JP5750916B2 - Polymer, organic electroluminescent element material, composition for organic electroluminescent element, organic electroluminescent element, organic EL display device, and organic EL lighting - Google Patents

Description

  The present invention relates to a polymer, and in particular, a polymer useful as a hole injection layer and a hole transport layer of an organic electroluminescence device, an organic electroluminescence device material containing the polymer, a composition for an organic electroluminescence device, and an organic material. The present invention relates to an electroluminescent element, an organic EL display device including the organic electroluminescent element, and organic EL illumination.

  Examples of the method for forming the organic layer in the organic electroluminescence device include a vacuum deposition method and a wet film formation method. Since the vacuum deposition method is easy to stack, it has the advantage that the charge injection from the anode and / or the cathode is improved and the exciton light-emitting layer is easily contained. On the other hand, the wet film formation method does not require a vacuum process, is easy to increase in area, and can be easily applied to a plurality of materials having various functions by using a coating liquid in which a plurality of materials having various functions are mixed. There is an advantage that a layer containing these materials can be formed.

However, since the wet film forming method is difficult to stack, the driving stability is inferior to that of the element by the vacuum vapor deposition method, and the present state is that it has not reached a practical level except for a part.
Therefore, in order to improve the characteristics of the device, a polymer material having a charge transporting ability has been developed. For example, Patent Documents 1 and 2 disclose an organic electroluminescent element containing a polymer and having a hole injection transport layer formed by a wet film forming method. However, these devices have a problem that the drive voltage is high and the light emission efficiency is low.

International Publication No. 2008-032843 Pamphlet International Publication No. 2008-038747 Pamphlet

This invention is made | formed in view of the said subject, and makes it a subject to provide the composition for organic electroluminescent elements containing a polymer with high hole injection transport capability and this polymer.
Another object of the present invention is to provide an organic electroluminescent element having a low driving voltage and high luminous efficiency, and a high-quality organic EL display device and organic EL illumination.

As a result of intensive studies to solve the above problems, the present inventors have found that (I) a methylene group in the main chain and (II) a heavy chain having two different specific aromatic condensed rings in the side chain. It has been found that coalescence solves the above problems, and has reached the present invention.
That is, the present invention includes a polymer containing a repeating unit represented by the following formula (1) and having two or more kinds of three condensed rings in a molecule in a side chain, an organic electroluminescent element material, and organic electroluminescence. It exists in an element composition, an organic electroluminescent element, an organic EL display device, and organic EL lighting.

(In the formula (1),
Ar ^{1 to} Ar ³ each independently represents an aromatic hydrocarbon ring group which may have a substituent or an aromatic heterocyclic group which may have a substituent,
Ar ⁴ and Ar ⁵ each independently represent a group containing three or more aromatic condensed rings.
Ar ⁶ and Ar ⁷ each independently represent a direct bond, an aromatic hydrocarbon ring group which may have a substituent or an aromatic heterocyclic group which may have a substituent,
R ¹ and R ² are each independently a hydrogen atom, an alkyl group which may have a substituent, an alkoxy group which may have a substituent, or an aromatic hydrocarbon which may have a substituent. Represents an aromatic heterocyclic group optionally having a ring group or a substituent,
q represents an integer of 1 to 6, and r represents an integer of 0 to 5.

R ¹ and R ² may combine with each other to form a ring. )

The polymer of the present invention is a polymer excellent in hole injecting and transporting ability.
In addition, it can be stacked by wet film formation, and has high singlet and triplet excitation levels, high hole transportability and electrochemical properties after cross-linking and insolubilization in organic solvents. Since it has stability, it is useful as a material for an organic electroluminescence device, and an organic electroluminescence device obtained using the polymer has high luminous efficiency, can be driven at a low voltage, and has high driving stability. It is useful for organic EL display devices and organic EL lighting.

It is sectional drawing which shows typically an example of the structure of the organic electroluminescent element of this invention.

Embodiments of the present invention will be described in detail below, but the description of the constituent elements described below is an example (representative example) of an embodiment of the present invention, and the present invention does not exceed the gist thereof. Not specified in the content of [Polymer]
The polymer of the present invention is a polymer containing a repeating unit represented by the following formula (1) and having two or more three condensed rings in a side chain in one molecule.

(In the formula (1),
Ar ^{1 to} Ar ³ each independently represents an aromatic hydrocarbon ring group which may have a substituent or an aromatic heterocyclic group which may have a substituent,
Ar ⁴ and Ar ⁵ each independently represent a group containing three or more aromatic condensed rings.
Ar ⁶ and Ar ⁷ each independently represent a direct bond, an aromatic hydrocarbon ring group which may have a substituent or an aromatic heterocyclic group which may have a substituent,
R ¹ and R ² are each independently a hydrogen atom, an alkyl group which may have a substituent, an alkoxy group which may have a substituent, or an aromatic hydrocarbon which may have a substituent. Represents an aromatic heterocyclic group optionally having a ring group or a substituent,
q represents an integer of 1 to 6, and r represents an integer of 0 to 5.

R ¹ and R ² may combine with each other to form a ring. )
The polymer of the present invention is a polymer having two or more three condensed rings in the side chain in one molecule.
“Having two or more condensed rings in a side chain in one molecule” means that (a) one repeating unit contains two or more condensed rings in three or more rings in a side chain, or (B) Means that two or more repeating units represented by the formula (1) containing only one kind of three or more condensed rings in the side chain are contained in one molecule.

That is, the polymer of the present invention may be (i) and / or (b).
Examples of (A) include a case where r is 1 or more and Ar ⁴ and Ar ⁵ are different tri-fused rings, or a plurality of Ar ⁵ are different tri-fused rings.
Examples of (b) include the following cases.
The repeating unit represented by the formula (1) containing only one kind of three or more condensed rings in the side chain is:
For example,
Repeating unit (A) in which r = 0 and the side chain is only Ar ⁴
A repeating unit (B) in which r = 1 to 5 and Ar ⁴ and Ar ⁵ included therein are all the same
Is mentioned.

That is, in order to make (b), when two or more types (A) are included, two or more types (B) are included, (A) and (B) are included, and the side chain (Ar ⁴ ) is different And so on.
(About Ar ^{1 to} Ar ³ )
Ar ^{1 to} Ar ³ each independently represents an aromatic hydrocarbon ring group which may have a substituent or an aromatic heterocyclic group which may have a substituent.

Examples of the aromatic hydrocarbon ring group which may have a substituent include, for example, a benzene ring, naphthalene ring, anthracene ring, phenanthrene ring, perylene ring, tetracene ring, pyrene ring, benzpyrene ring, chrysene ring, triphenylene ring, Examples thereof include groups derived from a 6-membered monocyclic ring or a 2-5 condensed ring, such as an acenaphthene ring, a fluoranthene ring, and a fluorene ring.
Examples of the aromatic heterocyclic group which may have a substituent include a furan ring, a benzofuran ring, a thiophene ring, a benzothiophene ring, a pyrrole ring, a pyrazole ring, an imidazole ring, an oxadiazole ring, an indole ring, and a carbazole. Ring, pyrroloimidazole ring, pyrrolopyrazole ring, pyrrolopyrrole ring, thienopyrrole ring, thienothiophene ring, furopyrrole ring, furofuran ring, thienofuran ring, benzoisoxazole ring, benzoisothiazole ring, benzimidazole ring, pyridine ring, pyrazine ring, 5- or 6-membered ring such as pyridazine ring, pyrimidine ring, triazine ring, quinoline ring, isoquinoline ring, sinoline ring, quinoxaline ring, phenanthridine ring, benzimidazole ring, perimidine ring, quinazoline ring, quinazolinone ring, azulene ring single Or 2-4 fused ring derived group.

Among them, Ar ^{1 to} Ar ³ are selected from the group consisting of a benzene ring, a naphthalene ring, an anthracene ring, a phenanthrene ring, a triphenylene ring, a pyrene ring, a thiophene ring, a pyridine ring, and a fluorene ring from the viewpoints of solubility and heat resistance. Ring-derived groups are preferred.
Further, the substituent that the aromatic hydrocarbon ring group or aromatic heterocyclic ring in Ar ^{1 to} Ar ³ may have is not particularly limited, and examples thereof include groups selected from the following substituent group Z. It is done. Ar ^{1 to} Ar ³ may have one substituent or two or more. When it has two or more, you may have one type and may have two or more types by arbitrary combinations and arbitrary ratios.

(Substituent group Z)
For example, an alkyl group, such as a methyl group or an ethyl group, having usually 1 or more carbon atoms and usually 24 or less, preferably 12 or less;
An alkenyl group having usually 2 or more carbon atoms and usually 24 or less, preferably 12 or less, such as a vinyl group;
An alkynyl group such as an ethynyl group, which usually has 2 or more carbon atoms and is usually 24 or less, preferably 12 or less;
For example, an alkoxy group having a carbon number of usually 1 or more and usually 24 or less, preferably 12 or less, such as a methoxy group or an ethoxy group;
For example, an aryloxy group having usually 4 or more, preferably 5 or more, usually 36 or less, preferably 24, such as a phenoxy group, a naphthoxy group, or a pyridyloxy group;
For example, an alkoxycarbonyl group having 2 or more carbon atoms, usually 24 or less, preferably 12 or less, such as a methoxycarbonyl group or an ethoxycarbonyl group;
For example, a dialkylamino group having 2 or more carbon atoms and usually 24 or less, preferably 12 or less, such as a dimethylamino group or a diethylamino group;
For example, a diarylamino group having a carbon number of usually 10 or more, preferably 12 or more, usually 36 or less, preferably 24 or less, such as a diphenylamino group, a ditolylamino group, or an N-carbazolyl group;
An arylalkylamino group having usually 7 carbon atoms, usually 36 or less, preferably 24 or less, such as a phenylmethylamino group;
For example, an acetyl group, a benzoyl group, etc., an acyl group having usually 2 carbon atoms and usually having 24 or less, preferably 12;
For example, a halogen atom such as a fluorine atom or a chlorine atom;
A haloalkyl group having usually 1 or more and usually 12 or less, preferably 6 or less, such as a trifluoromethyl group;
For example, an alkylthio group having a carbon number of usually 1 or more and usually 24 or less, preferably 12 or less, such as a methylthio group or an ethylthio group;
For example, an arylthio group having a carbon number of usually 4 or more, preferably 5 or more, usually 36 or less, preferably 24 or less, such as a phenylthio group, a naphthylthio group, or a pyridylthio group;
For example, a silyl group having a carbon number of usually 2 or more, preferably 3 or more, usually 36 or less, preferably 24 or less, such as a trimethylsilyl group or a triphenylsilyl group;
For example, a siloxy group having 2 or more, preferably 3 or more, usually 36 or less, preferably 24 or less, such as trimethylsiloxy group or triphenylsiloxy group;
A cyano group;
For example, an aromatic hydrocarbon ring group having usually 6 or more carbon atoms and usually 36 or less, preferably 24 or less, such as a phenyl group or a naphthyl group;
For example, an aromatic heterocyclic group having 3 or more, preferably 4 or more, usually 36 or less, preferably 24 or less, such as thienyl group or pyridyl group.

Among these substituents, an alkyl group having 1 to 12 carbon atoms and an alkoxy group having 1 to 12 carbon atoms are preferable from the viewpoint of improving solubility in an organic solvent.
Moreover, each said substituent may have a substituent further, The group illustrated to the said substituent group Z is mentioned as the example.
The formula weight of the substituents for Ar ^{1 to} Ar ³ is preferably 500 or less, more preferably 250 or less, including further substituted substituents. If the formula weight of the substituent is too large, the charge transport ability may be reduced.

Furthermore, the formula weight of Ar ^{1 to} Ar ³ is usually 65 or more, preferably 75 or more, and is usually 500 or less, preferably 300 or less, more preferably 200 or less.
It is preferable for it to be in the above range since the solubility in organic solvents is good.
When q is 2 or more, the plurality of Ar ² contained therein may be the same or different.

Furthermore, when r is 2 or more, the plurality of Ar ³ contained therein may be the same or different.
(About Ar ⁴ and Ar ⁵ )
Ar ⁴ and Ar ⁵ each independently represent a group containing three or more aromatic condensed rings.
That is, Ar ⁴ and Ar ⁵ may be three or more aromatic condensed rings, and may have three or more aromatic condensed rings as a substituent.

When r is 2 or more, the plurality of Ar ⁵ contained therein may be the same or different.
In the present invention, Ar ⁴ and Ar ⁵ are preferably groups represented by the following formula (2) from the viewpoint of easily improving the charge transport ability of the polymer.

(In the above formula, Ar ⁸ represents a direct bond, an aromatic monocyclic ring which may have a substituent, or an aromatic double condensed ring,
Ar ⁹ represents an aromatic condensed ring having 3 or more rings.
s represents an integer of 0 to 5, and t represents an integer of 1 to 5. )
{About Ar ⁸ and s}
Ar ⁸ represents a direct bond, an aromatic monocyclic ring which may have a substituent, or an aromatic bifused ring.

