JP5620173B2 - Cell stack device, fuel cell module and fuel cell device - Google Patents

Description

  The present invention relates to a cell stack device, a fuel cell module, and a fuel cell device that generate power using fuel gas generated by a reformer.

  2. Description of the Related Art Recently, various types of fuel cell modules in which fuel cell cells capable of obtaining power using fuel gas (hydrogen-containing gas) and air (oxygen-containing gas) are stored in storage containers as next-generation energy generation devices. Proposed.

  In generating a hydrogen-containing gas to be supplied to a fuel battery cell, for example, a steam reforming method is known in which a hydrocarbon such as natural gas is reacted with steam to generate hydrogen. It is equipped with a reformer for quality.

  The reformer described in Patent Document 1 has a vaporization section in the center of a cylindrical container, and has reforming sections on both sides of the container. The raw fuel is vaporized as necessary in the vaporization section, then flows to the reforming sections located on both sides of the container, and is reformed by the reforming catalyst provided in the reforming section to generate fuel gas. Is done. Since one reformer has two reforming sections, a reforming reaction can be performed efficiently.

International Publication No. 2009/119616

  In the reformer described in Patent Document 1, the raw fuel gas vaporized in the central vaporization section flows into the reforming sections on both sides and is reformed. The distribution of the raw fuel gas depends on the gas pressure. Therefore, if the pressure is non-uniform in the reformer, the distribution of the raw fuel gas flowing to both sides is non-uniform. If the distribution becomes non-uniform, the fuel gas generated in each reforming unit becomes non-uniform, and the supply of the fuel gas to the cell stack becomes non-uniform, resulting in a decrease in power generation efficiency.

  An object of the present invention is to provide a cell stack device, a fuel cell module, and a fuel cell device in which power generation efficiency is improved by uniformly supplying fuel gas generated by a reformer.

The cell stack device of the present embodiment is a cell stack formed by arranging and electrically connecting a plurality of fuel cells,
A gas case for fixing a lower end of the fuel cell and supplying fuel gas to the fuel cell;
A hollow container body that is disposed at a predetermined interval from the upper end of the fuel cell constituting the cell stack, and whose interior is vertically divided into one region and the other region by a partition member , The other region communicates with both end portions of the partition member, and the one region is disposed on the cell stack side and vaporizes raw fuel supplied from outside to generate raw fuel gas. The other region includes a reformer that is disposed on the vaporization unit and is a reformed gas generation unit that reforms the raw fuel gas generated in the vaporization unit to generate fuel gas. .

The fuel cell module of the present embodiment includes a storage container,
And the cell stack device stored in the storage container.

Further, the fuel cell device of the present embodiment includes an exterior case,
The above fuel cell module housed in the exterior case;
And an auxiliary machine for operating the fuel cell module.

According to the cell stack device of the present embodiment, the cell stack is configured by arranging and electrically connecting a plurality of fuel cells , and a gas case fixes the lower end of the fuel cell , and the fuel cell. Supply fuel gas to the cell.

The reformer is a hollow container body that is disposed at a predetermined interval from the upper end of the fuel cell constituting the cell stack, and whose interior is vertically divided into one region and the other region by a partition member. Thus, the one region and the other region communicate with each other at both end portions of the partition member . The one region is a vaporization unit that is disposed on the cell stack side and vaporizes raw fuel supplied from the outside to generate raw fuel gas, and the other region is disposed on the vaporization unit, and the vaporization It is a reformed gas generation unit that generates a fuel gas by reforming the raw fuel gas generated in the unit.

The raw fuel gas and water vapor vaporized in the vaporization section flow into the central portion as fuel gas while causing a reforming reaction from both ends of the partition member of the container body in the reformed gas generation section. Thereby, it can prevent that the fuel gas supplied to a gas case from a reformed gas production | generation part becomes non-uniform | heterogenous, and can improve electric power generation efficiency.

  Further, according to the fuel cell module and the fuel cell device of the present embodiment, the fuel cell module and the fuel cell device with improved power generation efficiency can be provided by including the cell stack device that can improve the power generation efficiency.

It is a perspective view which shows the external appearance of the cell stack apparatus 1 which is 1st Embodiment of this invention. It is sectional drawing which shows the structure of the modifier 14 cut | disconnected by cut surface line AA of FIG. It is sectional drawing of the reformer 15 with which the cell stack apparatus 1 which is 2nd Embodiment of this invention is provided. It is sectional drawing of the reformer 16 with which the cell stack apparatus 1 which is 3rd Embodiment of this invention is provided. It is an external appearance perspective view which shows the fuel cell module 22 of the 4th Embodiment of this invention. 2 is a cross-sectional view schematically showing an example of a fuel cell module 22. FIG. It is an external appearance perspective view which extracts and shows a part of side surface side and bottom face side among the storage containers 23 shown in FIG. It is a perspective view which shows the fuel cell apparatus 120 which is the 5th Embodiment of this invention.

Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the drawings.
FIG. 1 is a perspective view showing an appearance of a cell stack device 1 according to the first embodiment of the present invention. FIG. 2 is a cross-sectional view showing the configuration of the reformer 14 cut along the cutting plane line AA of FIG.

  The cell stack device 1 includes a reformer 14 that reforms the raw fuel after being vaporized to generate fuel gas, a cell stack 18 that is formed by electrically connecting a plurality of fuel cells 17, And a manifold 20 which is a gas case for supplying fuel gas to the fuel battery cell 17.

  Although details of the reformer 14 will be described later, for example, a hydrogen gas obtained by steam reforming the vaporized raw fuel gas and a vaporizing section that vaporizes raw fuel and water such as natural gas, methanol, kerosene, etc., which are hydrocarbon gases. And a reforming section that generates a fuel gas containing the fuel gas and disposed above the fuel cell 17 (cell stack 18) at a predetermined interval.

  The cell stack 18 is configured such that a plurality of fuel cells 17 each having a gas flow path are erected and are electrically connected with a current collecting member (not shown) interposed therebetween. .

  The manifold 20 as a gas case fixes the lower end of the fuel cell 17 constituting the cell stack 18 and supplies the fuel gas generated by the reformer 14 to each fuel cell 17.

The reformer 14 includes a hollow container body 2, a partition member 3 provided inside the container body 2, and a raw fuel supply pipe 4. The container body 2 is divided into an upper region (one region) and a lower region (the other region) by a partition member 3 , and the one region and the other region communicate with each other at both end portions of the partition member 3. ing. For example, in the rectangular parallelepiped container body 2, between the two side parts facing each other, in this embodiment, the two side parts 2 a and 2 b that form the short side when the container body 2 is viewed from above, and the partition member 3. The one region and the other region communicate with each other through the communication passages 3a and 3b formed in the above. In the container body 2, the other region on the lower side serves as the vaporization unit 5, and the one region on the upper side serves as the reformed gas generation unit 6.

  The raw fuel supply pipe 4 of the present embodiment is made of a cylindrical member, penetrates the center of the upper wall 2c of the container body 2 in the thickness direction, and further penetrates the reformed gas generator 6 and opens to the vaporizer 5. To be provided. The raw fuel supply pipe 4 communicates the outside of the reformer 14 with the vaporizer 5. Raw fuel and water (or water vapor) are introduced from one open end of the raw fuel supply pipe 4 and supplied to the vaporizer 5 through the raw fuel supply pipe 4.

The lower vaporization unit 5 vaporizes the supplied raw fuel and water as necessary. Central to the supplied raw fuel and water vaporization portion 5 flows into both ends of the partition member 3 becomes vaporized in the raw fuel gas and steam, reforming through communication passage 3a, and 3b at both ends It flows into the gas generator 6. In the upper reformed gas generation unit 6, the reforming catalyst 6a disposed inside contacts with the raw fuel gas and the steam to cause a steam reforming reaction. In the steam reforming reaction, a reformed gas containing carbon monoxide, carbon dioxide, and hydrogen, and methane and steam as remaining components is obtained.

  The above-described reformed gas generated by the steam reforming reaction moves from both ends of the container body 2 toward the central portion, and is supplied from the central portion of the container body 2 to the manifold 20 through the fuel gas supply pipe 7. The

  The fuel gas supply pipe 7 is provided at one end of two side portions of the container body 2 facing each other, in the center of the two side portions 2d and 2e forming the long sides when the container body 2 is viewed from above in this embodiment. Are connected, and the other end is connected to the central portion of the manifold 20. One end of the fuel gas supply pipe 7 is connected to the side parts 2 d and 2 e and opens to the reformed gas generation part 6. The other end of the fuel gas supply pipe 7 opens into the manifold 20. The generated reformed gas continuously flows into the central portion of the reformed gas generator 6 and is continuously discharged to the fuel gas supply pipe 7.

  In the reformer 14 of the present embodiment, the raw fuel gas and water vapor flow from the both ends of the container body 2 into the central portion as the fuel gas while undergoing a reforming reaction. It is possible to prevent the supplied fuel gas from becoming non-uniform and improve the power generation efficiency.

  Further, since the entire upper side of the container body 2 can be used as the reformed gas generator 6, the reforming reaction can be efficiently generated.

  As the reforming catalyst 6a disposed inside the reformed gas generation unit 6, it is preferable to use a reforming catalyst excellent in reforming efficiency and durability. For example, γ-alumina, α-alumina, cordierite, etc. A reforming catalyst in which a noble metal such as Ru or Pt or a base metal such as Ni or Fe is supported on a porous carrier made of any one of the above can be used. As the reforming catalyst 6a, a generally known reforming catalyst can be used as appropriate in accordance with the reforming reaction performed in the reformed gas generation unit 6.

  The inner wall of the reformed gas generator 6, the surface of the partition member 3, and a fixing member (not shown) so that the reformed catalyst 6a does not fall from the reformed gas generator 6 to the vaporizer 5 through the communication passages 3a and 3b. If it is not fixed, the communication passages 3a and 3b may be covered with a member that has sufficient air permeability to allow the fuel gas and water vapor to pass therethrough and cannot pass the reforming catalyst 6a. preferable.

  A fuel gas supply pipe 7 is connected to the center of both sides of the manifold 20, and a fuel gas containing hydrogen gas supplied through the fuel gas supply pipe 7 is supplied from the manifold 20 to each fuel cell 17.

  On both ends of the cell stack 18, current collecting members 19 having current drawing portions for collecting the current generated by the power generation of the fuel cell 17 and drawing it to the outside are arranged.

  Further, in the cell stack apparatus 1 shown in FIG. 1, the reformer 14 and the manifold 20 are connected by the two fuel gas supply pipes 7, so that the reformer 14 and the manifold 20 are firmly connected. Can be connected.

  Further, the cell stack device 1 is configured to burn excess fuel gas that has not been used for power generation in the combustion region on the upper end side of the fuel battery cell 17, and the vaporizer 5 of the reformer 14 performs this combustion. A reformer 14 is provided so as to face the region.

  By arranging the reformer 14 in this way, the temperature of the vaporizing section 5 of the reformer 14 can be raised by the combustion heat generated in the combustion region. Thereby, the reforming reaction can be efficiently performed in the reformer 14.

  Although heat is generated in the fuel cell 17 (cell stack 18) with the power generation of the fuel cell 17, the heat generated by the power generation is dissipated from between adjacent fuel cells 17 or the like.

  However, in a cell stack 18 in which a plurality of fuel cells 17 are juxtaposed and electrically connected in series, the fuel cells arranged at the end in the arrangement direction of the fuel cells 17 constituting the cell stack 18. 17 is easy to dissipate heat, but since the fuel cell 17 disposed on the center side in the arrangement direction of the fuel cells 17 constituting the cell stack 18 is difficult to dissipate, the cell stack 18 as a whole is located on the center side in the cell arrangement direction. May cause a non-uniform temperature distribution in which the temperature at the end in the arrangement direction is low.

  Further, in the configuration in which a combustion region is provided on the upper end portion side of the fuel battery cell 17 and the surplus fuel gas discharged from the fuel battery cell 17 is burned, the temperature on the upper end portion side of the fuel battery cell 17 is high, and the lower end side May cause a non-uniform temperature distribution with a low temperature.

  Here, in the cell stack apparatus 1 shown in FIG. 1, since the reformer 14 for performing the steam reforming is disposed above the cell stack 18, the vaporization unit 5 of the reformer 14 It is arranged on the cell stack 18 side. Since the raw fuel and water are supplied to the central part of the vaporizing unit 5, the temperature of the central part of the vaporizing unit 5 is relatively lower than both ends. By arranging the reformer 14 above the cell stack 18, the temperature on the center side of the cell stack 18 (particularly the upper end side of the fuel cell 17 located on the center side) can be lowered. The temperature distribution in the arrangement direction of the fuel cells 17 constituting the cell stack 18 can be made closer to a uniform distribution. In addition, the temperature distribution in the vertical direction of the fuel cells 17 can be made closer to a uniform distribution. Thereby, the cell stack apparatus 1 which can improve the power generation efficiency of the cell stack 18 is realizable.

  In FIG. 1, the fuel battery cell 17 is a hollow flat plate type having a gas flow path through which fuel gas (hydrogen-containing gas) flows in the longitudinal direction. A fuel side electrode layer, A solid oxide fuel cell 17 in which a solid electrolyte layer and an oxygen side electrode layer are provided in this order is illustrated.

  In particular, when the solid oxide fuel cell 17 is used as the fuel cell 17, the power generation temperature of the fuel cell 17 is as high as about 600 ° C. to 1000 ° C., and accordingly the fuel cell 17 The temperature distribution in the arrangement direction and the temperature distribution in the vertical direction of the fuel cells 17 are likely to be non-uniform.

  Here, in the cell stack apparatus 1 described above, the temperature on the center side of the cell stack 18 (particularly, the upper end side of the fuel cell 17 positioned on the center side) can be lowered. It is possible to make the temperature distribution in the arrangement direction of the fuel battery cells 17 constituting the above and the temperature distribution in the vertical direction of the fuel battery cells 17 more uniform. Therefore, it is particularly useful when a solid oxide fuel cell is used as the fuel cell 17.

  As the fuel cell 17, in addition to the above, for example, a cylindrical or flat fuel cell can be used, and an oxygen side electrode layer, a solid electrolyte layer, and a fuel side electrode layer are sequentially provided on the surface of the support. A solid oxide fuel cell can be obtained.

  FIG. 3 is a cross-sectional view of the reformer 15 provided in the cell stack device 1 according to the second embodiment of the present invention. The second embodiment is different from the first embodiment only in the configuration of the reformer 15, and the other configurations are the same. Therefore, about 2nd Embodiment, only the structure of the reformer 15 is demonstrated and description of another structure is abbreviate | omitted.

  In this embodiment, the adjustment member 4a for adjusting so that the raw fuel supplied to the vaporization part 5 flows equally toward the both ends of the vaporization part 5 is provided. The adjustment member 4a is a so-called baffle plate provided at the tip of the raw fuel supply pipe 4 on the vaporization section 5 side, and a blowing hole 4b is formed on the side wall of the raw fuel supply pipe 4 immediately before the adjustment member 4a. Provided. The flow direction of the raw fuel flowing along the axial direction of the raw fuel supply pipe 4 is changed by the adjusting member 4a in a direction substantially perpendicular to the axial direction, that is, in the longitudinal direction of the container body 2, and provided on the side wall of the pipe. It can flow toward the both ends of the container body 2 from the blowing hole 4b.

  By providing the adjusting member 4 a, the raw fuel supplied from the raw fuel supply pipe 4 can be evenly flown toward the both ends where the communication paths 3 a and 3 b are provided, and both ends of the reformed gas generation unit 6 are supplied to both ends. The amounts of raw fuel gas and water vapor flowing in from the sides can be made equal. Thereby, since a uniform reforming reaction can be caused in the reformed gas generation unit 6, the temperature distribution in the reformed gas generation unit 6 can be made uniform.

  In order to efficiently supply the raw fuel supplied from the raw fuel supply pipe 4 to both ends, it is preferable to provide the raw fuel supply pipe 4 so as to protrude into the vaporization section 5.

  In addition to the baffle plate as described above, a member that can flow the raw fuel in the opposite direction, such as a bifurcated tube, can be used as the adjustment member 4a.

  In providing the adjustment member 4 a, it is preferable that the blowout hole 4 b is provided so as not to face the bottom surface of the vaporizing unit 5. When the blowing hole 4b faces the bottom surface of the vaporizing unit 5 and the raw fuel is directly sprayed on the bottom surface, the temperature of a part of the vaporizing unit 5 may be drastically decreased, and the vaporization efficiency in the vaporizing unit 5 may be decreased. is there. In particular, when the reformer 15 is disposed above the fuel battery cell 17, the temperature of the fuel battery cell 17 at the position facing the bottom surface where the temperature has decreased sharply decreases, and the power generation efficiency of the fuel battery cell is reduced. May decrease.

  By providing the blowout hole 4 b so as not to face the bottom surface of the vaporization unit 5, it is possible to suppress a decrease in the temperature of a part of the vaporization unit 5, and the reformer 15 is disposed above the fuel cell 17. When it does, it can suppress that the temperature of the fuel cell 17 located under the vaporization part 5 falls rapidly.

  The adjustment member 4a is not configured to be directly connected to the raw fuel supply pipe 4, but may be configured to be suspended from the lower surface of the partition member 3, for example.

  FIG. 4 is a cross-sectional view of the reformer 16 provided in the cell stack device 1 according to the third embodiment of the present invention. The third embodiment is different from the first embodiment only in the configuration of the reformer 16, and the other configurations are the same. Therefore, about 3rd Embodiment, only the structure of the reformer 16 is demonstrated and description of another structure is abbreviate | omitted.

  In the present embodiment, the reformer 16 includes flow direction adjusting members 8 for flowing the raw fuel gas generated in the vaporizer 5 to the reformed gas generator 6 at both ends of the vaporizer 5.

  The flow direction adjusting member 8 is provided in the vicinity of the connecting portion between the bottom portion 2f of the container body 2 and the side portions 2a and 2b at both ends of the vaporizing portion 5, and is inclined with respect to the bottom portion 2f and the side portions 2a and 2b. It has an inclined surface 8a.

  The raw fuel supplied to the vaporization unit 5 through the raw fuel supply pipe 4 flows along the surface of the bottom 2f while being vaporized from the center to both ends. This flow suddenly changes in the upward direction due to the collision of the raw fuel gas with the side portions 2a and 2b perpendicular to the flow direction, and flows into the reformed gas generation unit 6 from the communication passages 3a and 3b. Due to this sudden change in the flow direction, the raw fuel gas and water vapor stay in the vicinity of the side portions 2a and 2b, and the inflow to the reformed gas generating unit 6 is prevented, or reformed gas is generated from the communication passages 3a and 3b, respectively. There is a possibility that the inflow amount flowing into the portion 6 becomes non-uniform. When the supply speed of the raw fuel is relatively slow, the flow direction of the raw fuel gas changes gently and flows into the reformed gas generation unit 6. However, when the supply speed increases, such a problem occurs.

  Due to the inclined surface 8a, the flow direction adjusting member 8 gently changes the flow direction of the raw fuel gas in the vicinity of the side portions 2a and 2b even when the supply speed of the raw fuel is high, and the side portions 2a and 2b. A stay in the vicinity is prevented, and a uniform inflow at both ends to the reformed gas generation unit 6 is realized.

  FIG. 5 is an external perspective view showing a fuel cell module 22 according to a fourth embodiment of the present invention in which the above-described cell stack device 1 is stored in a storage container 23. In FIG. 5, the reformers 14, 15, 16 are provided on the inner surface side of the upper wall of the storage container 23, and the cell stack device 1 is in a state in which the reformers 14, 15, 16 are removed. Show.

  Also, in the fuel cell module 22 shown in FIG. 5, a part (front and rear surfaces) of the storage container 23 is removed, and the cell stack device 1 (in FIG. 5, the reformers 14, 15, 16 are removed). Shows the state of taking it out backward. Below, the storage container 23 which comprises the fuel cell module 22 is demonstrated.

  6 is a cross-sectional view schematically showing an example of the fuel cell module 22, and FIG. 7 is an external perspective view showing a part of the side surface and bottom surface of the storage container 23 shown in FIG. .

  In the storage container 23 constituting the fuel cell module 22, an outer frame of the storage container 23 is formed on the outer wall 24, and a power generation chamber 31 that stores the fuel battery cell 17 (cell stack 18) is formed inside.

  In such a storage container 23, air or exhaust gas is allowed to flow between the side portion along the arrangement direction of the fuel cells 17 constituting the cell stack 18 and the outer wall 24 of the storage container 23 facing the side portion. The flow path for this is provided.

  Here, in the storage container 23, the first wall 25 is formed inside the outer wall 24 with a predetermined interval, and the second wall 26 is arranged inside the first wall 25 with a predetermined interval. Furthermore, a third wall 27 is arranged inside the second wall 26 with a predetermined interval.

  Thereby, the space formed between the outer wall 24 and the first wall 25 becomes the first flow path 28, and the space formed between the second wall 26 and the third wall 27 is the second. And the space formed between the first wall 25 and the second wall 26 becomes the third flow path 30.

  In the storage container 23 shown in FIG. 6, the upper end of the first wall 25 is connected to the second wall 26, and the second wall 26 is connected to the upper wall (outer wall 24) of the storage container 23. The upper end of the third wall 27 is connected to the second wall 26.

  An air supply pipe 32 for supplying oxygen-containing gas (air) into the storage container 23 is connected to the bottom of the storage container 23, and the air supplied from the air supply pipe 32 is provided at the bottom. The air flows into the air inlet 38. The air introduction part 38 communicates with the first flow path 28 through the air introduction port 39, and the air flowing through the air introduction part 38 flows into the first flow path 28 through the air introduction port 39. . The air flowing in from the lower part flows upward in the first flow path 28 and flows into the second flow path 29 through the air circulation port 33 provided in the upper part of the second wall 26. The air flowing in from the upper part flows downward in the second flow path 29 and is supplied into the power generation chamber 31 through the air supply port 34 provided in the lower part of the third wall 27.

  On the other hand, the exhaust gas discharged from the fuel cell 17 and the exhaust gas generated by burning surplus fuel gas in the combustion region 17a at the upper end of the fuel cell 17 are formed in the air circulation port 33 above the second wall 26. It flows into the third flow path 30 through the exhaust gas flow port 35 provided below. The exhaust gas flowing in from the top flows downward through the third flow path 30, passes through the exhaust gas collection port 41 provided in the lower part, and collects the exhaust gas provided at the bottom adjacent to the air supply pipe 32. It flows into the section 40 and is exhausted to the outside of the storage container 23 through the exhaust gas exhaust pipe 36 (see FIG. 5) connected to the exhaust gas collection section 40.

  The air supplied from the air supply pipe 32 undergoes heat exchange with the exhaust gas flowing through the exhaust gas collection unit 40 while flowing through the air introduction unit 38, and passes through the third flow channel 30 while flowing through the first flow channel 28. While exchanging heat with the flowing exhaust gas and flowing through the second flow path 29, heat is exchanged between the exhaust gas flowing through the third flow path 30 and the power generation chamber 31.

  Thereby, the temperature of the air can be increased efficiently, and the heated air can be supplied to the fuel battery cell 17, so that the power generation efficiency of the fuel battery cell 17 can be improved.

  Further, by configuring the fuel cell module 22 to burn surplus fuel gas in the combustion region 17a of the fuel cell 17, the reformers 14 and 15 are caused by combustion heat generated by burning surplus fuel gas. , 16 can be raised. Thereby, the reforming reaction can be efficiently performed in the reformers 14, 15, and 16.

  FIG. 7 shows an example in which a plurality of air circulation ports 33 and exhaust gas circulation ports 35 are provided. With such a configuration, the air flowing through the first flow path 28 efficiently flows into the second flow path 29 and is supplied into the power generation chamber 31. Further, the exhaust gas in the power generation chamber 31 can efficiently flow through the third flow path 30 and be exhausted to the outside of the storage container 23.

  In addition, the heat insulating material 37 arranged on both side surfaces of the cell stack 18 (fuel cell 17) is provided with holes for flowing air to the fuel cell 17 side corresponding to the air supply port 34. ing.

  The air supplied from the air supply port 34 into the power generation chamber 31 flows from the lower end side to the upper end side of the fuel cell 17, and a part of the air is disposed between the fuel cells 17. The inside of the electric member flows from the lower end side toward the upper end side, so that the fuel cell 17 can generate power efficiently.

  Note that the heat insulating material 37 can be provided as appropriate so that the temperature of the fuel cell 17 (cell stack 18) is not lowered due to the extreme heat dissipation of the storage container 23 and the power generation amount is not reduced. Are provided at the bottom of the manifold 20, on both side surfaces of the fuel cell 17 (cell stack 18), and between the upper wall (outer wall 24) of the storage container 23 and the reformers 14, 15, 16. An example is shown. That is, the reformers 14, 15, 16 are connected to the inner surface of the upper wall (outer wall 24) of the storage container 23 via the heat insulating material 37.

  FIG. 6 shows an example in which the cell stack device 1 having the cell stack 18 in one row is housed in the power generation chamber 31. In this case, air is introduced from both side surfaces of the fuel cell 17. Become.

  6 shows an example in which the air supply pipe 32 and the exhaust gas exhaust pipe 36 are provided with their positions shifted from each other, but the exhaust gas exhaust pipe 36 may be provided inside the air supply pipe 32. .

  FIG. 8 is a perspective view showing a fuel cell device 120 according to the fifth embodiment of the present invention. In FIG. 8, a part of the configuration is omitted.

  As shown in FIG. 8, the fuel cell device 120 divides the interior of the exterior case composed of the support columns 121 and the exterior plate 122 by a partition plate 123 and houses the above-described fuel cell module 22 on the upper side. A module storage chamber 124 is provided, and the lower side is configured as an auxiliary machine storage chamber 125 that stores auxiliary equipment for operating the fuel cell module. In addition, the auxiliary machine accommodated in the auxiliary machine storage chamber 125 is abbreviate | omitted.

  Further, the partition plate 123 is provided with an air circulation port 126 for flowing the air in the auxiliary machine storage chamber 125 to the module storage chamber 124 side, and a part of the exterior plate 122 constituting the module storage chamber 124 An exhaust port 127 for exhausting air in the module storage chamber 124 is provided.

  In such a fuel cell device 120, as described above, the fuel cell module 22 capable of improving the power generation efficiency is configured to be stored in the module storage chamber 124, thereby improving the power generation efficiency. 120.

  Although the present invention has been described in detail above, the present invention is not limited to the above-described embodiments, and various modifications and improvements can be made without departing from the scope of the present invention.

  For example, as the cell stack device 1 stored in the storage container 23, the example in which only one cell stack 18 in which a plurality of fuel cells 17 are arranged is arranged on the manifold 20 is shown above. Two 18 can be juxtaposed. In this case, air is supplied to the fuel cell 17 from the air supply port 34 located on the side surface side of each cell stack 18.

  Further, for example, the storage container 23 forms a first flow path 28 between the outer wall 24 and the first wall 25, and a second flow path between the second wall 26 and the third wall 27. 29, and the third flow path 30 may be formed between the first wall 25 and the second wall 26, and the positions of the air circulation port and the exhaust gas circulation port can be changed as appropriate. .

DESCRIPTION OF SYMBOLS 1 Cell stack apparatus 2 Container body 3 Partition member 4 Raw fuel supply pipe 4a Adjustment member 5 Vaporization part 6 Reformed gas generation part 6a Reforming catalyst 7 Fuel gas supply pipe 8 Direction adjustment member 8a Inclined surface 14, 15, 16 Reformation 17 Fuel cell 17a Combustion region 18 Cell stack 19 Current collecting member 20 Manifold 22 Fuel cell module 23 Storage container 120 Fuel cell device

Claims (8)

A cell stack in which a plurality of fuel cells are arranged and electrically connected;
A gas case for fixing a lower end of the fuel cell and supplying fuel gas to the fuel cell;
A hollow container body that is disposed at a predetermined interval from the upper end of the fuel cell constituting the cell stack, and whose interior is vertically divided into one region and the other region by a partition member , The other region communicates with both end portions of the partition member, and the one region is disposed on the cell stack side and vaporizes raw fuel supplied from outside to generate raw fuel gas. The other region includes a reformer that is disposed on the vaporization unit and is a reformed gas generation unit that reforms the raw fuel gas generated in the vaporization unit to generate fuel gas. A cell stack apparatus characterized by that. Wherein between the reformer and the cell stack, the cell stack device according to claim 1, wherein Tei Rukoto is a combustion region for combusting the fuel gas that was not used for power generation of the fuel cell.   The reformer includes a raw fuel introduction pipe for introducing the raw fuel from the outside into the vaporization unit, the external gas and the vaporization unit communicating with each other through the reformed gas generation unit. The cell stack apparatus according to claim 2. The reformer has one end connected to a central portion viewed from the side of the reformed gas generation unit and the other end connected to a central portion viewed from the side of the gas case. The cell stack device according to any one of claims 1 to 3, further comprising a fuel gas supply pipe for supplying the reformed gas generation unit to the gas case.   The said reformer is provided with the adjustment member for adjusting so that the said raw fuel supplied to the said vaporization part may flow toward the both ends of the said vaporization part, The any one of Claims 1-4 characterized by the above-mentioned. The cell stack apparatus according to one.   The said reformer is provided with the flow direction adjusting member for flowing the said raw fuel gas produced | generated by this vaporization part to the said reformed gas production | generation part in the both ends of the said vaporization part. The cell stack apparatus as described in any one of -5. A storage container;
A fuel cell module comprising the cell stack device according to any one of claims 1 to 6 housed in the housing container. An exterior case,
The fuel cell module according to claim 7 housed in the exterior case;
A fuel cell apparatus comprising: an auxiliary machine for operating the fuel cell module.

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