JP5756307B2 - Catalyst tower and wet deodorizing apparatus using the same - Google Patents

Description

The present invention relates to a wet deodorization apparatus mainly used for removing sulfur-based odor components from odor gas discharged from human waste treatment facilities, garbage treatment facilities, sewage treatment facilities, etc. The present invention relates to a catalyst tower that is circulated and supplied to a deodorizing carrier, and deodorized by passing an odor gas through a deodorizing carrier including a cleaning liquid, and a wet deodorizing apparatus using the catalyst tower .

  Odor gases emitted from human waste treatment facilities, waste treatment facilities, sewage treatment facilities, etc. mainly include basic odor components such as ammonia and amines, and sulfur such as hydrogen sulfide, methyl mercaptan, methyl sulfide, and methyl disulfide. Contains system odor components. The deodorizer is mainly used to remove these odor components.

  Patent document 1 is disclosing one of the conventional wet deodorizing apparatuses. The apparatus includes a deodorization tower having an odor gas inlet and a deodorized gas outlet, a storage tank for storing a cleaning liquid, and a filling unit in which a resin carrier is filled above the inlet and the storage tank. An injection part for injecting the cleaning liquid toward the filling part below the outlet and above the filling part, a pipe line connecting the storage tank and the injection part, a pump for sending the cleaning liquid from the storage tank to the injection part, etc. I have. And an odor component is removed by oxidizing odor gas with the support | carrier with which the washing | cleaning liquid was injected.

  The cleaning liquid circulating in the wet deodorizing apparatus contains a sulfur component. When this sulfur component is crystallized, it is deposited in the apparatus as a so-called “sulfur scale”. Patent document 2 is disclosing one of the removal methods of a sulfur scale.

JP 2009-112955 A JP-A-4-141299

Conventional wet deodorization apparatuses generally maintain smooth operation of the apparatus by periodically removing sulfur scale. However, the work of removing sulfur scale is easy and is rather than, enormous cost and time had Tsu written.

  As a result of examining the generation mechanism of sulfur scale, the present inventor has obtained the following conclusion. That is, in the case of the wet deodorizing apparatus, a part of the sulfur component in the odor gas taken into the apparatus is dissolved in the cleaning liquid, so that the concentration of the sulfur component in the cleaning liquid increases with the operation time. And it is thought that crystallization advances everywhere in an apparatus because the washing | cleaning liquid containing a high concentration sulfur component circulates in the apparatus. In fact, it was confirmed that the cleaning liquid of the wet deodorization apparatus immediately after the maintenance work after a long operation itself has a considerable odor and contains a high concentration of sulfur component.

  An object of the present invention is to drastically reduce the frequency of maintenance work of an apparatus by effectively suppressing the generation of sulfur scale, rather than removing the sulfur scale after it is generated.

The wet deodorization apparatus according to the present invention includes a deodorization tower 2 having an odor gas inlet 24 containing a sulfur-based odor component and a deodorized gas outlet 21, a storage tank 25 for storing the cleaning liquid 5, and A filling part 23 for filling the deodorizing carrier 6 inside the deodorizing tower above the inlet and the storage tank, and a filling part for the cleaning liquid inside the deodorizing tower below the outlet and above the filling part For deodorization in which the cleaning liquid is sprayed, including the injection section 22 that injects toward the tank, the first pipe 3 that connects the storage tank and the injection section, and the pump 4 for sending the cleaning liquid from the storage tank to the injection section. The wet deodorization apparatus 1 for deodorizing odorous gas with a carrier 6 further includes a catalyst tower 14 for the purpose of oxidizing the cleaning liquid itself, and the catalyst tower 14 includes a plurality of first degassing devices at least on the inlet side of the cleaning liquid. A first catalyst layer composed of an oxidation catalyst body of The Rukoto that having a second catalyst layer composed of first second oxidation catalyst more smaller than the oxidation catalyst body wherein the outlet side.

According to this configuration, even if sulfur generated during the deodorization of the odor gas containing the sulfur-based odor component is contained in the cleaning liquid 5, the oxidation catalyst 7 converts the sulfur into water-soluble sulfur-containing ions, for example, water-soluble sulfate ions. Oxidation to the extent that the crystallization of the sulfur component contained in the cleaning liquid 5 can be suppressed, and deposition in the apparatus as a sulfur scale can be suppressed. In addition, since the catalyst tower has a multilayer structure composed of oxidation catalyst bodies having different sizes, the catalyst tower is composed of small oxidation catalyst bodies that are first passed by oxidizing and removing large sulfur crystals and impurities. Sulfur can be efficiently oxidized by the catalyst layer, and clogging of the catalyst tower can be prevented. The oxidation catalyst 7 can be replaced with another substance as long as it can function to suppress crystallization of the sulfur component contained in the cleaning liquid. In this sense, the “oxidation catalyst” is understood in a broad sense.