  Specific examples of the aromatic monocyclic ring or aromatic double condensed ring include hydrocarbon aromatic compounds such as benzene ring, naphthalene ring, indene ring, furan ring, pyrrole ring, thiophene ring, benzofuran ring, indole ring, Rings with heterocyclic aromatic compounds such as indazole ring, coumarone ring, benzimidazolone ring, benzothiophene ring, benzoxazole ring, benzothiazole ring, benzimidazole ring, pyridine ring, quinoline ring, isoquinoline ring, pyrazine ring And their derivatives.

Moreover, the substituent which the said aromatic monocycle or aromatic 2 condensed ring may have is the same as the kind of substituent in Ar < ¹ > -Ar < ³ >.
The value of s is usually an integer of 0 to 5, preferably 0 to 2. Within this range, it is preferable in that the solubility of the polymer in an organic solvent is good.
When s is 2 or more, a plurality of Ar ⁸ may be the same as or different from each other.

{About Ar ⁹ and t}
Ar ⁹ represents an aromatic condensed ring having 3 or more rings. The aromatic condensed ring having 3 or more rings means an aromatic ring formed by condensing 3 or more rings.
The number of carbons in the aromatic condensed ring of 3 or more rings is usually 10 to 30, preferably 10 to 20 in that the hole injection / transport ability of the polymer is high and the solubility in an organic solvent is high.

  Specific examples of three or more aromatic condensed rings include fluorene ring, dibenzofuran ring, dibenzothiophene ring, carbazole ring, anthracene ring, dihydroanthracene ring, dihydrophenanthrene ring, fluoranthene ring, pyrene ring, tetrahydropyrene ring, benzoquinoline Ring, iminostilbene ring, pyridoindole ring, phenanthrene ring, phenanthroline ring, phenazine ring, acridone ring, dibenzodioxin ring, xanthone ring, phenoxazine ring, phenoxathiin ring, indenocarbazole ring, benzodithiophene ring, thianthrene Ring, phenothiazine ring, benzofluorene ring and the like.

Among these, a fluorene ring, a dibenzofuran ring, a dibenzothiophene ring and a carbazole ring having a 6-5-6 membered ring structure are preferable.
In other words, Ar ⁹ is preferably a polymer containing at least two kinds of groups consisting of a fluorene ring, a dibenzofuran ring, a dibenzothiophene ring, and a carbazole ring.
The aromatic condensed ring of 3 or more rings in Ar ⁹ may further have a substituent, and examples of the substituent include those described in the above section <Substituent group Z>.

Further, the number of substituents may be one or two or more. In the case of two or more, it may have one type, and may have two or more types in any combination and in any ratio.
The value of t is usually an integer of 1 to 5, preferably 1 or 2. Within this range, it is preferable in that the solubility of the polymer in an organic solvent is good.

When t is 2 or more, a plurality of Ar ⁹ may be the same or different.
(About Ar ⁶ and Ar ⁷ )
Ar ⁶ and Ar ⁷ each independently represent a direct bond, an aromatic hydrocarbon ring group that may have a substituent, or an aromatic heterocyclic group that may have a substituent.

The aromatic hydrocarbon ring group and the aromatic heterocyclic group are the same as those described in the above section (for Ar ^{1 to} Ar ³ ), and the substituents that may be included are also the same.
Ar ⁶ and Ar ⁷ are preferably a direct bond or a benzene ring in that the hole transport ability of the polymer is easy to improve.
(About R ¹ and R ² )
R ¹ and R ² are each independently a hydrogen atom, an alkyl group which may have a substituent, an alkoxy group which may have a substituent, or an aromatic hydrocarbon which may have a substituent. An aromatic heterocyclic group which may have a cyclic group or a substituent is represented.

Examples of the alkyl group include those having 1 to 30 carbon atoms.
Examples of the alkoxy group include methoxy group, ethoxy group, isopropyloxy group, cyclohexyloxy group, octadecyloxy group and the like.
Examples of the aromatic hydrocarbon ring group and the aromatic heterocyclic group are the same as those described in the above section (Ar ^{1 to} Ar ³ ). Moreover, the substituent which may have is the same.

Among them, R ¹ and R ^2, solubility in an organic solvent of the polymer, and the hole transport ability in high points is preferably an alkyl group having 1 to 10 carbon atoms.
That is, R ¹ and R ² may be a group containing three or more aromatic condensed rings. However, as described above, R ¹ and R ² are as follows from the viewpoint that the effects of the present invention can be obtained satisfactorily. An alkyl group having 1 to 10 carbon atoms is preferable.

R ¹ and R ² may be bonded to each other to form a ring. Examples of the ring include a cyclobutane ring, a cyclopentane ring, and a cyclohexane ring. , Cycloheptane ring, and cyclododecane ring.
In addition, when q is 2 or more, a plurality of R ¹ and R ² may be independently the same or different.

(About q)
q represents the integer of 1-6.
It is preferably 1 to 4 and more preferably 1 to 2 in that the ionization potential of the polymer can be easily controlled and the hole transport ability is increased.
(About r)
r represents an integer of 0 to 5.

Preferably it is 0-3, More preferably, it is 0-2 at the point which is easy to control the ionization potential of a polymer, and a hole transport ability becomes high.
[About the crosslinkable group]
The polymer of the present invention preferably contains a crosslinkable group in that a laminate can be easily formed by a wet film forming method.

Here, the crosslinkable group refers to a group that reacts with the same or different groups of other molecules located nearby by irradiation with heat and / or active energy rays to form a new chemical bond.
Among them, the crosslinkable group includes the following <crosslinkable group group T> from the viewpoint of easy crosslinking.
<Crosslinkable group T>

(In the formula, R ^{21 to} R ²³ each independently represents a hydrogen atom or an alkyl group which may have a substituent, and Ar ²¹ represents an aromatic hydrocarbon ring which may have a substituent. Represents an aromatic heterocyclic group which may have a group or a substituent.
The benzocyclobutene ring may have a substituent, or the substituents may be bonded to each other to form a ring. )
As the crosslinkable group, for example, a group that is crosslinked by cationic polymerization such as a cyclic ether group such as an epoxy group or an oxetane group, or a vinyl ether group is preferable. This is because the reactivity is high and the solubility in a solvent can be easily reduced. Among them, an oxetane group is particularly preferable in terms of easy control of the rate of cationic polymerization, and a vinyl group is bonded via an oxygen atom in that it is difficult to generate hydroxyl groups that may cause deterioration of the device during cationic polymerization. Particularly preferred are vinyl ether groups.

Further, for example, an arylvinylcarbonyl group such as a cinnamoyl group or a group that undergoes a cycloaddition reaction such as a group derived from a benzocyclobutene ring is preferable in terms of further improving electrochemical stability.
As the crosslinkable group, a group represented by the following formula is particularly preferable from the viewpoint of excellent electrochemical stability.

(The benzocyclobutene ring in the above formula may have a substituent. The substituents may be bonded to each other to form a ring.)
In addition, the kind of crosslinkable group which the polymer of this invention has may be one type, and two or more types may be used together by arbitrary combinations and arbitrary ratios.
When the polymer of the present invention has a crosslinkable group, it may be in the repeating unit represented by the formula (1), or may be in another repeating unit. It is preferably included in the chain.

That is, when the crosslinkable group is contained in the repeating unit represented by the formula (1), there are few unreacted crosslinkable groups after film formation, and it is difficult to affect the drive life of the obtained element. Ar ⁴ and / or Ar ⁵ preferably contains a crosslinkable group as a substituent.
In the molecule, the crosslinkable group may be directly bonded to three or more aromatic condensed rings of Ar ⁴ and / or Ar ⁵ , but may be bonded via an appropriate divalent group. As the divalent group, a group selected from the group consisting of an —O— group, a —C (═O) — group or a —CH ₂ — group optionally having a substituent, in any combination, ratio and A divalent group formed by connecting 1 to 30 in order is preferable.

(Ratio of crosslinkable groups)
The number of crosslinkable groups possessed by the polymer of the present invention can be represented by the number per 1000 molecular weight.
When the number of crosslinkable groups possessed by the polymer of the present invention is represented by the number per 1000 molecular weight, it is usually 3.0 or less, preferably 2.0 or less, more preferably 1.0 or less per 1000 molecular weight. In addition, it is usually 0.01 or more, preferably 0.05 or more.

Within the above range, it is difficult to form a flat film due to cracks, and there are few unreacted crosslinkable groups remaining in the film after crosslinking, which hardly affects the drive life of the resulting device.
Furthermore, the film after cross-linking is preferable in that the solubility in a solvent is sufficiently lowered and a multilayer laminated structure can be easily formed by wet film formation.

Here, the number of crosslinkable groups per 1000 molecular weight of the polymer is calculated from the molar ratio of charged monomers at the time of synthesis and the structural formula, excluding the terminal groups from the polymer.
For example, the case of the target polymer 1 synthesized in <Polymer synthesis> (Synthesis example 1 of target polymer 1) described later will be described.

In the target polymer 1, the average molecular weight of the repeating units excluding the terminal groups is 648.85, and the average number of crosslinkable groups is 0.057 per repeating unit. When this is calculated by simple proportion, the number of crosslinkable groups per 1000 molecular weight is calculated as 0.088.
[About other repeating units]
The polymer of the present invention may contain a repeating unit other than the repeating unit represented by the formula (1) (hereinafter referred to as “other repeating unit”). It is preferable that the repeating unit represented by 3) is included.

(In formula (3),
Ar ^{11 to} Ar ¹⁵ each independently represent an aromatic hydrocarbon ring group which may have a substituent or an aromatic heterocyclic group which may have a substituent.
However, Ar ¹⁴ and Ar ¹⁵ are not groups containing three or more aromatic condensed rings.
Ar ¹⁶ and Ar ¹⁷ each independently represent a direct bond, an aromatic hydrocarbon ring group which may have a substituent or an aromatic heterocyclic group which may have a substituent,
R ¹¹ and R ¹² are each independently a hydrogen atom, an alkyl group which may have a substituent, an alkoxy group which may have a substituent, or an aromatic hydrocarbon which may have a substituent. Represents an aromatic heterocyclic group optionally having a ring group or a substituent,
q ¹ represents an integer of ¹ to 6, and r ¹ represents an integer of 0 to 5.

R ¹¹ and R ¹² may combine with each other to form a ring. )
(About Ar ^{11 to} Ar ¹⁵ )
Ar ^{11 to} Ar ¹⁵ each independently represent an aromatic hydrocarbon ring group which may have a substituent or an aromatic heterocyclic group which may have a substituent. However, Ar ¹⁴ and Ar ¹⁵ are not groups containing three or more aromatic condensed rings.

The aromatic hydrocarbon ring group and the aromatic heterocyclic group are the same as those described in the section (about Ar ^{1 to} Ar ³ ). The same applies to the preferred embodiments and the substituents that may be present.
Incidentally, the polymer of the present invention preferably contains a crosslinkable group, when containing a repeating unit represented by the formula (3) is the Ar ¹⁴ and / or Ar ^15, may contain a crosslinking group Particularly preferred.

The crosslinkable group may be directly bonded to Ar ¹⁴ and / or Ar ¹⁵ or may be bonded via an appropriate divalent group. The appropriate divalent group is the same as in Ar ⁴ and / or Ar ⁵ for the above-mentioned [crosslinkable group].
(About Ar ¹⁶ and Ar ¹⁷ )
Ar ¹⁶ and Ar ¹⁷ each independently represent a direct bond, an aromatic hydrocarbon ring group which may have a substituent, or an aromatic heterocyclic group which may have a substituent.

The aromatic hydrocarbon ring group and the aromatic heterocyclic group are the same as those described in the section (about Ar ^{1 to} Ar ³ ). The same applies to the preferred embodiments and the substituents that may be present.
(About R ¹¹ and R ¹² )
R ¹¹ and R ¹² are each independently a hydrogen atom, an alkyl group which may have a substituent, an alkoxy group which may have a substituent, or an aromatic hydrocarbon which may have a substituent. An aromatic heterocyclic group which may have a cyclic group or a substituent is represented.

Specific examples and preferred embodiments of R ¹¹ and R ¹² are the same as those described in the above section (Regarding R ¹ and R ² ).
(For ^{q 1)}
q ¹ represents an integer of ¹ to 6. Preferred embodiments and the like are the same as in the above section (for q).

(For ^{r 1)}
r ¹ represents an integer of 0 to 5. Preferred embodiments and the like are the same as those in the above (for r).
[Proportion including repeating unit represented by formula (1)]
The polymer of the present invention may contain a repeating unit other than the repeating unit represented by the formula (1) (hereinafter referred to as “other repeating unit”).

