JP5758377B2 - Oil and fat composition and chocolate product using the oil and fat composition - Google Patents
Oil and fat composition and chocolate product using the oil and fat composition Download PDFInfo
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- JP5758377B2 JP5758377B2 JP2012505675A JP2012505675A JP5758377B2 JP 5758377 B2 JP5758377 B2 JP 5758377B2 JP 2012505675 A JP2012505675 A JP 2012505675A JP 2012505675 A JP2012505675 A JP 2012505675A JP 5758377 B2 JP5758377 B2 JP 5758377B2
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- oil
- triglyceride
- fat composition
- fat
- mass
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- 235000019219 chocolate Nutrition 0.000 title claims description 106
- 239000000203 mixture Substances 0.000 title claims description 91
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 claims description 54
- 125000004432 carbon atom Chemical group C* 0.000 claims description 24
- 239000007788 liquid Substances 0.000 claims description 14
- 150000003626 triacylglycerols Chemical class 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- 150000004671 saturated fatty acids Chemical class 0.000 claims description 13
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 11
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 9
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 9
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 9
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 9
- 239000005642 Oleic acid Substances 0.000 claims description 9
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 9
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims description 9
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims description 9
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 6
- 229910052740 iodine Inorganic materials 0.000 claims description 6
- 239000011630 iodine Substances 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- RBLADLVPSYELCA-IKPAITLHSA-N 1,3-bis(octadecanoyloxy)propan-2-yl (9z)-octadec-9-enoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC RBLADLVPSYELCA-IKPAITLHSA-N 0.000 claims description 4
- FDCOHGHEADZEGF-QPLCGJKRSA-N 1,3-dipalmitoyl-2-oleoylglycerol Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCC)OC(=O)CCCCCCC\C=C/CCCCCCCC FDCOHGHEADZEGF-QPLCGJKRSA-N 0.000 claims description 4
- 125000001124 arachidoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 125000001312 palmitoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 230000001629 suppression Effects 0.000 claims description 3
- 125000005457 triglyceride group Chemical group 0.000 claims description 3
- 239000003925 fat Substances 0.000 description 108
- 244000299461 Theobroma cacao Species 0.000 description 107
- 235000019197 fats Nutrition 0.000 description 97
- 239000003921 oil Substances 0.000 description 92
- 235000019198 oils Nutrition 0.000 description 92
- 238000004519 manufacturing process Methods 0.000 description 13
- 244000105624 Arachis hypogaea Species 0.000 description 12
- 235000020232 peanut Nutrition 0.000 description 12
- 238000002844 melting Methods 0.000 description 11
- 235000014571 nuts Nutrition 0.000 description 11
- 230000008018 melting Effects 0.000 description 10
- 235000014510 cooky Nutrition 0.000 description 9
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 9
- 239000002994 raw material Substances 0.000 description 8
- 235000005764 Theobroma cacao ssp. cacao Nutrition 0.000 description 7
- 235000005767 Theobroma cacao ssp. sphaerocarpum Nutrition 0.000 description 7
- 235000001046 cacaotero Nutrition 0.000 description 7
- 235000019482 Palm oil Nutrition 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 6
- 239000002540 palm oil Substances 0.000 description 6
- 238000005809 transesterification reaction Methods 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000005194 fractionation Methods 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 5
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical group CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 5
- 235000017060 Arachis glabrata Nutrition 0.000 description 4
- 235000010777 Arachis hypogaea Nutrition 0.000 description 4
- 235000018262 Arachis monticola Nutrition 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 4
- 229940110456 cocoa butter Drugs 0.000 description 4
- 235000019868 cocoa butter Nutrition 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- MVLVMROFTAUDAG-UHFFFAOYSA-N ethyl octadecanoate Chemical group CCCCCCCCCCCCCCCCCC(=O)OCC MVLVMROFTAUDAG-UHFFFAOYSA-N 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000000796 flavoring agent Substances 0.000 description 4
- 235000019634 flavors Nutrition 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- 239000008117 stearic acid Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 235000021314 Palmitic acid Nutrition 0.000 description 3
- 235000019486 Sunflower oil Nutrition 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 3
- 235000000346 sugar Nutrition 0.000 description 3
- 239000002600 sunflower oil Substances 0.000 description 3
- 238000005496 tempering Methods 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 244000144725 Amygdalus communis Species 0.000 description 2
- 241000282693 Cercopithecidae Species 0.000 description 2
- 241000723382 Corylus Species 0.000 description 2
- 235000007466 Corylus avellana Nutrition 0.000 description 2
- 241000208467 Macadamia Species 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 235000018936 Vitellaria paradoxa Nutrition 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 235000020224 almond Nutrition 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 235000014121 butter Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000009508 confectionery Nutrition 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- XIRNKXNNONJFQO-UHFFFAOYSA-N ethyl hexadecanoate Chemical group CCCCCCCCCCCCCCCC(=O)OCC XIRNKXNNONJFQO-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 235000021243 milk fat Nutrition 0.000 description 2
- 235000003441 saturated fatty acids Nutrition 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 235000005135 Micromeria juliana Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- 240000002114 Satureja hortensis Species 0.000 description 1
- 235000007315 Satureja hortensis Nutrition 0.000 description 1
- 244000000231 Sesamum indicum Species 0.000 description 1
- 235000003434 Sesamum indicum Nutrition 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 235000020986 nuts and seeds Nutrition 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- NGVDGCNFYWLIFO-UHFFFAOYSA-N pyridoxal 5'-phosphate Chemical compound CC1=NC=C(COP(O)(O)=O)C(C=O)=C1O NGVDGCNFYWLIFO-UHFFFAOYSA-N 0.000 description 1
- 235000021067 refined food Nutrition 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 235000020183 skimmed milk Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 235000008939 whole milk Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings, cooking oils
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings, cooking oils
- A23D9/02—Other edible oils or fats, e.g. shortenings, cooking oils characterised by the production or working-up
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
- A23G1/36—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the fats used
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
- A23G1/48—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds containing plants or parts thereof, e.g. fruits, seeds, extracts
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/56—Cocoa products, e.g. chocolate; Substitutes therefor making liquid products, e.g. for making chocolate milk drinks and the products for their preparation, pastes for spreading, milk crumb
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
- C11C3/10—Ester interchange
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Botany (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Confectionery (AREA)
- Edible Oils And Fats (AREA)
Description
本願は、日本国特許出願2010−063608を基礎としたパリ条約の優先権主張出願を伴った出願であり、本願は、この日本国特許出願に開示された事項の全てを包含するものである。 This application is an application accompanied by an application for claiming priority of the Paris Convention based on Japanese Patent Application 2010-063608, and this application includes all of the matters disclosed in this Japanese Patent Application.
本発明は、チョコレート生地を製造する際に使用される油脂組成物と該油脂組成物を使用したチョコレート生地を用いて製造されるチョコレート製品に関するものである。 TECHNICAL FIELD The present invention relates to an oil / fat composition used in producing a chocolate dough and a chocolate product produced using a chocolate dough using the oil / fat composition.
なお、本発明のチョコレート製品とは、規約「チョコレート類の表示に関する公正競争規約」乃至法規上の規定により限定されるものではなく、カカオ代用脂と呼ばれる油脂を使用したカカオ分を含まないチョコレート様の加工食品をも含むものである。 The chocolate product of the present invention is not limited by the provisions of the “Fair Competition Rules for the Display of Chocolates” or the provisions of laws and regulations, and does not contain a cacao component using fats and oils called cacao substitute fats. Including processed foods.
