JP5718107B2 - Mite control agent - Google Patents
Mite control agent Download PDFInfo
- Publication number
- JP5718107B2 JP5718107B2 JP2011053136A JP2011053136A JP5718107B2 JP 5718107 B2 JP5718107 B2 JP 5718107B2 JP 2011053136 A JP2011053136 A JP 2011053136A JP 2011053136 A JP2011053136 A JP 2011053136A JP 5718107 B2 JP5718107 B2 JP 5718107B2
- Authority
- JP
- Japan
- Prior art keywords
- control agent
- mite
- mites
- acarid
- active ingredient
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000642 acaricide Substances 0.000 title description 19
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- 239000004480 active ingredient Substances 0.000 claims description 17
- 241000238876 Acari Species 0.000 claims description 15
- 241000196324 Embryophyta Species 0.000 claims description 13
- IXSZQYVWNJNRAL-UHFFFAOYSA-N etoxazole Chemical compound CCOC1=CC(C(C)(C)C)=CC=C1C1N=C(C=2C(=CC=CC=2F)F)OC1 IXSZQYVWNJNRAL-UHFFFAOYSA-N 0.000 claims description 12
- 230000003071 parasitic effect Effects 0.000 claims description 11
- 239000005897 Etoxazole Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 241000219315 Spinacia Species 0.000 claims description 8
- 235000009337 Spinacia oleracea Nutrition 0.000 claims description 8
- XGWIJUOSCAQSSV-XHDPSFHLSA-N (S,S)-hexythiazox Chemical compound S([C@H]([C@@H]1C)C=2C=CC(Cl)=CC=2)C(=O)N1C(=O)NC1CCCCC1 XGWIJUOSCAQSSV-XHDPSFHLSA-N 0.000 claims description 4
- UXADOQPNKNTIHB-UHFFFAOYSA-N clofentezine Chemical compound ClC1=CC=CC=C1C1=NN=C(C=2C(=CC=CC=2)Cl)N=N1 UXADOQPNKNTIHB-UHFFFAOYSA-N 0.000 claims description 4
- 239000005654 Clofentezine Substances 0.000 claims description 3
- 239000005661 Hexythiazox Substances 0.000 claims description 3
- 241000611866 Tyrophagus putrescentiae Species 0.000 claims description 3
- -1 isoxazoline compound Chemical class 0.000 description 34
- 241000239290 Araneae Species 0.000 description 13
- 230000012010 growth Effects 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 230000001276 controlling effect Effects 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000002689 soil Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- 239000004563 wettable powder Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 235000019441 ethanol Nutrition 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 241001454295 Tetranychidae Species 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 241000851181 Eutetranychus orientalis Species 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000003125 aqueous solvent Substances 0.000 description 3
- 238000007865 diluting Methods 0.000 description 3
- 230000009969 flowable effect Effects 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 241000488589 Tetranychus kanzawai Species 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000012790 confirmation Methods 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 239000003349 gelling agent Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000035755 proliferation Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 1
- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 description 1
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 description 1
- FHNKBSDJERHDHZ-UHFFFAOYSA-N (2,4-dimethylphenyl)methyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCC1=CC=C(C)C=C1C FHNKBSDJERHDHZ-UHFFFAOYSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- XUNYDVLIZWUPAW-UHFFFAOYSA-N (4-chlorophenyl) n-(4-methylphenyl)sulfonylcarbamate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC(=O)OC1=CC=C(Cl)C=C1 XUNYDVLIZWUPAW-UHFFFAOYSA-N 0.000 description 1
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 description 1
- CFRPSFYHXJZSBI-DHZHZOJOSA-N (E)-nitenpyram Chemical compound [O-][N+](=O)/C=C(\NC)N(CC)CC1=CC=C(Cl)N=C1 CFRPSFYHXJZSBI-DHZHZOJOSA-N 0.000 description 1
- PCKNFPQPGUWFHO-SXBRIOAWSA-N (Z)-flucycloxuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1)=CC=C1CO\N=C(C=1C=CC(Cl)=CC=1)\C1CC1 PCKNFPQPGUWFHO-SXBRIOAWSA-N 0.000 description 1
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- 125000001494 2-propynyl group Chemical group [H]C#CC([H])([H])* 0.000 description 1
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 description 1
- YHBIGBYIUMCLJS-UHFFFAOYSA-N 5-fluoro-1,3-benzothiazol-2-amine Chemical compound FC1=CC=C2SC(N)=NC2=C1 YHBIGBYIUMCLJS-UHFFFAOYSA-N 0.000 description 1
- 239000005660 Abamectin Substances 0.000 description 1
- 239000005875 Acetamiprid Substances 0.000 description 1
- 239000005652 Acrinathrin Substances 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 241000254127 Bemisia tabaci Species 0.000 description 1
- 239000005653 Bifenazate Substances 0.000 description 1
- 241000256593 Brachycaudus schwartzi Species 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- 239000005885 Buprofezin Substances 0.000 description 1
- JFLRKDZMHNBDQS-UCQUSYKYSA-N CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C Chemical compound CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C JFLRKDZMHNBDQS-UCQUSYKYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 description 1
- RAPBNVDSDCTNRC-UHFFFAOYSA-N Chlorobenzilate Chemical compound C=1C=C(Cl)C=CC=1C(O)(C(=O)OCC)C1=CC=C(Cl)C=C1 RAPBNVDSDCTNRC-UHFFFAOYSA-N 0.000 description 1
- 239000005944 Chlorpyrifos Substances 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000005946 Cypermethrin Substances 0.000 description 1
- 239000005892 Deltamethrin Substances 0.000 description 1
