JP5796993B2 - Antifouling / cleaning sheet - Google Patents
Antifouling / cleaning sheet Download PDFInfo
- Publication number
- JP5796993B2 JP5796993B2 JP2011091765A JP2011091765A JP5796993B2 JP 5796993 B2 JP5796993 B2 JP 5796993B2 JP 2011091765 A JP2011091765 A JP 2011091765A JP 2011091765 A JP2011091765 A JP 2011091765A JP 5796993 B2 JP5796993 B2 JP 5796993B2
- Authority
- JP
- Japan
- Prior art keywords
- antifouling
- cleaning
- cleaning sheet
- sheet
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000004140 cleaning Methods 0.000 title claims description 39
- 230000003373 anti-fouling effect Effects 0.000 title claims description 34
- 229930195733 hydrocarbon Natural products 0.000 claims description 30
- 150000002430 hydrocarbons Chemical class 0.000 claims description 28
- 239000004745 nonwoven fabric Substances 0.000 claims description 20
- 239000002904 solvent Substances 0.000 claims description 20
- 239000004215 Carbon black (E152) Substances 0.000 claims description 17
- -1 polyoxyethylene Polymers 0.000 claims description 15
- 239000004094 surface-active agent Substances 0.000 claims description 14
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 3
- 150000003973 alkyl amines Chemical class 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 239000002519 antifouling agent Substances 0.000 claims 1
- 239000003921 oil Substances 0.000 description 19
- 235000019198 oils Nutrition 0.000 description 19
- 239000000835 fiber Substances 0.000 description 7
- 239000002689 soil Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 229920000297 Rayon Polymers 0.000 description 4
- CYDRXTMLKJDRQH-UHFFFAOYSA-N benzododecinium Chemical compound CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 CYDRXTMLKJDRQH-UHFFFAOYSA-N 0.000 description 4
- 239000002964 rayon Substances 0.000 description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000002608 ionic liquid Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
- 241000047703 Nonion Species 0.000 description 2
- 241000282320 Panthera leo Species 0.000 description 2
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 229960001716 benzalkonium Drugs 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000011086 high cleaning Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000003021 water soluble solvent Substances 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004147 Sorbitan trioleate Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- HTDKEJXHILZNPP-UHFFFAOYSA-N dioctyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OCCCCCCCC HTDKEJXHILZNPP-UHFFFAOYSA-N 0.000 description 1
- 229960000878 docusate sodium Drugs 0.000 description 1
- 229940069096 dodecene Drugs 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229940075529 glyceryl stearate Drugs 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004750 melt-blown nonwoven Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
Description
本発明は、被清掃面の汚れを除去しやすく、かつ同時に防汚効果を付与することができるドライタイプの防汚・清掃用シート関する。 The present invention relates to a dry-type antifouling / cleaning sheet that can easily remove dirt on a surface to be cleaned and can simultaneously provide an antifouling effect.
