JP5499423B2 - Ink jet recording ink and ink jet recording apparatus - Google Patents

Description

  The present invention relates to an ink for ink jet recording and an ink jet recording apparatus.

  In the inkjet recording method, droplets of ink of each color of yellow, magenta, cyan, and black are usually printed on paper by various ink ejection methods such as electrostatic suction, electro-mechanical conversion, and electro-thermal conversion. The recording material is ejected from a fine nozzle and adhered to the recording material, and ink dots are formed on the recording material to perform recording. In such an ink jet recording system, various colors are expressed by mixing these inks on the surface of a recording material based on image information. Therefore, in order to perform intended full color recording, it is necessary to mount a predetermined ink cartridge filled with ink of a predetermined color in the ink jet recording apparatus.

  Further, as the ink to be filled in such an ink cartridge, when an ink having the same color as that of the ink to be originally filled but having a different colorant composition is used, solidification or precipitation occurs in a fine nozzle, and normal printing is performed. It may not be possible. Therefore, it is required that an ink jet recording apparatus can identify whether or not a predetermined ink cartridge filled with ink of a predetermined colorant composition is mounted.

  By the way, the coloring agent used for ink-jet recording ink has a property of absorbing only light of a specific wavelength and transmitting light of other wavelengths. In response to the above-described demand, attempts have been made to identify the type of ink by irradiating the ink with light having the maximum absorption peak wavelength of the colorant for coloring. However, even when the ink for inkjet recording is irradiated with light having the maximum absorption peak wavelength of the colorant for color development, the concentration of the colorant in the ink is very high, so that light with such a wavelength hardly transmits the ink. Therefore, in order to accurately identify the type of ink by irradiating the ink with light having the maximum absorption peak wavelength of the coloring agent for color development, it is necessary to dilute the ink to a proper concentration with a solvent such as water. However, it is very difficult to easily identify the type of ink using such a method in the ink jet recording apparatus.

  Therefore, in the past, by mounting an ink cartridge of a predetermined color in advance while confirming visually at a predetermined position of the ink jet recording apparatus, or by attaching an IC chip to the ink cartridge and reading on the main body side of the ink jet recording apparatus, The color and position of the inserted ink cartridge were recognized (Patent Document 1).

JP 2002-192810 A

  However, when an ink cartridge of a predetermined color is visually confirmed in advance and is mounted at a predetermined position of the ink jet recording apparatus, it cannot be determined whether or not the ink filled in the ink cartridge is appropriate. Further, in the case of the method disclosed in Patent Document 1, it is necessary to use a dedicated ink cartridge for specific ink, and there is a problem in that the cost increase and management of the ink cartridge are complicated. In this case as well, it cannot be determined whether or not the ink filled in the ink cartridge is appropriate. In an inkjet printer, a pigment may be used as a colorant for the purpose of improving the weather resistance of the ink. However, since the solid content of the pigment ink is dispersed, if different types of ink are mistakenly introduced into the nozzle, the stability of the pigment particles may be impaired, and the pigment particles may aggregate and block the nozzle. . Further, by adding a colorant as a label to the pigment ink, it can be expected to prevent nozzle clogging due to aggregation of pigment particles in addition to the effects so far.

  SUMMARY An advantage of some aspects of the invention is that it is possible to easily determine whether or not a predetermined ink cartridge filled with a predetermined color ink is attached to an inkjet recording apparatus. The purpose is to enable identification.

  The present inventor uses a pigment as a coloring agent for ink-jet recording ink, and further exhibits an absorption peak wavelength that does not substantially overlap with the maximum absorption peak wavelength of the coloring agent, and develops the color of the ink. In the case where a detection colorant (dye or pigment) having a relatively low absorbance compared to the colorant for color development is used in combination, the absorption peak wavelength of the colorant for detection When light is irradiated, it is not absorbed by the colorant for color development, and therefore it has been found that the presence or absence of a colorant for detection can be easily detected, and the present invention has been completed.

