JP5721287B2 - Health supplement containing reduced hydrogen water and redox salt and weathered fossil - Google Patents

Health supplement containing reduced hydrogen water and redox salt and weathered fossil Download PDF

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JP5721287B2
JP5721287B2 JP2013232279A JP2013232279A JP5721287B2 JP 5721287 B2 JP5721287 B2 JP 5721287B2 JP 2013232279 A JP2013232279 A JP 2013232279A JP 2013232279 A JP2013232279 A JP 2013232279A JP 5721287 B2 JP5721287 B2 JP 5721287B2
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敏章 大久保
敏章 大久保
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株式会社活亜興
三宅 史朗
三宅 史朗
川端 彰
川端 彰
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本発明は、水と反応して水素分子を生成する還元性の強い塩を用いた健康補助食品に関するもので、その還元性の強い塩を水に接触させて生成した還元水素水と、この還元性の強い塩(以下、酸化還元塩と称す)、イオン化傾向の高い風化貝化石カルシウムを配合することで、体内で発生して細胞破壊、老化や疾病の元凶となる活性酸素(フリーラジカル)を効果的に捕促し、老化や疾病を防ぐことができる健康補助食品に関する。   The present invention relates to a health supplement using a highly reducible salt that reacts with water to generate hydrogen molecules, the reduced hydrogen water produced by contacting the highly reducible salt with water, and this reduction By combining strong salt (hereinafter referred to as redox salt) and weathered shell fossil calcium, which has a high ionization tendency, active oxygen (free radicals) that are generated in the body and cause cell destruction, aging and disease The present invention relates to a health supplement that can effectively capture and prevent aging and diseases.

近年、健康の決め手は体内で生成される活性酸素を如何に素早く除去するかに掛かっていると言われている。この活性酸素は、ガンを始めとして細胞の変異、病気老化の原因の90%に関わっていると言われ、その正体は酸素が全身の細胞に運ばれる過程で変化する物質で酸化力の強い悪玉活性酸素「ヒドロキシルラジカル」である。この悪玉活性酸素「ヒドロキシラジカル」が、細胞や遺伝子DNAにダメージを与え、ガンや病気を引き起こす原因となる。   In recent years, it is said that the decisive factor of health depends on how quickly active oxygen generated in the body is removed. This active oxygen is said to be involved in 90% of the causes of cell mutation and disease aging, including cancer, and its true identity is a substance that changes in the process of oxygen being transported to cells throughout the body. Active oxygen “hydroxyl radical”. This bad active oxygen “hydroxy radical” causes damage to cells and gene DNA, and causes cancer and illness.

そこで、水又は電解質を含む水を電気分解して得られる陰極水の電解還元水の利用(例えば、特許文献1など参照)、又は水と水素を混合後に加圧して水素を水に溶解させた溶液の利用(例えば、特許文献2など参照)により、その悪玉活性酸素「ヒドロキシルラジカル」の除去が提案されている。
しかしながら、電気分解に伴う陽極水の処理問題や、水素の揮発しやすさの点から生じる水素濃度の経時的な減少問題などが生じている。
Therefore, use of electrolyzed water of cathodic water obtained by electrolyzing water or water containing an electrolyte (see, for example, Patent Document 1), or water and hydrogen are mixed and then pressurized to dissolve hydrogen in water. Removal of the bad active oxygen “hydroxyl radical” has been proposed by using a solution (see, for example, Patent Document 2).
However, there are problems with the treatment of anodic water associated with electrolysis and the problem of a decrease in hydrogen concentration over time, which is caused by the ease of volatilization of hydrogen.

さらに、現代人の体調の不調は、「生体内の還元力不足」と「磁気の乱れ」に起因すると考えられている。なぜなら人体は生きた磁気体で、磁気とは「気」のことであり、「気」の医学とも言われ、不調はその「気」が低下した状態が表面に現れているものと考えられる。
そこで、その「磁気の乱れ」、即ち磁気異常の調整は、体内においてアルカリ性のミネラル物質であるカルシウム(Ca)、マグネシウム(Mg)、カリウム(K)、ナトリウム(Na)の4種類のミネラル成分を必要量、効率的に摂取することが最も効果的である。
Furthermore, the physical condition of modern people is thought to be caused by “insufficient reducing power in the living body” and “magnetic disturbance”. This is because the human body is a living magnetic body, and magnetism is “ki”, which is also called “ki” medicine, and it is thought that the state where the “ki” is lowered appears on the surface.
Therefore, the adjustment of the “magnetic disturbance”, that is, the magnetic anomaly, includes four mineral components of calcium (Ca), magnesium (Mg), potassium (K), and sodium (Na), which are alkaline mineral substances in the body. It is most effective to take the required amount efficiently.

特にカルシウム(Ca)は厚労省の発表では、その1日に必要とするカルシウム量は600mgであるが、日本人が摂取している量はその70%以下の400mg程度であると発表している。また、その吸収率は成人で30〜40%、老人では吸収率が20%以下に低下している。
従ってカルシウム不足が考えられ、その不足分を補うためのカルシウム摂取には、一般に市販されているカルシウム剤によって行われている。
In particular, the Ministry of Health, Labor and Welfare announced that calcium (Ca) requires 600 mg of calcium per day, but the amount consumed by Japanese is about 70 mg or less, about 400 mg. Yes. Moreover, the absorptance has fallen to 30-40% for adults, and the absorptivity has decreased to 20% or less for elderly people.
Therefore, calcium deficiency is considered, and calcium intake to compensate for the deficiency is generally performed by commercially available calcium preparations.

