JP5777853B2 - ナノスケール/略ナノスケールのアモルファスの鋼板の製造のための改善された処理方法 - Google Patents
ナノスケール/略ナノスケールのアモルファスの鋼板の製造のための改善された処理方法 Download PDFInfo
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- JP5777853B2 JP5777853B2 JP2009533530A JP2009533530A JP5777853B2 JP 5777853 B2 JP5777853 B2 JP 5777853B2 JP 2009533530 A JP2009533530 A JP 2009533530A JP 2009533530 A JP2009533530 A JP 2009533530A JP 5777853 B2 JP5777853 B2 JP 5777853B2
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- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 229910000831 Steel Inorganic materials 0.000 title description 42
- 239000010959 steel Substances 0.000 title description 42
- 238000003672 processing method Methods 0.000 title 1
- 229910045601 alloy Inorganic materials 0.000 claims description 51
- 239000000956 alloy Substances 0.000 claims description 51
- 238000001816 cooling Methods 0.000 claims description 49
- 238000000034 method Methods 0.000 claims description 31
- 238000007496 glass forming Methods 0.000 claims description 25
- 238000005266 casting Methods 0.000 claims description 24
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 20
- 230000008018 melting Effects 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 11
- 229910052742 iron Inorganic materials 0.000 claims description 10
- 229910000640 Fe alloy Inorganic materials 0.000 claims description 9
- 239000002131 composite material Substances 0.000 claims description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 229910052580 B4C Inorganic materials 0.000 claims description 3
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 229910052723 transition metal Inorganic materials 0.000 claims description 3
- 150000003624 transition metals Chemical class 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910001566 austenite Inorganic materials 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052733 gallium Inorganic materials 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 239000010955 niobium Substances 0.000 claims description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 229910052715 tantalum Inorganic materials 0.000 claims description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 239000010937 tungsten Substances 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910000859 α-Fe Inorganic materials 0.000 claims description 2
- 150000001247 metal acetylides Chemical class 0.000 claims 1
- 239000007788 liquid Substances 0.000 description 17
- 239000011521 glass Substances 0.000 description 15
- 238000004781 supercooling Methods 0.000 description 15
- 238000010899 nucleation Methods 0.000 description 14
- 230000006911 nucleation Effects 0.000 description 14
- 229910000851 Alloy steel Inorganic materials 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- 239000012071 phase Substances 0.000 description 11
- 239000005300 metallic glass Substances 0.000 description 9
- 238000007711 solidification Methods 0.000 description 9
- 230000008023 solidification Effects 0.000 description 9
- 238000010586 diagram Methods 0.000 description 7
- 239000013078 crystal Substances 0.000 description 6
- 230000009466 transformation Effects 0.000 description 6
- 230000005540 biological transmission Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 230000012010 growth Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 229910000881 Cu alloy Inorganic materials 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 229910052752 metalloid Inorganic materials 0.000 description 3
- 150000002738 metalloids Chemical class 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000007790 solid phase Substances 0.000 description 3