In the polymer of the present invention, the ratio of the repeating unit represented by the formula (1) to the other repeating units (repeating unit represented by the formula (1) / other repeating units) is a charged molar ratio. Usually, it is 0.01 times mole or more, preferably 50 mole times or more, more preferably 80 mole times or more.
Within the above range, it is preferable in that the effect of the present invention can be favorably obtained.

In addition, the polymer of the present invention is preferably a polymer composed of a repeating unit represented by the formula (1) and a repeating unit represented by the formula (3) from the viewpoint of particularly excellent charge injecting and transporting ability. First, preferred specific examples of Ar ⁴ and Ar ^{5 in} the present invention are shown below, but the present invention is not limited thereto.
<Specific examples of three or more condensed rings>

Next, although the preferable specific example of the repeating unit represented by Formula (1) of this invention is shown below, this invention is not limited to these.
<Specific Example (I) of Repeating Unit Represented by Formula (1)>

Next, although the preferable specific example of the repeating unit represented by Formula (3) is shown below, this invention is not limited to these.
<Specific Example of Repeating Unit Represented by Formula (3)>

Preferred specific examples of the polymer of the present invention are shown below, but the present invention is not limited thereto.
<Specific examples of polymer>

(In the above structural formulas, x, y and z each independently represent an arbitrary natural number.)
[Reason why the polymer of the present invention is effective]
About the point which the characteristic of the element obtained by using the polymer of this invention improves is estimated as follows.
The polymer of the present invention contains a methylene group in the main chain, and two or more aromatic condensed rings in the side chain. By containing two or more aromatic condensed rings of three or more rings, a unit having a partially different ionization potential exists in one polymer chain among units distinguished by methylene groups contained in the main chain. become.

That is, the polymer of the present invention is excellent in charge injectability and charge transport ability because units having different ionization potentials are present in one polymer chain.
Thus, for example, when used as a layer (hole injection layer or hole transport layer) included between the anode and the light emitting layer of an organic electroluminescent device, the resulting device has excellent charge injecting and transporting capability. This reduces the driving life.

[Molecular weight range]
The weight average molecular weight (Mw) of the polymer of the present invention is usually 3,000,000 or less, preferably 1,000,000 or less, more preferably 500,000 or less, further preferably 200,000 or less, Usually, it is 1,000 or more, preferably 2,500 or more, more preferably 5,000 or more, and further preferably 20,000 or more.

Within the above range, the solubility of the polymer in the organic solvent and the film formability are good. Moreover, since the glass transition temperature, melting | fusing point, and vaporization temperature are favorable, it is preferable at the point which heat resistance is enough.
The number average molecular weight (Mn) is usually 3,000,000 or less, preferably 1,000,000 or less, more preferably 500,000 or less, and further preferably 200,000 or less, and usually 15,000. As mentioned above, Preferably, it is 20,000 or more.
Within the above range, the solubility of the polymer in the organic solvent and the film formability are good. Moreover, since the glass transition temperature, melting | fusing point, and vaporization temperature are favorable, it is preferable at the point which heat resistance is enough.

Further, the degree of dispersion of the polymer of the present invention (Mw / Mn: Mw represents a weight average molecular weight and Mn represents a number average molecular weight) is usually 2.4 or less, preferably 2.0 or less. Further, the smaller the degree of dispersion, the better. Therefore, the lower limit value is ideally 1.0 or more.
Within the above range, purification is easy, and solubility in an organic solvent and charge transportability are good, which is preferable.

Below, the measuring method of a weight average molecular weight and a number average molecular weight is shown.
The weight average molecular weight is determined by SEC (size exclusion chromatography) measurement.
Here, SEC measurement conditions are shown.
The column is TSKgel (manufactured by Tosoh Corp.) GMHXL × 2 or those exhibiting a resolution equal to or higher than that,
Particle size: 9mm
Column size: 7.8 mm inner diameter x 30 cm length x 2
Guaranteed theoretical plate number: about 14000TP / 30cm
The column temperature is 40 ° C.

The moving bed is selected from tetrahydrofuran and chloroform that do not adsorb to the filler, and the flow rate is 1.0 ml / min. The injection concentration is 0.1% by weight, and the injection amount is 0.10 ml. As a detector, UV / Vis (SPD-20AV, manufactured by Shimadzu Corporation) is used.
In SEC measurement, the elution time is shorter for higher molecular weight components and the elution time is longer for lower molecular weight components, but using the calibration curve calculated from the elution time of polystyrene (standard sample) with a known molecular weight, the elution time of the sample is changed to the molecular weight. The molecular weight distribution is determined by conversion, and the number average molecular weight is calculated therefrom.

The measuring device is not particularly limited as long as the same measurement as described above is possible, and other measuring devices may be used, but the above measuring device is preferably used.
[Physical properties]
The glass transition temperature of the polymer of the present invention is usually 70 ° C. or higher, preferably 100 ° C. or higher, more preferably 120 ° C. or higher, and usually 400 ° C. or lower, preferably 300 ° C. or lower, more preferably 250 ° C. or lower.

Within the above range, heat resistance is good, which is preferable in terms of a long driving life when used as an element.
In addition, the polymer of the present invention is preferably higher in solubility in an organic solvent from the viewpoint that a film can be formed uniformly.
The ionization potential of the polymer of the present invention is usually 4.50 to 6.00 eV, preferably 4.90 to 5.90 eV, and more preferably 5.00 to 5.80 eV. Within the above range, holes are easily generated and the hole injection property from the electrode is excellent, which is preferable in terms of low driving voltage when used as an element.

[Synthesis method]
The polymer of the present invention can be synthesized by selecting a raw material according to the structure of the target polymer and using a known method. The method for producing the polymer of the present invention is not particularly limited, and is arbitrary as long as the polymer of the present invention is obtained. For example, it can be produced by a polymerization method using a Suzuki reaction, a polymerization method using a Grignard reaction, a polymerization method using a Yamamoto reaction, a polymerization method using an Ullmann reaction, a polymerization method using a Buchwald-Hartwig reaction, or the like. Among these, the polymerization method by Ullmann reaction and the polymerization method by Buchwald-Hartwig reaction are preferably used.

  In the case of the polymerization method by the Ullmann reaction and the polymerization method by the Buchwald-Hartwig reaction, for example, an aryl halide having the formula (1a) (X represents a halogen atom such as I, Br, Cl, F, etc.) and a formula ( The polymer of the present invention is synthesized by reacting with the primary aminoaryl or secondary diaminoaryl represented by 2a).

(Wherein X represents a halogen atom, Ar ^{1 to} Ar ⁵ , R ¹ , R ² , q and r are the same as above)
In the above polymerization method, the reaction for forming an N-aryl bond is usually performed in the presence of a base such as potassium carbonate, tert-butoxy sodium, triethylamine or the like. Moreover, it can also carry out in presence of transition metal catalysts, such as copper and a palladium complex, for example.
The polymer of the present invention can also be obtained by polymerizing a carbonyl compound or divinyl compound and a triarylamine whose amino group has a p-position being a hydrogen atom under an acid catalyst such as trifluoromethanesulfonic acid or sulfuric acid. Can be synthesized.

<Charge transport material>
The polymer of the present invention is preferably used as a charge transport material, and particularly preferably used as an organic electroluminescent element material. When used as an organic electroluminescent element material, it is preferably used as a material for forming a hole injection layer and / or a hole transport layer in the organic electroluminescent element.

Moreover, since an organic electroluminescent element can be manufactured easily, it is preferable to use the polymer of this invention for the organic layer formed by a wet film-forming method.
<Composition for organic electroluminescence device>
The composition for organic electroluminescent elements of the present invention contains at least one polymer of the present invention. In addition, the composition for organic electroluminescent elements of the present invention may contain one type of the polymer of the present invention, or may contain two or more types in any combination and in any ratio. Good.

The content of the polymer of the present invention contained in the composition for organic electroluminescent elements of the present invention is usually 0.01 to 70% by weight, preferably 0.1 to 60% by weight, more preferably 0.5 to 50%. % By weight.
Within the above range, it is preferable because defects are hardly generated in the formed organic layer and unevenness in film thickness is hardly generated.

(solvent)
The composition for organic electroluminescent elements of the present invention usually contains a solvent. This solvent is preferably one that dissolves the polymer of the present invention. Specifically, a solvent that dissolves the polymer of the present invention in an amount of usually 0.05% by weight or more, preferably 0.5% by weight or more, and more preferably 1% by weight or more is suitable.

  Examples of solvents include: aromatic solvents such as toluene, xylene, methicylene, cyclohexylbenzene; halogen-containing solvents such as 1,2-dichloroethane, chlorobenzene, o-dichlorobenzene; ethylene glycol dimethyl ether, ethylene glycol diethyl ether, propylene Aliphatic ethers such as glycol-1-monomethyl ether acetate (PGMEA), 1,2-dimethoxybenzene, 1,3-dimethoxybenzene, anisole, phenetole, 2-methoxytoluene, 3-methoxytoluene, 4-methoxytoluene, Ether solvents such as aromatic ethers such as 2,3-dimethylanisole and 2,4-dimethylanisole; aliphatic esters such as ethyl acetate, n-butyl acetate, ethyl lactate and n-butyl lactate; phenyl acetate, propylene And organic solvents such as; phenyl phosphate, methyl benzoate, ethyl benzoate, isopropyl benzoate, propyl benzoate, ester solvents such as aromatic esters such as benzoic acid n- butyl. In addition, 1 type may be used for a solvent and it may use 2 or more types together by arbitrary combinations and arbitrary ratios.

Among them, as a solvent contained in the composition for organic electroluminescent elements of the present invention, a solvent having a surface tension at 20 ° C. of usually less than 40 dyn / cm, preferably 36 dyn / cm or less, more preferably 33 dyn / cm or less. Is preferred.
In the case of forming a layer by crosslinking the polymer after applying the composition for organic electroluminescent elements of the present invention, it is preferable that the affinity with the base is high. This is because the uniformity of the film quality greatly affects the uniformity and stability of light emission of the organic electroluminescence device. Therefore, the composition for organic electroluminescent elements used in the wet film-forming method is required to have a low surface tension so as to form a uniform coating film with higher leveling properties. Therefore, it is preferable to use a solvent having a low surface tension as described above so that a uniform layer containing the polymer of the present invention can be formed, and thus a uniform crosslinked layer can be formed. is there.

  Specific examples of the low surface tension solvent include the above-mentioned aromatic solvents such as toluene, xylene, methicylene, cyclohexylbenzene, ester solvents such as ethyl benzoate, ether solvents such as anisole, trifluoromethoxyanisole, penta Examples include fluoromethoxybenzene, 3- (trifluoromethyl) anisole, ethyl (pentafluorobenzoate), and the like.

  On the other hand, as a solvent contained in the composition for organic electroluminescent elements of the present invention, a solvent having a vapor pressure at 25 ° C. of usually 10 mmHg or less, preferably 5 mmHg or less and usually 0.1 mmHg or more is preferable. . By using such a solvent, a composition for an organic electroluminescent device suitable for a process for producing an organic electroluminescent device by a wet film forming method and suitable for the properties of the conjugated polymer of the present invention can be prepared. Because.

Specific examples of such a solvent include the above-described aromatic solvents such as toluene, xylene, and methicylene, ether solvents, and ester solvents.
By the way, moisture may cause deterioration of the performance of the organic electroluminescent element, and in particular, may promote a decrease in luminance during continuous driving. Therefore, in order to reduce moisture remaining during wet film formation as much as possible, among the above solvents, those having a water solubility at 25 ° C. of preferably 1% by weight or less are preferred, and solvents having a water content of 0.1% by weight or less Is more preferable.

The concentration of the solvent contained in the composition for organic electroluminescent elements of the present invention is usually 10% by weight or more, preferably 30% by weight or more, more preferably 50% by weight or more, and particularly preferably 80% by weight or more. Thereby, the flatness and uniformity of the formed layer can be improved.
Furthermore, the composition for an organic electroluminescent element of the present invention is a polymer other than the polymer of the present invention, a light emitting material, a hole transporting compound, an electron transporting compound, depending on the type of the organic layer to be formed, etc. It may contain an electron-accepting compound.

In addition, the composition for organic electroluminescent elements of this invention may contain only 1 type of other components, and may contain 2 or more types by arbitrary combinations and arbitrary ratios.
When the composition for organic electroluminescent elements of the present invention is used for forming a hole injection layer, it is preferable to further contain an electron-accepting compound from the viewpoint of reducing resistance.
As the electron-accepting compound, a compound having an oxidizing power and an ability to accept one electron from the polymer of the present invention is preferable. Specifically, a compound with an electron affinity of 4 eV or more is preferable, and a compound with a compound of 5 eV or more is more preferable.

