JP5847389B2 - Effervescent candy - Google Patents

Effervescent candy Download PDF

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JP5847389B2
JP5847389B2 JP2010240528A JP2010240528A JP5847389B2 JP 5847389 B2 JP5847389 B2 JP 5847389B2 JP 2010240528 A JP2010240528 A JP 2010240528A JP 2010240528 A JP2010240528 A JP 2010240528A JP 5847389 B2 JP5847389 B2 JP 5847389B2
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candy
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effervescent
foamable
sugar alcohol
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牧子 平石
牧子 平石
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Kao Corp
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Description

本発明は、発泡性キャンディに関する。   The present invention relates to an effervescent candy.

一般に、発泡性キャンディは、砂糖等の糖類と水とを混合し、加熱により煮詰めて水分を蒸発させた後に香料等の添加物を配合してキャンディ生地を調製し、ここに発泡性成分を練り込み、押し型により切断・成型して製造される。かかる発泡性キャンディは、食した際に唾液等の水分によって、溶解すると同時に発泡性成分が分解され、口腔内にシュワシュワとした発泡感をもたらすこととなる。   In general, effervescent candy is prepared by mixing saccharides such as sugar and water, boiled by heating to evaporate the moisture, and then blended with additives such as fragrances to prepare candy dough. And cut and molded with a pressing die. Such effervescent candy dissolves with moisture such as saliva when eaten, and at the same time, the effervescent component is decomposed, resulting in a foamy feeling in the mouth.

こうした発泡性キャンディとして、様々な配合処方のものが開発されている。例えば、特許文献1には、発泡性成分に加えてのど作用性成分を配合することによって、のどに対する作用効果が増強される、発泡性成分を含有するのどケア用アメが開示されている。また、特許文献2には、発泡性成分に加えて麦芽糖類を特定の量で含有することによって、良好な保存安定性及び生産性を有する発泡性キャンディが開示されている。   As such effervescent candy, various compounding prescriptions have been developed. For example, Patent Document 1 discloses a candy for throat care containing a foamable component, in which the action effect on the throat is enhanced by blending a throat active component in addition to the foamable component. Patent Document 2 discloses an effervescent candy having good storage stability and productivity by containing maltose in a specific amount in addition to the effervescent component.

特開2002−184号公報Japanese Patent Laid-Open No. 2002-184 特開2004−16073号公報JP 2004-16073 A

しかしながら、これら発泡性キャンディに配合される有機酸や炭酸塩等の発泡性成分は、粉体状態でキャンディ生地に練り込むので、充分な発泡性を付与するためにその配合量を増大させると、キャンディ生地調製時の操作性が低下して調製しにくくなるおそれがあり、依然として改善の余地がある。   However, foaming components such as organic acids and carbonates blended with these foamable candy are kneaded into the candy dough in a powder state, so increasing the blending amount in order to give sufficient foaming, There is a possibility that the operability at the time of preparing the candy dough may be lowered and difficult to prepare, and there is still room for improvement.

本発明は、良好な生産性及び保存安定性を保持しつつ、優れた発泡感を発揮できる発泡性キャンディを提供することにある。   An object of the present invention is to provide an effervescent candy that can exhibit excellent foaming feeling while maintaining good productivity and storage stability.

本発明者は上記課題を解決すべく種々検討した結果、糖類に含まれる糖アルコール中でのエリスリトール含有量を特定の量とすることで、発泡感が著しく向上することを見出し、本発明を完成させるに至った。   As a result of various studies to solve the above problems, the present inventor has found that the foaming feeling is remarkably improved by setting the erythritol content in the sugar alcohol contained in the saccharide to a specific amount, thereby completing the present invention. I came to let you.

すなわち、本発明は、発泡性成分及び糖類を含有する発泡性キャンディであって、
前記糖類100質量%中に、糖アルコールを98質量%以上含有し、かつ
前記糖アルコール100質量%中に、エリスリトールを2〜12質量%含有する発泡性キャンディを提供するものである。
That is, the present invention is an effervescent candy containing an effervescent component and a saccharide,
The present invention provides an effervescent candy containing 98% by mass or more of sugar alcohol in 100% by mass of the saccharide and 2 to 12% by mass of erythritol in 100% by mass of the sugar alcohol.