従来より、汚れを除去する清掃用シートとしては、ウエットシートタイプやドライシートタイプなど様々な形状、材質のものが知られている。
ウエットシートタイプとしては様々なものがあり、特許文献１のガラス用洗浄シート及びガラス用洗浄シート物品では、レーヨン又はコットンの不織布に洗浄剤成分として界面活性剤及び親水性溶剤と防曇成分及び／又はアルカノールアミン及びアルカリ金属から選ばれる１種を含浸されたものが記載されている。また、特許文献２の清掃用不織布及び清掃用不織布物品は、スパンレース不織布に界面活性剤、水溶性溶剤及びアルカリ剤を含浸させたものが、硬表面の頑固な油汚れを従来の研磨性のあるスチールウール等による清掃方法にくらべて、傷つきの心配もなく、非常に少ない労力で簡便且つ効果的に清掃できることを示している。特許文献３の清掃用シート及びその製造方法では、水を使用する場所に設置してある家具、備品などに適する洗浄効果の高い清掃用シートとして、レーヨン繊維とポリエチレンテレフタレート繊維を含む不織布に、界面活性剤と多価アルコールを含む清掃剤を含有させたものが開示されている。特許文献４では、陰イオン界面活性剤又は非イオン界面活性剤からなる帯電防止剤及び陰イオン増粘剤又は非イオン増粘剤からなる増粘剤を含む水性洗浄剤を不織布に含浸したウエットタイプの清掃用シートが、静電気に起因する汚れの発生を防止することが示されている。しかし、これらのウエットタイプのシートは窓ガラスや網戸を拭き取った場合、一度拭き取った汚れが洗浄液によって被清掃面に押し出され、何度拭いても拭き取れず、拭きすじが残るという問題があり、清掃後に二度拭きする必要があった。
一方、ドライシートタイプとしては、特許文献５の清掃用払拭具があり、長繊維不織布に、親水性繊維と捲縮性合成繊維とからなる繊維ウェブが積層されてなるシートに、油剤成分と界面活性剤よりなるダストコントロール剤を担持させた清掃払拭具が示されている。また特許文献６の清掃用具では、ドライタイプの繊維状基材に、アレルギーを引き起こす物質の抗原性を低減化させる抗原性低減化成分と、油剤と、界面活性剤とを含む抗原性低減化組成物が付与されてなる掃除用具が示されている。しかし、これらのドライタイプのシートは、拭き取った汚れをしっかり吸着し、その汚れが被清掃面に再付着することはないが、ウエットタイプに使用されている水溶性の防汚成分を配合することは難しく、拭いた後の被清掃面に防汚効果を付与できるものではなかった。
2. Description of the Related Art Conventionally, cleaning sheets for removing dirt are known in various shapes and materials such as a wet sheet type and a dry sheet type.
There are various wet sheet types. In the glass cleaning sheet and the glass cleaning sheet article of Patent Document 1, a surfactant, a hydrophilic solvent, an antifogging component, and / or a detergent component on a rayon or cotton nonwoven fabric are used. Or what was impregnated with 1 type chosen from an alkanolamine and an alkali metal is described. In addition, the non-woven fabric for cleaning and the non-woven fabric article for cleaning described in Patent Document 2 are obtained by impregnating a spun lace non-woven fabric with a surfactant, a water-soluble solvent and an alkaline agent to remove stubborn oil stains on the hard surface. Compared with a cleaning method using steel wool or the like, it is possible to clean easily and effectively with very little effort without worrying about damage. In the cleaning sheet of Patent Document 3 and the manufacturing method thereof, as a cleaning sheet having a high cleaning effect suitable for furniture and fixtures installed in a place where water is used, a non-woven fabric containing rayon fibers and polyethylene terephthalate fibers is used as an interface. The thing containing the cleaning agent containing an activator and a polyhydric alcohol is disclosed. In patent document 4, the wet type which impregnated the nonwoven fabric with the aqueous | water-based cleaning agent containing the antistatic agent which consists of an anionic surfactant or a nonionic surfactant, and the thickener which consists of an anionic thickener or a nonionic thickener. This cleaning sheet is shown to prevent the occurrence of dirt due to static electricity. However, when these wet type sheets are wiped off the window glass or screen, the dirt once wiped out is pushed out to the surface to be cleaned by the cleaning liquid, and it cannot be wiped off even if wiped many times. It was necessary to wipe twice later.
On the other hand, as a dry sheet type, there is a cleaning wiping tool of Patent Document 5, and a sheet formed by laminating a fibrous web made of hydrophilic fibers and crimped synthetic fibers on a long fiber nonwoven fabric, an oil agent component and an interface. A cleaning wiping tool carrying a dust control agent made of an activator is shown. Moreover, in the cleaning tool of patent document 6, the antigenicity reduction composition containing the antigenicity reduction component which reduces the antigenicity of the substance which causes allergy, an oil agent, and surfactant in dry type fibrous base material A cleaning tool provided with an object is shown. However, these dry type sheets firmly adsorb the wiped dirt, and the dirt does not reattach to the surface to be cleaned, but it contains the water-soluble antifouling component used in the wet type. It was difficult to impart an antifouling effect to the surface to be cleaned after wiping.
