch syrup, 30 parts by weight of water, 0.15 part by weight of acesulfame K, 0.05 part by weight of sucralose, and gradually heat until completely dissolved until it reaches 155 ° C. by a conventional method. Boiled.
Comparative Example 4 is 0.3 parts by weight of lemon flavor, Comparative Example 5 is 0.3 parts by weight of lemon flavor, and 0.1 parts by weight of the extract of salmon water (Production Example 1). To 0.3 parts by mass of lemon flavor, 0.001 part by mass of a sunflower supercritical carbon dioxide extract (Production Example 2) was added and mixed, and then a candy was formed by depositing.
10名のパネルにより、シュガーレスチューインガムの場合と同じ評価基準により官能評価を行った。官能評価の結果を表5に示した。
サンショウ超臨界二酸化炭素抽出物を添加した実施例5のシュガーレスキャンディは不快な甘味の後残りが弱く、嗜好性が高かった。
一方、サンショウ超臨界二酸化炭素抽出物を添加しなかった比較例4および5のシュガーレスキャンディは不快な甘味の後残りが強く、嗜好性が低かった。
The sugar-free candy of Example 5 to which the salmon supercritical carbon dioxide extract was added had a weak rest after unpleasant sweetness and high palatability.
On the other hand, the sugarless candy of Comparative Examples 4 and 5 to which the salmon supercritical carbon dioxide extract was not added had a strong remaining after unpleasant sweetness and low palatability.
本発明の呈味改善剤は、飲食品又は口腔衛生製品の本来の風味を変えることなく、高甘味度甘味料特有の不快な後味や呈味を効果的に抑制することのできる呈味改善剤として広く利用可能である。 The taste improver of the present invention is a taste improver that can effectively suppress unpleasant aftertaste and taste peculiar to high-intensity sweeteners without changing the original flavor of food or drink products or oral hygiene products. As widely available.
Claims (27)
(a)超臨界流体が、圧力7.4〜60MPa、温度20〜100℃の領域における超臨界状態二酸化炭素である。
(b)超臨界流体の使用量がサンショウの1〜20倍容量である。
(c)抽出時間が1〜6時間である。 A taste-improving agent for high-intensity sweeteners, comprising as an active ingredient an extract obtained by extracting salamander with a supercritical fluid under the following conditions .
(A) The supercritical fluid is supercritical carbon dioxide in a region where the pressure is 7.4 to 60 MPa and the temperature is 20 to 100 ° C.
(B) The amount of supercritical fluid used is 1 to 20 times that of the salamander.
(C) Extraction time is 1 to 6 hours.
(a)超臨界流体が、圧力8〜20.5MPa、温度30〜80℃の領域における超臨界状態二酸化炭素である。(A) The supercritical fluid is supercritical carbon dioxide in the region of a pressure of 8 to 20.5 MPa and a temperature of 30 to 80 ° C.
(b)超臨界流体の使用量がサンショウの1〜15倍容量である。(B) The amount of supercritical fluid used is 1 to 15 times the capacity of the salamander.
(c)抽出時間が1.5〜3時間である。(C) The extraction time is 1.5 to 3 hours.
(a)超臨界流体が、圧力7.4〜60MPa、温度20〜100℃の領域における超臨界状態二酸化炭素である。
(b)超臨界流体の使用量がサンショウの1〜20倍容量である。
(c)抽出時間が1〜6時間である。 A fragrance composition for improving the taste of a high-intensity sweetener comprising an extract obtained by extracting a salamander with a supercritical fluid under the following conditions .
(A) The supercritical fluid is supercritical carbon dioxide in a region where the pressure is 7.4 to 60 MPa and the temperature is 20 to 100 ° C.
(B) The amount of supercritical fluid used is 1 to 20 times that of the salamander.
(C) Extraction time is 1 to 6 hours.
(a)超臨界流体が、圧力7.4〜60MPa、温度20〜100℃の領域における超臨界状態二酸化炭素である。
(b)超臨界流体の使用量がサンショウの1〜20倍容量である。
(c)抽出時間が1〜6時間である。 A method for improving the taste of a high-intensity sweetener, comprising adding 0.023 to 2.3 parts by mass of a supercritical fluid extract under the following conditions of a salamander to 100 parts by mass of a high-intensity sweetener.
(A) The supercritical fluid is supercritical carbon dioxide in a region where the pressure is 7.4 to 60 MPa and the temperature is 20 to 100 ° C.
(B) The amount of supercritical fluid used is 1 to 20 times that of the salamander.
(C) Extraction time is 1 to 6 hours.
(a)超臨界流体が、圧力7.4〜60MPa、温度20〜100℃の領域における超臨界状態二酸化炭素である。(A) The supercritical fluid is supercritical carbon dioxide in a region where the pressure is 7.4 to 60 MPa and the temperature is 20 to 100 ° C.
(b)超臨界流体の使用量がサンショウの1〜20倍容量である。(B) The amount of supercritical fluid used is 1 to 20 times that of the salamander.
(c)抽出時間が1〜6時間である。(C) Extraction time is 1 to 6 hours.
(a)超臨界流体が、圧力8〜20.5MPa、温度30〜80℃の領域における超臨界状態二酸化炭素である。(A) The supercritical fluid is supercritical carbon dioxide in the region of a pressure of 8 to 20.5 MPa and a temperature of 30 to 80 ° C.
(b)超臨界流体の使用量がサンショウの1〜15倍容量である。(B) The amount of supercritical fluid used is 1 to 15 times the capacity of the salamander.
(c)抽出時間が1.5〜3時間である。(C) The extraction time is 1.5 to 3 hours.
(a)超臨界流体が、圧力7.4〜60MPa、温度20〜100℃の領域における超臨界状態二酸化炭素である。(A) The supercritical fluid is supercritical carbon dioxide in a region where the pressure is 7.4 to 60 MPa and the temperature is 20 to 100 ° C.
(b)超臨界流体の使用量がサンショウの1〜20倍容量である。(B) The amount of supercritical fluid used is 1 to 20 times that of the salamander.
(c)抽出時間が1〜6時間である。(C) Extraction time is 1 to 6 hours.
(a)超臨界流体が、圧力7.4〜60MPa、温度20〜100℃の領域における超臨界状態二酸化炭素である。(A) The supercritical fluid is supercritical carbon dioxide in a region where the pressure is 7.4 to 60 MPa and the temperature is 20 to 100 ° C.
(b)超臨界流体の使用量がサンショウの1〜20倍容量である。(B) The amount of supercritical fluid used is 1 to 20 times that of the salamander.
(c)抽出時間が1〜6時間である。(C) Extraction time is 1 to 6 hours.
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