本発明の発泡性キャンディによれば、特定の量で含有されるエリスリトールにより、味の低下を引き起こすことなく、発泡性成分と相まって強力な発泡感をもたらすことができる。また、調製時にキャンディ生地の良好な流動性を確保することができるので、発泡性成分をキャンディ生地中に非常に良好に分散させることができ、その結果、極めて優れた発泡感をもたらすことができる。加えて、調製が容易であるとともに保形性にも優れ、生産性の向上を図ることが可能である。さらに、調製時や保存時における熱や水分による分解や発泡を有効に低減して、優れた保存安定性を発揮することができる。   According to the foamable candy of the present invention, the erythritol contained in a specific amount can bring about a strong foaming feeling in combination with the foamable component without causing a decrease in taste. In addition, since the good fluidity of the candy dough can be ensured at the time of preparation, the foamable component can be very well dispersed in the candy dough, and as a result, a very good foaming feeling can be brought about. . In addition, the preparation is easy, the shape retention is excellent, and the productivity can be improved. Furthermore, decomposition and foaming due to heat and moisture during preparation and storage can be effectively reduced, and excellent storage stability can be exhibited.

以下、本発明について詳細に説明する。
本発明の発泡性キャンディは、発泡性成分及び糖類を含有する。かかる発泡性成分としては、有機酸と、炭酸塩及び/又は炭酸水素塩とを含むのが好ましい。ここで、有機酸としては、25℃で固体の有機酸が好ましく、具体的には、クエン酸、酒石酸、アスコルビン酸、リンゴ酸、フマル酸、コハク酸、マロン酸等が挙げられ、なかでも充分な発泡性かつ良好な発泡感を得る観点及び入手容易性の観点から、クエン酸、酒石酸が好ましく、特に、クエン酸が好ましい。
Hereinafter, the present invention will be described in detail.
The foamable candy of the present invention contains a foamable component and a saccharide. Such foaming components preferably include an organic acid and a carbonate and / or bicarbonate. Here, the organic acid is preferably an organic acid that is solid at 25 ° C., and specifically, citric acid, tartaric acid, ascorbic acid, malic acid, fumaric acid, succinic acid, malonic acid, and the like can be mentioned. Citric acid and tartaric acid are preferable, and citric acid is particularly preferable from the viewpoints of obtaining good foamability and good foaming feeling and availability.

炭酸塩及び炭酸水素塩としては、炭酸ナトリウム、炭酸水素ナトリウム、炭酸カリウム、炭酸水素カリウム、炭酸アンモニウム、セスキ炭酸ナトリウム等が挙げられ、なかでも炭酸ナトリウム、炭酸水素ナトリウム、炭酸カリウムが好ましく、特に、炭酸水素ナトリウムが好ましい。   Examples of the carbonate and hydrogen carbonate include sodium carbonate, sodium hydrogen carbonate, potassium carbonate, potassium hydrogen carbonate, ammonium carbonate, sodium sesquicarbonate, etc., among which sodium carbonate, sodium hydrogen carbonate, and potassium carbonate are preferable. Sodium bicarbonate is preferred.

なお、炭酸塩及び/又は炭酸水素塩としては、優れた発泡性を保持しつつ、良好な保存安定性の発揮及び為害性の低減化を図る観点から、その混合前平均粒子径を50〜100μm、好ましくは80〜100μmとするのがよい。ここで、平均粒子径とは質量基準の平均粒子径であり、質量基準の累積粒度分布で50%の粒子径として定義され、例えば、JIS Z 8801−1に規定する篩分け法に従って、ロータップ型篩振盪機を用いて測定した値である。   In addition, as a carbonate and / or bicarbonate, while maintaining excellent foamability, the average particle size before mixing is 50 to 100 μm from the viewpoint of achieving good storage stability and reducing harmfulness. The thickness is preferably 80 to 100 μm. Here, the average particle size is a mass-based average particle size, and is defined as a 50% particle size in a mass-based cumulative particle size distribution. For example, according to a sieving method defined in JIS Z 8801-1, a low-tap type It is the value measured using a sieve shaker.