The wet deodorization apparatus according to the present invention further includes a second pipe 8 that is branched in the middle of the first pipe 3 and connected to the storage tank 25, and the catalyst tower 14 is in the middle of the second pipe. It is preferable to arrange | position. According to this configuration, a part of the cleaning liquid 5 that has flowed from the storage tank 25 into the first pipe 3 by the pump 4 flows into the second pipe 8, and the sulfur contained in the cleaning liquid 5 is oxidized by the catalyst tower 14 . Therefore, the cleaning liquid 5 can be circulated efficiently, and the maintenance frequency and life span of the catalyst tower 14 can be suppressed. Further , the wet deodorization apparatus 1 can adjust the maintenance frequency and life of the catalyst tower 14 by adjusting the amount of the cleaning liquid flowing into the second pipe 8.

The cleaning liquid 5 may flow into the second pipe in an amount of 5% or more and less than 100% with respect to the quantity flowing into the first pipe 3 from the storage tank 25. Alternatively, the cleaning liquid 5 may be circulated through the storage tank 25 and the catalyst tower 14 only by the second pipe 8 separately from the first pipe 3, and the cleaning liquid 5 may be circulated by a pump.

The wet deodorization apparatus according to the present invention stores a deodorization tower 2 having an inlet 24 for an odor gas containing a sulfur-based odor component and an outlet 21 for a deodorized gas, and stores a cleaning liquid 5 at a lower portion of the deodorization tower. Storage tank 25, a filling part 23 for filling the deodorization carrier 6 inside the deodorizing tower and above the inlet and the storage tank, and inside the deodorizing tower below the outlet and the filling part An injection part 22 for injecting the cleaning liquid toward the filling part, a first pipe 3 connecting the storage tank and the injection part, and a pump 4 for sending the cleaning liquid from the storage tank to the injection part, A wet deodorizing apparatus 1 for deodorizing odorous gas by a deodorizing carrier 6 sprayed with a cleaning liquid, further comprising a catalyst tower 14 for oxidizing the cleaning liquid, and the oxidation catalyst 7 is provided in the middle of the first pipe 3 You may arrange in.

The wet deodorization apparatus according to the present invention stores a deodorization tower 2 having an inlet 24 for an odor gas containing a sulfur-based odor component and an outlet 21 for a deodorized gas, and stores a cleaning liquid 5 at a lower portion of the deodorization tower. Storage tank 25, a filling part 23 for filling the deodorization carrier 6 inside the deodorizing tower and above the inlet and the storage tank, and inside the deodorizing tower below the outlet and the filling part An injection part 22 for injecting the cleaning liquid toward the filling part, a first pipe 3 connecting the storage tank and the injection part, and a pump 4 for sending the cleaning liquid from the storage tank to the injection part, A wet deodorizing apparatus 1 for deodorizing odorous gas by a deodorizing carrier 6 sprayed with a cleaning liquid, further comprising a catalyst tower 14 for oxidizing the cleaning liquid, and the oxidation catalyst 7 is inside a storage tank 25. You may arrange | position near the entrance of the 1st pipe line 3. FIG.

The oxidation catalyst 7, surface area, water absorption, chemical resistance, is preferably made of porous ceramic oxidation catalyst from the viewpoint of physical strength. Moreover, it is preferable to use the oxidation catalyst 7 in multiple layers. According to this configuration, sulfur contained in the cleaning liquid 5 can be efficiently oxidized by the oxidation catalyst 7 of each layer.

The oxidation catalyst 7 preferably has an oxidation catalyst ability to oxidize the cleaning liquid 5 in the deodorizing carrier 6 passes after a given time.

  In the deodorizing method according to the present invention, the cleaning liquid 5 and the deodorizing carrier 6 oxidize the odor gas containing the sulfur-based odor component, and the oxidation catalyst 7 oxidizes sulfur contained in the cleaning liquid 5 to water-soluble sulfur-containing ions. And a process.

According to the wet deodorization apparatus according to the present invention, even if sulfur generated during the deodorization of the odor gas containing the sulfur-based odor component is contained in the cleaning liquid, the sulfur is converted into water-soluble sulfur-containing ions by the oxidation catalyst, for example, water-soluble. It is possible to suppress the crystallization of the sulfur component contained in the cleaning liquid by oxidizing to the sulfate ion of the cleaning liquid, and to deposit in the apparatus as a sulfur scale while deodorizing the odorous gas by the deodorizing carrier injected with the cleaning liquid. Can be suppressed. Moreover, since the catalyst tower according to the present invention has a multilayer structure composed of oxidation catalyst bodies having different sizes, it is excellent in cleaning liquid purification efficiency and can prevent clogging of the catalyst tower. Therefore, the wet deodorizing apparatus according to the present invention can suppress a decrease in the deodorizing effect even when operated for a long period of time, and requires less maintenance than the conventional deodorizing apparatus, which is advantageous in terms of cost .

