JP5710126B2 - LED lighting device - Google Patents

LED lighting device Download PDF

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JP5710126B2
JP5710126B2 JP2010005370A JP2010005370A JP5710126B2 JP 5710126 B2 JP5710126 B2 JP 5710126B2 JP 2010005370 A JP2010005370 A JP 2010005370A JP 2010005370 A JP2010005370 A JP 2010005370A JP 5710126 B2 JP5710126 B2 JP 5710126B2
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chloride
light
led
washing
zinc sulfide
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JP2011146488A (en
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辰美 塩谷
辰美 塩谷
静芯 呂
静芯 呂
佳代子 渡邊
佳代子 渡邊
透 嵯峨
透 嵯峨
高橋 宏
高橋  宏
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ザイ&エス株式会社
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/4805Shape
    • H01L2224/4809Loop shape
    • H01L2224/48091Arched
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481Disposition
    • H01L2224/48135Connecting between different semiconductor or solid-state bodies, i.e. chip-to-chip
    • H01L2224/48137Connecting between different semiconductor or solid-state bodies, i.e. chip-to-chip the bodies being arranged next to each other, e.g. on a common substrate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/49Structure, shape, material or disposition of the wire connectors after the connecting process of a plurality of wire connectors
    • H01L2224/491Disposition
    • H01L2224/49105Connecting at different heights
    • H01L2224/49107Connecting at different heights on the semiconductor or solid-state body

Description

本発明は、LEDを用いた照明装置に関し、更に詳しくは、照明装置から離れても照度の低下が少ないLEDを用いた照明装置に関するものである。   The present invention relates to an illuminating device using LEDs, and more particularly to an illuminating device using LEDs in which the decrease in illuminance is small even if the illuminating device is separated from the illuminating device.

LEDを用いた照明装置については多く知られている(例えば、特許文献1〜2)。また、汎用の照明装置の代替品とするべく、外観を汎用の照明装置に模し、またLEDの光透過に磨りガラス状の光拡散による面発光も知られている(例えば、非特許文献1〜2)。   Many illuminating devices using LEDs are known (for example, Patent Documents 1 and 2). Moreover, in order to replace the general-purpose lighting device, the appearance is similar to that of a general-purpose lighting device, and surface light emission is also known by diffusing glass light into the light transmission of the LED (for example, Non-Patent Document 1). ~ 2).

これらLEDを用いた照明装置代替品は、汎用の照明装置に比べ、熱を持たない、電力消費量が少ない、寿命が長い等の特長がある反面、複数のLEDを並置しても点照明の集合体のため照度が充分でないという問題点があった。そして、照度を充分に確保するために更に多くのLEDを並置し面照明にすると、照明装置全体として高価になりコスト的に問題が生じる場合があった。   These lighting device substitutes using LEDs have features such as having no heat, less power consumption, and longer life compared to general-purpose lighting devices. There was a problem that the illuminance was not sufficient due to the aggregate. If more LEDs are juxtaposed in order to ensure sufficient illuminance and surface illumination is used, the lighting device as a whole becomes expensive and may cause problems in terms of cost.

それに加え、より大きな問題点として、更に多くのLEDを並置した場合LEDの発熱が問題になり、放熱を考慮しなければ熱破壊や照度が急激に落ちてしまうという問題点もあった。   In addition, as a larger problem, when more LEDs are juxtaposed, there is a problem that heat generation of the LEDs becomes a problem, and unless heat dissipation is taken into consideration, thermal destruction and illuminance rapidly decrease.

そのため、LEDを用いた照明装置は多くの特長を有するものの、上記した大きな問題点のために、汎用の照明装置の完全な代替品としては使用できるものではなく、従って一般的な照明装置としては支障なく使用することができなかった。   Therefore, although the lighting device using LED has many features, it cannot be used as a complete replacement for a general-purpose lighting device due to the above-mentioned major problems, and therefore, as a general lighting device, It could not be used without any trouble.

省エネルギー、長寿命等環境特性等の要求は、近年ますます高くなってきている。しかしながら、照明装置からの距離が離れた場所及び角度がずれた場所での照度が不十分なため、LEDを用いた照明装置については汎用のものにはなっておらず、更なる改善の余地があった。   The demands for environmental characteristics such as energy saving and long life have been increasing in recent years. However, since the illuminance at a place away from the lighting device and at a position where the angle is shifted is insufficient, the lighting device using the LED is not general-purpose, and there is room for further improvement. there were.