That is, the present invention is an inkjet recording ink containing a first colorant for color development and a second colorant for detection,
The first colorant is a pigment;
The maximum absorption peak wavelength of the first colorant and the detection absorption peak wavelength of the second colorant are different from each other;
The absorbance (b) at the detection absorption peak wavelength of the second colorant is 1.2 times or more the baseline absorbance (c) at the detection absorption peak wavelength of the second colorant,
The color difference (ΔE) between the ink for inkjet recording and the ink prepared by removing the second colorant from the ink is 3 or less, and the absorbance at the detection absorption peak wavelength of the second colorant ( An ink for inkjet recording is provided, wherein b) is 1 to 10 in terms of a measured optical path length of 1 mm.

  The present invention also provides an ink jet recording apparatus in which an ink cartridge filled with the ink for ink jet recording is detachably mounted and an optical sensor for detecting the second colorant is incorporated. Here, it is preferable that the optical sensor can recognize light having two or more wavelengths.

  The ink for inkjet recording of the present invention uses a pigment as a colorant for color development, and in addition to the pigment, a colorant for detection (dye or pigment) that does not substantially participate in the color development of the ink is used in combination. ing. The colorant for detection exhibits an absorption peak wavelength different from the maximum absorption peak wavelength of the colorant for color development, and exhibits a relatively low absorbance as compared with the colorant for color development. Therefore, when the ink for inkjet recording is irradiated with light having the absorption peak wavelength of the colorant for detection, the presence of the colorant for detection in the ink can be detected because it is not strongly influenced by the colorant for color development. . Therefore, the presence or absence of a colorant for detection is detected, and if it can be actually detected, it is determined that a predetermined ink cartridge filled with ink of a predetermined colorant composition is attached to the inkjet recording apparatus. On the other hand, if it cannot be detected, it can be determined that a predetermined ink cartridge filled with ink of a predetermined colorant composition is not attached to the ink jet recording apparatus. Note that when a pigment is used as a colorant for detection, even if the printed material touches water, the printed material does not bleed or change color unlike a dye.

  The ink for inkjet recording of the present invention contains a first colorant for color development and a second colorant for detection. In the present invention, as shown in FIG. 1A, the maximum absorption peak wavelength of the first colorant is different from the detected absorption peak wavelength of the second colorant. In this case, the maximum absorption peak wavelength of the first colorant and the detected absorption peak wavelength of the second colorant may be present in any of the infrared region, visible light region (ie, 360 nm to 780 nm), or ultraviolet region. Although it is good, it is preferable to exist in the visible light region.

  Further, the absorbance (b) at the detection absorption peak wavelength of the second colorant is 1.2 times or more of the baseline absorbance (c) at the detection absorption peak wavelength of the second colorant, as shown in FIG. 1B. It is necessary to become. Preferably it is 1.5 times or more. This is because if the absorbance (b) is less than 1.2 times the baseline absorbance (c), the second colorant tends not to be sufficiently detected. Here, the baseline absorbance (c) is the second coloration in the absorbance curve, wherein a straight line connecting the rising start point and end point of the detection peak of the second colorant is defined as the baseline. It means the absorbance at baseline at the detected absorption peak wavelength of the agent. Alternatively, the baseline absorbance (c) is also the absorbance of the liquid obtained by removing the second colorant for detection from the ink for ink jet recording at the detection absorption peak wavelength of the second colorant.

  In the ink for ink jet recording of the present invention, the absorbance (b) at the detection absorption peak wavelength of the second colorant is 1 when the measured optical path length is converted to 1 mm and converted to the ink stock solution (when measured after dilution). It is necessary to make it become -10. This is because if it is less than 1, the absorption of the colorant itself decreases, and detection of the detection absorption peak becomes difficult, and if it exceeds 10, light does not pass through the ink for ink jet recording. Here, conversion to the measurement optical path length of 1 mm means, for example, that if the measurement optical path length is 10 mm, the actual measurement value of the absorbance at that time is set to 1/10. This means that the measured value of absorbance is 1/5. Ink stock solution conversion is to multiply the actual value of absorbance measured by dilution by the dilution factor. For example, if the ink stock solution is diluted 1000 times and measured, the actual absorbance value at that time is multiplied by the dilution factor 1000. If the ink stock solution is diluted 1600 times and measured, This means that the actual measured value of the absorbance is multiplied by 1600 which is the dilution factor.