- LWLJUMBEZJHXHV-UHFFFAOYSA-N Dienochlor Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C1(Cl)C1(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl LWLJUMBEZJHXHV-UHFFFAOYSA-N 0.000 description 1
- 239000005893 Diflubenzuron Substances 0.000 description 1
- 239000005947 Dimethoate Substances 0.000 description 1
- 239000005894 Emamectin Substances 0.000 description 1
- 241001558880 Eriophyes insidiosus Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000005896 Etofenprox Substances 0.000 description 1
- 239000005898 Fenoxycarb Substances 0.000 description 1
- 239000005657 Fenpyroximate Substances 0.000 description 1
- PNVJTZOFSHSLTO-UHFFFAOYSA-N Fenthion Chemical compound COP(=S)(OC)OC1=CC=C(SC)C(C)=C1 PNVJTZOFSHSLTO-UHFFFAOYSA-N 0.000 description 1
- 239000005899 Fipronil Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920002148 Gellan gum Polymers 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 239000005906 Imidacloprid Substances 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 241000220225 Malus Species 0.000 description 1
- 239000005956 Metaldehyde Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- 239000005918 Milbemectin Substances 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- JAYZFNIOOYPIAH-UHFFFAOYSA-N Oxydeprofos Chemical compound CCS(=O)CC(C)SP(=O)(OC)OC JAYZFNIOOYPIAH-UHFFFAOYSA-N 0.000 description 1
- 239000005921 Phosmet Substances 0.000 description 1
- 239000005923 Pirimicarb Substances 0.000 description 1
- 229930182764 Polyoxin Natural products 0.000 description 1
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 description 1
- 239000005663 Pyridaben Substances 0.000 description 1
- 239000005927 Pyriproxyfen Substances 0.000 description 1
- ISRUGXGCCGIOQO-UHFFFAOYSA-N Rhoden Chemical compound CNC(=O)OC1=CC=CC=C1OC(C)C ISRUGXGCCGIOQO-UHFFFAOYSA-N 0.000 description 1
- PNAAEIYEUKNTMO-UHFFFAOYSA-N S-Seven Chemical compound C=1C=CC=CC=1P(=S)(OCC)OC1=CC=C(Cl)C=C1Cl PNAAEIYEUKNTMO-UHFFFAOYSA-N 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 101000984731 Salvia officinalis (+)-bornyl diphosphate synthase, chloroplastic Proteins 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229920000142 Sodium polycarboxylate Polymers 0.000 description 1
- 239000005930 Spinosad Substances 0.000 description 1
- 239000005664 Spirodiclofen Substances 0.000 description 1
- 239000005665 Spiromesifen Substances 0.000 description 1
- 239000005931 Spirotetramat Substances 0.000 description 1
- 239000005658 Tebufenpyrad Substances 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 239000005942 Triflumuron Substances 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 241000261596 Tyrophagus similis Species 0.000 description 1
- BZMIHNKNQJJVRO-LVZFUZTISA-N [(e)-c-(3-chloro-2,6-dimethoxyphenyl)-n-ethoxycarbonimidoyl] benzoate Chemical compound COC=1C=CC(Cl)=C(OC)C=1C(=N/OCC)\OC(=O)C1=CC=CC=C1 BZMIHNKNQJJVRO-LVZFUZTISA-N 0.000 description 1
- FSAVDKDHPDSCTO-WQLSENKSSA-N [(z)-2-chloro-1-(2,4-dichlorophenyl)ethenyl] diethyl phosphate Chemical compound CCOP(=O)(OCC)O\C(=C/Cl)C1=CC=C(Cl)C=C1Cl FSAVDKDHPDSCTO-WQLSENKSSA-N 0.000 description 1
- QSGNQELHULIMSJ-POHAHGRESA-N [(z)-2-chloro-1-(2,4-dichlorophenyl)ethenyl] dimethyl phosphate Chemical compound COP(=O)(OC)O\C(=C/Cl)C1=CC=C(Cl)C=C1Cl QSGNQELHULIMSJ-POHAHGRESA-N 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- YASYVMFAVPKPKE-UHFFFAOYSA-N acephate Chemical compound COP(=O)(SC)NC(C)=O YASYVMFAVPKPKE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- YLFSVIMMRPNPFK-WEQBUNFVSA-N acrinathrin Chemical compound CC1(C)[C@@H](\C=C/C(=O)OC(C(F)(F)F)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YLFSVIMMRPNPFK-WEQBUNFVSA-N 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- QGLZXHRNAYXIBU-WEVVVXLNSA-N aldicarb Chemical compound CNC(=O)O\N=C\C(C)(C)SC QGLZXHRNAYXIBU-WEVVVXLNSA-N 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 229940024113 allethrin Drugs 0.000 description 1
- 229960002587 amitraz Drugs 0.000 description 1
- QXAITBQSYVNQDR-ZIOPAAQOSA-N amitraz Chemical compound C=1C=C(C)C=C(C)C=1/N=C/N(C)\C=N\C1=CC=C(C)C=C1C QXAITBQSYVNQDR-ZIOPAAQOSA-N 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229910052586 apatite Inorganic materials 0.000 description 1
- 239000005667 attractant Substances 0.000 description 1
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 1
- YFXPPSKYMBTNAV-UHFFFAOYSA-N bensultap Chemical compound C=1C=CC=CC=1S(=O)(=O)SCC(N(C)C)CSS(=O)(=O)C1=CC=CC=C1 YFXPPSKYMBTNAV-UHFFFAOYSA-N 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- VHLKTXFWDRXILV-UHFFFAOYSA-N bifenazate Chemical compound C1=C(NNC(=O)OC(C)C)C(OC)=CC=C1C1=CC=CC=C1 VHLKTXFWDRXILV-UHFFFAOYSA-N 0.000 description 1
- FOANIXZHAMJWOI-UHFFFAOYSA-N bromopropylate Chemical compound C=1C=C(Br)C=CC=1C(O)(C(=O)OC(C)C)C1=CC=C(Br)C=C1 FOANIXZHAMJWOI-UHFFFAOYSA-N 0.000 description 1
- PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229960005286 carbaryl Drugs 0.000 description 1
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 1
- DUEPRVBVGDRKAG-UHFFFAOYSA-N carbofuran Chemical compound CNC(=O)OC1=CC=CC2=C1OC(C)(C)C2 DUEPRVBVGDRKAG-UHFFFAOYSA-N 0.000 description 1
- JLQUFIHWVLZVTJ-UHFFFAOYSA-N carbosulfan Chemical compound CCCCN(CCCC)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 JLQUFIHWVLZVTJ-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- IRUJZVNXZWPBMU-UHFFFAOYSA-N cartap Chemical compound NC(=O)SCC(N(C)C)CSC(N)=O IRUJZVNXZWPBMU-UHFFFAOYSA-N 0.000 description 1