特開2009−111346号公報JP 2009-111346 A 特開2009−286995号公報JP 2009-286995 A RoHS商品カタログ(PolelLED Series)RoHS product catalog (PoleLED Series)

本発明は上記背景技術に鑑みてなされたものであり、その課題は、発熱を抑え、電力消費量が少ない、寿命が長い等のLEDの特長を生かしつつ、LEDから離れても照度が急激に落ちてしまうことがなく、LEDの照射方向から角度的にずれても照度が急激に落ちてしまうことのない「複数のLED構造体が並置された照明装置」を提供することにある。   The present invention has been made in view of the above-described background art, and the problem is that the illuminance rapidly increases even if the LED is separated from the LED while taking advantage of the features of the LED such as suppressing heat generation, low power consumption, and long life. An object of the present invention is to provide a “lighting device in which a plurality of LED structures are juxtaposed” so that the illuminance does not drop sharply even if it is angularly deviated from the LED irradiation direction.

本発明者は、上記の課題を解決すべく鋭意検討を重ねた結果、個々のLEDの前方に光拡散効果を有する光透過体を設けると、設けないものと比較して、遠くまで照度が落ちず、また斜めの方向でも照度が落ちないことを見出した。そして、このような光透過体が設けられたLED構造体を複数個並置することによって、汎用の照明装置を代替するものになり得ることを確認し本発明を完成するに至った。   As a result of intensive studies to solve the above problems, the inventor has provided a light transmissive body having a light diffusion effect in front of each LED. In addition, it was found that the illuminance does not decrease even in an oblique direction. And it confirmed that it could substitute for a general purpose illuminating device by juxtaposing a plurality of LED structures provided with such a light transmission body, and came to complete this invention.

すなわち、本発明は、並置された複数のLED構造体と、これら複数のLED構造体を包囲する硫化亜鉛(ZnS-Ag)化合物を拡散配置した光透過体を有する照明装置であって、該LED構造体が、それぞれのLEDの前方に「光拡散効果を有する光透過体」が設けられているものであることを特徴とする照明装置を提供するものである。   That is, the present invention is a lighting device having a plurality of LED structures juxtaposed and a light transmitting body in which a zinc sulfide (ZnS-Ag) compound surrounding the plurality of LED structures is diffusely arranged. The structure is provided with an “illuminating device” in which a “light transmissive body having a light diffusion effect” is provided in front of each LED.

また、本発明は、上記硫化亜鉛(ZnS-Ag)化合物を拡散配置した光透過体LED構造体において、硫化亜鉛(ZnS-Ag)化合物を拡散配置した光透過体がLED構造体の基板バッファー層までを包囲し且つ接続のボンディングワイアーの上面までを包囲する、「光拡散効果を有する光屈折体」を有しているものである上記の照明装置を提供するものである。   The present invention also provides a light transmissive LED structure in which the zinc sulfide (ZnS-Ag) compound is diffusely arranged, wherein the light transmissive body in which the zinc sulfide (ZnS-Ag) compound is diffused is a substrate buffer layer of the LED structure. The above-described illumination device is provided that has a “light refracting body having a light diffusion effect” that surrounds the upper and lower surfaces of the connecting bonding wires.

また、本発明は、上記光照明装置が、極めて薄く且つ、内部に配置している個々のLEDの輪郭が目視で識別できない程度に面発光が可能な上記の照明装置を提供するものである。   In addition, the present invention provides the above-described illumination device that is capable of emitting light to the extent that the light illumination device is extremely thin and the contours of the individual LEDs disposed therein cannot be visually identified.

また、本発明は、上記照明装置の中央から、光の照射される方向に1mの距離を隔てて存在する平面上の照度において、上記照明装置の中央を通り、上記照明装置から直角に伸びた直線が該平面となす角が10°の地点の照度が、上記照明装置の中央を通る直線と該平面のなす角が90°の地点(照明装置の中央から該平面に垂直に下した地点)の照度の1/3以上である上記の照明装置を提供するものである。   Further, the present invention extends from the center of the illuminating device at a right angle from the illuminating device through the center of the illuminating device at an illuminance on a plane existing at a distance of 1 m from the center of the illuminating device. The illuminance at the point where the angle formed by the straight line and the plane is 10 ° is the point where the angle formed by the straight line passing through the center of the illuminating device and the plane is 90 ° (the point lowered from the center of the illuminating device perpendicular to the plane) The illuminating device is provided with the illuminance of 1/3 or more.

