JP5827029B2 - Easy dispersible granular whitener - Google Patents

Easy dispersible granular whitener Download PDF

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JP5827029B2
JP5827029B2 JP2011088466A JP2011088466A JP5827029B2 JP 5827029 B2 JP5827029 B2 JP 5827029B2 JP 2011088466 A JP2011088466 A JP 2011088466A JP 2011088466 A JP2011088466 A JP 2011088466A JP 5827029 B2 JP5827029 B2 JP 5827029B2
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whitener
easily dispersible
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dispersible granular
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JP2012217419A (en
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五味 俊一
俊一 五味
考一 野田
考一 野田
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Asahi Kasei Chemicals Corp
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本発明は水や温水に分散させて飲食する易分散性粒状ホワイトナーに関する。   The present invention relates to an easily dispersible granular whitener that is dispersed in water or warm water to eat and drink.

食品素材を加工処理して、例えばクリーム類の粉末状のコーヒーホワイトナーとし、コーヒーに分散させて飲食する場合、コーヒーホワイトナー中の脂質成分が高い。従来、この問題点を解決するために、乳製品とポリデキストロースを粉末化、乳蛋白や大豆蛋白を使用し植物油脂他を加えて粉末化などの方法を、単独もしくは複数組み合わせて用いられてきた。   When the food material is processed into a powdered coffee whitener such as a cream, and is dispersed in coffee to eat and drink, the lipid component in the coffee whitener is high. Conventionally, in order to solve this problem, methods such as pulverization of dairy products and polydextrose, pulverization using milk protein or soybean protein and addition of vegetable oils and fats, etc., have been used singly or in combination. .

例えば、特許文献1では乳製品とフルクタン類やポリデキストロースと共乾燥することで、得られた粉末を用いた食品組成物の口当たり、テクスチャーおよび味覚を改善する粉末が開示され、ホワイトナーとして使用できることが開示されている。   For example, Patent Document 1 discloses a powder that improves the mouthfeel, texture and taste of a food composition using the obtained powder by co-drying with a dairy product and fructans or polydextrose, and can be used as a whitener Is disclosed.

一方、脂質を減らした粒状食品を水や温水に投入する場合の分散性を改善し、投入した食品のホワイトニング性を改善する方法はほとんど知られていない。   On the other hand, there are few known methods for improving the dispersibility when a granular food with reduced lipids is added to water or warm water, and improving the whitening property of the input food.

特開平10−179025号公報Japanese Patent Laid-Open No. 10-179025

これまでの技術で、脂質を減らした粒状物をホワイトナーに使用する方法は上述の通り開示されている。しかし、特許文献1に記載されているポリデキストロースと共乾燥した粉末では、水や温水に分散させた場合の分散性が低く、またホワイトニング性が低いという問題があった。   As described above, a method of using a granule with reduced lipids in a whitener by the conventional technology has been disclosed. However, the powder co-dried with polydextrose described in Patent Document 1 has a problem of low dispersibility when dispersed in water or warm water and low whitening property.

本発明は、水や温水に分散させて飲食する易分散性粒状ホワイトナーを提供することを目的とする。   An object of this invention is to provide the easily dispersible granular whitener which disperse | distributes to water and warm water, and to eat and drink.

本発明者らは、前記課題を解決するために鋭意検討した結果、食品衛生法で規定される増粘安定剤を含む微結晶セルロース製剤と食品衛生法で使用可能な白色剤を用いることにより、蛋白素材を含有する粒状ホワイトナーの水への分散性を改善し、ホワイトニング性を改善することを見出し、本発明を成すに至った。すなわち本発明は下記の通りである。   As a result of intensive studies to solve the above problems, the present inventors have used a microcrystalline cellulose preparation containing a thickening stabilizer defined by the Food Sanitation Law and a whitening agent usable in the Food Sanitation Law, It has been found that the granular whitener containing a protein material is improved in water dispersibility and whitening properties are improved, and the present invention has been achieved. That is, the present invention is as follows.

(1)蛋白素材を5〜30質量%を含有し、増粘安定剤を含む微結晶セルロース製剤(固形分)を0.3〜10質量%、白色剤を0.2〜30質量%を含有することを特徴とする易分散性粒状ホワイトナー。
(2)増粘安定剤が天然添加物である、(1)に記載の易分散性粒状ホワイトナー。
(3)増粘安定剤を含む微結晶セルロース製剤が易分散性である、(1)または(2)に記載の易分散性粒状ホワイトナー。
(4)さらに部分アルファー化澱粉(固形分)を1〜30質量%を含有することを特徴とする、(1)〜(3)のいずれか一つに記載の易分散性粒状ホワイトナー。
(5)さらに糖アルコール(固形分)を0.5〜15質量%含有することを特徴とする、(1)〜(4)のいずれか一つに記載の易分散性粒状ホワイトナー。
(1) Contains 5 to 30% by mass of protein material, 0.3 to 10% by mass of microcrystalline cellulose preparation (solid content) containing a thickening stabilizer, and 0.2 to 30% by mass of white agent Easily dispersible granular whitener.
(2) The easily dispersible granular whitener according to (1), wherein the thickening stabilizer is a natural additive.
(3) The easily dispersible granular whitener according to (1) or (2), wherein the microcrystalline cellulose preparation containing a thickening stabilizer is easily dispersible.
(4) The easily dispersible granular whitener according to any one of (1) to (3), further comprising 1 to 30% by mass of partially pregelatinized starch (solid content).
(5) The easily dispersible granular whitener according to any one of (1) to (4), further comprising 0.5 to 15% by mass of a sugar alcohol (solid content).

本発明により、水や温水への分散性に優れ、直ぐに沈殿物を発生せず、投入した食品のホワイトニング性を改善する易分散性粒状ホワイトナーを提供できる。   According to the present invention, it is possible to provide an easily dispersible granular whitener that is excellent in dispersibility in water and warm water, does not immediately generate precipitates, and improves the whitening properties of the input food.

以下、本発明につき詳しく説明する。
本発明のホワイトナーは、蛋白素材、増粘安定剤を含む微結晶セルロース製剤、白色剤を含有する。
Hereinafter, the present invention will be described in detail.
The whitener of the present invention contains a protein material, a microcrystalline cellulose preparation containing a thickening stabilizer, and a whitening agent.

