JP5602514B2 - NOx concentration measuring device - Google Patents

NOx concentration measuring device Download PDF

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JP5602514B2
JP5602514B2 JP2010145814A JP2010145814A JP5602514B2 JP 5602514 B2 JP5602514 B2 JP 5602514B2 JP 2010145814 A JP2010145814 A JP 2010145814A JP 2010145814 A JP2010145814 A JP 2010145814A JP 5602514 B2 JP5602514 B2 JP 5602514B2
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仁一 南川
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Hino Motors Ltd
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本発明は、NOx濃度測定装置に関するものである。   The present invention relates to a NOx concentration measuring apparatus.

従来より、ディーゼルエンジンにおいては、排気ガスが流通する排気管の途中に、酸素共存下でも選択的にNOxを還元剤と反応させる性質を備えた選択還元型触媒を装備し、該選択還元型触媒の上流側に必要量の還元剤を添加して該還元剤を選択還元型触媒上で排気ガス中のNOx(窒素酸化物)と還元反応させ、これによりNOxの排出濃度を低減し得るようにしたものがある。   Conventionally, a diesel engine is equipped with a selective reduction catalyst having a property of selectively reacting NOx with a reducing agent even in the presence of oxygen in the middle of an exhaust pipe through which exhaust gas flows, and the selective reduction catalyst A required amount of a reducing agent is added to the upstream side of the catalyst so that the reducing agent undergoes a reduction reaction with NOx (nitrogen oxide) in the exhaust gas on the selective catalytic reduction catalyst, thereby reducing the NOx emission concentration. There is what I did.

このような選択還元型触媒を用いて排気ガス中のNOxを還元浄化しようとした場合、排気管の途中にNOxセンサを装備してNOxの濃度を計測し、その計測値に応じて還元剤の添加量を制御することが行われている(例えば下記の特許文献1参照)。   When attempting to reduce and purify NOx in exhaust gas using such a selective catalytic reduction catalyst, a NOx sensor is installed in the middle of the exhaust pipe to measure the concentration of NOx, and according to the measured value, the reducing agent concentration is reduced. Control of the amount of addition is performed (for example, refer to the following Patent Document 1).

一般的に、NOxセンサは、6層のジルコニア膜を積層した構成となっており、この種のジルコニア膜には、該ジルコニア膜の両面に形成された電極間に印加された電圧に応じて酸素イオンの移動が起こるという酸素ポンプ特性と、ジルコニア膜の内外の酸素濃度差に応じた起電力が発生するという酸素濃淡電池特性とがあるので、これらの特性を応用して排気ガス中のNOxの量を検出するようにしている。   In general, the NOx sensor has a structure in which six layers of zirconia films are laminated. This type of zirconia film has an oxygen gas depending on the voltage applied between the electrodes formed on both sides of the zirconia film. There are oxygen pump characteristics that cause ion migration and oxygen concentration cell characteristics that an electromotive force is generated according to the difference in oxygen concentration inside and outside the zirconia membrane. By applying these characteristics, the NOx concentration in the exhaust gas I try to detect the amount.

即ち、前記NOxセンサでは、2層目に排気ガスが導入される第一空間及び第二空間が連続して設けられ、4層目には大気中の酸素濃度と参照させるための空気通路が設けられており、5層と6層との間にはセンサ温度を加熱制御するための内部ヒータが設置された構造となっている。   That is, in the NOx sensor, a first space and a second space into which exhaust gas is introduced are provided continuously in the second layer, and an air passage for referring to the oxygen concentration in the atmosphere is provided in the fourth layer. An internal heater for controlling the sensor temperature is installed between the 5th and 6th layers.

排気ガスが最初に導かれる第一空間では、1層目のジルコニア膜を電圧の印加により酸素ポンプとして作動させて排気ガス中のO2を取り除き且つNO2をNOに還元するようになっている。この時、NOまで分解させないように第一空間内の酸素濃度を一定にする前記酸素ポンプの性能制御が行われる。 In the first space where the exhaust gas is first guided, the first zirconia film is operated as an oxygen pump by applying a voltage to remove O 2 in the exhaust gas and reduce NO 2 to NO. . At this time, the performance control of the oxygen pump is performed to keep the oxygen concentration in the first space constant so as not to decompose to NO.

