JP5684686B2 - Hair dye composition - Google Patents
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本発明はヘナを用いた染毛用組成物に関し、特に染毛後に安定した仕上がり色を発色させることのできるようにした組成物に関する。 The present invention relates to a hair dyeing composition using henna, and more particularly to a composition capable of developing a stable finished color after hair dyeing.
染毛用組成物には、染毛力に優れるとともに、多彩な色調を表現できるため、合成染料であるｐ−フェニレンジアミン系やアミノフェノール系の酸化染料が染料成分として広く用いられていた。しかし、この種の酸化染料は皮膚障害が懸念され、又生態系に悪影響を及ぼす環境ホルモンであること、及び発がん性やアレルギー誘発性が懸念されることが指摘されている。 Synthetic dyes such as p-phenylenediamine-based and aminophenol-based oxidative dyes have been widely used as dye components because the hair-dyeing composition has excellent hair dyeing power and can express various color tones. However, it has been pointed out that this type of oxidation dye is concerned about skin damage, is an environmental hormone that adversely affects the ecosystem, and is concerned about carcinogenicity and allergenicity.
他方、安全性が高いとされるＨＣ染料や塩基性染料等の直接染料も用いられている。直接染料を用いた染毛剤は、中性域での染毛が可能であることから、アルカリによる毛髪の損傷がなく、又過酸化水素などの酸化剤が不要であるため、皮膚刺激や目に入ることによって引き起こされる事故のおそれがなく、酸化染料を用いた染毛剤に比較して比較的安全性の高い染毛剤とされている。 On the other hand, direct dyes such as HC dyes and basic dyes that are considered to be highly safe are also used. Hair dyes using direct dyes can be dyed in the neutral range, so there is no damage to the hair due to alkali, and no oxidants such as hydrogen peroxide are needed. There is no fear of an accident caused by entering the hair dye, and it is a relatively safe hair dye compared to a hair dye using an oxidative dye.
例えば、ＨＣ染料や塩基性染料は、化学反応を起こすことなく毛髪に染着するため、繰り返し染毛しても毛髪のダメージが少ない。しかし、その染色効果は持続性に乏しく、シャンプーを繰り返すことなどにより色落ちしやすい。 For example, since HC dyes and basic dyes are dyed on the hair without causing a chemical reaction, even if the hair is repeatedly dyed, there is little damage to the hair. However, the dyeing effect is poor in sustainability, and color fading easily occurs by repeating shampooing.
最近、ヘナが染料として注目されている。ヘナは有効成分として2-ヒドロキシ-1, 4-ナフトキノンを含み、インドやイランなどの熱帯地方に産するミソハギ科の潅木であるＬａｗｓｏｎｉａｉｎｅｒｍｉｓの葉を乾燥し粉砕して得られるオレンジからブラウン系の天然染料である。 Recently, henna has attracted attention as a dye. Henna contains 2-hydroxy-1,4-naphthoquinone as an active ingredient, and is a natural orange-brown system that is obtained by drying and pulverizing the leaves of Lawsoniainermis, which is a shrub of the family Lamiaceae produced in tropical regions such as India and Iran. It is a dye.
例えば、ヘナ粉末とヘナ抽出液の一方又は両方を１〜４０重量％含有し、水分、油分、活性剤、トリートメント剤、ＨＣ染料、塩基性染料を含有するクリーム状の染毛剤組成物が提案されている（特許文献１）。 For example, a creamy hair dye composition containing 1 to 40% by weight of henna powder and / or henna extract and containing moisture, oil, activator, treatment agent, HC dye, and basic dye is proposed. (Patent Document 1).
また、ヘナ粉末２０〜９０重量％、インド藍の葉の乾燥粉末８０〜２０重量％を配合し、水と混練してペースト状にして使用するようにした染毛剤が提案されている（特許文献２）。 In addition, a hair dye is proposed in which 20 to 90% by weight of henna powder and 80 to 20% by weight of dry powder of Indian indigo leaves are mixed and kneaded with water to be used as a paste (patent). Reference 2).