The schematic diagram which shows the wet deodorizing apparatus of 1st Embodiment The schematic diagram which shows the catalyst tower of the wet deodorizing apparatus of 1st Embodiment The schematic diagram which shows the wet deodorizing apparatus of 2nd Embodiment. The schematic diagram which shows the wet deodorizing apparatus of 3rd Embodiment. It is a figure which shows the one part photograph of a deodorizing tower, (a) is a figure which shows the part mainly corresponded to area | region A1 of FIG. 1 in the conventional deodorizing tower, (b) is the deodorizing tower of 1st Embodiment. The figure which mainly shows the part of area | region A1 of FIG. It is a figure which shows the one part photograph of a deodorizing tower, (a) is a figure which shows the part mainly corresponded to area | region A2 of FIG. 1 in the conventional deodorizing tower, (b) is in the deodorizing tower of 1st Embodiment. The figure which mainly shows the part of area | region A2 of FIG. It is a figure which shows the one part photograph of a deodorizing tower, (a) is a figure which shows the part corresponded to area | region A3 located in the other side of area | region A2 of FIG. 1 mainly in the conventional deodorizing tower, (b) is the figure. The figure which shows the part of area | region A3 located in the other side of area | region A2 of FIG. 1 mainly in the deodorizing tower of 1 embodiment.

  The wet deodorization apparatus of the present embodiment is configured to efficiently oxidize the cleaning liquid in order to suppress the sulfur scale from adhering to the apparatus while deodorizing the odor gas mainly containing sulfur-based odor components by circulating the cleaning liquid. It was. In addition, the wet deodorizing apparatus of this embodiment shown below is an example, and this invention is not interpreted limitedly.

(First embodiment)
Drawing 1 is a mimetic diagram showing the wet deodorization device of a 1st embodiment. FIG. 1 mainly shows the internal structure of the deodorization tower in order to facilitate understanding of the flow of odor gas and cleaning liquid. In the figure, arrows F1, F2, and F3 indicate gas flows, and arrows L1, L2, L3, and L4 indicate cleaning liquid flows, respectively. As shown in FIG. 1, the wet deodorization apparatus 1 according to the first embodiment includes a deodorization tower 2, a first pipe 3, a pump 4, a second pipe 8, and a catalyst tower 14. .

  The deodorization tower 2 has a substantially square cylindrical structure, and has a storage tank 25 in the lower part, an inlet 24 on the side and above the storage tank 25, and a filling part 23 above the inlet 24 and the storage tank 25. And an injection part 22 above the filling part 23 and an outlet 21 above the injection part 22. The odor gas contains sulfur-based odor components such as hydrogen sulfide, methyl mercaptan methyl sulfide, and methyl disulfide, and flows into the deodorizing tower 2 from the inlet 24 as indicated by an arrow F1, and is filled in the filling portion 23 as indicated by an arrow F2. And passes through the injection unit 22. The gas deodorized in the filling section 23 flows out of the deodorizing tower 2 from the outlet 21 via the demister 12 as indicated by an arrow F3. Here, the demister 12 has a mesh shape, and mainly removes mist contained in the deodorized gas.

  The first pipe 3 has one end connected to the injection unit 22 and the other end connected to the storage tank 25. The second pipe line 8 is connected to the storage tank 25 at the other end in the middle of the first pipe line 3 so that one end branches from the first pipe line 3. A catalyst tower 14 is arranged in the middle of the second pipe line 8.

  The storage tank 25 stores the cleaning liquid 5 therein. The cleaning liquid 5 may be an aqueous solution that oxidizes with an odor gas, particularly a sulfur-based odor component, for example, an aqueous solution of hypochlorite such as sodium hypochlorite (NaOCl). The cleaning liquid 5 is sucked up by the pump 4 from the storage tank 25 to the injection unit 22 via the first pipe 3 as indicated by arrows L1 and L2, and a part of the cleaning liquid 5 is first expressed as indicated by the arrow L3. Branching in the middle of the pipe 3, flows into the second pipe 8, and returns to the storage tank 25 through the catalyst tower 14 as indicated by an arrow L 4. The cleaning liquid sucked up by the pump 4 to the injection unit 22 is injected over the entire filling unit 23 from the injection unit 11 provided at the distal end portion of the first pipe 3, and enters the storage tank 25 through the filling unit 23. Collected.

The filling unit 23 includes a net 13 and a plurality of deodorizing carriers 6 filled on the net 13. The deodorizing carrier 6 may be filled in an orderly manner on the net 13 or randomly stacked. The net 13 can be one that allows odor gas to pass mainly from below and the cleaning liquid 5 from above and does not cause the deodorizing carrier 6 to fall, and a partition plate having a plurality of through holes is used instead of the net 13. May be. Incidentally, the net 13, as both deodorization tower 2 or the like, odor gas in contact, have preferably be subjected to use or such processing of materials having durability against washing liquid 5 and deodorizing carrier 6.

  The deodorizing carrier 6 is not particularly limited as long as it is resistant to odor gas and the cleaning liquid 5 and can carry the cleaning liquid 5 for a certain period of time. The molded product made of plastic material or an additive such as an absorbent polymer in the plastic material. It is possible to use a general plastic product such as a molded product containing bismuth. As the plastic material, various materials such as polyethylene and polypropylene can be used. As the absorbent polymer, for example, vinylacetamide polymer, polyacrylate, polysulfate, polyvinyl alcohol-polyacrylate polymer, starch-based resin, cellulose-based resin graft polymer, and the like can be used. . Further, the deodorizing carrier 6 may be one that mainly promotes the oxidation of the odor component of the odor gas and the cleaning liquid 5.