本発明で言う蛋白素材とは、食用で使用されるものであればよく、蛋白質を主成分とする動物性蛋白素材、植物性蛋白素材であってもよい。蛋白素材に含有する脂質は少ない方が好ましい。例えば、カゼイン類、乳清蛋白分離物、乳蛋白濃縮物等の乳蛋白、大豆蛋白は好ましい例であり、これらを単独、または複数組み合わせて使用することも好ましい例である。   The protein material said by this invention should just be used by edible, and may be an animal protein material and a vegetable protein material which have protein as a main component. It is preferable that the protein material contains less lipid. For example, caseins, whey protein isolate, milk protein such as milk protein concentrate, and soy protein are preferable examples, and the use of these alone or in combination is also a preferable example.

蛋白素材の配合量(固形分)は、5〜30質量%であり、好ましくは10〜25質量%、さらに好ましくは15〜25質量%である。5質量%未満では、味覚上、ホワイトナーとしての風味が弱くなるので好ましくない。30質量%を超える場合、易分散性粒状ホワイトナーの分散性が悪化するため好ましくない。   The amount (solid content) of the protein material is 5 to 30% by mass, preferably 10 to 25% by mass, and more preferably 15 to 25% by mass. If it is less than 5% by mass, the taste as a whitener is weak in terms of taste, which is not preferable. When it exceeds 30 mass%, since the dispersibility of an easily dispersible granular whitener deteriorates, it is not preferable.

本発明で使用する微結晶セルロース製剤とは、例えば木材パルプ、精製リンターなどのセルロース系素材を、酸加水分解、アルカリ酸化分解、酵素分解などにより解重合処理して得られる平均重合度30〜400、結晶性部分が10%を超える微結晶セルロースと増粘安定剤とを複合体化したものをいう。本発明で言う増粘安定剤としては、食品衛生法で定義される食品添加物のうち、例えば、カラヤガム、キサンタンガム、カルボキシメチルセルロースナトリウム(CMC−Na)などが挙げられる。好ましくは天然添加物の増粘安定剤であり、特に粘稠性が適度となり、口当たりもよい点でカラヤガム、キサンタンガムが好ましい。配合量は特に規定しないが、1〜20%が好ましく、2〜13%が更に好ましい範囲である。
さらに、再分散性の補助剤としてデキストリンが入っていることが好ましい。
The microcrystalline cellulose preparation used in the present invention is, for example, an average degree of polymerization of 30 to 400 obtained by depolymerizing cellulose materials such as wood pulp and refined linter by acid hydrolysis, alkaline oxidation decomposition, enzyme decomposition, and the like. , Which is a composite of microcrystalline cellulose with a crystalline part exceeding 10% and a thickening stabilizer. Examples of the thickening stabilizer referred to in the present invention include karaya gum, xanthan gum, sodium carboxymethylcellulose (CMC-Na) and the like among food additives defined by the Food Sanitation Law. A thickening stabilizer for natural additives is preferable, and Karaya gum and xanthan gum are particularly preferable in terms of a moderate consistency and good mouthfeel. The blending amount is not particularly specified, but is preferably 1 to 20%, and more preferably 2 to 13%.
Furthermore, it is preferable that dextrin is contained as a redispersible auxiliary agent.

微結晶セルロース製剤の具体例としては、セオラスRC−N81(商品名、旭化成ケミカルズ株式会社製)、セオラスRC−N30(商品名、旭化成ケミカルズ株式会社製)、セオラスDX−2(商品名、旭化成ケミカルズ株式会社製)、セオラスRC−591(商品名、旭化成ケミカルズ株式会社製)などが挙げられる。   As specific examples of the microcrystalline cellulose preparation, Theolas RC-N81 (trade name, manufactured by Asahi Kasei Chemicals Corporation), Theolas RC-N30 (trade name, manufactured by Asahi Kasei Chemicals Corporation), Theolas DX-2 (trade name, Asahi Kasei Chemicals) Co., Ltd.), Theolas RC-591 (trade name, manufactured by Asahi Kasei Chemicals Corporation), and the like.

本発明の易分散性粒状ホワイトナーの分散性を向上させるためには、平均粒径が10μm以下である易分散性の微結晶セルロース製剤を用いることが好ましい。本発明で言う平均粒径は、具体的な測定方法は実施例に記載しているが、セルロース換算で1質量%の分散液となるように一般的な1〜2Lのステンレスビーカーに、微結晶セルロース製剤及び脱イオン水を、攪拌が十分できる量、例えば、2Lビーカーに1500mlを仕込み、半径30〜40mmの4枚パドル翼を取り付けたプロペラ攪拌機を用いて25℃、500rpmで20分間、水に分散させた場合の平均粒径のことを言う。例えばセオラスDX−2(商品名、旭化成ケミカルズ株式会社製)が、このような平均粒径10μm以下の要件を満たした微結晶セルロース製剤である。微結晶セルロース製剤の粒径は、強力な攪拌機、例えばエースホモジナイザー(日本精機製AM−T)などにより、10000回転/分以上の回転数で5分程度分散した粒径をさすことが多いが、この条件は非常に強い分散条件であるため、易分散性粒状ホワイトナーを水や温水に分散させる際にかかる攪拌力よりも遥かに強いものである。よって上記測定方法に準じて測定した平均粒径10μm以下の易分散性の微結晶セルロース製剤を易分散性粒状ホワイトナーに配合することは、分散性の改善に好ましい。   In order to improve the dispersibility of the easily dispersible granular whitener of the present invention, it is preferable to use an easily dispersible microcrystalline cellulose preparation having an average particle size of 10 μm or less. The average particle size referred to in the present invention is described in the Examples as a specific measuring method, but in a general 1-2 L stainless steel beaker, microcrystals are obtained so that a dispersion of 1% by mass in terms of cellulose is obtained. Sufficient stirring of cellulose preparation and deionized water, for example, 1500 ml in a 2 L beaker and using a propeller stirrer equipped with 4 paddle blades with a radius of 30 to 40 mm in water at 25 ° C. and 500 rpm for 20 minutes It means the average particle size when dispersed. For example, Theolas DX-2 (trade name, manufactured by Asahi Kasei Chemicals Corporation) is a microcrystalline cellulose preparation that satisfies the requirement of such an average particle size of 10 μm or less. The particle size of the microcrystalline cellulose preparation often refers to a particle size dispersed for about 5 minutes at a rotation speed of 10,000 rotations / minute or more by a powerful stirrer such as ACE homogenizer (AM-T manufactured by Nippon Seiki). Since this condition is a very strong dispersion condition, it is much stronger than the stirring force applied when dispersing the easily dispersible granular whitener in water or warm water. Therefore, it is preferable to improve the dispersibility to blend an easily dispersible microcrystalline cellulose preparation having an average particle diameter of 10 μm or less measured according to the above measuring method into an easily dispersible granular whitener.