本発明は、２０℃で液状の炭化水素系油性溶剤と、これに溶解する特定の界面活性剤を配合した油剤を含浸したシートから構成され、清掃時に拭き取った汚れの再付着がなく、被清掃面の汚れ落としと同時に防汚効果を付与可能な防汚・清掃用シートを提供することを目的とする。 The present invention is composed of a sheet impregnated with an oil containing a hydrocarbon-based solvent that is liquid at 20 ° C. and a specific surfactant that dissolves in the solvent. An object is to provide an antifouling / cleaning sheet capable of imparting an antifouling effect at the same time as removing dirt on the surface.
本発明は、以下の構成が上記目的を達成するために優れた効果を奏することを見出したものである。
（１）２０℃で液状である炭化水素系油性溶剤と、この炭化水素系油性溶剤に溶解する界面活性剤を配合した油剤を不織布に含浸させた防汚・清掃用シートであって、前記界面活性剤がエチレンオキサイド付加モル数が３モル以下であるポリオキシエチレンアルキルアミン及びポリオキシエチレンアルキルジアミンから選ばれる１種又は２種以上である、水を含まないドライタイプの防汚・清掃用シート。
（２）炭化水素系油性溶剤がパラフィン系炭化水素、オレフィン系炭化水素及びナフテン系炭化水素から選ばれる１種又は２種以上である（１）に記載の防汚・清掃用シート。
The present invention has been found that the following constitution has an excellent effect for achieving the above-mentioned object.
(1) An antifouling / cleaning sheet in which a nonwoven fabric is impregnated with an oil containing a hydrocarbon oil solvent that is liquid at 20 ° C. and a surfactant dissolved in the hydrocarbon oil solvent, the interface active agent is ethylene oxide addition mole number of 3 moles of one or more selected less is polyoxyethylene alkyl amines and polyoxyethylene alkyl di Amin or al, dry type antifouling water free Cleaning sheet.
(2) The antifouling / cleaning sheet according to (1), wherein the hydrocarbon oil solvent is one or more selected from paraffin hydrocarbons, olefin hydrocarbons, and naphthene hydrocarbons.
本発明の防汚・清掃用シートによれば、含浸油剤として、２０℃で液状である炭化水素系油性溶剤と、これに溶解する特定の界面活性剤を配合したことに基づき、高い洗浄効果を奏するとともに、清掃後の被清掃面に防汚効果を付与することが可能となる。
また、本発明の防汚・清掃用シートは、そのままもしくは、アプリケーターに装着して使用することができる。
According to the antifouling / cleaning sheet of the present invention, as an impregnating oil agent, a high cleaning effect is obtained based on the blending of a hydrocarbon-based oily solvent that is liquid at 20 ° C. and a specific surfactant that dissolves therein. In addition to the performance, an antifouling effect can be imparted to the surface to be cleaned after cleaning.
Further, the antifouling / cleaning sheet of the present invention can be used as it is or after being attached to an applicator.
以下、本発明の実施の形態を具体的に説明する。 Hereinafter, embodiments of the present invention will be specifically described.