  The deodorizing carrier 6 can be used in various shapes such as a pellet, a sphere, a rod, a tube, a honeycomb, and a column having a plurality of through holes in the axial direction. Specifically, the deodorizing carrier 6 having a substantially cylindrical shape with a diameter of 50 [mm] and a height of 40 [mm] and having a plurality of through holes in the axial direction can be used.

In the filling unit 23, the wet-type deodorizing apparatus 1 decomposes and removes the odor components of the odor gas by bringing the odor gas flowing from below into contact with the deodorization carrier 6 on which the cleaning liquid 5 is injected. For example, in the case where the odor component is hydrogen sulfide (H ₂ S) and the cleaning liquid 5 is an aqueous solution of sodium hypochlorite (NaOCl), in the filling portion 23, sulfur is represented by the reaction formulas (Chemical Formula 1) to (Chemical Formula 3). (S) is generated.

First, sodium sulfide (Na ₂ S) is generated from hydrogen sulfide as shown in the following reaction formula (Chemical Formula 1).
H ₂ S + 2NaOH → Na ₂ S + H ₂ O (Chemical Formula 1)
Thereafter, the following reaction formulas (Chemical Formula 2) and (Chemical Formula 3) are generated.
Na ₂ S + NaOCl → S + NaCl + 2NaOH (Chemical Formula 2)
Na ₂ S + 4NaOCl → Na ₂ SO ₄ + 4NaCl (Chemical Formula 3)

  Here, when the pH value of the cleaning liquid 5 is set to about 13.4, the ratio of the reaction formula (Chemical Formula 2) can be suppressed and the generation of sulfur (S) can be suppressed. Therefore, the wet deodorizing apparatus 1 is operated with a PH value of the cleaning liquid 5 of about 8 to 12 in general. In the normal operation of this wet deodorization apparatus 1, it has been found that the reaction formula of (Chemical Formula 2) is about 3.3 to 4.5 times that of the chemical formula of (Chemical Formula 3). Is recovered in the storage tank 25, and the sulfur is crystallized over time and deposited as a scale in the deodorizing carrier 6, the first conduit 3, the injection unit 11, and other devices. This sulfur scale not only prevents the deodorization of the odor gas, but also blocks the flow path of the odor gas and the cleaning liquid 5. Therefore, the wet deodorization apparatus 1 suppresses the generation of sulfur scale by reducing the sulfur contained in the cleaning liquid 5 by the catalyst tower 14. Next, the catalyst tower 14 will be described.

The catalyst tower 14 has the oxidation catalyst 7 inside, and is arranged in the middle of the second pipe line 8. Then, the wet deodorizing apparatus 1 passes a part of the cleaning liquid 5 through the catalyst tower 14 and reduces the sulfur (S) contained in the cleaning liquid 5 by the oxidation catalyst 7. For example, sulfur generated in the reaction formula of (Chemical Formula 2) is oxidized to water-soluble sodium sulfate (Na ₂ SO ₄ ) by the oxidation catalyst 7 as shown in the chemical formula of the following (Chemical Formula 4), thereby forming the cleaning liquid 5. The sulfur contained can be reduced.
S + 3NaOCl + 2NaOH → Na ₂ SO ₄ + 3NaCl + H ₂ O
Further, sodium sulfide (Na ₂ S) is also oxidized to water-soluble sodium sulfate (Na ₂ SO ₄ ) in the same manner as the reaction formula of (Chemical Formula 3).

Here, when sulfur is generated from the odor gas by the cleaning liquid 5 and the deodorizing carrier 6 as in the reaction formula of (Chemical Formula 3), the cleaning liquid 5 containing sulfur is oxidized by the oxidation catalyst 7 within a predetermined time. It has been found that the sulfur scale does not deposit in the wet deodorization apparatus 1. The predetermined time is about one hour, and oxidation of sulfur in the nascent stage (specifically, sulfur before crystallizing from hexamer to octamer) with the oxidation catalyst 7 causes the deposition of sulfur scale. It is effective to suppress. When the total amount of the cleaning liquid 5 stored in the storage tank 25 is 2400 [L] (2.4 [m ³ ]), the entire amount of the cleaning liquid 5 is oxidized at a frequency of about once per hour. 7, assuming that the cleaning liquid 5 is partly flowed into the second pipe 8 at a liquid amount of 40 [L / min], the wet deodorizing apparatus 1 can suppress deposition of sulfur scale. It turns out.

As the oxidation catalyst 7, one that mainly oxidizes sulfur (S) contained in the cleaning liquid 5 to water-soluble sulfur-containing ions can be used. The oxidation catalyst 7, surface area, water absorption, chemical resistance, when considering the physical strength and the like, in particular, it is preferable to use a porous ceramic oxidation catalyst.