このカルシウム剤は、産業廃棄物と呼んでも良い貝殻、卵の殻、鷄などの骨を、1000℃という高温で焼成、粉末化した後に、吸収しやすくするために水槽に粉末を入れた状態で電荷をかけてイオン化したもので、小腸で吸収され血液に入れると即座に血液のカルシウム濃度を急上昇させ、その後は急激に血中のカルシウム濃度は急降下し、体内のカルシウムバランスを壊してしまう。   This calcium preparation is made in a state where powder such as shells, eggshells, shells, etc., which may be called industrial waste, is baked and powdered at a high temperature of 1000 ° C and then put into a water tank to make it easy to absorb. It is ionized by applying electric charge, and when it is absorbed in the small intestine and enters the blood, it immediately increases the calcium concentration in the blood, and then the calcium concentration in the blood suddenly drops, destroying the calcium balance in the body.

さらに、このカルシウム剤のカルシウムは体内に入る前にすでにイオン化されているのでプラスの電荷を持ち、電気的にかなり活性化した状態で体内に入るために、既にストレス等でマイナスに傾いている血管、神経細胞、じん帯に沈着し、血栓や動脈硬化、高血圧を生起し、さらに神経細胞に沈着することで神経傷害をも起こしてしまう。
他方、血液中のカルシウム濃度が高くなるほど腎臓は、血中のカルシウムを減らそうとして急激な排泄を始め、逆にカルシウム不足が起きてカルシウムダウン症状を引き起こす恐れを有している。
Furthermore, since the calcium of this calcium agent is already ionized before entering the body, it has a positive charge, and since it enters the body in an electrically activated state, it is already a negative blood vessel due to stress etc. It deposits on nerve cells and ligaments, causes thrombosis, arteriosclerosis and hypertension, and also causes nerve damage by depositing on nerve cells.
On the other hand, as the calcium concentration in the blood increases, the kidney begins to excrete rapidly in an attempt to reduce calcium in the blood, and conversely, there is a risk that calcium deficiency may occur and cause calcium down symptoms.

特開平9−77672号公報JP-A-9-77672 特開2010−063629号公報JP 2010-063629 A

このような状況に鑑み本発明は、酸化還元塩が有する電子による還元性を有効に利用した還元水素水、及び、その酸化還元塩と、体内でイオン化して吸収され易いカルシウムである風化貝化石を原料とするカルシウムを配合し、骨格形成や血管内壁へのカルシウム沈着の防止などの効果を有する健康補助食品を提供する。   In view of such circumstances, the present invention provides reduced hydrogen water that effectively uses the reducing properties of electrons of redox salts, and weathered shell fossils that are redox salts and calcium that is easily ionized and absorbed in the body. A dietary supplement containing health supplements having effects such as skeleton formation and prevention of calcium deposition on the inner wall of blood vessels is provided.

本発明の第の発明は、酸化還元電位が−200〜−500mVを示す海水生成塩、酸化還元電位が−200〜−500mVを示すヒマラヤ岩塩の少なくとも一つの酸化還元塩と風化貝化石の混合物が水と接触、酸化還元反応して生成する水素が、前記水に溶存して形成された還元水素水であって、その風化貝化石が、貝類化石に含まれるCa成分のイオン化しない温度で貝類化石を粉末加工して形成した風化カルシウムであることを特徴とする酸化還元塩と風化貝化石の混合物を含む還元水素水。 The first aspect of the present invention, sea water produces salt redox potential indicates -200 to-500 mV, a mixture of at least one redox salts with weathering fossil shells Himalayan rock salt redox potential indicates -200 to-500 mV Is formed by dissolving hydrogen in the water, and the weathered shell fossils are shellfish at a temperature at which the Ca component contained in the shell fossils does not ionize Reduced hydrogen water containing a mixture of a redox salt and a weathered shell fossil that is weathered calcium formed by processing fossil powder.

本発明の第の発明は酸化還元電位が−200〜−500mVを示す海水生成塩、酸化還元電位が−200〜−500mVを示すヒマラヤ岩塩の少なくとも一つの酸化還元塩と、風化貝化石を配合していることを特徴とする健康補助食品であって、その風化貝化石が、貝類化石に含まれるCa成分がイオン化しない温度で、貝類化石を粉末加工して形成した風化カルシウムであることを特徴とする健康補助食品である。 The second invention of the present invention comprises seawater-generating salt having a redox potential of -200 to -500 mV , at least one redox salt of Himalayan rock salt having a redox potential of -200 to -500 mV, and weathered shell fossils. It is a health supplement characterized by the fact that the weathered shell fossils are weathered calcium formed by powder processing shellfish fossils at a temperature at which the Ca component contained in the shellfish fossils does not ionize It is a health supplement.