ブロック状、板状の形に成型されたチョコレート製品は、チョコレート生地が緩んで製品が変形することがないよう、カカオ脂の他に比較的融点の高い固形脂を加えて製造されることが多い。これは、流通段階で温度コントロールができず、高温にさらされることが珍しくないことであったという事情が多分に影響していると思われる。ところが近年は、食品の種類に合わせてさまざまな温度帯での配送が可能になった。流通の段階でチョコレート生地が溶けることを心配する必要はなくなり、逆にチョコレート製品においては、低い温度に置かれることによる低温ブルーム発生が問題になっている。 Chocolate products molded into block and plate shapes are often manufactured by adding solid fat with a relatively high melting point in addition to cocoa butter so that the chocolate dough will not loosen and deform the product. . This is probably due to the fact that it was not uncommon to be exposed to high temperatures because the temperature could not be controlled at the distribution stage. However, in recent years, it has become possible to deliver in various temperature zones according to the type of food. There is no need to worry about melting of the chocolate dough at the stage of distribution, and conversely, in chocolate products, the occurrence of low temperature bloom due to being placed at a low temperature has become a problem.
低温ブルームの発生は、特にアーモンド、マカデミアナッツ、ヘーゼルナッツ、ピーナッツ等の種実類を加えたチョコレート製品で問題になることが多い。種実類入りチョコレート製品は、種実類に含まれる脂肪とチョコレート生地に含まれる脂肪との間で油脂移行が起こる場合があり、その場合に製品の品質劣化が引き起こされる。種実類は色沢が失われ、白っぽく乾燥したようになり、ガリガリした食感に変化してしまう。一方、チョコレート生地はブルームが発生して粉がふき、光沢が失われ、硬さが変化するといった現象が見られる。 The occurrence of cold blooms is often a problem, especially in chocolate products with added seeds such as almonds, macadamia nuts, hazelnuts and peanuts. In a chocolate product containing seeds and nuts, fat and oil transfer may occur between the fats contained in the seeds and seeds and the fats contained in the chocolate dough, and in this case, the quality of the product is deteriorated. Nuts and seeds lose their color, become whitish and dry, and change to a crunchy texture. On the other hand, in the chocolate dough, blooming occurs, powder is wiped, gloss is lost, and hardness changes.
このような事情から、チョコレート製品は高温での耐熱性よりも、低温でのブルーム発生を抑制されることが求められつつある。また耐熱性を重視するあまりに犠牲にしてきた口溶けを改善し、口溶けの良さやソフトな食感のチョコレート生地の食味についても改良が進んでいる。チョコレート生地に含まれる油脂の種類を工夫することによって、低温ブルームの抑制や、チョコレート製品の食味を改良するなどのさまざまな工夫がなされてきた。 Under such circumstances, chocolate products are being demanded to suppress blooming at low temperatures rather than heat resistance at high temperatures. In addition, improving the melting of the mouth that has been sacrificed too much emphasizing heat resistance, and improving the taste of the chocolate dough with good mouth melting and soft texture. Various ideas, such as suppression of low-temperature bloom and improving the taste of chocolate products, have been made by devising the types of fats and oils contained in chocolate dough.
特許文献1はチョコレート用の油脂組成物に関するものである。特定のトリグリセリドを含有する油脂組成物をチョコレートに使用することによって、焼き菓子、ナッツ、クリーム類と組み合わせた複合菓子のマイグレーションを防ぎ、ブルーム発生を抑制することを目的としている。しかしながら、サル脂或いはサル脂の分別油を使用しなければならず、工業的な面において、原料供給や品質が不安定であった。 Patent Document 1 relates to a fat composition for chocolate. The object is to prevent migration of complex confectionery combined with baked confectionery, nuts, and creams and to suppress bloom by using an oil and fat composition containing a specific triglyceride in chocolate. However, it is necessary to use monkey fat or monkey oil fractionated oil, and the supply of raw materials and quality are unstable in an industrial aspect.
特許文献2はソフトチョコレート様油脂組成物に関するものである。ブルーム、グレイン耐性のあるソフトな食感のチョコレートの生産を可能にしたが、パーム軟質部を利用したやわらかいチョコレート生地であるため、ブロック状、板状のチョコレート製品には好適といえるものではなかった。 Patent Document 2 relates to a soft chocolate-like oil and fat composition. Made it possible to produce chocolate with a soft texture with bloom and grain resistance, but because it is a soft chocolate dough using the palm soft part, it was not suitable for block and plate chocolate products .
低温ブルームを抑制するチョコレート生地を生産するための油脂組成物を提供することである。特に種実類を含有するチョコレート製品の低温ブルームを抑制するチョコレート生地を生産するための油脂組成物を提供することである。 It is providing the oil-fat composition for producing the chocolate dough which suppresses low temperature bloom. It is providing the oil-and-fat composition for producing the chocolate dough which suppresses the low-temperature bloom of the chocolate product containing seeds and seeds especially.
本発明者らは、油脂組成物中のXOX型トリグリセリド含有量(Xは炭素数16以上の飽和脂肪酸、Oはオレイン酸)とその組成、1,3−ジパルミトイル−2−オレオイルグリセリン(POP)、1,3−ジステアロイル−2−オレオイルグリセリン(SOS)、2位にオレオイル基を有し、1,3位にパルミトイル基とステアロイル基を各1基づつ有するトリグリセリド(POS)を規定し、そこに液状油脂の含量とその組成の規定を組み合わせた油脂組成物をチョコレート生地に用いることで、低温ブルームを抑制することを見いだした。 The present inventors have described the content of XOX triglyceride (X is a saturated fatty acid having 16 or more carbon atoms, O is oleic acid) and its composition, 1,3-dipalmitoyl-2-oleoylglycerin (POP) in the oil and fat composition. ), 1,3-distearoyl-2-oleoylglycerin (SOS), triglyceride (POS) having an oleoyl group at the 2-position and a palmitoyl group and a stearoyl group at the 1,3-position, respectively And it discovered that low temperature bloom was suppressed by using the fats and oils composition which combined the content of the liquid fats and the regulation of the composition there for chocolate dough.
すなわち、本発明の一態様によれば、油脂組成物中のPOP型トリグリセリド(1,3−ジパルミトイル−2−オレオイルグリセリン、以下POPとも記載する)含有量が15〜40質量%、SOS型トリグリセリド(1,3−ジステアロイル−2−オレオイルグリセリン、以下SOSとも記載する)含有量が20〜35質量%、POS型トリグリセリド(2位にオレオイル基を有し、1,3位にパルミトイル基とステアロイル基を各1基づつ有するトリグリセリド、以下POSとも記載する)含有量が5〜11質量%、及び液状油脂含有量が15〜35質量%であり、なおかつ、上記POP、SOS、POSを含むXOX型トリグリセリド(2位にオレイン酸、1、3位に炭素数16以上の飽和脂肪酸が結合したトリグリセリド)の総含有量が62〜80質量%である油脂組成物が提供される。 That is, according to one aspect of the present invention, the content of POP triglyceride (1,3-dipalmitoyl-2-oleoylglycerin, hereinafter also referred to as POP) in the oil and fat composition is 15 to 40% by mass, SOS type Triglyceride (1,3-distearoyl-2-oleoylglycerin, hereinafter also referred to as SOS) content is 20 to 35% by mass, POS type triglyceride (having oleoyl group at 2nd position, palmitoyl at 1,3rd position) A triglyceride having one group each and one stearoyl group, hereinafter also referred to as POS), the content is 5 to 11% by mass, the liquid fat content is 15 to 35% by mass, and the POP, SOS, and POS are Contains XOX-type triglycerides (triglycerides combined with oleic acid at the 2nd position and saturated fatty acids with 16 or more carbon atoms at the 3rd position) Fat composition is provided but it is 62-80 wt%.