Porous ceramic oxidation catalyst, a material of the catalyst component having insoluble in and oxidation catalyst ability fired water, and natural clay minerals comprising after firing a ceramic substrate, and additives for making a porous structure after firing the main It can be obtained by mixing as a component and firing after molding.

  Substances of catalyst components that are insoluble in water after firing and have oxidation catalytic ability include metal oxides such as iron, cobalt, nickel, zinc, copper, lead, molybdenum, titanium, tungsten, chromium, manganese, vanadium and their metals One or more carbonates, ammonium salts, chlorides, hydroxides, sulfates, nitrates, and the like can be selected and used. As the natural clay mineral, feldspar, talc, montmorillonite, cordierite, mullite, natural zeolite and the like can be used. As the additive, diatomaceous earth, sawdust, udon powder, walnut powder, bamboo powder and the like can be used. In addition to these, as a binder for preventing mold breakage from molding to baking, acrylic, vinyl acetate, styrene or the like alone or copolymer emulsions, binders such as gelatin, agar, and methylcellulose, polymer compounds such as polyvinyl alcohol Etc. can also be used.

  The oxidation catalyst 7 can be of various shapes such as pellets, spheres, rods, tubes, honeycombs, and cylindrical shapes having a plurality of through holes in the axial direction. A cylindrical shape having a plurality of through holes in the axial direction is preferable.

Incidentally, deodorant carrier 6 may be the same porous ceramic oxidation catalyst and the oxidation catalyst 7. However, the deodorizing carrier 6 has a configuration that takes into account the oxidation of odor components and the passage of the odor gas and the cleaning liquid 5. The oxidation catalyst 7 is not the gas to be oxidized but the cleaning liquid 5 itself, strictly speaking, the cleaning liquid 5. The sulfur (S) component contained in is oxidized. Therefore, certain considerations are required for the preferable shape, size, arrangement, and the like of the deodorizing carrier 6 and the oxidation catalyst 7.

  FIG. 2 is a schematic diagram illustrating a catalyst tower of the wet deodorization apparatus according to the first embodiment. FIG. 2 mainly shows the internal structure of the catalyst tower for easy understanding of the flow of the cleaning liquid. Note that arrows L3, L4, and L34 in the figure indicate the flow of the cleaning liquid, respectively. As shown in FIG. 2, the catalyst tower 14 mainly includes two types of oxidation catalysts 71 and 72 and three nets 141, 142, and 143 therein. The catalyst tower 14 is divided into two regions by three nets 141, 142, and 143, and each region is filled with one type of oxidation catalyst 71 and one of oxidation catalyst 72 to form two layers A and B. ing. The nets 141, 142, and 143 may be any one that can separate the oxidation catalysts 71 and 72 and hold them in each region. A partition plate having a plurality of through holes may be used instead of the nets 141, 142, and 143. Each may be used. Further, the oxidation catalyst 71 and the oxidation catalyst 72 may be filled in an orderly manner or randomly as shown in FIG. 2 between the nets.

The oxidation catalyst 71, specifically the diameter 25 [mm], a porous ceramic oxidation catalyst substantially cylindrical and a height of 25 [mm], through circular diameter 4 [mm] which penetrates in the axial direction One having six holes 73 in the same direction around the axis can be used. Further, the oxidation catalyst 72, specifically the diameter 15 [mm], a porous ceramic oxidation catalyst substantially cylindrical and a height 17 [mm], a diameter of 2.5 to axially penetrating [mm] Can be used which have six circular through-holes 74 in the same direction around the axis.

  The wet deodorization apparatus 1 allows a part of the cleaning liquid 5 to pass through the catalyst tower 14 as indicated by arrows L3, L34, and L4. In this way, the wet deodorization apparatus 1 first oxidizes and removes the large sulfur crystals and impurities contained in the cleaning liquid 5 with the layer A having a large gap, so that the sulfur with the layer B having a small gap that is subsequently passed through. Can be efficiently oxidized. In this way, clogging of the layer B with a small gap can also be prevented. The catalyst tower 14 may have a multilayer structure having more than two layers depending on the type of the oxidation catalyst 7.

(Example)
In order to compare the wet deodorization apparatus 1 of the first embodiment with the conventional wet deodorization apparatus, the following experiments (I) and (II) were performed. In addition, the conventional wet deodorization apparatus used the structure remove | excluding the 2nd pipe line 8 and the catalyst tower 14 from the wet deodorization apparatus 1 of 1st Embodiment. The deodorizing carrier 6 was a general plastic filler.