  In the ink for ink jet recording of the present invention, the degree of difference between the maximum absorption peak wavelength of the first colorant and the detected absorption peak wavelength of the second colorant is the light of the first colorant in the ink absorbance curve. The detection absorption peak wavelength of the second colorant is preferably present at a position completely away from the absorption region. However, if the detection absorption peak wavelength of the second colorant can be detected, the first colorant The detected absorption peak wavelength of the second colorant may be located on the shoulder of the light absorption curve. Specifically, it is preferable that the detected absorption peak wavelength of the second colorant is at least 50 nm away from the maximum absorption peak wavelength of the first colorant.

  In the inkjet recording ink of the present invention, the detection absorption peak of the second colorant is the same as the maximum absorption peak of the second colorant as long as the detection absorption peak of the second colorant can be detected. It may be a peak or a different peak.

In the ink for ink jet recording of the present invention, the second colorant is used not for color development but for detection, but it is desirable that the second colorant does not substantially affect the color development of the ink for ink jet recording. It is. The level that does not affect this is the color difference (ΔE) between the inkjet recording ink of the present invention containing the second colorant for detection and the comparative ink prepared by removing the second colorant from the ink. If the color difference is too large, the intended color of the ink cannot be realized. Therefore, the color difference (ΔE) needs to be 3 or less (measurement of the color difference was performed in 1976 L ^* a ^* b ^* color system (CIE1976 (L ^* a ^* b ^* ) color system) or JIS Z8729 standardized by the committee (CIE)).

  In the inkjet recording ink of the present invention, the absorbance (a) at the maximum absorption peak wavelength of the first colorant and the absorbance (b) at the detected absorption peak wavelength of the second colorant are expressed by the formula (1). ) Is preferable. This is because if “a / b” is too small, the color difference (ΔE) tends to increase, and if it is too large, the second colorant tends not to be detected sufficiently.

  Examples of preferable combinations of the first colorant and the second colorant as described above are shown below. Note that each of the first colorant and the second colorant may use a single colorant, but two or more colorants may be used in combination. Here, the maximum absorption peak wavelength when two or more colorants are used in combination in the first colorant means a peak wavelength having the greatest absorption among the maximum absorption peak wavelengths of the respective colorants. The detection absorption peak wavelength when two or more colorants are used in combination in the second colorant is arbitrarily selected as long as a predetermined relationship is satisfied in the absorbances (b) and (c) defined above. be able to.

(In the case of yellow ink for inkjet recording)
The first colorant is a pigment (for example, CAB-O-JET (registered trademark) 270Y) having a maximum absorption peak wavelength within a wavelength range of 360 to 450 nm, and the second colorant has a wavelength of 550 to 780 nm. A dye having a detected absorption peak wavelength in the range (eg, CI Direct Blue 199, CI Acid Red 52, CI Acid Blue 9, CI Acid Blue 175, etc.) or a second A pigment whose colorant has a detection absorption peak wavelength within a wavelength range of 550 to 780 nm (for example, CAB-O-JET (registered trademark) 250C, CAB-O-JET (registered trademark) 554B, CAB-O-JET (registered trademark) Trademark) 1027R etc.).

(Magenta ink for inkjet recording)
The first colorant is a pigment (for example, CAB-O-JET (registered trademark) 260M) that exhibits the maximum absorption peak wavelength within a wavelength range of 500 to 570 nm, and the second colorant has a wavelength of 600 to 780 nm. The wavelength of the dye having a detection absorption peak wavelength within the range (for example, CI Direct Blue 199, CI Acid Blue 9, CI Acid Blue 175, etc.) or the second colorant is 600 to 780 nm. A combination that is a pigment having a detection absorption peak wavelength within the range (for example, CAB-O-JET (registered trademark) 250C, CAB-O-JET (registered trademark) 554B, etc.).