- UISUNVFOGSJSKD-UHFFFAOYSA-N chlorfluazuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1Cl)=CC(Cl)=C1OC1=NC=C(C(F)(F)F)C=C1Cl UISUNVFOGSJSKD-UHFFFAOYSA-N 0.000 description 1
- 125000004775 chlorodifluoromethyl group Chemical group FC(F)(Cl)* 0.000 description 1
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 125000004186 cyclopropylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C1([H])[H] 0.000 description 1
- 229960001591 cyfluthrin Drugs 0.000 description 1
- QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 description 1
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- 229960002483 decamethrin Drugs 0.000 description 1
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 1
- WOWBFOBYOAGEEA-UHFFFAOYSA-N diafenthiuron Chemical compound CC(C)C1=C(NC(=S)NC(C)(C)C)C(C(C)C)=CC(OC=2C=CC=CC=2)=C1 WOWBFOBYOAGEEA-UHFFFAOYSA-N 0.000 description 1
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 description 1
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 1
- 229950001327 dichlorvos Drugs 0.000 description 1
- UOAMTSKGCBMZTC-UHFFFAOYSA-N dicofol Chemical compound C=1C=C(Cl)C=CC=1C(C(Cl)(Cl)Cl)(O)C1=CC=C(Cl)C=C1 UOAMTSKGCBMZTC-UHFFFAOYSA-N 0.000 description 1
- 229940019503 diflubenzuron Drugs 0.000 description 1
- MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 1
- SPCNPOWOBZQWJK-UHFFFAOYSA-N dimethoxy-(2-propan-2-ylsulfanylethylsulfanyl)-sulfanylidene-$l^{5}-phosphane Chemical compound COP(=S)(OC)SCCSC(C)C SPCNPOWOBZQWJK-UHFFFAOYSA-N 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 description 1
- RDYMFSUJUZBWLH-UHFFFAOYSA-N endosulfan Chemical compound C12COS(=O)OCC2C2(Cl)C(Cl)=C(Cl)C1(Cl)C2(Cl)Cl RDYMFSUJUZBWLH-UHFFFAOYSA-N 0.000 description 1
- HEZNVIYQEUHLNI-UHFFFAOYSA-N ethiofencarb Chemical compound CCSCC1=CC=CC=C1OC(=O)NC HEZNVIYQEUHLNI-UHFFFAOYSA-N 0.000 description 1
- RIZMRRKBZQXFOY-UHFFFAOYSA-N ethion Chemical compound CCOP(=S)(OCC)SCSP(=S)(OCC)OCC RIZMRRKBZQXFOY-UHFFFAOYSA-N 0.000 description 1
- 125000005745 ethoxymethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 1
- 229950005085 etofenprox Drugs 0.000 description 1
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 description 1
- HJUFTIJOISQSKQ-UHFFFAOYSA-N fenoxycarb Chemical compound C1=CC(OCCNC(=O)OCC)=CC=C1OC1=CC=CC=C1 HJUFTIJOISQSKQ-UHFFFAOYSA-N 0.000 description 1
- YYJNOYZRYGDPNH-MFKUBSTISA-N fenpyroximate Chemical compound C=1C=C(C(=O)OC(C)(C)C)C=CC=1CO/N=C/C=1C(C)=NN(C)C=1OC1=CC=CC=C1 YYJNOYZRYGDPNH-MFKUBSTISA-N 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 229940013764 fipronil Drugs 0.000 description 1
- RYLHNOVXKPXDIP-UHFFFAOYSA-N flufenoxuron Chemical compound C=1C=C(NC(=O)NC(=O)C=2C(=CC=CC=2F)F)C(F)=CC=1OC1=CC=C(C(F)(F)F)C=C1Cl RYLHNOVXKPXDIP-UHFFFAOYSA-N 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000000216 gellan gum Substances 0.000 description 1
- 235000010492 gellan gum Nutrition 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- RGNPBRKPHBKNKX-UHFFFAOYSA-N hexaflumuron Chemical compound C1=C(Cl)C(OC(F)(F)C(F)F)=C(Cl)C=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F RGNPBRKPHBKNKX-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- HICUREFSAIZXFQ-JOWPUVSESA-N i9z29i000j Chemical compound C1C[C@H](C)[C@@H](CC)O[C@@]21O[C@H](C\C=C(C)\[C@H](OC(=O)C(=N/OC)\C=1C=CC=CC=1)[C@@H](C)\C=C\C=C/1[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\1)O)C[C@H]4C2 HICUREFSAIZXFQ-JOWPUVSESA-N 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- HOQADATXFBOEGG-UHFFFAOYSA-N isofenphos Chemical compound CCOP(=S)(NC(C)C)OC1=CC=CC=C1C(=O)OC(C)C HOQADATXFBOEGG-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000012669 liquid formulation Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- GKKDCARASOJPNG-UHFFFAOYSA-N metaldehyde Chemical compound CC1OC(C)OC(C)OC(C)O1 GKKDCARASOJPNG-UHFFFAOYSA-N 0.000 description 1
- MEBQXILRKZHVCX-UHFFFAOYSA-N methidathion Chemical compound COC1=NN(CSP(=S)(OC)OC)C(=O)S1 MEBQXILRKZHVCX-UHFFFAOYSA-N 0.000 description 1
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 description 1
- VOEYXMAFNDNNED-UHFFFAOYSA-N metolcarb Chemical compound CNC(=O)OC1=CC=CC(C)=C1 VOEYXMAFNDNNED-UHFFFAOYSA-N 0.000 description 1
- ZLBGSRMUSVULIE-GSMJGMFJSA-N milbemycin A3 Chemical compound O1[C@H](C)[C@@H](C)CC[C@@]11O[C@H](C\C=C(C)\C[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 ZLBGSRMUSVULIE-GSMJGMFJSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 230000002013 molluscicidal effect Effects 0.000 description 1
- KRTSDMXIXPKRQR-AATRIKPKSA-N monocrotophos Chemical compound CNC(=O)\C=C(/C)OP(=O)(OC)OC KRTSDMXIXPKRQR-AATRIKPKSA-N 0.000 description 1
- 230000001069 nematicidal effect Effects 0.000 description 1
- 229940079888 nitenpyram Drugs 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- RLBIQVVOMOPOHC-UHFFFAOYSA-N parathion-methyl Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C=C1 RLBIQVVOMOPOHC-UHFFFAOYSA-N 0.000 description 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229960003536 phenothrin Drugs 0.000 description 1
- XAMUDJHXFNRLCY-UHFFFAOYSA-N phenthoate Chemical compound CCOC(=O)C(SP(=S)(OC)OC)C1=CC=CC=C1 XAMUDJHXFNRLCY-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- LMNZTLDVJIUSHT-UHFFFAOYSA-N phosmet Chemical compound C1=CC=C2C(=O)N(CSP(=S)(OC)OC)C(=O)C2=C1 LMNZTLDVJIUSHT-UHFFFAOYSA-N 0.000 description 1