この結果、第一空間でNO以外の酸素イオンが全て取り除かれた排気ガスが第二空間へ移動するので、該第二空間にて3層目のジルコニア膜を電解質としたNOの電気分解を行い且つその分解時に3層目のジルコニア膜を酸素濃淡電池として第二空間と大気雰囲気の空気通路との間の酸素濃度差に応じて流れる電流を計測する。   As a result, the exhaust gas from which all oxygen ions other than NO have been removed in the first space moves to the second space, so that NO electrolysis is performed using the third layer zirconia film as the electrolyte in the second space. At the time of decomposition, the third layer zirconia film is used as an oxygen concentration cell, and the current flowing in accordance with the oxygen concentration difference between the second space and the air passage in the atmospheric atmosphere is measured.

第二空間における電気分解の際の酸素源はNOしか存在しておらず、この際に計測される電流はNOに相当した量となるので、その電流値に基づき排気ガス中のNOx濃度を制御装置内で演算処理して算出することができる。   Since only NO is present as the oxygen source during electrolysis in the second space, the current measured at this time is an amount corresponding to NO, so the NOx concentration in the exhaust gas is controlled based on the current value. It can be calculated by performing arithmetic processing in the apparatus.

特開2006−57576号公報JP 2006-57576 A

しかしながら、制動時に排気流路を閉じて排気抵抗を高めることで排気行程でもピストン圧縮を行わしめてエンジンブレーキの効果を高めるようにした排気ブレーキがNOxセンサより下流側の排気管に備えられている場合、前記排気ブレーキの作動時に前記NOxセンサが異常値を出力してしまうという不具合があり、実際にはアクセルオフの制動状態となっていてNOxが殆ど発生していない状況(燃料無噴射)であるにもかかわらず、前記NOxセンサの異常値に基づいて過剰な還元剤の添加が実施されてしまうという問題があった。   However, if the exhaust pipe downstream of the NOx sensor is equipped with an exhaust brake that closes the exhaust flow path and increases the exhaust resistance during braking to increase the engine braking effect by compressing the piston even during the exhaust stroke. There is a problem in that the NOx sensor outputs an abnormal value when the exhaust brake is operated, and the actual situation is that the accelerator is off and almost no NOx is generated (no fuel injection). Nevertheless, there is a problem in that excessive reducing agent is added based on the abnormal value of the NOx sensor.

即ち、車型等によっては、エンジンルーム内におけるレイアウト上の制約により排気ブレーキの上流側にしかNOxセンサの配置スペースを確保できない場合があるが、このような場合において、排気ブレーキ作動時の圧力上昇によりNOxセンサの第一空間のO2の量が大幅に増加すると、この第一空間のO2が第二空間へも流出してNOxが発生しているかの如き誤計測が起きてしまっていた。 In other words, depending on the vehicle model and the like, there may be a case where the NOx sensor placement space can be secured only upstream of the exhaust brake due to layout restrictions in the engine room. When the amount of O 2 in the first space of the NOx sensor increased significantly, an erroneous measurement occurred as if O 2 in the first space also flowed into the second space and NOx was generated.

より具体的に述べると、第一空間内の酸素濃度は一定に維持されるように酸素ポンプの性能制御が行われているので、この酸素ポンプのための電流値が増やされることになるが、既存のNOxセンサでは、排気ブレーキによる圧力上昇まで想定されていないため、酸素ポンプのための電流値が許容値を超えてショートし、これにより第二空間へのO2の流出が更に増加して計測電流値までもが許容値を超えてショートする結果、NOxセンサが異常値を出力してしまうという現象を招いていた。 More specifically, since the performance control of the oxygen pump is performed so that the oxygen concentration in the first space is kept constant, the current value for this oxygen pump is increased. In the existing NOx sensor, since the pressure increase due to the exhaust brake is not assumed, the current value for the oxygen pump is short-circuited beyond the allowable value, thereby further increasing the outflow of O 2 into the second space. As a result of short-circuiting the measured current value exceeding the allowable value, the phenomenon that the NOx sensor outputs an abnormal value has been caused.

本発明は上述の実情に鑑みてなしたもので、排気ブレーキの作動時にNOxセンサが異常値を出力しても、NOx濃度に基づく制御系に悪影響を及ぼす虞れを未然に回避し得るようにしたNOx濃度測定装置を提供することを目的とする。   The present invention has been made in view of the above-described circumstances, so that even if the NOx sensor outputs an abnormal value when the exhaust brake is operated, the possibility of adversely affecting the control system based on the NOx concentration can be avoided. An object of the present invention is to provide a NOx concentration measuring apparatus.

本発明は、排気ブレーキより上流側の排気管に装備されたNOxセンサと、該NOxセンサの出力信号に基づいてNOx濃度を算出する制御装置とを備えたNOx濃度測定装置において
排気ガスが流通する排気管の途中に選択還元型触媒を装備し、該選択還元型触媒より上流側の排気管に、尿素水を還元剤として噴射する尿素水添加手段が設置され、該尿素水添加手段より上流側の排気管に排気ブレーキが装備され、
前記排気ブレーキの作動信号が検知されている間は前記NOxセンサからの出力信号を一時的に零出力として扱い、この間の尿素水の添加は一時的に中断するように前記制御装置を構成したことを特徴とするNOx濃度測定装置、に係るものである。
The present invention relates to a NOx concentration measuring device including a NOx sensor provided in an exhaust pipe upstream of an exhaust brake, and a control device that calculates a NOx concentration based on an output signal of the NOx sensor.
A selective reduction catalyst is provided in the middle of the exhaust pipe through which the exhaust gas flows, and urea water addition means for injecting urea water as a reducing agent is installed in the exhaust pipe upstream of the selective reduction catalyst, the urea water The exhaust pipe is equipped with an exhaust brake upstream of the adding means.
During the operation signal of the exhaust brake is detected to constitute the control device to the output signal from the NOx sensor handled have a zero temporarily output, is added during this period of the urea water temporarily suspend so The present invention relates to a NOx concentration measuring device characterized by the above.

而して、このようにすれば、排気ブレーキが作動している間に圧力上昇によりNOxセンサが異常値を出力しても、その出力信号は制御装置にて一時的に零出力として扱われるので、前記NOxセンサの異常値に基づいて過剰な尿素水の添加が実施されてしまうといった、NOx濃度に基づく制御系に悪影響を及ぼす虞れが未然に回避されることになり、しかも、排気ブレーキの作動時は、アクセルがオフとなった制動状態になっていて実質的にNOxが生成されない状態となっているため、NOxセンサからの出力信号が一時的に零出力として扱われても、尿素水の添加が一時的に中断されるような、NOx濃度に基づく制御系が機能しないことにより多量のNOxが車外へ排出されてしまうといった不都合を招く虞れはない。 Thus, in this way, even if the NOx sensor outputs an abnormal value due to pressure increase while the exhaust brake is operating, the output signal is temporarily treated as zero output by the control device. In addition, the possibility of adversely affecting the control system based on the NOx concentration, such as excessive addition of urea water based on the abnormal value of the NOx sensor, is avoided, and the exhaust brake during operation, because the accelerator is in a state which is not generated substantially NOx they become braking state turned off, the output signal from the NOx sensor be treated as zero temporarily output, urea water There is no possibility of inconvenience that a large amount of NOx is discharged out of the vehicle because the control system based on the NOx concentration does not function such that the addition of NOx temporarily stops.

上記した本発明のNOx濃度測定装置によれば、排気ブレーキの作動時にNOxセンサが異常値を出力しても、制御装置にてNOxセンサからの出力信号を一時的に零出力として扱うようにしているので、前記NOxセンサの異常値に基づいて過剰な尿素水の添加が実施されてしまうといった、NOx濃度に基づく制御系に悪影響を及ぼす虞れを未然に回避することができるという優れた効果を奏し得る。 According to the above-described NOx concentration measuring device of the present invention, even if the NOx sensor outputs an abnormal value when the exhaust brake is operated, the control device treats the output signal from the NOx sensor as zero output temporarily. Therefore, it is possible to avoid the possibility of adversely affecting the control system based on the NOx concentration, such as excessive urea water being added based on the abnormal value of the NOx sensor. Can play.

本発明を実施する形態の一例を示す概略図である。It is the schematic which shows an example of the form which implements this invention. 図1の制御装置でのNOxセンサ出力の処理に関するフローチャートである。It is a flowchart regarding the process of NOx sensor output in the control apparatus of FIG.

以下本発明の実施の形態を図面を参照しつつ説明する。   Embodiments of the present invention will be described below with reference to the drawings.

図1及び図2は本発明を実施する形態の一例を示すもので、ここに図示している例では、ディーゼルエンジン1から排気マニホールド2を介して排出される排気ガス3が流通する排気管4の途中に、酸素共存下でも選択的にNOxをアンモニアと反応させ得る性質を備えた選択還元型触媒5が装備されている。   1 and 2 show an example of an embodiment of the present invention. In the example shown here, an exhaust pipe 4 through which exhaust gas 3 discharged from a diesel engine 1 through an exhaust manifold 2 flows is shown. In the middle of this, a selective reduction catalyst 5 having the property of selectively reacting NOx with ammonia even in the presence of oxygen is provided.

そして、この選択還元型触媒5より上流側の排気管4に、尿素水6を還元剤として噴射する尿素水添加用インジェクタ7(尿素水添加手段)が設置されていると共に、前記選択還元型触媒5の直後には、リークアンモニア対策として余剰のアンモニアを酸化処理するNH3スリップ触媒8が装備されている。 A urea water addition injector 7 (urea water addition means) for injecting urea water 6 as a reducing agent is installed in the exhaust pipe 4 upstream of the selective reduction catalyst 5 and the selective reduction catalyst. Immediately after 5, an NH 3 slip catalyst 8 that oxidizes excess ammonia as a countermeasure against leaked ammonia is provided.

更に、排気管4の最上流部に、既に従来技術として詳述した通りの既存のNOxセンサ9が装備されていると共に、該NOxセンサ9の下流側には、制動時に排気流路を閉じて排気抵抗を高めることで排気行程でもピストン圧縮を行わしめてエンジンブレーキの効果を高める排気ブレーキ10が装備されている。   Further, an existing NOx sensor 9 as already described in detail as the prior art is installed in the most upstream part of the exhaust pipe 4, and the exhaust passage is closed at the downstream side of the NOx sensor 9 during braking. An exhaust brake 10 is provided that increases the exhaust resistance to increase the effect of the engine brake by compressing the piston even in the exhaust stroke.

また、前記NOxセンサ9の出力信号9aは、エンジン制御コンピュータ(ECU:Electronic Control Unit)を兼ねた制御装置11に入力されるようになっており、該制御装置11において、前記NOxセンサ9からの出力信号9aに基づきNOxの濃度が演算処理により算出されると共に、ここで算出されたNOx濃度に基づき前記尿素水6の添加量が決定されて前記インジェクタ7ヘ向け制御信号7aとして出力されるようになっている。   The output signal 9a of the NOx sensor 9 is input to a control device 11 that also serves as an engine control computer (ECU: Electronic Control Unit). The concentration of NOx is calculated by calculation processing based on the output signal 9a, and the addition amount of the urea water 6 is determined based on the NOx concentration calculated here and is output to the injector 7 as a control signal 7a. It has become.

ここで、尿素水6の添加量を決定するにあたっては、算出されたNOx濃度に基づきNOx生成量を算出する必要があるため、排気ガス3の流量を把握しなければならないが、前記制御装置11は、エンジン制御コンピュータを兼ねていて、ディーゼルエンジン1の回転数や負荷の情報を回転センサ12及びアクセルセンサ13からの検出信号12a,13aに基づき既に持っているので、これらを利用して排気ガス3の流量を算出することで尿素水6の添加量の制御に用いている。   Here, in determining the amount of urea water 6 to be added, it is necessary to calculate the NOx generation amount based on the calculated NOx concentration, so the flow rate of the exhaust gas 3 must be grasped. Also serves as an engine control computer and already has information on the rotational speed and load of the diesel engine 1 based on the detection signals 12a and 13a from the rotation sensor 12 and the accelerator sensor 13, so that exhaust gas can be exhausted using them. 3 is used to control the amount of urea water 6 added.

更に、前記制御装置11は、図示しない運転席の排気ブレーキスイッチ14からのオン信号14aが入力されている条件下で、回転センサ12及びアクセルセンサ13からの検出信号12a,13aに基づき走行中にアクセルオフが検出された際に、排気ブレーキ10の作動信号10aを前記排気ブレーキ10のエア駆動系のマグネチックバルブ15に向け出力して前記排気ブレーキ10を作動させるようになっている。   Further, the control device 11 is in the middle of traveling based on the detection signals 12a and 13a from the rotation sensor 12 and the accelerator sensor 13 under the condition that the ON signal 14a from the exhaust brake switch 14 in the driver's seat (not shown) is input. When the accelerator-off is detected, an operation signal 10a of the exhaust brake 10 is output to the magnetic valve 15 of the air drive system of the exhaust brake 10 to operate the exhaust brake 10.

そして、前記排気ブレーキ10の作動信号10aが制御装置11内で検知されている間は、前記NOxセンサ9からの出力信号9aが一時的に零出力として扱われるようになっており、この間の尿素水6の添加は一時的に中断されるようになっている。   While the operation signal 10a of the exhaust brake 10 is detected in the control device 11, the output signal 9a from the NOx sensor 9 is temporarily treated as zero output. The addition of water 6 is temporarily interrupted.

即ち、図2にフローチャートで示す通り、ステップS1でNOxセンサ9からの出力信号9aが制御装置11で認識されると、次のステップS2で排気ブレーキ10が作動中であるか否かが判定され(マグネチックバルブ15へ向けた作動信号10aの有無の確認)、排気ブレーキ10が作動中であれば、「YES」へ進んでステップS3にてNOxセンサ9からの出力信号9aが一時的に零出力として扱われ、排気ブレーキ10が作動中でなければ、「NO」へ進んでステップS4にてNOxセンサ9からの出力信号9aがそのまま採用されて尿素水6の添加量の制御に用いられるようになっている。   That is, as shown in the flowchart in FIG. 2, when the output signal 9a from the NOx sensor 9 is recognized by the control device 11 in step S1, it is determined whether or not the exhaust brake 10 is in operation in the next step S2. (Confirmation of the presence or absence of the operation signal 10a toward the magnetic valve 15) If the exhaust brake 10 is in operation, the process proceeds to "YES" and the output signal 9a from the NOx sensor 9 is temporarily zero in step S3. If the exhaust brake 10 is not in operation, the process proceeds to “NO” and the output signal 9a from the NOx sensor 9 is adopted as it is in step S4 and used for controlling the amount of urea water 6 added. It has become.

尚、図1中における16は排気ガス3中の未燃燃料分を酸化処理する機能を高めた酸化触媒、17は排気ガス3中のパティキュレートを捕集するパティキュレートフィルタを示し、必要時にディーゼルエンジン1側でメイン噴射に続いて圧縮上死点より遅い非着火のタイミングでポスト噴射を実施し、このポスト噴射により排気ガス3中に未燃の燃料(主としてHC:炭化水素)を添加して酸化触媒16で酸化反応させ、その反応熱でパティキュレートフィルタ17の強制再生を図り得るようにしてある。   In FIG. 1, reference numeral 16 denotes an oxidation catalyst that enhances the function of oxidizing unburned fuel in the exhaust gas 3, and 17 denotes a particulate filter that collects particulates in the exhaust gas 3. After the main injection on the engine 1 side, post injection is performed at a non-ignition timing later than the compression top dead center, and unburned fuel (mainly HC: hydrocarbon) is added to the exhaust gas 3 by this post injection. The oxidation reaction is performed by the oxidation catalyst 16, and the particulate filter 17 can be forcibly regenerated by the reaction heat.

而して、このようにすれば、排気ブレーキ10が作動している間に圧力上昇によりNOxセンサ9が異常値を出力しても、その出力信号9aは制御装置11にて一時的に零出力として扱われるので、前記NOxセンサ9の異常値に基づいて過剰な尿素水6の添加が実施されてしまうといった虞れ(NOx濃度に基づく制御系への悪影響)が未然に回避されることになり、しかも、排気ブレーキ10の作動時は、アクセルがオフとなった制動状態になっていて実質的にNOxが生成されない状態となっているため、NOxセンサ9からの出力信号9aが一時的に零出力として扱われても、尿素水6の添加が一時的に中断されることにより多量のNOxが車外へ排出されてしまうといった不都合を招く虞れはない。   Thus, in this way, even if the NOx sensor 9 outputs an abnormal value due to a pressure increase while the exhaust brake 10 is operating, the output signal 9a is temporarily output by the control device 11 to zero. Therefore, the possibility that excessive urea water 6 is added based on the abnormal value of the NOx sensor 9 (adverse effect on the control system based on the NOx concentration) is avoided in advance. In addition, when the exhaust brake 10 is operated, since the brake is in a state where the accelerator is off and NOx is not substantially generated, the output signal 9a from the NOx sensor 9 is temporarily zero. Even if it is handled as an output, there is no possibility of inconvenience that a large amount of NOx is discharged outside the vehicle due to the temporary interruption of the addition of the urea water 6.

従って、上記形態例によれば、排気ブレーキ10の作動時にNOxセンサ9が異常値を出力しても、制御装置11にてNOxセンサ9からの出力信号9aを一時的に零出力として扱うようにしているので、実際にはアクセルオフの制動状態となっていてNOxが殆ど発生していない状況であるにもかかわらず、前記NOxセンサ9の異常値に基づいて過剰な尿素水6の添加が実施されてしまうといった虞れ(NOx濃度に基づく制御系への悪影響)を未然に回避することができる。   Therefore, according to the above embodiment, even when the NOx sensor 9 outputs an abnormal value when the exhaust brake 10 is operated, the control device 11 temporarily treats the output signal 9a from the NOx sensor 9 as zero output. Therefore, excessive urea water 6 is added based on the abnormal value of the NOx sensor 9 in spite of the fact that the accelerator is off and the NOx is hardly generated. It is possible to avoid the fear that the control system is adversely affected (adverse effects on the control system based on the NOx concentration).

尚、本発明のNOx濃度測定装置は、上述の形態例にのみ限定されるものではなく本発明の要旨を逸脱しない範囲内において種々変更を加え得ることは勿論である。 It should be noted that the NOx concentration measuring device of the present invention is not limited to the above-described embodiments, and various changes can be made without departing from the scope of the present invention.

4 排気管
9 NOxセンサ
9a 出力信号
10 排気ブレーキ
10a 作動信号
11 制御装置
4 Exhaust pipe 9 NOx sensor 9a Output signal 10 Exhaust brake 10a Actuation signal 11 Controller

Claims (1)

排気ブレーキより上流側の排気管に装備されたNOxセンサと、該NOxセンサの出力信号に基づいてNOx濃度を算出する制御装置とを備えたNOx濃度測定装置において
排気ガスが流通する排気管の途中に選択還元型触媒を装備し、該選択還元型触媒より上流側の排気管に、尿素水を還元剤として噴射する尿素水添加手段が設置され、該尿素水添加手段より上流側の排気管に排気ブレーキが装備され、
前記排気ブレーキの作動信号が検知されている間は前記NOxセンサからの出力信号を一時的に零出力として扱い、この間の尿素水の添加は一時的に中断するように前記制御装置を構成したことを特徴とするNOx濃度測定装置。
In a NOx concentration measuring device comprising: a NOx sensor provided in an exhaust pipe upstream from an exhaust brake; and a control device that calculates a NOx concentration based on an output signal of the NOx sensor;
A selective reduction catalyst is provided in the middle of the exhaust pipe through which the exhaust gas flows, and urea water addition means for injecting urea water as a reducing agent is installed in the exhaust pipe upstream of the selective reduction catalyst, the urea water The exhaust pipe is equipped with an exhaust brake upstream of the adding means.
During the operation signal of the exhaust brake is detected to constitute the control device to the output signal from the NOx sensor handled have a zero temporarily output, is added during this period of the urea water temporarily suspend so A NOx concentration measuring device characterized by that.
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