ヘナ粉末を主成分とする染毛剤では、染毛剤のペーストを毛髪に塗布し、３０°Ｃ〜３５°Ｃ程度の温度で１０〜３０分間程度加温するか、キャップをかぶせて水分の蒸発を防ぎながら１時間程度保持した後、シャンプーし、ドライヤーで乾燥させるようにしているが、安定した発色までに時間がかかり、染毛後数日経過しないと、安定した仕上がり色を確認できない。 For hair dyes based on henna powder, apply a hair dye paste to the hair and heat it at a temperature of about 30 ° C. to 35 ° C. for about 10 to 30 minutes, or cover it with a cap to remove moisture. After holding for about 1 hour while preventing evaporation, it is shampooed and dried with a dryer. However, it takes time until stable color development, and a stable finished color cannot be confirmed until several days have passed after hair dyeing.
本発明はかかる問題点に鑑み、ヘナを用いた染毛において染毛後直ちに安定した仕上がり色を発色させることのできるようにした染毛用組成物を提供することを課題とする。 In view of such problems, an object of the present invention is to provide a hair dyeing composition capable of developing a stable finished color immediately after hair dyeing in a hair dye using henna.
そこで、本発明に係る染毛用組成物は、ヘナ粉末１００重量部に対し、表面にリン酸カルシウム微粒子及びシルク微粒子を吸着させた二酸化チタン粉末０．００７５重量部〜０．０１５重量部を配合したことを特徴とする。 Therefore, the hair dye composition according to the present invention was blended with 0.0075 parts by weight to 0.015 parts by weight of titanium dioxide powder having calcium phosphate fine particles and silk fine particles adsorbed on the surface to 100 parts by weight of henna powder. It is characterized by.
本発明の特徴の１つは表面にリン酸カルシウム微粒子及びシルク微粒子を吸着させた二酸化チタン粉末をヘナ粉末に配合するようにした点にある。 One of the characteristics of the present invention is that titanium dioxide powder having calcium phosphate fine particles and silk fine particles adsorbed on the surface is mixed with henna powder.
リン酸カルシウム微粒子及びシルク微粒子を吸着させた二酸化チタン粉末は、可視光、特に４５０ｎｍ以上の波長の光で光触媒反応を呈し、この二酸化チタン粉末は微量であっても可視光の光触媒反応によって毛髪に超親水性（非常に強い親水性）を付与することができる。ヘナの主成分であるポリフェノール類は毛髪表面の超親水性によって毛髪内部に迅速に浸透して毛髪組織に結合するとともに、仕上がり色を呈するので、染毛後直ちに安定した仕上がり色を発色させることができる。 Titanium dioxide powder with adsorbed calcium phosphate fine particles and silk fine particles exhibits a photocatalytic reaction with visible light, particularly light with a wavelength of 450 nm or more, and this titanium dioxide powder is superhydrophilic to the hair by visible light photocatalytic reaction even with a small amount. (Very strong hydrophilicity) can be imparted. Polyphenols, which are the main components of henna, penetrate rapidly into the hair due to the superhydrophilicity of the hair surface and bind to the hair tissue and exhibit a finished color, so that a stable finished color can be developed immediately after dyeing. it can.
リン酸カルシウム微粒子の量は二酸化チタン１００重量部に対して１重量部〜２５重量部、シルク微粒子の量は二酸化チタン１００重量部に対して０．１重量部〜２．５重量部の範囲内の量とする。シルク微粒子はリン酸カルシウムが二酸化チタン表面で結晶化しながら吸着されるのを促進する働きがあるとされている。 The amount of calcium phosphate fine particles is 1 to 25 parts by weight with respect to 100 parts by weight of titanium dioxide, and the amount of silk fine particles is within the range of 0.1 to 2.5 parts by weight with respect to 100 parts by weight of titanium dioxide. And Silk fine particles are said to have a function of promoting adsorption of calcium phosphate while crystallizing on the surface of titanium dioxide.
ここで、ヘナ粉末１００質量部に対し、表面にリン酸カルシウム微粒子及びシルク微粒子を吸着させた二酸化チタン粉末を０．００７５重量部〜０．０１５重量部としたのは、００７５重量部満では親水性が十分に付与されず、０．０１５重量部を超えても親水性がそれ以上強くならず、無駄になるからである。 Here, with respect to 100 parts by mass of henna powder, the titanium dioxide powder having calcium phosphate fine particles and silk fine particles adsorbed on the surface was made 0.0075 parts by weight to 0.015 parts by weight. This is because it is not sufficiently imparted, and even if it exceeds 0.015 part by weight, the hydrophilicity is not increased any more and is wasted.
本発明に係る染毛用組成物には種々な色に発色させる染料、例えば天然インディゴ、ウコン、クルミ殻粒、茶葉、バラ、柿葉、コーヒー種子、レモン果皮、ＨＣ染料の１つ又は２つ以上を用いてもよく、染毛直後に安定した仕上がり色を発色させることができる。これらの染料はヘナの主成分であるポリフェノール類によって毛髪に固定され、発色が安定し、色落ちしにくくなるものと考えられる。 The hair dye composition according to the present invention has dyes for developing various colors, such as natural indigo, turmeric, walnut shell, tea leaves, roses, persimmon leaves, coffee seeds, lemon peels, HC dyes, or two of them. The above may be used, and a stable finished color can be developed immediately after hair dyeing. These dyes are considered to be fixed to the hair by polyphenols, which are the main components of henna, to stabilize the color development and make it difficult to lose color.
さらに、毛髪の保水性を高めるために、セチルＰＧヒドロキシエチルパルミタミドを、毛髪の染料に対する親和性を高めるために、加水分解ケラチンを配合するようにしてもよい。 Furthermore, cetyl PG hydroxyethyl palmitamide may be added to increase the water retention of hair, and hydrolyzed keratin may be added to increase the affinity for hair dyes.
本発明に係る染毛用組成物を用いる場合、適量の水又は７０°Ｃ程度の温水を加えてペースト状に混練し、ペーストを毛髪に塗布し、毛髪表面温度が３５°Ｃ〜４０°Ｃ程度になるように加温して１０分〜２０分間維持し、洗髪して毛髪に付着した余分なペーストを洗い流し、毛髪を乾燥することによって染毛を行うことができる。 When the hair dye composition according to the present invention is used, an appropriate amount of water or warm water of about 70 ° C. is added and kneaded into a paste, the paste is applied to the hair, and the hair surface temperature is 35 ° C. to 40 ° C. The hair can be dyed by heating it to the extent that it is maintained for 10 to 20 minutes, washing the hair to wash away the excess paste adhering to the hair, and drying the hair.
また、毛髪を乾燥させた後、毛髪に表面温度１５０〜２００℃に制御したアイロンプレスによりプレス処理するようにしてもよい。アイロンプレスにより、高温及び高圧で処理するためにヘナ中の染料成分を安定にすることができ、繰り返しシャンプーした場合にも色落ちがほとんどない。 Moreover, after drying hair, you may make it press-process with the iron press controlled to surface temperature 150-200 degreeC to hair. The iron press can stabilize the dye component in the henna for processing at high temperature and high pressure, and there is almost no discoloration even after repeated shampooing.
以下、本発明に係る染毛用組成物を実施例に基づいて詳細に説明する。 Hereinafter, the hair dye composition according to the present invention will be described in detail based on examples.
ヘナ粉末（近代化学社製：商品名彩輝ヘナ）１０００ｋｇに、表面にリン酸カルシウム微粒子及びシルク微粒子を吸着させた二酸化チタン粉末（環境保全研究所社製：商品名トリニティ）１５０ｇを配合して染毛用組成物を調製した。
この染毛用組成物を７０°Ｃ前後の温水（又は水）でペースト状に混練し、室温まで冷えたペーストを毛髪（白髪）に塗布し、毛髪表面温度が３５°Ｃ〜４０°Ｃになるように加温して１０〜２０分間保持し、洗髪して毛髪に付着した余分なペーストを洗い流し、毛髪を乾燥することによって染毛を行ったところ、白髪全体を仕上がり色であるナチュラルオレンジ色に染毛できた。また、染毛後、繰り返しシャンプーを行っても、色落ちはほとんど起きなかった。
Hair dye by blending 1000g of henna powder (made by Modern Chemical Co., Ltd., trade name: Akiraki Henna) with 150g titanium dioxide powder (trade name: Trinity made by Environmental Conservation Laboratories, Inc.) with calcium phosphate fine particles and silk fine particles adsorbed on the surface. A composition was prepared.
This hair dyeing composition is kneaded into a paste with warm water (or water) at around 70 ° C., and the paste cooled to room temperature is applied to the hair (white hair) so that the hair surface temperature is 35 ° C. to 40 ° C. After warming up and holding for 10 to 20 minutes, washing the hair to wash away the excess paste attached to the hair and drying the hair, the whole white hair is finished in natural orange color I was able to dye my hair. Moreover, even after repeated shampooing after dyeing, color fading hardly occurred.
表面にリン酸カルシウム微粒子及びシルク微粒子を吸着させた二酸化チタン粉末を１００ｇとした以外、実施例１と同様に染毛用組成物を調製し、この組成物を水又は温水でペースト状に混練して白髪の染毛を行ったところ、ナチュラルオレンジ色に染毛でき、この仕上がり色は安定していた。 A hair coloring composition was prepared in the same manner as in Example 1 except that 100 g of titanium dioxide powder on which calcium phosphate fine particles and silk fine particles were adsorbed on the surface, and this composition was kneaded into a paste with water or warm water to make white hair After dyeing the hair, it was possible to dye it in a natural orange color, and this finished color was stable.
表面にリン酸カルシウム微粒子及びシルク微粒子を吸着させた二酸化チタン粉末を７５ｇとした以外、実施例１と同様に染毛用組成物を調製し、この組成物を水又は温水でペースト状に混練して染毛を行ったところ、白髪全体を仕上がり色であるナチュラルオレンジ色に染毛できた。 A hair dye composition was prepared in the same manner as in Example 1 except that 75 g of titanium dioxide powder having calcium phosphate fine particles and silk fine particles adsorbed on the surface thereof, and this composition was kneaded into a paste with water or warm water. When the hair was applied, the entire gray hair was dyed to a natural orange color.
加水分解ケラチン０．１ｇ、セチルＰＧヒドロキシエチルパルミタミド０．１ｇを更に配合した以外、実施例１と同様にして染毛用組成物を調製し、この組成物を水又は温水でペースト状に混練して染毛を行ったところ、白髪全体を仕上がり色であるナチュラルオレンジ色に安定に染毛できただけではなく、毛髪全体がしっとりと潤い、しかも毛髪のボリュームをだすことができた。 A hair dyeing composition was prepared in the same manner as in Example 1 except that 0.1 g of hydrolyzed keratin and 0.1 g of cetyl PG hydroxyethyl palmitamide were further blended, and this composition was made into a paste with water or warm water As a result of kneading and dyeing, not only was it possible to stably dye the entire gray hair to the natural orange color that was the finished color, but the entire hair was moist and moisturized, and the volume of the hair could be increased.
実施例１〜３記載の染毛用組成物に、ホソバタイセイ葉、茶葉、ブッソウケ花、アンマクロ果実、アカシアコンシナ果実、加水分解ケラチン、セチルＰＧヒドロキシエチルパルミタミド、ＨＣ青２、ＨＣ黄色４、ＨＣ赤３を適量配合して染毛用組成物を調製した。
この染毛用組成物を水又は温水でペースト状に混練し、ペーストを用いて染毛を行ったところ、チョコブラウン色、オリーブブラウン色、チェリーレッド色、アプリコット色（但し、この場合はＨＣ青２を使用していない）に安定に発色させることができた。
The composition for hair dyeing described in Examples 1 to 3 was added to the flower of Japanese butterfly, tea leaves, bushusuke flowers, anmacros fruit, acacia consina fruit, hydrolyzed keratin, cetyl PG hydroxyethyl palmitamide, HC blue 2, HC yellow 4 An appropriate amount of HC Red 3 was blended to prepare a hair dye composition.
When this hair dyeing composition was kneaded into a paste with water or warm water and dyed with the paste, it was chocolate brown, olive brown, cherry red, apricot (however, in this case HC blue 2 was not used).
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| CN108042445B (en) * | 2017-12-05 | 2020-07-28 | 王伟明 | Preparation method and use method of natural anti-allergy nourishing black hair dye |
| CN111728915A (en) * | 2020-08-10 | 2020-10-02 | 黑龙江天龙药业有限公司 | Membrane patch for improving neck wrinkles and preparation method thereof |
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Free format text: JAPANESE INTERMEDIATE CODE: R250 |
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| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
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| LAPS | Cancellation because of no payment of annual fees |