- YFGYUFNIOHWBOB-UHFFFAOYSA-N pirimicarb Chemical compound CN(C)C(=O)OC1=NC(N(C)C)=NC(C)=C1C YFGYUFNIOHWBOB-UHFFFAOYSA-N 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- YEBIHIICWDDQOL-YBHNRIQQSA-N polyoxin Polymers O[C@@H]1[C@H](O)[C@@H](C(C=O)N)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 YEBIHIICWDDQOL-YBHNRIQQSA-N 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- QYMMJNLHFKGANY-UHFFFAOYSA-N profenofos Chemical compound CCCSP(=O)(OCC)OC1=CC=C(Br)C=C1Cl QYMMJNLHFKGANY-UHFFFAOYSA-N 0.000 description 1
- PWYIUEFFPNVCMW-UHFFFAOYSA-N propaphos Chemical compound CCCOP(=O)(OCCC)OC1=CC=C(SC)C=C1 PWYIUEFFPNVCMW-UHFFFAOYSA-N 0.000 description 1
- ZYHMJXZULPZUED-UHFFFAOYSA-N propargite Chemical compound C1=CC(C(C)(C)C)=CC=C1OC1C(OS(=O)OCC#C)CCCC1 ZYHMJXZULPZUED-UHFFFAOYSA-N 0.000 description 1
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 1
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 description 1
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- FBQQHUGEACOBDN-UHFFFAOYSA-N quinomethionate Chemical compound N1=C2SC(=O)SC2=NC2=CC(C)=CC=C21 FBQQHUGEACOBDN-UHFFFAOYSA-N 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 229940080817 rotenone Drugs 0.000 description 1
- JUVIOZPCNVVQFO-UHFFFAOYSA-N rotenone Natural products O1C2=C3CC(C(C)=C)OC3=CC=C2C(=O)C2C1COC1=C2C=C(OC)C(OC)=C1 JUVIOZPCNVVQFO-UHFFFAOYSA-N 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229940014213 spinosad Drugs 0.000 description 1
- DTDSAWVUFPGDMX-UHFFFAOYSA-N spirodiclofen Chemical compound CCC(C)(C)C(=O)OC1=C(C=2C(=CC(Cl)=CC=2)Cl)C(=O)OC11CCCCC1 DTDSAWVUFPGDMX-UHFFFAOYSA-N 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- CLSVJBIHYWPGQY-GGYDESQDSA-N spirotetramat Chemical compound CCOC(=O)OC1=C(C=2C(=CC=C(C)C=2)C)C(=O)N[C@@]11CC[C@H](OC)CC1 CLSVJBIHYWPGQY-GGYDESQDSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- JXHJNEJVUNHLKO-UHFFFAOYSA-N sulprofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(SC)C=C1 JXHJNEJVUNHLKO-UHFFFAOYSA-N 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- ZZYSLNWGKKDOML-UHFFFAOYSA-N tebufenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(=CC=2)C(C)(C)C)=C1Cl ZZYSLNWGKKDOML-UHFFFAOYSA-N 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- DNVLJEWNNDHELH-UHFFFAOYSA-N thiocyclam Chemical compound CN(C)C1CSSSC1 DNVLJEWNNDHELH-UHFFFAOYSA-N 0.000 description 1
- BAKXBZPQTXCKRR-UHFFFAOYSA-N thiodicarb Chemical compound CSC(C)=NOC(=O)NSNC(=O)ON=C(C)SC BAKXBZPQTXCKRR-UHFFFAOYSA-N 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
本発明は、コナダニ防除剤およびコナダニを防除する方法に関する。より詳細に、本発明は、土壌中に生息するコナダニの増殖または成長を阻害し、ホウレンソウなどへの加害を防ぐための、コナダニ防除剤およびコナダニを防除する方法に関する。 The present invention relates to a mite control agent and a method for controlling acarid mites. More specifically, the present invention relates to a mite control agent and a method for controlling acarid mites that inhibit the growth or growth of mite that live in the soil and prevent harm to spinach and the like.
近年、雨よけホウレンソウ産地では、ホウレンソウケナガコナダニなどのコナダニによる被害が拡大し、生産振興上の障害となっている。コナダニは土壌中で増殖および成長した後、ホウレンソウを加害するが、増殖または成長してからの防除は極めて困難である。よって、土壌中でのコナダニの増殖または成長を抑える防除技術の開発が望まれている。 In recent years, in spinach producing areas from rain, damage caused by spider mites such as spinach fern mite has increased, which has been an obstacle to the promotion of production. Acarid mites, which multiply and grow in the soil, harm spinach, but it is extremely difficult to control after growing or growing. Therefore, development of the control technique which suppresses the proliferation or growth of acarid mite in soil is desired.
特許文献１には、式（１）で表される置換イソキサゾリン化合物［式（１）中、Ａ1はＣ−Ｙ又は窒素原子を表し、Ａ2及びＡ3はＣ−Ｈなどを表し、Ａ4はＣ−Ｈ又は窒素原子を表し、Ｇはベンゼン環などを表し、Ｌは−ＣＨ（Ｒ4）−などを表し、Ｘはハロゲン原子、トリフルオロメチルなどを表し、Ｒ1は−Ｃ（Ｏ）Ｒ1a、−Ｃ（Ｏ）ＮＨＲ1cなどを表し、Ｒ2は水素原子、メチル、エチル、シクロプロピルメチル、メトキシメチル、エトキシメチル、シアノメチル、アリル、プロパルギルなどを表し、Ｒ3はトリフルオロメチル、クロロジフルオロメチルなどを表し、ｍは０〜５の整数を表す。］と、エトキサゾールなどの公知の有害生物防除活性成分とを含有する殺虫、殺ダニ、殺線虫、殺軟体動物、殺菌又は殺バクテリア剤組成物が開示されている。この組成物の一部に、ナミハダニ、モモアカアブラムシおよびタバココナジラミに対する防除効果を奏するものがあることを示している。しかしながら、特許文献１は、土壌中のコナダニの増殖または成長を抑えることができることを具体的に示した組成物を開示していない。 Patent Document 1 discloses a substituted isoxazoline compound represented by formula (1) [in formula (1), A 1 represents CY or a nitrogen atom, A 2 and A 3 represent C—H, etc. 4 represents C—H or a nitrogen atom, G represents a benzene ring or the like, L represents —CH (R 4 ) — or the like, X represents a halogen atom, trifluoromethyl or the like, and R 1 represents —C ( O) R 1a , —C (O) NHR 1c and the like, R 2 represents a hydrogen atom, methyl, ethyl, cyclopropylmethyl, methoxymethyl, ethoxymethyl, cyanomethyl, allyl, propargyl and the like, and R 3 represents trifluoro Represents methyl, chlorodifluoromethyl, and the like, and m represents an integer of 0 to 5. And a known pesticidal active ingredient such as etoxazole, an insecticidal, acaricidal, nematicidal, molluscicidal, bactericidal or bactericidal composition is disclosed. It has been shown that some of the compositions have a controlling effect on the spider mite, peach aphid and tobacco whitefly. However, Patent Document 1 does not disclose a composition that specifically shows that the growth or growth of acarid mites in soil can be suppressed.
本発明の課題は、土壌中に生息するコナダニの増殖または成長を阻害し、ホウレンソウなどへの加害を防ぐための、コナダニ防除剤およびコナダニを防除する方法を提供することである。 An object of the present invention is to provide a mite control agent and a method for controlling acarid mites that inhibit the growth or growth of mite that live in the soil and prevent harm to spinach and the like.