本発明の発泡性キャンディ全量100質量%中における上記発泡性成分の含有量は、充分な発泡性を得る観点から、その合計量が、通常1〜30質量%、好ましくは3〜20質量%、より好ましくは5〜15質量%であるのが望ましい。発泡性成分の含有量が上記範囲内であると、発泡性成分の練り込み時における作業性の低下を有効に防止することができ、キャンディ生地中における発泡性成分の分散性の向上を容易に図ることが可能となる。このように、本発明の発泡性キャンディでは、優れた発泡感を保持したまま、発泡性成分の配合量を低減することも可能となり、その結果、優れた発泡感を保持したまま、更に優れた生産性及び保存安定性を有する発泡性キャンディを実現することができる。   The total content of the foamable component in 100% by mass of the foamable candy of the present invention is usually 1 to 30% by mass, preferably 3 to 20% by mass, from the viewpoint of obtaining sufficient foaming properties. More preferably, it is 5-15 mass%. When the content of the foamable component is within the above range, it is possible to effectively prevent a decrease in workability during the kneading of the foamable component, and to easily improve the dispersibility of the foamable component in the candy dough It becomes possible to plan. As described above, in the foamable candy of the present invention, it is possible to reduce the blending amount of the foamable component while maintaining an excellent foaming feeling, and as a result, further excellent while maintaining the excellent foaming feeling. An effervescent candy having productivity and storage stability can be realized.

本発明の発泡性キャンディに含有される糖類としては、砂糖、麦芽糖、ブドウ糖、オリゴ糖等のほか、糖アルコールが挙げられる。糖アルコールとしては、エリスリトール、マルチトール(還元麦芽糖水飴)、還元パラチノース(パラチニット(登録商標))、ラクチトール(還元乳糖)、還元水飴、ソルビトール、マンニトール、キシリトール等が挙げられる。そして、上記発泡性キャンディは糖類100質量%中に、糖アルコールを98質量%以上、好ましくは98.5〜100質量%含有する。糖類中における糖アルコールの含有量が上記範囲内であると、キャンディ生地の調製が容易であるとともに良好な保存安定性を保持することができる。   Examples of the saccharide contained in the foamable candy of the present invention include sugar alcohol, in addition to sugar, maltose, glucose, oligosaccharide and the like. Examples of the sugar alcohol include erythritol, maltitol (reduced maltose starch syrup), reduced palatinose (palatinite (registered trademark)), lactitol (reduced lactose), reduced starch syrup, sorbitol, mannitol, xylitol and the like. And the said effervescent candy contains 98 mass% or more of sugar alcohols in 100 mass% of saccharides, Preferably 98.5-100 mass%. When the content of the sugar alcohol in the saccharide is within the above range, the candy dough can be easily prepared and good storage stability can be maintained.

本発明の発泡性キャンディは、糖アルコール100質量%中に、エリスリトールを2〜18質量%、好ましくは3〜15質量%、より好ましくは7〜12質量%含有する。エリスリトールの含有量が上記範囲内であると、キャンディ生地に良好な流動性を付与することができるので、調製作業が容易になるとともに、発泡性成分をキャンディ生地中に極めて良好に分散させることが可能となる。また、エリスリトール自体がもたらす清涼感が発泡性成分による発泡感を増強させる効果を発揮し、キャンディの発泡性を顕著に向上させることができる。さらに、キャンディ生地のベタツキを有効に抑制しつつ、良好な保形性と保存安定性とを保持することもできる。   The foamable candy of the present invention contains 2 to 18% by mass, preferably 3 to 15% by mass, more preferably 7 to 12% by mass of erythritol in 100% by mass of the sugar alcohol. When the content of erythritol is within the above range, good fluidity can be imparted to the candy dough, so that the preparation operation becomes easy and the foaming component can be dispersed extremely well in the candy dough. It becomes possible. Moreover, the refreshing feeling brought about by erythritol itself exerts the effect of enhancing the foaming feeling by the foaming component, and the foamability of the candy can be remarkably improved. Furthermore, good shape retention and storage stability can be maintained while effectively suppressing stickiness of the candy dough.