- 229910001315 Tool steel Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 238000009749 continuous casting Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000004031 devitrification Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000002003 electron diffraction Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000007712 rapid solidification Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 229910001141 Ductile iron Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 229910000797 Ultra-high-strength steel Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910000808 amorphous metal alloy Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000010261 cell growth Effects 0.000 description 1
- UFGZSIPAQKLCGR-UHFFFAOYSA-N chromium carbide Chemical compound [Cr]#C[Cr]C#[Cr] UFGZSIPAQKLCGR-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- -1 copper Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000001887 electron backscatter diffraction Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 230000005415 magnetization Effects 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 238000001350 scanning transmission electron microscopy Methods 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910000601 superalloy Inorganic materials 0.000 description 1
- 229910003470 tongbaite Inorganic materials 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
- B22D11/0622—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars formed by two casting wheels
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/003—Making ferrous alloys making amorphous alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C45/00—Amorphous alloys
- C22C45/02—Amorphous alloys with iron as the major constituent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Continuous Casting (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Description
12 溶融合金鋼
14 第1ローラー
16 ストリップまたは薄板
18 第2ローラー
20 冷却表面
Claims (6)
- a)50重量%より多い鉄、b)ホウ素、炭素、ケイ素、リン、及びガリウムから選択されるPグループ元素、及びc)クロム、モリブデン、タングステン、タンタル、バナジウム、ニオブ、マンガン、ニッケル、銅、アルミニウム、及びコバルトから選択される遷移金属を含み、800から1500℃の融点と、105K/s未満の臨界冷却速度とを有する主成分が鉄のガラス形成合金を溶融する段階と、
上部ベルト及び下部ベルトの間で前記鉄合金溶融物を冷却することによる双ベルト鋳造工程により前記主成分が鉄のガラス形成合金を冷却し、冷却につれて前記鉄合金の収縮を補うように、及び前記鉄合金に一定圧力を提供するように、前記ベルト表面間の距離は前記ベルトの長さに沿って減少され、及び50体積%以上で存在する150から1000nmの範囲の構造ユニットを生成するのに十分な速度で0.1mmから30mmの範囲の厚さを有する薄板を形成する段階と、
を含み、前記薄板がα‐Fe、γ‐Fe相、及び複合ホウ素炭化物を含むことを特徴とする主成分が鉄のガラス形成合金薄板の製造方法。 - (a)0.5nmから10nm、および/または
(b)10nmから150nm
の構造ユニットを含む主成分が鉄のガラス形成合金をさらに含むことを特徴とする請求項1に記載の方法。 - 1μm以上の構造ユニットを含む主成分が鉄のガラス形成合金をさらに含むことを特徴とする請求項1に記載の方法。
- 前記主成分が鉄のガラス形成合金の構成要素が、複合炭化物、複合ホウ化物、及びそれらの組み合わせからなる群から選択された相をさらに含むことを特徴とする請求項1に記載の方法。
- 前記方法が、前記主成分が鉄のガラス形成合金薄板を熱処理によって失透させる段階をさらに含むことを特徴とする請求項1に記載の方法。
- 前記主成分が鉄のガラス形成合金を500℃から1000℃の範囲で過冷却することを特徴とする請求項1に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US82998806P | 2006-10-18 | 2006-10-18 | |
US60/829,988 | 2006-10-18 | ||
PCT/US2007/081810 WO2008049069A2 (en) | 2006-10-18 | 2007-10-18 | Improved processing method for the production of amorphous/nanoscale/near nanoscale steel sheet |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2010507023A JP2010507023A (ja) | 2010-03-04 |
JP5777853B2 true JP5777853B2 (ja) | 2015-09-09 |
Family
ID=39314840
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009533530A Expired - Fee Related JP5777853B2 (ja) | 2006-10-18 | 2007-10-18 | ナノスケール/略ナノスケールのアモルファスの鋼板の製造のための改善された処理方法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US8133333B2 (ja) |
EP (1) | EP2087142B1 (ja) |
JP (1) | JP5777853B2 (ja) |
AU (1) | AU2007310973B2 (ja) |
CA (1) | CA2667095C (ja) |
ES (1) | ES2540206T3 (ja) |
WO (1) | WO2008049069A2 (ja) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8882941B2 (en) * | 2008-10-21 | 2014-11-11 | The Nanosteel Company, Inc. | Mechanism of structural formation for metallic glass based composites with enhanced ductility |
CN102686762B (zh) * | 2009-09-17 | 2014-03-12 | 思高博塔公司 | 确定用于热喷涂、堆焊、热喷涂后处理应用和铸造的合金的组合体和方法 |
FI125358B (fi) | 2010-07-09 | 2015-09-15 | Teknologian Tutkimuskeskus Vtt Oy | Termisesti ruiskutettu täysin amorfinen oksidipinnoite |