  Such a compound is preferably an ionic compound having a structure in which at least one organic group is bonded to an element belonging to Groups 15 to 17 of the periodic table with a carbon atom. In particular, the following formula (I-1) It is preferable that it is a compound represented by these.

In formula (I-1), R ¹¹ represents an organic group bonded to A ^{1 through a} carbon atom, and R ¹² represents an arbitrary substituent. R ¹¹ and R ¹² may be bonded to each other to form a ring.
The type of R ¹¹ is not particularly limited as long as it is an organic group having a carbon atom at the bonding portion with A ¹ unless it is contrary to the gist of the present invention. The molecular weight of R ¹¹ is a value including a substituent and is usually 1000 or less, preferably 500 or less.

Preferred examples of R ¹¹ include alkyl groups, alkenyl groups, alkynyl groups, aromatic hydrocarbon groups, and aromatic heterocyclic groups from the viewpoint of delocalizing positive charges. Among them, an aromatic hydrocarbon group or an aromatic heterocyclic group is preferable because it delocalizes positive charges and is thermally stable.
Examples of the aromatic hydrocarbon group include a monovalent group derived from a 5- or 6-membered monocyclic ring or a 2-5 condensed ring, and a group capable of delocalizing a positive charge on the group. Specific examples thereof include monovalent groups derived from a benzene ring, naphthalene ring, anthracene ring, phenanthrene ring, perylene ring, tetracene ring, pyrene ring, benzpyrene ring, chrysene ring, triphenylene ring, acenaphthene ring, fluorene ring, and the like. Can be mentioned.

  The aromatic heterocyclic group is a monovalent group derived from a 5- or 6-membered monocyclic ring or a 2-4 condensed ring, and includes a group that can delocalize a positive charge on the group. Specific examples thereof include furan ring, benzofuran ring, thiophene ring, benzothiophene ring, pyrrole ring, pyrazole ring, triazole ring, imidazole ring, oxadiazole ring, indole ring, carbazole ring, pyrroloimidazole ring, pyrrolopyrazole ring, Pyrrolopyrrole ring, thienopyrrole ring, thienothiophene ring, furopyrrole ring, furofuran ring, thienofuran ring, benzisoxazole ring, benzisothiazole ring, benzimidazole ring, pyridine ring, pyrazine ring, pyridazine ring, pyrimidine ring, triazine ring, quinoline And monovalent groups derived from a ring, an isoquinoline ring, a sinoline ring, a quinoxaline ring, a phenanthridine ring, a benzimidazole ring, a perimidine ring, a quinazoline ring, a quinazolinone ring, an azulene ring, and the like.

Examples of the alkyl group include linear, branched, or cyclic alkyl groups having a carbon number of usually 1 or more and usually 12 or less, preferably 6 or less. Specific examples include methyl group, ethyl group, n-propyl group, 2-propyl group, n-butyl group, isobutyl group, tert-butyl group, cyclohexyl group and the like.
Examples of the alkenyl group include those having usually 2 or more, usually 12 or less, preferably 6 or less. Specific examples include a vinyl group, an allyl group, and a 1-butenyl group.

Examples of the alkynyl group include those having usually 2 or more, usually 12 or less, preferably 6 or less. Specific examples include ethynyl group and propargyl group.
R ¹² is not particularly limited as long as it is not contrary to the gist of the present invention. The molecular weight of R ¹² is a value including a substituent and is usually 1000 or less, preferably 500 or less.
Examples of R ¹² are alkyl group, alkenyl group, alkynyl group, aromatic hydrocarbon group, aromatic heterocyclic group, amino group, alkoxy group, aryloxy group, acyl group, alkoxycarbonyl group, aryloxycarbonyl group, alkyl Examples include carbonyloxy group, alkylthio group, arylthio group, sulfonyl group, alkylsulfonyl group, arylsulfonyl group, cyano group, hydroxyl group, thiol group, silyl group and the like.

Among them, like R ¹¹ , an organic group having a carbon atom at the bonding portion to A ¹ is preferable because of its high electron accepting property. Examples thereof include an alkyl group, an alkenyl group, an alkynyl group, an aromatic hydrocarbon group, Aromatic heterocyclic groups are preferred. In particular, an aromatic hydrocarbon group or an aromatic heterocyclic group is preferable because it has a large electron accepting property and is thermally stable.
Examples of the alkyl group, alkenyl group, alkynyl group, aromatic hydrocarbon group, and aromatic heterocyclic group are the same as those described above for R ¹¹ .

Examples of the amino group include an alkylamino group, an arylamino group, and an acylamino group.
Examples of the alkylamino group include alkylamino groups having one or more alkyl groups usually having 1 or more carbon atoms and usually 12 or less, preferably 6 or less carbon atoms. Specific examples include methylamino group, dimethylamino group, diethylamino group, dibenzylamino group and the like.

Examples of the arylamino group include arylamino groups having at least one aromatic hydrocarbon group or aromatic heterocyclic group having usually 3 or more, preferably 4 or more, and usually 25 or less, preferably 15 or less. It is done. Specific examples include phenylamino group, diphenylamino group, tolylamino group, pyridylamino group, thienylamino group and the like.
The acylamino group includes an acylamino group having one or more acyl groups having usually 2 or more carbon atoms and usually 25 or less, preferably 15 or less carbon atoms. Specific examples include an acetylamino group and a benzoylamino group.

The alkoxy group includes an alkoxy group having usually 1 or more carbon atoms and usually 12 or less, preferably 6 or less. Specific examples include a methoxy group, an ethoxy group, and a butoxy group.
Examples of the aryloxy group include aryloxy groups having an aromatic hydrocarbon group or an aromatic heterocyclic group having usually 3 or more, preferably 4 or more, and usually 25 or less, preferably 15 or less. Specific examples include phenyloxy group, naphthyloxy group, pyridyloxy group, thienyloxy group and the like.

Examples of the acyl group include acyl groups having usually 1 or more carbon atoms and usually 25 or less, preferably 15 or less. Specific examples include formyl group, acetyl group, benzoyl group and the like.
The alkoxycarbonyl group includes an alkoxycarbonyl group having usually 2 or more carbon atoms and usually 10 or less, preferably 7 or less. Specific examples include a methoxycarbonyl group and an ethoxycarbonyl group.

Examples of the aryloxycarbonyl group include those having an aromatic hydrocarbon group or an aromatic heterocyclic group having usually 3 or more, preferably 4 or more, and usually 25 or less, preferably 15 or less. Specific examples include a phenoxycarbonyl group and a pyridyloxycarbonyl group.
Examples of the alkylcarbonyloxy group include alkylcarbonyloxy groups having usually 2 or more carbon atoms and usually 10 or less, preferably 7 or less. Specific examples include an acetoxy group and a trifluoroacetoxy group.

The alkylthio group includes an alkylthio group having usually 1 or more carbon atoms and usually 12 or less, preferably 6 or less. Specific examples include a methylthio group and an ethylthio group.
The arylthio group includes an arylthio group having usually 3 or more, preferably 4 or more, and usually 25 or less, preferably 14 or less. Specific examples include a phenylthio group, a naphthylthio group, and a pyridylthio group.

Specific examples of the alkylsulfonyl group and the arylsulfonyl group include a mesyl group and a tosyl group.
Specific examples of the sulfonyloxy group include a mesyloxy group and a tosyloxy group.
Specific examples of the silyl group include a trimethylsilyl group and a triphenylsilyl group.

As described above, the groups exemplified as R ¹¹ and R ¹² may be further substituted with other substituents as long as not departing from the spirit of the present invention. The type of the substituent is not particularly limited, and examples thereof include a halogen atom, a cyano group, a thiocyano group, and a nitro group, in addition to the groups exemplified as R ¹¹ and R ¹² . Among these, from the viewpoint of not hindering the heat resistance and electron acceptability of the ionic compound (electron accepting compound), an alkyl group, an alkenyl group, an alkynyl group, an alkoxy group, an aryloxy group, an aromatic hydrocarbon group, an aromatic heterocyclic ring. Groups are preferred.

In Formula (I-1), A ¹ is preferably an element belonging to Group 17 of the long-period periodic table, and from the viewpoint of electron acceptability and availability, the first period before the fifth period of the periodic table (first 3 to 5th element) is preferable. That is, as A ¹ , any ^one of an iodine atom, a bromine atom, and a chlorine atom is preferable.
In particular, from the viewpoint of electron acceptability and stability of the compound, an ionic compound in which A ¹ in formula (I-1) is a bromine atom or an iodine atom, particularly preferably an ionic compound in which an iodine atom is used.

In formula (I-1), Z ₁ ^n1- each independently represents a counter anion. The type of the counter anion is not particularly limited, and may be a monoatomic ion or a complex ion. However, the larger the size of the counter anion, the more the negative charge is delocalized, and the positive charge is also delocalized thereby increasing the electron accepting ability. Therefore, the complex ion is preferable to the monoatomic ion.
n ₁ is each independently an arbitrary positive integer corresponding to the ionic value of the counter anion Z ₁ ⁿ¹⁻ . The value of n ₁ is not particularly limited, but is preferably 1 or 2, and most preferably 1.

Specific examples of Z ₁ ^n1- include hydroxide ion, fluoride ion, chloride ion, bromide ion, iodide ion, cyanide ion, nitrate ion, nitrite ion, sulfate ion, sulfite ion, perchloric acid. Ion, perbromate ion, periodate ion, chlorate ion, chlorite ion, hypochlorite ion, phosphate ion, phosphite ion, hypophosphite ion, borate ion, isocyanate ion, Hydrosulfide ion, tetrafluoroborate ion, hexafluorophosphate ion, hexachloroantimonate ion; carboxylate ion such as acetate ion, trifluoroacetate ion, benzoate ion; methanesulfonic acid, trifluoromethanesulfonate ion, etc. Sulfonate ion; alkoxy ion such as methoxy ion and t-butoxy ion Tetrafluoroborate periodate ion and hexane tetrafluoroborate periodate ion.

Further, as the counter anion Z ₁ ⁿ¹⁻ , in ^terms of the stability of the compound and solubility in the solvent, the negative charge is delocalized due to its large size, and the positive charge is also delocalized accordingly. Therefore, the complex ion represented by the formula (I-2) is particularly preferable.

In formula (I-2), each E ³ independently represents an element belonging to Group 13 of the long-period periodic table. Of these, a boron atom, an aluminum atom, and a gallium atom are preferable, and a boron atom is preferable from the viewpoint of stability of the compound and ease of synthesis and purification.
In formula (I-2), Ar ^{31 to} Ar ³⁴ each independently represents an aromatic hydrocarbon group or an aromatic heterocyclic group. Examples of the aromatic hydrocarbon group and the aromatic heterocyclic group include monovalent groups derived from 5- or 6-membered monocyclic rings or 2 to 4 condensed rings similar to those exemplified above for R ^11. It is done. Among these, a monovalent group derived from a benzene ring, a naphthalene ring, a pyridine ring, a pyrazine ring, a pyridazine ring, a pyrimidine ring, a triazine ring, a quinoline ring, or an isoquinoline ring is preferable from the viewpoint of stability and heat resistance of the compound.

The aromatic hydrocarbon group and the aromatic heterocyclic group exemplified as Ar ^{31 to} Ar ³⁴ may be further substituted with another substituent as long as not departing from the gist of the present invention. The type of the substituent is not particularly limited, and any substituent can be applied, but an electron-withdrawing group is preferable.
Illustrative examples of preferred electron-withdrawing groups as the substituent that Ar ^{31 to} Ar ³⁴ may have include halogen atoms such as fluorine atom, chlorine atom and bromine atom; cyano group; thiocyano group; nitro group; mesyl group Alkylsulfonyl groups such as tosyl group; arylsulfonyl groups such as tosyl group; acyl groups such as formyl group, acetyl group, benzoyl group and the like, usually having 1 or more, usually 12 or less, preferably 6 or less; methoxycarbonyl group, ethoxycarbonyl An alkoxycarbonyl group having 2 or more carbon atoms, usually 10 or less, preferably 7 or less; a phenoxycarbonyl group, a pyridyloxycarbonyl group or the like, and usually having 3 or more carbon atoms, preferably 4 or more and usually 25 or less. Preferably an aryloxycarbonyl group having 15 or less aromatic hydrocarbon groups or aromatic heterocyclic groups; Carbonyl group; aminosulfonyl group; fluorine atom in a linear, branched or cyclic alkyl group having usually 1 or more, usually 10 or less, preferably 6 or less, such as trifluoromethyl group or pentafluoroethyl group And a haloalkyl group substituted with a halogen atom such as a chlorine atom.

Especially, it is more preferable that at least one group among Ar ^{31 to} Ar ³⁴ has one or two or more fluorine atoms or chlorine atoms as a substituent. In particular, it is most preferably a perfluoroaryl group in which all the hydrogen atoms of Ar ^{31 to} Ar ³⁴ are substituted with fluorine atoms from the viewpoint of efficiently delocalizing negative charges and having an appropriate sublimation property. preferable. Specific examples of the perfluoroaryl group include a pentafluorophenyl group, a heptafluoro-2-naphthyl group, and a tetrafluoro-4-pyridyl group.