微結晶セルロース製剤(固形分)の配合量は、0.3〜10質量%であり、好ましくは1〜8質量%、さらに好ましくは2〜7質量%である。0.3質量%未満では易分散性粒状ホワイトナーの分散性が不足し、の沈殿物が発生しやすくなり、白濁10質量%を超えると分散液が粘稠になり食感を損なうため好ましくない。   The compounding quantity of a microcrystalline cellulose formulation (solid content) is 0.3-10 mass%, Preferably it is 1-8 mass%, More preferably, it is 2-7 mass%. If the amount is less than 0.3% by mass, the dispersibility of the easily dispersible granular whitener is insufficient, and a precipitate is easily generated. If the amount exceeds 10% by mass, the dispersion becomes viscous and the texture is impaired, which is not preferable. .

易分散性粒状ホワイトナーに微結晶セルロース製剤を含有させる方法は、特に限定はないが、微結晶セルロース製剤が偏在しないようにすることは、必要である。食品素材と予め混合し、結合液を噴霧しながら造粒する方法は好ましい方法の一つである。   The method for incorporating the microcrystalline cellulose preparation into the easily dispersible granular whitener is not particularly limited, but it is necessary to prevent the microcrystalline cellulose preparation from being unevenly distributed. A method of pre-mixing with a food material and granulating while spraying the binding liquid is one of the preferred methods.

本発明でいう白色剤とは、食用で使用されるものであればよく、無機物、有機物であってもよい。無機部の例である二酸化チタン、有機物の例である難消化性澱粉は好ましい例である。
難消化性澱粉の例としては、アミロジェル(商品名、三和澱粉工業株式会社製)が挙げられる。
The whitening agent referred to in the present invention is not limited as long as it is used for food, and may be inorganic or organic. Titanium dioxide, which is an example of an inorganic part, and resistant starch, which is an example of an organic substance, are preferable examples.
Examples of the resistant starch include amylogel (trade name, manufactured by Sanwa Starch Co., Ltd.).

白色剤の配合量は、0.2〜30質量%であり、好ましくは1〜25質量%、さらに好ましくは7〜20質量%である。0.2質量%未満では、易分散性粒状ホワイトナーのホワイトニング性が劣るため好ましくない。30質量%を越える場合、易分散性粒状ホワイトナーを投入した食品の沈殿物が多くなるため、好ましくない。   The compounding quantity of a white agent is 0.2-30 mass%, Preferably it is 1-25 mass%, More preferably, it is 7-20 mass%. If it is less than 0.2% by mass, the whitening property of the easily dispersible granular whitener is inferior. If it exceeds 30% by mass, the amount of precipitates in the food containing the easily dispersible granular whitener increases, which is not preferable.

また、本発明では部分アルファー化澱粉を微結晶セルロース製剤と併用すると、より分散性が向上するため好ましい。部分アルファー化澱粉(固形分)を1〜30質量%配合することが好ましい。より好ましくは3〜25質量%、さらに好ましくは5〜20質量%である。1質量%以上の場合は分散性向上効果がより向上し、30質量%以下の場合はその他の食品素材の配合量が適度となるので好ましい。   In the present invention, it is preferable to use partially pregelatinized starch in combination with the microcrystalline cellulose preparation because dispersibility is further improved. It is preferable to blend 1-30% by mass of partially pregelatinized starch (solid content). More preferably, it is 3-25 mass%, More preferably, it is 5-20 mass%. When the content is 1% by mass or more, the effect of improving dispersibility is further improved, and when the content is 30% by mass or less, the amount of other food materials to be blended is preferable.

ここでいう部分アルファー化澱粉とは、澱粉を湿熱処理により部分的にアルファー化したものである。その原料は特に制限はなく、とうもろこし澱粉、小麦澱粉、米澱粉、馬鈴薯澱粉などいずれの澱粉原料でもよい。部分アルファー化澱粉のなかでも、外殻薄膜構造が残ったものが好ましい。具体的には冷水可溶分が6質量%以下のものが好ましい。冷水可溶分が6質量%以下のとき、糊成分の流出が少なく、良好な食感を維持できる。   The partially pregelatinized starch as used herein is a product obtained by partially pregelatinizing starch by wet heat treatment. The raw material is not particularly limited, and any starch raw material such as corn starch, wheat starch, rice starch, and potato starch may be used. Among the partially pregelatinized starches, those in which the outer shell thin film structure remains are preferable. Specifically, those having a cold water soluble content of 6% by mass or less are preferable. When the cold water soluble content is 6% by mass or less, there is little outflow of the paste component, and a good texture can be maintained.

また、本発明では糖アルコールを微結晶セルロース製剤と併用すると、より分散性が向上するため好ましい。易分散性粒状ホワイトナー(固形分)100質量%のうち、糖アルコール(固形分)を0.5〜15質量%配合することが好ましい。より好ましくは、1〜10質量%である。糖アルコール(固形分)の配合が、0.5質量%以上の場合は分散性向上効果がより向上し、15質量%以下の場合はその他の食品素材の配合量が適度となるので好ましい。   In the present invention, it is preferable to use sugar alcohol together with the microcrystalline cellulose preparation because dispersibility is further improved. Of 100% by mass of the easily dispersible granular whitener (solid content), 0.5 to 15% by mass of sugar alcohol (solid content) is preferable. More preferably, it is 1-10 mass%. When the amount of the sugar alcohol (solid content) is 0.5% by mass or more, the effect of improving dispersibility is further improved, and when the amount is 15% by mass or less, the amount of other food materials to be mixed is preferable.

糖アルコールの種類に特に制限はないが、溶解度が高く、吸湿性の低い糖アルコールが好ましい。例えば、ソルビトール、トレハロースは好ましい例である。   Although there is no restriction | limiting in particular in the kind of sugar alcohol, A sugar alcohol with high solubility and low hygroscopicity is preferable. For example, sorbitol and trehalose are preferable examples.

本発明の易分散性粒状ホワイトナーは、コーヒーや紅茶のホワイトナーやシチューのホワイトナーとして使用される。   The easily dispersible granular whitener of the present invention is used as a whitener for coffee or tea or a stew whitener.