WO2012061282A2 (en) * | 2010-11-02 | 2012-05-10 | The Nanosteel Company, Inc. | Glassy nano-materials |
US8257512B1 (en) * | 2011-05-20 | 2012-09-04 | The Nanosteel Company, Inc. | Classes of modal structured steel with static refinement and dynamic strengthening and method of making thereof |
US8419869B1 (en) * | 2012-01-05 | 2013-04-16 | The Nanosteel Company, Inc. | Method of producing classes of non-stainless steels with high strength and high ductility |
EP2759614B1 (de) * | 2013-01-25 | 2019-01-02 | ThyssenKrupp Steel Europe AG | Verfahren zum Erzeugen eines Stahlflachprodukts mit einem amorphen, teilamorphen oder feinkristallinen Gefüge und derart beschaffenes Stahlflachprodukt |
SI3063305T1 (sl) * | 2013-10-28 | 2021-07-30 | The Nanosteel Company, Inc. | Proizvodnja kovinskega jekla z ulivanjem plošč |
WO2019006095A1 (en) * | 2017-06-30 | 2019-01-03 | The Nanosteel Company, Inc. | RETENTION OF MECHANICAL PROPERTIES IN STEEL ALLOYS AFTER PROCESSING AND IN THE PRESENCE OF CONSTRAINTS CONCENTRATION SITES |
DE102021116380B4 (de) | 2021-06-24 | 2023-04-06 | Thyssenkrupp Steel Europe Ag | Verfahren zum Erzeugen eines Stahlflachprodukts mit einem amorphen oder teilamorphen Gefüge und Produkt hergestellt aus einem solchen Stahlflachprodukt |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4576653A (en) * | 1979-03-23 | 1986-03-18 | Allied Corporation | Method of making complex boride particle containing alloys |
US4297135A (en) * | 1979-11-19 | 1981-10-27 | Marko Materials, Inc. | High strength iron, nickel and cobalt base crystalline alloys with ultrafine dispersion of borides and carbides |
US4552201A (en) * | 1981-12-14 | 1985-11-12 | Hazelett Strip-Casting Corp. | Methods for shaping the casting region in a twin-belt continuous casting machine for improving heat transfer and product uniformity and enhanced machine performance |
US5056585A (en) * | 1982-09-03 | 1991-10-15 | General Motors Corporation | High energy product rare earth-iron magnet alloys |
US5379828A (en) * | 1990-12-10 | 1995-01-10 | Inland Steel Company | Apparatus and method for continuous casting of molten steel |
JPH10125518A (ja) * | 1996-10-18 | 1998-05-15 | Sumitomo Special Metals Co Ltd | 微細結晶組織を有する薄板磁石 |
US20040060620A1 (en) * | 2000-10-05 | 2004-04-01 | Johns Hopkins University | High performance nanostructured materials and methods of making the same |
JP5079498B2 (ja) * | 2004-04-28 | 2012-11-21 | ザ・ナノスティール・カンパニー・インコーポレーテッド | ナノ結晶金属シートの製造方法 |
TWI268289B (en) * | 2004-05-28 | 2006-12-11 | Tsung-Shune Chin | Ternary and multi-nary iron-based bulk glassy alloys and nanocrystalline alloys |
US7553382B2 (en) * | 2005-02-11 | 2009-06-30 | The Nanosteel Company, Inc. | Glass stability, glass forming ability, and microstructural refinement |
-
2007
- 2007-10-18 AU AU2007310973A patent/AU2007310973B2/en not_active Ceased
- 2007-10-18 ES ES07863428.4T patent/ES2540206T3/es active Active
- 2007-10-18 EP EP07863428.4A patent/EP2087142B1/en not_active Not-in-force
- 2007-10-18 US US11/874,361 patent/US8133333B2/en not_active Expired - Fee Related
- 2007-10-18 JP JP2009533530A patent/JP5777853B2/ja not_active Expired - Fee Related
- 2007-10-18 WO PCT/US2007/081810 patent/WO2008049069A2/en active Application Filing
- 2007-10-18 CA CA2667095A patent/CA2667095C/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP2087142A2 (en) | 2009-08-12 |
AU2007310973B2 (en) | 2013-04-18 |
ES2540206T3 (es) | 2015-07-09 |
WO2008049069A3 (en) | 2008-07-10 |
US20080213517A1 (en) | 2008-09-04 |
CA2667095A1 (en) | 2008-04-24 |
AU2007310973A1 (en) | 2008-04-24 |
US8133333B2 (en) | 2012-03-13 |
JP2010507023A (ja) | 2010-03-04 |
WO2008049069A2 (en) | 2008-04-24 |
EP2087142B1 (en) | 2015-03-25 |
EP2087142A4 (en) | 2011-05-25 |
CA2667095C (en) | 2017-11-07 |
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