上記発泡性キャンディは、エリスリトール以外の糖アルコールとして、還元パラチノースを含有するのが好ましい。還元パラチノースを含有する場合、その含有量は、糖アルコール100質量%中に通常70〜98重量%、好ましくは75〜95重量%、より好ましくは80〜90重量%であるのが望ましい。還元パラチノースの含有量が上記範囲内であると、調製をより良好に行うことができるとともに、キャンディ生地中における発泡性成分の分散性をさらに向上させることができるため、発泡感のさらなる向上が期待される。また、還元パラチノースを含有することによるこれらの効果をより有効に発揮させる観点から、上記還元パラチノースと上記エリスリトールとの含有量の比(還元パラチノースの含有量/前記エリスリトールの含有量(質量比))は、好ましくは5〜30であり、より好ましくは6〜20、最も好ましくは7〜10であるのが望ましい。   The effervescent candy preferably contains reduced palatinose as a sugar alcohol other than erythritol. When the reduced palatinose is contained, the content thereof is usually 70 to 98% by weight, preferably 75 to 95% by weight, more preferably 80 to 90% by weight in 100% by mass of the sugar alcohol. When the content of the reduced palatinose is within the above range, the preparation can be performed better and the dispersibility of the foamable component in the candy dough can be further improved. Is done. Further, from the viewpoint of more effectively exerting these effects by containing reduced palatinose, the ratio of the content of the reduced palatinose and the erythritol (the content of the reduced palatinose / the content of the erythritol (mass ratio)). Is preferably 5-30, more preferably 6-20, and most preferably 7-10.

さらに、エリスリトール以外の好適な糖アルコールとして、還元パラチノースのほかに、流動性や味の点で他の糖アルコールと比較して好ましいマルチトールが挙げられ、その含有量は糖アルコール100質量%中に、20質量%以下、好ましくは15質量%以下であると良い。   In addition to reduced palatinose, preferred sugar alcohols other than erythritol include maltitol, which is preferable compared to other sugar alcohols in terms of fluidity and taste, and the content thereof is 100% by weight of sugar alcohol. 20 mass% or less, preferably 15 mass% or less.

さらに、本発明の発泡性キャンディには、所望により、スペアミント油、ペパーミント油、ウインターグリーン油、サッサフラス油、セージ油、ユーカリ油、マヨナラ油、肉桂油、タイム油、レモン油及びオレンジ油等の天然香料や各種合成香料;サッカリンやスクラロース等の甘味料;ベニコウジ色素、アントシアニン系色素、クチナシ色素及びカロテン色素等の着色料を含有させてもよい。   Furthermore, the foamable candy of the present invention may be added to natural oils such as spearmint oil, peppermint oil, winter green oil, sassafras oil, sage oil, eucalyptus oil, mayonnaise oil, cinnamon oil, thyme oil, lemon oil and orange oil. Perfumes and various synthetic fragrances; sweeteners such as saccharin and sucralose; and coloring agents such as Benikouji pigment, anthocyanin pigment, gardenia pigment and carotene pigment may be included.

本発明の発泡性キャンディは、ドロップ、アメ等のハードキャンディの形態を有する。本発明の発泡性キャンディの製造法は、略均一構造の場合は常法によりキャンディ生地の調製及び成形を行えば良い。   The effervescent candy of the present invention has a form of hard candy such as drop or candy. In the production method of the foamable candy of the present invention, the candy dough may be prepared and molded by a conventional method in the case of a substantially uniform structure.

具体的な調製及び成形方法としては、例えば、糖アルコール類を180〜200℃にて加熱溶融し、次に加熱を停止して温度を低下させ、該キャンディ生地が100℃以下になった時点で、糖アルコール以外の糖類、及び発泡性成分を添加混合してキャンディ生地を調製し、得られたキャンディ生地を適宜成形する、という方法を採用することができる。なお、発泡性成分のうち、有機酸はキャンディ生地が100℃以下になった時点で添加し、さらに、炭酸塩及び/又は炭酸水素塩は70℃以下になった時点で添加混合する。また、香料、甘味料、着色料、のど作用性成分等を配合する場合、各々の成分の特性に合わせ、適切なタイミングで添加混合するとよい。   As a specific preparation and molding method, for example, sugar alcohols are heated and melted at 180 to 200 ° C., then the heating is stopped to lower the temperature, and when the candy dough becomes 100 ° C. or less. A method of preparing a candy dough by adding and mixing saccharides other than sugar alcohol and an effervescent component and appropriately shaping the obtained candy dough can be employed. Of the foamable components, the organic acid is added when the candy dough is 100 ° C. or lower, and the carbonate and / or bicarbonate is added and mixed when the candy dough is 70 ° C. or lower. Further, when blending a flavoring agent, a sweetening agent, a coloring agent, a throat active ingredient, or the like, it may be added and mixed at an appropriate timing in accordance with the characteristics of each ingredient.