実施例により本発明をさらに具体的に説明するが、これらによって本発明は何ら制限されるものではない。なお、測定及び評価は以下の通りに行った。   The present invention will be described more specifically with reference to examples, but the present invention is not limited to these examples. Measurement and evaluation were performed as follows.

<微結晶セルロース製剤の平均粒径[μm]>
(1)固形分濃度が1%、総量1300〜1700mlの水分散液となるようにサンプルと純水を2Lステンビーカーに量り取り、汎用攪拌翼かい十字(半径35mm)を取り付けたプロペラ攪拌機(スリーワンモーターHEIDON(商品名)BL−600)を用いて25℃、500rpmで20分間分散した。
(2)レーザー回折散乱装置((株)堀場製作所製 LA−910、超音波分散1分)により積算体積が50%になる値(メジアン径)を読み取り、平均粒径とした。
<Average particle size of microcrystalline cellulose preparation [μm]>
(1) A propeller stirrer (three-one) equipped with a general-purpose stirring blade and cross (radius 35 mm) was weighed in a 2 L stainless steel beaker so that the aqueous dispersion had a solid content of 1% and a total amount of 1300 to 1700 ml. Motor HEIDON (trade name) BL-600) was dispersed at 25 ° C. and 500 rpm for 20 minutes.
(2) A value (median diameter) at which the integrated volume becomes 50% was read by a laser diffraction scattering apparatus (LA-910, manufactured by Horiba, Ltd., ultrasonic dispersion 1 minute) and used as an average particle diameter.

<易分散性粒状ホワイトナーの分散性>
インスタントコーヒー(商品名:ネスカフェゴールドブレンド、ネスレ日本(株)製)1.5gを98℃の温水100gに投入し、スプーンで撹拌し溶解させる。次いで、易分散性粒状ホワイトナー2.0gを投入し、スプーンで10秒間撹拌し、易分散性粒状ホワイトナーの分散性を以下の通り評価した。
○:速やかに分散し、分散性良好
△:分散するが未分散物が存在する
×:分散し難く、未分散物が多く存在し分散性不良
<Dispersibility of easily dispersible granular whitener>
Instant coffee (trade name: Nescafe Gold Blend, manufactured by Nestle Japan Co., Ltd.) (1.5 g) is added to 100 g of hot water at 98 ° C. and stirred to dissolve. Next, 2.0 g of the easily dispersible granular whitener was added and stirred with a spoon for 10 seconds, and the dispersibility of the easily dispersible granular whitener was evaluated as follows.
○: Dispersed quickly and good dispersibility △: Dispersed but undispersed material exists ×: Difficult to disperse, many undispersed materials exist and poor dispersibility

<易分散性粒状ホワイトナーのホワイトニング性>
(1)易分散性粒状ホワイトナーの分散性を評価した液を液中の未分散物がなくなるまでスプーンで撹拌した後、室温まで冷却した。
(2)冷却した液をスプーンで10秒間撹拌後、丸セル(直径35mm、高さ15mm)に6.5g投入し、直ちに分光色差計(日本電色工業(株)製、SE−2000、反射モード)で白色度を測定した。易分散性粒状ホワイトナーのホワイトニング性は、以下の式により求めた。
ホワイトニング性(−)=易分散性粒状ホワイトナーの白色度(−)−インスタントコーヒーの白色度(−)
<Whitening of easily dispersible granular whitener>
(1) The liquid which evaluated the dispersibility of an easily dispersible granular whitener was stirred with the spoon until there was no undispersed substance in the liquid, and then cooled to room temperature.
(2) After stirring the cooled liquid with a spoon for 10 seconds, 6.5 g was put into a round cell (diameter 35 mm, height 15 mm), and a spectral color difference meter (SE-2000, manufactured by Nippon Denshoku Industries Co., Ltd., reflection) Mode). The whitening property of the easily dispersible granular whitener was determined by the following formula.
Whitening property (-) = Whiteness of easily dispersible granular whitener (-)-Whiteness of instant coffee (-)

[製造例1]
60℃の温水10kgを用意し、軽く攪拌しながら、微結晶性セルロース80質量%とカラヤガム10質量%とデキストリン10質量%からなる乾燥状態のセルロース複合体(商品名:セオラスRC−N81、旭化成ケミカルズ(株)製)を1.35kg加えた後、分散助剤として、デキストリン(商品名:パインデックス#3、松谷化学工業(株)製)1.65kgを加え、さらに20分間攪拌した。この分散溶解液を高圧ホモジナイザー(APV社製)を用いて15MPaの圧力で2パスして混合処理したのち、スプレードライヤーを用いて入り口温度が90〜100℃、出口温度が70〜80℃の条件で噴霧乾燥して、易分散性の微結晶セルロース製剤Aを得た。この微結晶セルロース製剤Aは、分散助剤を加えて高圧ホモジナイザーで処理し、スプレードライで乾燥しているので、非常に分散し易い微結晶セルロース製剤である。微結晶セルロース製剤Aの平均粒径は8.0μmであった。
[Production Example 1]
Prepare 10 kg of warm water at 60 ° C., and with light agitation, dry cellulose composite consisting of 80% by weight of microcrystalline cellulose, 10% by weight of Karaya gum and 10% by weight of dextrin (trade name: Theolas RC-N81, Asahi Chemical Chemicals After adding 1.35 kg (manufactured by Co., Ltd.), 1.65 kg of dextrin (trade name: Paindex # 3, manufactured by Matsutani Chemical Industry Co., Ltd.) was added as a dispersion aid, and the mixture was further stirred for 20 minutes. After this dispersion solution was mixed by two passes at a pressure of 15 MPa using a high-pressure homogenizer (manufactured by APV), an inlet temperature was 90-100 ° C. and an outlet temperature was 70-80 ° C. using a spray dryer. Was spray-dried to obtain an easily dispersible microcrystalline cellulose preparation A. This microcrystalline cellulose preparation A is a microcrystalline cellulose preparation that is very easy to disperse because it is treated with a high-pressure homogenizer after adding a dispersion aid and dried by spray drying. The average particle size of the microcrystalline cellulose preparation A was 8.0 μm.