The molecular weight of the electron-accepting compound in the present invention is usually 100 to 5000, preferably 300 to 3000, and more preferably 400 to 2000.
Within the above range, the positive charge and the negative charge are sufficiently delocalized, the electron accepting ability is good, and it is preferable that the charge transport is not hindered.
Specific examples of the electron-accepting compound in the present invention are shown below, but the present invention is not limited thereto.

In addition, an electron-accepting compound may be used individually by 1 type, and may use 2 or more types by arbitrary combinations and a ratio.
<Organic electroluminescent device>
The organic electroluminescent device of the present invention has an anode, a cathode, and an organic layer between the anode and the cathode on a substrate, and the organic layer is formed using the composition for an organic electroluminescent device of the present invention. An organic electroluminescence device including a layer formed by a wet film formation method.

In the present invention, the organic layer formed by the wet film formation method is particularly preferably a hole injection layer or a hole transport layer.
In the present invention, it is particularly preferable to form the hole injection layer, the hole transport layer, and the light emitting layer among the organic layers by wet film formation.
<Configuration of organic electroluminescent element>
Below, the layer structure of the organic electroluminescent element of this invention, its formation method, etc. are demonstrated with reference to FIG.

FIG. 1 is a schematic cross-sectional view showing a structural example of an organic electroluminescent device according to the present invention. In FIG. 1, 1 is a substrate, 2 is an anode, 3 is a hole injection layer, 4 is a hole transport layer, 5 Represents a light-emitting layer, 6 represents a hole blocking layer, 7 represents an electron transport layer, 8 represents an electron injection layer, and 9 represents a cathode.
[substrate]
The substrate serves as a support for the organic electroluminescence device, and quartz or glass plates, metal plates or metal foils, plastic films or sheets are used. In particular, a glass plate or a transparent synthetic resin plate such as polyester, polymethacrylate, polycarbonate, or polysulfone is preferable. When using a synthetic resin substrate, it is necessary to pay attention to gas barrier properties. If the gas barrier property of the substrate is too small, the organic electroluminescent element may be deteriorated by the outside air that has passed through the substrate, which is not preferable. For this reason, a method of providing a gas barrier property by providing a dense silicon oxide film or the like on at least one surface of the synthetic resin substrate is also a preferable method.

[2] Anode
The anode plays a role of hole injection into a layer on the light emitting layer side (hole injection layer, light emitting layer, or the like) described later. This anode is usually made of metal such as aluminum, gold, silver, nickel, palladium, platinum, metal oxide such as oxide of indium and / or tin, metal halide such as copper iodide, carbon black, or poly It is composed of conductive polymers such as (3-methylthiophene), polypyrrole, and polyaniline. In general, the anode is often formed by a sputtering method, a vacuum deposition method, or the like. Also, in the case of fine metal particles such as silver, fine particles such as copper iodide, carbon black, conductive metal oxide fine particles, conductive polymer fine powder, etc., it is dispersed in an appropriate binder resin solution and placed on the substrate. An anode can also be formed by coating. Furthermore, in the case of a conductive polymer, a thin film can be directly formed on a substrate by electrolytic polymerization, or an anode can be formed by applying a conductive polymer on a substrate (Applied
Physics Letters, 1992, Vol. 60, pp. 2711). The anode can be formed by stacking different materials.

  The thickness of the anode varies depending on the required transparency. When transparency is required, it is desirable that the visible light transmittance is usually 60% or more, preferably 80% or more. In this case, the thickness is usually 5 nm or more, preferably 10 nm or more, Usually, it is 1000 nm or less, preferably 500 nm or less. If it may be opaque, the anode may be the same as the substrate. Furthermore, it is also possible to laminate different conductive materials on the anode.

In addition, the surface of the anode is treated with ultraviolet (UV) / ozone, oxygen plasma, or argon plasma for the purpose of removing impurities adhering to the anode and adjusting the ionization potential to improve the hole injection property. Is preferred.
[3] Hole injection layer
A hole injection layer is formed on the anode.

The hole injection layer is a layer that transports holes to a layer adjacent to the cathode side of the anode.
The organic electroluminescent device of the present invention may have a configuration in which the hole injection layer is omitted.
The hole injection layer preferably contains a hole transporting compound, and more preferably contains a hole transporting compound and an electron accepting compound. Further, the hole injection layer preferably contains a cation radical compound, and particularly preferably contains a cation radical compound and a hole transporting compound.

The hole injection layer may contain a binder resin and a coating property improving agent as necessary. The binder resin is preferably one that hardly acts as a charge trap.
The hole injection layer can be formed by depositing only the electron-accepting compound on the anode by a wet film-forming method, and directly applying and laminating the charge transport material composition thereon. In this case, a part of the charge transport material composition interacts with the electron-accepting compound, so that a layer excellent in hole injecting property is formed.

(Hole transporting compound)
As said hole transportable compound, the compound which has the ionization potential of 4.5 eV-6.0 eV is preferable. However, when used in the wet film forming method, it is preferable that the solubility in the solvent used in the wet film forming method is high.
As the hole transporting compound, the polymer of the present invention is preferable from the viewpoint of excellent film formability and high charge injecting and transporting ability. That is, it is preferable to form a layer using the composition for organic electroluminescent elements of the present invention.

When a compound other than the polymer of the present invention is used as the hole transporting compound, examples of the hole transporting compound include aromatic amine compounds, phthalocyanine derivatives, porphyrin derivatives, oligothiophene derivatives, polythiophene derivatives, and the like. Of these, aromatic amine compounds are preferred from the viewpoints of amorphousness and visible light transmittance.
The type of the aromatic amine compound is not particularly limited, and may be a low molecular compound or a high molecular compound. From the viewpoint of the surface smoothing effect, a polymer having a weight average molecular weight of 1,000 or more and 1,000,000 or less. A compound (polymerizable hydrocarbon compound in which repeating units are continuous) is preferred.

  Preferable examples of the aromatic tertiary amine polymer compound also include a polymer compound having a repeating unit represented by the following formula (1).

(In the above formula (1), Ar ^b1 and Ar ^b2 are each independently an aromatic hydrocarbon ring group which may have a substituent, or an aromatic heterocycle which may have a substituent. Represents a group Ar ^b3 to
Ar ^b5 each independently represents an aromatic hydrocarbon ring group which may have a substituent, or an aromatic heterocyclic group which may have a substituent. Z ^b represents a linking group selected from the following linking group group. Of Ar ^{b1 to} Ar ^b5 , two groups bonded to the same N atom may be bonded to each other to form a ring. )

(In the above formulas, Ar ^{b6 to} Ar ^b16 are each independently an aromatic hydrocarbon ring which may have a substituent or an aromatic heterocyclic ring which may have a substituent. R ^b1 and R ^b2 each independently represents a hydrogen atom or an arbitrary substituent.
As Ar ^{b1 to} Ar ^b16 , a monovalent or divalent group derived from any aromatic hydrocarbon ring or aromatic heterocycle is applicable. These groups may be the same or different from each other. Further, these groups may further have an arbitrary substituent.

Specific examples of the aromatic tertiary amine polymer compound having a repeating unit represented by the general formula (1) include compounds described in International Publication No. 2005/089024 pamphlet.
The hole transporting compound used as the material for the hole injection layer may contain any one of these compounds alone, or may contain two or more.

In the case of containing two or more kinds of hole transporting compounds, the combination is arbitrary, but one or more kinds of aromatic tertiary amine polymer compounds and one or two kinds of other hole transporting compounds. It is preferable to use the above together.
(Electron-accepting compound)
The electron-accepting compound is the same as that described in the section <Composition for organic electroluminescence device>. The same applies to preferred specific examples.

(Cation radical compound)
As the cation radical compound, an ionic compound composed of a cation radical which is a chemical species obtained by removing one electron from a hole transporting compound and a counter anion is preferable. However, when the cation radical is derived from a hole transporting polymer compound, the cation radical has a structure in which one electron is removed from the repeating unit of the polymer compound.

The cation radical is preferably a chemical species obtained by removing one electron from the compound described above as the hole transporting compound. A chemical species obtained by removing one electron from a compound preferable as a hole transporting compound is preferable in terms of amorphousness, visible light transmittance, heat resistance, solubility, and the like.
Here, the cation radical compound can be generated by mixing the hole transporting compound and the electron accepting compound. That is, by mixing the hole transporting compound and the electron accepting compound, electron transfer occurs from the hole transporting compound to the electron accepting compound, and the cation radical and the counter anion of the hole transporting compound A cation ion compound consisting of

Cationic radical compounds derived from polymer compounds such as PEDOT / PSS (Adv. Mater., 2000, 12, 481) and emeraldine hydrochloride (J. Phys. Chem., 1990, 94, 7716) It is also produced by oxidative polymerization (dehydrogenation polymerization).
Oxidative polymerization here refers to oxidation of a monomer chemically or electrochemically with peroxodisulfate in an acidic solution. In the case of this oxidative polymerization (dehydrogenation polymerization), the monomer is polymerized by oxidation, and a cation radical that is removed from the polymer repeating unit by using an anion derived from an acidic solution as a counter anion is removed. Generate.

The hole injection layer can be formed by either a wet film formation method or a dry film formation method such as a vacuum deposition method. The film is preferably formed by a wet film forming method from the viewpoint of excellent film forming properties.
The thickness of the hole injection layer is usually 5 nm or more, preferably 10 nm or more, and usually 1000 nm or less, preferably 500 nm or less.
The content of the electron-accepting compound in the hole-injecting layer with respect to the hole-transporting compound is usually 0.1 mol% or more, preferably 1 mol% or more. However, it is usually 100 mol% or less, preferably 40 mol% or less.

(Other components)
As a material for the hole injection layer, other components may be further contained in addition to the above-described hole transporting compound and electron accepting compound as long as the effects of the present invention are not significantly impaired. Examples of other components include various light emitting materials, electron transporting compounds, binder resins, and coating property improving agents. In addition, only 1 type may be used for another component and it may use 2 or more types together by arbitrary combinations and ratios.

(solvent)
At least one of the solvents of the composition for forming a hole injection layer used in the wet film formation method is preferably a compound that can dissolve the constituent material of the hole injection layer. The boiling point of this solvent is usually 110 ° C. or higher, preferably 140 ° C. or higher, particularly 200 ° C. or higher, usually 400 ° C. or lower, and preferably 300 ° C. or lower. If the boiling point of the solvent is too low, the drying speed is too high and the film quality may be deteriorated. Further, if the boiling point of the solvent is too high, it is necessary to increase the temperature of the drying step, which may adversely affect other layers and the substrate.

Examples of the solvent include ether solvents, ester solvents, aromatic hydrocarbon solvents, amide solvents, and the like.
Examples of ether solvents include aliphatic ethers such as ethylene glycol dimethyl ether, ethylene glycol diethyl ether, and propylene glycol-1-monomethyl ether acetate (PGMEA); 1,2-dimethoxybenzene, 1,3-dimethoxybenzene, anisole , Phenetole, 2-methoxytoluene, 3-methoxytoluene, 4-methoxytoluene, 2,3-dimethylanisole, aromatic ethers such as 2,4-dimethylanisole, and the like.

Examples of the ester solvent include aromatic esters such as phenyl acetate, phenyl propionate, methyl benzoate, ethyl benzoate, propyl benzoate, and n-butyl benzoate.
Examples of the aromatic hydrocarbon solvent include toluene, xylene, cyclohexylbenzene, 3-isopropylpropylphenyl, 1,2,3,4-tetramethylbenzene, 1,4-diisopropylbenzene, cyclohexylbenzene, and methylnaphthalene. Can be mentioned.
Examples of the amide solvent include N, N-dimethylformamide, N, N-dimethylacetamide, and the like.

In addition, dimethyl sulfoxide and the like can also be used.
These solvent may use only 1 type and may use 2 or more types by arbitrary combinations and a ratio.
(Film formation method)
After preparing the composition for forming a hole injection layer, the composition is applied onto a layer corresponding to the lower layer of the hole injection layer (usually an anode) by wet film formation and dried to form a hole injection layer. Form.

The temperature in the film forming step is preferably 10 ° C. or higher, and preferably 50 ° C. or lower in order to prevent film loss due to the formation of crystals in the composition.
Although the relative humidity in a film-forming process is not limited unless the effect of this invention is impaired remarkably, it is 0.01 ppm or more normally and 80% or less normally.
After coating, the film of the composition for forming a hole injection layer is usually dried by heating or the like. As a drying method, a heating step is usually performed. Examples of the heating means used in the heating step include a clean oven, a hot plate, infrared rays, a halogen heater, microwave irradiation and the like. Among them, a clean oven and a hot plate are preferable in order to uniformly apply heat to the entire film.