本発明の第の発明は、第1の発明における酸化還元塩が、少なくともカルシウム(Ca)、ナトリウム(Na)、マグネシウム(Mg)、カリウム(K)、リン(P)、鉄(Fe)、銅(Cu)、亜鉛(Zn)、マンガン(Mn)、フッ素(F)、ケイ素(Si)、セレン(Se)、コバルト(Co)、ニッケル(Ni)、バリウム(Ba)、硫黄(S)、及び塩素(Cl)を含むことを特徴とする還元水素水である。 According to a third aspect of the present invention, the redox salt in the first aspect is at least calcium (Ca), sodium (Na), magnesium (Mg), potassium (K), phosphorus (P), iron (Fe), Copper (Cu), zinc (Zn), manganese (Mn), fluorine (F), silicon (Si), selenium (Se), cobalt (Co), nickel (Ni), barium (Ba), sulfur (S), And reduced hydrogen water characterized by containing chlorine (Cl).

本発明の第の発明は、第の発明における酸化還元塩が、少なくともカルシウム(Ca)、ナトリウム(Na)、マグネシウム(Mg)、カリウム(K)、リン(P)、鉄(Fe)、銅(Cu)、亜鉛(Zn)、マンガン(Mn)、フッ素(F)、ケイ素(Si)、セレン(Se)、コバルト(Co)、ニッケル(Ni)、バリウム(Ba)、硫黄(S)、及び塩素(Cl)を含むことを特徴とする健康補助食品である。 According to a fourth aspect of the present invention, the redox salt in the second aspect is at least calcium (Ca), sodium (Na), magnesium (Mg), potassium (K), phosphorus (P), iron (Fe), Copper (Cu), zinc (Zn), manganese (Mn), fluorine (F), silicon (Si), selenium (Se), cobalt (Co), nickel (Ni), barium (Ba), sulfur (S), And a dietary supplement characterized by containing chlorine (Cl).

本発明に係る酸化還元塩を用いて生成した還元水素水は、溶存水素量の経時変化が小さく、従来の電解水素水に比して長時間にわたり水素を溶存させ、水素による還元作用を維持することが可能であった。さらに、イオン化していないカルシウム(Ca)、例えば風化貝化石を含む還元水素水は、さらに長時間にわたり水素を溶存させ、その効果を持続していた。   Reduced hydrogen water produced using the redox salt according to the present invention has a small amount of change in dissolved hydrogen over time, dissolves hydrogen over a longer period of time than conventional electrolytic hydrogen water, and maintains the reduction action by hydrogen. It was possible. Furthermore, non-ionized calcium (Ca), for example, reduced hydrogen water containing weathered fossil fossil, dissolved hydrogen for a longer time and maintained its effect.

酸化還元塩とイオン化していないカルシウム(Ca成分:例えば、風化貝化石)を配合した本発明に係る健康補助食品は、市販のカルシウム剤と比較して、摂取開始時から12時間後も血中カルシウム値の変動が抑制された安定的な挙動を示し、体内のカルシウムバランスを崩すことなく、容易にカルシウム(Ca)摂取を可能とした。   The health supplement according to the present invention containing a redox salt and non-ionized calcium (Ca component: for example, weathered shell fossil) is in the blood 12 hours after the start of ingestion, as compared with a commercially available calcium preparation. It showed a stable behavior in which fluctuations in calcium level were suppressed, and calcium (Ca) intake could be easily performed without losing the calcium balance in the body.

[酸化還元塩]
本発明で用いる酸化還元塩は、海水から作られた自然塩を800℃以上の高温による長時間加熱して形成した海水酸化還元塩、又は堆積していた岩塩がヒマラヤ山脈が隆起した際、マグマ溶岩の高温、高熱で焼かれることにより、塩に含まれている有機化合物や微生物また有害物質は消去され無機化し、更にニガリ成分の「塩化マグネシウム」、「硫酸マグネシウム」は焼却され、酸素や窒素は気化し、焼かれたことで電子を持った酸化還元塩を生成して、その酸化還元塩が有する電子のやり取りによって酸化を防止し還元する働きを有するものである。
[Redox salt]
The redox salt used in the present invention is a hydrated sea salt formed by heating natural salt made from seawater at a high temperature of 800 ° C or higher for a long time, or when the deposited rock salt rises in the Himalayas. By burning the lava at high temperature and high temperature, organic compounds, microorganisms and harmful substances contained in the salt are eliminated and mineralized, and the negative components “magnesium chloride” and “magnesium sulfate” are incinerated to produce oxygen and nitrogen. Has a function of generating a redox salt having electrons by being vaporized and burned, and preventing and reducing oxidation by exchanging electrons of the redox salt.

本発明で用いる酸化還元塩の具体例は、天然産の紅塩(ヒマラヤ産天然岩塩、チベット産天然岩塩)である。
紅塩は、ヒマラヤ山脈が海底から隆起するとき、高温のマグマで焼けながら数億年かけて生成されたものであるとされている。
Specific examples of the redox salt used in the present invention are natural red salt (natural rock salt from Himalaya, natural rock salt from Tibet).
Red salt is said to have been produced over hundreds of millions of years while burning in hot magma when the Himalayas rise from the seabed.