本発明で用いる不織布は、含浸油剤を十分量含浸することができ、清掃に耐えうる強度を持つものであれば、特に制限なく使用することが可能である。特に好ましい不織布としては、例えば、スパンレース不織布、スパンボンド不織布、サクション不織布、ヒートボンド不織布、メルトブロー不織布等が挙げられ、その一部もしくは全部に分割繊維を使用しても良い。不織布を形成する繊維組成は、適宜選定することができ、レーヨン、ポリオレフィン、ポリエステル、パルプ等の繊維を単独で、又は、積層して用いることができる。さらに本発明で用いる不織布は、３０〜２００ｇ／ｍ２の目付けであることが望ましい。目付けが小さすぎると清掃用シートとして使用した際に、強度が不十分となり、破れたり繊維が脱落して汚れの原因となる。また、大きすぎるとコストが高くなり、また清掃面に力が伝わり難くなる等、実用性の乏しいものとなってしまう。 The nonwoven fabric used in the present invention can be used without particular limitation as long as it can be impregnated with a sufficient amount of impregnating oil and has a strength capable of withstanding cleaning. Particularly preferred nonwoven fabrics include, for example, spunlace nonwoven fabrics, spunbond nonwoven fabrics, suction nonwoven fabrics, heat bond nonwoven fabrics, melt blown nonwoven fabrics, and the like. The fiber composition which forms a nonwoven fabric can be selected suitably, and fibers, such as rayon, polyolefin, polyester, a pulp, can be used individually or in a laminated form. Furthermore, it is desirable that the nonwoven fabric used in the present invention has a basis weight of 30 to 200 g / m 2 . If the basis weight is too small, when used as a cleaning sheet, the strength becomes insufficient, and tears or fibers fall off, causing dirt. On the other hand, if it is too large, the cost becomes high, and it becomes difficult to transmit the force to the cleaning surface.
本発明に用いられる２０℃で液状である炭化水素系油性溶剤としては、パラフィン系炭化水素、オレフィン系炭化水素、ナフテン系炭化水素、芳香族系炭化水素が挙げられる。パラフィン系ではノルマルパラフィンやイソパラフィン、オレフィン系ではαオレフィンとして１−ドデセン、１−テトラデセン、１−ヘキサデセン、１−オクタデセンなどが挙げられる。また、これらの炭化水素が混合された鉱物油等であってもよい。特に、パラフィン系炭化水素、オレフィン系炭化水素又はナフテン系炭化水素は、汚れ吸着性や潤滑性が良く好適に用いられる。 Examples of the hydrocarbon-based oily solvent that is liquid at 20 ° C. used in the present invention include paraffinic hydrocarbons, olefinic hydrocarbons, naphthenic hydrocarbons, and aromatic hydrocarbons. Examples of paraffins include normal paraffins and isoparaffins, and olefins include α-olefins such as 1-dodecene, 1-tetradecene, 1-hexadecene, and 1-octadecene. Moreover, the mineral oil etc. with which these hydrocarbons were mixed may be sufficient. In particular, paraffinic hydrocarbons, olefinic hydrocarbons, or naphthenic hydrocarbons are preferably used because they have good soil adsorbability and lubricity.
炭化水素系油性溶剤に溶解する特定の界面活性剤としては、溶解性、防汚性の観点から、ポリオキシエチレンアルキルアミン、ポリオキシエチレンアルキルジアミン、ソルビタン脂肪酸エステル及びイオン液体が採用され、ポリオキシエチレンアルキルアミン及びポリオキシエチレンアルキルジアミンのエチレンオキサイド付加モル数が3以下のものが好ましい。これら以外の、例えばポリオキシエチレンアルキルエーテルや脂肪酸アルカノールアミド、グリセリン脂肪酸エステルなどの界面活性剤は、ＨＬＢの低いものであっても、炭化水素系油性溶剤に難溶なため好ましくない。
炭化水素系油性溶剤に溶解する界面活性剤の配合量としては、防汚効果の観点から５質量％以上が好ましいが、３０質量％を超えて配合量を増やしても相応した防汚効果が得られないうえ、コストアップにつながるので、５〜３０質量％の範囲が適当である。
As specific surfactants to be dissolved in the hydrocarbon oil solvent, polyoxyethylene alkylamine, polyoxyethylene alkyldiamine, sorbitan fatty acid ester and ionic liquid are adopted from the viewpoint of solubility and antifouling property. Those having an ethylene oxide addition mole number of ethylene alkylamine and polyoxyethylene alkyldiamine of 3 or less are preferred. Surfactants other than these, such as polyoxyethylene alkyl ether, fatty acid alkanolamide, and glycerin fatty acid ester, are not preferable because they are poorly soluble in hydrocarbon oil-based solvents even if they have a low HLB.