(I) The conventional wet deodorization apparatus and the wet deodorization apparatus 1 of the first embodiment are each operated for 4 months under the following conditions, and then the pressures in the vicinity of the inlet 24 and the outlet 21 in the deodorization tower 2 ( Atmospheric pressure) difference (hereinafter simply referred to as “pressure loss”) was investigated. The conventional wet deodorization apparatus and the wet deodorization apparatus 1 of the first embodiment each had a pressure loss of about 216 [Pa] (= 22 [mmAq]) at the beginning of operation.
The following (a) to (c) are common conditions for the conventional wet deodorization apparatus and the wet deodorization apparatus 1 of the first embodiment.
(A) Odor gas of interest: human waste odor (b) Air volume of odor gas: 250 [m ³ / min]
(C) Liquid volume of the cleaning liquid (L2) sucked up to the injection unit 22: 750 [L / min]
In addition, the following (d) to (f) are conditions of the wet deodorization apparatus 1 of the first embodiment.
(D) Catalyst tower 14: Two-layer structure as shown in FIG. 2 (e) Liquid amount of the cleaning liquid (L3) in the second pipe line 8: 40 [L / min]
(F) Flow rate of cleaning liquid when passing through oxidation catalysts 71 and 72: 0.2 [m / s]

  As a result of the experiment (I), the conventional wet deodorization apparatus has a pressure loss of about 471 [Pa] (= 48 [mmAq]), and the wet deodorization apparatus 1 of the first embodiment has a pressure loss of 275 [Pa]. It was about (= 28 [mmAq]). From this, it can be seen that the wet deodorization apparatus 1 of the first embodiment can reduce the increase in pressure loss less than the conventional wet deodorization apparatus. This is considered to be because in the wet deodorization apparatus 1 of the first embodiment, sulfur (S) contained in the cleaning liquid 5 is oxidized by the oxidation catalysts 71 and 72 of the catalyst tower 14 to suppress sulfur scale deposition. It is done.

  FIG. 5 is a view showing a photograph of a part of the deodorization tower. FIG. 5A is a diagram showing a portion corresponding to the area A1 of FIG. 1 mainly in the conventional deodorizing tower, and FIG. 5B is a diagram mainly showing the portion of FIG. 1 in the deodorizing tower of the first embodiment. It is a figure which shows the part of area | region A1. 5A is a photograph taken one month after the operation of the conventional wet deodorizing apparatus in the experiment of (I), and FIG. 5B is the first photograph in the experiment of (I). It is the photograph image | photographed 4 months after operating the wet deodorizing apparatus 1 of embodiment. As shown to Fig.5 (a), in the conventional wet deodorizing apparatus, it turns out that the transparent window W1 has deposited sulfur scale S1 in large quantities. The circular transparent portion C is a portion where the sulfur scale has been removed in advance with a scale removing device in order to clarify the deposition of the sulfur scale. Moreover, as shown in FIG.5 (b), in the wet deodorizing apparatus 1 of 1st Embodiment, it turns out that the transparent window W1 hardly deposits a sulfur scale and can confirm an internal cleaning liquid.

  FIG. 6 is a view showing a photograph of a part of the deodorization tower. FIG. 6A is a diagram showing a portion corresponding to the area A2 of FIG. 1 mainly in the conventional deodorization tower, and FIG. 6B is a diagram mainly showing the part of FIG. 1 in the deodorization tower of the first embodiment. It is a figure which shows the part of area | region A2. 6A is a photograph taken one month after the operation of the conventional wet deodorization apparatus in the experiment of (I), and FIG. 6B is the first photograph in the experiment of (I). It is the photograph image | photographed 4 months after operating the wet deodorizing apparatus 1 of embodiment. As shown to Fig.6 (a), in the conventional wet deodorizing apparatus, it turns out that the transparent window W2 has a large amount of sulfur scale S2 deposited over the whole. Moreover, as shown in FIG.6 (b), in the wet deodorizing apparatus 1 of 1st Embodiment, the transparent window W2 has almost no sulfur scale deposited, and it can confirm an internal washing | cleaning liquid and a deodorizing support | carrier. I understand.

  FIG. 7 is a view showing a photograph of a part of the deodorization tower. Fig.7 (a) is a figure which shows the part corresponded mainly to area | region A3 located in the other side of area | region A2 of FIG. 1 in the conventional deodorizing tower, FIG.7 (b) is a figure of 1st Embodiment. It is a figure which shows the part of area | region A3 located in the deodorizing tower mainly on the opposite side of area | region A2 of FIG. 7A is a photograph taken one month after operating the conventional wet deodorization apparatus in the experiment of (I), and FIG. 7B is the first photograph in the experiment of (I). It is the photograph image | photographed 4 months after operating the wet deodorizing apparatus 1 of embodiment. As shown to Fig.7 (a), in the conventional wet deodorizing apparatus, it turns out that the transparent window W3 has sulfur scale S3 deposited over the whole. Moreover, as shown in FIG.7 (b), in the wet deodorizing apparatus 1 of 1st Embodiment, the transparent window W3 has hardly deposited sulfur scale, and it can confirm an internal washing | cleaning liquid and a deodorizing support | carrier. I understand.