即ち、紅塩は、マグマの高温(1100℃〜1200℃程度)に長時間曝されることで、天然岩塩中に含まれていた有機化合物、酸素や窒素などの非金属化合物の多くが気化し、無機質の化合物の塩になったものといわれている。また、塩の中に含まれている微量元素、即ち、カルシウム、マグネシウム、ナトリウム、カリウム、鉄、銅、亜鉛、リン、マンガン、硫黄、フッ素、ケイ素、塩素、ストロンチウム、バリウム、コバルトなどミネラル成分は、長い年月、高温・高圧力化に曝されることで、還元作用をもたらす電子を保有したといわれている。   That is, when red salt is exposed to the high temperature of magma (about 1100 ° C to about 1200 ° C) for a long time, many organic compounds, non-metallic compounds such as oxygen and nitrogen contained in natural rock salt are vaporized, It is said to have become a salt of an inorganic compound. Also, trace elements contained in the salt, that is, mineral components such as calcium, magnesium, sodium, potassium, iron, copper, zinc, phosphorus, manganese, sulfur, fluorine, silicon, chlorine, strontium, barium, cobalt, etc. For many years, it is said that it possessed electrons that bring about a reducing action by being exposed to high temperature and high pressure.

また、本発明で用いる海水生成塩は、上記ミネラル成分を含む海水から製塩した塩を数回(例えば5回以上)釜の中で1200〜1300℃の高温で焼く「高温熱焼法」により製造したものである。   In addition, the seawater-generating salt used in the present invention is produced by a “high temperature thermal baking method” in which a salt made from seawater containing the above mineral components is baked several times (for example, 5 times or more) at a high temperature of 1200 to 1300 ° C. in a kettle. It is a thing.

上記酸化還元塩である紅塩(ヒマラヤ岩塩)は、酸化還元電位測定器(ORPメーター)で測定すると、マイナス値を示し、具体的に−200〜−500mVの値を示し、強い還元力を保持しているものであることがわかる。
海水生成塩では、−150〜−500mVの値を示している。
Red salt (Himalayan rock salt), which is the redox salt, shows a negative value when measured with a redox potential meter (ORP meter), specifically a value of -200 to -500 mV, and maintains a strong reducing power. It can be seen that
In the seawater-generated salt, a value of −150 to −500 mV is indicated.

ところで、「酸化」とは人の健康状態から言えば、「老化する」、「病気がち」、「疲れる」、「シミ、シワが増えること」である。また「還元」とは人の健康状態から言えば、「元気である」、「健康で若返ること」、「美しさがパワーアップすること」で、つまりこの「還元」の働きを有するのが還元力を持った酸化還元塩である。
さらに、化学的に捉えると、「酸化」とは、ある物質が酸素と化合する反応であり、水素又は電子を奪われる反応でもある。一方、「還元」とは、その逆で酸素が切り離される反応であり、水素又は電子を得る反応である。この「酸化」と「還元」の反応はわずか一個の電子のやり取りをする化学反応であり、この「酸化」と「還元」は同時に起きる反応でもある。
By the way, “oxidation” means “aging”, “prone to illness”, “getting tired”, “increasing spots and wrinkles” in terms of human health. In terms of human health, “reduction” means “healthy”, “healthy and rejuvenating”, and “beauty powers up”. It is a powerful redox salt.
Furthermore, from a chemical viewpoint, “oxidation” is a reaction in which a certain substance combines with oxygen, and is also a reaction in which hydrogen or electrons are deprived. On the other hand, “reduction” is a reaction in which oxygen is cut off in reverse, and is a reaction for obtaining hydrogen or electrons. The reaction of “oxidation” and “reduction” is a chemical reaction in which only one electron is exchanged, and this “oxidation” and “reduction” are reactions that occur simultaneously.

即ち、「還元力」とは電子の働きにより酸化物を還元するもので、その時酸素を切り離し、電子により水素を与える力が働くもので、以下に、その状態を本発明で用いる還元力を有する酸化還元塩で示す。
水道水には滅菌の為に使用した塩素ガスが水に溶け、塩酸(HCl)と次亜塩素酸(HClO)という酸化力の強い塩素化合物に変える。この強い酸化力が雑菌を酸化させて殺菌している。
そこで、この塩素化合物を無害化するには、塩素化合物を切り離し、分解することで、それには本発明の酸化還元塩が有する電子により還元すると、水と塩素イオンに分解され、無害となる。
In other words, “reducing power” means that the oxide is reduced by the action of electrons, and at that time, the ability to cut off oxygen and give hydrogen by the electrons works, and the state has the reducing power used in the present invention below. Indicated by redox salt.
In the tap water, the chlorine gas used for sterilization dissolves in the water and is converted into a highly oxidizing chlorine compound such as hydrochloric acid (HCl) and hypochlorous acid (HClO). This strong oxidizing power oxidizes various bacteria and sterilizes them.
Therefore, in order to detoxify the chlorine compound, the chlorine compound is separated and decomposed, and when it is reduced by the electrons contained in the redox salt of the present invention, it is decomposed into water and chlorine ions and becomes harmless.

その還元力を知るために、3つのビーカー、A、B、Cを準備し、そのビーカーに塩素で滅菌した水道水を約8分目まで入れ、試薬液(0−トリジン溶液)を少量入れると黄色に変色する。これは水道水に塩素化合物が入っていることを示すものである。
次にビーカーAに、本発明で使用する酸化還元塩を約1g〜2g投入すると黄色に変色している色が一瞬にして透明になる。
これが、有害な塩素化合物を無害に還元(分解)する化学反応である。
In order to know the reducing power, prepare three beakers, A, B, and C, put tap water sterilized with chlorine into the beaker for about 8 minutes, and put a small amount of reagent solution (0-Toridine solution). Turns yellow. This indicates that tap water contains chlorine compounds.
Next, when about 1 to 2 g of the redox salt used in the present invention is added to the beaker A, the color that has turned yellow is instantly transparent.
This is a chemical reaction that harmlessly reduces (decomposes) harmful chlorine compounds.