本発明によれば、発熱が小さく効率的で、電力消費量が少ないため発電に必要な天然資源を削減でき、CO2の排出削減が可能で環境に優しく、寿命が長い等のLEDの特長を発揮しつつ、照明装置用としてはLEDの欠点であった、LEDから距離が離れると急激に照度が落ちてしまい、LEDの照射方向から角度的にずれると急激に照度が落ちてしまうという点発光の問題点を解決したLED面発光照明装置を提供することができる。   According to the present invention, the heat generation is small and efficient, and the power consumption is small, so that natural resources necessary for power generation can be reduced, CO2 emissions can be reduced, the environment is friendly, and the life of the LED is long. On the other hand, it was a drawback of LEDs for lighting devices. The point of light emission is that the illuminance suddenly drops when the distance from the LED increases, and the illuminance drops suddenly when it is angularly shifted from the irradiation direction of the LED. It is possible to provide an LED surface emitting illumination device that solves the problem.

また、硫化亜鉛(ZnS-Ag)化合物を拡散配置した光透過体包囲した複数のLED構造体を並置することによって、汎用の照明装置と光学的には殆ど性能に差がない照明装置を提供できる。すなわち、LED構造体若しくは照明装置から距離が離れても汎用の照明装置と同程度に照度が落ちず、LED構造体若しくは照明装置の照射方向から角度的にずれても汎用の照明装置と同程度に照度が落ちない。そのため、光学的に、使用上、汎用の照明装置と同様の輝度を持ち、照明装置の代替として通用する薄型の照明装置を提供することができる。   Further, by arranging a plurality of LED structures surrounded by a light transmitting body in which a zinc sulfide (ZnS-Ag) compound is diffusely arranged, a lighting device having almost no difference in optical performance from a general-purpose lighting device can be provided. . That is, the illuminance does not decrease as much as a general-purpose lighting device even if the distance from the LED structure or the lighting device is large, and the same degree as a general-purpose lighting device even if it is angularly deviated from the irradiation direction of the LED structure or lighting device. The illuminance does not decrease. Therefore, it is possible to provide a thin illuminating device that has the same luminance as a general-purpose illuminating device in terms of use and can be used as a substitute for the illuminating device.

以下、本発明について説明するが、本発明は、以下の具体的形態に限定されるものではなく、技術的思想の範囲内で任意に変形することができる。   Hereinafter, the present invention will be described, but the present invention is not limited to the following specific embodiments, and can be arbitrarily modified within the scope of the technical idea.

本発明の照明装置は、複数のLED構造体が並置されており、個々のLED構造体は、そのLEDの前方に「光拡散効果を有する光透過体」(以下、括弧内を「光透過体」と略記する)が設けられた構造を有している。   In the lighting device of the present invention, a plurality of LED structures are juxtaposed, and each LED structure has a “light transmitting body having a light diffusion effect” (hereinafter referred to as “light transmitting body” in parentheses) in front of the LED. "Is abbreviated as").

図1は、LED構造体1の断面形状の代表的な例を示している。LED構造体1は、図1のp電極の1の照射方向(以下、「前方」と略記することもある)から8の基板までを包囲する光透過体11が設けられている。光透過体11は、「LEDから距離が離れても照度が落ちない」、「LEDの照射方向から角度がずれても照度が落ちない」という本発明の上記効果を得るために設けられる。光透過体11は、以下の方法によって製造された。   FIG. 1 shows a typical example of the cross-sectional shape of the LED structure 1. The LED structure 1 is provided with a light transmitting body 11 that surrounds from the irradiation direction of the p-electrode 1 in FIG. 1 (hereinafter sometimes abbreviated as “front”) to 8 substrates. The light transmitting body 11 is provided in order to obtain the above-described effects of the present invention, such as “the illuminance does not decrease even when the LED is separated from the LED” and “the illuminance does not decrease even if the angle is shifted from the irradiation direction of the LED”. The light transmissive body 11 was manufactured by the following method.

光透過体11は、フラックスとしてBaCl,MgCl,NaCl等の適切なハロゲン化物をドープした硫化亜鉛(ZnS-Ag)が活性化剤としての硫化銀Ag2S、と混合され混合物を構成する。   The light transmissive body 11 is mixed with zinc sulfide (ZnS-Ag) doped with an appropriate halide such as BaCl, MgCl, or NaCl as a flux and silver sulfide Ag2S as an activator to form a mixture.