(II) The conventional wet deodorization apparatus and the wet deodorization apparatus 1 of the first embodiment were respectively operated under the following conditions, and the odor concentration in the vicinity of the outlet 21 after 4 months was investigated. Here, the odor concentration (M) indicates the value of the dilution factor, and expresses the numerical value of how much the gas to be measured is diluted with odorless air so that no odor is felt. In the conventional wet deodorization apparatus and the wet deodorization apparatus 1 of the first embodiment, the odor concentration in the vicinity of the inlet 24 was about 5000 (M = 5000).
The following (g) to (i) are common conditions for the conventional wet deodorization apparatus and the wet deodorization apparatus 1 of the first embodiment.
(G) Target odor gas: Garbage odor (h) Air volume of odor gas: 300 [m ³ / min]
(I) Liquid amount of the cleaning liquid (L2) sucked up to the injection unit 22: 750 [L / min]
Moreover, the following (j)-(l) are conditions of the wet deodorizing apparatus 1 of 1st Embodiment.
(J) Catalyst tower 14: Two-layer structure as shown in FIG. 2 (k) Liquid amount of cleaning liquid (L3) in second pipe line 8: 60 [L / min]
(L) Flow rate of cleaning liquid when passing through oxidation catalysts 71 and 72: 0.3 [m / s]

  As a result of the experiment of (II), the conventional wet deodorization apparatus has an odor concentration of about 3200 (M = 3200), and the wet deodorization apparatus 1 of the first embodiment has an odor concentration of about 300 (M = 300). It was. This shows that the wet deodorization apparatus 1 of 1st Embodiment can make an odor density smaller than the conventional wet deodorization apparatus. This is because in the wet deodorization apparatus 1 of the first embodiment, sulfur (S) contained in the cleaning liquid 5 is oxidized by the oxidation catalysts 71 and 72 of the catalyst tower 14 to suppress deposition of sulfur scale, and the cleaning liquid 5 is jetted. This is probably because the odor component of the odor gas is sufficiently decomposed and removed by the deodorizing carrier 6.

  Further, as is clear from the experimental results (I) and (II) above, the amount of the cleaning liquid 5 that flows into the second conduit 8 may be only a part of the circulating cleaning liquid 5, and specifically, May be 5% or more of the amount of liquid flowing into the first pipeline 3 before branching. If the amount of the cleaning liquid flowing into the second pipe line 8 is small, the wet deodorization apparatus 1 is naturally advantageous in terms of maintenance, life and cost of the oxidation catalysts 71 and 72.

The wet deodorizing apparatus 1 may replenish or discard the cleaning liquid 5 by measuring the concentration of the cleaning liquid 5 with a densitometer. In this way, the pH value of the cleaning liquid 5 circulated by the pump 4 can be maintained at a predetermined value. Further, the wet deodorizing apparatus 1 may be provided with a valve for opening and closing near the both ends of the second pipe line 8. In conventional deodorization device had to stop the operation of the apparatus upon maintenance of the catalyst tower, but by taking the above configuration, the wet deodorizing apparatus 1 temporarily Switching Operation release the catalyst tower 14 Driving can be continued.

  In the wet deodorization apparatus 1 of the first embodiment, a part of the cleaning liquid 5 that circulates the injection unit 22 and the storage tank 25 by the pump 4 is branched and connected in the middle of the first pipeline 3. In this case, the sulfur tank is prevented from depositing and is effectively deodorized even if it is continuously operated for a long period of time. Can be implemented. In addition, the wet deodorizing apparatus 1 can significantly reduce the frequency of maintenance compared with the conventional deodorizing apparatus, and is advantageous in terms of cost.

(Second Embodiment)
FIG. 3 is a schematic view showing a wet deodorizing apparatus according to the second embodiment. FIG. 3 mainly shows the internal structure of the deodorization tower in order to make the flow of the odor gas and the cleaning liquid easy to understand. In the figure, arrows F1, F2, and F3 indicate gas flows, and an arrow L1 indicates a cleaning liquid flow. As shown in FIG. 3, the wet deodorization apparatus 31 of the second embodiment is basically the same as the wet deodorization apparatus 1 of the first embodiment, and the oxidation catalyst 7 is placed in the middle of the first pipeline 3. A catalyst tower 14 is disposed. In addition, the same structure as the wet deodorizing apparatus 1 of 1st Embodiment uses the same code | symbol also in FIG. 3, and abbreviate | omits description. The wet deodorization apparatus 31 of the second embodiment suppresses sulfur scale deposition by oxidizing all of the cleaning liquid 5 circulated by the pump 4 with the oxidation catalyst 7 of the catalyst tower 14, and odor gas even when continuously operated for a long period of time. Can be effectively carried out.

(Third embodiment)
FIG. 4 is a schematic view showing a wet deodorizing apparatus according to the third embodiment. FIG. 4 mainly shows the internal structure of the deodorization tower in order to make the flow of the odor gas and the cleaning liquid easy to understand. In the figure, arrows F1, F2, and F3 indicate gas flows, and an arrow L1 indicates a cleaning liquid flow. As shown in FIG. 4, the wet deodorization apparatus 41 of the third embodiment is basically the same as the wet deodorization apparatus 1 of the first embodiment, and is inside the storage tank 25 and the first pipeline. A catalyst body 15 including an oxidation catalyst 7 is disposed in the vicinity of the inlet 3. In addition, the same structure as the wet deodorizing apparatus 1 of 1st Embodiment uses the same code | symbol in FIG. 4, and abbreviate | omits description.