  The heating temperature in the heating step is preferably heated at a temperature equal to or higher than the boiling point of the solvent used in the composition for forming a hole injection layer as long as the effects of the present invention are not significantly impaired. In the case of a mixed solvent containing two or more types of solvents used in the composition for forming a hole injection layer, it is preferable that at least one type is heated at a temperature equal to or higher than the boiling point of the solvent. In consideration of an increase in the boiling point of the solvent, the heating step is preferably performed at 120 ° C. or higher, preferably 410 ° C. or lower.

  In the heating step, the heating temperature is preferably equal to or higher than the boiling point of the solvent of the composition for forming a hole injection layer. The heating time is not limited as long as the coating film does not sufficiently crosslink, but is preferably 10 seconds or longer and usually 180 minutes or shorter. If the heating time is too long, the components of the other layers tend to diffuse, and if it is too short, the hole injection layer tends to be inhomogeneous. Heating may be performed in two steps.

<Formation of hole injection layer by vacuum deposition>
When forming the hole injection layer by vacuum deposition, one or more of the constituent materials of the hole injection layer (the aforementioned hole transporting compound, electron accepting compound, etc.) are placed in a vacuum vessel. Put in crucibles (in case of using two or more kinds of materials, put them in each crucible), evacuate the inside of the vacuum vessel to about 10 ⁻⁴ Pa with a suitable vacuum pump, and then heat the crucible (two or more kinds) When using materials, heat each crucible) and evaporate by controlling the amount of evaporation (when using two or more materials, evaporate by independently controlling the amount of evaporation) and place it facing the crucible. A hole injection layer is formed on the anode of the substrate. In addition, when using 2 or more types of materials, those hole mixture layers can also be formed by putting them in a crucible and heating and evaporating them.

The degree of vacuum at the time of vapor deposition is not limited as long as the effects of the present invention are not significantly impaired, but usually 0.1 × 10 ⁻⁶ Torr (0.13 × 10 ⁻⁴ Pa) or more, usually 9.0 × 10 ⁻⁶ Torr. (12.0 × 10 ⁻⁴ Pa) or less. The deposition rate is not limited as long as the effect of the present invention is not significantly impaired, but is usually 0.1 Å / second or more and usually 5.0 Å / second or less. The film forming temperature at the time of vapor deposition is not limited as long as the effect of the present invention is not significantly impaired, but is preferably 10 ° C. or higher, preferably 50 ° C. or lower.

The thickness of the hole injection layer is usually 5 nm or more, preferably 10 nm or more, and usually 1000 nm or less, preferably 500 nm or less.
[4] Hole transport layer
The hole transport layer can be formed on the hole injection layer when there is a hole injection layer and on the anode when there is no hole injection layer. The organic electroluminescent device of the present invention may have a configuration in which the hole transport layer is omitted.

  The material for forming the hole transport layer is preferably a material having a high hole transport capability and capable of efficiently transporting the injected holes. Therefore, it is preferable that the ionization potential is small, the transparency to visible light is high, the hole mobility is large, the stability is high, and impurities that become traps are not easily generated during manufacturing or use. In many cases, since it is in contact with the light emitting layer, it is preferable not to quench the light emitted from the light emitting layer or to reduce the efficiency by forming an exciplex with the light emitting layer.

As the hole-transporting compound, the polymer of the present invention is particularly preferable from the above points. When a compound other than the polymer of the present invention is used as the hole transporting compound, a material conventionally used as a constituent material of the hole transport layer can be used. Examples of conventionally used materials include those exemplified as the hole transporting compound used in the above-described hole injection layer. In addition, two or more condensed aromatic rings including two or more tertiary amines represented by 4,4′-bis [N- (1-naphthyl) -N-phenylamino] biphenyl are substituted with nitrogen atoms. Aromatic amine compounds having a starburst structure such as aromatic diamines (Japanese Patent Laid-Open No. Hei 5-234681), 4,4 ′, 4 ″ -tris (1-naphthylphenylamino) triphenylamine (J. Lumin. 72-74, 985, 1997), aromatic amine compounds consisting of tetramers of triphenylamine (Chem. Commun., 2175, 1996), 2,2 ′, 7,7′-tetrakis. Spiro compounds such as-(diphenylamino) -9,9'-spirobifluorene (Synth. Metals, 91, 209)
Page, 1997), and carbazole derivatives such as 4,4′-N, N′-dicarbazolebiphenyl. Further, for example, polyvinyl carbazole, polyvinyl triphenylamine (Japanese Patent Laid-Open No. 7-53953), polyarylene ether sulfone (Polym. Adv. Tech., 7, 33, 1996) containing tetraphenylbenzidine, etc. Can be mentioned.

When the hole transport layer is formed by wet film formation, a composition for forming a hole transport layer is prepared in the same manner as in the formation of the hole injection layer, and then heated and dried after coating.
The composition for forming a hole transport layer contains a solvent in addition to the above hole transport compound. The solvent used is the same as that used for the composition for forming a hole injection layer. Also, the coating conditions, heating and drying conditions, and the like are the same as in the case of forming the hole injection layer.

In the case of forming the hole transport layer by vacuum deposition, the film forming conditions are the same as in the case of forming the hole injection layer.
The hole transport layer may contain various light emitting materials, electron transport compounds, binder resins, coatability improvers, and the like in addition to the hole transport compound.
The hole transport layer may also be a layer formed by crosslinking a crosslinkable compound. The crosslinkable compound is a compound having a crosslinkable group, and forms a network polymer compound by crosslinking.

Examples of such crosslinkable groups include cyclic ether groups such as oxetane groups and epoxy groups; groups containing unsaturated double bonds such as vinyl groups, trifluorovinyl groups, styryl groups, acrylic groups, methacryloyl groups, and cinnamoyl groups. A group derived from a benzocyclobutene ring;
The crosslinkable compound may be any of a monomer, an oligomer, and a polymer. The crosslinkable compound may have only 1 type, and may have 2 or more types by arbitrary combinations and ratios.

  As the crosslinkable compound, a hole transporting compound having a crosslinkable group is preferably used. Examples of hole transporting compounds include nitrogen-containing aromatic compound derivatives such as pyridine derivatives, pyrazine derivatives, pyrimidine derivatives, triazine derivatives, quinoline derivatives, phenanthroline derivatives, carbazole derivatives, phthalocyanine derivatives, porphyrin derivatives; triphenylamine derivatives Silole derivatives; oligothiophene derivatives, condensed polycyclic aromatic derivatives, metal complexes and the like. Among them, nitrogen-containing aromatic derivatives such as pyridine derivatives, pyrazine derivatives, pyrimidine derivatives, triazine derivatives, quinoline derivatives, phenanthroline derivatives, carbazole derivatives; triphenylamine derivatives, silole derivatives, condensed polycyclic aromatic derivatives, metal complexes, etc. Particularly preferred are triphenylamine derivatives.

In order to form a hole transport layer by crosslinking a crosslinkable compound, a composition for forming a hole transport layer in which a crosslinkable compound is dissolved or dispersed in a solvent is usually prepared and applied by wet film formation to crosslink. Let
The composition for forming a hole transport layer may contain an additive for promoting a crosslinking reaction in addition to the crosslinking compound. Examples of additives that promote the crosslinking reaction include polymerization initiators and polymerization accelerators such as alkylphenone compounds, acylphosphine oxide compounds, metallocene compounds, oxime ester compounds, azo compounds, onium salts; condensed polycyclic hydrocarbons, And photosensitizers such as porphyrin compounds and diaryl ketone compounds.

Further, it may contain a coating property improving agent such as a leveling agent and an antifoaming agent; an electron accepting compound; a binder resin;
In the composition for forming a hole transport layer, the crosslinkable compound is usually 0.01% by weight or more, preferably 0.05% by weight or more, more preferably 0.1% by weight or more, usually 50% by weight or less, preferably 20%. It is contained in an amount of not more than wt%, more preferably not more than 10 wt%.

After forming a composition for forming a hole transport layer containing a crosslinkable compound at such a concentration on a lower layer (usually a hole injection layer), the crosslinkable compound is formed by heating and / or irradiation with active energy such as light. It is crosslinked to form a network polymer compound.
Conditions such as temperature and humidity during coating, and heating conditions after coating are described in <7. Organic electroluminescence device> Same as the method described in [Film formation method]. Moreover, a preferable aspect is also the same.

The thickness of the hole transport layer is usually 5 nm or more, preferably 10 nm or more, and usually 1000 nm or less, preferably 500 nm or less.
[5] Light emitting layer
The light emitting layer is formed on the hole transport layer when there is a hole transport layer, and on the hole injection layer when there is no hole transport layer without the hole transport layer. When there is no hole injection layer, it is formed on the anode.

The light emitting layer may be a layer independent of the hole injection layer, the hole transport layer, and the hole blocking layer, the electron transport layer, etc., which will be described later, but does not form an independent light emitting layer. Other organic layers such as a transport layer and an electron transport layer may serve as the light emitting layer.
The light-emitting layer is formed by directly injecting holes from an anode or through a hole injection layer or a hole transport layer between electrodes to which an electric field is applied, and directly from a cathode, or a cathode buffer layer or an electron transport layer. It is a layer that is excited by recombination with electrons injected through a hole blocking layer or the like and becomes a main light emitting source.

The light emitting layer can be formed by any method as long as the effects of the present invention are not significantly impaired. For example, the light emitting layer is formed on the anode by a wet film forming method or a vacuum deposition method. However, in the case of manufacturing a light emitting element having a large area, the wet film forming method is preferable. The wet film formation method and the vacuum deposition method can be performed using the same method as the hole injection layer.
The light emitting layer contains at least a material having a light emitting property (light emitting material), and preferably a material having a hole transporting property (hole transporting material) or a material having an electron transporting property (electron). Transport material). Furthermore, the light emitting layer may contain other components without departing from the spirit of the present invention. As these materials, it is preferable to use low molecular weight materials from the viewpoint of forming a light emitting layer by a wet film forming method as described later.

Any known material can be applied as the light emitting material. For example, a fluorescent material or a phosphorescent material may be used, but a phosphorescent material is preferable from the viewpoint of internal quantum efficiency.
In order to improve the solubility in a solvent, it is also important to reduce the symmetry and rigidity of the molecules of the luminescent material, or to introduce a lipophilic substituent such as an alkyl group.
Hereinafter, although the example of a fluorescent dye is mentioned among light emitting materials, a fluorescent dye is not limited to the following illustrations.

Examples of the fluorescent light-emitting material (blue fluorescent dye) that emits blue light include naphthalene, chrysene, perylene, pyrene, anthracene, coumarin, p-bis (2-phenylethenyl) benzene, and derivatives thereof.
Examples of fluorescent dyes that give green light emission (green fluorescent dyes) include quinacridone derivatives, coumarin derivatives, and aluminum complexes such as Al (C ₉ H ₆ NO) ₃ .

Examples of the fluorescent light emitting material (yellow fluorescent dye) that gives yellow light include rubrene, perimidone derivatives, and the like.
Examples of the fluorescent light-emitting material (red fluorescent dye) that emits red light include, for example, DCM (4- (dicyanomethylene) -2-methyl-6- (p-dimethylaminostyryl) -4H-pyran) -based compounds, benzopyran derivatives, rhodamine derivatives, Examples thereof include benzothioxanthene derivatives and azabenzothioxanthene.

  Specific examples of the phosphorescent material include tris (2-phenylpyridine) iridium, tris (2-phenylpyridine) ruthenium, tris (2-phenylpyridine) palladium, bis (2-phenylpyridine) platinum, tris (2- Phenylpyridine) osmium, tris (2-phenylpyridine) rhenium, octaethyl platinum porphyrin, octaphenyl platinum porphyrin, octaethyl palladium porphyrin, octaphenyl palladium porphyrin, and the like.

Polymeric light-emitting materials include poly (9,9-dioctylfluorene-2,7-diyl), poly [(9,9-dioctylfluorene-2,7-diyl) -co- (4,4′- (N
-(4-sec-butylphenyl)) diphenylamine)], poly [(9,9-dioctylfluorene-2,7-diyl) -co- (1,4-benzo-2 {2,1'-3}- And polyfluorene-based materials such as poly [2-methoxy-5- (2-hexylhexyloxy) -1,4-phenylenevinylene].

The polymer of the present invention can also be used as a light emitting material.
The molecular weight of the compound used as the light emitting material is arbitrary as long as the effect of the present invention is not significantly impaired, but is usually 10,000 or less, preferably 5000 or less, more preferably 4000 or less, still more preferably 3000 or less, and usually 100 or more, Preferably it is 200 or more, More preferably, it is 300 or more, More preferably, it is the range of 400 or more. If the molecular weight of the luminescent material is too small, the heat resistance will be significantly reduced, gas will be generated, the film quality will deteriorate when the film is formed, or the morphology of the organic electroluminescent element will change due to migration, etc. Sometimes come. On the other hand, if the molecular weight of the luminescent material is too large, it tends to be difficult to purify the organic compound, or it may take time to dissolve in the solvent.