本発明者らは、上記課題を解決するために鋭意検討した結果、植物の葉などに寄生するハダニを防除するための薬剤を活性成分として含有するものを、土壌中に生息するコナダニに対して施用したところ、コナダニの増殖または成長が阻害されて、コナダニを効率的に防除できることを見出した。 As a result of intensive studies to solve the above-mentioned problems, the present inventors have found that an active ingredient containing a drug for controlling spider mites parasitic on the leaves of plants, etc. As a result of application, it was found that the growth or growth of acarid mites was inhibited and the acarids could be efficiently controlled.
すなわち、本発明は、以下の態様を含むものである。
〔１〕 植物寄生性ハダニ防除剤を含有するコナダニ防除剤。
〔２〕 植物寄生性ハダニ防除剤が、ヘキシチアゾクス、エトキサゾールおよびクロフェンテジンからなる群から選ばれる少なくとも１種の活性成分を含有するものである〔１〕に記載のコナダニ防除剤。
〔３〕 ホウレンソウケナガコナダニの防除に用いられる〔１〕に記載のコナダニ防除剤。
That is, the present invention includes the following aspects.
[1] An acarid control agent containing a plant parasitic spider mite control agent.
[2] The mite control agent according to [1], wherein the plant parasitic spider mite control agent contains at least one active ingredient selected from the group consisting of hexythiazox, etoxazole and clofentezin.
[3] The mite control agent according to [1], which is used for controlling spinach mushroom mites.
〔４〕 前記〔１〕〜〔３〕のいずれか１項に記載のコナダニ防除剤を用いてコナダニを防除する方法。 [4] A method for controlling acarid mites using the acarid control agent according to any one of [1] to [3].
本発明のコナダニ防除剤を用いると、土壌中のコナダニの増殖や成長が阻害され、コナダニの防除を行うことができる。 When the acarid mite control agent of the present invention is used, the proliferation and growth of acarid mites in soil are inhibited, and acarid mites can be controlled.
本発明のコナダニ防除剤は、植物寄生性ハダニ防除剤を活性成分として含有するものである。 The mite control agent of the present invention contains a plant parasitic spider mite control agent as an active ingredient.
植物寄生性ハダニ防除剤としては、下記の活性成分を含有するものが挙げられる。例えば、フェンチオン、フェニトロチオン、ダイアジノン、クロルピリホス、ＥＳＰ、バミドチオン、フェントエート、ジメトエート、ホルモチオン、マラソン、トリクロルホン、チオメトン、ホスメット、ジクロルボス、アセフェート、ＥＰＢＰ、メチルパラチオン、オキシジメトンメチル、エチオン、サリチオン、シアノホス、イソキサチオン、ピリダフェンチオン、ホサロン、メチダチオン、スルプロホス、クロルフェンビンホス、テトラクロルビンホス、ジメチルビンホス、プロパホス、イソフェンホス、エチルチオメトン、プロフェノホス、ピラクロホス、モノクロトホス、アジンホスメチル、アルディカルブ、メソミル、チオジカルブ、カルボフラン、カルボスルファン、ベンフラカルブ、フラチオカルブ、プロポキスル、ＢＰＭＣ、ＭＴＭＣ、ＭＩＰＣ、カルバリル、ピリミカーブ、エチオフェンカルブ、フェノキシカルブなどの有機燐およびカーバメート化合物；。 Examples of plant parasitic spider mite control agents include the following active ingredients. For example, fenthion, fenitrothion, diazinon, chlorpyrifos, ESP, bamidthione, phentoate, dimethoate, formothione, marathon, trichlorphone, thiomethone, phosmet, dichlorvos, acephate, EPBP, methyl parathion, oxydimethone methyl, ethion, salicione, cyanopyrithione, Hosalon, methidathion, sulprophos, chlorfenvinphos, tetrachlorbinphos, dimethylvinphos, propaphos, isofenphos, ethylthiomethone, profenofos, pyracrofos, monocrotophos, azinephosmethyl, aldicarb, mesomil, thiodicarb, carbofuran, carbosulfan, benfracarb, Frathiocarb, propoxur, BP C, MTMC, MIPC, carbaryl, pirimicarb, ethiofencarb, organophosphorus and carbamate compounds such as fenoxycarb;.
ペルメトリン、シペルメトリン、デルタメスリン、フェンバレレート、フェンプロパトリン、ピレトリン、アレスリン、テトラメスリン、レスメトリン、ジメスリン、プロパスリン、フェノトリン、プロトリン、フルバリネート、シフルトリン、シハロトリン、フルシトリネート、エトフェンプロクス、シクロプロトリン、トロラメトリン、シラフルオフェン、ブロフェンプロクス、アクリナスリンなどのピレスロイド化合物； Permethrin, cypermethrin, deltamethrin, fenvalerate, fenpropatoline, pyrethrin, allethrin, tetramethrin, resmethrin, dimethrin, propraslin, phenothrin, protorin, fulvalinate, cyfluthrin, cyhalothrin, flucitrinate, etofenprox, cycloprotorin, thoramethrin , Pyrethroid compounds such as silafluophene, brofenprox, acrinathrin;
ジフルベンズロン、クロルフルアズロン、ヘキサフルムロン、トリフルムロン、テトラベンズロン、フルフェノクスロン、フルシクロクスロン、ブプロフェジン、ピリプロキシフェン、メトプレン、ベンゾエピン、ジアフェンチウロン、アセタミプリド、イミダクロプリド、ニテンピラム、フィプロニル、カルタップ、チオシクラム、ベンスルタップ、硫酸ニコチン、ロテノン、メタアルデヒド、エマメクチン、フルベンジアミド、スピノサド、エトキサゾール； Diflubenzuron, chlorfluazuron, hexaflumuron, triflumuron, tetrabenzuron, flufenoxuron, flucycloxuron, buprofezin, pyriproxyfen, metoprene, benzoepin, diafenthiuron, acetamiprid, imidacloprid, nitenpyram, fipronil, cartap Thiocyclam, bensultap, nicotine sulfate, rotenone, metaldehyde, emamectin, fulvendiamide, spinosad, etoxazole;
フェナミホス、ホスチアゼート；
クロルベンジレート、フェニソブロモレート、ジコホル、アミトラズ、ＢＰＰＳ、ベンゾメート、ヘキシチアゾクス、酸化フェンブタスズ、ポリナクチン、キノメチオネート、ＣＰＣＢＳ、テトラジホン、アベルメクチン、ミルベメクチン、クロフェンテジン、シヘキサチン、ピリダベン、フェンピロキシメート、テブフェンピラド、ピリミジフェン、フェノチオカルブ、ジエノクロル、フルアクリピリム、スピロジクロフェン、スピロメシフェン、スピロテトラマト、シエノピラフェン、シフルメトフェン、アセキノシル、ビフェナゼート、レピメクチン、ポリオキシンなどが挙げられる。
Fenamifos, phostiazate;
Chlorbenzilate, phenisobromolate, dicofol, amitraz, BPPS, benzomate, hexithiazox, fenbutazin oxide, polynactin, quinomethionate, CPCBS, tetradiphone, avermectin, milbemectin, clofentedin, cihexatin, pyridaben, fenpyroximate, tebufenpyrad, thiomidibene Examples include dienochlor, fluacripyrim, spirodiclofen, spiromesifen, spirotetramat, sienopyrafen, cyflumethofene, acequinosyl, bifenazate, lepimectin, polyoxin and the like.