(Cyan ink for inkjet recording)
The first colorant is a pigment exhibiting the maximum absorption peak wavelength within the wavelength range of 570 to 780 nm (for example, CAB-O-JET (registered trademark) 250C), and the second colorant has a wavelength of 450 to 500 nm. A dye having a detection absorption peak wavelength in the range (for example, CI Acid Orange 122, CI Acid Orange 80, etc.) or the second colorant has a detection absorption peak wavelength in the wavelength range of 450 to 500 nm. A combination of pigments such as CI Pigment Orange 71.

  The respective contents of the first colorant and the second colorant in the ink jet recording ink of the present invention are the absorbance (b) and the absorbance (b) ( and c) satisfying a predetermined relationship (preferably absorbances (a), (b) and (c) satisfy a predetermined relationship), and containing a second colorant for detection Assuming that the color difference (ΔE) between the inkjet recording ink and the comparative ink prepared by removing the second colorant from the ink is 3 or less, the former (ie, the first colorant) is generally used. For example, 0.1 to 15% by weight, preferably 0.3 to 13% by weight, more preferably 0.5 to 10% by weight, and the latter (ie, the second colorant) is generally 0.001. -0.3% by weight, preferably 0.01-0.1% by weight.

  The ink for inkjet recording of the present invention preferably contains a mixed solvent of water and a water-soluble organic solvent as a solvent in addition to the first colorant and the second colorant.

  As water, it is preferable to use deionized water. The water content in the ink for ink jet recording of the present invention is determined in a wide range according to the type and composition of the water-soluble organic solvent and desired ink characteristics, but is based on the total amount of ink for ink jet recording of the present invention. Generally, it is 10 to 95% by weight, preferably 40 to 80% by weight.

  Water-soluble organic solvents are mainly classified into a wetting agent having an effect of preventing ink drying at the tip of the ink jet head and a penetrating agent that increases the drying speed on the paper surface.

  The wetting agent is not particularly limited. For example, lower alcohols such as methyl alcohol, ethyl alcohol, n-propyl alcohol, isopropyl alcohol, n-butyl alcohol, sec-butyl alcohol, tert-butyl alcohol; dimethylformamide, dimethylacetamide Amides such as acetone, ketones such as diacetone alcohol or keto alcohols; Ethers such as tetrahydrofuran and dioxane; Polyalkylene glycols such as polyethylene glycol and polypropylene glycol; Ethylene glycol, propylene glycol, butylene glycol, diethylene glycol, triethylene glycol, di Alkylene such as propylene glycol, tripropylene glycol, thiodiglycol, hexylene glycol Recall; glycerin; 2-pyrrolidone; N- methyl-2-pyrrolidone; and 1,3-dimethyl-2-imidazolidinone. Of these, polyhydric alcohols such as alkylene glycol and glycerin are preferable. Moreover, these wetting agents can also be used individually or in mixture of 2 or more types.

  The content of the wetting agent in the ink for ink jet recording of the present invention is generally 0 to 95% by weight, preferably 10 to 80% by weight, more preferably 10 to 50% by weight based on the total amount of the ink for ink jet recording of the present invention. %.

  The penetrant is not particularly limited. For example, ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, diethylene glycol methyl ether, diethylene glycol ethyl ether, diethylene glycol propyl ether, diethylene glycol butyl ether, triethylene glycol methyl ether, triethylene Glycol ethyl ether, triethylene glycol propyl ether, triethylene glycol butyl ether, propylene glycol methyl ether, propylene glycol ethyl ether, propylene glycol propyl ether, propylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol ethyl ether Dipropylene glycol propyl ether, dipropylene glycol butyl ether, tripropylene glycol methyl ether, tripropylene glycol ethyl ether, tripropylene glycol propyl ether, and glycol ethers such as tripropylene glycol butyl ether. Moreover, these penetrants can be used alone or in admixture of two or more.

  If the content of the penetrant in the ink for ink jet recording of the present invention is excessive, the penetrability of the ink into the paper becomes too high, which may cause bleeding. It is generally 0 to 20% by weight, preferably 0.1 to 15% by weight, and more preferably 1 to 10% by weight, based on the total amount of ink for inkjet recording.

  The ink for inkjet recording of the present invention may further contain conventionally known additives such as a viscosity modifier, a surface tension modifier, and an antifungal agent, if necessary. It does not specifically limit as said viscosity modifier, For example, polyvinyl alcohol, cellulose, water-soluble resin etc. can be mentioned.

  The ink for ink jet recording of the present invention uniformly mixes the first colorant, the second colorant, and other additive components such as water and a water-soluble organic solvent, and removes insoluble matters with a filter. Can be prepared.

  By filling the ink cartridge for ink-jet recording of the present invention described above into an ink cartridge and detachably mounting the ink cartridge on an ink-jet recording apparatus incorporating a photosensor for detecting the second colorant, It is possible to easily determine whether or not the ink cartridge is filled with appropriate ink. As the ink cartridge, a known cartridge can be used (for example, see JP-A-2002-292890). Moreover, a well-known optical sensor can also be utilized as an optical sensor (for example, Unexamined-Japanese-Patent No. 2004-181474, Unexamined-Japanese-Patent No. 7-232440). In this case, it is preferable that a known light source (for example, Japanese Patent Application Laid-Open Nos. 2004-181474 and 7-232440) that emit light having a detection absorption peak wavelength of the second colorant is incorporated in the ink jet recording apparatus. In addition, it is preferable to use the sensor which can recognize the light of 2 wavelengths or more as an optical sensor. Measurement of absorption at one wavelength is easily affected by the influence of ink density or when different components are mixed, so that the detection accuracy can be improved by measuring the intensity difference between two wavelengths (one light source). Is possible.

  FIG. 2 is a perspective view showing a schematic configuration of an ink jet recording apparatus main body using the ink for ink jet recording of the present invention. The ink jet recording apparatus 1 includes a head unit including an ink cartridge 2 filled with four color inks of cyan, magenta, yellow, and black, and an ink jet head 3 for printing on a recording material P such as recording paper. 4, a carriage 5 on which the ink cartridge 2 and the head unit 4 are mounted, a drive unit 6 that reciprocates the carriage 5 in a linear direction, and extends in the reciprocating direction of the carriage 5, and is disposed to face the inkjet head 3. A platen roller 7 and a purge device 8 are provided. In addition, a light source for irradiating light of the detection absorption peak wavelength of the second colorant to the ink in each ink flow path from the ink cartridge 2 to the nozzle of the ink jet head 3 and light transmitted through the ink are received. With a light sensor. For example, in the case of the ink jet recording apparatus shown in FIG. 2 in which the ink cartridge is directly mounted on the carriage, a light sensor may be provided inside the carriage 5 or on the side surface facing the carriage 5 and a light source may be installed at the reset position. Although not shown, in the case of an ink jet recording apparatus in which ink is supplied from an ink cartridge to an ink jet head through a tube, an optical sensor is installed in front of the ink cartridge, the ink flow path, and the nozzle in the head, preferably the cartridge. And a light source may be installed at an appropriate position corresponding to it.

  Four inks filled with cyan ink, magenta ink, yellow ink, and black ink are placed between the pair of side covers 4b formed on both sides of the placement portion 4a on the placement portion 4a of the head unit 4. A cartridge 2 is mounted.

  The drive unit 6 includes a carriage shaft 9 disposed at the lower end portion of the carriage 5 and extending in parallel with the platen roller 7, a guide plate 10 disposed at the upper end portion of the carriage 5 and extending in parallel with the carriage shaft 9, and the carriage shaft 9. It consists of two pulleys 11 and 12 disposed between the guide plate 10 and at both ends of the carriage shaft 9, and an endless belt 13 spanned between these pulleys 11 and 12.

  When one pulley 11 is rotated forward and backward by driving the carriage motor 101, the carriage 5 joined to the endless belt 13 is moved along with the forward and reverse rotation of the pulley 11 to the carriage shaft 9 and the guide plate. 10 is reciprocated in a linear direction.

  The recording material P is fed from a paper feed cassette (not shown) provided on the side or lower side of the ink jet recording apparatus 1 and is introduced between the ink jet head 3 and the platen roller 7, and the ink jet head. Predetermined printing is performed with the ink ejected from 3, and then the paper is discharged. In FIG. 2, the paper feed mechanism and paper discharge mechanism for the recording material P are not shown.

  The purge device 8 is provided on the side of the platen roller 7 and is disposed so as to face the inkjet head 3 when the head unit 4 is at the reset position. The purge device 8 includes a purge cap 14 that abuts against an opening surface of the nozzle so as to cover a plurality of nozzles (not shown) of the inkjet head 3, a pump 15 and a cam 16, and an ink storage portion 17. When the head unit 4 is at the reset position, the nozzle of the ink jet head 3 is covered with the purge cap 14, and defective ink containing bubbles and the like accumulated inside the ink jet head 3 is driven by the pump 15 by driving the cam 16. By sucking, the inkjet head 3 is recovered. The sucked defective ink is stored in the ink storage unit 17.

  A wiper member 20 is disposed adjacent to the purge device 8 at a position on the platen roller 7 side in the purge device 8. The wiper member 20 is formed in a spatula shape and wipes the nozzle forming surface of the inkjet head 3 as the carriage 5 moves. The cap 18 covers a plurality of nozzles of the inkjet head 3 that is returned to the reset position when printing is completed in order to prevent ink from drying.

  In this ink jet recording apparatus, light is emitted from a light source that emits light having a detection absorption peak wavelength of the second colorant to the ink in each ink flow path from the ink cartridge 2 to the nozzles of the ink jet head 3. The light transmitted through the ink is received by the optical sensor. Then, at the detected absorption peak wavelength of the second colorant, an absorption peak showing an absorbance exceeding the base line absorbance can be detected, and the ratio between the incident light intensity and the transmitted light intensity can be taken. Therefore, the presence of the second colorant in the ink can be confirmed, and it can be determined that the ink cartridge filled with the appropriate ink is mounted on the ink jet recording apparatus.

Examples Y1-Y5, Comparative Examples Y1-Y5
The ink composition shown in Table 1 was mixed and stirred, and then filtered through a cellulose acetate type membrane filter (manufactured by Toyo Filter Paper Co., Ltd.) having a pore size of 3 μm to obtain a yellow ink for ink jet recording.

Examples M1 to M5, Comparative Examples M1 to M4
After mixing and stirring the ink compositions in Table 2, magenta ink for inkjet recording was obtained by filtering through a cellulose acetate type membrane filter (manufactured by Toyo Roshi Kaisha, Ltd.) having a pore diameter of 3 μm.

Examples C1-C3, Comparative Examples C1-C4
The ink compositions in Table 3 were mixed and stirred, and then filtered through a cellulose acetate type membrane filter having a pore diameter of 3 μm (manufactured by Toyo Roshi Kaisha, Ltd.) to obtain a cyan ink for inkjet recording.

(Evaluation method)
The obtained ink for inkjet recording of each color is subjected to absorbance measurement as described below, the absorbance (a) at the maximum absorption peak wavelength of the first colorant, and the absorbance at the detection absorption peak wavelength of the second colorant. (B) The baseline absorbance (c) at the detected absorption peak wavelength of the second colorant was determined, and the baseline absorbance ratio (b / c) and the colorant absorbance ratio (a / b) were calculated. The obtained results are shown in Tables 1 to 3. In addition, ink detection evaluation, color difference evaluation, and comprehensive evaluation were performed on the obtained inks for ink jet recording of each color as described below. The obtained results are also shown in Tables 1 to 3.