混合物は摂氏1250度において2時間加熱し加熱炉から取り出した焼成物は残留フラックスを水洗により除去し乾燥後分級粉砕し粒子を概略一定にする。この段階ではまだ光透過体としては不活性である。   The mixture is heated at 1250 degrees Celsius for 2 hours, and the fired product taken out from the heating furnace is washed with water, dried, classified and pulverized to make the particles substantially constant. At this stage, it is still inactive as a light transmissive body.

乾燥後分級粉砕し粒子を概略一定にされた材料を硫化亜鉛(ZnS-Ag)などとともに加熱炉において摂氏730度で8時間30分程度加熱し取り出した焼成物を分級粉砕し20ミクロンから40ミクロンの粒子とし、稀酢酸水で洗浄し脱イオン水で水洗いし活性化し活性化された粒子と透明バインダーとしての熱硬化型シリコン樹脂またはUV硬化型の樹脂と混合され光透過体として実用化に供される。混合比率は7%から15%程度の活性化された粒子とバインダーの混合物として光透過体となる。   After drying and classifying and pulverizing the material, the particles are roughly constant and heated together with zinc sulfide (ZnS-Ag) in a heating furnace at 730 degrees Celsius for about 8 hours and 30 minutes. The particles are washed with dilute acetic acid, washed with deionized water, activated and activated, and mixed with thermosetting silicone resin or UV curable resin as a transparent binder and put into practical use as a light transmissive body. Is done. The mixing ratio is about 7% to 15%, and becomes a light transmitting body as a mixture of activated particles and a binder.

LED照明装置を構成する光透過体11は、図2のように、複数のLED13を包含するように配置されその前方にLEDの波長変換剤が設けられている。   As shown in FIG. 2, the light transmissive body 11 constituting the LED illumination device is arranged so as to include a plurality of LEDs 13, and an LED wavelength conversion agent is provided in front of the LEDs 13.

LED13は、光透過体11は初期の焼成に際し活性化剤を選択することにより効率よくUV−LEDもしくは青色LEDの何れのものにも対応でき、また、複数種類のLEDを用いることもできる。   The LED 13 can efficiently correspond to either a UV-LED or a blue LED by selecting an activator when the light transmitting body 11 is initially fired, and a plurality of types of LEDs can also be used.

LED構造体において、LED13と光透過体11の位置関係は特に限定はないが、複数のLED13とLED13との間隔はLED13の光照射面の2の断面の幅の5倍以上の間隔をあけて配置され、LED13の発光している点とLED13の発光している点とのあいだの光透過体11によって点光源が光拡散効果によって面発光できることになり、「LEDから距離が離れても照度が落ちない」、「LEDの照射方向から角度的にずれても照度が落ちない」という本発明の効果が得るのである。   In the LED structure, the positional relationship between the LED 13 and the light transmitting body 11 is not particularly limited, but the interval between the plurality of LEDs 13 and the LED 13 is at least 5 times the width of the cross section of the light irradiation surface of the LED 13. The point light source can be surface-emitted by the light diffusing effect by the light transmissive body 11 between the point where the LED 13 emits light and the point where the LED 13 emits light. The effect of the present invention is obtained such that “the illumination does not fall” and “the illuminance does not fall even if it is angularly shifted from the irradiation direction of the LED”.

LED13の発光強度は4付近にあり光透過体11と複数のLED13のあいだを図2より図4にした場合より効果が表れる、発光強度の最大値は4にあるためLED同士のあいだに溝を作り溝の深さをLEDの基板面9よりp電極面の厚さの3倍以上の溝を作った16の場合、LED13を14に配置した場合より効果が得れる。   The light emission intensity of the LED 13 is in the vicinity of 4 and is more effective than the case where the light transmission body 11 and the plurality of LEDs 13 are changed from FIG. 2 to FIG. 4. The maximum value of the light emission intensity is 4, so a groove is formed between the LEDs. In the case of 16 in which the depth of the groove to be formed is not less than 3 times the thickness of the p-electrode surface from the substrate surface 9 of the LED, an effect can be obtained more than when the LED 13 is arranged at 14.

本発明の照明装置の形状は特に限定はなく、平面状のもで、平たい(高さの極低い)円柱状、角柱状等何れでもよい。 The shape of the lighting device of the present invention is not particularly limited, and may be any of a flat shape, a flat shape (very low height), a prism shape, and the like.

以下に、実施例及び比較例を挙げて本発明を更に具体的に説明するが、本発明は、その要旨を超えない限りこれらの実施例に限定されるものではない。   EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples and comparative examples. However, the present invention is not limited to these examples unless it exceeds the gist.