これらのうち、ヘキシチアゾクス、エトキサゾールおよびクロフェンテジンからなる群から選ばれる少なくとも１種を含有するものが好ましい。 Among these, those containing at least one selected from the group consisting of hexothiazox, etoxazole and clofentezin are preferable.
ヘキシチアゾクスは、化合物名：ｔｒａｎｓ−５−（４−クロロフェニル）−Ｎ−シクロヘキシル−４−メチル−２−オキソチアゾリジン−３−カルボキサミドであり、式（I）に示される化合物である。ヘキシチアゾクスは、ミカンハダニ、リンゴハダニ、ナミハダニなどのハダニ類に適用される防除剤の活性成分である。 Hexithiazox is a compound name: trans-5- (4-chlorophenyl) -N-cyclohexyl-4-methyl-2-oxothiazolidine-3-carboxamide, which is a compound represented by the formula (I). Hexithiazox is an active ingredient of a control agent applied to spider mites such as citrus mite, apple spider mite, and spider mite.
エトキサゾールは、化合物名：４−（４−ｔ−ブチル−２−エトキシフェニル）−２−（２，６−ジフルオロフェニル）−４，５−ジヒドロオキサゾールであり、式（II）に示される化合物である。エトキサゾールは、ミカンハダニ、ミカンサビダニ、リンゴハダニ、モモサビダニ、カンザワハダニなどのハダニ類に適用される防除剤の活性成分である。 Etoxazole is a compound name: 4- (4-t-butyl-2-ethoxyphenyl) -2- (2,6-difluorophenyl) -4,5-dihydrooxazole, which is a compound represented by the formula (II). is there. Etoxazole is an active ingredient of a control agent applied to ticks such as citrus mite, citrus mite, apple mite, peach mite, and kanzawa spider mite.
クロフェンテジンは、化合物名：３，６−ビス（２−クロロフェニル）−１，２，４，５−テトラジンであり、式（III）に示される化合物である。クロフェンテジンは、カンザワハダニ、チャノナガサビダニ、リンゴハダニ、ナミハダニなどのハダニ類に適用される防除剤の活性成分である。 Clofentezine is a compound name: 3,6-bis (2-chlorophenyl) -1,2,4,5-tetrazine, and is a compound represented by the formula (III). Clofentedine is an active ingredient of a control agent that is applied to spider mites such as the Kanzawa spider mite, the Chinese spider mite, the apple spider mite, and the spider mite.
本発明に係るコナダニ防除剤を製造するための植物寄生性防除剤として、前記活性成分そのものを用いてもよいし；前記活性成分を、粉剤、粒剤、水和剤、顆粒水和剤、乳剤、液剤、懸濁剤、水溶剤、マイクロカプセル化剤、フロアブルなどに製剤化してなるものを用いてもよい。 The active ingredient itself may be used as a plant parasitic control agent for producing the acarid control agent according to the present invention; the active ingredient may be a powder, a granule, a wettable powder, a granular wettable powder, or an emulsion. , Liquids, suspensions, aqueous solvents, microencapsulating agents, flowables and the like may be used.
本発明のコナダニ防除剤は、活性成分と他の成分とからなる製剤であってもよい。製剤中の活性成分量は、特に限定されないが、通常、製剤全体に対して、好ましくは０．５〜９５質量％であり、より好ましくは２〜７０質量％である。 The mite control agent of the present invention may be a preparation comprising an active ingredient and other ingredients. Although the amount of the active ingredient in the preparation is not particularly limited, it is usually preferably 0.5 to 95% by mass, more preferably 2 to 70% by mass with respect to the whole preparation.
本発明のコナダニ防除剤は、一般の農薬のとり得る形態、即ち、水和剤、粒剤、粉剤、乳剤、水溶剤、懸濁剤、フロアブルなどの形態に製剤化することができる。固形製剤においては、大豆粉、小麦粉などの植物性粉末、珪藻土、燐灰石、石こう、タルク、ベントナイト、パイロフィライト、クレーなどの鉱物性微粉末、安息香酸ソーダ、尿素、芒硝などの有機および無機化合物などの添加剤および／または担体を用いることができる。液体製剤においては、ケロシン、キシレンおよびソルベントナフサなどの石油留分、シクロヘキサン、シクロヘキサノン、ジメチルホルムアミド、ジメチルスルホキシド、アルコール、アセトン、トリクロロエチレン、メチルｉ−ブチルケトン、鉱物油、植物油、水などの溶剤を用いることができる。 The acarid control agent of the present invention can be formulated into a form that can be taken by general agricultural chemicals, that is, a wettable powder, granule, powder, emulsion, aqueous solvent, suspension, flowable and the like. In solid preparations, vegetable powders such as soybean flour and wheat flour, mineral fine powders such as diatomaceous earth, apatite, gypsum, talc, bentonite, pyrophyllite, clay, and organic and inorganic compounds such as sodium benzoate, urea, and mirabilite Such additives and / or carriers can be used. In liquid formulations, use petroleum fractions such as kerosene, xylene and solvent naphtha, solvents such as cyclohexane, cyclohexanone, dimethylformamide, dimethyl sulfoxide, alcohol, acetone, trichloroethylene, methyl i-butyl ketone, mineral oil, vegetable oil, water, etc. Can do.