[製造例2]
60℃の温水10kgを用意し、軽く攪拌しながら、微結晶性セルロース75質量%とキサンタンガム5質量%とデキストリン20質量%からなる乾燥状態のセルロース複合体(商品名:セオラスRC−N30、旭化成ケミカルズ(株)製)を1.2kg加えた後、分散助剤として、デキストリン(商品名:パインデックス#3、松谷化学工業(株)製)1.8kgを加え、さらに20分間攪拌した。この分散溶解液を高圧ホモジナイザーを用いて15MPaの圧力で2パスして混合処理したのち、スプレードライヤーを用いて入り口温度が90〜100℃、出口温度が70〜80℃の条件で噴霧乾燥して、易分散性の微結晶セルロース製剤Bを得た。この微結晶セルロース製剤Bは、分散助剤を加えて高圧ホモジナイザーで処理し、スプレードライで乾燥しているので、非常に分散し易い微結晶セルロース製剤である。微結晶セルロース製剤Bの平均粒径は7.3μmであった。
[Production Example 2]
Prepare 10 kg of warm water at 60 ° C. and stir lightly, and dry cellulose composite consisting of 75% by weight of microcrystalline cellulose, 5% by weight of xanthan gum and 20% by weight of dextrin (trade name: Theolas RC-N30, Asahi Chemical Chemicals After adding 1.2 kg of (manufactured by Co., Ltd.), 1.8 kg of dextrin (trade name: Paindex # 3, manufactured by Matsutani Chemical Co., Ltd.) was added as a dispersion aid, and the mixture was further stirred for 20 minutes. This dispersion / dissolution solution was mixed by two passes at a pressure of 15 MPa using a high-pressure homogenizer, and then spray-dried using a spray dryer under conditions of an inlet temperature of 90 to 100 ° C. and an outlet temperature of 70 to 80 ° C. An easily dispersible microcrystalline cellulose preparation B was obtained. This microcrystalline cellulose preparation B is a microcrystalline cellulose preparation that is very easy to disperse because it is treated with a high-pressure homogenizer after adding a dispersing aid and dried by spray drying. The average particle size of the microcrystalline cellulose preparation B was 7.3 μm.

[実施例1]
デキストリン(サンデック#300、三和澱粉工業(株)製)31.8質量%、乳蛋白(MPC480、フォンテラジャパン(株)製)20質量%、難消化性澱粉(商品名アミロジェルHB−450)20質量%、部分アルファー化澱粉(PCS FC−30、旭化成ケミカルズ製)10質量%、平均粒径7.2μmの微結晶セルロース製剤(セオラス DX−2(微結晶性セルロース36質量%とカラヤガム4.5質量%とデキストリン59.5質量%からなる乾燥状態の微結晶セルロース複合体)6質量%、シュガーエステル(商品名:リョートーシュガーエステルP−1670、三菱化学フーズ(株)製)4.64質量%、ソルビトール(物産フードサイエンス(株)製)1.8質量%の割合で固形分として471.2gをビニール袋に入れ、3分間混合した。この混合粉体を転動流動コーティング装置((株)パウレック製、「マルチプレックス」MP−01型)の流動層カラムを用いて、スプレーノズル径1.2mm、ノズル先端1mm出し、スプレー位置はトップ(中段セット)、スプレー圧力0.12MPa、スプレー流量30L/分、バグフィルター種はT−4000、バグフィルター払い落とし圧力0.65MPa、給気温度設定80℃、風量30〜50m/時、結合液投入速度12g/分の条件で造粒した。なお、混合粉体を造粒する際の結合液としては、ソルビトールとシュガーエステルの混合溶液180g(混合溶液中のソルビトールの固形分:27.0g、シュガーエステルの固形分:1.8g)噴霧後、造粒された混合粉体を排気温度が40℃になるまで乾燥させた。さらに、目開き:500μmの篩で篩過して粗大粒子を取り除き、易分散性粒状ホワイトナーAを得た。粗大粒子の割合は0.9%、水分は4.1%であった。
易分散性粒状ホワイトナーAは、分散性○、ホワイトニング性18.4であり、分散性、ホワイトニング性ともに良好だった。
[Example 1]
Dextrin (Sandek # 300, manufactured by Sanwa Starch Co., Ltd.) 31.8% by mass, milk protein (MPC480, manufactured by Fontera Japan Co., Ltd.) 20% by mass, resistant starch (trade name amylogel HB-450) 20 % By mass, partially pregelatinized starch (PCS FC-30, manufactured by Asahi Kasei Chemicals) 10% by mass, and microcrystalline cellulose preparation having an average particle size of 7.2 μm (Theorax DX-2 (36% by mass of microcrystalline cellulose and Karaya gum 4.5) 6% by mass of dried microcrystalline cellulose complex consisting of 5% by mass and 59.5% by mass of dextrin, 4.64% by mass of sugar ester (trade name: Ryoto Sugar Ester P-1670, manufactured by Mitsubishi Chemical Foods Co., Ltd.) %, 471.2 g of sorbitol (manufactured by Food Science Co., Ltd.) at 1.8% by mass as a solid content in a plastic bag This mixed powder was mixed for 3 minutes using a fluidized bed column of a tumbling fluidized coating apparatus ("Multiplex" MP-01, manufactured by POWREC Co., Ltd.). 1mm out, spray position top (middle set), spray pressure 0.12MPa, spray flow rate 30L / min, bag filter type T-4000, bag filter discharge pressure 0.65MPa, supply air temperature setting 80 ° C, air volume 30 Granulation was carried out at a rate of 12 g / min at a binding solution input speed of ˜50 m 3 / hour, and as a binding solution for granulating the mixed powder, 180 g of a mixed solution of sorbitol and sugar ester (sorbitol in the mixed solution) Solid content: 27.0 g, sugar ester solid content: 1.8 g) After spraying, the granulated mixed powder has an exhaust temperature of 40 ° C. Further, the sieve was sieved with a 500 μm sieve to remove coarse particles to obtain an easily dispersible granular whitener A. The proportion of coarse particles was 0.9%, and the water content was 4.1%. Met.
The easily dispersible granular whitener A had dispersibility ○ and whitening property 18.4, and both dispersibility and whitening property were good.