そこで、このビーカーの水(還元水)の酸化還元電位をORP測定器で測定すると、−350mV以下の値を示し、還元していることがわかる。   Then, when the oxidation-reduction potential of the water (reduced water) of this beaker is measured with an ORP measuring device, it shows a value of −350 mV or less, indicating that it is being reduced.

次にビーカーBに、一般に使用されている精製塩を5g入れても黄色のままで同じくORP測定器による測定値は、+650mV以上の値を示す。これは、還元が行われていないことを示している。   Next, even if 5 g of generally used refined salt is added to the beaker B, it remains yellow and the measured value by the ORP measuring instrument shows a value of +650 mV or more. This indicates that reduction has not been performed.

そこで、さらにビーカーCにビーカーBと同様に市販の精製塩を5g入れ、撹拌するが色はビーカーBと同様にそのまま変わらない。その時の酸化還元電位は+650mV以上の値を示していた。
次に、そのビーカーCに酸化還元塩を1g〜2g入れ、撹拌すると一瞬にして透明になる。これは塩素化合物を消去した実証、その時の酸化還元電位は、−350mV以下となり、還元が行われていることを示している。
Therefore, 5 g of commercially available purified salt is added to beaker C in the same manner as beaker B and stirred, but the color remains the same as in beaker B. The redox potential at that time showed a value of +650 mV or more.
Next, 1 to 2 g of redox salt is put into the beaker C, and when it is stirred, it becomes transparent instantly. This demonstrates that the chlorine compound has been erased, and the oxidation-reduction potential at that time is −350 mV or less, indicating that reduction is being performed.

このビーカーCの中での反応の違いは、使用した塩の成分及びその成分の状態の違いによるものと考えられる。即ち、本発明で使用する酸化還元塩では、長い時間、高温に曝されたことにより、酸化還元塩に含まれているミネラル成分が電子を保有し、その電子の働きによるものである。   The difference in reaction in the beaker C is considered to be due to the difference in the components of the salt used and the state of the components. That is, in the redox salt used in the present invention, the mineral component contained in the redox salt retains electrons when exposed to a high temperature for a long time, and is due to the action of the electrons.

この電子を出す物質とは酸化還元塩に含まれているミネラル成分である。
つまり金属元素「鉄、銅、亜鉛、カリウム、カルシウム、ナトリウム、マグネシウム、アルミニウム、マンガン、フッ素、ケイ素、ストロンチウム、ルビジウム等」が電子を出している。
The substance that emits electrons is a mineral component contained in the redox salt.
That is, the metal element “iron, copper, zinc, potassium, calcium, sodium, magnesium, aluminum, manganese, fluorine, silicon, strontium, rubidium, etc.” emits electrons.

[還元水素水]
ところで、元素を構成するのは原子である。
その原子は3つの要素で構成され、中心に陽子と中性子で構成される原子核があり、この原子核の周りを電子が回り電子殻を構成している。
その陽子は、+の電荷を帯び、電子は−の電荷を帯び、中性子は非電荷であり、その原子の中で水素原子は、陽子1個の原子核と電子1個で構成され、電子を放して+1価にもなり、電子を捕えて−1価にもなる両方の振る舞いをもつ特性がある。またイオン化することもでき、電子を簡単にやり取りできる特性を持っている。
即ち、水素は電気化学的特性である電子を供給する還元力を持っている。そこで、本発明で示した酸化還元塩が水と反応して水素を発生し、水素イオン化して水に溶けて還元水素水が生成される。
[Reduced hydrogen water]
By the way, it is atoms that constitute elements.
The atom is composed of three elements, and there is a nucleus composed of protons and neutrons at the center, and electrons turn around this nucleus to form an electron shell.
The proton is positively charged, the electron is negatively charged, the neutron is uncharged, and the hydrogen atom is composed of one proton nucleus and one electron, releasing electrons. Therefore, there is a characteristic that both have a behavior of becoming +1 valent and capturing electrons to be −1 valent. It can also be ionized and has the property of easily exchanging electrons.
That is, hydrogen has a reducing power to supply electrons which are electrochemical characteristics. Therefore, the redox salt shown in the present invention reacts with water to generate hydrogen, which is hydrogen ionized and dissolved in water to produce reduced hydrogen water.

即ち、本発明では、上記特性を持つ水素が溶存した水素水(以後、還元水素水と称す)を、上記酸化還元塩を用いて生成するものである。
一般に供されている水道水は、酸化力があるので酸化還元電位はプラスになる。水素は還元力があるのでマイナスになる。電子のやり取りで電子を失うと酸化され、電子をもらうと還元される。
酸素は電子を奪うもので酸化を行い、水素は電子を与えるので還元を行うものである。したがって、強い還元力を持った上記酸化還元塩が、その還元力により水と反応し、電子のやり取りにより水素を発生することを見出し、その発生した水素がイオン化して水に溶けて還元水素水を作り出すものである。
That is, in the present invention, hydrogen water in which hydrogen having the above characteristics is dissolved (hereinafter referred to as reduced hydrogen water) is generated using the redox salt.
Since tap water generally provided has an oxidizing power, the redox potential is positive. Hydrogen is negative because it has reducing power. When an electron is lost due to exchange of electrons, it is oxidized, and when an electron is received, it is reduced.
Oxygen deprives electrons and oxidizes, while hydrogen gives electrons and performs reduction. Therefore, it has been found that the above redox salt having a strong reducing power reacts with water by its reducing power and generates hydrogen by the exchange of electrons, and the generated hydrogen is ionized and dissolved in water to reduce hydrogenated water. Is to create.