さらに、本発明のコナダニ防除剤には、製剤化において、結合剤、ゲル化剤、液体成分、色素、吸水性ポリマー、防腐剤、保存剤、共力剤、酸化防止剤、誤食防止剤、界面活性剤、消泡剤、誘引剤などの添加剤を配合することができる。
界面活性剤としては、例えば、ポリオキシエチレンが付加したアルキルフェニルエーテル、ポリオキシエチレンが付加したアルキルエーテル、ポリオキシエチレンが付加した高級脂肪酸エステル、ポリオキシエチレンが付加したソルビタン高級脂肪酸エステル、ポリオキシエチレンが付加したトリスチリルフェニルエーテルなどの非イオン性界面活性剤；ポリオキシエチレンが付加したアルキルフェニルエーテルの硫酸エステル塩、アルキルベンゼンスルホン酸塩、高級アルコールの硫酸エステル塩、アルキルナフタレンスルホン酸塩、ポリカルボン酸塩、リグニンスルホン酸塩、アルキルナフタレンスルホン酸塩のホルムアルデヒド縮合物、ｉ−ブチレン−無水マレイン酸の共重合体などが挙げられる。
結合剤としては、ニトロセルロース、カルボキシメチルセルロース、ヒドロキシプロピルセルロースなどが挙げられる。
ゲル化剤としては、ゼラチン、カラギーナン、寒天、ジェランガムなどが挙げられる。
液体成分としては、水、アルコールなどが挙げられる。アルコールとしては、エチルアルコール、イソプロピルアルコールなどが挙げられる。
色素としては、青色１号、黄色２０３号、赤色ｌ０２号などが挙げられる。
Furthermore, the mite control agent of the present invention includes a binder, a gelling agent, a liquid component, a dye, a water-absorbing polymer, an antiseptic, a preservative, a synergist, an antioxidant, an anti-corrosion agent, Additives such as surfactants, antifoaming agents and attractants can be blended.
Examples of the surfactant include alkyl phenyl ether added with polyoxyethylene, alkyl ether added with polyoxyethylene, higher fatty acid ester added with polyoxyethylene, sorbitan higher fatty acid ester added with polyoxyethylene, polyoxyethylene Nonionic surfactants such as tristyrylphenyl ether with addition of ethylene; sulfates of alkylphenyl ethers with addition of polyoxyethylene, alkylbenzene sulfonates, sulfates of higher alcohols, alkylnaphthalene sulfonates, poly Examples thereof include a carboxylate, a lignin sulfonate, a formaldehyde condensate of an alkyl naphthalene sulfonate, and an i-butylene-maleic anhydride copolymer.
Examples of the binder include nitrocellulose, carboxymethylcellulose, hydroxypropylcellulose and the like.
Gelling agents include gelatin, carrageenan, agar, gellan gum and the like.
Examples of the liquid component include water and alcohol. Examples of the alcohol include ethyl alcohol and isopropyl alcohol.
Examples of the dye include Blue No. 1, Yellow No. 203, and Red No. 02.
本発明のコナダニ防除剤の施用方法は特に限定されない。例えば、水和剤、乳剤、フロアブル剤などである場合には、水で所定の濃度に希釈して、それを植物または土壌に散布することができる。水和剤、乳剤、懸濁剤、水溶剤、顆粒水和剤などを水で希釈して施用する場合、その施用濃度は１〜１０００ｐｐｍ、好ましくは１０〜２５０ｐｐｍである。
また、本発明のコナダニ防除剤が、粉剤・粒剤などである場合には、そのまま植物または土壌に散布することができる。
本発明のコナダニ防除剤の施用量は、気象条件、製剤形態、施用時期、施用方法、施用場所、防除対象病害、対象作物などにより異なるが、通常１ヘクタール当たり有効成分化合物量にして１〜１，０００ｇ、好ましくは１０〜１００ｇである。
The application method of the mite control agent of the present invention is not particularly limited. For example, in the case of wettable powders, emulsions, flowables, etc., they can be diluted with water to a predetermined concentration and sprayed onto plants or soil. When a wettable powder, emulsion, suspension, aqueous solvent, granular wettable powder, etc. are diluted with water and applied, the applied concentration is 1-1000 ppm, preferably 10-250 ppm.
Moreover, when the dust mite control agent of this invention is a powder agent, a granule, etc., it can spray on a plant or soil as it is.
The application rate of the acarid control agent of the present invention varies depending on weather conditions, formulation form, application time, application method, application place, disease to be controlled, target crop, etc., but usually 1 to 1 active ingredient compound amount per hectare. 1,000 g, preferably 10 to 100 g.
本発明のコナダニ防除剤は、除草剤、殺菌剤、殺虫剤、植物成長調整剤、肥料などと併用することができる。併用することによって、それぞれの使用薬量を減少させることができたり、省力化をもたらすことができたりする場合がある。 The acarid control agent of the present invention can be used in combination with herbicides, fungicides, insecticides, plant growth regulators, fertilizers and the like. By using together, there are cases where the amount of each drug used can be reduced or labor saving can be achieved.
次に、本発明の製剤実施例を若干示すが、添加物および添加割合は、これら実施例に限定されるものではなく、広範囲に変化させることが可能である。 製剤実施例中の部は質量部を示す。 Next, some preparation examples of the present invention will be shown. However, the additives and addition ratios are not limited to these examples, and can be varied in a wide range. The part in a formulation example shows a mass part.
製剤実施例１ ヘキシチアゾクス水和剤
ヘキシチアゾクス４０重量部、クレー５３重量部、ジオクチルスルホサクシネートナトリウム塩４重量部、およびリグニンスルホン酸ナトリウム塩３重量部を均一に混合して微細に粉砕して、有効成分４０％の水和剤を得る。
Formulation Example 1 Hexithiazox wettable powder 40 parts by weight of hexythiazox, 53 parts by weight of clay, 4 parts by weight of dioctylsulfosuccinate sodium salt, and 3 parts by weight of lignin sulfonic acid sodium salt are uniformly mixed and finely pulverized. A 40% wettable powder is obtained.
製剤実施例２ エトキサゾール懸濁剤
エトキサゾール１０質量部、ポリオキシエチレンアルキルアリルエーテル４質量部、ポリカルボン酸ナトリウム塩２質量部、グリセリン１０質量部、キサンタンガム０．２質量部および水７３．８質量部を混合し、粒度が３ミクロン以下になるまで湿式粉砕して、有効成分１０％の懸濁剤を得る。
Formulation Example 2 Etoxazole Suspension Etoxazole 10 parts by mass, polyoxyethylene alkylallyl ether 4 parts by mass, polycarboxylic acid sodium salt 2 parts by mass, glycerin 10 parts by mass, xanthan gum 0.2 parts by mass and water 73.8 parts by mass And wet milling until the particle size is 3 microns or less to obtain a suspension with 10% active ingredient.
製剤実施例３ クロフェンテジン懸濁剤
クロフェンテジン１０質量部、ポリオキシエチレンアルキルアリルエーテル４質量部、ポリカルボン酸ナトリウム塩２質量部、グリセリン１０質量部、キサンタンガム０．２質量部および水７３．８質量部を混合し、粒度が３ミクロン以下になるまで湿式粉砕して、有効成分１０％の懸濁剤を得る。
Formulation Example 3 Clofentedine Suspension Agent 10 parts by weight of clofentezin, 4 parts by weight of polyoxyethylene alkyl allyl ether, 2 parts by weight of sodium polycarboxylate, 10 parts by weight of glycerin, 0.2 part by weight of xanthan gum and 73 of water 8 parts by mass are mixed and wet-pulverized until the particle size is 3 microns or less to obtain a suspension with 10% active ingredient.