[実施例2]
デキストリンを21.8質量%、乳蛋白を20質量%、難消化性澱粉を20質量%、部分アルファー化澱粉を20質量%、DX−2を6質量%、シュガーエステルを4.82質量%、ソルビトール4.5質量%の割合で固形分として485.6gをビニール袋に入れ、3分間混合した。この混合粉体を造粒する際の結合液として、ソルビトールとシュガーエステルの混合溶液90g(混合溶液中のソルビトールの固形分:13.5g、シュガーエステルの固形分:0.9g)とした以外は、実施例1と同様に造粒し、易分散性粒状ホワイトナーBを得た。粗大粒子の割合は0.3%、水分は4.9%であった。
易分散性粒状ホワイトナーBは、分散性○、ホワイトニング性18.5であり、分散性、ホワイトニング性ともに良好だった。
[Example 2]
21.8% by mass of dextrin, 20% by mass of milk protein, 20% by mass of resistant starch, 20% by mass of partially pregelatinized starch, 6% by mass of DX-2, 4.82% by mass of sugar ester, 485.6 g of sorbitol as a solid content at a ratio of 4.5 mass% was put in a plastic bag and mixed for 3 minutes. As a binding liquid when granulating the mixed powder, 90 g of a mixed solution of sorbitol and sugar ester (solid content of sorbitol in the mixed solution: 13.5 g, solid content of sugar ester: 0.9 g) was used. Granulation was performed in the same manner as in Example 1 to obtain an easily dispersible granular whitener B. The proportion of coarse particles was 0.3%, and the water content was 4.9%.
The easily dispersible granular whitener B had dispersibility ○ and whitening property 18.5, and both dispersibility and whitening property were good.

[実施例3]
難消化性澱粉を10質量%、ソルビトール11.8質量%とした以外は、実施例1と同様に造粒し、易分散性粒状ホワイトナーCを得た。粗大粒子の割合は1.0%、水分は3.8%であった。
易分散性粒状ホワイトナーCは、分散性○、ホワイトニング性16.9であり、分散性、ホワイトニング性ともに良好だった。
[Example 3]
Easily dispersible granular whitener C was obtained in the same manner as in Example 1 except that the amount of resistant starch was changed to 10% by mass and 11.8% by mass of sorbitol. The proportion of coarse particles was 1.0%, and the water content was 3.8%.
The easily dispersible granular whitener C had dispersibility ○ and whitening property 16.9, and both dispersibility and whitening property were good.

[実施例4]
DX−2を微結晶セルロース製剤Aとした以外は、実施例1と同様に造粒し、易分散性粒状ホワイトナーDを得た。粗大粒子の割合は0.5%、水分は4.0%であった。
易分散性粒状ホワイトナーDは、分散性○、ホワイトニング性17.9であり、分散性、ホワイトニング性ともに良好だった。
[Example 4]
Except that DX-2 was changed to microcrystalline cellulose preparation A, granulation was performed in the same manner as in Example 1 to obtain an easily dispersible granular whitener D. The proportion of coarse particles was 0.5%, and the water content was 4.0%.
The easily dispersible granular whitener D had dispersibility ○ and whitening property of 17.9, and both dispersibility and whitening property were good.

[実施例5]
DX−2を微結晶セルロース製剤Bとした以外は、実施例1と同様に造粒し、易分散性粒状ホワイトナーEを得た。粗大粒子の割合は1.2%、水分は4.3%であった。
易分散性粒状ホワイトナーDは、分散性○、ホワイトニング性17.7であり、分散性、ホワイトニング性ともに良好だった。
[Example 5]
Except that DX-2 was changed to microcrystalline cellulose formulation B, granulation was performed in the same manner as in Example 1 to obtain an easily dispersible granular whitener E. The proportion of coarse particles was 1.2%, and the water content was 4.3%.
The easily dispersible granular whitener D had dispersibility ○ and whitening property of 17.7, and both dispersibility and whitening property were good.

[実施例6](参考例)
DX−2を製造例1で使用したRC−N81(微結晶セルロース製剤の平均粒径は約70μm)とした以外は、実施例1と同様に造粒し、易分散性粒状ホワイトナーFを得た。
粗大粒子の割合は0.6%、水分は3.8%であった。
易分散性粒状ホワイトナーFは、分散性△、ホワイトニング性16.4であり、分散性はほぼ良好であり、ホワイトニング性は良好だった。
[Example 6] (Reference Example)
Granulate in the same manner as in Example 1 except that DX- 2 is RC-N81 used in Production Example 1 (the average particle size of the microcrystalline cellulose preparation is about 70 μm) to obtain an easily dispersible granular whitener F. It was.
The proportion of coarse particles was 0.6%, and the water content was 3.8%.
The easily dispersible granular whitener F had a dispersibility Δ and a whitening property of 16.4. The dispersibility was almost good and the whitening property was good.

[実施例7](参考例)
DX−2を結晶性セルロース89質量%とカルボキシメチルセルロースナトリウム11質量%からなる乾燥状態のセルロース複合体(商品名:セオラスRC−591、旭化成ケミカルズ(株)製、微結晶セルロースの平均粒径は約35μm)とした以外は、実施例1と同様に造粒し、易分散性粒状ホワイトナーGを得た。粗大粒子の割合は1.1%、水分は4.2%であった。
易分散性粒状ホワイトナーGは、分散性△、ホワイトニング性15.7であり、分散性はほぼ良好であり、ホワイトニング性は良好だった。
[Example 7] (Reference Example)
DX-2 is a dried cellulose composite composed of 89% by mass of crystalline cellulose and 11% by mass of sodium carboxymethyl cellulose (trade name: Theorus RC-591, manufactured by Asahi Kasei Chemicals Co., Ltd., average particle size of microcrystalline cellulose is about Except that it was 35 μm), granulation was performed in the same manner as in Example 1 to obtain an easily dispersible granular whitener G. The ratio of coarse particles was 1.1%, and the water content was 4.2%.
The easily dispersible granular whitener G had a dispersibility Δ and a whitening property of 15.7. The dispersibility was almost good and the whitening property was good.

[実施例8]
デキストリンを51.55質量%、乳蛋白を20質量%、二酸化チタン(CR−97、石原産業(株)製)0.25質量%、部分アルファー化澱粉を10質量%、DX−2を6質量%、シュガーエステルを4.64質量%、ソルビトール1.8質量%の割合で固形分として471.2gとした以外は、実施例1と同様に造粒し、易分散性粒状ホワイトナーHを得た。粗大粒子の割合は1.5%、水分は4.4%であった。
易分散性粒状ホワイトナーHは、分散性○、ホワイトニング性16.7であり、分散性、ホワイトニング性ともに良好だった。
[Example 8]
Dextrin 51.55 wt%, milk protein 20 wt%, titanium dioxide (CR-97, manufactured by Ishihara Sangyo Co., Ltd.) 0.25 wt%, partially pregelatinized starch 10 wt%, DX-2 6 wt% %, Sugar ester was 4.64% by mass, and sorbitol was 1.8% by mass, and the solid content was changed to 471.2 g to obtain an easily dispersible granular whitener H. It was. The ratio of coarse particles was 1.5%, and the water content was 4.4%.
The easily dispersible granular whitener H had dispersibility ○ and whitening property 16.7, and both dispersibility and whitening property were good.

