JP5843460B2 - Gel-like food and method for producing the same - Google Patents

Gel-like food and method for producing the same Download PDF

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JP5843460B2
JP5843460B2 JP2011078784A JP2011078784A JP5843460B2 JP 5843460 B2 JP5843460 B2 JP 5843460B2 JP 2011078784 A JP2011078784 A JP 2011078784A JP 2011078784 A JP2011078784 A JP 2011078784A JP 5843460 B2 JP5843460 B2 JP 5843460B2
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石橋 三希
三希 石橋
起矢 岩澤
起矢 岩澤
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Megmilk Snow Brand Co Ltd
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本発明は、複数相構造を有するゲル状食品およびその製造方法に関する。   The present invention relates to a gel food having a multiphase structure and a method for producing the same.

従来、ゼリーやプリンなどのゲル状食品が多く市販されている。一方、このようなゲル状食品の市場価値を高めるべく、食品自体を複数相化した例も多い。例えば、カラギナン、寒天、ゼラチン、その他を膠質として、これにアルギン酸ナトリウム塩などを添加した水性ゲルと飲料水中にカルシウム塩を存在させたものとを層状に接合して一体とした多層型ゼリーが提案されている(特許文献1参照)。また、原料液にゲル化剤を含有させ、他の原料液にゲル化剤のゲル化を触発させる成分を含有させて別個に調製し、これらを混合して固化し、その上にゲル状食品などの他の食品を充填する多層ゲル化食品の製造方法も提案されている。(特許文献2参照)。さらにまた、ゲル状物の中に液状物が取り込まれたタイプのものとしては、アルギン酸塩やLMペクチンを配合してなるゲル状物の中に、液状食品を分散させた例が知られている(特許文献3参照)。   Conventionally, many gel foods such as jelly and pudding are commercially available. On the other hand, in order to increase the market value of such a gel food, there are many examples in which a plurality of foods are phased. For example, a multi-layer jelly is proposed in which carrageenan, agar, gelatin, etc. are used as a colloid, and an aqueous gel in which sodium alginate is added to this and a calcium salt present in drinking water are joined together in layers. (See Patent Document 1). In addition, the raw material liquid contains a gelling agent, and the other raw material liquid contains a component that triggers gelation of the gelling agent and is separately prepared, mixed and solidified, and then a gel food A method for producing a multilayer gelled food filling other foods such as the above has also been proposed. (See Patent Document 2). Furthermore, as a type in which a liquid material is taken into a gel-like material, an example in which a liquid food is dispersed in a gel-like material containing alginate or LM pectin is known. (See Patent Document 3).

特開昭62−248464号公報Japanese Patent Laid-Open No. 62-248464 特開2000−60450号公報JP 2000-60450 A 特開2002−27925号公報JP 2002-27925 A

しかしながら、従来知られた多層構造のゲル状食品は、その製造方法が必ずしも簡便ではなく、さらに得られた多層ゲル状食品においては各層の境界が必ずしも鮮明ではなかった。さらにまた、各相のゾル−ゲル状態を可逆的に制御することも困難であった。例えば、複数相ゲル状食品の中の各相についてゾル−ゲル変化を可逆的に制御できれば充填時あるいは商品提供時において好ましいがそのような複数相ゲル状食品は知られていなかった。   However, the conventionally known multilayered gel foods are not always easy to produce, and the obtained multilayer gelled foods do not always have clear boundaries between the layers. Furthermore, it has been difficult to reversibly control the sol-gel state of each phase. For example, if it is possible to reversibly control the sol-gel change for each phase in the multi-phase gel food, it is preferable at the time of filling or product provision, but such multi-phase gel food has not been known.

本発明の目的は、明確な複数相構造からなり全体としてゲル状でありながら、少なくとも1相についてはゾル−ゲル変化を可逆的に制御し得るゲル状食品およびその簡便な製造方法を提供することにある。   An object of the present invention is to provide a gel food capable of reversibly controlling a sol-gel change for at least one phase and a simple production method thereof, while having a clear multi-phase structure and being in a gel state as a whole. It is in.

前記課題を解決すべく、本発明は、以下のようなゲル状食品およびその製造方法を提供するものである。
(1)複数相構造を有するゲル状食品であって、前記複数相構造のうち一つの相に可逆的熱ゲル化剤を配合してなることを特徴とするゲル状食品。
(2)上述の(1)に記載のゲル状食品において、前記可逆的熱ゲル化剤が酵素処理タマリンドシードガムであることを特徴とするゲル状食品。
(3)上述の(1)または(2)に記載のゲル状食品において、当該ゲル状食品が低温から高温になるに従い、前記可逆的熱ゲル化剤を配合してなる相がゾルからゲルに変化する
ことを特徴とするゲル状食品。
(4)上述の(3)に記載のゲル状食品において、当該ゲル状食品がさらに高温になるに従い、前記可逆的熱ゲル化剤を配合してなる相がゲルからゾルに変化することを特徴とするゲル状食品。
(5)上述の(3)または(4)に記載のゲル状食品において、前記可逆的熱ゲル化剤を低温度帯で配合して溶解した場合、当該ゲル状食品が低温から高温になるに従い、20℃以上70℃以下の温度で前記可逆的熱ゲル化剤を配合してなる相がゾルからゲルに変化し、かつ、当該ゲル状食品がさらに高温になるに従い、75℃以上95℃以下の温度で前記可逆的熱ゲル化剤を配合してなる相がゲルからゾルに変化することを特徴とするゲル状食品。
(6)上述の(3)または(4)に記載のゲル状食品において、前記可逆的熱ゲル化剤を高温度帯で配合して溶解した場合、当該ゲル状食品が低温から高温になるに従い、15℃以上45℃以下の温度で前記可逆的熱ゲル化剤を配合してなる相がゾルからゲルに変化し、かつ、当該ゲル状食品がさらに高温になるに従い、50℃以上95℃以下の温度で前記可逆的熱ゲル化剤を配合してなる相がゲルからゾルに変化することを特徴とするゲル状食品。
(7)複数相構造を有するゲル状食品の製造方法であって、ゲル化性溶液を充填する第1充填工程と、前記工程後に可逆的熱ゲル化剤を配合してなる溶液を充填する第2充填工程と、充填された前記両溶液を冷却する冷却工程とを備えることを特徴とするゲル状食品の製造方法。
(8)上述の(7)に記載のゲル状食品の製造方法において、前記第2充填工程における前記可逆的熱ゲル化剤を配合してなる溶液の温度が0℃以上90℃以下であることを特徴とするゲル状食品の製造方法。
(9)上述の(7)に記載のゲル状食品の製造方法において、前記第2充填工程における前記可逆的熱ゲル化剤を低温度帯で溶解することを特徴とするゲル状食品の製造方法。
(10)上述の(7)に記載のゲル状食品の製造方法において、前記第2充填工程における前記可逆的熱ゲル化剤を高温度帯で溶解することを特徴とするゲル状食品の製造方法。(11)上述の(9)に記載のゲル状食品の製造方法において、前記第2充填工程における前記可逆的熱ゲル化剤を5℃以下で溶解することを特徴とするゲル状食品の製造方法。(12)上述の(10)に記載のゲル状食品の製造方法において、前記第2充填工程における前記可逆的熱ゲル化剤を120℃以上で溶解することを特徴とするゲル状食品の製造方法。
In order to solve the above problems, the present invention provides the following gel food and a method for producing the same.
(1) a gelled food product having a plurality phase structure, gelled food product, characterized in that by blending a reversible thermal gelation agent to the multi-phase structure sac Chi one phase.
(2) The gel food as described in (1) above, wherein the reversible thermal gelling agent is enzyme-treated tamarind seed gum.
(3) In the gel food described in (1) or (2) above, the phase formed by blending the reversible thermal gelling agent is changed from sol to gel as the gel food increases from low temperature to high temperature. Gel-like food characterized by changing.
(4) The gel food according to (3) above, wherein the phase formed by blending the reversible thermal gelling agent changes from gel to sol as the gel food further increases in temperature. A gel food.
(5) In the gel food as described in (3) or (4) above, when the reversible thermal gelling agent is blended and dissolved in a low temperature zone, as the gel food goes from low temperature to high temperature The phase formed by blending the reversible thermal gelling agent at a temperature of 20 ° C. or higher and 70 ° C. or lower changes from sol to gel, and as the gel food further increases in temperature, 75 ° C. or higher and 95 ° C. or lower. A gel-like food characterized in that the phase formed by blending the reversible thermal gelling agent at a temperature changes from gel to sol.
(6) In the gel food as described in (3) or (4) above, when the reversible thermal gelling agent is blended and dissolved in a high temperature zone, the gel food is changed from a low temperature to a high temperature. The phase formed by blending the reversible thermal gelling agent at a temperature of 15 ° C. or higher and 45 ° C. or lower changes from sol to gel, and as the gel food further increases in temperature, 50 ° C. or higher and 95 ° C. or lower. A gel-like food characterized in that the phase formed by blending the reversible thermal gelling agent at a temperature changes from gel to sol.
(7) A method for producing a gel-like food having a multiphase structure, the first filling step of filling a gelling solution, and the first filling step of filling a solution formed by blending a reversible thermal gelling agent after the step. The manufacturing method of the gel-like food characterized by including the 2 filling process and the cooling process which cools both the said filled solutions.
(8) In the method for producing a gel food described in (7) above, the temperature of the solution formed by blending the reversible thermal gelling agent in the second filling step is 0 ° C. or higher and 90 ° C. or lower. A method for producing a gel food characterized by the above.
(9) The method for producing a gelled food according to (7), wherein the reversible thermal gelling agent in the second filling step is dissolved in a low temperature zone. .
(10) The method for producing a gelled food according to (7), wherein the reversible thermal gelling agent in the second filling step is dissolved in a high temperature zone. . (11) The method for producing a gelled food according to (9), wherein the reversible thermal gelling agent in the second filling step is dissolved at 5 ° C. or less. . (12) The method for producing a gelled food according to (10), wherein the reversible thermal gelling agent in the second filling step is dissolved at 120 ° C. or higher. .