The blending amount of the surfactant dissolved in the hydrocarbon-based oily solvent is preferably 5% by mass or more from the viewpoint of the antifouling effect, but a corresponding antifouling effect can be obtained even if the blending amount is increased beyond 30% by mass. In addition, the cost is increased, so the range of 5 to 30% by mass is appropriate.
本発明の防汚・清掃用シートの含浸油剤には、本発明の特徴を損なわない範囲で、適宜、他の添加剤を配合することができる。例えば、シリコーンオイル、合成油、動物油及び植物油などの油性溶剤、グリコールエーテルなどの水溶性溶剤、殺菌剤、防腐剤、除菌剤、虫よけ剤、殺虫剤、消臭剤、香料などが挙げられる。 The impregnating oil of the antifouling / cleaning sheet of the present invention can be appropriately blended with other additives as long as the characteristics of the present invention are not impaired. Examples include oily solvents such as silicone oil, synthetic oil, animal oil and vegetable oil, water-soluble solvents such as glycol ether, bactericides, preservatives, disinfectants, insect repellents, insecticides, deodorants, and fragrances. It is done.
次に具体的な実施例に基づき、本発明の防汚・清掃用シートについて、更に詳細に説明する。 Next, based on a specific Example, the antifouling / cleaning sheet of the present invention will be described in more detail.
表１に示す組成の実施例および比較例の含浸油剤を調製し、レーヨン／ポプロピレン／ポリエチレンのスパンレース不織布（目付け：７０ｇ／ｍ２）に１ｍ２当たり１５ｇになるよう含浸し、ドライタイプの防汚・清掃用シートを作製した。
用いた炭化水素系油性溶剤や界面活性剤の仕様は下記のとおりである。
ＩＰソルベント２８３５（出光興産（株）製 イソパラフィン）、リニアレン１４（出光興産（株）製 Ｃ１４α−オレフィン）、エクソールＤ１３０（エクソンモービル製 ナフテン系炭化水素）、エソミンＯ／１２（ライオン（株）製 ＰＯＥ（２）オレイルアミン）、エソミンＣ／１２（ライオン（株）製 ＰＯＥ（２）ラウリルアミン）、エソデュオミンＴ／１３（ライオン（株）製 ＰＯＥ（３）牛脂ジアミン）、ノニオンＯＰ−８０Ｒ（日油（株）製 ソルビタンモノオレエート）、ノニオンＯＰ−８５Ｒ（日油（株）製 ソルビタントリオレエート）、Ｘ−８１２８（日華化学製イオン液体 ベンザルコニウム（Ｃ１２）ジオクチル燐酸塩）、Ｘ８１２９（日華化学製イオン液体 ベンザルコニウム（Ｃ１２）ジオクチルスルホコハク酸塩）、モノグリＭＢ（日油（株）製 ステアリン酸グリセリル）、ニッコールＳＬ−１０（日光ケミカル（株）製 オレイン酸グリセリル）、アデカソールＣＯＡ（（株）ＡＤＥＫＡ製 ヤシ油脂肪酸ジエタノールアミド（１：１型））、ブラウノンＥＮ１５０２（青木油脂（株）製 ＰＯＥ（２）オレイルエーテル）
＜防汚試験＞
厚さ１ｍｍの塩化ビニル製の板を５×１０ｃｍに切断し、防汚・清掃用シートで片面をまんべんなく拭いた後、拭いた面を下にして、乾燥した土を入れた直径９ｃｍのシャーレの上に置き、裏面を不織布で１０回こすり静電気を起こして土を付着させた。土の付着量を測定して、防汚率（％）を以下の式で算出した。
防汚率（％）＝（Ａ−Ｂ）／Ａ×１００
Ａ：無処理の塩化ビニル板への土の付着量
Ｂ：防汚・清掃用シートで拭いた塩化ビニル板への土の付着量
また、このときの防汚効果を目視にて以下の基準で評価した。
○：無処理よりも明らかに汚れの付着を抑えている
△：無処理よりもやや汚れの付着を抑えている
×：無処理と同じくらい汚れが付着している
The impregnating oils of Examples and Comparative Examples having the compositions shown in Table 1 were prepared, impregnated into a rayon / popylene / polyethylene spunlace nonwoven fabric (weight per unit: 70 g / m 2 ) so as to be 15 g per m 2 , and dry type An antifouling / cleaning sheet was prepared.