  The catalyst body 15 may have any structure as long as it holds the oxidation catalyst 7 inside and can bring the cleaning liquid 5 into contact with the oxidation catalyst 7. The catalyst body 15 basically has a two-layer structure similar to that of the catalyst tower 14.

  The wet deodorization apparatus 41 of the third embodiment suppresses the deposition of sulfur scale by oxidizing the cleaning liquid 5 of the storage tank 25 by the oxidation catalyst 7 of the catalyst body 15, and deodorizes odorous gas even after continuous operation for a long period of time. Can be implemented effectively.

  In addition, as a structure other than the said 1st-3rd embodiment, a wet deodorizing apparatus is the structure of the conventional wet deodorizing apparatus, the 2nd pipe line which connected both ends to the storage tank, and a 2nd pipe line A catalyst tower arranged in the middle and another pump may be further provided, and the cleaning liquid may be circulated between the storage tank and the catalyst tower through the second pipe by the other pump. Further, a plurality of catalyst towers and catalyst bodies may be provided in the wet deodorization apparatus, or may be appropriately arranged at an arbitrary place.

Since the wet deodorization apparatus according to the present invention maintains the deodorization effect for a long period of time and reduces the frequency of maintenance, the industrial applicability is extremely large as it greatly reduces the running cost.

DESCRIPTION OF SYMBOLS 1, 31, 41 Wet deodorizing apparatus 2 Deodorizing tower 3 1st pipe line 4 Pump 5 Cleaning liquid 6 Deodorizing support | carrier 7 Oxidation catalyst 8 2nd pipe line 11 Injection unit 12 Demister 13 Net 14 Catalyst tower 21 Outlet 22 Injection part 23 Filling section 24 Inlet 25 Storage tank

Claims (10)

A deodorization tower (2) having an inlet (24) of odor gas containing a sulfur-based odor component and an outlet (21) of deodorized gas;
A storage tank (25) for storing the cleaning liquid (5);
A filling section (23) for filling the deodorizing carrier (6) inside the deodorization tower and above the inlet and the storage tank;
An injection part (22) for injecting the cleaning liquid toward the filling part inside the deodorization tower and below the outlet and above the filling part;
A first pipe (3) connecting the storage tank and the injection unit;
A pump (4) for sending the cleaning liquid from the storage tank to the injection unit;
A wet deodorizing apparatus for deodorizing the odor gas by the deodorizing carrier sprayed with the cleaning liquid,
A catalyst tower (14) for oxidizing the cleaning liquid;
The catalyst tower includes at least a first catalyst layer composed of a plurality of first oxidation catalyst bodies on the inlet side of the cleaning liquid, and a plurality of second smaller than the first oxidation catalyst bodies on the outlet side. A wet deodorizing device comprising: a second catalyst layer composed of an oxidation catalyst body . A second pipe (8) branched in the middle of the first pipe and connected to the storage tank;
The wet deodorization apparatus according to claim 1, wherein the oxidation catalyst is disposed in the middle of the second pipeline. The cleaning liquid is
3. The wet deodorization according to claim 2, wherein an amount of 5% or more and less than 100% of the amount flowing into the first pipeline from the storage tank is allowed to flow into the second pipeline. apparatus. The wet deodorization apparatus according to claim 1, wherein the catalyst tower is disposed in the middle of the first pipe line. The wet deodorization apparatus according to claim 1, wherein the catalyst tower is disposed in the storage tank and in the vicinity of an inlet of the first pipe line. The oxidation catalyst according to any one of claims 1-5, characterized in <br/> to have the oxidation catalyst ability to oxidize the cleaning liquid into the passage after a predetermined deodorizing carrier time Wet deodorization device. A deodorization tower (2) having an inlet (24) of odor gas containing a sulfur-based odor component and an outlet (21) of deodorized gas;
A storage tank (25) for storing the cleaning liquid (5);
A filling section (23) for filling the deodorizing carrier (6) inside the deodorization tower and above the inlet and the storage tank;
An injection part (22) for injecting the cleaning liquid toward the filling part inside the deodorization tower and below the outlet and above the filling part;
A first pipe (3) connecting the storage tank and the injection unit;
A pump (4) for sending the cleaning liquid from the storage tank to the injection unit;
A catalyst tower (14) for oxidizing the cleaning liquid, which is used in a wet deodorizing apparatus that deodorizes the odorous gas by the deodorizing carrier to which the cleaning liquid has been jetted,
At least a first catalyst layer composed of a plurality of first oxidation catalyst bodies on the inlet side of the cleaning liquid, and a plurality of second oxidation catalyst bodies smaller than the first oxidation catalyst body on the outlet side. A second catalyst layer
A catalyst tower characterized by that. The oxidation catalyst body is composed of a porous ceramic oxidation catalyst.
The catalyst tower according to claim 7. At least one of the first oxidation catalyst body and the second oxidation catalyst body has a substantially cylindrical shape.
The catalyst tower according to claim 7 or 8, characterized in that. The substantially cylindrical oxidation catalyst body has at least one through hole in the axial direction.
The catalyst tower according to claim 9.

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