本発明の別の態様によれば、上記の油脂組成物は、上記液状油脂が、1、2、3位の全てに炭素数16以上の不飽和脂肪酸が結合したトリグリセリド(UUU型トリグリセリド)と、1位に炭素数16以上の飽和脂肪酸が結合し、2、3位に炭素数16以上の不飽和脂肪酸が結合したトリグリセリド(XUU型トリグリセリド)とを含んでなり、前記液状油脂中のUUU/(XUU+UUU)のトリグリセリド比が0.08〜0.15である油脂組成物が提供される。 According to another aspect of the present invention, the above fat composition is a triglyceride (UUU type triglyceride) in which the liquid fat is bonded with unsaturated fatty acids having 16 or more carbon atoms in all of positions 1, 2, and 3. A triglyceride (XUU type triglyceride) in which a saturated fatty acid having 16 or more carbon atoms is bonded to the 1st position and an unsaturated fatty acid having 16 or more carbon atoms is bonded to the 2nd or 3rd position, and UUU / ( An oil composition having a triglyceride ratio of (XUU + UUU) of 0.08 to 0.15 is provided.
本発明の別の態様によれば、上記の油脂組成物は、油脂組成物中のSOA型トリグリセリド(2位にオレオイル基を有し、1,3位にステアロイル基とアラキドイル基とを各1基づつ有するトリグリセリド、以下SOAとも記載する)含有量が1.5質量%以下である油脂組成物が提供される。 According to another aspect of the present invention, the oil / fat composition described above comprises an SOA-type triglyceride (having an oleoyl group at the 2-position and a stearoyl group and an arachidoyl group at the 1,3-position. An oil or fat composition having a content of 1.5% by mass or less is provided.
本発明の別の態様によれば、上記の油脂組成物は、ヨウ素価が26.0〜53.0である、油脂組成物が提供される。 According to another aspect of the present invention, there is provided an oil and fat composition having an iodine value of 26.0 to 53.0.
本発明の別の態様によれば、上記の油脂組成物を含有させてなるチョコレート生地が提供される。 According to another aspect of the present invention, there is provided a chocolate dough comprising the above oil composition.
本発明の別の態様によれば、上記のチョコレート生地を使用したチョコレート製品が提供される。 According to another aspect of the present invention, a chocolate product using the above chocolate dough is provided.
本発明の別の態様によれば、上記のチョコレート生地と種実類を混合してなる種実類入りチョコレート製品が提供される。 According to another aspect of the present invention, a chocolate product containing seeds and seeds is provided by mixing the above chocolate dough and seeds and seeds.
本発明の別の態様によれば、上記の油脂組成物を用いたチョコレート生地の低温ブルーム抑制方法が提供される。 According to another aspect of the present invention, there is provided a method for suppressing low-temperature bloom of chocolate dough using the above oil and fat composition.
本発明の別の態様によれば、上記の油脂組成物を用いた低温ブルーム抑制剤が提供される。 According to another aspect of the present invention, there is provided a low temperature bloom inhibitor using the above oil composition.
本発明の油脂組成物を使用したチョコレート生地は、低温ブルームを抑制することができる。加えて、従来のブロック状、板状のチョコレート製品に比べ、食感はソフトな仕上がりとなる。ブロック状、板状の形状を維持できる硬さとスナップ性を保持しつつ、適度な軟らかさを有している。ブロック状、板状に成形する以外に、コーティング用途にも適している。 The chocolate dough using the oil and fat composition of the present invention can suppress low temperature bloom. In addition, the texture is softer than conventional block and plate chocolate products. While maintaining the hardness and snapping property that can maintain the block shape and the plate shape, it has an appropriate softness. In addition to molding into blocks and plates, it is also suitable for coating applications.
このチョコレート生地に種実類を加えたチョコレート製品は、種実類のカリカリした食感を強調することができる。さらに口溶けが良いことから、ローストした香ばしさの発現も良好である。低温ブルームが抑制されることから、種実類の歯ごたえやチョコレート生地の色沢を損なわれず、製造当初の良好な硬さと外観を保つことができる。 Chocolate products obtained by adding seeds and seeds to this chocolate dough can emphasize the crunchy texture of seeds and seeds. Furthermore, since the mouth melts well, the expression of the roasted fragrance is also good. Since low-temperature bloom is suppressed, it is possible to maintain good hardness and appearance at the beginning of production without impairing the texture of the seeds and fruits and the variety of chocolate dough.
定義・分析
本発明において、油脂中のトリグリセリドとは、1分子のグリセロールに、3分子の脂肪酸がエステル結合した構造を有するものである。トリグリセリドの1、2、3位とは、脂肪酸が結合した位置を表す。なお、トリグリセリドの構成脂肪酸の略称として、以下を用いる。X:炭素数16以上の飽和脂肪酸、P:パルミチン酸、S:ステアリン酸、A:アラキジン酸、U:炭素数16以上の不飽和脂肪酸、O:オレイン酸。トリグリセリド組成の分析は、ガスクロマトグラフ法(JAOCS,vol70,11,1111−1114(1993)準拠)及び銀イオンカラム−HPLC法(J.High Resol.Chromatogr.,18,105−107(1995)準拠)を用いて行うことができる。油脂の構成脂肪酸の分析は、ガスクロマトグラフ法(AOCS Ce1f−96準拠)を用いて行うことができる。ヨウ素価は、基準油脂分析試験法(2.3.4.1−1996)に従い、ウィイス法により測定することができる。 Definitions / Analysis In the present invention, triglycerides in fats and oils have a structure in which three molecules of fatty acid are ester-bonded to one molecule of glycerol. The 1, 2, and 3 positions of triglyceride represent the positions where fatty acids are bonded. In addition, the following is used as an abbreviation for the constituent fatty acid of triglyceride. X: saturated fatty acid having 16 or more carbon atoms, P: palmitic acid, S: stearic acid, A: arachidic acid, U: unsaturated fatty acid having 16 or more carbon atoms, O: oleic acid. The triglyceride composition was analyzed by gas chromatography (JAOCS, vol 70, 11, 1111-1114 (1993)) and silver ion column-HPLC (J. High Resol. Chromatogr., 18, 105-107 (1995)). Can be used. Analysis of the constituent fatty acids of the fats and oils can be performed using a gas chromatographic method (AOCS Ce1f-96 compliant). The iodine value can be measured by the Wiis method according to the standard oil analysis test method (2.3.4.1-1996).
以下本発明の油脂組成物について順を追って記述する。
本発明の油脂組成物は低温ブルーム抑制用の油脂組成物であり、2位にオレイン酸、1、3位に炭素数16以上の飽和脂肪酸が結合したXOX型トリグリセリド(以下、XOXとも記載する)を含有することを特徴とする。XOX型トリグリセリドの含有量は、油脂組成物中に62〜80質量%である。のぞましくは62〜79質量%、さらにのぞましくは62〜75質量%である。XOXの1、3位には炭素数16以上の飽和脂肪酸が結合していれば、必ずしも同じ飽和脂肪酸が結合していなくともよい。1、3位に結合する飽和脂肪酸の炭素数は16〜26がのぞましく、より望ましくは16〜22、最ものぞましくは16〜20である。Hereinafter, the oil and fat composition of the present invention will be described in order.
The oil / fat composition of the present invention is an oil / fat composition for low-temperature bloom suppression, which is an XOX triglyceride in which oleic acid is bonded to the 2-position and a saturated fatty acid having 16 or more carbon atoms is bonded to the 3-position (hereinafter also referred to as XOX) It is characterized by containing. Content of XOX type | mold triglyceride is 62-80 mass% in an oil-fat composition. It is preferably 62 to 79% by mass, and more preferably 62 to 75% by mass. As long as a saturated fatty acid having 16 or more carbon atoms is bonded to the 1st and 3rd positions of XOX, the same saturated fatty acid is not necessarily bonded. The saturated fatty acid bonded to the 1st and 3rd positions preferably has 16 to 26 carbon atoms, more preferably 16 to 22 carbon atoms, and most preferably 16 to 20 carbon atoms.
本発明の油脂組成物は、XOX型トリグリセリドの1つとして、2位にオレイン酸、1、3位にパルミチン酸が結合したPOP型トリグリセリド(1,3−ジパルミトイル−2−オレオイルグリセリン、以下POPとも記載する)を含有することを特徴とする。油脂組成物中のPOP含有量は、15〜40質量%である。のぞましくは20〜38質量%、さらにのぞましくは20〜30質量%である。 The oil and fat composition of the present invention is a POP triglyceride (1,3-dipalmitoyl-2-oleoylglycerin, hereinafter referred to as “XOX type triglyceride” in which oleic acid is bonded to the 2nd position and palmitic acid is bonded to the 3rd position. (Also referred to as POP). The POP content in the oil / fat composition is 15 to 40% by mass. It is preferably 20 to 38% by mass, and more preferably 20 to 30% by mass.
本発明の油脂組成物は、XOX型トリグリセリドの1つとして、2位にオレイン酸、1、3位にステアリン酸が結合したSOS型トリグリセリド(1,3−ジステアロイル−2−オレオイルグリセリン、以下SOSとも記載する)を含有することを特徴とする。油脂組成物中のSOS含有量は、20〜35質量%である。のぞましくは25〜35質量%、さらにのぞましくは28〜35質量%である。 The oil and fat composition of the present invention is an SOX triglyceride (1,3-distearoyl-2-oleoyl glycerin, hereinafter referred to as “XOX type triglyceride” in which oleic acid is bonded to the 2nd position and stearic acid is bonded to the 3rd position. (Also referred to as SOS). The SOS content in the oil and fat composition is 20 to 35% by mass. It is preferably 25 to 35% by mass, and more preferably 28 to 35% by mass.
本発明の油脂組成物は、XOX型トリグリセリドの1つとして、POS型トリグリセリド(2位にオレオイル基を有し、1,3位にパルミトイル基とステアロイル基を各1基づつ有するトリグリセリド、以下POSとも記載する)を含有することを特徴とする。油脂組成物のPOS含有量は、5〜11質量%である。のぞましくは7〜10.4質量%、さらにのぞましくは7〜10質量%である。 The oil and fat composition of the present invention is a POS type triglyceride (triglyceride having an oleoyl group at the 2-position and one palmitoyl group and one stearoyl group at the 1- and 3-positions as one of XOX-type triglycerides, hereinafter referred to as POS. Which is also described). The POS content of the oil and fat composition is 5 to 11% by mass. It is preferably 7 to 10.4% by mass, and more preferably 7 to 10% by mass.
油脂組成物中に対称型トリグリセリドであるXOX、POP、SOS、POSが上記の範囲内であると、本発明の油脂組成物を用いて製造されたチョコレート生地は、低温ブルームが抑制される。また、ブロック状、板状の成形に必要な適度な硬さと口溶けが付与される。 When the fat and oil composition contains XOX, POP, SOS, and POS, which are symmetric triglycerides, within the above range, the chocolate dough produced using the oil and fat composition of the present invention has low temperature bloom. Moreover, moderate hardness and meltability required for block-shaped and plate-shaped molding are imparted.
本発明の油脂組成物は、XOX型トリグリセリドの1つとして、のぞましくはSOA型トリグリセリド(2位にオレオイル基を有し、1,3位にステアロイル基とアラキドイル基を各1基づつ有するトリグリセリド、以下SOAとも記載する)を含有する。油脂組成物のSOA含有量は、のぞましくは1.5質量%以下、さらにのぞましくは0.1〜1.5質量%、最ものぞましくは0.1〜1.0質量%である。SOAが上記の範囲内であると、油脂の固化速度が上昇するため、チョコレート生地の製造時における作業性をより向上させることができる。Aはアラキジン酸である。またアラキドイル基はアラキジン酸残基のことである。 The oil composition of the present invention is preferably an SOA triglyceride (having an oleoyl group at the 2-position and one stearoyl group and one arachidoyl group at the 1,3-positions) as one of the XOX-type triglycerides. Having triglycerides, hereinafter also referred to as SOA). The SOA content of the oil / fat composition is preferably 1.5% by mass or less, more preferably 0.1 to 1.5% by mass, most preferably 0.1 to 1.0%. % By mass. When the SOA is within the above range, the solidification rate of the fat increases, so that the workability during the production of the chocolate dough can be further improved. A is arachidic acid. The arachidoyl group is an arachidic acid residue.
油脂組成物中の液状油脂含量は、15〜35質量%である。のぞましくは17〜30質量%、さらにのぞましくは22〜30質量%である。液状油脂含有量がこの範囲にあると、本発明の油脂組成物を用いて製造されたチョコレート生地は、適度な軟らかさが付与される。またコーティングに用いた際のチョコレート生地の伸びが良いものとなる。 The liquid fat content in the fat composition is 15 to 35% by mass. It is preferably 17 to 30% by mass, and more preferably 22 to 30% by mass. When the liquid fat content is within this range, the chocolate dough produced using the fat composition of the present invention is given moderate softness. Moreover, the elongation of the chocolate dough when used for coating is good.
本発明でいう液状油脂は、1分子中に二重結合を2つ以上持つトリグリセリドの合計量をいう。本発明の油脂組成物に含有される液状油脂のトリグリセリド組成は、例えば、PLP、POO、PLS、POL、PLL、SOO、SLS、OOO、SOL、OOLである。Pはパルミチン酸、Lはリノール酸、Oはオレイン酸、Sはステアリン酸である。 The liquid fat according to the present invention refers to the total amount of triglycerides having two or more double bonds in one molecule. The triglyceride composition of the liquid fat contained in the fat composition of the present invention is, for example, PLP, POO, PLS, POL, PLL, SOO, SLS, OOO, SOL, or OOL. P is palmitic acid, L is linoleic acid, O is oleic acid, and S is stearic acid.
上記の液状油脂中は、1、2、3位の全てに炭素数16以上の不飽和脂肪酸が結合したトリグリセリド(UUU型トリグリセリド)と、1位に炭素数16以上の飽和脂肪酸が結合し、2、3位に炭素数16以上の不飽和脂肪酸が結合したトリグリセリド(XUU型トリグリセリド)とを含むことがのぞましい。上記の油脂組成物中、UUU型トリグリセリドの含有量は、のぞましくは0.3〜5.0質量%であり、よりのぞましくは0.7〜4.0質量%であり、さらにのぞましくは1.0〜3.0質量%である。また、上記の油脂組成物中、XUU型トリグリセリドの含有量は、のぞましくは4.0〜26質量%であり、よりのぞましくは6.0〜24質量%であり、さらにのぞましくは8.5〜22質量%である。 In the above-mentioned liquid fats and oils, triglycerides (UUU type triglycerides) in which unsaturated fatty acids having 16 or more carbon atoms are bonded to all 1, 2, and 3 positions, and saturated fatty acids having 16 or more carbon atoms are bonded to the 1st positions. It is desirable to include a triglyceride (XUU type triglyceride) in which an unsaturated fatty acid having 16 or more carbon atoms is bonded to the 3-position. In the oil composition, the content of UUU-type triglyceride is preferably 0.3 to 5.0% by mass, more preferably 0.7 to 4.0% by mass, More preferably, it is 1.0-3.0 mass%. Further, in the above oil and fat composition, the content of XUU type triglyceride is preferably 4.0 to 26% by mass, more preferably 6.0 to 24% by mass, Preferably, it is 8.5 to 22% by mass.
また本発明の油脂組成物は、液状油脂のUUU/(XUU+UUU)のトリグリセリド比が0.08〜0.15であることがのぞましい。さらにのぞましくは0.09〜0.12である。Uは炭素数16以上の不飽和脂肪酸である。不飽和脂肪酸の炭素数は16〜26がのぞましく、より望ましくは16〜22、最ものぞましくは16〜20である。Xは炭素数16以上の飽和脂肪酸である。飽和脂肪酸の炭素数は16〜26がのぞましく、より望ましくは16〜22、最ものぞましくは16〜20である。例えば、SOLはXUU、OOOはUUUである。UUU/(XUU+UUU)のトリグリセリド比がこの範囲にあると、低温ブルームが抑制される。また種実類とチョコレート生地との間の油脂移行を抑制することができる。 Moreover, it is preferable that the oil-and-fat composition of this invention is 0.08 to 0.15 in the triglyceride ratio of UUU / (XUU + UUU) of liquid oil. More preferably, it is 0.09 to 0.12. U is an unsaturated fatty acid having 16 or more carbon atoms. The carbon number of the unsaturated fatty acid is preferably 16 to 26, more preferably 16 to 22, and most preferably 16 to 20. X is a saturated fatty acid having 16 or more carbon atoms. The saturated fatty acid preferably has 16 to 26 carbon atoms, more preferably 16 to 22 carbon atoms, and most preferably 16 to 20 carbon atoms. For example, SOL is XUU and OOO is UUU. When the triglyceride ratio of UUU / (XUU + UUU) is within this range, low temperature bloom is suppressed. Moreover, the fats and oils transfer between a seed seed and chocolate dough can be suppressed.
本発明の油脂組成物は、本発明の構成要件を満たしていればどのような油脂原料、加工方法を用いることができる。天然油脂原料を単品で用いても、2種以上をブレンドしてもよい。また分別、エステル交換、水素添加等の加工を施した油脂でもよい。本発明の油脂組成物に用いられる好ましい油脂原料として、例えばパーム分別油、シア脂ステアリン、サル脂ステアリン、エステル交換により製造したXOX型トリグリセリドに富む油脂などが挙げられる。 Any oil and fat raw material and processing method can be used for the oil and fat composition of the present invention as long as the constituent requirements of the present invention are satisfied. The natural fat / oil raw material may be used alone or in combination of two or more. Moreover, the fats and oils which gave processes, such as fractionation, transesterification, and hydrogenation, may be sufficient. Examples of preferable fats and oils used in the oil and fat composition of the present invention include palm fractionated oil, shea fat stearin, sal fat stearin, fats and oils rich in XOX type triglyceride produced by transesterification, and the like.
パーム分別油は、パーム油を乾式分別または溶剤分別あるいは乳化分別することによって得られるオレイン部(液状部)、ステアリン部(固体脂部)の両方を使用することができる。パームステアリン部をさらに分別したオレイン部や、パームオレイン部をさらに分別したステアリン部などのパーム油の中融点部は、本発明の油脂組成物に含有されるXOX型トリグリセリドの供給源とすることができる。 As the palm fractionated oil, both olein part (liquid part) and stearin part (solid fat part) obtained by subjecting palm oil to dry fractionation, solvent fractionation or emulsion fractionation can be used. The middle melting point part of palm oil such as an olein part obtained by further separating the palm stearin part and a stearin part obtained by further separating the palm olein part may be used as a source of the XOX type triglyceride contained in the oil and fat composition of the present invention. it can.
また、パームオレイン部、さらに2段階分別あるいは3段階分別したオレイン部は、本発明の油脂組成物に含有される液状油脂の供給源とすることができる。本発明の油脂組成物に含有される液状油脂(1分子中に二重結合が2つ以上存在するトリグリセリド)の供給源として、これらのパーム分別軟質油が好ましい。 Moreover, the palm olein part and the olein part classified into 2 steps | paragraphs or 3 steps | paragraphs can be used as the supply source of the liquid fat contained in the fat composition of this invention. These palm fraction soft oils are preferred as a source of liquid oil (triglyceride having two or more double bonds in one molecule) contained in the oil composition of the present invention.
XOX型トリグリセリドに富む油脂は、例えばトリグリセリドの2位にオレイン酸が多いハイオレイックヒマワリ油等の油脂とステアリン酸エチルエステル、パルミチン酸エチルエステルなどを用い、1、3位選択性を有する酵素剤を使用し、既知の方法によりエステル交換反応を行うことで製造することができる。分別により中融点部を分取することで、XOX型トリグリセリドの濃度が高まるため、本発明の油脂組成物の好適な供給源とすることができる。 The fats and oils rich in XOX type triglycerides use, for example, fats and oils such as high oleic sunflower oil with high oleic acid at the 2-position of triglycerides, stearic acid ethyl ester, palmitic acid ethyl ester, etc. And can be produced by performing a transesterification reaction by a known method. Since the concentration of the XOX type triglyceride is increased by separating the middle melting point portion by fractionation, it can be a suitable supply source of the oil and fat composition of the present invention.
本発明の油脂組成物は、例えばエステル交換によって得られたXOX型トリグリセリドに富む油脂を25〜60質量%、パーム油の中融点部が10〜60質量%、パーム分別軟質油を0〜40質量%の割合で配合することがのぞましい。よりのぞましくは、エステル交換によって得られたXOX型トリグリセリドに富む油脂を35〜55質量%、パーム油の中融点部が15〜40質量%、パーム分別軟質油を5〜35質量%である。最ものぞましくは、エステル交換によって得られたXOX型トリグリセリドに富む油脂を35〜50質量%、パーム油の中融点部が15〜30質量%、パーム分別軟質油を10〜35質量%である。 The oil and fat composition of the present invention is, for example, 25 to 60% by mass of fat and oil rich in XOX triglyceride obtained by transesterification, 10 to 60% by mass of the middle melting point of palm oil, and 0 to 40% by mass of palm fractionated soft oil. It is recommended to blend at a ratio of%. More preferably, the oil and fat rich in XOX type triglyceride obtained by transesterification is 35 to 55% by mass, the middle melting point of palm oil is 15 to 40% by mass, and the palm fraction soft oil is 5 to 35% by mass. is there. Most preferably, the oil rich in XOX triglyceride obtained by transesterification is 35 to 50% by mass, the middle melting point of palm oil is 15 to 30% by mass, and the palm fractionated soft oil is 10 to 35% by mass. is there.
本発明の油脂組成物のヨウ素価は、好ましくは26.0〜53.0、より好ましくは33.0〜48.0、さらに好ましくは40.5〜44.0である。ヨウ素価が上記範囲内であれば、低温ブルームが抑制される。また種実類とチョコレート生地との間の油脂移行を抑制することができる。 The iodine value of the oil and fat composition of the present invention is preferably 26.0 to 53.0, more preferably 33.0 to 48.0, and still more preferably 40.5 to 44.0. When the iodine value is within the above range, low temperature bloom is suppressed. Moreover, the fats and oils transfer between a seed seed and chocolate dough can be suppressed.