In addition, any 1 type may be used for the luminescent material mentioned above, and 2 or more types may be used together by arbitrary combinations and a ratio.
The ratio of the light emitting material in the light emitting layer is arbitrary as long as the effect of the present invention is not significantly impaired, but is preferably 0.05% by weight or more, and preferably 35% by weight or less. If the amount of the light emitting material is too small, uneven light emission may occur. If the amount is too large, the current efficiency may decrease. In addition, when using together 2 or more types of luminescent material, it is made for the total content of these to be contained in the said range.

Examples of the low molecular weight hole transport material include various compounds exemplified as the hole transport material of the above-described hole transport layer, and 4,4′-bis [N- (1-naphthyl) -N—. Aromatic diamines, including two or more tertiary amines, represented by phenylamino] biphenyl, wherein two or more condensed aromatic rings are substituted with nitrogen atoms (Japanese Patent Laid-Open No. 5-234681), 4, 4 ′, Aromatic amine compounds having a starburst structure such as 4 "-tris (1-naphthylphenylamino) triphenylamine (Journal of Luminescence, 1997, Vol.72-74, pp.985), tetramer of triphenylamine Aromatic amine compounds (Chemical Communications, 1996, pp.2175), spiro compounds such as 2,2 ′, 7,7′-tetrakis- (diphenylamino) -9,9′-spirobifluorene (Synthetic Metals, 1997, Vol.91, pp.209 )
Etc.

  Examples of low molecular weight electron transport materials include 2,5-bis (1-naphthyl) -1,3,4-oxadiazole (BND) and 2,5-bis (6 ′-(2 ′, 2 "-bipyridyl))-1,1-dimethyl-3,4-diphenylsilole (PyPySPyPy), bathophenanthroline (BPhen), 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP) , Bathocuproine), 2- (4-biphenylyl) -5- (p-tertiarybutylphenyl) -1,3,4-oxadiazole (tBu-PBD) and 4,4′-bis (9-carbazole) -Biphenyl (CBP), 9,10-di- (2-naphthyl) anthracene (ADN) and the like.

These hole transport materials and electron transport materials are preferably used as host materials in the light emitting layer. Specific examples of the host material include those described in JP-A-2007-067383, JP-A-2007-88433, and JP-A-2007-110093, and preferred examples thereof are also the same.
Examples of the method for forming the light emitting layer include a wet film forming method and a vacuum deposition method. As described above, a homogeneous and defect-free thin film can be easily obtained, and the time required for the formation can be shortened. Furthermore, a wet film-forming method is preferable because the effect of crosslinking the hole transport layer by the organic compound of the present invention can be enjoyed. When forming a light-emitting layer by a wet film formation method, prepare the coating solution by dissolving the above materials in an appropriate solvent, apply it to the hole transport layer after the above-mentioned formation, coat it, and dry it. Then, it is formed by removing the solvent. The formation method is the same as the formation method of the hole transport layer.

The thickness of the light emitting layer is usually 3 nm or more, preferably 5 nm or more, and usually 300 nm or less, preferably 100 nm or less.
[6] Hole blocking layer
A hole blocking layer 6 may be provided between the light emitting layer 5 and an electron injection layer 8 described later. The hole blocking layer 6 is a layer laminated on the light emitting layer 5 so as to be in contact with the interface of the light emitting layer 5 on the cathode 9 side.

The hole blocking layer 6 has a role of blocking holes moving from the anode 2 from reaching the cathode 9 and a role of efficiently transporting electrons injected from the cathode 9 toward the light emitting layer 5. Have
The physical properties required for the material constituting the hole blocking layer 6 include high electron mobility, low hole mobility, a large energy gap (difference between HOMO and LUMO), and excited triplet level (T1). Is high. Examples of the material for the hole blocking layer satisfying such conditions include bis (2-methyl-8-quinolinolato) (phenolato) aluminum, bis (2-methyl-8-quinolinolato) (triphenylsilanolato) aluminum, and the like. Mixed metal complexes such as bis (2-methyl-8-quinolato) aluminum-μ-oxo-bis- (2-methyl-8-quinolinato) aluminum binuclear metal complexes, distyrylbiphenyl derivatives, etc. Triazole derivatives such as styryl compounds (JP-A-11-242996), 3- (4-biphenylyl) -4-phenyl-5 (4-tert-butylphenyl) -1,2,4-triazole (JP-A-7 -41759), phenanthroline derivatives such as bathocuproine (JP-A-10-79297), and the like. That. Further, a compound having at least one pyridine ring substituted at the 2,4,6-position described in International Publication No. 2005-022962 is also preferable as the material for the hole blocking layer 6.

In addition, the material of the hole-blocking layer 6 may use only 1 type, and may use 2 or more types together by arbitrary combinations and a ratio.
There is no restriction | limiting in the formation method of the hole-blocking layer 6. FIG. Therefore, it can be formed by a wet film forming method, a vapor deposition method, or other methods.
The thickness of the hole blocking layer 6 is arbitrary as long as the effect of the present invention is not significantly impaired, but is usually 0.3 nm or more, preferably 0.5 nm or more, and usually 100 nm or less, preferably 50 nm or less.

[7] Electron transport layer
The electron transport layer is provided between the light emitting layer and the electron injection layer for the purpose of further improving the current efficiency of the device.
The electron transport layer is formed of a compound capable of efficiently transporting electrons injected from the cathode between the electrodes to which an electric field is applied in the direction of the light emitting layer. The electron transporting compound used in the electron transporting layer is a compound that has high electron injection efficiency from the cathode or the electron injection layer and has high electron mobility and can efficiently transport injected electrons. It is necessary.

  Materials satisfying such conditions include metal complexes such as aluminum complexes of 8-hydroxyquinoline (Japanese Patent Laid-Open No. 59-194393), metal complexes of 10-hydroxybenzo [h] quinoline, oxadiazole derivatives, Styryl biphenyl derivative, silole derivative, 3- or 5-hydroxyflavone metal complex, benzoxazole metal complex, benzothiazole metal complex, trisbenzimidazolylbenzene (US Pat. No. 5,645,948), quinoxaline compound 6-207169), phenanthroline derivative (Japanese Patent Laid-Open No. 5-33159), 2-t-butyl-9,10-N, N′-dicyanoanthraquinonediimine, n-type hydrogenated amorphous silicon carbide, n Type zinc sulfide, n-type zinc selenide and the like.

The lower limit of the thickness of the electron transport layer is usually 1 nm, preferably about 5 nm, and the upper limit is usually 300 nm, preferably about 100 nm.
The electron transport layer is formed by laminating on the hole blocking layer by a wet film formation method or a vacuum deposition method in the same manner as described above. Usually, a vacuum deposition method is used.
[8] Electron injection layer
The electron injection layer plays a role of efficiently injecting electrons injected from the cathode into the electron transport layer or the light emitting layer.

In order to perform electron injection efficiently, the material for forming the electron injection layer is preferably a metal having a low work function. Examples include alkali metals such as sodium and cesium, and alkaline earth metals such as barium and calcium. The film thickness is usually preferably from 0.1 nm to 5 nm.
Further, organic electron transport materials represented by metal complexes such as nitrogen-containing heterocyclic compounds such as bathophenanthroline and aluminum complexes of 8-hydroxyquinoline described later are doped with alkali metals such as sodium, potassium, cesium, lithium and rubidium. (Described in JP-A-10-270171, JP-A 2002-1000047, JP-A 2002-1000048, and the like) makes it possible to improve electron injection / transport properties and achieve excellent film quality. Therefore, it is preferable. The film thickness in this case is usually in the range of 5 nm or more, preferably 10 nm or more, and usually 200 nm or less, preferably 100 nm or less.

The electron injection layer is formed by laminating on the light emitting layer or the hole blocking layer thereon by a wet film formation method or a vacuum deposition method.
Details of the wet film forming method are the same as those of the hole injection layer and the light emitting layer.
On the other hand, in the case of the vacuum deposition method, a deposition source is put into a crucible or a metal boat installed in a vacuum vessel, and the inside of the vacuum vessel is evacuated to about 10 ⁻⁴ Pa with an appropriate vacuum pump, and then the crucible or metal The boat is heated and evaporated to form an electron injection layer on the light emitting layer, hole blocking layer or electron transport layer on the substrate placed facing the crucible or metal boat.

The alkali metal as the electron injection layer is deposited by using an alkali metal dispenser in which nichrome is filled with an alkali metal chromate and a reducing agent. By heating the dispenser in a vacuum container, the alkali metal chromate is reduced and the alkali metal is evaporated. In the case of co-evaporating the organic electron transport material and the alkali metal, the organic electron transport material is put in a crucible installed in a vacuum vessel, and the inside of the vacuum vessel is evacuated to about 10 ⁻⁴ Pa with a suitable vacuum pump. Each crucible and dispenser are simultaneously heated and evaporated to form an electron injection layer on the substrate placed facing the crucible and dispenser.

At this time, co-evaporation is uniformly performed in the film thickness direction of the electron injection layer, but there may be a concentration distribution in the film thickness direction.
[9] Cathode
The cathode plays a role of injecting electrons into a layer on the light emitting layer side (such as an electron injection layer or a light emitting layer). As the material of the cathode, it is possible to use the material used for the anode, but in order to efficiently inject electrons, a metal having a low work function is preferable, and tin, magnesium, indium, calcium, aluminum, A suitable metal such as silver or an alloy thereof is used. Specific examples include low work function alloy electrodes such as magnesium-silver alloy, magnesium-indium alloy, and aluminum-lithium alloy.

The thickness of the cathode is usually the same as that of the anode.
For the purpose of protecting the cathode made of a low work function metal, it is preferable to further stack a metal layer having a high work function and stable to the atmosphere because the stability of the device is increased. For this purpose, metals such as aluminum, silver, copper, nickel, chromium, gold, platinum are used.
[10] Other
The organic electroluminescent element having the layer configuration shown in FIG. 1 has been described above as an example. However, the organic electroluminescent element of the present invention may have another configuration without departing from the gist thereof. For example, as long as the performance is not impaired, an arbitrary layer may be provided between the anode and the cathode in addition to the layers described above, and an arbitrary layer may be omitted.

In the present invention, by using the polymer of the present invention for the hole transport layer, all of the hole injection layer, the hole transport layer, and the light emitting layer can be laminated by a wet film formation method. This makes it possible to manufacture a large area display.
In addition, the structure opposite to that shown in FIG. 1, that is, a cathode, an electron injection layer, a light emitting layer, a hole injection layer, and an anode can be laminated in this order on a substrate, and at least one of them is transparent as described above. It is also possible to provide the organic electroluminescence device of the present invention between two high-height substrates.

Further, a structure in which a plurality of layers shown in FIG. 1 are stacked (a structure in which a plurality of light emitting units are stacked) may be employed. In that case, for example, V ₂ O ₅ or the like is used as the charge generation layer (CGL) instead of the interfacial layer (between the light emitting units) (two layers when the anode is ITO and the cathode is Al). This is more preferable from the viewpoint of current efficiency and driving voltage.
The present invention can be applied to any of an organic electroluminescent element having a single element, an element having a structure arranged in an array, and a structure having an anode and a cathode arranged in an XY matrix.

<Organic EL display device>
The organic EL display device of the present invention uses the above-described organic electroluminescent element of the present invention. There is no restriction | limiting in particular about the model and structure of the organic electroluminescent display apparatus of this invention, It can assemble in accordance with a conventional method using the organic electroluminescent element of this invention.
For example, the organic EL display device of the present invention can be obtained by the method described in “Organic EL display” (Ohm, published on Aug. 20, 2004, Shizushi Tokito, Chiba Adachi, Hideyuki Murata). Can be formed.

<Organic EL lighting>
The organic EL illumination of the present invention uses the above-described organic electroluminescent element of the present invention. There is no restriction | limiting in particular about the model and structure of the organic EL illumination of this invention, It can assemble in accordance with a conventional method using the organic electroluminescent element of this invention.