実施例1
汎用の照明装置40型蛍光灯具と、同じ輝度を有するため、図4で示したような配置で、31個のLED13を14のアルミ基板上に均一に並置した。LED13としては、1ミリ角の350mAチップ青色LEDを217mAの電流で使用した。すなわち、1ミリ角のLED13を5ミリ間隔に直列に取り付け、それを光拡散効果を有する光透過体11で包囲し、定電流回路と整流ダイオードを介して商用電源に接続できるようにボンディングワイアー等で電気的に配線をした。消費電力は同じ形状の照明装置の約1/2であった。また、寿命は10倍以上あるはずである。
Example 1
Since it has the same luminance as that of a general-purpose lighting device 40 type fluorescent lamp, 31 LEDs 13 were uniformly arranged on 14 aluminum substrates in the arrangement as shown in FIG. As the LED 13, a 1 mm square 350 mA chip blue LED was used at a current of 217 mA. That is, 1 mm square LEDs 13 are mounted in series at 5 mm intervals, surrounded by a light transmissive body 11 having a light diffusion effect, and bonded to a commercial power source via a constant current circuit and a rectifier diode. Wiring was done electrically. The power consumption was about ½ of the illumination device of the same shape. Moreover, the lifetime should be 10 times or more.

光拡散効果を有する光透過体11としての拡散剤は第1の加熱材料(ZnS:Mn,Ag)として以下に準備される、塩化物を含む適当な量の硫化亜鉛(ZnS-Ag)、主要な活性剤として(ZnSとの重量比で)の0.1%の硫酸マンガン(MnSO4)と、0,015%の塩化ハフニウムHfCl、0.5%の酸化亜鉛(ZnO)、3%の塩化バリウム(BaCl2)、3%の塩化マグネシウム(MgCl2)、0.012%の塩化イリジウム(IrCl)、0.02%の硫酸銀(Ag2SO)と0.37%の酸化ガリウムGa、28%の硫黄及び2%の塩化ナトリウムと一緒に混ぜ合わされる。
混ぜ合わされた材料は高温反応炉において1250℃で2時間加熱される。
The diffusing agent as the light transmitting body 11 having a light diffusing effect is prepared as follows as a first heating material (ZnS: Mn, Ag), an appropriate amount of zinc sulfide containing chloride (ZnS-Ag), main Activators (by weight with ZnS) 0.1% manganese sulfate (MnSO 4 ), 0.015% hafnium chloride HfCl 4 , 0.5% zinc oxide (ZnO), 3% Barium chloride (BaCl 2 ), 3% magnesium chloride (MgCl 2 ), 0.012% iridium chloride (IrCl), 0.02% silver sulfate (Ag 2 SO 4 ) and 0.37% gallium oxide Ga Mixed with 2 O 3 , 28% sulfur and 2% sodium chloride.
The mixed material is heated at 1250 ° C. for 2 hours in a high temperature reactor.

第2段階焼成物質は第1の加熱反応された焼成物質に1%の硫酸亜鉛ZnSO・7HO、と0.5%の塩化バリウム(BaCl2)、と1.5%の塩化ナトリウムと2%の塩化マグネシウム(MgCl2)、と3%の硫酸マンガン(MnSO)と0.5%のガリウムGa、と2.5%の硫黄とを添加して、アルミナ坩堝に装填し、アルミナの蓋で覆い、窒素気流中730℃で8時間30分熱して立方晶系の結晶が得られる。
このステップは残りの6方結晶ZnSを立法結晶ZnSに変え、立法結晶ZnSは大部分は活性光拡散材料である。灼熱した後、蓋付きのるつぼは加熱炉から取り除かれて室温まで冷却され、材料は一緒に混合されて脱イオン(DI)水を用いて洗浄された。2つ又は3つのDI水が洗浄した後、未反応のZnO及びいくらかの取り入れられていない酸化銅を除去するために、材料は酢酸で洗浄された。酸で洗浄された材料は、少なくとも2回、DI水で再度洗浄され、次に残滓の大部分を光拡散材料から除去するためにKCNで再度洗浄される。洗浄の後、光拡散粒子はKCN洗浄の前に光拡散粒子が有したダークグレイの実体色から明るい実体色に変化する。
The second stage calcination material comprises a first heat-reacted calcination material, 1% zinc sulfate ZnSO 4 .7H 2 O, 0.5% barium chloride (BaCl 2 ), and 1.5% sodium chloride. Add 2% magnesium chloride (MgCl 2 ), 3% manganese sulfate (MnSO 4 ), 0.5% gallium Ga 2 O 3 , and 2.5% sulfur and load into an alumina crucible. Then, it is covered with an alumina lid and heated in a nitrogen stream at 730 ° C. for 8 hours 30 minutes to obtain cubic crystals.
This step converts the remaining hexagonal crystal ZnS to cubic crystal ZnS, which is mostly active light diffusing material. After heating, the covered crucible was removed from the furnace and cooled to room temperature, and the materials were mixed together and washed with deionized (DI) water. After 2 or 3 DI water was washed, the material was washed with acetic acid to remove unreacted ZnO and some unincorporated copper oxide. The acid washed material is washed again at least twice with DI water and then again with KCN to remove most of the residue from the light diffusing material. After washing, the light diffusing particles change from a dark gray solid color that the light diffusing particles had to a light solid color before the KCN washing.