〔コナダニ防除効果確認試験〕
春日・天野、日本応用動物昆虫学会(応動昆) ４６（２）、９９−１０１（２００２）に記載されている方法に準じて行った。具体的には、４ｃｍ四方の黒画用紙を、水９０ｇおよび乾燥酵母粉末１０ｇからなる懸濁液に浸漬した。風乾後の前記黒画用紙を所定濃度の薬液に浸漬した。薬液を風乾後、９ｃｍシャーレ内に該黒画用紙を設置した。これにホウレンソウケナガコナダニ（Tyrophagus similis）雌成虫１０頭を放虫した。シャーレを２０℃の全暗状態に保持した。８日および１５日経過後に、若虫、幼虫および卵の数を計測した。試験は２反復で行った。
[Confirmation test for mite control effect]
It was performed according to the method described in Kasuga and Amano, Japan Society for Applied Animal Entomology (Odori Kun) 46 (2), 99-101 (2002). Specifically, 4 cm square black drawing paper was immersed in a suspension composed of 90 g of water and 10 g of dry yeast powder. The black drawing paper after air drying was immersed in a chemical solution having a predetermined concentration. After the chemical solution was air-dried, the black drawing paper was placed in a 9 cm petri dish. Ten adult females of Tyrophagus similis were released. The petri dish was kept in an entirely dark state at 20 ° C. After 8 and 15 days, the numbers of nymphs, larvae and eggs were counted. The test was performed in duplicate.
薬液として、ニッソランＷＰを水で２０００倍に希釈した液（ヘキシチアゾクスを含有する植物寄生性ハダニ防除剤）、バロックＳＣを水で２０００倍に希釈した液（エトキサゾールを含有する植物寄生性ハダニ防除剤）およびカーラＳＣを水で２０００倍に希釈した液（クロフェンテジンを含有する植物寄生性ハダニ防除剤）をそれぞれ用いた。
比較例として、上記コナダニ防除効果確認試験において、薬液浸漬を行わなかった場合（表１中、「無処理」と表記する。）を示した。
As a chemical solution, a solution obtained by diluting Nissoran WP 2000 times with water (plant parasitic spider mite control agent containing hexithiazox), a solution obtained by diluting Baroque SC 2000 times with water (plant parasitic spider mite control agent containing etoxazole) A solution obtained by diluting Cala SC with water 2000 times (plant parasitic spider mite control agent containing clofentezin) was used.
As a comparative example, the case where the chemical solution immersion was not performed in the above-mentioned mite control effect confirmation test (shown as “no treatment” in Table 1) is shown.
以上の結果から、本発明に係るコナダニ防除剤は、ホウレンソウケナガコナダニなどのコナダニ類の増殖や成長を阻害して、コナダニ類を効果的に防除できることがわかる。 From the above results, it can be seen that the mite controlling agent according to the present invention can effectively control mites by inhibiting the growth and growth of mites such as spinach mushroom mites.
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011053136A JP5718107B2 (en) | 2011-03-10 | 2011-03-10 | Mite control agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011053136A JP5718107B2 (en) | 2011-03-10 | 2011-03-10 | Mite control agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2012188382A JP2012188382A (en) | 2012-10-04 |
| JP5718107B2 true JP5718107B2 (en) | 2015-05-13 |
Family
ID=47081949
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011053136A Active JP5718107B2 (en) | 2011-03-10 | 2011-03-10 | Mite control agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5718107B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013095740A (en) | 2011-11-04 | 2013-05-20 | Sumitomo Chemical Co Ltd | Aqueous suspension agrochemical composition and aqueous suspension agrochemical formulation |
| JP2013095739A (en) * | 2011-11-04 | 2013-05-20 | Kyoyu Agri Kk | Arthropod pest control composition |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0005912B1 (en) * | 1978-05-25 | 1982-07-14 | Fbc Limited | Acaricidal, larvicidal and ovicidal tetrazine derivatives and compositions, processes for their preparation and methods of using them |
| JPS5750982A (en) * | 1980-09-12 | 1982-03-25 | Nippon Soda Co Ltd | Thiazolidine derivative, its preparation and acaricide |
| JP3299395B2 (en) * | 1993-09-22 | 2002-07-08 | 八洲化学工業株式会社 | Insecticidal and acaricidal compositions |
| JP3428112B2 (en) * | 1993-12-21 | 2003-07-22 | 八洲化学工業株式会社 | Composite acaricide composition |
-
2011
- 2011-03-10 JP JP2011053136A patent/JP5718107B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2012188382A (en) | 2012-10-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2004143174A (en) | Insecticidal aminothiazole derivative | |
| KR101292940B1 (en) | Tetrazoyloxime derivative and plant disease control agent | |
| TW201242962A (en) | Pyrimidine compound and use for pest control thereof | |
| UA128352C2 (en) | (hetero)arylimidazole compound and harmful organism control agent | |
| UA127424C2 (en) | Heteroarylazole compound and pest control agent | |
| AU2013219467B2 (en) | Aryloxyacetamide compound and pesticide | |
| MX2010012843A (en) | 1,2-benzisothiazole compounds useful for combating animal pests. | |
| JP6221103B2 (en) | Method for producing co-crystal | |
| US20150099883A1 (en) | Aryloxyurea compound and pest control agent | |
| JP3580589B2 (en) | Insecticide, acaricide composition | |
| JP5718107B2 (en) | Mite control agent | |
| TW201008490A (en) | Pesticidal composition | |
| KR20130121979A (en) | Aqueous horticultural microbicidal composition suspension | |
| JPH08291171A (en) | Insecticidal 5-((tetrahydro-3-furanyl)methyl)-4-nitroiminoperphydro-1,3,5-oxadiazine derivative | |
| WO2012050141A1 (en) | Heteroaromatic ring compound and use thereof for pest control | |
| JP4655302B2 (en) | Clubroot control agent | |
| JP2009062277A (en) | Benzisothiazoline compound and pest control agent | |
| WO2012073995A1 (en) | Heteroaromatic ring compound and pest control application thereof | |
| JP2004210764A (en) | 2-iminothiazole derivative and insecticide/acaricide | |
| WO2012008526A1 (en) | Pyridine compound and pest-control usage therefor | |
| WO2017122687A1 (en) | Blood-sucking-arthropod control method and blood-sucking-arthropod control composition for treating elements that form living spaces | |
| JPH08277275A (en) | Nitrogen-containing 6-membered ring compound, its production and harmful life controlling agent | |
| JPH07330742A (en) | Triazole derivative, its production and insect pest controlling agent | |
| JP3116497B2 (en) | Nematicide acaricide | |
| WO2023112988A1 (en) | Method for controlling noxious arthropods |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20131114 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20141009 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20141021 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20141219 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20150317 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20150318 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5718107 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |