JP5574662B2 - Method for suppressing warming deterioration of fruit juice for warm sale, method for producing fruit juice for warm sale, and fruit juice drink for warm sale - Google Patents

Method for suppressing warming deterioration of fruit juice for warm sale, method for producing fruit juice for warm sale, and fruit juice drink for warm sale Download PDF

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JP5574662B2
JP5574662B2 JP2009230006A JP2009230006A JP5574662B2 JP 5574662 B2 JP5574662 B2 JP 5574662B2 JP 2009230006 A JP2009230006 A JP 2009230006A JP 2009230006 A JP2009230006 A JP 2009230006A JP 5574662 B2 JP5574662 B2 JP 5574662B2
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潤 稲垣
英樹 叶
洋輔 藤井
和之 濱
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株式会社 伊藤園
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本発明は、加温販売用果汁飲料の加温による劣化を抑制する方法、加温販売用果汁飲料を製造する方法、及び加温販売用果汁飲料に関するものである。   The present invention relates to a method for suppressing deterioration due to warming of a juice for warm sale, a method for producing a juice drink for warm sale, and a juice drink for warm sale.

天然果実等の果汁を含有する清涼飲料(果汁飲料)は、店頭や自動販売機等で販売に供される際に冷却されたり、50〜70℃程度に加温されたりしている。このうち、加温販売用の果汁飲料は、加温によりその香味や風味等の品質が劣化したり、液色の褐変等の視覚的変化(色調変化)が生じたりすることがある。   Soft drinks (fruit juice drinks) containing fruit juices such as natural fruits are cooled or warmed to about 50 to 70 ° C. when they are offered for sale in stores or vending machines. Among these, fruit juice beverages for sale with warming may deteriorate in quality such as flavor and flavor due to heating, or may cause visual changes (changes in color tone) such as browning of liquid color.

近年、PETボトル等の透明密閉容器に充填した果汁飲料が普及しており、かかる透明密閉容器による販売に供される場合に、特に液色の褐変のような視覚的変化が生じると商品価値及び商品寿命を低下させてしまうため、視覚的変化に対応することが必要となる。   In recent years, fruit juice beverages filled in transparent sealed containers such as PET bottles have become widespread, and when they are sold for sale by such transparent sealed containers, particularly when a visual change such as browning of liquid color occurs, the commercial value and In order to reduce the product life, it is necessary to cope with visual changes.

このような状況において、従来、茶系飲料に関するものではあるが、茶飲料の調製において、有効成分としてサイクロデキストリンとアスコルビン酸又はアスコルビン酸塩とを配合することにより、加温販売される茶飲料の品質の加温劣化を抑制する方法が提案されている(特許文献1参照)。しかしながら、果汁飲料の加温による品質の劣化や液色の褐変等の色調変化を抑制する方法は、従来提案されていない。   In such a situation, conventionally related to tea-based beverages, in the preparation of tea beverages, by blending cyclodextrin and ascorbic acid or ascorbate as active ingredients, There has been proposed a method for suppressing quality deterioration by heating (see Patent Document 1). However, no method has been proposed in the past to suppress color tone changes such as deterioration of quality due to warming of fruit juice beverages and browning of liquid color.

特開2004−73057号公報JP 2004-73057 A

本発明は、加温販売に供される果汁飲料の加温による品質の劣化や液色の褐変等の色調変化を抑制する方法、当該果汁飲料の製造方法、及び当該果汁飲料を提供することを目的とする。   The present invention provides a method for suppressing color change such as deterioration in quality and browning of liquid color due to heating of a juice drink to be sold for heating, a method for producing the juice drink, and the juice drink. Objective.

上記目的を達成するために本発明者らが鋭意研究した結果、加温販売に供される果汁飲料にショ糖と高甘味度甘味料とを所定の割合で配合することによって、加温による品質の劣化や液色の褐変等の色調変化を抑制することができることが判明した。   As a result of intensive research conducted by the present inventors to achieve the above object, the quality of warming is obtained by blending sucrose and a high-intensity sweetener in a predetermined ratio into a fruit juice drink to be sold for warming. It was found that changes in color tone such as deterioration of color and browning of liquid color can be suppressed.

すなわち、本発明は、加温販売用果汁飲料の加温による劣化を抑制する方法であって、前記果汁飲料の製造工程において、ショ糖と高甘味度甘味料とを、前記ショ糖の甘味度と配合量との積及び前記高甘味度甘味料の甘味度と配合量との積の和が所定の値になるように配合することを特徴とする加温劣化抑制方法を提供する(発明1)。 That is, the present invention is a method for suppressing deterioration due to warming of a fruit juice beverage for warming sale, and in the production process of the fruit juice beverage, sucrose and a high-intensity sweetener are used. And a blending amount, and the sum of the product of the sweetness and blending amount of the high-intensity sweetener becomes a predetermined value. ( Invention 1) ).

本発明において「甘味度」とは、甘味料の甘味の強さを意味し、具体的には、ショ糖の甘味度を1としたときの甘味の度合いを示す数値である。また、「高甘味度甘味料」とは、ショ糖の甘味度よりも高い甘味度を有する甘味料を意味し、天然甘味料、合成甘味料のいずれをも含む概念である。また、当該高甘味度甘味料には、2種以上の甘味料を混合した混合甘味料であって当該混合甘味料全体の甘味度がショ糖の甘味度よりも高いものも含まれるものとし、その混合甘味料にはショ糖の甘味度よりも低い甘味度を有する甘味料が含まれていてもよいし、含まれていなくてもよい。   In the present invention, “sweetness” means the intensity of sweetness of a sweetener, and specifically is a numerical value indicating the degree of sweetness when the sweetness of sucrose is 1. The term “highly sweetened sweetener” means a sweetener having a sweetness higher than that of sucrose and is a concept including both natural sweeteners and synthetic sweeteners. The high-intensity sweetener includes a mixed sweetener in which two or more kinds of sweeteners are mixed, and the sweetness of the whole mixed sweetener is higher than that of sucrose. The mixed sweetener may or may not contain a sweetener having a sweetness lower than that of sucrose.

上記発明(発明1)によれば、ショ糖及び高甘味度甘味料が所定の割合で果汁飲料中に配合されていることで、果汁飲料を加温することによって生じ得る液色の劣化を抑制することができ、また果汁飲料の風味や香味等の品質の劣化も抑制することができる。これにより、果汁飲料が加温状態で長期間(例えば、2週間以上)保存されていたとしても、商品劣化が抑制され、商品寿命を延長させることができる。 According to the said invention ( invention 1), sucrose and a high-intensity sweetener are mix | blended in a fruit juice drink by the predetermined | prescribed ratio, and the deterioration of the liquid color which may arise by heating a fruit juice drink is suppressed. Moreover, deterioration of quality, such as a flavor and flavor of a fruit juice drink, can also be suppressed. Thereby, even if a fruit juice drink is preserve | saved for a long time (for example, 2 weeks or more) in the warmed state, merchandise deterioration is suppressed and merchandise lifetime can be extended.

上記発明(発明1)においては、脱気水をさらに配合するのが好ましい(発明2)。かかる発明(発明2)によれば、果汁飲料の調製用の水の一部又はすべてとして脱気水を使用することで、果汁飲料を加温することによって生じ得る液色の劣化をより抑制することができる。 In the said invention ( invention 1), it is preferable to further mix deaerated water ( invention 2). According to this invention ( invention 2), by using deaerated water as part or all of the water for preparing the fruit juice beverage, the deterioration of the liquid color that can be caused by heating the fruit juice beverage is further suppressed. be able to.

なお、本発明において「脱気水」とは、水、イオン交換水又は蒸留水等に含まれる溶存酸素量を低下させたものを意味する。その製造方法としては、加熱脱気、真空脱気、膜脱気等の方法が挙げられるが、本発明における脱気水は、いずれの方法により製造されたものであってもよい。
In the present invention, “degassed water” means water in which the amount of dissolved oxygen contained in water, ion-exchanged water, distilled water or the like is reduced. Examples of the production method include methods such as heat deaeration, vacuum deaeration, and membrane deaeration. The deaerated water in the present invention may be produced by any method.
*

上記発明(発明1,2)においては、前記高甘味度甘味料が、アセスルファムカリウム及びスクラロースを含有するのが好ましい(発明3)。 In the said invention ( invention 1 and 2), it is preferable that the said high sweetness degree sweetener contains acesulfame potassium and sucralose ( invention 3).

また、本発明は、少なくとも果汁と、ショ糖と、高甘味度甘味料とを配合する工程を含み、前記工程において、前記ショ糖の甘味度と配合量との積及び前記高甘味度甘味料の甘味度と配合量との積の和が所定の値になるように、前記ショ糖及び前記高甘味度甘味料を配合することを特徴とする加温販売用果汁飲料の製造方法を提供する(発明4)。 In addition, the present invention includes a step of blending at least fruit juice, sucrose, and a high-sweetness sweetener, wherein in the step, the product of the sweetness degree and the blending amount of the sucrose and the high-sweetness sweetener A method for producing a juice drink for warming sale, characterized in that the sucrose and the high-intensity sweetener are blended so that the sum of the products of the sweetness level and the blending amount becomes a predetermined value. ( Invention 4).

上記発明(発明4)によれば、ショ糖及び高甘味度甘味料を所定の割合で配合することだけで、加温することによって生じ得る液色の劣化を抑制することができ、また風味や香味等の品質の劣化も抑制することのできる果汁飲料を容易に製造することができる。 According to the said invention ( invention 4), only by mix | blending sucrose and a high-intensity sweetener in a predetermined ratio, the deterioration of the liquid color which may arise by heating can be suppressed, and flavor and It is possible to easily produce a fruit juice drink capable of suppressing deterioration in quality such as flavor.

上記発明(発明4)においては、脱気水をさらに配合するのが好ましく(発明5)、上記発明(発明4,5)においては、前記高甘味度甘味料が、アセスルファムカリウム及びスクラロースを含有するのが好ましい(発明6)。 In the said invention ( invention 4), it is preferable to mix | blend deaerated water further ( invention 5), In the said invention ( invention 4 and 5), the said high sweetness degree sweetener contains acesulfame potassium and sucralose. ( Invention 6).

さらに、本発明は、少なくとも果汁と、ショ糖と、高甘味度甘味料とを含有し、前記ショ糖の甘味度と配合量との積及び前記高甘味度甘味料の甘味度と配合量との積の和が所定の値になるように、前記ショ糖及び前記高甘味度甘味料を含有することを特徴とする加温販売用果汁飲料を提供する(発明7)。 Furthermore, the present invention contains at least fruit juice, sucrose, and a high-intensity sweetener, the product of the sweetness and blending amount of the sucrose, and the sweetness and blending amount of the high-sweetness sweetener. A heated fruit juice drink characterized by comprising the sucrose and the high-intensity sweetener so that the sum of the products of the two becomes a predetermined value ( Invention 7).

上記発明(発明7)によれば、ショ糖及び高甘味度甘味料が所定の割合で果汁飲料中に配合されていることで、果汁飲料を加温することによって生じ得る液色の劣化を抑制することができ、また果汁飲料の風味や香味等の品質の劣化も抑制することができる。これにより、果汁飲料が加温状態で長期間(例えば、2週間以上)保存されていたとしても、商品劣化が抑制され、商品寿命を延長させることができる。 According to the said invention ( invention 7), sucrose and a high-intensity sweetener are mix | blended with a predetermined ratio in a fruit juice drink, and the deterioration of the liquid color which may arise by heating a fruit juice drink is suppressed. Moreover, deterioration of quality, such as a flavor and flavor of a fruit juice drink, can also be suppressed. Thereby, even if a fruit juice drink is preserve | saved for a long time (for example, 2 weeks or more) in the warmed state, merchandise deterioration is suppressed and merchandise lifetime can be extended.

上記発明(発明7)においては、脱気水をさらに含有するのが好ましく(発明8)、上記発明(発明7,8)においては、前記高甘味度甘味料が、アセスルファムカリウム及びスクラロースを含有するのが好ましい(発明9)。 In the said invention ( invention 7), it is preferable to contain deaerated water further ( invention 8), and in the said invention ( invention 7 and 8), the said high sweetness degree sweetener contains acesulfame potassium and sucralose. ( Invention 9)

上記発明(発明7〜9)においては、透明密閉容器に充填されてなるのが好ましい(発明10)。加温販売に供される果汁飲料は、加温による品質の劣化や液色の褐変等の色調変化が抑制されるため、上記発明(発明10)によれば、透明密閉容器に充填された上での加温販売に好適に供され得る。 In the said invention ( invention 7-9), it is preferable to be filled with a transparent airtight container ( invention 10). According to the invention ( invention 10), the fruit juice drink to be sold for warming is not filled with quality deterioration due to warming or browning of the liquid color is suppressed. It can be suitably used for warming sales in Japan.

本発明によれば、加温販売に供される果汁飲料の加温による品質の劣化や液色の褐変等の色調変化を抑制する方法、当該果汁飲料の製造方法、及び当該果汁飲料を提供することができる。   ADVANTAGE OF THE INVENTION According to this invention, the method of suppressing color change, such as deterioration of the quality by the heating of the fruit juice used for heating sales, and the browning of liquid color, the manufacturing method of the said fruit juice, and the said fruit drink are provided. be able to.

実施例1〜4及び比較例1〜3の果汁飲料における加温前と60℃に加温14日間経過後及び加温前と70℃に加温14日間経過後の色差(ΔE)を示すグラフである。The graph which shows the color difference ((DELTA) E) after heating for 14 days before heating and after heating for 14 days before heating, and after heating for 14 days for 70 degreeC in the fruit juice drink of Examples 1-4 and Comparative Examples 1-3. It is. 実施例1〜4及び比較例1〜3の果汁飲料における60℃及び70℃に加温14日間経過後の官能評価試験の結果(加熱臭)を示すグラフである。It is a graph which shows the result (heating odor) of the sensory evaluation test after heating for 14 days at 60 degreeC and 70 degreeC in the fruit juice drinks of Examples 1-4 and Comparative Examples 1-3. 実施例1〜4及び比較例1〜3の果汁飲料における60℃及び70℃に加温14日間経過後の官能評価試験の結果(嗜好性)を示すグラフである。It is a graph which shows the result (preference) of the sensory evaluation test after 14-day heating to 60 degreeC and 70 degreeC in the fruit juice drink of Examples 1-4 and Comparative Examples 1-3. 実施例1〜4及び比較例1〜3の果汁飲料における60℃及び70℃に加温14日間経過後の官能評価試験の結果(糖と酸とのバランス)を示すグラフである。It is a graph which shows the result (balance of saccharide | sugar and an acid) of the sensory evaluation test after 14-day heating to 60 degreeC and 70 degreeC in the fruit juice drink of Examples 1-4 and Comparative Examples 1-3. 実施例5〜9の果汁飲料における加温前と60℃に加温14日間経過後の色差(ΔE)を示すグラフである。It is a graph which shows the color difference ((DELTA) E) before a heating in the fruit juice drinks of Examples 5-9, and after a heating for 14 days at 60 degreeC. 実施例10〜15の果汁飲料における加温前と60℃に加温14日間経過後の色差(ΔE)を示すグラフである。It is a graph which shows the color difference ((DELTA) E) before heating in the fruit juice drink of Examples 10-15, and after heating for 14 days at 60 degreeC.

以下、本発明の実施形態について説明する。
本実施形態に係る加温販売用果汁飲料は、少なくとも果汁と、ショ糖と、高甘味度甘味料を含むものである。
Hereinafter, embodiments of the present invention will be described.
The heated fruit juice beverage according to this embodiment includes at least fruit juice, sucrose, and a high-intensity sweetener.

本実施形態に係る加温販売用果汁飲料に含まれ得る果汁としては、特に限定されるものではなく、レモン果汁、ユズ果汁、オレンジ果汁、グレープフルーツ果汁等の柑橘類果汁、リンゴ果汁、モモ果汁、ブドウ果汁等が挙げられる。これらのうち、レモン果汁、ユズ果汁等の柑橘類果汁、リンゴ果汁が好適に用いられ、特にレモン果汁やユズ果汁は、加温による液色の劣化が生じやすいため、好適に用いられる。   The fruit juice that can be included in the heated beverage juice for sale according to the present embodiment is not particularly limited, and citrus fruit juice such as lemon juice, yuzu juice, orange juice, grapefruit juice, apple juice, peach juice, grapes Examples include fruit juices. Among these, citrus fruit juices such as lemon juice and yuzu juice, and apple juice are preferably used, and particularly lemon juice and yuzu juice are preferably used because they tend to deteriorate in liquid color due to heating.

また、上記果汁としては、果実の搾汁液(ストレート果汁)、搾汁液を濃縮した濃縮果汁、濃縮果汁をさらに希釈した還元果汁、搾汁液に酵素処理等を施すことで清澄化した透明果汁等が挙げられる。   Examples of the fruit juice include fruit juice (straight juice), concentrated juice obtained by concentrating the juice, reduced fruit juice obtained by further diluting the concentrated juice, and transparent juice obtained by clarification by applying enzyme treatment to the juice. Can be mentioned.

上記果汁の配合量は、特に限定されるものではないが、飲料全量に対して1〜15質量%であるのが好ましく、1〜10質量%であるのがより好ましい。果汁の配合量が上記範囲内であることで、加温状態で摂飲した際に嗜好性の高い果汁飲料とすることができる。   Although the compounding quantity of the said fruit juice is not specifically limited, It is preferable that it is 1-15 mass% with respect to drink whole quantity, and it is more preferable that it is 1-10 mass%. When the amount of fruit juice is within the above range, a fruit juice drink having high palatability can be obtained when swallowed in a heated state.

本実施形態に係る加温販売用果汁飲料に含まれ得る高甘味度甘味料としては、例えば、ショ糖の甘味度よりも高い甘味度を有する一の甘味料や、当該一の甘味料にショ糖の甘味度よりも低い甘味度を有する甘味料のうちの1種若しくは2種以上の甘味料及び/又はショ糖の甘味度よりも高い甘味度を有する他の甘味料のうちの1種若しくは2種以上の甘味料を混合した混合甘味料であって混合甘味料全体の甘味度がショ糖の甘味度よりも高いもの等を用いることができる。   Examples of the high-intensity sweetener that can be included in the heated fruit juice beverage according to the present embodiment include one sweetener having a sweetness higher than that of sucrose and the one sweetener. One or more sweeteners having a sweetness lower than that of sugar and / or one of other sweeteners having a sweetness higher than that of sucrose or A mixed sweetener in which two or more kinds of sweeteners are mixed and the sweetness of the whole mixed sweetener is higher than that of sucrose can be used.

上記ショ糖の甘味度よりも高い甘味度を有する甘味料としては、食品添加物として認められているものであれば特に限定されるものではなく、例えば、アセスルファムカリウム、スクラロース、ネオテーム等の合成甘味料;アスパルテーム、アリテーム等のアミノ酸系甘味料;ステビア、グリチルリチン、カンゾウ抽出物等の天然甘味料等が挙げられ、これらのうちアセスルファムカリウム及びスクラロースを好適に用いることができる。   The sweetener having a sweetness higher than that of sucrose is not particularly limited as long as it is recognized as a food additive. For example, synthetic sweetness such as acesulfame potassium, sucralose, neotame, etc. Amino acids such as aspartame and alitame; natural sweeteners such as stevia, glycyrrhizin and licorice extract, among which acesulfame potassium and sucralose can be preferably used.

また、上記ショ糖の甘味度よりも低い甘味度を有する甘味料としては、例えば、イソマルツロース、エリスリトール、ラクチトール、マルチトール、マンニトール、ソルビトール、キシリトール等の糖アルコールやそれらの還元体、さらにはオリゴ糖類、その他の甘味料が挙げられる。   Examples of sweeteners having sweetness lower than that of sucrose include sugar alcohols such as isomaltulose, erythritol, lactitol, maltitol, mannitol, sorbitol, xylitol, and their reduced forms, and Examples include oligosaccharides and other sweeteners.

本実施形態に係る加温販売用果汁飲料におけるショ糖の配合量は、飲料全量に対して1.4〜6.6質量%であるのが好ましく、特に2.0〜5.5質量%であるのが好ましい。ショ糖の配合量が6.6質量%を超えると、果汁飲料の加温による品質の劣化や液色の褐変等の色調変化を抑制するのが困難になるおそれがあり、1.4質量%未満であると、高甘味度甘味料の配合量が多くなりすぎて、高甘味度甘味料の苦味や後引きの悪さに加え、濃度感、バランスが悪くなるおそれがある。   It is preferable that the compounding quantity of the sucrose in the fruit juice drink for heating sale which concerns on this embodiment is 1.4-6.6 mass% with respect to drink whole quantity, and is 2.0-5.5 mass% especially. Preferably there is. If the blending amount of sucrose exceeds 6.6% by mass, it may be difficult to suppress color change such as quality deterioration or liquid color browning due to warming of the fruit juice beverage, and 1.4% by mass. If it is less than 1, the blending amount of the high-intensity sweetener will be too large, and in addition to the bitterness and poor pull-back of the high-intensity sweetener, the sense of concentration and balance may be deteriorated.

本実施形態に係る加温販売用果汁飲料における高甘味度甘味料の配合量は、配合する甘味料の甘味度に応じて適宜決定すればよいが、ショ糖の甘味度を基準としてショ糖の配合量に換算したショ糖換算(高甘味度甘味料の甘味度×高甘味度甘味料の配合率)で、飲料全量に対して2.4〜13.6質量%であるのが好ましく、特に3.0〜11.0質量%であるのが好ましい。高甘味度甘味料の配合量が13.6質量%(ショ糖換算)を超えると、高甘味度甘味料の苦味や後引きの悪さに加え、濃度感、バランスが悪くなり、2.4質量%(ショ糖換算)未満であると甘味度を維持するためにショ糖配合量が多くなり、果汁飲料の加温による品質の劣化や液色の褐変等の色調変化を抑制するのが困難となる。なお、低甘味度甘味料を配合する場合、その配合量は得られる果汁飲料の風味や香味が嗜好性の高いものとなるように、適宜調整すればよい。   The blending amount of the high-intensity sweetener in the fruit juice beverage for warm sale according to the present embodiment may be appropriately determined according to the sweetness of the sweetener to be blended. It is preferably 2.4 to 13.6% by mass in terms of sucrose in terms of blending amount (sweetness of high-intensity sweetener x blending ratio of high-intensity sweetener), and particularly with respect to the total amount of beverage. It is preferable that it is 3.0-11.0 mass%. When the blending amount of the high-intensity sweetener exceeds 13.6% by mass (converted to sucrose), in addition to the bitterness and poor pull-out of the high-intensity sweetener, the sense of concentration and balance deteriorate, and 2.4 mass % (In terms of sucrose conversion), the amount of sucrose is increased to maintain the sweetness, and it is difficult to suppress color change such as deterioration of quality and browning of liquid color due to warming of fruit juice beverages. Become. In addition, when mix | blending a low sweetness degree sweetener, the compounding quantity should just adjust suitably so that the flavor and flavor of the obtained fruit juice drink may become a thing with high palatability.

本実施形態に係る加温販売用果汁飲料におけるショ糖と高甘味度甘味料との配合量は、ショ糖の甘味度と配合量との積及び高甘味度甘味料の甘味度(高甘味度甘味料として混合甘味料を用いる場合には混合甘味料全体の甘味度)と配合量との積の和が所定の値、具体的には7〜15、好ましくは8〜13、より好ましくは8〜11になるように決定する。   The blending amount of sucrose and the high-intensity sweetener in the fruit juice beverage for warm sale according to the present embodiment is the product of the sweetness and blending amount of sucrose and the sweetness of the high-intensity sweetener (high sweetness When a mixed sweetener is used as the sweetener, the sum of the products of the sweetness of the entire mixed sweetener) and the blending amount is a predetermined value, specifically 7 to 15, preferably 8 to 13, and more preferably 8 Determine to be ~ 11.

ショ糖及び高甘味度甘味料の配合割合は、例えば、下記式(1)に基づいて算出する。   The blending ratio of sucrose and high-intensity sweetener is calculated based on the following formula (1), for example.

Figure 0005574662
Figure 0005574662

式(1)中、Xは「ショ糖の甘味度と配合量との積及び高甘味度甘味料の甘味度と配合量との積の和」を、Yは「ショ糖の甘味度(=1)」を、yは「ショ糖の配合量(質量%)」を、Zは「高甘味度甘味料の甘味度(高甘味度甘味料として混合甘味料を用いる場合には当該混合甘味料全体の甘味度)」を、zは「高甘味度甘味料(混合甘味料)の配合量(質量%)」を表す。   In the formula (1), X is “the sum of the product of the sweetness and blending amount of sucrose and the product of the sweetness and blending amount of the high sweetness sweetener”, and Y is “the sweetness of sucrose (= 1) ”, y is“ amount of sucrose (% by mass) ”, Z is“ the sweetness of a high-intensity sweetener (in the case of using a mixed sweetener as a high-intensity sweetener, the mixed sweetener "Overall sweetness degree" ", z represents" amount (mass%) of high-intensity sweetener (mixed sweetener) ".

例えば、甘味度200のアセスルファムカリウムを高甘味度甘味料として用い、ショ糖の甘味度と配合量との積及び高甘味度甘味料の甘味度と配合量との積の和を9.2と設定した場合、ショ糖の配合量を4質量%と決定すれば、高甘味度甘味料の配合量を、(9.2−4)/200=0.026質量%と決定することができる。また、高甘味度甘味料として、アセスルファムカリウム、スクラロース及びイソマルツロースの還元体からなる混合甘味料(混合甘味料全体の甘味度=200)を用い、ショ糖の甘味度と配合量との積及び高甘味度甘味料の甘味度と配合量との積の和を9.2と設定した場合、ショ糖の配合量を4質量%と決定すれば、高甘味度甘味料(混合甘味料)の配合量を、(9.2−4)/200=0.026質量%と決定することができる。   For example, acesulfame potassium having a sweetness level of 200 is used as a high-potency sweetener, and the sum of the product of the sweetness level and the blending amount of sucrose and the product of the sweetness level and the blending amount of the high-sweetness sweetener is 9.2. When it is set, if the blending amount of sucrose is determined to be 4 mass%, the blending amount of the high-intensity sweetener can be determined to be (9.2-4) /200=0.026 mass%. Moreover, as a high sweetness degree sweetener, a mixed sweetener composed of reduced forms of acesulfame potassium, sucralose and isomaltulose (sweetness of the whole mixed sweetener = 200) is used. When the sum of the product of the sweetness and blending amount of the high-intensity sweetener is set to 9.2, if the blending amount of sucrose is determined to be 4% by mass, the high-sweetness sweetener (mixed sweetener) Can be determined as (9.2-4) /200=0.026 mass%.

このようにしてショ糖と高甘味度甘味料との配合割合を決定することで、加温販売に供される果汁飲料における加温による品質の劣化や液色の褐変等の色調変化を効果的に抑制することができる。また、上記配合割合によりショ糖と高甘味度甘味料とを含有せしめることで、果汁飲料の香味や風味を嗜好性の高いものとすることができる。   By determining the blending ratio of sucrose and high-intensity sweeteners in this way, it is possible to effectively prevent color deterioration such as deterioration of quality and browning of liquid color due to heating in fruit juice beverages that are subjected to heated sales. Can be suppressed. Moreover, the flavor and flavor of a fruit juice drink can be made high by adding sucrose and a high-intensity sweetener by the said mixture ratio.

本実施形態に係る加温販売用果汁飲料のpHは、2.0〜4.5であるのが好ましく、2.5〜4.0であるのがより好ましい。果汁飲料のpHが上記範囲であれば、果実(果汁)の呈味を損なうことなくほどよい酸味を与えることができる。   The pH of the fruit juice beverage for warm sale according to the present embodiment is preferably 2.0 to 4.5, and more preferably 2.5 to 4.0. If pH of a fruit juice drink is the said range, moderate acidity can be given, without impairing the taste of fruit (fruit juice).

なお、本実施形態に係る加温販売用果汁飲料は、所望により、ペクチン、ゼラチン、コラーゲン、寒天、カラギーナン、アルギン酸ナトリウム、大豆多糖類、アラビアガム、グァーガム、キサンタンガム、タマリンドシードガム、ジェランガム等の増粘安定剤;クエン酸、リンゴ酸、酒石酸、乳酸、グルコン酸等の酸味料;酸化防止剤;炭酸水素ナトリウム(重曹)等のpH調整剤;グリセリン脂肪酸エステル、ショ糖脂肪酸エステル等の乳化剤;食物繊維、カルシウム塩、マグネシウム塩、ナイアシン、パントテン酸等の強化剤;各種乳酸菌等をさらに含有していてもよい。   It should be noted that the fruit juice beverage for warming sale according to the present embodiment can be added to pectin, gelatin, collagen, agar, carrageenan, sodium alginate, soybean polysaccharide, gum arabic, guar gum, xanthan gum, tamarind seed gum, gellan gum and the like as desired. Sticky stabilizers; Acidulants such as citric acid, malic acid, tartaric acid, lactic acid, and gluconic acid; Antioxidants; pH adjusters such as sodium bicarbonate (bicarbonate); Emulsifiers such as glycerin fatty acid ester and sucrose fatty acid ester; Food Strengthening agents such as fiber, calcium salt, magnesium salt, niacin, pantothenic acid; various lactic acid bacteria and the like may further be contained.

本実施形態に係る加温販売用果汁飲料は、容器に充填した形態で提供することができ、特に、加温による液色の褐変等の色調変化が効果的に抑制されているため、透明密閉容器に充填した形態で提供するのが好ましい。当該透明密閉容器としては、例えば、PETボトル、ガラスビン等が挙げられる。   The fruit juice beverage for warming sale according to the present embodiment can be provided in a form filled in a container, and in particular, since color change such as liquid color browning due to warming is effectively suppressed, the transparent hermetically sealed It is preferable to provide in the form with which the container was filled. Examples of the transparent sealed container include a PET bottle and a glass bottle.

本実施形態に係る加温販売用果汁飲料は、従来公知の方法により製造することができる。例えば、まず、飲用に適した水に果汁、ショ糖及び高甘味度甘味料を上述したような配合量となるように添加し、所望によりその他の食品添加物等をさらに添加して攪拌し、飲料原液を調製する。   The heated fruit juice drink according to this embodiment can be produced by a conventionally known method. For example, first, add fruit juice, sucrose and high-intensity sweetener to water suitable for drinking so as to have the above-mentioned blending amount, and if necessary, further add other food additives and the like, and stir. Prepare beverage stock solution.

上記飲用に適した水としては、例えば、市水、井水、イオン交換水、脱気水等が挙げられるが、これらのうちイオン交換水又は脱気水を用いるのが好ましく、特に脱気水を用いるのが好ましい。脱気水を用いることで、果汁飲料の加温による品質の劣化や液色の褐変等の色調変化をより効果的に抑制することができる。なお、脱気水を用いる場合、飲用に適した水の一部又はすべてを脱気水とすることができる。   Examples of the water suitable for drinking include city water, well water, ion exchange water, deaerated water, etc. Among these, it is preferable to use ion exchange water or deaerated water, and in particular, deaerated water. Is preferably used. By using deaerated water, it is possible to more effectively suppress color tone changes such as quality deterioration and liquid color browning due to heating of fruit juice beverages. In addition, when using deaerated water, a part or all of the water suitable for drinking can be made into deaerated water.

加温販売用果汁飲料の製造に脱気水を用いる場合、脱気水の溶存酸素量は、5.0μg/mL以下であるのが好ましく、特に0.1〜1.0μg/mLであるのが好ましい。溶存酸素量が5.0μg/mLを超えると、脱気水を用いることによる効果が弱くなるおそれがある。   When deaerated water is used in the production of a warm beverage for sale, the amount of dissolved oxygen in the deaerated water is preferably 5.0 μg / mL or less, particularly 0.1 to 1.0 μg / mL. Is preferred. When the amount of dissolved oxygen exceeds 5.0 μg / mL, the effect of using deaerated water may be weakened.

上述のようにして得られた飲料原液にpH調整剤等を添加することにより、飲料原液のpHを所定の範囲に調整する。その後、pHを調整した飲料原液を加熱殺菌して透明密閉容器等の容器に充填する。このようにして、本実施形態に係る加温販売用果汁飲料を製造することができる。   The pH of the beverage stock solution is adjusted to a predetermined range by adding a pH adjuster or the like to the beverage stock solution obtained as described above. Thereafter, the beverage stock solution adjusted in pH is heat sterilized and filled in a container such as a transparent sealed container. Thus, the fruit juice drink for heating sale which concerns on this embodiment can be manufactured.

このようにして製造された加温販売用果汁飲料中の溶存酸素量は、0.1〜5μg/mLであるのが好ましく、特に0.1〜3μg/mLであるのが好ましい。果汁飲料中の溶存酸素量が5μg/mLを超えると、商品価値を低下させ、商品寿命を短縮させてしまうおそれがある。   The amount of dissolved oxygen in the heated fruit juice drink thus produced is preferably 0.1 to 5 μg / mL, and particularly preferably 0.1 to 3 μg / mL. If the amount of dissolved oxygen in the fruit juice drink exceeds 5 μg / mL, the commercial value may be reduced and the commercial life may be shortened.

このようにして製造される本実施形態に係る加温販売用果汁飲料は、50〜70℃程度で加温されて販売に供されることになるが、ショ糖と高甘味度甘味料とを含み、それらの配合割合が一定の範囲に調整されていることで、加温による品質の劣化や液色の褐変等の色調変化を効果的に抑制することができる。したがって、本実施形態によれば、加温販売用果汁飲料の商品劣化が抑制され、商品寿命を延長させることができる。   The fruit juice beverage for warming sale according to the present embodiment manufactured in this way is heated at about 50 to 70 ° C. and supplied for sale, but sucrose and a high-intensity sweetener are used. In addition, by adjusting the blending ratio thereof to a certain range, it is possible to effectively suppress color tone changes such as quality deterioration and liquid color browning due to heating. Therefore, according to the present embodiment, the product deterioration of the warm-sale fruit juice beverage is suppressed, and the product life can be extended.

以上説明した実施形態は、本発明の理解を容易にするために記載されたものであって、本発明を限定するために記載されたものではない。したがって、上記実施形態に開示された各要素は、本発明の技術的範囲に属する全ての設計変更や均等物をも含む趣旨である。   The embodiment described above is described for facilitating understanding of the present invention, and is not described for limiting the present invention. Therefore, each element disclosed in the above embodiment is intended to include all design changes and equivalents belonging to the technical scope of the present invention.

以下、実施例及び比較例を示すことにより本発明をさらに詳細に説明するが、本発明は下記の実施例等に何ら限定されるものではない。   EXAMPLES Hereinafter, although this invention is demonstrated further in detail by showing an Example and a comparative example, this invention is not limited to the following Example etc. at all.

〔実施例1〜4,比較例1〜3〕
表1及び表2に示す配合に従って飲料原料を混合し、得られた混合物を95℃まで加温し、PETボトルに充填することで、果汁飲料(実施例1〜4、比較例1〜3)を製造した。実施例1〜2及び4、並びに比較例1〜3の果汁飲料は、水としてイオン交換水を用い、実施例3の果汁飲料は、水としてイオン交換水を脱気した脱気水を用いた。また、比較例1の果汁飲料は、砂糖としてグラニュー糖と果糖ブドウ糖液糖との混合物(同量(4.6質量%)ずつ配合)を用いた。さらに、実施例1〜4及び比較例1〜3の果汁飲料における砂糖及び高甘味度甘味料の配合量は、下記式(1)に基づき、砂糖を9.2質量%配合したときの甘味度と同一の甘味度になるように適宜調整した。
[Examples 1-4, Comparative Examples 1-3]
Beverage ingredients are mixed according to the formulations shown in Table 1 and Table 2, and the resulting mixture is heated to 95 ° C. and filled into a PET bottle, thereby allowing fruit juice beverages (Examples 1 to 4, Comparative Examples 1 to 3). Manufactured. The juice drinks of Examples 1-2 and 4 and Comparative Examples 1-3 used ion-exchanged water as water, and the juice drink of Example 3 used deaerated water degassed ion-exchanged water as water. . Moreover, the fruit juice drink of Comparative Example 1 used a mixture of granulated sugar and fructose-glucose liquid sugar (compounded in the same amount (4.6% by mass)) as sugar. Furthermore, the compounding quantities of sugar and high-intensity sweeteners in the fruit juice drinks of Examples 1 to 4 and Comparative Examples 1 to 3 are based on the following formula (1), and the sweetness when 9.2% by mass of sugar is compounded. Was adjusted as appropriate so as to achieve the same sweetness.

Figure 0005574662
Figure 0005574662

式(1)中、Xは「砂糖(ショ糖)の甘味度と配合量との積及び高甘味度甘味料の甘味度と配合量との積の和」を、Yは「砂糖(ショ糖)の甘味度(=1)」を、yは「砂糖(ショ糖)の配合量(質量%)」を、Zは「混合甘味料(高甘味度甘味料)の甘味度」を、zは「混合甘味料(高甘味度甘味料)の配合量(質量%)」を表す。   In the formula (1), X is “the sum of the product of the sweetness and blending amount of sugar (sucrose) and the product of the sweetness and blending amount of the high sweetness sweetener”, and Y is “sugar (sucrose). ), “Y” is “sugar (sucrose) blending amount (% by mass)”, Z is “sweetness of mixed sweetener (high-intensity sweetener)”, z is “Mixed amount of sweetener (high-intensity sweetener) (% by mass)” is expressed.

Figure 0005574662
Figure 0005574662

Figure 0005574662
Figure 0005574662

実施例1〜4及び比較例1〜3の果汁飲料を、60℃又は70℃で加温した状態で保管し、加温前及び2週間後の飲料の液色についてのLab表色系におけるL値、a値及びb値を、分光色差計(spectrophotometer SE2000,日本電色工業社製)を用いて測定した。得られた結果から、加温前における飲料の液色を基準とした色差(ΔE)を下記式により算出した。   The fruit juice drinks of Examples 1 to 4 and Comparative Examples 1 to 3 are stored in a heated state at 60 ° C. or 70 ° C., and L in the Lab color system for the liquid color of the beverage before heating and after 2 weeks. The value, a value, and b value were measured using a spectrophotometer (spectrophotometer SE2000, manufactured by Nippon Denshoku Industries Co., Ltd.). From the obtained results, the color difference (ΔE) based on the liquid color of the beverage before heating was calculated by the following formula.

ΔE={(ΔL)+(Δa)+(Δb)}1/2
式中、ΔLは「加温前の果汁飲料のL値と加温後の果汁飲料のL値との差分」を、Δaは「加温前の果汁飲料のa値と加温後の果汁飲料のa値との差分」を、Δbは「加温前の果汁飲料のb値と加温後の果汁飲料のb値との差分」を表す。
結果を図1及び表4に示す。なお、表4中、色調評価は、ΔEの平均値が5未満のものを「◎」、5以上7未満のものを「○」、7以上のものを「×」と評価した。
ΔE = {(ΔL) 2 + (Δa) 2 + (Δb) 2 } 1/2
In the formula, ΔL is “the difference between the L value of the juice drink before warming and the L value of the juice drink after warming”, and Δa is “a value of the juice drink before warming and the juice drink after warming” Δb represents “the difference between the b value of the fruit juice before warming and the b value of the fruit juice after warming”.
The results are shown in FIG. In Table 4, the evaluation of color tone was evaluated as “「 ”when the average value of ΔE was less than 5,“ ◯ ”when 5 or more and less than 7, and“ × ”when 7 or more.

また、実施例1〜4及び比較例1〜3の果汁飲料を60℃及び70℃で保管したものについて、官能評価を行った。かかる官能評価は、果汁飲料の開発を担当する訓練された7名のパネラーにより、60℃で2週間、70℃で2週間保管した各果汁飲料について、加熱臭、嗜好性、糖と酸とのバランスを表3に示す判断基準に従って4段階で評価した。結果を図2〜4、表4及び表5に示す。なお、表4中における総合評価は、色調評価及び官能評価のうちの低い方の評価を採用した。また、表5中における数値は、7人のパネラーの評価点の平均値を示すものであり、総点が12点未満のものを「×」、12点以上15点未満のものを「○」、15点以上のものを「◎」と評価した。   Moreover, sensory evaluation was performed about what stored the fruit juice drink of Examples 1-4 and Comparative Examples 1-3 at 60 degreeC and 70 degreeC. Such sensory evaluation was conducted by seven trained panelists responsible for the development of fruit juice beverages. Each fruit juice stored at 60 ° C. for 2 weeks and at 70 ° C. for 2 weeks was heated with odor, palatability, sugar and acid. The balance was evaluated in four stages according to the judgment criteria shown in Table 3. The results are shown in FIGS. In addition, the comprehensive evaluation in Table 4 employ | adopted the lower evaluation of color tone evaluation and sensory evaluation. In addition, the numerical values in Table 5 indicate the average value of the evaluation scores of the seven panelists. “X” indicates that the total score is less than 12 points, and “◯” indicates that the total score is 12 points or more and less than 15 points. Those with 15 points or more were evaluated as “◎”.

Figure 0005574662
Figure 0005574662

Figure 0005574662
Figure 0005574662

Figure 0005574662
Figure 0005574662

図1及び表4に示すように、砂糖(ショ糖)と高甘味度甘味料とを配合した実施例1〜4の果汁飲料は、砂糖(ショ糖)のみを配合した比較例1〜2の果汁飲料に比して、色調の劣化が抑制されていることが確認され、実施例2及び3の果汁飲料のように、ショ糖の配合量と甘味度との積及び高甘味度甘味料の配合量と甘味度との積の和が9.2程度となるようにそれらを配合することで、液色の褐変等の色調の劣化を効果的に抑制し得ることが確認された。特に、実施例3の果汁飲料のように、脱気水を用いて製造されたものは、色調の劣化を極めて抑制し得ることが確認された。   As shown in FIG. 1 and Table 4, the fruit juice drinks of Examples 1 to 4 in which sugar (sucrose) and a high-intensity sweetener are blended are those in Comparative Examples 1 and 2 in which only sugar (sucrose) is blended. It was confirmed that the deterioration of color tone was suppressed as compared with the fruit juice beverage, and as in the fruit juice beverages of Examples 2 and 3, the product of the blended amount of sucrose and the sweetness degree and the high sweetness degree sweetener It was confirmed that deterioration of the color tone such as browning of the liquid color can be effectively suppressed by blending them so that the sum of the product of the blending amount and the sweetness level is about 9.2. In particular, as in the fruit juice beverage of Example 3, it was confirmed that the product manufactured using deaerated water can extremely suppress the deterioration of the color tone.

また、図2〜4、表4及び表5に示すように、官能試験の結果、比較例1及び比較例2の果汁飲料は加熱臭が際立っており、比較例3の果汁飲料は、嗜好性、濃度感が弱く、また糖と酸とのバランスも悪く、甘味料の後引きの悪さも目立っていた。一方、実施例2及び実施例3の果汁飲料では加熱臭も少なく、濃度感も適度にあり、最もバランスの優れた風味を有した。また、実施例1の果汁飲料では、若干加熱臭があるが、濃度感もありバランスが良好であった。さらに、実施例4の果汁飲料では、濃度感、バランスにやや劣るが、加熱臭は少なかった。   Moreover, as shown in FIGS. 2-4, Table 4, and Table 5, as a result of a sensory test, the fruit juice drink of the comparative example 1 and the comparative example 2 has a remarkable heating odor, and the fruit juice drink of the comparative example 3 is palatability. The concentration was weak, the balance between sugar and acid was poor, and the postpone of sweeteners was conspicuous. On the other hand, the fruit juice beverages of Example 2 and Example 3 had less heat odor, moderate concentration, and the most balanced flavor. In addition, the fruit juice beverage of Example 1 had a slightly heated odor, but also had a good feeling of concentration and a good balance. Furthermore, in the fruit juice drink of Example 4, although it was a little inferior in a density feeling and balance, there was little heating odor.

総合的な評価として、比較例1〜2の果汁飲料は、色調の変化及び糖の加熱臭が際立ち、加温販売用果汁飲料としての商品価値の低下が著しく、比較例3の果汁飲料は、色調の変化は少ないが、甘味料独特の後引きが目立ち、バランスが悪いため、加温販売用果汁飲料としての商品価値が低いものであった。一方、実施例1〜4の果汁飲料に関しては、色調の変化が少なく、かつ香味が良いため、加温販売用果汁飲料としての商品価値が高く、特に実施例2及び実施例3において液色の褐変抑制、さらには香味の良さが確認された。このように、加温販売用果汁飲料の色調の劣化及び香味において、ショ糖と甘味料との配合割合の重要性が示唆された結果となった。   As a comprehensive evaluation, the fruit juice drinks of Comparative Examples 1 and 2 are prominent in the change in color tone and the heated odor of sugar. The fruit juice drink of Comparative Example 3 Although there was little change in color tone, the postponement peculiar to sweeteners was conspicuous and the balance was poor, so the product value as a fruit juice drink for warm sale was low. On the other hand, regarding the fruit juice drinks of Examples 1 to 4, since the color change is small and the flavor is good, the commercial value as a fruit juice drink for warming sales is high. Suppression of browning and good flavor were confirmed. Thus, the result of the importance of the blending ratio of sucrose and sweetener was suggested in the deterioration of color tone and flavor of the fruit juice beverage for warm sale.

〔実施例5〜9〕
実施例3の果汁飲料において、高甘味度甘味料としての混合甘味料を表6に示す高甘味度甘味料に変更した以外は実施例3と同様にして果汁飲料を製造した(実施例5〜9)。
[Examples 5 to 9]
In the juice drink of Example 3, fruit juice drinks were produced in the same manner as in Example 3 except that the mixed sweetener as the high-intensity sweetener was changed to the high-intensity sweetener shown in Table 6 (Examples 5 to 5). 9).

実施例5〜9の果汁飲料を、60℃で加温した状態で保管し、加温前及び2週間後の飲料の液色についてのLab表色系におけるL値、a値及びb値を、分光色差計(spectrophotometer SE2000,日本電色工業社製)を用いて測定した。得られた結果から、加温前における飲料の液色を基準とした色差(ΔE)を下記式により算出した。   The fruit juice beverages of Examples 5 to 9 were stored in a heated state at 60 ° C., and the L value, a value, and b value in the Lab color system for the liquid color of the beverage before warming and after 2 weeks were determined. It measured using the spectral color difference meter (spectrophotometer SE2000, Nippon Denshoku Industries Co., Ltd.). From the obtained results, the color difference (ΔE) based on the liquid color of the beverage before heating was calculated by the following formula.

ΔE={(ΔL)+(Δa)+(Δb)}1/2
式中、ΔLは「加温前の果汁飲料のL値と加温後の果汁飲料のL値との差分」を、Δaは「加温前の果汁飲料のa値と加温後の果汁飲料のa値との差分」を、Δbは「加温前の果汁飲料のb値と加温後の果汁飲料のb値との差分」を表す。
結果を図5及び表6に示す。
ΔE = {(ΔL) 2 + (Δa) 2 + (Δb) 2 } 1/2
In the formula, ΔL is “the difference between the L value of the juice drink before warming and the L value of the juice drink after warming”, and Δa is “a value of the juice drink before warming and the juice drink after warming” Δb represents “the difference between the b value of the fruit juice before warming and the b value of the fruit juice after warming”.
The results are shown in FIG.

Figure 0005574662
Figure 0005574662

図5及び表6から明らかなように、高甘味度甘味料の種類によって果汁飲料の液色の劣化の抑制効果に有意な差は確認されなかった。また、実施例5〜9の果汁飲料は、いずれも比較例2の果汁飲料に比して液色の劣化が抑制されていることが確認された。このことから、高甘味度甘味料の種類にかかわらず、ショ糖と高甘味度甘味料との配合割合を所定の範囲にすることで、果汁飲料の液色の劣化を抑制し得ることが判明した。   As is clear from FIG. 5 and Table 6, no significant difference was observed in the effect of suppressing the deterioration of the liquid color of the fruit juice beverage depending on the type of high-intensity sweetener. Moreover, as for the fruit juice drink of Examples 5-9, compared with the fruit juice drink of the comparative example 2, it was confirmed that deterioration of a liquid color is suppressed. From this, it was found that, regardless of the type of high-intensity sweetener, deterioration of the liquid color of the fruit juice beverage can be suppressed by setting the blending ratio of sucrose and high-intensity sweetener to a predetermined range. did.

〔実施例10〜15〕
実施例2の果汁飲料において、果汁の種類及び配合量を表7に示すように変更した以外は実施例2と同様にして果汁飲料を製造した(実施例10〜15)。
[Examples 10 to 15]
In the fruit juice beverage of Example 2, fruit juice beverages were produced in the same manner as in Example 2 except that the kind and amount of fruit juice were changed as shown in Table 7 (Examples 10 to 15).

Figure 0005574662
Figure 0005574662

実施例10〜15の果汁飲料を、60℃で加温した状態で保管し、加温前及び2週間後の飲料の液色についてのLab表色系におけるL値、a値及びb値を、分光色差計(spectrophotometer SE2000,日本電色工業社製)を用いて測定した。得られた結果から、加温前における飲料の液色を基準とした色差(ΔE)を下記式により算出した。   The fruit juice beverages of Examples 10 to 15 were stored in a heated state at 60 ° C., and the L value, a value, and b value in the Lab color system for the liquid color of the beverage before warming and after two weeks, It measured using the spectral color difference meter (spectrophotometer SE2000, Nippon Denshoku Industries Co., Ltd.). From the obtained results, the color difference (ΔE) based on the liquid color of the beverage before heating was calculated by the following formula.

ΔE={(ΔL)+(Δa)+(Δb)}1/2
式中、ΔLは「加温前の果汁飲料のL値と加温後の果汁飲料のL値との差分」を、Δaは「加温前の果汁飲料のa値と加温後の果汁飲料のa値との差分」を、Δbは「加温前の果汁飲料のb値と加温後の果汁飲料のb値との差分」を表す。
結果を図6及び表8に示す。
ΔE = {(ΔL) 2 + (Δa) 2 + (Δb) 2 } 1/2
In the formula, ΔL is “the difference between the L value of the juice drink before warming and the L value of the juice drink after warming”, and Δa is “a value of the juice drink before warming and the juice drink after warming” Δb represents “the difference between the b value of the fruit juice before warming and the b value of the fruit juice after warming”.
The results are shown in FIG.

Figure 0005574662
Figure 0005574662

図6及び表8から明らかなように、果汁量の増加に従って果汁飲料の液色の劣化が加速することが確認された。また、レモン果汁、ユズ果汁等の柑橘類果汁は、果汁飲料の液色が劣化しやすいことが確認された。このことから、特に柑橘類果汁を含む果汁飲料においてショ糖と高甘味度甘味料とを所定の割合で配合することで、優れた液色の劣化抑制効果を奏し得ると考えられる。
As is apparent from FIG. 6 and Table 8, it was confirmed that the deterioration of the liquid color of the fruit juice drink accelerated as the amount of the fruit juice increased. Moreover, it was confirmed that the citrus fruit juices such as lemon juice and yuzu fruit juice are liable to deteriorate the liquid color of the fruit juice drink. From this, it is considered that an excellent liquid color deterioration suppressing effect can be obtained by blending sucrose and a high-intensity sweetener in a predetermined ratio particularly in a fruit juice beverage containing citrus fruit juice.
*

本発明の劣化抑制方法は、加温販売に供される果汁飲料の液色や品質の劣化の抑制に有用である。   The deterioration suppressing method of the present invention is useful for suppressing deterioration of the liquid color and quality of fruit juice beverages that are subjected to warm sales.

Claims (7)

加温販売用果汁飲料の加温による劣化を抑制する方法であって、
前記果汁飲料の製造工程において、ショ糖と高甘味度甘味料とを、前記ショ糖の配合量が飲料全量に対して1.4〜6.6質量%になるように、前記高甘味度甘味料の配合量がショ糖換算(高甘味度甘味料の甘味度×高甘味度甘味料の配合率)で飲料全量に対して2.4〜13.6質量%になるように、かつ前記ショ糖の甘味度と配合量との積及び前記高甘味度甘味料の甘味度と配合量との積の和が7〜15になるように配合し、さらに脱気水を配合することを特徴とする加温劣化抑制方法。
A method of suppressing deterioration due to warming of a juice drink for warming,
In the manufacturing process of the fruit juice beverage, the high-sweetness sweetener is mixed with sucrose and a high-sweetness sweetener so that the blending amount of the sucrose is 1.4 to 6.6% by mass with respect to the total amount of the beverage. The blending amount of the sucrose is 2.4 to 13.6% by mass with respect to the total amount of the beverage in terms of sucrose (sweetness of high-intensity sweetener x blending ratio of high-intensity sweetener), and It is characterized in that the sum of the product of the sweetness level of the sugar and the blending amount and the product of the sweetness level and the blending amount of the high sweetness sweetener is 7 to 15 , and further deaerated water is blended. How to suppress warming deterioration.
前記高甘味度甘味料が、アセスルファムカリウム及びスクラロースを含有することを特徴とする請求項に記載の加温劣化抑制方法。 The method for inhibiting deterioration of heating according to claim 1 , wherein the high-intensity sweetener contains acesulfame potassium and sucralose. 少なくとも果汁と、ショ糖と、高甘味度甘味料とを配合する工程を含み、
前記工程において、前記ショ糖の配合量が飲料全量に対して1.4〜6.6質量%になるように、前記高甘味度甘味料の配合量がショ糖換算(高甘味度甘味料の甘味度×高甘味度甘味料の配合率)で飲料全量に対して2.4〜13.6質量%になるように、かつ前記ショ糖の甘味度と配合量との積及び前記高甘味度甘味料の甘味度と配合量との積の和が7〜15になるように、前記ショ糖及び前記高甘味度甘味料を配合し、さらに脱気水を配合することを特徴とする加温販売用果汁飲料の製造方法。
Including a step of blending at least fruit juice, sucrose, and a high-intensity sweetener,
In the above step, the blending amount of the high-intensity sweetener is sucrose-converted (of high-intensity sweetener) so that the blending amount of the sucrose is 1.4 to 6.6% by mass relative to the total amount of beverage. The product of the sweetness and the blending amount of sucrose and the high sweetness so that it becomes 2.4 to 13.6% by mass with respect to the total amount of beverage. Mixing the sucrose and the high-intensity sweetener so that the sum of the products of the sweetness and the blending amount of the sweetener is 7 to 15 , and further adding deaerated water Manufacturing method of fruit juice drink for sale.
前記高甘味度甘味料が、アセスルファムカリウム及びスクラロースを含有することを特徴とする請求項に記載の加温販売用果汁飲料の製造方法。 The method for producing a heated beverage for warm sale according to claim 3 , wherein the high-intensity sweetener contains acesulfame potassium and sucralose. 少なくとも果汁と、ショ糖と、高甘味度甘味料とを含有し、
前記ショ糖の配合量が飲料全量に対して1.4〜6.6質量%になるように、前記高甘味度甘味料の配合量がショ糖換算(高甘味度甘味料の甘味度×高甘味度甘味料の配合率)で飲料全量に対して2.4〜13.6質量%になるように、かつ前記ショ糖の甘味度と配合量との積及び前記高甘味度甘味料の甘味度と配合量との積の和が7〜15になるように、前記ショ糖及び前記高甘味度甘味料を含有し、さらに脱気水を含有することを特徴とする、加温による品質の劣化及び液色の色調変化が抑制された加温販売用果汁飲料。
Contains at least fruit juice, sucrose, and a high intensity sweetener,
The blending amount of the high-intensity sweetener is sucrose equivalent so that the blending amount of the sucrose is 1.4 to 6.6% by mass with respect to the total amount of the beverage (sweetness of the high-intensity sweetener × high The blending ratio of the sweetness degree sweetener is 2.4 to 13.6% by mass with respect to the total amount of the beverage, and the product of the sweetness degree and the blending quantity of the sucrose and the sweetness of the high sweetness degree sweetener. It contains the sucrose and the high-intensity sweetener so that the sum of the product of the degree and the blending amount is 7 to 15 , and further contains deaerated water . A fruit juice drink for warming sales in which deterioration and liquid color change are suppressed .
前記高甘味度甘味料が、アセスルファムカリウム及びスクラロースを含有することを特徴とする請求項に記載の加温販売用果汁飲料。 The warm drink fruit juice drink according to claim 5 , wherein the high-intensity sweetener contains acesulfame potassium and sucralose. 透明密閉容器に充填されてなることを特徴とする請求項5又は6に記載の加温販売用果汁飲料。 The fruit juice beverage for warming sales according to claim 5 or 6 , wherein the juice is filled in a transparent sealed container.
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