このようにして光拡散粒子は分級粉砕し20ミクロンから40ミクロンの粒子と乾燥後分級粉砕し粒子を概略一定にされ、透明バインダーとしての熱硬化型シリコン樹脂と混合され光透過体として実用化に供される。混合比率は8%から10%程度の活性化された光拡散粒子とバインダーの混合物として光透過体となる。   In this way, the light diffusing particles are classified and pulverized, and after being dried and classified and pulverized, the particles are made substantially constant, and mixed with a thermosetting silicone resin as a transparent binder to be put into practical use as a light transmitting body. Provided. The mixing ratio is about 8% to 10%, and becomes a light transmitting body as a mixture of activated light diffusing particles and a binder.

図5において、実施例1で得られた照明装置の中央21から、光の照射される方向に1mの距離を隔てて存在する17上の照度を測定した。上記照明装置から直角に伸びた直線17が該平面角が90°の地点の照度を測定した。
また、照明装置の17から20よりに10度きざみに18の方向に10度まで測定した。
輝度の測定は、トプコン製輝度計を使用して行った。
In FIG. 5, the illuminance on 17 existing at a distance of 1 m in the direction of light irradiation was measured from the center 21 of the lighting device obtained in Example 1. The illuminance was measured at a point where the straight line 17 extending perpendicularly from the lighting device had a plane angle of 90 °.
Moreover, it measured to 10 degree | times in the direction of 18 in 10 degree increments from 17-20 of the illuminating device.
The luminance was measured using a Topcon luminance meter.

比較例1
実施例1において、光透過体11を15にした以外は実施例1と同様にして照明装置を得た。すなわち、光拡散効果を持つ光透過体を使用せず透明バインダーを使用した以外は実施例1と同様にして照明装置を得て、同様に照度を測定した。結果を表3に示す。
Comparative Example 1
In Example 1, an illuminating device was obtained in the same manner as in Example 1 except that the light transmitting body 11 was changed to 15. That is, an illuminating device was obtained in the same manner as in Example 1 except that a transparent binder was used without using a light transmissive material having a light diffusion effect, and the illuminance was measured in the same manner. The results are shown in Table 3.

表1に各地点の照度を示す。全ての表中の単位は「cd/m2」である。また、表1に、輝度が図5のどの角度であるかを示した。表1中の条件は、条件Aは図3の光透過体を使用しない場合、条件Bは光拡散効果を持つ光透過体を使用し図4のLED間の基板16の溝をつけた状態、条件Cは図2のLED間の基板16の溝のない平面の状態。
Table 1 shows the illuminance at each point. The unit in all tables is “cd / m 2”. Table 1 shows which angle the luminance is in FIG. The conditions in Table 1 are as follows: Condition A does not use the light transmitting body of FIG. 3, Condition B uses a light transmitting body having a light diffusing effect, and the groove of the substrate 16 between the LEDs of FIG. Condition C is a planar state without a groove in the substrate 16 between the LEDs in FIG.

表2に表1をグラフにし縦軸に輝度(cd/m2)、横軸に図5の発光面21より1mの間隔と面に鉛直を90度、発光面に平行に1mの間隔を持たせた0までの折れ線グラフで、光拡散効果を持たない光透過体を使用した条件Aに比較し図4の条件Bが視野角、輝度ともに優れた結果である、また、条件CはLED間の基板16の溝をつけた状態に比較し輝度が劣ることはn−p接合面の発光をLED間の基板16の溝をつけたことの効果と考える。
Table 2 is a graph of Table 1. The vertical axis represents luminance (cd / m2), the horizontal axis represents 1 m from the light emitting surface 21 in FIG. 5, the surface is 90 degrees vertical, and the space 1 m parallel to the light emitting surface. 4 is a line graph up to 0. Condition B in FIG. 4 is superior in both viewing angle and luminance as compared to condition A using a light transmissive material having no light diffusion effect. The fact that the luminance is inferior compared with the state in which the groove of the substrate 16 is provided is considered to be due to the effect of providing the groove of the substrate 16 between the LEDs on the np junction surface.

本発明のLEDを用いた照明装置は、発熱が少なく、電力消費量が少ない、寿命が長い等のLEDの特長をそのまま保持しつつ、LEDから離れても照度が落ちない、LEDの照射方向から角度的にずれても照度が落ちないという、LEDを用いた照明装置の欠点が解消されているため、汎用の照明装置に取って代わるものであるのみならず、面発光の面照明装置で厚み方向は3mmないし5mmと薄く製造可能で、照明が用いられるあらゆる分野に広く利用されるものである。   The illumination device using the LED of the present invention retains the features of the LED such as low heat generation, low power consumption, long life, etc., and the illumination intensity does not decrease even if it is away from the LED. Since the disadvantage of the illumination device using LEDs that the illuminance does not decrease even if the angle is shifted, it is not only a substitute for a general-purpose illumination device, but also a surface emitting device with surface emission. The direction can be as thin as 3 mm to 5 mm, and is widely used in all fields where illumination is used.

本発明の照明装置に用いられる一般的なLEDの断面図の例である。It is an example of sectional drawing of common LED used for the illuminating device of this invention. 本発明の「光拡散効果を持つ光透過体」とLEDの位置関係の一例について示す模式図である。It is a schematic diagram shown about an example of the positional relationship of "light-transmitting body with a light-diffusion effect" of this invention, and LED. 「一般的な光透過体」とLEDの位置関係の一例について示す模式図である。It is a schematic diagram shown about an example of the positional relationship of a "general light transmissive body" and LED. 本発明の「光拡散効果を持つ光透過体」とLEDの位置関係のより効果的な一例について示す模式図である。It is a schematic diagram shown about a more effective example of the positional relationship of "the light transmissive body with a light-diffusion effect" of this invention, and LED. 図2、図3、図4の照射面を測定する角度と輝度測定位置の場所を示す図である。It is a figure which shows the place which measures the angle and brightness | luminance measurement position which measure the irradiation surface of FIG.2, FIG.3, FIG.4.

1 p電極
2 p層
3 p層
4 pn接合層
5 n層
6 n層
7 n電極
8 バッファ層
9 サファイア基板など
10 波長変換層(イットリウム等蛍光層)
11 光拡散効果を持つ光透過体
12 ボンディングワイアー(電極間接続)
13 LED
14 LED構造体取り付け基板
15 一般的な光透過体
16 光屈折体の実質的焦点距離
17 発光面から90度の方向
18 発光面方向に40度の角度
19 発光面より1mの地点
20 平面照明装置(照明板)発光面
21 測定ポイント
1 p-electrode 2 p-layer 3 p-layer 4 pn junction layer 5 n-layer 6 n-layer 7 n-electrode 8 buffer layer 9 sapphire substrate, etc. 10 wavelength conversion layer (fluorescent layer such as yttrium)
11 Light Transmitter with Light Diffusing Effect 12 Bonding Wire (interelectrode connection)
13 LED
DESCRIPTION OF SYMBOLS 14 LED structure mounting board 15 General light transmissive body 16 Substantive focal length of photorefractive body 17 Direction of 90 degrees from light emitting surface 18 Angle of 40 degrees to light emitting surface 19 Point 1 m from light emitting surface 20 Flat illumination device (Lighting plate) Light emitting surface 21 Measurement points

Claims (2)