The specifications of the hydrocarbon-based oil solvent and the surfactant used are as follows.
IP solvent 2835 (isoparaffin manufactured by Idemitsu Kosan Co., Ltd.), linearene 14 (C14 α-olefin manufactured by Idemitsu Kosan Co., Ltd.), Exol D130 (naphthenic hydrocarbon manufactured by ExxonMobil), Esomin O / 12 (POE manufactured by Lion Co., Ltd.) (2) Oleylamine), Esomine C / 12 (POE (2) Laurylamine manufactured by Lion Corporation), Esoduomine T / 13 (POE (3) Tallow diamine manufactured by Lion Corporation), Nonion OP-80R (Nippon Oil ( Sorbitan monooleate), Nonion OP-85R (manufactured by NOF Corporation sorbitan trioleate), X-8128 (ionic liquid benzalkonium (C12) dioctyl phosphate), X8129 (Nikka) Chemical ionic liquid benzalkonium (C12) dioctylsulfosuccinate Monogly MB (manufactured by NOF Corporation, glyceryl stearate), Nikkor SL-10 (manufactured by Nikko Chemical Co., Ltd., glyceryl oleate), Adekasol COA (manufactured by ADEKA, coconut oil fatty acid diethanolamide (1: 1 type)) , Brownon EN1502 (POE (2) oleyl ether manufactured by Aoki Oil & Fat Co., Ltd.)
<Anti-fouling test>
A 1 mm thick vinyl chloride plate is cut to 5 x 10 cm, wiped evenly with an antifouling / cleaning sheet, and then wiped down with a 9 cm diameter petri dish containing dry soil. It was placed on top and the back side was rubbed 10 times with a non-woven fabric to cause static electricity to adhere the soil. The amount of soil adhesion was measured, and the antifouling rate (%) was calculated by the following formula.
Antifouling rate (%) = (A−B) / A × 100
A: Amount of soil adhering to untreated vinyl chloride plate B: Amount of soil adhering to vinyl chloride plate wiped with antifouling / cleaning sheet
Moreover, the antifouling effect at this time was visually evaluated according to the following criteria.
○: Slightly less adherence of dirt than untreated △: Slightly less dirt than untreated ×: Stained as much as untreated
表１の実施例１乃至１４に示すように、炭化水素系油性溶剤に溶解する特定の界面活性剤を含浸した本発明品の防汚・清掃用シートは、良好な防汚効果が認められた。 As shown in Examples 1 to 14 in Table 1, the antifouling / cleaning sheet of the product of the present invention impregnated with a specific surfactant dissolved in a hydrocarbon-based oily solvent showed a good antifouling effect. .
一方、比較例１乃至４の界面活性剤は炭化水素系油性溶剤に溶解せず、不織布シートに均一に含浸することができなかった。また、比較例５乃至７で示すように、アミン、脂肪酸及びアルコールは、炭化水素系油性溶剤に溶解したが、防汚効果は認められなかった。 On the other hand, the surfactants of Comparative Examples 1 to 4 were not dissolved in the hydrocarbon-based oily solvent and could not be uniformly impregnated into the nonwoven fabric sheet. Further, as shown in Comparative Examples 5 to 7, amine, fatty acid and alcohol were dissolved in a hydrocarbon oil solvent, but no antifouling effect was observed.
本発明の防汚・清掃用シートは、ウエットタイプのシートのような清掃時の拭き取った汚れの再付着がなく、拭くだけで汚れ落しと被清掃面に防汚効果の付与を同時に行うことができるため非常に有用である。 The antifouling / cleaning sheet of the present invention does not re-attach dirt that has been wiped off during cleaning like a wet-type sheet, and it can simultaneously remove dirt and impart an antifouling effect to the surface to be cleaned. It is very useful because it can.
本発明の防汚・清掃用シートは、広範な防汚・清掃用途を目的として利用することが可能である。 The antifouling / cleaning sheet of the present invention can be used for a wide range of antifouling / cleaning purposes.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011091765A JP5796993B2 (en) | 2011-04-18 | 2011-04-18 | Antifouling / cleaning sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011091765A JP5796993B2 (en) | 2011-04-18 | 2011-04-18 | Antifouling / cleaning sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2012223265A JP2012223265A (en) | 2012-11-15 |
| JP5796993B2 true JP5796993B2 (en) | 2015-10-21 |
Family
ID=47274171
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011091765A Active JP5796993B2 (en) | 2011-04-18 | 2011-04-18 | Antifouling / cleaning sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5796993B2 (en) |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62276078A (en) * | 1986-05-23 | 1987-11-30 | 株式会社 ダスキン | Dust control product and its production |
| JPH0711000B2 (en) * | 1991-12-02 | 1995-02-08 | 三洋化成工業株式会社 | Oil agent for dust adsorption |
| JP4688455B2 (en) * | 2004-09-09 | 2011-05-25 | ユニ・チャーム株式会社 | Cleaning tool |
| JP4673640B2 (en) * | 2004-12-02 | 2011-04-20 | 大王製紙株式会社 | Wet type wipes with antibacterial properties |
| JP2006158771A (en) * | 2004-12-09 | 2006-06-22 | Earth Chem Corp Ltd | Stationary house dust removal sheet, and kit for removing house dust |
-
2011
- 2011-04-18 JP JP2011091765A patent/JP5796993B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2012223265A (en) | 2012-11-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR100822576B1 (en) | Multi-Purpose Cleaning Articles | |
| US7307055B2 (en) | Cleaning implements | |
| CN101535464B (en) | Premoistened cleaning disposable substrate | |
| EP1434847B2 (en) | Pre-moistened wipe for treating a surface | |
| DE60019790T2 (en) | CLEANING PROCEDURE USING ULTRASONIC SHAFT | |
| CA2725772C (en) | Low residue cleaning solution | |
| DE60020728T2 (en) | ULTRASOUND DEVICE | |
| AU2002254108A1 (en) | Multi-purpose cleaning articles | |
| AU2003202670A1 (en) | Improvements in and relating to cleaning implements | |
| TW201527515A (en) | Bactericidal cleaning composition for hard surfaces | |
| ZA200500231B (en) | Cleaning wipe having water staining resistance | |
| JP5796993B2 (en) | Antifouling / cleaning sheet | |
| US20190161624A1 (en) | Anti-adhesive composition for unvulcanized rubber | |
| PL198957B1 (en) | Anti-static cleaning wipes | |
| CN110914399B (en) | Liquid detergent composition for hard surface | |
| JP2007291207A (en) | Dust-attaching agent | |
| JP4033381B2 (en) | Washing | |
| JP4043011B2 (en) | Wet wiper | |
| EP4148112B1 (en) | Biobased cleaning compositions and methods of preparation thereof | |
| US8845817B2 (en) | Non-toxic cleaning agent | |
| JP7454000B2 (en) | Cleaning composition and cleaning cloth | |
| JP5822256B2 (en) | Cleaning sheet | |
| JP4069466B2 (en) | Yani dirt cleaning composition | |
| JP3812911B2 (en) | Wet wiper for wax application | |
| JP4304389B2 (en) | Cleaning fluid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20140328 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20141114 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20141209 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150205 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20150818 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20150818 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5796993 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |