JP5672948B2 - Optical filter and image display device - Google Patents

Description

  The present invention relates to an optical filter and an image display device including the optical filter.

  An image display device that emits an image to an observer includes an image source and an optical filter in which layers having various functions are stacked in order to improve the quality of image light from the image source and emit the image light to the observer. Is provided.

  For example, in a plasma television which is a video display device having a plasma display panel (PDP) as a video source, when the viewer side is bright, the contrast is insufficient and the quality of the provided image may be reduced. On the other hand, a layer for improving contrast may be provided as one layer in the optical filter. Such a layer has a light transmission part capable of transmitting light and a light absorption part capable of absorbing light, and appropriately shields external light by the light absorption part to improve contrast. Here, the contrast means the ratio of the luminance of the white portion (white luminance) that has the maximum luminance when the screen is displayed in black and white and the luminance of the black portion (black luminance) that has the minimum luminance.

  For example, Patent Document 1 includes a filter base, a base made of a transparent resin material formed on one surface of the filter base, and an external light shielding layer having a number of wedge-shaped black stripes arranged in parallel to the one surface of the base. Disclosed is a filter for a display device.

  As can be seen from, for example, FIGS. 3 and 4 of Patent Document 1, the light-incident side surface of the wedge-shaped outside light shielding layer (light absorbing portion) described here is smooth, and the portion through which light is transmitted. It has a flat structure. However, when an external light shielding layer (light absorption part) is to be manufactured more efficiently, there is a technique in which a liquid composition is filled here, the excess composition is scraped off with a blade, and the rest is cured. Often taken. In this case, a concave depression is formed on the surface of the external light shielding layer (light absorbing portion). This occurs because the volume shrinks when the filled composition is cured, or the composition is scraped off by a blade.

  That is, as described in Patent Document 2 and Patent Document 3, the light absorbing portion has a shape in which a depression is generated on the surface.

JP 2006-189867 A JP 2009-80198 A JP 2008-46644 A

  However, when an optical sheet such as that described in Patent Documents 2 and 3 is arranged with the depression of the light absorbing portion facing the viewer to form an image display device, rainbow-like color unevenness occurs on the screen. There was a thing. Such color unevenness needs to be improved from the viewpoint of improving the quality of the image.

  In view of the above problems, it is an object of the present invention to provide an optical filter that can suppress the occurrence of color unevenness and provide a high-quality image. In addition, an image display device using the optical filter is provided.

  The present invention will be described below. In order to facilitate understanding of the present invention, reference numerals in the accompanying drawings are appended in parentheses, but the present invention is not limited to the illustrated embodiment.

  As a result of intensive studies, the inventors have obtained knowledge that chromatic dispersion generated in the depression formed in the light absorbing portion is a cause of the occurrence of color unevenness. Based on this knowledge, the following invention has been completed.

The invention of claim 1 includes a video source (5), said video source (5) an optical filter having a layer of several that will be disposed on the viewer's side of (10), met video display apparatus comprising a The base material layer (11), the optical functional layer (12) laminated on the base material layer, and the pressure-sensitive adhesive layer laminated on the side opposite to the base material layer among the surfaces of the optical functional layer ( 23), and the optical functional layer is arranged in parallel along the sheet surface so as to transmit light, and has a trapezoidal cross section with a short upper base on the viewer side and a long lower base on the image source side. And a light absorption part (14) arranged in parallel so as to be able to absorb light having a trapezoidal cross section disposed between the light transmission parts and having a long lower base on the viewer side and a short upper base on the image source side. and, the light absorbing portion, the lower base directed toward the observer side recessed curved or polygonal line (17) is formed, the light transmission section, the light-absorbing portion And the adhesive layer is a video display device, characterized in that both the refractive index difference is within 0.02.

According to a second aspect of the present invention, in the video display device according to the first aspect , the depth of the recess (17) of the light absorbing portion (14) is not less than 0.5 μm and not more than 6.0 μm. .

According to a third aspect of the present invention, the surface of the base material layer (11) of the video display device according to the first or second aspect of the invention includes an adhesive on the surface opposite to the optical functional layer (12). It is an optical filter in which the adhesive layer (22) is formed.

According to a fourth aspect of the present invention, in the video display device according to any one of the first to third aspects, the outermost layer has an antireflection layer (26) or an antiglare layer.

Invention of Claim 5 is equipped with the wavelength filter layer (24) which has a function which suppresses permeation | transmission of the light of a predetermined | prescribed wavelength in the video display apparatus as described in any one of Claims 1-4. Features.

The invention according to claim 6 is the video display device according to any one of claims 1 to 5, further comprising an electromagnetic wave shielding layer (21) having a function of shielding electromagnetic waves.

  According to the present invention, it is possible to provide an optical filter capable of suppressing color unevenness generated on a screen and a video display device including the optical filter.

It is the figure which showed roughly a part of thickness direction cross section of the optical filter concerning one Embodiment. It is sectional drawing which expanded and showed a part of optical function layer shown in FIG. It is sectional drawing which showed the other example of the light absorption part schematically. 3A is an example in which a triangle is formed, FIG. 3B is an example in which an oblique side is a polygonal line, and FIG. 3C is an example in which an oblique side is a curved line. It is a figure which illustrates schematically a part of process about an example of the manufacturing method of an optical function layer. It is a figure which illustrates schematically another part of process about an example of the manufacturing method of an optical function layer. It is the figure which showed schematically the structure of the video display apparatus concerning one Embodiment. It is the figure which showed schematically the structure of PDP and an optical filter among the video display apparatuses concerning one Embodiment. It is the figure which showed roughly the example of optical paths, such as image light which passes along an optical function layer. It is a figure for demonstrating color unevenness.

  The above-described operation and gain of the present invention will be clarified from embodiments for carrying out the invention described below. Hereinafter, the present invention will be described based on embodiments shown in the drawings. However, the present invention is not limited to these embodiments.

  FIG. 1 is a diagram schematically showing a layer configuration of a part of a cross section in the thickness direction of an optical filter 10 according to one embodiment. As will be described later, the left side of the optical filter 10 is the image source side, and the right side of the optical filter 10 is the observer side. Further, in FIG. 1, for ease of viewing, some of the reference numerals of repeated configurations and configurations not described may be omitted (the same applies to the following drawings).

  The optical filter 10 is a member that is arranged closer to the viewer than the video source, and controls the light incident from the video source to be emitted to the viewer. The optical filter 10 has a plurality of layers, and as shown in FIG. 1, the pressure-sensitive adhesive layer 20, the electromagnetic wave shielding layer 21, the pressure-sensitive adhesive layer 22, the optical sheet 19, the pressure-sensitive adhesive layer 23, and the wavelength filter layer 24. A hard coat layer 25 and an antireflection layer 26. Each layer will be described below. Here, for easy understanding, the optical sheet 19 and the pressure-sensitive adhesive layer 23 will be described first, and then the other layers will be described.

The optical sheet 19 has a base material layer 11 and an optical function layer 12.
The base material layer 11 is a layer that becomes a base material for forming the optical functional layer 12. The base material layer 11 is preferably composed of a material mainly composed of polyethylene terephthalate (PET). When the base material layer 11 has PET as a main component, the base material layer 11 may contain other resins. Various additives may be added as appropriate. Examples of general additives include phenol-based antioxidants, lactone-based stabilizers, and the like. Here, “main component” means that the PET is contained in an amount of 50% by mass or more with respect to the entire material forming the base material layer (hereinafter the same).

However, the main component of the material constituting the base material layer 11 is not necessarily PET, and may be other materials. Examples thereof include polybutylene terephthalate, polyethylene naphthalate, terephthalic acid-isophthalic acid-ethylene glycol copolymer, polyester resins such as terephthalic acid-cyclohexanedimethanol-ethylene glycol copolymer, and polyamide resins such as nylon 6. , Polyolefin resins such as polypropylene and polymethylpentene, acrylic resins such as polymethyl methacrylate, styrene resins such as polystyrene and styrene-acrylonitrile copolymer, cellulose resins such as triacetyl cellulose, imide resins and polycarbonate resins Etc. Moreover, you may add additives, such as a ultraviolet absorber, a filler, a plasticizer, an antistatic agent, in these resins suitably as needed.
In this embodiment, the example which comprises the base material layer 11 with resin which has PET as a main component from viewpoints of mass productivity, a price, availability, etc. was given in addition to performance.

  The optical functional layer 12 is a layer having a function of appropriately absorbing stray light and external light while controlling the optical path of the image light from the image source side. The optical functional layer 12 has a shape that has the cross section shown in FIG. 1 and extends to the back / near side of the drawing. As can be seen from FIG. 1, the optical function layer 12 includes a light transmission portion 13 arranged in parallel in the direction along the sheet surface, and the light absorption portion 14 is disposed between the adjacent light transmission portions 13. In FIG. 2, a part of the optical functional layer 12 is enlarged, and the light absorbing portion 14 and the light transmitting portion 13 adjacent thereto are enlarged. The optical functional layer 12 will be described in detail with reference to FIGS.

  The light transmitting portion 13 is a portion having a function of transmitting image light, has a substantially trapezoidal cross-sectional shape, and has a short upper base and a long lower bottom arranged in a direction along the sheet surface of the optical sheet 19.

  The light transmitting portion 13 has a predetermined refractive index, and such a light transmitting portion 13 can be formed by curing a light transmitting portion constituent composition described below. In addition, although the value of a refractive index is not specifically limited, From a viewpoint of the availability of the material to apply, etc., it is preferable that it is 1.49-1.56.

  As a light transmissive part composition, for example, a photocurable prepolymer (P1), a reactive diluent monomer (M1), a mold release agent (S1), and a photopolymerization initiator (I1) are blended. A resin composition is preferably used.

  Examples of the photocurable prepolymer (P1) include epoxy acrylate-based, urethane acrylate-based, polyether acrylate-based, polyester acrylate-based, and polythiol-based prepolymers.

  Examples of the reactive dilution monomer (M1) include phenoxyethyl acrylate, phenoxytetraethylene glycol acrylate, β-hydroxy acrylate, 2-hydroxyethyl acrylate, 2-ethylhexyl acrylate, tetrahydrofurfuryl acrylate, and o-phenylphenyl. Examples thereof include oxyethyloxyethyl acrylate, methoxytriethylene glycol acrylate, tripropylene glycol diacrylate, bisphenol A tetraethoxy diacrylate, bisphenol A polyethoxy diacrylate, and 1,6-hexanediol diacrylate.

  Examples of the mold release agent (S1) include, for example, a phosphate of tetradecanol ethylene oxide 10 mol adduct / a salt of lauryldimethylamine, a phosphate of tetradecanol ethylene oxide 10 mol adduct / dimethylstearyl. Salt of amine, phosphate ester of lauryl alcohol ethylene oxide 2 mol adduct / salt of ethylene oxide 10 mol adduct of laurylamine, phosphate ester of tetradecanol ethylene oxide 2 mol adduct / salt of ethylene oxide 10 mol adduct of stearylamine And a phosphate ester of stearyl alcohol ethylene oxide 10 mol adduct / a salt of stearylamine 15 mol adduct of stearylamine.

  Examples of the photopolymerization initiator (I1) include hydroxybenzoyl compounds (2-hydroxy-2-methyl-1-phenylpropan-1-one, 1-hydroxycyclohexyl phenyl ketone, benzoin alkyl ether, etc.), benzoyl Formate compounds (such as methylbenzoylformate), thioxanthone compounds (such as isopropylthioxanthone), benzophenones (such as benzophenone), phosphate compounds (1,3,5-trimethylbenzoyldiphenylphosphine oxide, bis (2,4,6-) Trimethylbenzoyl) phenylphosphine oxide and the like, and benzyldimethyl ketal and the like. Of these, 2-hydroxy-2-methyl-1-phenylpropan-1-one, 1-hydroxycyclohexyl phenyl ketone, and bis (2,4) are preferable from the viewpoint of preventing coloring of the light transmitting portions 13, 13,. , 6-trimethylbenzoyl) phenylphosphine oxide. In addition, it is preferable that the said photoinitiator (I1) is contained 0.5 mass% or more and 5.0 mass% or less on the basis (100 mass%) of light transmission part structure composition whole quantity.

  These photocurable prepolymer (P1), reactive diluent monomer (M1), mold release agent (S1), and photopolymerization initiator (I1) are each used alone or in combination of two or more. be able to.

  Further, if necessary, in order to improve the coating film modification and coating suitability in the light transmitting part constituting composition, various additives such as silicone additives, rheology control agents, defoaming agents, antistatic agents, It is also possible to add an ultraviolet absorber or the like.

  Next, the light absorption unit 14 will be described. The light absorption part 14 is an element which is arrange | positioned between the adjacent light transmission parts 13, and has a substantially trapezoidal cross section in the cross section which appears in FIG. 1, FIG. The short upper base of the light absorbing portion 14 is in parallel with the long lower bottom side (base material layer 11 side) of the light transmitting portion 13 and the long lower bottom of the light absorbing portion 14 is parallel to the short upper bottom side of the light transmitting portion 13. Has been. Here, the angle θ (see FIG. 2) formed by the sheet surface normal line and the hypotenuse in the trapezoidal cross section of the light absorbing portion 14 is preferably in the range of greater than 0 degrees and less than or equal to 10 degrees. A more preferable angle is greater than 0 degree and 6 degrees or less.

As can be seen from FIG. 2, the light absorbing portion 14 includes a binder 15 and light absorbing particles 16 contained in the binder 15.
The binder 15 is made of a predetermined material having the same refractive index as that of the light transmitting portion 13. As described above, by making the refractive index of the light transmitting portion 13, the refractive index of the binder 15, and the refractive index layer of the pressure-sensitive adhesive layer 23 described in detail later, uneven color can be suppressed. Details will be described later. Here, the same refractive index means that the refractive index difference is within 0.02.

  Although the substance used as a binder is not specifically limited, Since it is the same refractive index as the light transmissive part 13, the same substance as the light transmissive part 13 may be sufficient. However, it is not always necessary to use the same substance. For example, a photocurable resin composition containing a photocurable prepolymer (P2), a reactive dilution monomer (M2), and a photopolymerization initiator (I2) is preferably used.

  Examples of the photocurable prepolymer (P2) include urethane (meth) acrylate, polyester (meth) acrylate, epoxy (meth) acrylate, and butadiene (meth) acrylate.

  Examples of the reactive dilution monomer (M2) include monofunctional monomers such as N-vinyl pyrrolidone, N-vinyl caprolactone, vinyl imidazole, vinyl pyridine, styrene, and other vinyl monomers, lauryl (meth) acrylate, stearyl ( (Meth) acrylate, butoxyethyl (meth) acrylate, ethoxydiethylene glycol (meth) acrylate, methoxytriethylene glycol (meth) acrylate, methoxypolyethylene glycol (meth) acrylate, methoxydipropylene glycol (meth) acrylate, paracumylphenoxyethyl (meth) ) Acrylate, nonylphenoxy polyethylene glycol (meth) acrylate, tetrahydrofurfuryl (meth) acrylate, isobornyl (meth) a (Meth) acrylic acid ester monomers such as relate, cyclohexyl (meth) acrylate, benzyl methacrylate, N, N-dimethyl (meth) acrylamide, N, N-dimethylaminopropyl (meth) acrylate, acryloylmorpholine, A (meth) acrylamide derivative is mentioned. Polyfunctional monomers include ethylene glycol di (meth) acrylate, diethylene glycol di (meth) acrylate, triethylene glycol di (meth) acrylate, polyethylene glycol di (meth) acrylate, tripropylene glycol di (meth) acrylate, polytetra Methylene glycol di (meth) acrylate, 1,4-butanediol di (meth) acrylate, 1,6-hexanediol di (meth) acrylate, 1,9-nonanediol di (meth) acrylate, 3-methyl-1, 5-pentanediol di (meth) acrylate, neopentyl glycol di (meth) acrylate, dimethylol-tricyclodecane di (meth) acrylate, hydroxypivalate neopentyl glycol di (meth) acrylate Bisphenol A polypropoxydiol di (meth) acrylate, trimethylolpropane tri (meth) acrylate, ethoxylated trimethylolpropane tri (meth) acrylate, propoxylated trimethylolpropane tri (meth) acrylate, pentaerythritol tri (meth) Acrylate, glyceryl tri (meth) acrylate, propoxylated glyceryl tri (meth) acrylate, tris (2-hydroxyethyl) isocyanurate triacrylate, pentaerythritol tetra (meth) acrylate, ditrimethylolpropane tetra (meth) acrylate And dipentaerythritol penta (meth) acrylate, dipentaerythritol hexa (meth) acrylate, and the like.

  Examples of the photopolymerization initiator (I2) include 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenylpropan-1-one, 2,2-dimethoxy-1,2-diphenylethane- Examples include 1-one, 2,4,6-trimethylbenzoyldiphenylphosphine oxide, and bis (2,4,6-trimethylbenzoyl) -phenylphosphine oxide. Among these, the irradiation device for curing the photocurable resin composition and the curability of the photocurable resin composition can be arbitrarily selected. The amount of the photopolymerization initiator (I2) contained in the photocurable resin composition is based on the total amount of the photocurable resin composition (100% by mass) from the viewpoint of curability and cost of the photocurable resin composition. 0.5 mass% or more and 10.0 mass% or less is preferable.

  These photocurable prepolymer (P2), reactive diluent monomer (M2) and photopolymerization initiator (I2) can be used singly or in combination of two or more.

  Specifically, a photopolymerizable component composed of urethane acrylate, epoxy acrylate, tripropylene glycol diacrylate and methoxytriethylene glycol acrylate (specifically, photocurable prepolymer and reactive dilution monomer), refractive index, viscosity, Alternatively, in consideration of the influence on the performance of the optical functional layer 12, etc., it can be arbitrarily mixed and used.

  In addition, you may add silicone, an antifoamer, a leveling agent, a solvent, etc. to a photocurable resin composition as an additive.

  The light absorbing particles 16 are particles having a light absorbing property dispersed in the binder 15. As a result, light (stray light or external light) incident on the binder 15 can be absorbed.

  As the light absorbing particles 16, light absorbing colored particles such as carbon black are preferably used. However, the light absorbing particles 16 are not limited to these, and colored particles that selectively absorb a specific wavelength in accordance with the characteristics of the image light may be used as the light absorbing particles 16. Specific examples include organic fine particles colored with metal salts such as carbon black, graphite, and black iron oxide, dyes, pigments, colored glass beads, and the like. In particular, colored organic fine particles are preferably used from the viewpoints of cost, quality, availability, and the like. More specifically, acrylic cross-linked fine particles containing carbon black, urethane cross-linked fine particles containing carbon black, and the like are preferably used. Such colored particles are usually contained in the above-mentioned photocurable resin composition in the range of 3% by mass to 30% by mass. The average particle diameter of the colored particles is preferably 1.0 μm or more and 20 μm or less. Here, the “average particle diameter” means that obtained by particle size measurement by a mass distribution method. By using colored particles having an average particle size of 1.0 μm or more, when forming the light absorbing portion 14 as described below, the colored particles are not scraped off by the doctor blade, and the light transmitting portion 13 It can prevent remaining on the bottom portion.

  The means for absorbing light is not limited to the method using light absorbing particles as in this embodiment. Alternatively, for example, the entire binder may be colored with a pigment or a dye.

  In the light absorbing portion 14 configured as described above, as can be seen from FIG. 1 and FIG. 2, a surface corresponding to the long lower bottom side of the light absorbing portion 14 (a surface / observer on the side opposite to the base material layer 11) The side surface) is recessed in a curved or broken line shape and has a recess 17. Here, the “dent” means a portion that is depressed with respect to a surface (dashed line II shown in FIG. 2) connecting the upper bottom sides of the light transmitting portion 13. The depth of the recess 17 is preferably 0.5 μm or more and 6.0 μm or less, and more preferably 2.0 μm or more and 4.0 μm or less at the deepest portion. If it is smaller than 0.5 μm, the light absorbing particles remain on the light transmitting portion during filling and scraping of the binder containing the light absorbing particles, and there is a high possibility that defects in appearance will occur. Further, if the depth of the dent is larger than 6.0 μm, the followability to the shape of the pressure-sensitive adhesive laminated here is poor, and a problem of entraining bubbles may occur.

  The depth of the recess 17 is most preferably 0, but as described above, it is often difficult to make the recess 0 in the manufacturing process. On the other hand, in the optical filter 10, the depression is not zero, and even if there is a depression, it is possible to suppress color unevenness. Details will be described later.

In the description so far, the configuration in which the cross-sectional shape of the light absorbing portion is a trapezoid has been described, but the present invention is not limited to such a configuration. A cross section of another embodiment of the light absorbing portion is shown in FIG.
3A shows an example in which the cross-sectional shape of the light absorbing portion 14a is a triangle, FIG. 3B shows an example in which the hypotenuse of the light absorbing portion 14b is a polygonal line, and FIG. 3C shows the light absorbing portion 14c. In this example, the hypotenuse is curved.

  In the example shown in FIG. 3A, the cross-sectional shape of the light absorbing portion 14a is a triangle. Specifically, the above-described light absorbing portion 14 is a triangle having a bottom side (opposite to the base material layer 11) on the bottom side and a vertex facing the bottom side, and a depression is formed on the bottom side. The oblique side of the triangle forms an angle θ1 with respect to the normal line of the light exit surface of the optical sheet. θ1 is preferably in the range of greater than 0 degrees and less than 10 degrees. A more preferable angle is greater than 0 degree and 6 degrees or less.

  In the example shown in FIG. 3B, the hypotenuse (oblique side of the light transmission unit 13b) in the cross section of the light absorption unit 14b is composed of two sides instead of one side. That is, the cross section has a polygonal oblique side. Specifically, the oblique side on the long lower bottom side (right side of the drawing) of the light absorbing portion 14b forms an angle θ2 with respect to the normal line of the light exit surface of the optical sheet. On the other hand, the hypotenuse arranged on the short upper base side (base material layer 11 side / left side of the paper surface) forms an angle θ3 with respect to the normal line of the sheet exit surface of the optical sheet. This angle is in a relation of θ2> θ3, and it is preferable that both of these angles are in the range of 0 ° to 10 °. A more preferable angle is greater than 0 degree and 6 degrees or less. In addition, the example of FIG. 3B is an example in which one is constituted by two oblique sides, but a polygonal line shape may be constituted by more sides.

  In the example shown in FIG. 3C, the hypotenuse (the hypotenuse of the light transmitting portion 13c) in the cross section of the light absorbing portion 14c is formed in a curved shape. Thus, the hypotenuse part in the light absorption part may be curved. Even in this case, the angle formed between the curve and the normal line of the light exit surface of the optical sheet is shorter on the upper bottom side (base material layer 11 side / left side of the paper surface) than the long lower bottom side (right side of the paper surface) of the light absorbing portion. It is preferable that this is smaller. Furthermore, the angle is preferably in the range of more than 0 degree and not more than 10 degrees at any part. A more preferable angle is greater than 0 degree and 6 degrees or less. Here, the angle formed between the curved portion and the normal line of the light exit surface of the optical sheet divides the curve into 10 equal parts, the line connecting the adjacent ends, and the normal line of the optical surface of the optical sheet. Defined by the angle between

  In addition, the shape of the light absorbing portion is not limited to that of the present embodiment, and can be appropriately changed as long as it can absorb external light appropriately. This can include, for example, a case where the cross-sectional shape is substantially rectangular.

Returning to FIG. 1, the adhesive layer 23 will be described.
The pressure-sensitive adhesive layer 23 is a layer composed of a pressure-sensitive adhesive composition containing a pressure-sensitive adhesive. As an adhesive, a well-known thing can be used which can obtain required light transmittance, adhesiveness, and weather resistance. The pressure-sensitive adhesive composition may contain a UV absorber, a near-infrared absorber, a neon ray absorber, a toning pigment, and the like.

  Here, the pressure-sensitive adhesive is a kind of adhesive, and it can be bonded with only the adhesiveness of the surface by simply applying moderate pressure (usually lightly pressed by hand). Say something. In order to develop the adhesive strength of the pressure-sensitive adhesive, usually, physical energy or action such as heating, humidification, and radiation (ultraviolet ray, electron beam, etc.) irradiation is unnecessary, and chemical reaction such as polymerization reaction is also unnecessary. In addition, the pressure-sensitive adhesive can maintain the adhesive strength to the extent that it can be re-peeled after bonding.

  However, the refractive index of the pressure-sensitive adhesive layer 23 in the present invention is the same refractive index as that of the binder 15 of the light transmission part 13 and the light absorption part 14 described above. Thereby, color unevenness can be suppressed. Details will be described later.

The pressure-sensitive adhesive layer 23 is the thickest part, and the thickness is preferably 20 μm or more and 50 μm or less. If the thickness of the pressure-sensitive adhesive layer 23 is less than 20 μm, the followability to the recesses and projections of the light absorbing portion will be reduced, causing a problem of entraining bubbles, and if it exceeds 50 μm, the pressure-sensitive adhesive composition is uniformly applied. It becomes difficult.
Furthermore, the storage elastic modulus at 23 ° C. of the adhesive of the adhesive layer 23 is desirably 0.1 MPa or more and 0.8 MPa or less. If it is larger than this, the followability to the depressions and projections of the depression of the light absorption part will be reduced, and a problem of entraining bubbles will occur, and if it is smaller than this, it will be soft and a problem of dirt due to the sticking out of the adhesive composition may occur. .

Hereinafter, other layers appearing in FIG. 1 will be described.
The pressure-sensitive adhesive layer 20 can be the same as the pressure-sensitive adhesive layer 23. However, the refractive index is not particularly limited, and may be a refractive index different from that of the binder 15 of the light transmitting portion 13 or the light absorbing portion 14.

  As the name indicates, the electromagnetic wave shielding layer 21 is a layer having a function of shielding electromagnetic waves. As long as the layer has such a function, the means for blocking electromagnetic waves is not particularly limited. For example, as can be seen from FIG. 1, the copper mesh layer 21b can be formed on the transparent substrate 21a by an etching method, a printing method, a vapor deposition method, a sputtering method, or the like. It is designed appropriately according to the electromagnetic wave to be used. In addition, as a method of forming the copper mesh layer 21b, a method of forming a metal foil by photolithography after laminating the transparent base material 21a and the metal foil with an adhesive (for example, JP-A-11-145678). Can be prevented by adding an antioxidant similar to that of the pressure-sensitive adhesive layer 22 to be described later to the adhesive. For example, PET can be used as the transparent substrate 21a.

  The pressure-sensitive adhesive layer 22 is preferably configured as follows in addition to the pressure-sensitive adhesive layer 20 described above. That is, the pressure-sensitive adhesive layer 22 is preferably a pressure-sensitive adhesive having an acid value from the viewpoint of enhancing the adhesion between the electromagnetic wave shielding layer 21 and the base material layer 11 of the optical sheet 19. As an adhesive which has an acid value, what has an acid value is mentioned, for example among natural rubber and a synthetic resin. Specific examples include those composed of a substance having a carboxyl group in the molecule, and an acrylic pressure-sensitive adhesive is preferred. This is because the transparency is high. Moreover, it is preferable that the acid value of an acrylic adhesive is 1 or more from a viewpoint that the adhesiveness of the electromagnetic wave shielding layer 21 and the base material layer 11 can be made favorable.

  As an acrylic pressure-sensitive adhesive having an acid value, it has appropriate adhesive strength, transparency, and coating suitability among those commonly used as known pressure-sensitive adhesives, and substantially changes the transmission spectrum of the optical sheet. Select one that does not have any problems.

  The acrylic pressure-sensitive adhesive having an acid value is a polymer containing at least a (meth) acrylic acid alkyl ester monomer and is a (meth) acrylic acid alkyl ester monomer having an alkyl group of about 1 to 18 carbon atoms. Generally, it is a copolymer of a monomer having a carboxyl group. The adhesive ability of the pressure-sensitive adhesive contained in the pressure-sensitive adhesive layer 22 is manifested by strongly adsorbing carboxyl groups present in the pressure-sensitive adhesive molecules on the surface of the copper mesh layer of the electromagnetic wave shielding layer 21.

Examples of (meth) acrylic acid alkyl ester monomers used here include methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, sec-propyl (meth) acrylate, N-butyl (meth) acrylate, sec-butyl (meth) acrylate, tert-butyl (meth) acrylate, isoamyl (meth) acrylate, n-hexyl (meth) acrylate, cyclohexyl (meth) acrylate, Examples thereof include n-octyl (meth) acrylate, isooctyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, undecyl (meth) acrylate and lauryl (meth) acrylate. Of these, butyl acrylate and 2-ethylhexyl acrylate are preferable, and butyl acrylate and 2-ethylhexyl acrylate are preferably used in combination.
Moreover, the said (meth) acrylic-acid alkylester is normally copolymerized in the quantity of 30.0 mass parts-99.5 mass parts in acrylic adhesive.

  Moreover, as a monomer which has a carboxyl group which forms an acrylic adhesive, monomers containing a carboxyl group such as (meth) acrylic acid, itaconic acid, crotonic acid, maleic acid, monobutyl maleate and β-carboxyethyl acrylate are used. Can be mentioned.

  Furthermore, in addition to the above, the acrylic pressure-sensitive adhesive may be copolymerized with a monomer having another functional group within a range that does not impair the properties of the acrylic pressure-sensitive adhesive. Examples of monomers having other functional groups include monomers containing hydroxyl groups such as 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate and allyl alcohol; (meth) acrylamide, N-methyl Monomers containing amide groups such as (meth) acrylamide and N-ethyl (meth) acrylamide; Monomers containing amide groups and methylol groups such as N-methylol (meth) acrylamide and dimethylol (meth) acrylamide; Monomers containing amino groups such as (meth) acrylate and dimethylaminoethyl (meth) acrylate; and epoxy group-containing monomers such as allyl glycidyl ether and (meth) acrylic acid glycidyl ether. Other examples include fluorine-substituted (meth) acrylic acid alkyl esters and (meth) acrylonitrile, vinyl group-containing aromatic compounds such as styrene, methylstyrene, and vinylpyridine, vinyl acetate, and vinyl halide compounds. it can.

  Further, in the acrylic pressure-sensitive adhesive, in addition to the monomer having the other functional group as described above, another monomer having an ethylenic double bond can be used. Examples of monomers having an ethylenic double bond include diesters of α, β-unsaturated dibasic acids such as dibutyl maleate, dioctyl maleate and dibutyl fumarate; vinyl esters such as vinyl propionate; vinyl ethers; And vinyl aromatic compounds such as vinyl toluene.

  In addition to the monomer having an ethylenic double bond as described above, a compound having two or more ethylenic double bonds may be used in combination. Examples of such compounds include divinylbenzene, diallyl malate, diallyl phthalate, ethylene glycol di (meth) acrylate, trimethylolpropane tri (meth) acrylate, methylenebis (meth) acrylamide, and the like.

  Furthermore, in addition to the above-described monomers, monomers having an alkoxyalkyl chain can be used. Examples of (meth) acrylic acid alkoxyalkyl esters include 2-methoxyethyl (meth) acrylate, methoxyethyl (meth) acrylate, 2-methoxypropyl (meth) acrylate, and 3-methoxypropyl (meth) acrylate. , 2-methoxybutyl (meth) acrylate, 4-methoxybutyl (meth) acrylate, 2-ethoxyethyl (meth) acrylate, 3-ethoxypropyl (meth) acrylate, 4-ethoxybutyl (meth) acrylate And so on. As a commercial item of an acrylic adhesive, Nippon Synthetic Chemical Co., Ltd. product name: "5407" etc. can be mentioned, for example.

  By including an antioxidant, the pressure-sensitive adhesive layer 22 can prevent discoloration of the electromagnetic wave shielding layer 21 while using a pressure-sensitive adhesive having good acidity. The compound used as the antioxidant is selected from benzotriazole antioxidants, phenolic antioxidants, phosphite antioxidants, amine antioxidants, sulfur-containing organometallic salt antioxidants, etc. Although it can be used, the antioxidant contained in the pressure-sensitive adhesive layer 22 is preferably a benzotriazole antioxidant from the viewpoint of blue discoloration prevention performance of the copper mesh layer of the electromagnetic wave shielding layer 21.

  Examples of the benzotriazole antioxidants include compounds characterized by containing at least the structure of the following formula (1) as a skeleton, and sodium salts, potassium salts, and amine salts thereof. Examples of the substituent that may have the structure of the following formula (1) include an alkyl group that may have a substituent, an aryl group that may have a substituent, and a halogen atom. It is done.

  Specifically, 1,2,3-benzotriazole (1H-benzotriazole), 1H-benzotriazole sodium salt, 4-methyl-1H-benzotriazole, 5-methyl-1H-benzotriazole, 4-methyl-1H -Benzotriazole potassium salt, 5-methyl-1H-benzotriazole potassium salt, 4-methyl-1H-benzotriazoleamine salt, 5-methyl-1H-benzotriazoleamine salt, 2- (3,5-di-t- Butyl-2-hydroxyphenyl) -5-chlorobenzotriazole, 2- (3,5-di-t-amyl-2-hydroxyphenyl) benzotriazole and the like, among which 1,2,3-benzotriazole (1H -Benzotriazole) is preferred.

  In the pressure-sensitive adhesive layer 22, the adhesive strength of the pressure-sensitive adhesive layer 22 is sufficient and the surface of the copper mesh layer of the electromagnetic wave shielding layer 21 is not discolored. It is preferable that 1 mass part or more of inhibitor is included. When the content of the antioxidant is less than the above range, discoloration of the copper mesh layer of the electromagnetic wave shielding layer 21 may not be sufficiently prevented even if the antioxidant is contained in the adhesive layer 22.

  In particular, the acid value of the pressure-sensitive adhesive is preferably 1 or more, and the pressure-sensitive adhesive layer 22 preferably contains 1 part by mass or more of the benzotriazole-based antioxidant with respect to 100 parts by mass of the pressure-sensitive adhesive.

  Furthermore, a curing agent (crosslinking agent) such as an isocyanate compound, a tackifier, a silane coupling agent, a filler, and the like can be blended in the adhesive layer 22.

  Next, the wavelength filter layer 24 will be described. The wavelength filter layer 24 is a layer having a function of suppressing transmission of light having a predetermined wavelength. The wavelength whose transmission should be suppressed can be appropriately selected as necessary. Specific examples include a layer for cutting neon lines emitted from the PDP, a layer for cutting infrared rays, near infrared rays, and ultraviolet rays, a layer for adjusting color tone, and the like. Below, a layer for cutting near infrared rays (near infrared absorption filter), a layer for cutting neon lines (neon light absorption filter), a layer for adjusting color tone (color tone adjustment filter), and a layer for cutting ultraviolet rays (ultraviolet absorption filter) ).

  As the near-infrared absorbing filter, a commercially available film having a near-infrared absorbing agent (for example, trade name No. 2832 manufactured by Toyobo Co., Ltd.) or a composition containing a near-infrared absorbing dye in the adhesive layer or the resin layer is used. A film formed or coated on a transparent substrate or other functional filter and dried or cured as necessary can be used.

  As the near-infrared absorbing dye, a near-infrared region generated due to the xenon gas discharge emitted by the PDP, that is, a pigment that absorbs a wavelength region of 800 nm to 1100 nm is used. The near-infrared transmittance of the band is preferably 20% or less, more preferably 10% or less. At the same time, it is desirable that the near-infrared absorption filter has a sufficient light transmittance in the visible light region, that is, in the wavelength region of 380 nm to 780 nm.

  Specific examples of near-infrared absorbing dyes include polymethine compounds, cyanine compounds, phthalocyanine compounds, naphthalocyanine compounds, naphthoquinone compounds, anthraquinone compounds, dithiol compounds, imonium compounds, diimonium compounds, Aminium compounds, pyrylium compounds, cerium compounds, squarylium compounds, copper complexes, nickel complexes, dithiol metal complexes organic near-infrared absorbing dyes, tungsten oxide, tin oxide, indium oxide, magnesium oxide, oxidation Titanium, chromium oxide, zirconium oxide, nickel oxide, aluminum oxide, zinc oxide, iron oxide, ammonium oxide, lead oxide, bismuth oxide, inorganic near-infrared absorbing dyes such as lanthanum oxide, or a combination of two or more Can .

  Moreover, as binder resin which disperse | distributes a near-infrared absorption pigment | dye, resin, such as a polyester resin, a polyurethane resin, an acrylic resin, an epoxy resin, is used. Binder resin drying and curing methods include a drying and solidification method by drying a solvent (or dispersion medium) from a solution (or emulsion), polymerization by energy such as heat, ultraviolet rays and electron beams, a curing method utilizing a crosslinking reaction, Alternatively, a curing method using a reaction such as crosslinking or polymerization between a functional group such as a hydroxyl group or an epoxy group in a resin and an isocyanate group in a curing agent can be applied.

  The neon light absorption filter absorbs neon light emitted from the PDP, that is, an emission spectrum of neon atoms when the optical filter is used for a plasma display. Since the emission spectrum band of neon light has a wavelength of 550 nm to 640 nm, the neon light absorption filter is preferably designed so that the spectral transmittance is 50% or less at the wavelength of 550 nm to 640 nm. A neon light absorption filter is a composition in which a dye conventionally used as a dye having the maximum absorption ability in a wavelength region of at least 550 nm to 640 nm is dispersed in a binder resin as mentioned in the near infrared absorption filter. Can be formed, or can be formed on a transparent substrate or other functional filter and dried or cured as necessary. Specific examples of the dye include cyanine, oxonol, methine, subphthalocyanine or porphyrin. As the binder resin, the resins described in the description of the near infrared absorption filter can be used.

  The color tone adjustment filter is for adjusting the color of the display filter in order to improve the color purity of the light emitted from the panel, the color reproduction range, the display color when the power is turned off, and the like. For example, a composition in which a color tone-adjusting pigment is dispersed in a binder resin is formed into a film, or this is applied on a transparent substrate or other functional filter, and formed through drying, curing treatment, or the like as necessary. be able to. As the color tone adjusting dye, a known dye having a maximum absorption wavelength in the visible region of 380 nm to 780 nm can be used in combination with any dye according to the purpose. Examples of known dyes that can be used as the color tone adjusting dyes include the dyes described in JP 2000-275432 A, JP 2001-188121 A, JP 2001-350013 A, JP 2002-131530 A, and the like. Can be suitably used. In addition, other dyes such as anthraquinone, naphthalene, azo, phthalocyanine, pyromethene, tetraazaporphyrin, squarylium, and cyanine that absorb visible light such as yellow light, red light, and blue light. Can be used. As the binder resin, the resins mentioned in the above-mentioned near infrared absorption filter can be used.

  As an ultraviolet absorption filter, for example, a composition in which an ultraviolet absorber is dispersed in a binder resin is formed, or this is coated on a transparent substrate or other functional filter, and dried and cured as necessary. Or the like. Examples of the ultraviolet absorber include organic compounds such as benzotriazole and benzophenone, and inorganic compounds composed of particulate zinc oxide, cerium oxide, and the like. As the binder resin, the resins mentioned in the above-mentioned near infrared absorption filter can be used.

  The wavelength filter layer 24 is not necessarily constituted by one layer, and may be constituted by a plurality of layers having each function.

  Next, the hard coat layer 25 will be described. The hard coat layer 25 may also be called an HC layer. This is a layer in which a film having a function capable of imparting scratch resistance is provided in order to prevent the image display surface from being scratched. A known hard coat layer can be applied here.

  Next, the antireflection layer 26 will be described. The antireflection layer 26 is a layer that is disposed closest to the viewer and has a function of preventing reflection of external light. According to this, it is possible to prevent external light from being reflected on the viewer side surface of the optical filter and returning to the viewer side, so that the so-called reflection occurs and the image becomes difficult to see. Such an antireflection layer 26 can be constituted by using a known antireflection film.

  In the description of the present invention thus far, the optical sheet 19 (base material layer 11, optical functional layer 12), pressure-sensitive adhesive layers 20, 22, 23, electromagnetic wave shielding layer 21, wavelength filter layer 24, hard coat layer 25, and reflection Although the optical filter 10 provided with the prevention layer 26 has been described, the optical filter of the present invention only needs to include at least the base material layer 11, the optical function layer 12, and the pressure-sensitive adhesive layer 23, and so far depending on the application. It is also possible to provide a layer having various functions other than those described above. As other layers that can be provided in the optical filter, those used in conventional optical filters can be used without any particular limitation, including those described above. Examples of the other layer include an antiglare layer.

  The antiglare layer is a layer having a function of suppressing so-called glare and is sometimes called an antiglare layer or an AG layer. A commercially available layer can be used as such an antiglare layer.

As described above, the optical filter is not limited to this embodiment, and can be changed as appropriate. Three other examples are given below.
(1) Adhesive layer 20 / optical sheet 19 / adhesive layer 23 / electromagnetic wave shielding layer 21 / wavelength filter layer 24 / hard coat layer 25 / antireflection layer 26
(2) Adhesive layer 20 / optical sheet 19 / adhesive layer 23 / wavelength filter layer 24 / hard coat layer 25 / antireflection layer 26
(3) Adhesive layer 20 / optical sheet 19 / adhesive material layer 23 (having a neon light absorption function) / wavelength filter layer 24 / hard coat layer 25 / antireflection layer 26
Here, the pressure-sensitive adhesive layer 23 having a neon light absorption function includes the above-described pressure-sensitive adhesive layer 23 containing the above-described dye for absorbing neon light.

  Next, a method for manufacturing the optical sheet 19 having a particularly complicated shape in the optical filter 10 will be described. FIG. 4 is a cross-sectional view schematically illustrating a part of the process for an example of the method for manufacturing the optical sheet 19. FIG. 5 is a perspective view schematically illustrating another process in the example of the method for manufacturing the optical sheet 19.

  When manufacturing the optical sheet 19, as shown in FIG. 4, the light transmission part 13 is formed on the base material 11 'including what becomes the base material layer 11, and the sheet 19' is obtained. In order to form the light transmission part 13, first, a mold roll 42 having a groove having a shape corresponding to the shape of the light transmission part 13 at a predetermined pitch is prepared. Next, the base material 11 ′ is fed between the mold roll 42 and the nip roll 41. The arrow IV shown in FIG. 4 is the direction in which the substrate 11 'is fed. In accordance with the feeding of the base material 11 ′, the droplets of the light transmitting portion constituting composition 30 are continuously supplied from the supply device 40 between the mold roll 42 and the base material 11 ′. When the light transmitting portion constituting composition 30 is supplied onto the base material 11 ′ from the supply device 40, a bank 31 in which the light transmitting portion constituting composition 30 is accumulated is formed between the mold roll 42 and the base material 11 ′. To be. In the bank 31, the light transmitting portion constituting composition 30 spreads in the width direction of the base material 11 '.

  The light transmitting portion constituting composition supplied between the mold roll 42 and the base material 11 ′ as described above is formed by the pressing force between the mold roll 42 and the nip roll 41. 42 is filled. Thereafter, the light transmissive part 13 can be formed by irradiating the light transmissive part constituting composition with light by the light irradiation device 44 and curing the light transmissive part constituting composition. After the light transmission part 13 is formed, the sheet 19 ′ on which the light transmission part 13 is formed on the sheet 11 ′ is pulled off from the mold roll 42 by being pulled through the peeling roll 43.

Next, as shown in FIG. 5, the optical absorption layer 14 is formed between the light transmission portions 13 of the sheet 19 ′ to obtain the optical functional layer 12. Specifically, it is as follows.
While supplying the binder constituent composition 36 in which the light absorbing particles are dispersed on the light transmitting portion 13 and filling the grooves 37 between the light transmitting portions 13 with the light absorbing particles and the binder constituent composition 36 by the doctor blade 35, Scrape off the surplus. Then, the binder constituent composition 36 remaining in the groove 37 between the light transmitting portions 13 is irradiated with light and cured. Note that the arrow V shown in FIG. 5 is the feeding direction of the sheet 19 ′.

  At this time, it is preferable that the elastic modulus of the light transmission part 13 is 10 MPa or more and 2000 MPa or less. When the elastic modulus of the light transmitting portion 13 is greater than 2000 MPa, it becomes hard and defects such as cracks and chipping occur, or when the light absorbing portion 14 is formed as described above, the appearance of the optical functional layer 12 is poor. Or the transmittance of the optical function layer 12 may be reduced. That is, if the light transmission part 13 is too hard, even if the doctor blade 35 is pressed against the light transmission part 13 when the surplus portion of the binder constituent composition supplied onto the light transmission part 13 is scraped by the doctor blade 35, the light transmission part 13 The part 13 is not deformed. Therefore, there is a possibility that an excess of these compositions cannot be scraped off. When the elastic modulus of the light transmission part 13 is set to the above range, when the doctor blade 35 is pressed, due to the deformation of the light transmission part 13, the scraping failure of the surplus composition is eliminated, and the appearance of the optical functional layer 12 is poor. Or the transmittance of the optical function layer 12 can be prevented from being lowered. In addition, since the light transmission part 13 is too soft when the elasticity modulus of the light transmission part 13 is 10 Mpa or less, the light transmission part 13 becomes difficult to release from the mold roll 42 in the process shown in FIG.

  The pressure-sensitive adhesive layer 23 is laminated on the opposite side of the surface of the optical functional layer 12 of the optical sheet 19 manufactured as described above from the side on which the base material layer 11 is laminated to form an optical filter. At this time, the depression 17 formed in the optical function layer 12 is also filled with the adhesive layer 23.

  Next, the plasma television 1 as an image display device including the optical filter 10 will be described. FIG. 6 is an exploded perspective view schematically showing a plasma television 1 which is a video display device according to one embodiment. In FIG. 6, the upper right side of the drawing shows the observer side, and the lower left side of the drawing shows the back side. As can be seen from FIG. 6, the plasma television 1 includes a plasma display panel unit 4 (PDP unit 4) as a video source unit inside a casing formed by the front casing 2 and the rear casing 3. I have.

  In addition to the PDP unit 4, the plasma television 1 is provided with usual devices included in the plasma television in the casing. Examples thereof include various electric circuits and cooling means.

  FIG. 7 schematically shows the configuration of the PDP unit 4. The PDP unit 4 includes an optical filter 10 disposed on the image light emission side of the plasma display panel 5 (PDP 5). The video display device 1 includes a PDP 5 and an optical filter 10 disposed on the viewer side from the PDP 5. At this time, the base material layer 11 of the optical sheet 19 is disposed on the PDP 5 side, and the depression 17 of the light absorbing portion 14 is disposed facing the observer side.

Next, an optical path in the image display device 1, particularly an optical path of image light passing through the optical function layer 12 and the adhesive layer 23 will be described. 8 and 9 are diagrams for explaining the optical path.
FIG. 8 is a diagram showing a typical optical path example of light incident on the optical function layer 12.
The light L1 enters the light transmission part 13 from the PDP 5, passes through the light transmission part 13 as it is, and is emitted to the observer side.
The light L2 enters the light transmission part 13 from the PDP 5 and further enters the light absorption part 14 and is absorbed by the light absorption particles 16. Thereby, for example, stray light can be absorbed.
The light L3 is an example in which so-called external light from the observer side is incident on the light absorbing portion 14 and absorbed by the light absorbing particles 16. Thereby, a part of outside light can be absorbed, and the contrast can be improved.

  FIG. 9 is a diagram illustrating that the color unevenness is suppressed by the optical filter 10. FIG. 9B also shows a conventional example for comparison.

  As shown in FIG. 9B, in the conventional optical filter, when the light L101 is emitted from the portion thinned by the depression 117 of the light absorbing portion 114 to the viewer side, the adhesive layer 123 in the depression 117 is formed. Chromatic dispersion occurs at the interface. In the conventional optical filter, it is considered that rainbow-like color unevenness has occurred due to the wavelength dispersion generated at the end of the depression 117.

  On the other hand, in the optical filter 10 shown in FIG. 9A, the light transmission part 13, the binder 15 of the light absorption part 14, and the refractive index of the adhesive layer 23 are all the same. L4 is emitted to the viewer side without causing chromatic dispersion. Therefore, it is considered that no rainbow-like color unevenness occurs.

  As described above, according to the optical filter 10 and the video display device 1 using the same, the occurrence of color unevenness can be suppressed. In addition, the improvement in contrast, which is a basic function of the optical function layer 12, is sufficiently ensured.

  Hereinafter, the present invention will be described in more detail with reference to examples. However, the present invention is not limited to the examples.

Example 1
In Example 1, an optical filter in which the light transmission part 13, the binder 15 of the light absorption part 14, and the refractive index of the adhesive layer 23 are all the same was manufactured. Specifically, it is as follows.

(1) Preparation of composition for composition of light transmission part 10.0 parts by mass of photocurable prepolymer (P1) comprising polyester diol / tolylene diisocyanate / 2-hydroxyethyl acrylate = 85: 10: 5, reactive dilution monomer 30.0 parts by mass of phenoxyethyl acrylate as (M1), 30.0 parts by mass of bisphenol A polyethoxyethoxy acrylate, 30.0 parts by mass of tripropylene glycol diacrylate, and as a mold release agent (S1) 0.05 parts by mass of tetradecanol-ethylene oxide 10-mole adduct phosphate (monoester / diester = molar ratio 1/1), 1-hydroxycyclohexyl phenylphenyl as photopolymerization initiator (I1) Ketone (Product name: Irgacure 184, Ciba Specialty Chemical) The Co., Ltd.) was used 3.0 parts by weight.
These photocurable prepolymer (P1), reactive diluent monomer (M1), mold release agent (S1), and photopolymerization initiator (I1) are mixed and homogenized to obtain a light transmitting part constituting composition. It was. This light transmitting portion constituting composition is applied at a thickness of 100 μm, cured by irradiating with an ultraviolet ray of 800 mJ / cm ² with a high-pressure mercury lamp, and a refractive index of 589 nm using a multiwavelength Abbe refractometer DR-M4 (Atago). Was 1.51.

(2) Formation of base material layer with pressure-sensitive adhesive layer Acrylic resin pressure-sensitive adhesive (trade name: SK Dyne 2094, manufactured by Soken Chemical Co., Ltd., solid content: 25.0%, solvents are ethyl acetate and methyl ethyl ketone), 100 parts by mass, Cross-linking agent (E-5XM, L-45, manufactured by Soken Chemical Co., Ltd., solid content 5, 0%) 0.28 parts by mass, 0.25 parts by mass of 1,2,3-benzotriazole, and diluent (toluene / (Methyl ethyl ketone / cyclohexanone = 27.69 g / 27.69 g / 4.61 g) 32 parts by mass were mixed to obtain an adhesive coating solution.
The coating liquid is applied on a substrate (PET film, trade name: A4300, manufactured by Toyobo Co., Ltd., thickness 100 μm) to a thickness of 25 μm, dried, and then a release film (product) Name: E7007, manufactured by Toyobo Co., Ltd., thickness 38 μm) was bonded to prepare a base material layer with an adhesive layer (hereinafter simply referred to as “base material”).
In addition, about this adhesive layer, it was 1.490 when the refractive index of 589 nm was measured using multiwavelength Abbe refractometer DR-M4 (made by Atago Co., Ltd.). Moreover, the storage elastic modulus in 23 degreeC of the adhesive used for this adhesive layer was 0.2 MPa. This storage elastic modulus is a value measured using a solid viscoelasticity analyzer (RSAII manufactured by Rheometrics Co., Ltd.) in a compression mode at a measurement frequency of 1 Hz and a measurement temperature in the range of −50 ° C. to 150 ° C. at a temperature rising rate of 5 ° C./min. Based on.

(3) Formation of mold roll The mold roll has a cylindrical shape and is plated with copper. A groove was cut in the circumferential direction of this copper-plated portion using a diamond tool. The diamond tool had a shape with a tip width of 35 μm, a slope angle of 1.9 °, and a width of 41 μm when the depth was 85 μm. In the groove cross section, a trapezoidal shape having a groove bottom width of 35 μm, a mold surface groove width of 41 μm and a depth of 85 μm was formed, and periodic grooves were formed in the entire roll width at a pitch of 45 μm. After cutting, chrome plating was performed to obtain a mold roll.

(4) Formation of light transmission part The base material produced by said (2) was inserted and conveyed between the mold roll produced by said (3), and the nip roll. In accordance with the conveyance of the base material, the light transmission part constituting composition obtained in (1) above is supplied from the supply device onto the base material layer of the base material, and the base material is pressed by the pressing force between the mold roll and the nip roll. The light transmitting portion constituting composition was filled between the layer and the mold roll. Then, 800 mJ / cm < ² > of ultraviolet rays were irradiated from the base material side with the high pressure mercury lamp, the light transmissive part constituent composition was hardened, and the light transmissive part was formed. Then, the light transmission part was released from the mold roll with a peeling roll, and a sheet (intermediate member) having a thickness including the light transmission part of 252 ± 20 μm was produced.
About this intermediate member, the elastic modulus of the light transmission part was measured by applying a load to the micro-indenter material using a compression microhardness meter (FISCHER HM2000) and unloading it. At this time, the load force was 100 mN, the load speed was 4 μm / 10 seconds, and the holding time was 60 seconds. As a result, the elastic modulus of the light transmission part was 800 MPa.

(5) Preparation of binder composition containing light-absorbing particles 8.0 parts by mass of a photocurable prepolymer (P2) comprising polyester diol / tolylene diisocyanate / 2-hydroxyethyl acrylate = 85: 10: 5, 24.0 parts by mass of phenoxyethyl acrylate as a reactive diluent monomer (M2), 24.0 parts by mass of bisphenol A polyethoxyethoxy acrylate, 24.0 parts by mass of tripropylene glycol diacrylate, a photopolymerization initiator (I2 1) Hydroxy cyclohexyl phenyl ketone (trade name: Irgacure 184, manufactured by Ciba Specialty Chemicals Co., Ltd.) 5.0 parts by mass, carbon black having an average particle size of 4.0 μm as light absorbing particles Acrylic crosslinked fine particles containing 25% by mass 20.0 parts by mass was used.
These photocurable prepolymer (P2), reactive diluent monomer (M2), photopolymerization initiator (I2), and light absorbing particles were mixed and homogenized to obtain a light absorbing portion constituting composition.
In addition, only the binder composition (excluding the light absorbing particles) was applied at a thickness of 10 μm, cured by irradiating with 800 mJ / cm ² of ultraviolet light with a high-pressure mercury lamp, and a multi-wavelength Abbe refractometer DR-M4 (Co., Ltd.). When the refractive index at 589 nm was measured by using Atago, it was 1.51.

(6) Formation of light-absorbing part The binder constituent composition containing the light-absorbing particles obtained in (5) above was supplied from the supply device onto the intermediate member prepared in (4) above. In addition, using a doctor blade arranged substantially perpendicular to the traveling direction of the intermediate member, the binder constituent composition supplied onto the intermediate member is inserted into a wedge-shaped groove (groove between light transmitting portions) formed on the intermediate member. While filling, the excess binder constituent composition was scraped off. Thereafter, the binder constituent composition was cured by irradiating with an ultraviolet ray of 800 mJ / cm ^{2 with} a high-pressure mercury lamp. In this state, a recess having a depth of 7.0 μm was generated on the surface of the light absorbing portion.

  The optical sheet concerning Example 1 was produced as mentioned above. Thereafter, an adhesive was applied to the optical sheet, and a wavelength filter layer, a hard coat layer, and an antireflection layer were laminated to obtain an optical filter. Here, the pressure-sensitive adhesive layer was the same as the pressure-sensitive adhesive applied to the base material layer described in (2) above.

  In addition, as examples 2 to 4, regarding the formation of the light absorption part described above, only the binder of the light absorption part is filled several times and cured in the same manner, and the depth of the depression is 6.0 μm (Example 2). Samples of 3.0 μm (Example 3) and 0.5 μm (Example 4) were produced. Other conditions are the same as those in the first embodiment.

(Comparative Example 1)
In Comparative Example 1, the light transmitting part constituting composition and the binder constituting composition containing the light absorbing particles were adjusted as follows.
(7) Preparation of composition for composition of light transmission part of Comparative Example 1 30.0 parts by mass of a photocurable prepolymer (P1) composed of polyester diol / tolylene diisocyanate / 2-hydroxyethyl acrylate = 85: 10: 5, 30.0 parts by mass of phenoxyethyl acrylate as reactive diluent monomer (M1), 30.0 parts by mass of bisphenol A polyethoxyethoxy acrylate, 10.0 parts by mass of tripropylene glycol diacrylate, mold release agent ( 0.05 parts by mass of phosphoric acid ester (monoester / diester = molar ratio 1/1) of tetradecanol-ethylene oxide 10-mole adduct as S1) and 1-hydrokeshi as photopolymerization initiator (I1) Cyclohexyl phenyl ketone (trade name: Irgacure 184, Ciba Specialty) The Chemicals Co., Ltd.) was used 3.0 parts by weight.
These photocurable prepolymer (P1), reactive diluent monomer (M1), mold release agent (S1), and photopolymerization initiator (I1) are mixed and homogenized to obtain a light transmitting part constituting composition. It was. This light transmitting portion constituting composition is applied at a thickness of 100 μm, cured by irradiating with an ultraviolet ray of 800 mJ / cm ² with a high-pressure mercury lamp, and a refractive index of 589 nm using a multiwavelength Abbe refractometer DR-M4 (Atago). Was 1.53.

(8) Preparation of Binder Constituent Composition Containing Light Absorbing Particles of Comparative Example 1 24. A photocurable prepolymer (P2) comprising polyester diol / tolylene diisocyanate / 2-hydroxyethyl acrylate = 85: 10: 5. 0 parts by mass, 24.0 parts by mass of phenoxyethyl acrylate as a reactive diluent monomer (M2), 24.0 parts by mass of bisphenol A polyethoxyethoxy acrylate, 8.0 parts by mass of tripropylene glycol diacrylate, photopolymerization 5.0 parts by mass of 1-hydrokicyclohexylcyclohexyl phenyl ketone (trade name: Irgacure 184, manufactured by Ciba Specialty Chemicals Co., Ltd.) as an initiator (I2), and an average particle diameter of 4.0 μm as light absorbing particles Acrylic crosslinked fine particles containing 25% carbon black 20.0 parts by mass was used.
These photocurable prepolymer (P2), reactive diluent monomer (M2), photopolymerization initiator (I2), and light absorbing particles were mixed and homogenized to obtain a light absorbing portion constituting composition.
In addition, only the binder composition (excluding the light absorbing particles) was applied at a thickness of 10 μm, cured by irradiating with 800 mJ / cm ² of ultraviolet light with a high-pressure mercury lamp, and a multi-wavelength Abbe refractometer DR-M4 (Co., Ltd.). When the refractive index at 589 nm was measured using Atago Co., Ltd., it was 1.53.

  Comparative Example 1 was the same as Example 1 except for the light transmitting part constituent composition and the binder constituent composition containing light absorbing particles.

(Comparative Example 2)
In Comparative Example 2, the light transmitting part constituent composition and the binder constituent composition containing the light absorbing particles were adjusted as follows.
(9) Preparation of composition for composition of light transmission part of Comparative Example 2 50.0 parts by mass of a photocurable prepolymer (P1) composed of polyester diol / tolylene diisocyanate / 2-hydroxyethyl acrylate = 85: 10: 5, 30.0 parts by mass of phenoxyethyl acrylate as reactive diluent monomer (M1), 10.0 parts by mass of bisphenol A polyethoxyethoxy acrylate, 10.0 parts by mass of tripropylene glycol diacrylate, mold release agent ( 0.05 parts by mass of phosphoric acid ester (monoester / diester = molar ratio 1/1) of tetradecanol-ethylene oxide 10-mole adduct as S1) and 1-hydrokeshi as photopolymerization initiator (I1) Cyclohexyl phenyl ketone (trade name: Irgacure 184, Ciba Specialty) The Chemicals Co., Ltd.) was used 3.0 parts by weight.
These photocurable prepolymer (P1), reactive diluent monomer (M1), mold release agent (S1), and photopolymerization initiator (I1) are mixed and homogenized to obtain a light transmitting part constituting composition. It was. This light transmitting portion constituting composition is applied at a thickness of 100 μm, cured by irradiating with an ultraviolet ray of 800 mJ / cm ² with a high-pressure mercury lamp, and a refractive index of 589 nm using a multiwavelength Abbe refractometer DR-M4 (Atago). Was 1.55.

(10) Preparation of binder constituent composition containing light absorbing particles of Comparative Example 2 40. A photocurable prepolymer (P2) comprising polyester diol / tolylene diisocyanate / 2-hydroxyethyl acrylate = 85: 10: 5. 0 parts by mass, 24.0 parts by mass of phenoxyethyl acrylate as reactive diluent monomer (M2), 8.0 parts by mass of bisphenol A polyethoxyethoxy acrylate, 8.0 parts by mass of tripropylene glycol diacrylate, photopolymerization 5.0 parts by mass of 1-hydrokicyclohexylcyclohexyl phenyl ketone (trade name: Irgacure 184, manufactured by Ciba Specialty Chemicals Co., Ltd.) as an initiator (I2), and an average particle diameter of 4.0 μm as light absorbing particles Acrylic crosslinked fine particles containing 25% carbon black 20.0 parts by mass was used.
These photocurable prepolymer (P2), reactive diluent monomer (M2), photopolymerization initiator (I2), and light absorbing particles were mixed and homogenized to obtain a light absorbing portion constituting composition.
In addition, only the binder composition (excluding the light absorbing particles) was applied at a thickness of 10 μm, cured by irradiating with 800 mJ / cm ² of ultraviolet light with a high-pressure mercury lamp, and a multi-wavelength Abbe refractometer DR-M4 (Co., Ltd.). When the refractive index at 589 nm was measured using Atago, it was 1.55.

(Reference Example 1)
As Reference Example 1, using the light transmitting part and the light absorbing part of Comparative Example 2, the material of the light transmitting part is coated flat instead of the adhesive layer, and molded using a mirror mold, and the high pressure mercury lamp Was irradiated with an ultraviolet ray of 800 mJ / cm ² and cured to prepare an optical sheet.

(Reference Example 2)
In addition, regarding the formation of the light absorption part of Example 1 described above as Reference Example 2, only the binder of the light absorption part was filled several times and cured in the same manner to prepare a sample with a depth of 0.0 μm. . Other conditions are the same as those in the first embodiment.

  Table 1 summarizes the conditions of each example and shows the results. The manufactured optical filter was directly attached to the plasma display panel and observed. Here, the occurrence of color unevenness was observed by visual observation, and when no color unevenness occurred, “◯” was indicated, and when color unevenness occurred, “x” was indicated. In addition, when the front luminance is set to 100%, the viewing angle is half of the viewing angle, and with reference example 1 as a reference, a case where the viewing angle is equal to or greater than “O” is indicated, and the viewing angle is narrowed. The case was set as “x”. In addition, the pressure-sensitive adhesive layer in Table 1 means a pressure-sensitive adhesive layer laminated on the hollow side of the optical functional layer. Therefore, the pressure-sensitive adhesive layer corresponds to the pressure-sensitive adhesive layer 23 in the optical filter 10 of the above embodiment.

  As can be seen from Table 1, the rainbow-shaped color unevenness is prevented by making the refractive index of the light transmitting part, the light absorbing part (binder) and the pressure-sensitive adhesive layer substantially the same (refractive index difference is within 0.02). I was able to. Also, the viewing angle at this time was good.

  In addition, in the manufacture of Examples 1 to 4 and Reference Example 2, when the depth of the depression of the light absorbing portion is 0.5 μm or more and 6.0 μm or less, such as poor appearance or entrapment of bubbles in adhesive bonding, etc. It was difficult for problems to occur. When the dent was 0.0 μm as in Reference Example 2, it was easy for the binder to cover the light transmitting portion, and appearance problems were likely to occur. Further, when the depression was 7.0 μm as in Example 1, bubbles were easily generated when the adhesive was bonded.

1 Video display device 4 PDP unit 5 PDP panel (video source)
DESCRIPTION OF SYMBOLS 10 Optical filter 11 Base material layer 12 Optical functional layer 13 Light transmission part 14 Light absorption part 15 Binder 16 Light absorption particle 17 Depression 19 Optical sheet 20 Adhesive layer 21 Electromagnetic wave shielding layer 22 Adhesive layer 23 Adhesive layer 24 Wavelength filter layer 25 Hard coat layer 26 Antireflection layer

Claims (6)

A video display apparatus comprising: a video source, an optical filter having a layer of several that will be placed on the observer side of the image source, and
The optical filter is
A base material layer, an optical functional layer laminated on the base material layer, and an adhesive layer laminated on the side opposite to the base material layer among the surfaces of the optical functional layer,
The optical functional layer has a trapezoidal cross section which is arranged in parallel along the sheet surface so as to transmit light and has a short upper base on the observer side and a long lower bottom on the image source side, and the light transmitting part A light absorption part arranged in parallel so as to be able to absorb light having a trapezoidal cross section disposed between and having a long lower base on the viewer side and a short upper base on the image source side ,
The light absorbing portion has a curved or broken line-shaped depression formed in the lower bottom directed to the observer side ,
The image display device , wherein the light transmission part, the light absorption part, and the pressure-sensitive adhesive layer all have a refractive index difference of 0.02 or less . The image display device according to claim 1, wherein a depth of the recess of the light absorption unit is 0.5 μm or more and 6.0 μm or less. The image display apparatus by which the adhesive layer which contains an adhesive is formed also in the surface on the opposite side to the said optical function layer among the said base material layers of the optical filter of Claim 1 or 2. The video display device according to claim 1, wherein the outermost layer has an antireflection layer or an antiglare layer. The image display apparatus according to claim 1, further comprising a wavelength filter layer having a function of suppressing transmission of light having a predetermined wavelength. The image display device according to claim 1, further comprising an electromagnetic wave shielding layer having a function of shielding electromagnetic waves.

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