本発明によれば、明確な複数相構造からなり全体としてゲル状でありながら、少なくとも一つの相については温度によりゾル−ゲル変化を可逆的に制御し得るゲル状食品およびその簡便な製造方法を提供できる。   According to the present invention, there is provided a gel-like food having a clear multi-phase structure as a whole and a gel-like food capable of reversibly controlling a sol-gel change by temperature for at least one phase and a simple production method thereof. Can be provided.

本実施形態におけるゲル状食品の例1(ゲル状食品を上から見た図および断面図を示した図である。以下同様である)Example 1 of gel food in the present embodiment (a diagram showing a gel food viewed from above and a cross-sectional view thereof; the same applies hereinafter) 本実施形態におけるゲル状食品の例2Example 2 of gel food in this embodiment 本実施形態におけるゲル状食品の例3Example 3 of gel food in this embodiment 本実施形態におけるゲル状食品の例4Example 4 of gel food in this embodiment 本実施形態におけるゲル状食品の例5Example 5 of gel food in this embodiment 本実施形態におけるゲル状食品の例6Example 6 of gel food in this embodiment 本実施形態におけるゲル状食品の例7Example 7 of gel food in this embodiment 本実施形態におけるゲル状食品の例8Example 8 of gel food in this embodiment 本実施形態におけるゲル状食品の例9Example 9 of gel food in this embodiment 本実施形態におけるゲル状食品の例10Example 10 of gel food in this embodiment 本実施形態におけるゲル状食品の例11Example 11 of gel food in this embodiment 本実施形態におけるゲル状食品の例12Example 12 of gel food in this embodiment 本実施形態におけるゲル状食品の例13(底面から見た図も含む。)Example 13 of gelled food in the present embodiment (including a view seen from the bottom)

以下、本発明のゲル状食品およびその製造方法について詳細に説明する。
〔ゲル状食品の構成〕
本発明のゲル状食品は、複数相構造を有し、この複数相構造のうち少なくとも一つが可逆的熱ゲル化剤を配合してなる相からなる。
このような複数相構造を有するゲル状食品としては、ゲル状物からなるマトリックス相中にゾル状物(流動食品)が分散した構造でもよく、ゲル状物同士からなる構造でもよい。分散相としては、塊状でも層状でもよい。
Hereinafter, the gel food of the present invention and the production method thereof will be described in detail.
[Composition of gel food]
The gel food of the present invention has a multi-phase structure, and at least one of the multi-phase structures is composed of a phase formed by blending a reversible thermal gelling agent.
The gel food having such a multi-phase structure may have a structure in which a sol (fluid food) is dispersed in a matrix phase made of a gel, or a structure made of gels. The dispersed phase may be a block or a layer.

本発明におけるゲル状食品の具体的な複数相構造としては、例えば図1から図13までに示すように種々の態様が挙げられる。具体的には、ゲル状あるいはゾル状からなる第1相1の内部に、ゲル状あるいはゾル状の第2相2が内包されているもの(例えば、図1)、水玉様として配置されているもの(例えば、図2、図12)、規則的に縦・横に配置されているもの(例えば、図3、図4、図7、図13)、上下に積層されているもの(例えば、図8、図9、図10)、マーブル状に配置されているもの(例えば、図5、図6、図11)などや、他に、第1相1の表面に第2相2により模様が描かれているものなどが挙げられる。なお、これらの分散構造は2種類の相に限られず、3種類以上の相からなるものであってもよい。   Specific examples of the multiphase structure of the gel food according to the present invention include various modes as shown in FIGS. Specifically, a gel-like or sol-like second phase 2 is encapsulated inside the first phase 1 made of gel or sol (for example, FIG. 1), and arranged as a polka dot. (For example, FIG. 2 and FIG. 12), regularly arranged vertically and horizontally (for example, FIG. 3, FIG. 4, FIG. 7, and FIG. 13), and stacked one above the other (for example, FIG. 8, 9, 10), those arranged in a marble shape (for example, FIGS. 5, 6, and 11), and others, and a pattern is drawn by the second phase 2 on the surface of the first phase 1 And the like. These dispersed structures are not limited to two types of phases, and may be composed of three or more types of phases.

上述した第1相1をゲル状物とした具体例として、プリン、ゼリー、ムース、ババロア、ヨーグルト、酸性プリン、飲むプリン、飲むゼリー、およびドリンクヨーグルトなどが挙げられる。また、第2相2をゾル状物(流動食品)とした具体例として、カラメルソース、フルーツソース、コーヒーソース、チョコソース、ココアソース、クリーム、ホイップクリーム、練乳、ジャム、シロップ、コーヒー、紅茶、牛乳、緑茶、抹茶、ウーロン茶、ココア飲料、果汁、果汁入りミルク、および炭酸飲料などが挙げられる。
第2相2の中に可逆的ゲル化剤を含有させると、温度により容易に第2相2をゲル化したり、またもとのゾル状物(流動食品)に戻したりすることができる。
Specific examples of the above-described first phase 1 in the form of a gel include pudding, jelly, mousse, bavaroa, yogurt, acidic pudding, drinking pudding, drinking jelly, and drink yogurt. Specific examples of the second phase 2 as a sol (fluid food) include caramel sauce, fruit sauce, coffee sauce, chocolate sauce, cocoa sauce, cream, whipped cream, condensed milk, jam, syrup, coffee, tea, Examples include milk, green tea, matcha tea, oolong tea, cocoa beverages, fruit juice, milk with fruit juice, and carbonated beverages.
When a reversible gelling agent is contained in the second phase 2, the second phase 2 can be easily gelled or returned to the original sol (fluid food) depending on the temperature.

なお、上述したゲル状食品には、果実、さのう、ハーブ、野菜、チーズ、飴、チョコレート、およびその他の固形物が含まれていてもよい。
このようなゲル状食品を食する際は、スプーンを用いるだけでなく、その性状に応じて容器の開口部から直接飲用したり、あるいはストローにより吸引してもよい。
In addition, the above-mentioned gel food may contain fruit, sao, herbs, vegetables, cheese, strawberries, chocolate, and other solid substances.
When eating such a gel food, not only a spoon may be used, but it may be taken directly from the opening of the container or sucked with a straw depending on its properties.

上述の可逆的熱ゲル化剤としては、温度によるゲル化・ゾル化の制御の容易性から酵素処理タマリンドシードガムが好適である。
本発明で用いられる酵素処理タマリンドシードガムは、低温度帯でゾル状態、中温度帯でゲル状態、高温度帯でゾル状態を示すものである。酵素処理タマリンドシードガムとしては、側鎖ガラクトースの除去率が30質量%以上65質量%以下のものが好ましく、より好ましくは35質量%以上45質量%以下である。側鎖ガラクトースの除去率が30質量%未満であると、ゾル−ゲル変化が起こりにくくなるおそれがあり、また、側鎖ガラクトースの除去率が65質量%を超えてもゾル−ゲル変化が起こりにくくなるおそれがある。
As the above-mentioned reversible thermal gelling agent, an enzyme-treated tamarind seed gum is suitable because of the ease of control of gelation and solification by temperature.
The enzyme-treated tamarind seed gum used in the present invention exhibits a sol state at a low temperature zone, a gel state at a medium temperature zone, and a sol state at a high temperature zone. The enzyme-treated tamarind seed gum preferably has a side chain galactose removal rate of 30% by mass to 65% by mass, more preferably 35% by mass to 45% by mass. If the removal rate of the side chain galactose is less than 30% by mass, the sol-gel change may not easily occur, and even if the removal rate of the side chain galactose exceeds 65% by mass, the sol-gel change hardly occurs. There is a risk.

また、酵素処理タマリンドシードガムのような可逆的熱ゲル化剤を溶解した相の性質は、溶解処理を上述した低温度帯で行うか高温度帯で行うかによって異なる。
本発明のゲル状食品としては、低温度帯で溶解した可逆的熱ゲル化剤を用いた場合、当該ゲル状食品が低温から高温になるに従い、20℃以上70℃以下の温度で前記可逆的熱ゲル化剤を配合してなる相がゾルからゲルに変化することが好ましい。また、当該ゲル状食品がさらに高温になるに従い、75℃以上95℃以下の温度で前記可逆的熱ゲル化剤を配合してなる相がゲルからゾルに変化することが好ましい。
酵素処理タマリンドシードガムを用いた場合、併せて配合する他のゲル化剤や増粘剤の種類や配合量によって、酵素処理タマリンドシートガムを溶解する温度は異なるが、5℃以下の低温で溶解することが好ましい。
Moreover, the property of the phase which melt | dissolved the reversible thermogelling agent like an enzyme treatment tamarind seed gum changes with whether it performs in a low temperature zone mentioned above, or a high temperature zone.
As the gel food of the present invention, when a reversible thermal gelling agent dissolved in a low temperature zone is used, the reversible heat treatment is performed at a temperature of 20 ° C. or more and 70 ° C. or less as the gel food is changed from low temperature to high temperature. It is preferable that the phase formed by blending the thermal gelling agent changes from sol to gel. Moreover, it is preferable that the phase which mix | blends the said reversible thermogelling agent at the temperature of 75 degreeC or more and 95 degrees C or less changes from gel to sol as the said gel-like food becomes still higher temperature.
When enzyme-treated tamarind seed gum is used, the temperature at which the enzyme-treated tamarind sheet gum is dissolved varies depending on the type and amount of other gelling agents and thickeners to be blended together, but dissolves at a low temperature of 5 ° C or less. It is preferable to do.

本発明のゲル状食品としては、高温度帯で溶解した可逆的熱ゲル化剤を用いた場合、当該ゲル状食品が低温から高温になるに従い、15℃以上45℃以下の温度で前記可逆的熱ゲル化剤を配合してなる相がゾルからゲルに変化することが好ましい。また、当該ゲル状食品がさらに高温になるに従い、50℃以上95℃以下の温度で前記可逆的熱ゲル化剤を配合してなる相がゲルからゾルに変化することが好ましい。
酵素処理タマリンドシードガムを用いた場合、併せて配合する他のゲル化剤や増粘剤の種類や配合量によって、酵素処理タマリンドシートガムを溶解する温度は異なるが、120℃以上の高温で溶解することが好ましい。このような高温であると短時間で溶解が可能となる。
なお、以下の説明では、可逆的ゲル化剤の低温度帯(高温度帯)における溶解を、単に「低温(高温)で溶解」のように記載する。
As the gel food of the present invention, when a reversible thermal gelling agent dissolved in a high temperature zone is used, the reversible heat treatment is performed at a temperature of 15 ° C. or higher and 45 ° C. or lower as the gel food increases from low temperature to high temperature. It is preferable that the phase formed by blending the thermal gelling agent changes from sol to gel. Moreover, it is preferable that the phase which mix | blends the said reversible thermogelling agent at the temperature of 50 degreeC or more and 95 degrees C or less changes from gel to sol as the said gelatinous food becomes still higher temperature.
When enzyme-treated tamarind seed gum is used, the temperature at which the enzyme-treated tamarind sheet gum is dissolved depends on the type and amount of other gelling agents and thickeners to be blended together, but dissolves at a high temperature of 120 ° C or higher. It is preferable to do. Such a high temperature enables dissolution in a short time.
In the following description, dissolution of a reversible gelling agent in a low temperature zone (high temperature zone) is simply described as “dissolution at a low temperature (high temperature)”.

このゾル−ゲル相転移温度は、基質の濃度および側鎖ガラクトース除去率により制御することができる。例えば、側鎖ガラクトースの除去率が40質量%の酵素処理タマリンドシードガムは、基質として2質量%のガラクトキシログルカン水溶液を用いて酵素反応により得ることができる。この酵素処理タマリンドシードガムを配合した相は、およそ30℃以下と90℃以上ではゾル状態となり、およそ30℃から90℃まではゲル状態を示す。側鎖ガラクトース除去率としては、30質量%以上65質量%以下が好ましく、特に35質量%以上45質量%以下がより好ましい。30質量%未満もしくは65質量%を超えると、相転換(ゾル−ゲルの逆転)が上手く起こらない場合があるからである。
なお、側鎖ガラクトースの除去率は、遊離のガラクトースの量をHPLC(高速液体クロマトグラフィー)で測定することにより算出することができる(Shirakawa.et.al., Food Hydrocolloids 12.1.25-28(1998))。
This sol-gel phase transition temperature can be controlled by the concentration of the substrate and the side chain galactose removal rate. For example, an enzyme-treated tamarind seed gum with a side chain galactose removal rate of 40% by mass can be obtained by enzymatic reaction using a 2% by mass galactoxyloglucan aqueous solution as a substrate. The phase in which the enzyme-treated tamarind seed gum is blended is in a sol state at about 30 ° C. or lower and 90 ° C. or higher, and shows a gel state from about 30 ° C. to 90 ° C. The side chain galactose removal rate is preferably 30% by mass to 65% by mass, and more preferably 35% by mass to 45% by mass. This is because if it is less than 30% by mass or exceeds 65% by mass, phase transformation (sol-gel reversal) may not occur well.
The removal rate of side chain galactose can be calculated by measuring the amount of free galactose by HPLC (High Performance Liquid Chromatography) (Shirakawa. Et.al., Food Hydrocolloids 12.1.25-28 (1998 )).

このような酵素処理タマリンドシードガムを配合する場合の配合量は、配合される相基準で、0.1質量%以上4質量%以下が好ましく、0.75質量%以上3質量%以下がより好ましい。酵素処理タマリンドシードガムの配合量が4質量%を超えると粘度が高くなりすぎて均一に溶解させることが困難となるおそれがある。一方、配合量が0.1質量%未満であるとゲル化の効果が十分に発揮されないおそれがある。   The blending amount in the case of blending such an enzyme-treated tamarind seed gum is preferably 0.1% by mass or more and 4% by mass or less, and more preferably 0.75% by mass or more and 3% by mass or less, based on the phase to be blended. . If the blending amount of the enzyme-treated tamarind seed gum exceeds 4% by mass, the viscosity becomes too high and it may be difficult to dissolve uniformly. On the other hand, if the blending amount is less than 0.1% by mass, the effect of gelation may not be sufficiently exhibited.

酵素処理タマリンドシードガムを配合する際は、併せて他のゲル化剤や増粘剤を配合してもよく、必要に応じて乳化剤を配合してもよい。
このようなゲル化剤や増粘剤としては特に限定されるものではなく、例えば、アルギン酸、アルギン酸ナトリウム、カルボキシメチルセルロースナトリウム、メチルセルロース、結晶セルロース、微小繊維状セルロース、発酵セルロース、ナタデココ、アラビアガム、ガティガム、カードラン、カラギナン、キサンタンガム、グァーガム、サイリウムシードガム、ジェランガム、タマリンドシードガム、タラガム、ペクチン、ダイズ多糖類、デンプン、加工デンプン(アセチル化アジピン酸架橋デンプン、アセチル化酸化デンプン、アセチル化リン酸架橋デンプン、オクテニルコハク酸デンプンナトリウム、酢酸デンプン、酸化デンプン、デンプングリコール酸ナトリウム、ヒドロキシプロピル化リン酸架橋デンプン、ヒドロキシプロピルデンプン、リン酸架橋デンプン、リン酸化デンプン、リン酸モノエステル化リン酸架橋デンプン)、寒天、ゼラチン、プルランおよびマンナンなどが挙げられる。
When blending the enzyme-treated tamarind seed gum, other gelling agents and thickeners may be blended together, and an emulsifier may be blended as necessary.
Such a gelling agent or thickener is not particularly limited. For example, alginic acid, sodium alginate, sodium carboxymethylcellulose, methylcellulose, crystalline cellulose, microfibrous cellulose, fermented cellulose, natadeco, gum arabic, gati gum , Curdlan, carrageenan, xanthan gum, guar gum, psyllium seed gum, gellan gum, tamarind seed gum, tara gum, pectin, soybean polysaccharide, starch, modified starch (acetylated adipic acid crosslinked starch, acetylated oxidized starch, acetylated phosphate crosslinked) Starch, starch sodium octenyl succinate, starch acetate, oxidized starch, sodium starch glycolate, hydroxypropylated phosphate cross-linked starch, hydroxypropylde Pung, phosphoric acid crosslinked starch, phosphorylated starch, phosphoric acid monoester phosphate-crosslinked starch), agar, gelatin, pullulan and mannan and the like.