本発明の油脂組成物には、先に挙げた油脂以外でも本発明の構成要件を満たしていればどのような油脂原料を用いることができる。例えば、大豆油、菜種油、パーム油、綿実油、サフラワー油、ひまわり油、米油、コーン油、ゴマ油、オリーブ油、牛脂、豚脂、乳脂などの動植物油脂あるいはそれらの加工油脂の中から1種以上を選択して使用することができる。 Any oil / fat raw material can be used for the oil / fat composition of the present invention other than the oils and fats listed above as long as the constituents of the present invention are satisfied. For example, one or more of animal and vegetable oils such as soybean oil, rapeseed oil, palm oil, cottonseed oil, safflower oil, sunflower oil, rice oil, corn oil, sesame oil, olive oil, beef tallow, lard, milk fat, or processed oils thereof Can be selected and used.
本発明の油脂組成物は、通常、油脂以外の成分を含まないが、本発明の効果を損なわない限りにおいて、油脂以外の成分を少量加えることができる。これらは、油脂に溶解する油溶性成分であることがのぞましく、例えば、乳化剤、抗酸化剤、香料等が挙げられる。これらの添加量は油脂組成物に対して好ましくは5質量%未満、より好ましくは3質量%未満、さらに好ましくは1質量%未満である。 The oil and fat composition of the present invention usually does not contain components other than fats and oils, but a small amount of components other than fats and oils can be added as long as the effects of the present invention are not impaired. These are preferably oil-soluble components that dissolve in fats and oils, and examples include emulsifiers, antioxidants, and fragrances. These addition amounts are preferably less than 5% by mass, more preferably less than 3% by mass, and even more preferably less than 1% by mass with respect to the oil and fat composition.
本発明のチョコレート生地は、本発明の油脂組成物を原材料として使用したものをいう。またカカオ分を含まないチョコレート様の生地も本発明のチョコレート生地に含まれる。本発明の油脂組成物を用いる以外は、通常のチョコレート生地に用いられる原材料や製造方法を採用することができる。 The chocolate dough of the present invention refers to one using the oil and fat composition of the present invention as a raw material. A chocolate-like dough that does not contain cacao is also included in the chocolate dough of the present invention. Except for using the oil and fat composition of the present invention, raw materials and manufacturing methods used for ordinary chocolate dough can be employed.
本発明のチョコレート生地に使用される原材料として、通常、チョコレート生地を製造する際に用いられる食材であれば制限なく使用することができる。例えば、砂糖、粉末水飴などの糖類、本発明の油脂組成物以外の油脂(乳脂肪やカカオバター、カカオ代用脂など)、脱脂粉乳、全脂粉乳などの乳製品、コーヒー粉末、カカオマス、ココアパウダー、澱粉、野菜や果実の加工品などを挙げることができる。 As a raw material used for the chocolate dough of the present invention, it can be used without limitation as long as it is a food used for producing a chocolate dough. For example, sugars such as sugar and powdered starch syrup, fats and oils other than the fat composition of the present invention (milk fat, cacao butter, cacao substitute fat, etc.), dairy products such as skim milk powder, whole milk powder, coffee powder, cacao mass, cocoa powder And processed products of starch, vegetables and fruits.
添加剤についても、通常、チョコレート生地に用いる添加剤であれば、効果を損ねない程度に用いることができる。乳化剤、酸化防止剤、着色料、香料、などを挙げることができる。 Also about an additive, if it is an additive normally used for chocolate dough, it can be used to such an extent that an effect is not spoiled. An emulsifier, antioxidant, a coloring agent, a fragrance | flavor, etc. can be mentioned.
本発明のチョコレート生地における本発明の油脂組成物の含有量は、チョコレート生地の中3〜50質量%であり、のぞましくは5〜40質量%、最ものぞましくは7〜20質量%である。 Content of the oil-fat composition of this invention in the chocolate dough of this invention is 3-50 mass% in chocolate dough, preferably 5-40 mass%, most preferably 7-20 mass. %.
本発明のチョコレート生地に、本発明の油脂組成物以外の油脂を併用する場合は、カカオバターとの混合油脂であることが好ましい。カカオバターを含有させるものについては、カカオ脂の使用量はチョコレート生地中の3質量%以上であり、のぞましくは10質量%以上、最ものぞましくは18質量%以上である。カカオバターと本発明の油脂組成物の混合比は5〜90:10〜95であり、のぞましくは、10〜80:20〜90、最ものぞましくは30〜60:40〜70である。 When using together fats and oils other than the oil-fat composition of this invention with the chocolate dough of this invention, it is preferable that it is a mixed fat with cacao butter. About what contains cocoa butter, the usage-amount of cocoa butter is 3 mass% or more in chocolate dough, Preferably it is 10 mass% or more, Most preferably, it is 18 mass% or more. The mixing ratio of cocoa butter and the oil and fat composition of the present invention is 5 to 90:10 to 95, preferably 10 to 80:20 to 90, most preferably 30 to 60:40 to 70. It is.
本発明のチョコレート生地は、チョコレート生地を製造する通常の方法により製造することができる。本発明の油脂組成物を使用することによって、チョコレート生地の低温ブルームを抑制する方法とすることができる。一般的なチョコレート生地は、原材料を混合させた後に、ロール掛けによるリファイニング、コンチング、テンパリング、充填・成形の工程で製造される。 The chocolate dough of this invention can be manufactured by the normal method of manufacturing chocolate dough. By using the oil and fat composition of the present invention, a method for suppressing low temperature bloom of chocolate dough can be obtained. A general chocolate dough is manufactured by mixing raw materials and then performing refining by rolling, conching, tempering, filling and molding.
本発明のチョコレート生地は、種実類を混合し、種実類入りチョコレート製品を製造することができる。本発明でいう種実類とは、日本食品標準栄養成分表に記載されているアーモンド、マカデミアナッツ、ヘーゼルナッツ、ピーナッツ、ゴマなどのナッツ類を指す。種実類はローストしたもの、薄皮をむいたもの、細かく刻むなどの加工したものが好ましい。チョコレート生地に種実類特有の歯ごたえを付与するためには、種実類はペースト状ではなく、形状を留めているもののほうが好ましい。種実類の添加量は、種実類入りチョコレート製品中5〜50質量%がのぞましく、さらに10〜45質量%がのぞましく、最ものぞましくは20〜40質量%である。 The chocolate dough of the present invention can be mixed with seeds and seeds to produce a seeded chocolate product. The seeds and nuts referred to in the present invention refer to nuts such as almonds, macadamia nuts, hazelnuts, peanuts, sesame and the like described in the Japanese Food Standard Nutrition Facts Table. The seeds and seeds are preferably roasted, peeled, or finely chopped. In order to give the chocolate dough a texture specific to seeds and seeds, it is preferable that the seeds and seeds are not pasty but have a fixed shape. The amount of seeds and seeds added is preferably 5 to 50% by weight, more preferably 10 to 45% by weight, and most preferably 20 to 40% by weight in the chocolate product containing seeds and seeds.
本発明の低温ブルーム抑制剤は、本発明の油脂組成物を用いたものである。該油脂組成物のトリグリド組成については、上記で説明したとおりである。上記のトリグリセリド組成を有する油脂組成物を用いた低温ブルーム抑制剤をチョコレート生地の油脂中に配合することで、低温ブルームの発生を抑制することができる。 The low-temperature bloom inhibitor of the present invention uses the oil and fat composition of the present invention. The triglyceride composition of the oil / fat composition is as described above. Generation | occurrence | production of a low temperature bloom can be suppressed by mix | blending the low temperature bloom inhibitor using the oil-and-fat composition which has said triglyceride composition in the fats and oils of chocolate dough.