この酸化還元塩を水に投入することで発生する水素が、水に溶存した酸化還元水素水においては、含まれる水素は電子を放して+1価にもなり、電子を捕えて−1価にもなる性質を持ち、イオン化へも働くこともでき、また電気陰性度も示す。
つまり、電子を簡単にやり取りできる能力をもっている還元水素水である点、電子を供給する還元水素水である点、そして還元水素水が抗酸化物質を持っている点から、癌をはじめとして細胞の変異、病気老化の原因の90%に係わる活性酸素、その活性酸素を生み出す元凶である酸素が全身の細胞に運ばれる過程で変化する物質で、且つ酸化力の強い悪玉活性酸素ヒドロキシルラジカル、これが細胞や遺伝子DNAにダメージを与え癌や病気を引き起こす原因となる。
即ち、還元水素水はこの悪玉活性酸素を消去する効果、所謂抗酸化性を有する抗酸化物質である。
In the redox hydrogen water in which the hydrogen generated by introducing this redox salt into water is dissolved in water, the contained hydrogen releases electrons and becomes +1 valent, and captures electrons and becomes −1 valent. It can also act on ionization and has an electronegativity.
In other words, it is a reduced hydrogen water that has the ability to easily exchange electrons, is a reduced hydrogen water that supplies electrons, and the reduced hydrogen water has antioxidants, so Active oxygen related to 90% of the causes of mutation and disease aging, a substance that changes in the process of transporting oxygen, which is the cause of the generation of active oxygen, to cells throughout the body, and is a bad reactive oxygen hydroxyl radical with strong oxidizing power, this is a cell It can cause damage to genetic DNA and cause cancer and illness.
That is, the reduced hydrogen water is an antioxidant substance having an effect of eliminating this bad active oxygen, that is, so-called antioxidant property.

[易吸収Ca健康補助食品]
Ca吸収のデメリットを排除してCaを摂取するには、イオン化していない状態で体内に摂取し、体内で容易にイオン化するような状態でCaを摂取するのが望ましいとの知見を得て、本発明では風化貝化石から作られるカルシウム(Ca)と、電子を持ち水素を発生させる酸化還元塩とを混合して用いることで、上記知見を具現化したものである。
[Easy Absorption Ca Health Supplement]
In order to eliminate the disadvantages of Ca absorption and ingest Ca, it is desirable to ingest it in the body in a non-ionized state, and to ingest Ca in a state that is easily ionized in the body, In the present invention, the above knowledge is embodied by using a mixture of calcium (Ca) made from weathered shell fossil and an oxidation-reduction salt that has electrons and generates hydrogen.

先ず、Ca源となる風化貝化石は、数千年前(例えば2000万年前)のホタテ貝、ニシキ貝などのカキ殻が化石化したもので、その使用に際しては、この風化貝化石をイオン化させない温度(280℃以下)で滅菌処理、粉末加工したものである。
そのCaは、水溶性で、体内においてイオン化するCaである。
即ち、この風化貝化石をCa源とするCaは、イオン化されていない状態で体内に摂取され、腸において吸収、血液に運びこまれた時、イオン化していないので血管やじん帯に沈着する事がなく、骨の隅々まで運ばれることになり、その場所で、酸化還元塩の電子を受け取ることでイオン化し、堆積しているものである。
First, weathered shell fossils that are the source of Ca are fossilized oyster shells such as scallops and sea urchins several thousand years ago (for example, 20 million years ago). Sterilized at a temperature (not higher than 280 ° C.) and processed into powder.
The Ca is water-soluble and ionizes in the body.
That is, Ca, which is derived from this weathered shell fossil, is taken into the body in a non-ionized state, and when absorbed in the intestine and carried into the blood, it is not ionized and can be deposited in blood vessels and ligaments. Instead, it is transported to every corner of the bone, where it is ionized and deposited by receiving redox salt electrons.

以下、実施例を用いて本発明を詳述する。   Hereinafter, the present invention will be described in detail using examples.

(参考例1
水素を測定するポータブル溶存水素計を用い、ビーカーA1、A2に水道水を適量入れて、その水道水の溶存水素量を測定した。両者ともに、ゼロ(0)を示した。
次に、ビーカーA1に酸化還元塩として、塊状のヒマラヤ紅塩を約5〜7gに投入し、溶存水素量を測定した。投入直後に、600ppb(0.6ppm)の値を示し、水素分子H2が水の中に溶存した。
さらに、溶存水素量の経時変化を測定したところ、溶存水素量は若干低下するが24時間後で、518ppbの値を得た。
(Reference Example 1 )
Using a portable dissolved hydrogen meter that measures hydrogen, an appropriate amount of tap water was added to beakers A1 and A2, and the amount of dissolved hydrogen in the tap water was measured. Both showed zero (0).
Next, about 5 to 7 g of massive Himalayan red salt was added to beaker A1 as a redox salt, and the amount of dissolved hydrogen was measured. Immediately after the addition, a value of 600 ppb (0.6 ppm) was shown, and hydrogen molecule H2 was dissolved in water.
Furthermore, when the change over time in the amount of dissolved hydrogen was measured, the amount of dissolved hydrogen slightly decreased, but a value of 518 ppb was obtained after 24 hours.