乳化剤としては、例えば、キラヤ抽出物、グリセリン脂肪酸エステル(グリセリン酢酸脂肪酸エステル、グリセリン乳酸脂肪酸エステル、グリセリンクエン酸脂肪酸エステル、グリセリンコハク酸脂肪酸エステル、グリセリンジアセチル酒石酸脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、グリセリン酢酸エステル)、酵素処理レシチン、酵素分解レシチン、植物性ステロール、植物レシチン、ショ糖脂肪酸エステル、ステアロイル乳酸カルシウム、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、分別レシチン、卵黄レシチン、ポリソルベート20、ポリソルベート60、ポリソルベート65、およびポリソルベート80など一般に市販されているものが挙げられる。   Examples of emulsifiers include quilla extract, glycerol fatty acid ester (glycerol acetate fatty acid ester, glycerol lactate fatty acid ester, glycerol citrate fatty acid ester, glycerol succinate fatty acid ester, glycerol diacetyl tartaric acid fatty acid ester, polyglycerol fatty acid ester, polyglycerol condensation. (Ricinoleic acid ester, glycerin acetic acid ester), enzyme-treated lecithin, enzymatically decomposed lecithin, plant sterol, plant lecithin, sucrose fatty acid ester, calcium stearoyl lactate, sorbitan fatty acid ester, propylene glycol fatty acid ester, fractionated lecithin, egg yolk lecithin, polysorbate 20 , Polysorbate 60, polysorbate 65, and polysorbate 80, which are generally commercially available.

〔ゲル状食品の製造方法〕
本発明のゲル状食品の製造方法は、ゲル化性溶液を充填する第1充填工程と、前記工程後に前記可逆的熱ゲル化剤を配合してなる溶液を充填する第2充填工程と、充填された前記両溶液を冷却する冷却工程とを備えている。
例えば、図1から図13までに挙げたような相構造を有するゲル状食品を製造する場合、まず、第1相1となるゲル化性溶液(以下、「1液」ともいう。)と、第2相2となる溶液(酵素処理タマリンドシードガムを含んでいる。以下、「2液」ともいう)とを酵素処理タマリンドシードガムを用いる以外はゲル状食品を調製する一般的な方法に従って調製することができる。酵素処理タマリンドシードガムは低温にて溶解しても良いし、高温にて溶解してもよい。
次に、第1充填工程で所定の容器に1液を充填し、その後に第2充填工程で2液を充填する。本発明においては、1液を容器に充填後、いつでも2液を充填することができる。例えば、1液を充填した直後に2液を充填して直ちに冷却してもよい。それ故、本発明によれば、従来の複数相ゲル状食品の製造方法にくらべ製造時間を大幅に短縮することができるだけでなく、設備投資を節約できるので、大幅なコストダウンが可能となる。
[Method for producing gel food]
The method for producing a gel food according to the present invention includes a first filling step of filling a gelling solution, a second filling step of filling a solution obtained by blending the reversible thermal gelling agent after the step, and filling And a cooling step for cooling both of the solutions.
For example, when producing a gel-like food having a phase structure as shown in FIGS. 1 to 13, first, a gelling solution (hereinafter also referred to as “one solution”) that becomes the first phase 1, Prepared according to a general method for preparing a gel-like food, except that enzyme-treated tamarind seed gum is used as a solution for phase 2 (containing enzyme-treated tamarind seed gum, hereinafter also referred to as “part 2”). can do. The enzyme-treated tamarind seed gum may be dissolved at a low temperature or may be dissolved at a high temperature.
Next, one liquid is filled in a predetermined container in the first filling process, and then two liquids are filled in the second filling process. In the present invention, two liquids can be filled at any time after filling one liquid into a container. For example, two liquids may be filled immediately after filling one liquid and immediately cooled. Therefore, according to the present invention, not only can the production time be greatly shortened compared to the conventional method for producing a multi-phase gelled food product, but also the capital investment can be saved, so that the cost can be greatly reduced.

また、1液と2液の比重差、1液の充填時における1液の充填温度、2液の充填時における2液の充填温度、さらには2液の充填時における2液の充填速度を調整することにより、任意の複数相構造を得ることができる。
例えば、1液に比べて2液の比重が小さいほど2液は上部に分布し、2液の比重が大きいほど2液は下部に分布する。また、1液の充填時における1液の充填温度が低いほど2液は上部に分布し、1液の充填温度が高いほど2液は下部に分布する。2液の充填時における2液の充填温度が低いほど2液は上部に分布し、2液の充填時における2液の充填温度が高いほど2液は下部に分布する。2液の充填時における2液の充填速度が遅いほど2液は上部に分布し、2液の充填速度が速いほど2液は下部に分布する。
Also, the specific gravity difference between 1 and 2 liquids, 1 liquid filling temperature when filling 1 liquid, 2 liquid filling temperature when filling 2 liquids, and 2 liquid filling speed when filling 2 liquids are adjusted By doing so, an arbitrary multiphase structure can be obtained.
For example, the two liquids are distributed in the upper part as the specific gravity of the two liquids is smaller than that in the first liquid, and the two liquids are distributed in the lower part as the specific gravity of the two liquids is larger. Further, the lower the filling temperature of one liquid at the time of filling one liquid, the more the two liquids are distributed in the upper part, and the higher the filling temperature of the one liquid, the more the two liquids are distributed in the lower part. The lower the filling temperature of the two liquids when filling the two liquids, the two liquids are distributed in the upper part, and the higher the filling temperature of the two liquids when filling the two liquids, the lower the two liquids are distributed. The lower the filling speed of the two liquids when the two liquids are filled, the more the two liquids are distributed in the upper part, and the higher the filling speed of the two liquids, the more the two liquids are distributed in the lower part.

本発明では、2液の充填時における2液の温度は、0℃以上90℃以下であることが好ましい。この温度が90℃を超えると2液のしずくが再滴下して任意の形状になりにくくなるおそれがある。一方、この温度が0℃未満では、にじみを起こして模様が不明瞭になるおそれがある。   In this invention, it is preferable that the temperature of 2 liquid at the time of filling of 2 liquid is 0 degreeC or more and 90 degrees C or less. If this temperature exceeds 90 ° C., the drops of the two liquids may drop again and become difficult to have an arbitrary shape. On the other hand, if the temperature is less than 0 ° C., the pattern may become unclear due to bleeding.

本発明では、充填時の温度における1液の比重dと2液の比重dとの関係は、d−dが−0.004以上0.2以下であることが好ましく、−0.004以上0.06以下であることがより好ましい。d−dの値が0.2を超えると2液がわずかににじみ、模様が不明瞭となるおそれがある。一方、d−dの値−0.004未満であると2液がにじみ模様が不明瞭となるおそれがある。 In the present invention, the relationship between the temperature at the time of filling 1 solution of specific gravity d 1 and the specific gravity d 2 of 2 liquid, preferably d 2 -d 1 is 0.2 or less than -0.004, -0 More preferably, it is 0.004 or more and 0.06 or less. If the value of d 2 -d 1 exceeds 0.2, the two liquids may slightly blur and the pattern may become unclear. On the other hand, if the value of d 2 −d 1 is less than −0.004, the two liquids may be blurred.

本発明では、1液の充填時における1液の温度は、ゲル化温度以上であることが好ましい。ゲル化温度未満では、1液の充填直後に2液を充填すると2液がにじみ任意の形状としにくくなるおそれがある。
本発明では、2液の充填は、単孔ノズルでもよいが、多孔ノズルを用いて充填することがより好ましい。多孔ノズルを用いると2液のにじみを抑制できるので、2液を任意の形状とすることが容易であり好ましい。
In this invention, it is preferable that the temperature of 1 liquid at the time of filling of 1 liquid is more than a gelling temperature. Below the gelation temperature, if two liquids are filled immediately after the filling of one liquid, the two liquids may bleed and become difficult to have an arbitrary shape.
In the present invention, the filling of the two liquids may be a single-hole nozzle, but it is more preferable to use a multi-hole nozzle. If a multi-hole nozzle is used, bleeding of the two liquids can be suppressed. Therefore, it is easy and preferable to make the two liquids have any shape.

上述したように本発明によれば、各相の境界が明確な複数相構造を有するので、外観を損ねることなく、しかも、色彩、風味、食感ともに従来品より商品価値の高いゲル状食品を提供できる。しかも、本発明のゲル状食品は、簡便な方法で製造可能である。   As described above, according to the present invention, since the boundary of each phase has a clear multi-phase structure, a gel-like food having a higher commercial value than conventional products in terms of color, flavor, and texture is obtained without impairing the appearance. Can be provided. Moreover, the gel food of the present invention can be produced by a simple method.

以下、実施例により本発明をさらに詳細に説明するが、本発明はこれにより何ら限定されるものではない。
[実施例1]
<プリン/縦断内包フルーツソース>
(1液の調製)
パーム油5.0質量%、脱脂粉乳9.6質量%、糖類15.0質量%、乳化剤0.1質量%、ペクチン0.15質量%、デン粉0.4質量%、ゼラチン0.15質量%、および香料と着色料を若干量配合して温水に溶解して均質化した後、125℃で2秒間殺菌し、50℃に保持して1液を調製した。この1液の比重は1.061、ゲル化温度は50℃であった。
EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, this invention is not limited at all by this.
[Example 1]
<Pudding / longitudinal inclusion fruit sauce>
(Preparation of one solution)
Palm oil 5.0% by mass, skim milk powder 9.6% by mass, sugar 15.0% by mass, emulsifier 0.1% by mass, pectin 0.15% by mass, den powder 0.4% by mass, gelatin 0.15% by mass %, And some amounts of fragrances and coloring agents were mixed, dissolved in warm water and homogenized, sterilized at 125 ° C. for 2 seconds, and maintained at 50 ° C. to prepare one solution. The specific gravity of this one liquid was 1.061, and the gelation temperature was 50 ° C.

(2液の調製)
果汁10質量%、2℃の低温で3時間かけてあらかじめ溶解した酵素処理タマリンドシードガム2.0質量%、および若干量の香料と着色料と水を基本配合とし、糖類の組み合わせと配合量により充填温度における比重が1.081となるように調整して2液を調製した。2液は、85℃で20分間殺菌し、−2℃、0℃、10℃、90℃、95℃の5通りに分けて保持した。
(Preparation of two liquids)
10% by weight of fruit juice, 2.0% by weight of enzyme-treated tamarind seed gum dissolved in advance at a low temperature of 2 ° C. for 3 hours, and a slight amount of fragrance, colorant and water. Two liquids were prepared by adjusting the specific gravity at the filling temperature to 1.081. The two liquids were sterilized at 85 ° C. for 20 minutes, and kept in 5 different ways: −2 ° C., 0 ° C., 10 ° C., 90 ° C., and 95 ° C.

(1液および2液の充填)
1液を容器に90g充填し、多孔ノズルを用いて2液を1.1秒間で10g充填した。
充填後の容器を5℃に冷却後、ゲル状食品を上から見た場合および食品の上面に対し垂直方向に割った断面図の様子を目視にて観察した(図3参照)。なお、実施品は通常冷蔵状態(例えば、0℃以上20℃以下)で食するが、各相の状態を観察するため、冷蔵温度(5℃)および加温温度(本実施例のように、酵素処理タマリンドシードガムを低温溶解した場合は60℃、後述する実施例のように高温溶解した場合は40℃)で評価を行なった。
総合評価を以下の基準の通りに定め、結果を表1に示した。なお、後述する実施例でも同じ基準を用いた。
○:任意の複数相を有する形状であり、見た目にも美しい。
△:わずかなにじみがあり、模様が若干不明瞭である。
×:任意の複数相を有する形状にはならない。
(1 and 2 liquid filling)
90 g of 1 liquid was filled in a container, and 10 g of 2 liquids were filled in 1.1 seconds using a porous nozzle.
After cooling the container after filling to 5 ° C., the state of the gel food was observed from above and the state of the cross-sectional view perpendicular to the upper surface of the food was visually observed (see FIG. 3). The product is usually eaten in a refrigerated state (for example, 0 ° C. or more and 20 ° C. or less), but in order to observe the state of each phase, the refrigeration temperature (5 ° C.) and the heating temperature (as in this example, The evaluation was performed at 60 ° C. when the enzyme-treated tamarind seed gum was dissolved at a low temperature and 40 ° C. when it was dissolved at a high temperature as in the examples described later.
The overall evaluation was determined according to the following criteria, and the results are shown in Table 1. The same standard was used in the examples described later.
○: A shape having an arbitrary plurality of phases, which is also visually attractive.
Δ: Slight blurring and slightly unclear pattern.
X: It does not become a shape which has arbitrary multiple phases.

Figure 0005843460
Figure 0005843460

〔評価結果〕
冷蔵品(5℃)では、2液の充填時における2液の温度が−2℃の場合は、2液がわずかににじみ、模様が少し不明瞭であった。2液の温度が95℃の場合は、2液の再滴下により、食品の上面に2液が点々と載った状態であった。2液の充填時における2液の温度が0℃から90℃までであると、2液が界面に対し明確に分布しやすく、見た目にも特に美しい範囲であった。
加温品(60℃)でも冷蔵品(5℃)と同様に、2液の充填時における2液の温度が−2℃の場合は、2液がわずかににじみ、模様が少し不明瞭であった。また、2液の温度が95℃と高い場合は、2液の再滴下により食品の上面に2液が点々と載った状態であった。それ故、2液の充填時における2液の温度が、0℃から90℃までであると、2液が界面に対し垂直方向に分布し、見た目の美しさやおもしろさを与え、同時に複数の異なる食感や風味を味わうことができるのでより好ましいことがわかる。
〔Evaluation results〕
In the refrigerated product (5 ° C.), when the temperature of the two liquids at the time of filling the two liquids was −2 ° C., the two liquids slightly blotted and the pattern was slightly unclear. When the temperature of the two liquids was 95 ° C., the two liquids were put on the upper surface of the food by the re-dropping of the two liquids. When the temperature of the two liquids at the time of filling the two liquids was from 0 ° C. to 90 ° C., the two liquids were easily distributed clearly on the interface, and the range was particularly beautiful in appearance.
As with the refrigerated product (5 ° C), the warmed product (60 ° C) was slightly blurred and the pattern was slightly unclear when the temperature of the second solution was -2 ° C when filling with the second solution. It was. In addition, when the temperature of the two liquids was as high as 95 ° C., the two liquids were placed on the upper surface of the food by the dropwise addition of the two liquids. Therefore, if the temperature of the two liquids at the time of filling with the two liquids is from 0 ° C. to 90 ° C., the two liquids are distributed in the vertical direction with respect to the interface, giving an appearance beauty and fun, It turns out that it is more preferable because it can taste a different texture and flavor.

[実施例2]
<飲むプリン/水玉カラメルソース>
(1液の調製)
パーム油5.0質量%、脱脂粉乳9.6質量%、糖類15.0質量%、乳化剤0.1質量%、ペクチン0.05質量%、デン粉0.13質量%、ゼラチン0.05質量%、ジェランガム0.04質量%、クエン酸三ナトリウム0.01質量%、乳酸カルシウム0.02質量%、および香料と着色料を若干量配合して温水に溶解、均質化した後、125℃で2秒間殺菌し、70℃に保持して1液とした。1液の比重は1.071、ゲル化温度は50℃であった。
[Example 2]
<Drinking pudding / polka dot caramel sauce>
(Preparation of one solution)
Palm oil 5.0% by weight, skim milk powder 9.6% by weight, sugar 15.0% by weight, emulsifier 0.1% by weight, pectin 0.05% by weight, den powder 0.13% by weight, gelatin 0.05% by weight %, Gellan gum 0.04% by mass, trisodium citrate 0.01% by mass, calcium lactate 0.02% by mass, and a small amount of fragrance and colorant were mixed and dissolved in warm water, homogenized, and then at 125 ° C. Sterilized for 2 seconds and kept at 70 ° C. to make 1 solution. The specific gravity of one liquid was 1.071, and the gelation temperature was 50 ° C.

(2液の調製)
粉末カラメル0.4質量%、酵素処理タマリンドンードガム2.0質量%、および若干量の香料と着色料と水を基本配合とし、糖類の組み合わせと配合量により比重差(1液の比重dと2液の比重dとの差、d−d)について、−0.005、−0.004、0.036、0.060、0.20、および0.21の計6種類を設定し、各比重差を満たすように2液を調製した。2液は、125℃2秒間の高温で溶解と殺菌を行い、60℃に保持した。
(Preparation of two liquids)
Powdered caramel 0.4% by mass, enzyme-treated tamarin dondum gum 2.0% by mass, and a certain amount of flavor, colorant and water, and specific gravity difference (specific gravity d of one liquid d) For the difference between the specific gravity d 2 of 1 and 2 liquids, d 2 -d 1 ), a total of 6 types: -0.005, -0.004, 0.036, 0.060, 0.20, and 0.21 And two solutions were prepared so as to satisfy each specific gravity difference. The two liquids were dissolved and sterilized at a high temperature of 125 ° C. for 2 seconds and maintained at 60 ° C.