本発明の低温ブルーム抑制剤は、チョコレート生地中に、好ましくは3〜50質量%、より好ましくは5〜40質量%、さらに好ましくは7〜20質量%配合することが好ましい。 The low-temperature bloom inhibitor of the present invention is preferably blended in the chocolate dough, preferably 3 to 50% by mass, more preferably 5 to 40% by mass, and even more preferably 7 to 20% by mass.
次に、実施例及び比較例を挙げ、本発明を更に詳しく説明するが、本発明はこれらに何ら制限されるものではない。 EXAMPLES Next, although an Example and a comparative example are given and this invention is demonstrated in more detail, this invention is not restrict | limited at all to these.
以下において「%」とは、特別な記載がない場合、質量%を示す。 In the following, “%” indicates mass% unless otherwise specified.
〔油脂組成物の製造〕
ハイオレイックヒマワリ油とステアリン酸エチルエステルとを、1、3位位置特異性リパーゼによりエステル交換を行い、トリグリセリドの1又は3位にステアリン酸が結合するように反応させた。このエステル交換油を分別により、SOS型トリグリセリド濃度を高めたSOS−FAT(日清オイリオグループ株式会社:社内製)を製造した。[Production of oil and fat composition]
High oleic sunflower oil and stearic acid ethyl ester were transesterified with a 1,3-position specific lipase and reacted so that stearic acid was bound to the 1- or 3-position of the triglyceride. This transesterified oil was fractionated to produce SOS-FAT (Nisshin Oilio Group Co., Ltd .: in-house) with an increased SOS type triglyceride concentration.
さらにSOS−FATとパーム中融点部(日清オイリオグループ株式会社:社内製)、パーム軟質部(日清オイリオグループ株式会社:社内製)、シア脂ステアリン(日清オイリオグループ株式会社:社内製)を種々の割合で混合し、表1、2のような油脂組成物、実施例1〜6と比較例1〜3を得た。成分分析はGLC法によりおこなった。 Furthermore, SOS-FAT and palm mid-melting point (Nisshin Oillio Group Co., Ltd .: made in-house), palm soft part (Nisshin Oillio Group Co., Ltd .: made in-house), shea stearin (Nisshin Oillio Group Co., Ltd .: in-house) Were mixed in various proportions to obtain oil and fat compositions as shown in Tables 1 and 2, Examples 1 to 6 and Comparative Examples 1 to 3. Component analysis was performed by the GLC method.
また、上記で製造した実施例1〜6および比較例1〜3の油脂組成物のヨウ素価を、基準油脂分析試験法(2.3.4.1−1996)に従い、ウィイス法により測定した。測定結果は表3、4に示すとおりであった。 Moreover, the iodine number of the oil-fat composition of Examples 1-6 manufactured above and Comparative Examples 1-3 was measured by the Wiis method according to the standard oil-fat analysis test method (2.3.4.1-1996). The measurement results were as shown in Tables 3 and 4.
〔油脂組成物の固化速度の評価〕
上記で製造した実施例2及び実施例6の油脂組成物を用いて、以下の方法で固化速度を測定した。完全に溶融した各油脂組成物を30℃まで冷却し、シード剤を0.5質量%となるように添加して分散させ、20℃の水槽中で冷却したときの経時的な固体脂含量(SFC)を測定した。固体脂含量は、基準油脂分析試験法(2.2.9−2003 固体脂含量(NMR法))に従い、測定した。なお、シード剤とは、チョコレートを固化する時に結晶核として作用する物質であり、通常、XOX型トリグリセリドのV型結晶を含む油脂である。[Evaluation of solidification rate of oil and fat composition]
Using the oil and fat compositions of Example 2 and Example 6 produced above, the solidification rate was measured by the following method. Each fat composition that has been completely melted is cooled to 30 ° C., the seed agent is added and dispersed so as to be 0.5% by mass, and the solid fat content over time when cooled in a 20 ° C. water bath ( SFC) was measured. The solid fat content was measured according to the standard fat analysis method (2.2.9-2003 solid fat content (NMR method)). The seed agent is a substance that acts as a crystal nucleus when the chocolate is solidified, and is usually an oil containing V-type crystals of XOX triglyceride.
測定結果は表5に示すとおりであった。実施例2の油脂組成物は、実施例6の油脂組成物に比べて固化速度が上がっているため、チョコレート生地の製造時における作業性を向上させることができる。 The measurement results are as shown in Table 5. Since the fat and oil composition of Example 2 has a higher solidification rate than the fat and oil composition of Example 6, it is possible to improve workability at the time of manufacturing the chocolate dough.
〔チョコレート生地配合〕 [Contains chocolate dough]
〔チョコレート生地の製造方法〕
実施例1〜6、比較例1〜3の油脂組成物を用い、表6の配合で常法に従って製造し、チョコレート生地を得た。[Production method of chocolate dough]
Using the oil and fat compositions of Examples 1 to 6 and Comparative Examples 1 to 3, the composition of Table 6 was used in accordance with a conventional method to obtain a chocolate dough.
〔種実類入りチョコレート製品の製造方法〕
テンパリング後の表6チョコレート生地60%に対してローストしたピーナツ40%を混ぜて冷却固化し、種実類入りチョコレート製品を得た。[Manufacturing method of chocolate products with seeds and seeds]
Table 6 Chocolate material 60% after tempering was mixed with roasted peanut 40% and solidified by cooling to obtain a chocolate product containing seeds and seeds.
〔種実類入りチョコレート製品の評価方法〕
製造した種実類入りチョコレート製品を20℃に保管し、1週間後に下記の項目を評価した。評価結果は表7、8のとおりであった。
(1)ブルーム:チョコレートにブルームの発生の有無を目視で確認する。
評点5・・・ブルームの発生はみられない。なおかつ表面に光沢がある。
4・・・ブルームの発生はみられない。
3・・・ブルームははっきり判別できないが、表面にムラがみられる。
2・・・ブルームの発生がみられる。
1・・・ブルームがチョコレートの全体を覆うように発生している。
(2)食味:チョコレートとピーナツの食感についてチョコレートを食して官能評価を行う。チョコとピーナツについて、チョコ食味、ピーナツ食味として下記のように評価した。
(チョコ食味)
評点5・・チョコレートは製造直後の硬さを保ち、口溶けは良好である。
4・・チョコレートは適度な硬さをもち、口溶けは良好である。
3・・チョコレートはやや軟らかくなっているが、口溶けは良好である。
2・・チョコレートが軟らかくなり、べたべたして形状が崩れやすい。
1・・チョコレートが軟らかくなり、形状を保つのが困難。
(ピーナツ食味)
評点5・・ピーナツは製造直後のカリカリとした食感保ち、香ばしい風味が感じられる。
4・・ピーナツは適度な硬さをもち、香ばしい風味が感じられる。
3・・ピーナツはややガリガリしているか、またはやや軟らかい硬さだが、
ナッツ特有の風味が感じられる。
2・・ピーナツはやや軟らかく、色沢が見られず、香ばしさが少ない。
1・・ピーナツはガリガリした硬さで、色が白濁し、香ばしさが感じられない。[Method for evaluating chocolate products with seeds and seeds]
The produced chocolate products with seeds and nuts were stored at 20 ° C., and the following items were evaluated after one week. The evaluation results are shown in Tables 7 and 8.
(1) Bloom: The presence or absence of bloom in the chocolate is confirmed visually.
Score 5: Bloom is not observed. Moreover, the surface is glossy.
4 ... No bloom is observed.
3 ... Bloom cannot be clearly identified, but the surface is uneven.