[実施例9]
デキストリンを50.8質量%、乳蛋白を20質量%、二酸化チタン(CR−97、石原産業(株)製)1質量%、部分アルファー化澱粉を10質量%、DX−2を6質量%、シュガーエステルを4.64質量%、ソルビトール1.8質量%の割合で固形分として471.2gとした以外は、実施例1と同様に造粒し、易分散性粒状ホワイトナーIを得た。粗大粒子の割合は1.3%、水分は4.0%であった。
易分散性粒状ホワイトナーIは、分散性○、ホワイトニング性21.8であり、分散性、ホワイトニング性ともに良好だった。
[Example 9]
Dextrin 50.8% by mass, milk protein 20% by mass, titanium dioxide (CR-97, manufactured by Ishihara Sangyo Co., Ltd.) 1% by mass, partially pregelatinized starch 10% by mass, DX-2 6% by mass, Easily dispersible granular whitener I was obtained in the same manner as in Example 1 except that the sugar ester was 4.64% by mass and sorbitol was 1.8% by mass, and the solid content was 471.2 g. The ratio of coarse particles was 1.3%, and the water content was 4.0%.
The easily dispersible granular whitener I had dispersibility ○ and whitening property 21.8, and both dispersibility and whitening property were good.

[実施例10](参考例)
デキストリンを53質量%、乳蛋白を20質量%、難消化性澱粉を20質量%、DX−2を6質量%の割合で固形分として495.0gをビニール袋に入れ、3分間混合した。この混合粉体を造粒する際の結合液として、デキストリン水溶液100g(混合溶液中のデキストリンの固形分:5g)とした以外は、実施例1と同様に造粒し、易分散性粒状ホワイトナーJを得た。粗大粒子の割合は1.8%、水分は4.6%であった。
易分散性粒状ホワイトナーJは、分散性△、ホワイトニング性17.1であり、分散性はほぼ良好であり、ホワイトニング性は良好だった。
[Example 10] (Reference Example)
Dextrin (53% by mass), milk protein (20% by mass), resistant starch (20% by mass) and DX-2 (solid content) at a ratio of 6% by mass were placed in a plastic bag and mixed for 3 minutes. An easily dispersible granular whitener was granulated in the same manner as in Example 1 except that 100 g of dextrin aqueous solution (solid content of dextrin in the mixed solution: 5 g) was used as a binding liquid when granulating this mixed powder. J was obtained. The proportion of coarse particles was 1.8%, and the water content was 4.6%.
The easily dispersible granular whitener J had dispersibility Δ and whitening property of 17.1, dispersibility was almost good, and whitening property was good.

[実施例11](参考例)
デキストリンを43質量%、乳蛋白を20質量%、難消化性澱粉を10質量%、部分アルファー化澱粉を20質量%、DX−2を6質量%の割合で固形分として495.0gとした以外は、実施例10と同様に造粒し、易分散性粒状ホワイトナーKを得た。粗大粒子の割合は1.8%、水分は4.6%であった。
易分散性粒状ホワイトナーKは、分散性△、ホワイトニング性17.5であり、分散性はほぼ良好であり、ホワイトニング性は良好だった。
[Example 11] (Reference Example)
Except for dextrin 43% by weight, milk protein 20% by weight, resistant starch 10% by weight, partially pregelatinized starch 20% by weight, DX-2 6% by weight as solid content 495.0g Was granulated in the same manner as in Example 10 to obtain an easily dispersible granular whitener K. The proportion of coarse particles was 1.8%, and the water content was 4.6%.
The easily dispersible granular whitener K had a dispersibility Δ and a whitening property of 17.5. The dispersibility was almost good and the whitening property was good.

[実施例12]
デキストリンを43.1質量%、乳蛋白を20質量%、難消化性澱粉を10質量%、部分アルファー化澱粉を10質量%、DX−2を2質量%、シュガーエステルを4.64質量%、ソルビトール4.5質量%の割合で固形分として471.2gとした以外は、実施例1と同様に造粒し、易分散性粒状ホワイトナーLを得た。粗大粒子の割合は0.8%、水分は4.0%であった。
易分散性粒状ホワイトナーLは、分散性○、ホワイトニング性17.0であり、分散性、ホワイトニング性ともに良好だった。
[Example 12]
Dextrin 43.1% by weight, milk protein 20% by weight, resistant starch 10% by weight, partially pregelatinized starch 10% by weight, DX-2 2% by weight, sugar ester 4.64% by weight, Granulation was performed in the same manner as in Example 1 except that the solid content was 471.2 g at a ratio of 4.5% by mass of sorbitol to obtain an easily dispersible granular whitener L. The proportion of coarse particles was 0.8%, and the water content was 4.0%.
The easily dispersible granular whitener L had dispersibility ○ and whitening property of 17.0, and both dispersibility and whitening property were good.

[比較例1]
デキストリンを51.8質量%、乳蛋白を20質量%、部分アルファー化澱粉を10質量%、DX−2を6質量%、シュガーエステルを4.64質量%、ソルビトール1.8質量%の割合で固形分として471.2gとした以外は、実施例1と同様に造粒し、粒状ホワイトナーMを得た。粗大粒子の割合は0.8%、水分は3.8%であった。
粒状ホワイトナーMは、分散性○、ホワイトニング性14.3であり、分散性は良好だが、ホワイトニング性が良好ではなかった。
[Comparative Example 1]
Dextrin 51.8% by mass, milk protein 20% by mass, partially pregelatinized starch 10% by mass, DX-2 6% by mass, sugar ester 4.64% by mass, sorbitol 1.8% by mass. Granular whitener M was obtained by granulation in the same manner as in Example 1 except that the solid content was 471.2 g. The proportion of coarse particles was 0.8%, and the water content was 3.8%.
The granular whitener M had dispersibility (circle) and whitening property 14.3, and dispersibility was good, but whitening property was not good.