(1液および2液の充填)
次に、1液を容器に90g充填し、多孔ノズルを用いて2液を断続的に1.5秒間で10g充填した。冷却後中身を容器から取り出し、食品の上面に対し垂直方向に割り、目視にて界面の様子を観察した。同様に加温品も観察した(図12参照)。結果を表2に示した。
(1 and 2 liquid filling)
Next, 90 g of 1 liquid was filled in the container, and 10 g of 2 liquids were intermittently filled in 1.5 seconds using a porous nozzle. After cooling, the contents were taken out of the container, divided in a direction perpendicular to the upper surface of the food, and the appearance of the interface was visually observed. Similarly, warmed products were also observed (see FIG. 12). The results are shown in Table 2.

Figure 0005843460
Figure 0005843460

〔評価結果〕
冷蔵品(5℃)では、1液の比重dと2液の比重dとの差d−dが−0.005の場合は、2液が少しにじみ、模様がやや不明瞭であった。この比重差が0.21の場合も2液がわずかににじみ、模様がやや不明瞭であった。1液の比重と2液の比重差が−0.004から0.20までの範囲では、2液が水玉状にきれいに分布したものであった。さらに、この比重差が−0.004から0.06までの範囲である場合は、2液が水玉状で全体的に分布し、見た目にも特に美しいものであった。
〔Evaluation results〕
When the difference d 2 -d 1 between the specific gravity d 1 of the first liquid and the specific gravity d 2 of the second liquid is −0.005 in the refrigerated product (5 ° C.), the two liquids are slightly blurred and the pattern is slightly unclear. there were. When the specific gravity difference was 0.21, the two liquids were slightly blurred and the pattern was slightly unclear. In the range where the specific gravity difference between the first liquid and the second liquid was between -0.004 and 0.20, the two liquids were neatly distributed in a polka dot shape. Furthermore, when this specific gravity difference was in the range of -0.004 to 0.06, the two liquids were distributed in the form of polka dots and were particularly beautiful in appearance.

加温品(40℃)でも冷蔵品(5℃)と同様に、1液と2液の比重差が−0.005の場合は、2液が少しにじみ、模様がやや不明瞭であった。この比重差が0.21の場合も2液がわずかににじみ、模様がやや不明瞭であった。この比重差が−0.004から0.2までの範囲であると2液が水玉状にきれいに分布したものであった。さらに、この比重差が−0.004から0.06までの範囲であると、2液が水玉状で全体的に分布し、見た目にも特に美しいものであった。   In the case of the warmed product (40 ° C.), similarly to the refrigerated product (5 ° C.), when the difference in specific gravity between the first and second liquids was −0.005, the two liquids were slightly blurred and the pattern was slightly unclear. When the specific gravity difference was 0.21, the two liquids were slightly blurred and the pattern was slightly unclear. When this specific gravity difference was in the range of -0.004 to 0.2, the two liquids were neatly distributed in a polka dot shape. Furthermore, when this specific gravity difference is in the range of -0.004 to 0.06, the two liquids are distributed in a polka dot shape as a whole, and the appearance is particularly beautiful.

[実施例3]
<コーヒーゼリー/マーブル状クリーム>
(1液の調製)
インスタントコーヒー1.5質量%、ローカストビーンガム0.3質量%、カラギナン0.15質量%、ペクチン0.1質量%、ゼラチン0.1質量%、乳酸カルシウム0.02質量%、および若干量の香料と水を基本配合とし、糖類の組み合わせと配合量により充填温度における比重が1.088となるように調整して1液を調製した。1液は、均質化した後、110℃で2秒間殺菌し、35℃と50℃に保持した。得られた1液のゲル化温度は40℃であった。
[Example 3]
<Coffee jelly / Marble cream>
(Preparation of one solution)
1.5% by weight instant coffee, 0.3% by weight locust bean gum, 0.15% by weight carrageenan, 0.1% by weight pectin, 0.1% by weight gelatin, 0.02% by weight calcium lactate, and some amount One liquid was prepared by using a fragrance and water as a basic blend and adjusting the specific gravity at the filling temperature to 1.088 depending on the combination and blending amount of sugars. One liquid was homogenized, sterilized at 110 ° C. for 2 seconds, and maintained at 35 ° C. and 50 ° C. The gelation temperature of the obtained 1 liquid was 40 ° C.

(2液の調製)
精製パーム油30.0質量%を80℃まで加温した。これとは別に、脱脂粉乳1.0質量%、ミネラル濃縮ホエー1.0質量%、3℃の低温で3時間かけてあらかじめ溶解した酵素処理タマリンドシードガム2.0質量%、ゼラチン0.30質量%、グァーガム0.12質量%、キサンタンガム0.06質量%、糖類8.0質量%、ポリグリセリン脂肪酸エステル(HLB15)0.20質量%、グリセリン脂肪酸エステル0.30質量、クエン酸三ナトリウム0.30質量%、第二リン酸カリウム0.20質量%、および香料0.08質量%を水に添加、溶解して水相を調製し、65℃まで加温した。そして水相を撹拌しながら、加温した油相(上述のパーム油)を水相に添加し、予備乳化および均質化した後、120℃で2秒間殺菌し、その後再び均質化を行い、10℃まで急速冷却した。得られた2液の比重は1.098であった。
(Preparation of two liquids)
Refined palm oil 30.0 mass% was heated to 80 degreeC. Separately, skim milk powder 1.0% by mass, mineral concentrated whey 1.0% by mass, enzyme-treated tamarind seed gum 2.0% by mass preliminarily dissolved at 3 ° C. for 3 hours, gelatin 0.30% by mass %, Guar gum 0.12% by weight, xanthan gum 0.06% by weight, sugars 8.0% by weight, polyglycerol fatty acid ester (HLB15) 0.20% by weight, glycerol fatty acid ester 0.30% by weight, trisodium citrate 0. 30% by mass, dibasic potassium phosphate 0.20% by mass, and fragrance 0.08% by mass were added and dissolved in water to prepare an aqueous phase, which was heated to 65 ° C. Then, while stirring the aqueous phase, the heated oil phase (the above-mentioned palm oil) is added to the aqueous phase, pre-emulsified and homogenized, sterilized at 120 ° C. for 2 seconds, and then homogenized again. Cooled rapidly to ° C. The specific gravity of the obtained two liquids was 1.098.

(1液と2液の充填)
1液を容器に85g充填し、多孔ノズルを用いて2液を0.6秒間で15g充填した。5℃に冷却後中身を容器から取り出し、食品の上面に対し垂直方向に割り、目視にて界面の様子を観察した。同様に加温品(60℃)も観察した。図6参照。結果を表3に示した。
(1 and 2 liquid filling)
85 g of 1 liquid was filled in the container, and 15 g of 2 liquids were filled in 0.6 seconds using a porous nozzle. After cooling to 5 ° C., the contents were taken out of the container, divided in the direction perpendicular to the upper surface of the food, and the appearance of the interface was visually observed. Similarly, a warmed product (60 ° C.) was also observed. See FIG. The results are shown in Table 3.

Figure 0005843460
Figure 0005843460

〔評価結果〕
冷蔵品(5℃)では、1液の充填時における1液の温度が35℃の場合(ゲル化温度40℃より低い)、2液が容器壁面に流れてにじみ、任意の形状にはややなりにくかった。1液の充填時における1液の温度が50℃の場合(ゲル化温度40℃より高い)は、2液がマーブル状に分布し、見た目にも美しいものであった。
加温品(60℃)でも冷蔵品と同様に、1液の充填時における1液の温度が、ゲル化温度より低い場合は、2液が容器壁面に流れてにじみ、任意の形状にはややなりにくかった。1液の充填時における1液の温度が、ゲル化温度以上である場合は、2液がマーブル状に分布し、見た目にも美しいものであった。
〔Evaluation results〕
In a refrigerated product (5 ° C), when the temperature of one liquid at the time of filling with one liquid is 35 ° C (lower than the gelation temperature of 40 ° C), the two liquids flow on the container wall and bleed. It was difficult. When the temperature of one liquid at the time of filling with one liquid was 50 ° C. (higher than the gelation temperature of 40 ° C.), the two liquids were distributed in a marble shape, and the appearance was also beautiful.
In the case of a warmed product (60 ° C.), as in the case of a refrigerated product, when the temperature of one liquid at the time of filling one liquid is lower than the gelation temperature, the two liquids flow on the wall of the container and bleed. It was hard to become. When the temperature of one liquid at the time of filling with one liquid was equal to or higher than the gelation temperature, the two liquids were distributed in a marbled manner, and the appearance was also beautiful.