2 ... Bloom is observed.
1 ... Bloom is generated so as to cover the entire chocolate.
(2) Taste: The chocolate and peanuts are eaten with a chocolate for sensory evaluation. About chocolate and peanut, it evaluated as follows as chocolate taste and peanut taste.
(Chocolate taste)
Rating 5 ··· Chocolate maintains the hardness immediately after production and melts well in the mouth.
4. Chocolate has moderate hardness and good melting in the mouth.
3. Chocolate is slightly soft but melts well in the mouth.
2. The chocolate becomes soft and sticky and easily loses its shape.
1 ・ ・ Chocolate becomes soft and difficult to keep in shape.
(Peanut taste)
Score 5 ・ ・ Peanuts have a crunchy texture immediately after production and have a fragrant flavor.
4. Peanuts have moderate hardness and a savory flavor.
3. Peanuts are slightly crisp or slightly soft,
The flavor unique to nuts is felt.
2 ・ ・ Peanuts are slightly soft, do not look colorful, and have little fragrance.
1 ・ ・ Peanuts are crunchy, the color is cloudy and no fragrance is felt.
〔種実類入りチョコレート製品の評価結果〕 [Evaluation results of chocolate products with seeds]
〔ナッツ入りクッキー生地配合〕 [Contains cookie dough with nuts]
〔ナッツ入りクッキーの製造方法〕
表9のクッキー生地をシュガーバッター法に従って生地を調整し、20gに分割・成形後、170℃のオーブンで焼成した。[Method of manufacturing cookies with nuts]
The cookie doughs in Table 9 were prepared according to the sugar batter method, divided into 20 g and molded, and then baked in an oven at 170 ° C.
〔チョコレートコーティングクッキーの製造方法〕
上記で焼成した表9のクッキーに実施例7〜12、比較例4〜6のチョコレート生地をテンパリング後、ナッツ入りクッキーにチョコレートをコーティングしたチョコレート製品を得た。[Method for producing chocolate-coated cookies]
After tempering the chocolate doughs of Examples 7-12 and Comparative Examples 4-6 to the cookies of Table 9 baked as described above, a chocolate product obtained by coating chocolate on nut-containing cookies was obtained.
〔チョコレートコーティングクッキーの評価方法〕
製造したチョコレートコーティングクッキーを(1)作業性と20℃に1週間保管した後の(2)ブルームを下記の項目を評価した。評価結果は表10、11のとおりであった。
(1)作業性:チョコレートコーティング時の作業性について評価する。
評点A・・・チョコレート生地は均一に薄く伸び、乾きが良好。
B・・・チョコレート生地は均一に伸びる、乾きが良好。
C・・・チョコレート生地は伸びが悪い。または伸びが良好だが乾きが悪い。
(2)ブルーム:チョコレートにブルームの発生の有無を目視で確認する。
評点5・・・ブルームの発生はみられない。なおかつ表面に光沢がある。
4・・・ブルームの発生はみられない。
3・・・ブルームははっきり判別できないが、表面にムラがみられる。
2・・・ブルームの発生がみられる。
1・・・ブルームがチョコレートの全体を覆うように発生している。[Method for evaluating chocolate-coated cookies]
The manufactured chocolate coated cookies were evaluated for the following items: (1) workability and (2) bloom after storage at 20 ° C. for 1 week. The evaluation results were as shown in Tables 10 and 11.
(1) Workability: Workability at the time of chocolate coating is evaluated.
Score A: The chocolate dough is uniformly thin and stretches well.
B: The chocolate dough is uniformly stretched and dry.
C: The chocolate dough does not stretch well. Or the elongation is good but the drying is bad.
(2) Bloom: The presence or absence of bloom in the chocolate is visually confirmed.
Score 5: Bloom is not observed. Moreover, the surface is glossy.
4 ... No bloom is observed.
3 ... Bloom cannot be clearly identified, but the surface is uneven.
2 ... Bloom is observed.
1 ... Bloom is generated so as to cover the entire chocolate.
〔チョコレートコーティングクッキーの評価結果〕 [Evaluation results of chocolate coating cookies]
Claims (10)
前記液状油脂中の、UUU型/(XUU型+UUU型)のトリグリセリド比が0.08〜0.15である、請求項1又は2に記載の油脂組成物。 The liquid fat is a triglyceride (UUU type triglyceride) in which an unsaturated fatty acid having 16 or more carbon atoms is bonded to all of 1, 2, and 3 positions, and a saturated fatty acid having 16 or more carbon atoms is bonded to the first position. A triglyceride (XUU type triglyceride) in which an unsaturated fatty acid having 16 or more carbon atoms is bonded to the position,
Wherein in the liquid fat, UUU type / (XUU type + UUU type) triglycerides ratio is 0.08 to 0.15, fat composition according to claim 1 or 2.
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BR112014010386B1 (en) | 2011-11-02 | 2019-11-12 | Fuji Oil Co Ltd | combined oil or fat composition, alternative cocoa butter, chocolate and confectionery |
JP5901345B2 (en) * | 2012-02-27 | 2016-04-06 | 日清オイリオグループ株式会社 | Chocolate for frozen dessert |
KR101968892B1 (en) | 2012-02-29 | 2019-04-12 | 가부시키가이샤 메이지 | Baked confectionery and method for manufacturing same |
WO2013146834A1 (en) * | 2012-03-30 | 2013-10-03 | 不二製油株式会社 | Oil or fat composition and chocolate |
KR101984347B1 (en) * | 2012-08-29 | 2019-05-30 | 닛신 오일리오그룹 가부시키가이샤 | Combined confectionery |
JP6313554B2 (en) * | 2013-07-29 | 2018-04-18 | 日清オイリオグループ株式会社 | chocolate |
JP6254595B2 (en) * | 2013-07-29 | 2017-12-27 | 日清オイリオグループ株式会社 | Chocolate and hard butter |
JP5864685B2 (en) * | 2013-09-02 | 2016-02-17 | 日清オイリオグループ株式会社 | chocolate |
CN105517444A (en) * | 2013-09-06 | 2016-04-20 | 日清奥利友集团株式会社 | Chocolate |
CN105873446B (en) * | 2013-12-19 | 2020-04-28 | 日清奥利友集团株式会社 | Oil and fat |
JP5940612B2 (en) * | 2014-08-27 | 2016-06-29 | ニッシン グローバル リサーチ センター エスディエヌ ビーエイチディー | Oil composition and chocolate |
JP6050923B1 (en) * | 2015-05-28 | 2016-12-21 | 日清オイリオグループ株式会社 | chocolate |
WO2018222116A1 (en) * | 2017-05-30 | 2018-12-06 | Aak Ab | Anti-blooming composition |
JP6509398B2 (en) * | 2018-03-23 | 2019-05-08 | 日清オイリオグループ株式会社 | chocolate |
CN111357832B (en) * | 2018-12-25 | 2023-04-07 | 丰益(上海)生物技术研发中心有限公司 | Chocolate-flavored margarine and preparation method thereof |
JP6969708B1 (en) * | 2020-03-11 | 2021-11-24 | 不二製油株式会社 | Oils and fats for chocolates suitable for complex confectionery |
JP7460277B2 (en) | 2020-03-26 | 2024-04-02 | 日清オイリオグループ株式会社 | chocolate |
CN114521595A (en) * | 2020-11-23 | 2022-05-24 | 丰益(上海)生物技术研发中心有限公司 | Oil composition and application thereof in chocolate |
CN114097915B (en) * | 2021-11-25 | 2023-04-28 | 江南大学 | Oil composition for chocolate |
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