実施例2
水素を測定するポータブル溶存水素計を用い、ビーカーB1、B2に水道水を適量入れて、その水道水の溶存水素量を測定した。両者ともに、ゼロ(0)を示した。
次に、ビーカーB1に酸化還元塩として、塊状のヒマラヤ紅塩を約4gと、風化貝化石の粉末7gを投入し、溶存水素量を測定した。投入直後に、710ppb(0.71ppm)の値を示し、水素分子H2が水の中に溶存した。
さらに、溶存水素量の経時変化を測定したところ、溶存水素量は若干低下するが24時間後で、638ppbの値を得た。
[ Example 2 ]
Using a portable dissolved hydrogen meter that measures hydrogen, an appropriate amount of tap water was added to beakers B1 and B2, and the amount of dissolved hydrogen in the tap water was measured. Both showed zero (0).
Next, about 4 g of massive Himalayan red salt and 7 g of weathered shell fossil powder were added as redox salts to the beaker B1, and the amount of dissolved hydrogen was measured. Immediately after the addition, a value of 710 ppb (0.71 ppm) was shown, and hydrogen molecule H2 was dissolved in water.
Furthermore, when the change over time in the amount of dissolved hydrogen was measured, the amount of dissolved hydrogen slightly decreased, but a value of 638 ppb was obtained after 24 hours.

(参考例3)
ビーカーC1、C2を用意して、投入する酸化還元塩を800℃の高温に48時間加熱して生成した海水生成塩を用いた以外は、参考例1と同様にして、溶存水素量を測定した。投入直後に、565ppb(0.565ppm)の値を示し、水素分子H2が水の中に溶存した。
さらに、溶存水素量の経時変化を測定したところ、溶存水素量は若干低下するが24時間後で、488ppbの値を得た。
(Reference Example 3)
Beakers C1 and C2 were prepared, and the amount of dissolved hydrogen was measured in the same manner as in Reference Example 1 except that the redox salt to be added was heated to a high temperature of 800 ° C. for 48 hours and the seawater-generating salt was used. . Immediately after the addition, a value of 565 ppb (0.565 ppm) was shown, and hydrogen molecule H2 was dissolved in water.
Furthermore, when the change over time in the amount of dissolved hydrogen was measured, the amount of dissolved hydrogen slightly decreased, but a value of 488 ppb was obtained after 24 hours.

(比較例1)
次に、ビーカーDに市販の精製塩10gを投入し、参考例1同様に溶存水素量を測定したが、溶存水素量は投入直後から検出限度以下で変化しなかった。
(Comparative Example 1)
Next, 10 g of commercially available purified salt was introduced into the beaker D, and the amount of dissolved hydrogen was measured in the same manner as in Reference Example 1. However, the amount of dissolved hydrogen did not change below the detection limit immediately after the addition.

(従来例)
市販の電解水素水整水器を用いて電解水素水を生成して、その溶存水素量を測定した。生成当初は710ppbの値を示し、生成後24時間後では検出限度以下であった。
(Conventional example)
Electrolyzed hydrogen water was produced using a commercially available electrolytic hydrogen water conditioner, and the amount of dissolved hydrogen was measured. Initially, it showed a value of 710 ppb and was below the detection limit 24 hours after the generation.

本発明に係る酸化還元塩を含む還元水素水(参考例1、実施例2)、及び酸化還元塩と風化貝化石を含む還元水素水(参考例3)は、従来の電解水素水に比べて長時間にわたり水素を溶存させていることが判る。 The reduced hydrogen water containing the redox salt according to the present invention ( Reference Example 1, Example 2) and the reduced hydrogen water containing the redox salt and weathered shell fossil ( Reference Example 3) are compared to the conventional electrolytic hydrogen water. It can be seen that hydrogen is dissolved for a long time.

実施例4
酸化還元塩(塊状のヒマラヤ紅塩)を4gと風化貝化石粉末7gを、食後に服用して成人の血中カルシウム値の経時変化を測定した。血中カルシウム値の測定は、富士フイルムメディカル株式会社製ドライケムで行った。
なお、以下の実施例は成人を対象に行った。
その結果を、表1に示す。
[ Example 4 ]
4 g of redox salt (bulky Himalayan red salt) and 7 g of weathered shell fossil powder were taken after meal, and the time course of blood calcium level in adults was measured. The blood calcium level was measured with a dry chem manufactured by Fuji Film Medical Co., Ltd.
In the following examples, adults were used as subjects.
The results are shown in Table 1.

実施例5
酸化還元塩(塊状のヒマラヤ紅塩)を4gと風化貝化石粉末7gを、食事せずに服用して血中カルシウム値の経時変化を実施例4と同様の測定法で測定した。
その結果を表1に示す。
[ Example 5 ]
4 g of redox salt (bulky Himalayan red salt) and 7 g of weathered shell fossil powder were taken without eating, and the time course of blood calcium level was measured by the same measurement method as in Example 4.
The results are shown in Table 1.

(比較例2)
市販のカルシウム剤を食後に20錠服用して血中カルシウム値を経時変化を測定した。
その結果を表1に合わせて示す。
(Comparative Example 2)
Twenty tablets of a commercially available calcium preparation were taken after meals, and the time course of blood calcium level was measured.
The results are also shown in Table 1.