[比較例2]
デキストリンを67.8質量%、乳蛋白を20質量%、シュガーエステルを4.64質量%、ソルビトール1.8質量%の割合で固形分として485.7gとした以外は、実施例1と同様に造粒し、粒状ホワイトナーNを得た。粗大粒子の割合は0.5%、水分は4.0%であった。
粒状ホワイトナーNは、分散性△、ホワイトニング性12.2であり、分散性はほぼ良好だが、直ぐに沈殿物を生じ、ホワイトニング性は良好ではなかった。
[Comparative Example 2]
Example 1 except that dextrin was 67.8% by weight, milk protein was 20% by weight, sugar ester was 4.64% by weight, and sorbitol was 1.8% by weight, and the solid content was 485.7 g. The granulated whitener N was obtained by granulation. The proportion of coarse particles was 0.5%, and the water content was 4.0%.
The granular whitener N had a dispersibility Δ and a whitening property of 12.2. Although the dispersibility was almost good, a precipitate was formed immediately and the whitening property was not good.

[比較例3]
デキストリンを37.8質量%、乳蛋白を20質量%、難消化性澱粉を10質量%、部分アルファー化澱粉を10質量%、シュガーエステルを4.64質量%、ソルビトール11.8質量%の割合で固形分として471.2gとした以外は、実施例1と同様に造粒し、粒状ホワイトナーOを得た。粗大粒子の割合は0.5%、水分は3.8%であった。
粒状ホワイトナーOは、分散性×、ホワイトニング性15.8であり、分散性は不良で、直ぐに沈殿を生じ、ホワイトニング性は良好だった。
[Comparative Example 3]
Ratio of 37.8% by weight of dextrin, 20% by weight of milk protein, 10% by weight of resistant starch, 10% by weight of partially pregelatinized starch, 4.64% by weight of sugar ester, and 11.8% by weight of sorbitol A granulated whitener O was obtained by granulation in the same manner as in Example 1 except that the solid content was 471.2 g. The proportion of coarse particles was 0.5%, and the water content was 3.8%.
The granular whitener O had dispersibility x and whitening property 15.8, and the dispersibility was poor, precipitation immediately occurred, and the whitening property was good.

[比較例4]
デキストリンを79質量%、乳蛋白を20質量%の割合で固形分として495gとした以外は、実施例10と同様に造粒し、粒状ホワイトナーPを得た。粗大粒子の割合は0.8%、水分は4.0%であった。
粒状ホワイトナーPは、分散性△、ホワイトニング性13.5であり、分散性はほぼ良好だが、直ぐに沈殿を生じ、ホワイトニング性は良好ではなかった。
[Comparative Example 4]
Granular whitener P was obtained in the same manner as in Example 10, except that 79% by mass of dextrin and 20% by mass of milk protein were used and the solid content was changed to 495 g. The proportion of coarse particles was 0.8%, and the water content was 4.0%.
The granular whitener P had a dispersibility Δ and a whitening property of 13.5, and the dispersibility was almost good. However, precipitation immediately occurred and the whitening property was not good.

[比較例5]
DX−2をポリデキストロース(商品名ライテス、ダニスコジャパン(株)製)に代えた以外は、実施例1と同様に造粒し、粒状ホワイトナーQを得た。粗大粒子の割合は1.8%、水分は4.3%であった。
粒状ホワイトナーQは、分散性×、ホワイトニング性15.1であり、分散性は不良で、直ぐに沈殿を生じ、ホワイトニング性は良好だった。
[Comparative Example 5]
Granular whitener Q was obtained by granulating in the same manner as in Example 1 except that DX-2 was replaced with polydextrose (trade name: Lites, manufactured by Danisco Japan Co., Ltd.). The ratio of coarse particles was 1.8%, and the water content was 4.3%.
The granular whitener Q had dispersibility x and whitening property of 15.1. The dispersibility was poor, precipitation immediately occurred, and the whitening property was good.

[比較例6]
デキストリンを11.12質量%、乳蛋白を50質量%、部分アルファー化澱粉を10質量%、DX−2を6質量%、難消化性澱粉を20質量%の割合で固形分として485.6gとした以外は、実施例2と同様に造粒し、粒状ホワイトナーRを得た。粗大粒子の割合は2.3%、水分は4.4%であった。
粒状ホワイトナーRは、スプーンで撹拌しても大きな未分散物がなくならず分散性×で、ホワイトニング性も評価できなかった。
[Comparative Example 6]
Dextrin 11.12% by mass, milk protein 50% by mass, partially pregelatinized starch 10% by mass, DX-2 6% by mass, resistant starch 20% by mass as a solid content of 485.6 g Except that, granulation was performed in the same manner as in Example 2 to obtain a granular whitener R. The ratio of coarse particles was 2.3%, and the water content was 4.4%.
Even when the granular whitener R was stirred with a spoon, a large undispersed material was not lost and the dispersibility x was not able to be evaluated.

本発明は粒状ホワイトナーを水や温水に分散させる場合の分散性を向上し、投入した食品のホワイトニング性を向上させるため、粒状ホワイトナーに好適に利用できる。 The present invention improves the dispersibility when the granular whitener is dispersed in water or warm water, and improves the whitening properties of the input food, and therefore can be suitably used for the granular whitener.

Claims (3)

蛋白素材を5〜30質量%を含有し、増粘安定剤を含む易分散性微結晶セルロース製剤(固形分)を0.3〜10質量%、白色剤を0.2〜30質量%、糖アルコール(固形分)を0.5〜15質量%を含有し、上記易分散性微結晶セルロース製剤が該セルロース製剤1質量%を純水中でプロペラ攪拌機を用いて25℃、500rpm、20分間分散させた水分散液においてレーザー回折散乱装置によって測定される平均粒径が10μm以下であることを特徴とする易分散性粒状ホワイトナー。 0.3 to 10% by mass of a readily dispersible microcrystalline cellulose preparation (solid content) containing 5 to 30% by mass of a protein material and containing a thickening stabilizer, 0.2 to 30% by mass of a white agent , sugar Alcohol (solid content) is contained in an amount of 0.5 to 15% by mass, and the above easily dispersible microcrystalline cellulose preparation disperses 1% by mass of the cellulose preparation in pure water using a propeller stirrer at 25 ° C. and 500 rpm for 20 minutes. An easily dispersible granular whitener having an average particle diameter measured by a laser diffraction scattering apparatus of 10 μm or less in a water dispersion liquid . 増粘安定剤が天然添加物である、請求項1に記載の易分散性粒状ホワイトナー。   The easily dispersible granular whitener according to claim 1, wherein the thickening stabilizer is a natural additive. さらに部分アルファー化澱粉(固形分)を1〜30質量%を含有することを特徴とする、請求項1または2に記載の易分散性粒状ホワイトナー。 Furthermore, 1-30 mass% of partially pregelatinized starch (solid content) is contained, The easily dispersible granular whitener of Claim 1 or 2 characterized by the above-mentioned.
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