EXAMPLES Next, although an Example demonstrates this invention further more concretely, this invention is not limited to description of a following example, unless the summary is exceeded.
<Synthesis of side chain monomer>
(Synthesis Example 1)

At room temperature, dibenzofuran (10.0 g) was dissolved in acetic acid (70 ml), an aqueous solution (12 ml) of sulfuric acid (1.8 ml), iodine (6.04 g) and potassium iodate (2.54 g) were added. The reaction was carried out at 5 ° C. for 5 hours. Water was added to the reaction solution and filtered. The obtained crystal was washed with methanol and recrystallized (ethyl acetate / methanol) to obtain Compound 1 (9.93 g).
(Synthesis Example 2)

Mg (416 mg, 27.7 mmol) and 15 ml of THF were placed in a flask under a nitrogen stream, and a solution of compound 1 (4.2 g, 23.1 mmol) in THF (21 mL) was added dropwise at room temperature, followed by reaction at 90 ° C. for 5 hours. It was. The solution was cooled to 5 ° C. or lower with an ice bath, a solution of Me ₃ SiCH ₂ N ₃ (2.19 g, 27.7 mmol) in THF (4 ml) was added dropwise, and then the mixture was warmed to room temperature and stirred for 2 hours. Water was added to the reaction mixture, and the mixture was extracted with ethyl acetate. The organic layer was concentrated and purified by column chromatography (developing solution: hexane / ethyl acetate = 4/1). By drying under reduced pressure at 40 ° C., Compound 10 (1.23 g, yield 47.6%) was obtained. The HPLC purity of Compound 2 was 99.5 area%.
(Synthesis Example 3)

Under a nitrogen stream, Compound 3 (7.3 mmol), Compound 4 (7.0 mmol), 42 mL of toluene, and 21 mL of ethanol were placed in a flask and stirred at room temperature. To this, 22 mL of 2M aqueous sodium carbonate solution was added, and nitrogen bubbling was performed at room temperature for 30 minutes. Next, tetrakis (triphenylphosphine) palladium (0.14 mmol) was added, and the mixture was heated to reflux for 4 hours under nitrogen. After allowing to cool, the organic layer was concentrated and purified by column chromatography (developing solution: toluene / ethyl acetate = 4/1). Compound 8 (yield 73.6%) was obtained by drying under reduced pressure at 60 ° C. Ethanol was added thereto, suspended and washed at a bath temperature of 90 ° C. for 10 minutes, and filtered. Compound 5 had an HPLC purity of 99.5 area%.
<Synthesis of main chain monomer>
(Synthesis Example 4)

Under a nitrogen atmosphere, 4,4 ′-(1,3-dimethylbutylidene) diphenol (15 g, 55.48 mmol), triethylamine (22.46 g, 221.92 mmol), and methylene chloride (150 mL) were added, and at 0 ° C. Stir. Trifluoromethanesulfonic anhydride (37.56 g, 133.16 mmol) was added thereto, and the mixture was stirred at room temperature for 6 hours. Water and 1N hydrochloric acid were added to the reaction mixture and extracted with methylene chloride. The organic layer was washed with a mixed solution of water and 1N hydrochloric acid, washed with brine, dried over magnesium sulfate, and concentrated under reduced pressure. The residue was purified by silica gel column chromatography (hexane / methylene chloride = 3/1) to obtain Compound 6 (19.1 g, yield 64%).
(Synthesis Example 5)

Under nitrogen atmosphere, Compound 6 (19.1 g, 35.73 mmol), bispinacolatodiborane (21.78 g, 85.76 mmol), potassium acetate (17.89 g, 182.55 mmol) suspended in dehydrated dimethyl sulfoxide (157 mL) After heating the solution to 60 ° C., dichloro [1,1′-bis (diphenylphosphino) ferrocene] palladium (II) dichloromethane adduct (1.46 g, 1.79 mol) was added and the temperature was raised to 80 ° C. Stir for 4 hours. After allowing to cool to room temperature, water is added to the reaction mixture, the precipitated crystals are collected by filtration, dissolved in methylene chloride, magnesium sulfate and clay are added, stirred, filtered, the filtrate is concentrated, and the residue is subjected to silica gel column chromatography. The product was purified with (hexane / methylene chloride = 1/1) and washed with hexane to obtain Compound 7 (7.9 g, yield 45%).
(Synthesis Example 6)

  Under a nitrogen atmosphere, tetrakis (triphenylphosphine) was added to a solution of compound 7 (13.2 g, 26.92 mmol), 4-bromoiodobenzene (17.67 g, 62.47 mmol), toluene (268 mL), ethanol (134 mL) at room temperature. ) Palladium (0) (1.56 g, 1.35 mmol), 2M aqueous potassium triphosphate solution (67 mL) was added, and the mixture was refluxed for 8 and a half hours. After allowing to cool to room temperature, the reaction mixture was extracted with toluene, the organic layer was washed with water, dried over magnesium sulfate, and concentrated under reduced pressure. The residue was purified by silica gel column chromatography (hexane / methylene chloride = 8/1), concentrated, and then a small amount of hexane was added to precipitate crystals to obtain compound 8 (8.3 g, yield 56%).

<Polymer synthesis>
(Polymer synthesis example 1: target polymer 1)

Compound 9 (1.082 g, 3.0954 mmol), Compound 10 (0.0732 g, 0.3749 mmol), Compound 2 (0.567 g, 3.0954 mmol), Compound 8 (1.8 g, 3.2826 mmol) and tert- Butoxy sodium (2.15 g, 22.
32 mmol) and toluene (20 ml) were charged, the inside of the system was sufficiently purged with nitrogen, and the mixture was heated to 60 ° C. (solution A). Tri-t-butylphosphine (0.107 g, 0.528 mmol) was added to a 5 ml toluene solution of tris (dibenzylideneacetone) dipalladium chloroform complex (0.069 g, 0.066 mmol) and heated to 60 ° C. ( Solution B). Solution B was added to solution A in a nitrogen stream and heated to reflux for 2.0 hours. After confirming the disappearance of compounds 2 and 8-10, compound 8 (1.72 g) was additionally added. The mixture was heated to reflux for 1.5 hours, the reaction solution was allowed to cool, and the reaction solution was dropped into 300 ml of ethanol to crystallize crude polymer 1.

The obtained crude polymer 1 was dissolved in 120 ml of toluene, bromobenzene (0.21 g) and tert-butoxy sodium (2.15 g) were charged, the inside of the system was sufficiently purged with nitrogen, and 6
Warmed to 0 ° C. (Solution C). Tri-t-butylphosphine (0.107 g) was added to a 5 ml toluene solution of tris (dibenzylideneacetone) dipalladium chloroform complex (0.069 g) and heated to 60 ° C. (solution D). In a nitrogen stream, solution D was added to solution C, and heated to reflux for 2 hours. To this reaction solution was added a solution of N, N-diphenylamine (1.1 g) in toluene (5 ml), and the mixture was further heated and refluxed for 4 hours. The reaction solution was allowed to cool and dropped into an ethanol / water (400 ml / 30 ml) solution to obtain an end-capped crude polymer 1.

This end-capped crude polymer 1 was dissolved in toluene, reprecipitated in acetone, and the precipitated polymer was separated by filtration. The obtained polymer was dissolved in toluene, washed with dilute hydrochloric acid, and reprecipitated with ammonia-containing ethanol. The polymer collected by filtration was purified by column chromatography to obtain the target polymer 1 (0.67 g).
Weight average molecular weight (Mw) = 95500
Number average molecular weight (Mn) = 66870
Dispersity (Mw / Mn) = 1.43
(Polymer synthesis example 2: target polymer 2)

Compound 9 (0.7762 g, 2.2207 mmol), Compound 10 (0.0586 g, 0.3001 mmol), Compound 5 (0.7426 g, 2.2207 mmol), Compound 8 (1.3 g, 2.3707 mmol) and tert- Butoxy sodium (1.55 g, 1
6.12 mmol) and toluene (15 ml) were charged, the inside of the system was sufficiently purged with nitrogen, and the mixture was heated to 60 ° C. (solution A). Tri-t-butylphosphine (0.077 g, 0.38 mmol) was added to a 4 ml toluene solution of tris (dibenzylideneacetone) dipalladium chloroform complex (0.05 g, 0.047 mmol) and heated to 60 ° C. ( Solution B). Solution B was added to solution A in a nitrogen stream and heated to reflux for 2.0 hours. After confirming disappearance of compounds 5 and 8-10, compound 8 (1.3 g) was additionally added. The mixture was heated to reflux for 2.0 hours, the reaction solution was allowed to cool, and the reaction solution was dropped into 250 ml of ethanol to crystallize the crude polymer 2.

The obtained crude polymer 2 was dissolved in 100 ml of toluene, bromobenzene (0.15 g) and tert-butoxy sodium (1.55 g) were charged, the inside of the system was sufficiently purged with nitrogen, and 6
Warmed to 0 ° C. (Solution C). Tri-t-butylphosphine (0.077 g) was added to a 5 ml toluene solution of tris (dibenzylideneacetone) dipalladium chloroform complex (0.05 g) and heated to 60 ° C. (solution D). In a nitrogen stream, solution D was added to solution C, and heated to reflux for 2 hours. To this reaction solution, a toluene (5 ml) solution of N, N-diphenylamine (0.8 g) was added, and the mixture was further heated and refluxed for 4 hours. The reaction solution was allowed to cool and added dropwise to an ethanol / water (300 ml / 20 ml) solution to obtain an end-capped crude polymer 2.

This end-capped crude polymer 2 was dissolved in toluene, reprecipitated in acetone, and the precipitated polymer was separated by filtration. The obtained polymer was dissolved in toluene, washed with dilute hydrochloric acid, and reprecipitated with ammonia-containing ethanol. The polymer collected by filtration was purified by column chromatography to obtain the target polymer 2 (1.42 g).
Weight average molecular weight (Mw) = 71000
Number average molecular weight (Mn) = 44100
Dispersity (Mw / Mn) = 1.61
(Reference example: HOMO value of partial structure)
A conjugated molecular structure containing a nitrogen atom in the main chain was used as a partial structure, and the ground state optimization calculation of the partial structure was performed using the PM3 semiempirical molecular orbital method.
The obtained optimized structure was further subjected to further ground state optimization calculation of the partial structure using 6-31G ** basis function by B3LYP molecular orbital method. All molecular optimization calculations were performed with the Gaussian03 program.

The HOMO energy value in the optimized structure finally obtained from the above was calculated.
Table 1 shows the calculation result of HOMO around the nitrogen atom including the side chain in the present invention.
Since the HOMO energy value has a correlation with the ionization potential of the polymer, it is estimated from this result that the ionization energy of the polymer varies greatly depending on the type of the side chain.

1 Substrate
2 Anode
3 Hole injection layer
4 hole transport layer
5 Light emitting layer
6 Hole blocking layer
7 Electron transport layer
8 Electron injection layer
9 Cathode

Claims (9)

It contains a repeating unit represented by the following formula (1), has two or more three condensed rings in the side chain in one molecule, and further contains a group selected from the following crosslinkable group T The polymer characterized by the above-mentioned.

(In the formula (1),
Ar ^{1 to} Ar ³ each independently represents an aromatic hydrocarbon ring group which may have a substituent or an aromatic heterocyclic group which may have a substituent,
Ar ⁴ and Ar ⁵ each independently represent a group containing three or more aromatic condensed rings.
Ar ⁶ and Ar ⁷ each independently represent a direct bond, an aromatic hydrocarbon ring group which may have a substituent or an aromatic heterocyclic group which may have a substituent,
R ¹ and R ² are each independently a hydrogen atom, an alkyl group which may have a substituent, an alkoxy group which may have a substituent, or an aromatic hydrocarbon which may have a substituent. Represents an aromatic heterocyclic group optionally having a ring group or a substituent,
q represents an integer of 1 to 6, and r represents an integer of 0 to 5.
R ¹ and R ² may combine with each other to form a ring. )
<Crosslinkable group T>

(In the above formula, R ^{21 to} R ²³ each independently represents a hydrogen atom or an alkyl group which may have a substituent, and Ar ²¹ represents an aromatic hydrocarbon ring which may have a substituent. An aromatic heterocyclic group which may have a group or a substituent The benzocyclobutene ring may have a substituent, and the substituents may be bonded to each other to form a ring. May be.)   The polymer according to claim 1, wherein the polymer has a weight average molecular weight (Mw) of 20,000 or more and a dispersity (Mw / Mn; Mn represents a number average molecular weight) of 2.4 or less.   The organic electroluminescent element material which consists of a polymer of Claim 1 or 2. The composition for organic electroluminescent elements containing the polymer of Claim 1 or 2 . In an organic electroluminescence device having an anode, a cathode, and an organic layer between the anode and the cathode on a substrate,
An organic electroluminescence device, wherein the organic layer includes a layer formed by a wet film formation method using the composition for an organic electroluminescence device according to claim 4.   The organic electroluminescent device according to claim 5, wherein the layer formed by the wet film forming method is a hole injection layer and / or a hole transport layer. The hole injection layer and the hole transport layer and the light emitting layer,
The organic electroluminescent element according to claim 6, wherein all of the hole injection layer, the hole transport layer, and the light emitting layer are formed by a wet film forming method.   The organic electroluminescence display which has an organic electroluminescent element as described in any one of Claims 5-7.   Organic EL illumination which has the organic electroluminescent element as described in any one of Claims 5-7.

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