(比較例3)
食事せずに市販のカルシウム剤を20錠服用して血中カルシウム値の経時変化を測定した。
その結果を表1に合わせて示す。
(Comparative Example 3)
Twenty tablets of commercially available calcium preparation were taken without eating, and the time course of blood calcium level was measured.
The results are also shown in Table 1.

Figure 0005721287
Figure 0005721287

比較例2、3の市販のカルシウム剤を服用した場合には、1時間目に急上昇するが、その後は急低下して、しかも12時間後には服用前の数値よりも下回っている事が伺える。これは腎臓が急激に上昇したカルシウムを減らそうとして排泄を始めた現れと考えられる。   When the commercially available calcium preparations of Comparative Examples 2 and 3 are taken, it rises rapidly at the first hour, but then drops sharply, and after 12 hours it can be seen that it is lower than the value before taking. This is thought to be an indication that the kidneys began to excrete in an attempt to reduce the rapidly rising calcium.

この表1からも明らかなように本願実施例4、5においては市販のカルシウム剤(比較例2、3)と比較して、摂取開始時から12時間後も血中カルシウム値の変動を抑制した安定的な挙動を示していることがわかる。   As is clear from Table 1, in Examples 4 and 5 of the present application, compared with the commercially available calcium preparations (Comparative Examples 2 and 3), fluctuations in blood calcium level were suppressed even 12 hours after the start of ingestion. It can be seen that the behavior is stable.

Claims (4)

酸化還元電位が−200〜−500mVを示す海水生成塩、酸化還元電位が−200〜−500mVを示すヒマラヤ岩塩の少なくとも一つの酸化還元塩と風化貝化石の混合物が水と接触、酸化還元反応して生成する水素が、前記水に溶存して形成された還元水素水であって、
前記風化貝化石が、貝類化石に含まれるCa成分のイオン化しない温度で、前記貝類化石を粉末加工して形成した風化カルシウムであることを特徴とする前記酸化還元塩と風化貝化石の混合物を含む還元水素水。
A mixture of at least one oxidation-reduction salt and weathered fossil of a seawater-generating salt having an oxidation-reduction potential of −200 to −500 mV and a Himalayan rock salt having an oxidation-reduction potential of −200 to −500 mV comes into contact with water and undergoes oxidation-reduction reaction The hydrogen produced is reduced hydrogen water formed by dissolving in the water,
The weathered shell fossil is a weathered calcium formed by powder processing of the shellfish fossil at a temperature at which the Ca component contained in the shellfish fossil is not ionized, and includes the mixture of the redox salt and the weathered shell fossil Reduced hydrogen water.
酸化還元電位が−200〜−500mVを示す海水生成塩、酸化還元電位が−200〜−500mVを示すヒマラヤ岩塩の少なくとも一つの酸化還元塩と、風化貝化石を配合していることを特徴とする健康補助食品であって、
前記風化貝化石が、貝類化石に含まれるCa成分がイオン化しない温度で、前記貝類化石を粉末加工して形成した風化カルシウムであることを特徴とする健康補助食品。
A seawater-generating salt having a redox potential of −200 to −500 mV, a Himalayan rock salt having a redox potential of −200 to −500 mV, and a weathered shell fossil are blended. A health supplement,
A health supplement, wherein the weathered shell fossil is weathered calcium formed by powder processing of the shell fossil at a temperature at which a Ca component contained in the shellfish fossil is not ionized.
前記酸化還元塩が、少なくともカルシウム(Ca)、ナトリウム(Na)、マグネシウム(Mg)、カリウム(K)、リン(P)、鉄(Fe)、銅(Cu)、亜鉛(Zn)、マンガン(Mn)、フッ素(F)、ケイ素(Si)、セレン(Se)、コバルト(Co)、ニッケル(Ni)、バリウム(Ba)、硫黄(S)、及び塩素(Cl)を含むことを特徴とする請求項1に記載の還元水素水。 The redox salt is at least calcium (Ca), sodium (Na), magnesium (Mg), potassium (K), phosphorus (P), iron (Fe), copper (Cu), zinc (Zn), manganese (Mn ), Fluorine (F), silicon (Si), selenium (Se), cobalt (Co), nickel (Ni), barium (Ba), sulfur (S), and chlorine (Cl). Item 2. Reduced hydrogen water according to Item 1 . 前記酸化還元塩が、少なくともカルシウム(Ca)、ナトリウム(Na)、マグネシウム(Mg)、カリウム(K)、リン(P)、鉄(Fe)、銅(Cu)、亜鉛(Zn)、マンガン(Mn)、フッ素(F)、ケイ素(Si)、セレン(Se)、コバルト(Co)、ニッケル(Ni)、バリウム(Ba)、硫黄(S)、及び塩素(Cl)を含むことを特徴とする請求項に記載の健康補助食品。 The redox salt is at least calcium (Ca), sodium (Na), magnesium (Mg), potassium (K), phosphorus (P), iron (Fe), copper (Cu), zinc (Zn), manganese (Mn ), Fluorine (F), silicon (Si), selenium (Se), cobalt (Co), nickel (Ni), barium (Ba), sulfur (S), and chlorine (Cl). Item 3. A health supplement according to Item 2 .
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