以下、本発明について、実施例に基づき具体的に説明するが、本発明はこれら実施例に限定されるものではない。   EXAMPLES Hereinafter, although this invention is demonstrated concretely based on an Example, this invention is not limited to these Examples.

[実施例1〜4、及び比較例1〜5]
表1〜2に示す組成に従って各キャンディ生地を調製し、発泡性成分が成形後のキャンディ生地中に略均一に含有される球状の発泡性キャンディを得た。具体的には、まず、糖アルコール類を180℃で煮詰めてキャンディ生地を調製し、次いでこれを冷却し、100℃以下になった時点で香料と甘味料(スクラロース)を添加して、混合した。続いて、クエン酸を添加して混合し、70℃以下になった時点で炭酸水素ナトリウムを添加し、混合した。得られたキャンディ生地を所定量に切断し、球状に成型した。
なお、用いた炭酸水素ナトリウムの添加前の平均粒子径をJIS Z 8801−1に規定する篩分け法に従って、ロータップ型篩振盪機で測定したところ、90μmであった。
[Examples 1 to 4 and Comparative Examples 1 to 5]
Each candy dough was prepared according to the composition shown in Tables 1 and 2, and a spherical effervescent candy in which the effervescent component was contained substantially uniformly in the formed candy dough was obtained. Specifically, first, sugar alcohols are boiled at 180 ° C. to prepare a candy dough, then this is cooled, and when it becomes 100 ° C. or less, a flavor and sweetener (sucralose) are added and mixed. . Subsequently, citric acid was added and mixed. When the temperature reached 70 ° C. or lower, sodium bicarbonate was added and mixed. The obtained candy dough was cut into a predetermined amount and molded into a spherical shape.
In addition, it was 90 micrometers when the average particle diameter before addition of the sodium hydrogencarbonate used was measured with the low tap type sieve shaker according to the sieving method prescribed | regulated to JISZ8801-1.

[評価方法]
得られた各キャンディについて、以下の方法に従い、生産性、保存安定性、発泡感、及び味の各評価を行った。結果を表1〜2に示す。
[Evaluation method]
About each obtained candy, according to the following method, each evaluation of productivity, storage stability, a feeling of foaming, and taste was performed. The results are shown in Tables 1-2.

(1)生産性:キャンディ成型後30〜60分経過しキャンディ温度が室温まで低下した時の外観を観察し、保形性を評価した。なお、保形性が良好であるほど、生産性が高いものと判断した。
○:球型を保っている
△:成型直後に比べて、球型が崩れている(軟化によりドーム状に変形)
×:軟化が激しく、成型が困難、または成型後すぐに球型が崩れている
(1) Productivity: 30 to 60 minutes after candy molding, the appearance when the candy temperature was lowered to room temperature was observed, and the shape retention was evaluated. The better the shape retention, the higher the productivity.
○: Keeping a spherical shape
Δ: Spherical shape is broken compared to immediately after molding (deformed into a dome shape by softening)
X: Severe softening, difficult to mold, or sphere shape collapsed immediately after molding

(2)保存安定性:アルミラミネートフィルムで各キャンディを個別包装し、30℃室内で6ヶ月間保存する前後の球径をノギスで測定した。
○:変化率が5%以内
×:変化率が5%超
(2) Storage stability: Each candy was individually wrapped with an aluminum laminate film, and the spherical diameter before and after storage for 6 months in a 30 ° C. room was measured with a caliper.
○: Change rate is within 5%
×: Change rate exceeds 5%