所定の基板上に並置された複数のLED構造体を包囲する硫化亜鉛化合物(ZnS−Ag)を拡散配置した光透過体を有する面発光を行う照明装置に利用される光透過体を生成する方法であって、
塩化物を含む硫化亜鉛と、主要な活性剤としての0.1%の硫酸マンガンと、0.015%の塩化ハフニウムと、0.5%の酸化亜鉛と、3%の塩化バリウムと、3%の塩化マグネシウムと、0.012%の塩化イリジウムと、0.02%の硫酸銀と、0.37%の酸化ガリウムと、28%の硫黄と、2%の塩化ナトリウムと、を混合して、当該混合物を1250℃で2時間加熱した後、焼成物から残留フラックスを水洗により除去して、乾燥後、分級粉砕して粒子を一定にし、
当該一定にした粒子に、1%の硫化亜鉛と、0.5%の塩化バリウムと、1.5%の塩化ナトリウムと、2%の塩化マグネシウムと、3%の硫酸マンガンと、0.5%のガリウムと、2.5%の硫黄と、を加えて、窒素気流中730℃で8時間30分熱した後再度分級粉砕し、脱イオン水で洗浄した後、酢酸で洗浄して、再度脱イオン水で洗浄した後、さらにKCNで洗浄することで活性化した粒子を生成し、
前記活性化した粒子と熱硬化型シリコンとを、混合比率が8%から10%になるように混合する、
光透過体生成方法。
Method for generating a light transmitting body used for a surface emitting device having a light transmitting body having a light transmitting body in which a zinc sulfide compound (ZnS-Ag) is diffused and arranged to surround a plurality of LED structures juxtaposed on a predetermined substrate Because
Zinc sulfide containing chloride, 0.1% manganese sulfate as the main activator, 0.015% hafnium chloride, 0.5% zinc oxide , 3% barium chloride, 3% Of magnesium chloride, 0.012% iridium chloride, 0.02% silver sulfate, 0.37% gallium oxide, 28% sulfur, and 2% sodium chloride, After heating the mixture at 1250 ° C. for 2 hours, the residual flux is removed from the fired product by washing with water, dried, classified and ground to make the particles constant,
The constant particles include 1% zinc sulfide, 0.5% barium chloride, 1.5% sodium chloride, 2% magnesium chloride, 3% manganese sulfate, 0.5% Gallium and 2.5% sulfur were added, heated in a nitrogen stream at 730 ° C. for 8 hours and 30 minutes, classified and ground again, washed with deionized water, washed with acetic acid, and degassed again. After washing with ionic water, further washing with KCN produces activated particles,
The activated particles and thermosetting silicon are mixed so that the mixing ratio is 8% to 10%.
Light transmitting body generation method.
所定の基板上に並置された複数のLED構造体と、これら複数のLED構造体を包囲する硫化亜鉛化合物(ZnS−Ag)を拡散配置した光透過体を有する面発光を行う照明装置であって、
前記光透過体は、フラックスとしての塩化物を含む硫化亜鉛と、主要な活性剤としての0.1%の硫酸マンガンと、0.015%の塩化ハフニウムと、0.5%の酸化亜鉛と、3%の塩化バリウムと、3%の塩化マグネシウムと、0.012%の塩化イリジウムと、0.02%の硫酸銀と、0.37%の酸化ガリウムと、28%の硫黄と、2%の塩化ナトリウムと、を混合して、1250℃で2時間加熱した後、焼成物から残留フラックスを水洗により除去して、乾燥後、分級粉砕することで粒子を一定にし、当該一定にした粒子に、1%の硫化亜鉛と、0.5%の塩化バリウムと、1.5%の塩化ナトリウムと、2%の塩化マグネシウムと、3%の硫酸マンガンと、0.5%のガリウムと、2.5%の硫黄と、を加えて、窒素気流中730℃で8時間30分熱した後再度分級粉砕し、脱イオン水で洗浄した後、酢酸で洗浄して、再度脱イオン水で洗浄した後、さらにKCNで洗浄することで生成した、活性化した粒子と、熱硬化型シリコン樹脂と、を混合比率が8%から10%になるように混合した混合物である、
照明装置。
An illumination device that performs surface light emission having a plurality of LED structures juxtaposed on a predetermined substrate and a light transmitting body in which a zinc sulfide compound (ZnS-Ag) surrounding the plurality of LED structures is diffused. ,
The light transmissive body includes zinc sulfide containing chloride as a flux, 0.1% manganese sulfate as a main activator, 0.015% hafnium chloride, 0.5% zinc oxide , 3% barium chloride, 3% magnesium chloride, 0.012% iridium chloride, 0.02% silver sulfate, 0.37% gallium oxide, 28% sulfur, 2% After mixing with sodium chloride and heating at 1250 ° C. for 2 hours, the residual flux is removed from the fired product by washing with water, dried and then classified and pulverized to make the particles constant. 1% zinc sulfide, 0.5% barium chloride, 1.5% sodium chloride, 2% magnesium chloride, 3% manganese sulfate, 0.5% gallium, 2.5 % Of sulfur and 730 in a nitrogen stream Activated particles produced by heating for 8 hours 30 minutes, classification and grinding again, washing with deionized water, washing with acetic acid, washing again with deionized water, and further washing with KCN And a thermosetting silicone resin, so that the mixing ratio is 8% to 10%.
Lighting device.
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