[実施例4]
<プリン/界面模様内包フルーツソース>
(1液の調製)
パーム油5.0質量%、脱脂粉乳9.6質量%、糖類15。0質量%、乳化剤0.1質量%、ペクチン0.15質量%、デン粉0.4質量%、ゼラチン0.15質量%、カラギナン0.04質量%、キサンタンガム0.05質量%、ローカストビーンガム0.1質量%、および香料と着色料を若干量配合して温水に溶解し、均質化した後、125℃で2
秒間殺菌し、55℃に保持した。得られた1液の比重は1.059、ゲル化温度は50℃であった。
[Example 4]
<Pudding / interface pattern inclusion fruit sauce>
(Preparation of one solution)
Palm oil 5.0% by weight, skim milk powder 9.6% by weight, sugar 15.0% by weight, emulsifier 0.1% by weight, pectin 0.15% by weight, den powder 0.4% by weight, gelatin 0.15% by weight %, Carrageenan 0.04% by weight, xanthan gum 0.05% by weight, locust bean gum 0.1% by weight, and some flavors and coloring agents were mixed and dissolved in warm water and homogenized.
Sterilized for 2 seconds and kept at 55 ° C. The specific gravity of the obtained 1 liquid was 1.059, and the gelation temperature was 50 ° C.

(2液の調製)
果汁10質量%、糖類20質量%、2℃の低温で3時間かけてあらかじめ溶解した酵素処理タマリンドシードガム2.0質量%、および酸味料と香料と着色料を若干量配合して温水に溶解し、分散させた後、85℃で20分間殺菌し、10℃に保持した。得られた2液の比重は1.084であった。
(Preparation of two liquids)
10% fruit juice, 20% sugar, 2% enzyme-treated tamarind seed gum dissolved in advance at a low temperature of 2 ° C. for 3 hours, and a small amount of sour, flavoring and coloring ingredients dissolved in warm water And then dispersed and sterilized at 85 ° C. for 20 minutes and kept at 10 ° C. The specific gravity of the obtained two liquids was 1.084.

(1液と2液の充填)
1液を容器に85g充填し、送液ポンプ自体の回転数を直接制御することで脈流させながら円周状に配置された孔径3mmの6孔ノズルを用いて2液を1.5秒間で15g充填した。別の容器に1液を85g充填し、送液ポンプ自体の回転数を直接制御することで脈流させながら単孔ノズルを用いて2液を1.5秒間で15g充填した。冷却後中身を容器から取り出し、食品の上面に対し垂直方向に割り、目視にて界面の様子を観察した。同様に加温品も観察した。図7参照。結果を表4に示した。
(1 and 2 liquid filling)
Fill the container with 85g of 1 liquid, and directly control the number of revolutions of the liquid feed pump itself, and pulsate the 2 liquids in 1.5 seconds using a 6-hole nozzle with a hole diameter of 3mm arranged circumferentially. 15 g was filled. One container was filled with 85 g of 1 liquid, and 15 g of 2 liquids were filled in 1.5 seconds using a single hole nozzle while pulsating by directly controlling the rotation speed of the liquid feed pump itself. After cooling, the contents were taken out of the container, divided in a direction perpendicular to the upper surface of the food, and the appearance of the interface was visually observed. Similarly, warmed products were also observed. See FIG. The results are shown in Table 4.

Figure 0005843460
Figure 0005843460

〔評価結果〕
冷蔵品(5℃)では、単孔ノズルでも任意の形状をとることはできるが、6孔ノズルを用いた場合のほうが、2液を充填すると2液が界面に大きな6つの円が分布し、見た目にも美しいものであった。
加温品(60℃)でも冷蔵品と同様に、単孔ノズルでも任意の形状をとることはできるが、6孔ノズルを用いた場合のほうが、2液を充填すると2液が界面に大きな6つの円が分布し、見た目にも美しいものであった。
〔Evaluation results〕
With a refrigerated product (5 ° C), even a single hole nozzle can take any shape, but when using a 6 hole nozzle, when two liquids are filled, two large liquids are distributed at the interface. It looked beautiful.
A heated product (60 ° C.) can take an arbitrary shape with a single-hole nozzle as well as a refrigerated product, but when a 6-hole nozzle is used, 2 liquids are larger at the interface when 2 liquids are filled. Two circles were distributed and looked beautiful.

[実施例5]
<プリン/縦断内包カラメルソース>
(1液の調製)
パーム油5.0質量%、脱脂粉乳9.6質量%、糖類15.0質量%、乳化剤0.1質量%、ペクチン0.15質量%、デン粉0.4質量%、ゼラチン0.15質量%、および香料と着色料を若干量配合して温水に溶解、均質化した後、120℃で2秒間殺菌し、50℃に保持した。得られた1液の比重は1.059、ゲル化温度は50℃であった。
[Example 5]
<Purin / Longitudinal inclusion caramel sauce>
(Preparation of one solution)
Palm oil 5.0% by mass, skim milk powder 9.6% by mass, sugar 15.0% by mass, emulsifier 0.1% by mass, pectin 0.15% by mass, den powder 0.4% by mass, gelatin 0.15% by mass %, And some amounts of fragrance and coloring were mixed, dissolved in warm water and homogenized, then sterilized at 120 ° C. for 2 seconds and kept at 50 ° C. The specific gravity of the obtained 1 liquid was 1.059, and the gelation temperature was 50 ° C.

(2液の調製)
粉末カラメル0.4質量%、糖類31.5質量%、安定剤を所定量、および香料を若干量配合して温水に溶解、分散した後、85℃で15分間殺菌し、10℃に保持した。得られた2液の比重は1.084であった。2液の安定剤は、酵素処理タマリンドシードガム2.0質量%使用したものとローカストビーンガム1.1質量%およびカラギナン0.05質量%を併用して使用したものの2を種調製した。
(Preparation of two liquids)
Powdered caramel 0.4% by mass, sugar 31.5% by mass, stabilizer in a predetermined amount, and some amount of flavoring were blended and dissolved and dispersed in warm water, then sterilized at 85 ° C. for 15 minutes and kept at 10 ° C. . The specific gravity of the obtained two liquids was 1.084. Two types of stabilizers were used, two of which were 2.0% by weight of enzyme-treated tamarind seed gum and 1.1% by weight of locust bean gum and 0.05% by weight of carrageenan.

(1液と2液の充填)
1液を容器に85g充填し、円周状に配置された孔径3mmで6孔の多孔ノズルを用いて2液を0.8秒間で15g充填した。冷却後中身を容器から取り出し、食品の上面に対し垂直方向に割り、目視にて界面の様子を観察した。同様に加温品も観察した(図3参照)。結果を表5に示した。
(1 and 2 liquid filling)
85 g of 1 liquid was filled in a container, and 15 g of 2 liquids were filled in 0.8 seconds using a 6-hole porous nozzle with a hole diameter of 3 mm arranged circumferentially. After cooling, the contents were taken out of the container, divided in a direction perpendicular to the upper surface of the food, and the appearance of the interface was visually observed. Similarly, warmed products were also observed (see FIG. 3). The results are shown in Table 5.

Figure 0005843460
Figure 0005843460

〔評価結果〕
2液中に酵素処理タマリンドシードガムを含まない場合、2液は冷蔵時(5℃)においては非常ににじみ、加温時(60℃)においては1液と混合した状態であった。
一方、2液中に酵素処理タマリンドンードガムを含む本発明の実施品では、5℃ではゲル中にゾルが不連続相として内包されており、これを60℃に加温すると形状を維持したまま相転換が起こり、ゾル中にゲルが不連続相として内包され、2液が界面に対し垂直方向に分布し、見た目にも美しいものであった。また、食する際には最初から最後までプリンとフルーツソースが同時に食せる形状であった。
〔Evaluation results〕
When the enzyme-treated tamarind seed gum was not included in the two liquids, the two liquids were very bleed when refrigerated (5 ° C.) and mixed with the first liquid when heated (60 ° C.).
On the other hand, in the product of the present invention containing the enzyme-treated tamarind gum in the two liquids, the sol was included as a discontinuous phase in the gel at 5 ° C, and the shape was maintained when this was heated to 60 ° C. The phase change occurred, the gel was included as a discontinuous phase in the sol, and the two liquids were distributed in a direction perpendicular to the interface, which was also beautiful. In addition, the pudding and fruit sauce can be eaten simultaneously from the beginning to the end when eating.

[実施例6]
<ゼリー/底面模様内包フルーツソース>
(1液の調製)
1液は、糖類18.0質量%、透明りんご果汁6.0質量%、キサンタンガム0.08質量%、ジェランガム0.07質量%、ローカストビーンガム0.02質量%、クエン酸三ナトリウム0.04質量%、乳酸カルシウム0.04質量%、および酸味料と香料を若干量配合して温水に溶解、均質化した後、110℃で2秒間保持して殺菌し、65℃に保持した。得られた1液の比重は1.061、ゲル化温度は55℃、pHは3.9であった。
[Example 6]
<Jelly / bottom-patterned fruit sauce>
(Preparation of one solution)
1 liquid is sugar 18.0 mass%, transparent apple fruit juice 6.0 mass%, xanthan gum 0.08 mass%, gellan gum 0.07 mass%, locust bean gum 0.02 mass%, trisodium citrate 0.04 A mass%, calcium lactate 0.04 mass%, and some sour and flavoring ingredients were blended, dissolved in warm water and homogenized, then held at 110 ° C. for 2 seconds to sterilize, and maintained at 65 ° C. The specific gravity of the obtained one liquid was 1.061, the gelation temperature was 55 ° C., and the pH was 3.9.

(2液の調製)
果汁10質量%、糖類20質量%、1℃の低温で3時間かけてあらかじめ溶解した側鎖ガラクトース除去率が35質量%および45質量%の酵素処理タマリンドシードガム1.0質量%、および酸味料と香料と着色料を若干量配合して温水に溶解、分散させた後、85℃で20分間殺菌し、25℃に保持した。得られた2液の比重は1.091であった。
(Preparation of two liquids)
10% by weight fruit juice, 20% by weight sugar, 1.0% by weight enzyme-treated tamarind seed gum with 35% by weight and 45% by weight side-chain galactose pre-dissolved at a low temperature of 1 ° C. over 3 hours, and acidulant A small amount of fragrance and colorant were mixed, dissolved and dispersed in warm water, sterilized at 85 ° C. for 20 minutes, and kept at 25 ° C. The specific gravity of the obtained two liquids was 1.091.

(1液と2液の充填)
1液を容器に90g充填し、多孔ノズルを用いて2液を0.6秒で10g充填した。冷却後中身を容器から取り出し、食品の上面に対し垂直方向に割り、目視にて界面の様子を観察した。同様に加温品も観察した(図13参照)。結果を表6に示した。
(1 and 2 liquid filling)
90 g of 1 liquid was filled in a container, and 10 g of 2 liquids were filled in 0.6 seconds using a porous nozzle. After cooling, the contents were taken out of the container, divided in a direction perpendicular to the upper surface of the food, and the appearance of the interface was visually observed. Similarly, warmed products were also observed (see FIG. 13). The results are shown in Table 6.

Figure 0005843460
Figure 0005843460

〔評価結果〕
側鎖ガラクトース除去率が35%と45%の酵素処理タマリンドシードガムを用いた2液は低温品(5℃)と加温品(60℃)において、ゾルーゲルが逆転した。また、2液がにじみもなく底面に6つの円が分布し、見た目にも美しいものであった。
〔Evaluation results〕
In the two liquids using the enzyme-treated tamarind seed gum with side chain galactose removal rates of 35% and 45%, the sol-gel was reversed between the low temperature product (5 ° C.) and the warm product (60 ° C.). In addition, the two liquids were not smeared and 6 circles were distributed on the bottom, which was also beautiful.

1…第1相(1液)
2…第2相(2液)
1 ... 1st phase (1 liquid)
2 ... 2nd phase (2 liquids)

Claims (12)

複数相構造を有するゲル状食品であって、
前記複数相構造のうち一つの相に可逆的熱ゲル化剤を配合してなる
ことを特徴とするゲル状食品。
A gel-like food having a multi-phase structure,
Gelled food product, characterized in that by blending a reversible thermal gelation agent to the multi-phase structure sac Chi one phase.
請求項1に記載のゲル状食品において、
前記可逆的熱ゲル化剤が酵素処理タマリンドシードガムである
ことを特徴とするゲル状食品。
In the gel food according to claim 1,
The gel food characterized in that the reversible thermal gelling agent is an enzyme-treated tamarind seed gum.
請求項1または請求項2に記載のゲル状食品において、
当該ゲル状食品が低温から高温になるに従い、前記可逆的熱ゲル化剤を配合してなる相がゾルからゲルに変化する
ことを特徴とするゲル状食品。
In the gel food according to claim 1 or 2,
A gel food, wherein the phase formed by blending the reversible thermal gelling agent changes from sol to gel as the gel food is changed from low temperature to high temperature.
請求項3に記載のゲル状食品において、
当該ゲル状食品がさらに高温になるに従い、前記可逆的熱ゲル化剤を配合してなる相がゲルからゾルに変化する
ことを特徴とするゲル状食品。
In the gel food according to claim 3,
As the gel food further increases in temperature, the phase formed by blending the reversible thermal gelling agent changes from gel to sol.
請求項3または請求項4に記載のゲル状食品において、
前記可逆的熱ゲル化剤を低温度帯で配合して溶解した場合、
当該ゲル状食品が低温から高温になるに従い、20℃以上70℃以下の温度で前記可逆的熱ゲル化剤を配合してなる相がゾルからゲルに変化し、かつ、
当該ゲル状食品がさらに高温になるに従い、75℃以上95℃以下の温度で前記可逆的熱ゲル化剤を配合してなる相がゲルからゾルに変化する
ことを特徴とするゲル状食品。
In the gel food according to claim 3 or 4,
When the reversible thermal gelling agent is blended and dissolved in a low temperature zone,
As the gel food is changed from low temperature to high temperature, the phase formed by blending the reversible thermal gelling agent at a temperature of 20 ° C. or higher and 70 ° C. or lower changes from sol to gel, and
As the gel food further increases in temperature, the phase formed by blending the reversible thermal gelling agent at a temperature of 75 ° C. or higher and 95 ° C. or lower changes from gel to sol.
請求項3または請求項4に記載のゲル状食品において、
前記可逆的熱ゲル化剤を高温度帯で配合して溶解した場合、
当該ゲル状食品が低温から高温になるに従い、15℃以上45℃以下の温度で前記可逆的熱ゲル化剤を配合してなる相がゾルからゲルに変化し、かつ、
当該ゲル状食品がさらに高温になるに従い、50℃以上95℃以下の温度で前記可逆的熱ゲル化剤を配合してなる相がゲルからゾルに変化する
ことを特徴とするゲル状食品。
In the gel food according to claim 3 or 4,
When the reversible thermal gelling agent is blended and dissolved in a high temperature zone,
As the gel food is changed from low temperature to high temperature, the phase formed by blending the reversible thermal gelling agent at a temperature of 15 ° C. or higher and 45 ° C. or lower changes from sol to gel, and
As the gel food further increases in temperature, a phase formed by blending the reversible thermal gelling agent at a temperature of 50 ° C. or higher and 95 ° C. or lower changes from gel to sol.
複数相構造を有するゲル状食品の製造方法であって、
ゲル化性溶液を充填する第1充填工程と、
前記工程後に可逆的熱ゲル化剤を配合してなる溶液を充填する第2充填工程と、
充填された前記両溶液を冷却する冷却工程とを備える
ことを特徴とするゲル状食品の製造方法。
A method for producing a gel food having a multiphase structure,
A first filling step of filling the gelling solution;
A second filling step of filling a solution comprising a reversible thermal gelling agent after the step;
And a cooling step for cooling both of the filled solutions. A method for producing a gel-like food, comprising:
請求項7に記載のゲル状食品の製造方法において、
前記第2充填工程における前記可逆的熱ゲル化剤を配合してなる溶液の温度が0℃以上90℃以下である
ことを特徴とするゲル状食品の製造方法。
In the manufacturing method of the gel food of Claim 7,
The temperature of the solution formed by blending the reversible thermal gelling agent in the second filling step is 0 ° C or higher and 90 ° C or lower.
請求項7に記載のゲル状食品の製造方法において、
前記第2充填工程における前記可逆的熱ゲル化剤を低温度帯で溶解する
ことを特徴とするゲル状食品の製造方法。
In the manufacturing method of the gel food of Claim 7,
The reversible thermal gelling agent in the second filling step is dissolved in a low temperature zone.
請求項7に記載のゲル状食品の製造方法において、
前記第2充填工程における前記可逆的熱ゲル化剤を高温度帯で溶解する
ことを特徴とするゲル状食品の製造方法。
In the manufacturing method of the gel food of Claim 7,
The reversible thermal gelling agent in the second filling step is dissolved in a high temperature zone.
請求項9に記載のゲル状食品の製造方法において、
前記第2充填工程における前記可逆的熱ゲル化剤を5℃以下で溶解する
ことを特徴とするゲル状食品の製造方法。
In the manufacturing method of the gel-like food of Claim 9,
The reversible thermal gelling agent in the second filling step is dissolved at 5 ° C. or less.
請求項10に記載のゲル状食品の製造方法において、
前記第2充填工程における前記可逆的熱ゲル化剤を120℃以上で溶解する
ことを特徴とするゲル状食品の製造方法。
In the manufacturing method of the gel food of Claim 10,
The reversible thermal gelling agent in the second filling step is dissolved at 120 ° C. or higher.
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