(3)発泡感:4人で試食し、発泡感を評価し、最も人数の多い評価を表1、2に示した。
◎:比較例1に比べて発泡感をかなり強く感じる
○:比較例1に比べて発泡感を強く感じる
×:比較例1と比べて発泡感が同程度又はそれ以下
(3) Foaming feeling: Four people tasted and evaluated the foaming feeling. Tables 1 and 2 show the evaluation with the largest number of people.
A: A feeling of foaming is considerably stronger than in Comparative Example 1.
○: Feeling of foaming stronger than Comparative Example 1
X: Compared with Comparative Example 1, the foaming feeling is comparable or less

(4)味:4人で試食し、味を評価し、最も人数の多い評価を表1、2に示した。
○:比較例1に比べて発泡感を強く感じながらも、良好な味であった。
×:比較例1と比べて発泡感が同程度又はそれ以下であり、物足りない味であった。
(4) Taste: Four people tasted and evaluated the taste, and Tables 1 and 2 show the evaluation with the largest number of people.
○: Although the foaming feeling was strongly felt as compared with Comparative Example 1, the taste was good.
X: The foaming feeling was comparable or lower than that of Comparative Example 1, and the taste was unsatisfactory.

Figure 0005847389
Figure 0005847389

Figure 0005847389
Figure 0005847389

上記結果によれば、実施例1〜4のキャンディは、比較例1〜5のものと比べ、優れた発泡感を発揮しながら、良好な生産性及び保存安定性を保持し、味も良好であることがわかる。特に、比較例4ではキャンディが軟化し、変形してしまい、さらにこの軟化に伴って発泡性成分の分解が起こったため、試食時の発泡感、味も良好ではなかった。   According to the said result, the candy of Examples 1-4 compared with those of Comparative Examples 1-5, maintaining good productivity and storage stability while exhibiting an excellent foaming feeling, and having a good taste. I know that there is. In particular, in Comparative Example 4, the candy was softened and deformed, and further, the foamable component was decomposed along with the softening, so the foaming feeling and taste at the time of tasting were not good.

Claims (4)

発泡性成分及び糖類を含有する発泡性キャンディであって、
前記糖類100質量%中に、糖アルコールを98質量%以上含有し、
前記糖アルコール100質量%中に、エリスリトールを3〜12質量%及び還元パラチノースを70〜95質量%含有し、かつ
前記還元パラチノースと前記エリスリトールの含有量の質量比(還元パラチノースの含有量/エリスリトールの含有量)が、6〜30である発泡性キャンディ。
An effervescent candy containing an effervescent component and a saccharide,
In 100% by mass of the saccharide, 98% by mass or more of sugar alcohol is contained,
100% by mass of the sugar alcohol contains 3-12% by mass of erythritol and 70-95 % by mass of reduced palatinose, and the mass ratio of the content of the reduced palatinose and the erythritol (content of reduced palatinose / erythritol Effervescent candy whose content is 6-30.
前記発泡性成分が、有機酸と、炭酸塩及び/又は炭酸水素塩とを含み、
発泡性キャンディ全量100質量%中に、前記発泡性成分を1〜30質量%含有する請求項1に記載の発泡性キャンディ。
The foamable component comprises an organic acid and a carbonate and / or bicarbonate;
The effervescent candy according to claim 1, wherein the effervescent candy is contained in an amount of 1 to 30% by mass in 100% by mass of the total effervescent candy.
前記糖アルコール中におけるマルチトールの含有量が、20質量%以下である請求項1又は2に記載の発泡性キャンディ。   The foamable candy according to claim 1 or 2, wherein the content of maltitol in the sugar alcohol is 20% by mass or less. 糖アルコール類を180〜200℃にて加熱溶融した後、100℃以下に温度を低下させた時点で、糖アルコール以外の糖類及び発泡性成分を添加混合して調製したキャンディ生地から得られる請求項1〜3の何れか一項に記載の発泡性キャンディ。   Claims obtained from candy dough prepared by adding and mixing sugars other than sugar alcohol and foamable components at the time when the temperature is lowered to 100 ° C or lower after sugar alcohols are heated and melted at 180 to 200 ° C. The effervescent candy as described in any one of 1-3.
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