<Absorbance measurement>
In measuring the absorbance (a) at the maximum absorption peak wavelength of the first colorant, the yellow ink is 1600 times diluted (diluted solvent: pure water), the magenta ink 1000 times diluted (diluted solvent: pure water), and the cyan ink 1000. In the measurement of the absorbance (b) at the detection absorption peak wavelength of the second coloring agent (dilution solvent: pure water), the yellow ink stock solution, the magenta ink stock solution, and the cyan ink 10-fold dilution solution (dilution solvent: pure water) ) Was measured using a spectrophotometer (UV3600, manufactured by Shimadzu Corporation) with a cell length of 1 mm and pure water as a reference. Thereafter, values obtained by converting the measured optical path length to 1 mm and the ink stock solution were calculated.

<Ink detection evaluation>
A yellow ink stock solution, a magenta ink stock solution, and a cyan ink stock solution were respectively filled in ink cartridges for a commercially available ink jet recording apparatus (DCP-330C, manufactured by Brother Industries, Ltd.). A protrusion region having a cell length of 2 mm was formed on the ink cartridge, and an optical sensor was installed at the location of the ink jet recording apparatus corresponding to that location to detect the detection absorption peak wavelength of the second colorant. When it was detected, “G” was described in Tables 1 to 3, and “NG” was described when it was not detected.

<Color difference evaluation>
Yellow ink 1600-fold diluted solution (diluted solvent: pure water), magenta ink 1000-fold diluted solution (diluted solvent: pure water) and cyan ink 1000-fold diluted solution (diluted solvent: pure water) obtained in each Example and Comparative Example ) Was measured using a spectrophotometer (UV3600, manufactured by Shimadzu Corporation) with a cell length of 10 mm and pure water as a reference, and L ^* value, a ^* value and b ^* value were obtained, respectively. The obtained numerical values were defined as L ^* ₁ , a ^* _1, and b ^* ₁ , respectively. These numerical values are based on the L ^* a ^* b ^* color system (CIE1976 (L ^* a ^* b ^* ) color system) standardized by the International Commission on Illumination (CIE) in 1976 (JIS). Z8729).

A reference ink-jet recording ink was prepared without using the second colorant, and the decrease in the second colorant was supplemented with water, and the color measurement was performed in the same manner. The L ^* value, a ^* value and b ^* values were determined. The obtained numerical values were defined as L ^* ₂ , a ^* ₂ and b ^* ₂ , respectively.

The obtained L ^* ₁ , a ^* _1, and b ^* ₁ , L ^* ₂ , a ^* _2, and b ^* ₂ values were substituted into Equation (3) to determine the color difference (ΔE).

  Further, the ink obtained in each of the examples and comparative examples is filled in a desired ink cartridge, and is mounted on a digital multifunction machine equipped with an inkjet printer (manufactured by Brother Industries, Ltd .; DCP-110C). In addition, a monochrome gradation sample of each color of cyan ink was printed. Similarly, a reference inkjet recording ink in which the second colorant was not used and the decrease in the second colorant was compensated with water was prepared, and a monochrome gradation sample was printed. The glossy paper used is Image (registered trademark) Fujifilm high-grade glossy paper (manufactured by Fuji Photo Film Co., Ltd.).

  When the obtained monochrome gradation samples corresponding to each color are visually observed and the printed matter cannot be distinguished, “G” is described in Tables 1 to 3, and “NG” is described when the distinction is made. did.

<Comprehensive evaluation>
Considering the result of ink detection evaluation and the result of color difference evaluation, comprehensive evaluation was performed according to the following criteria.

Comprehensive evaluation criteria A: When the results of ink detection evaluation and color difference evaluation are both G: C: When at least one of the results of ink detection evaluation and color difference evaluation is NG

  As apparent from Tables 1 to 3, the absorbance (b) at the detection absorption peak wavelength of the second colorant is 1.2 times or more the baseline absorbance (c) at the detection absorption peak wavelength of the second colorant. Ink-jet recording ink, wherein the color difference (ΔE) between the ink and the ink prepared by removing the second colorant from the ink is 3 or less, and at the detection absorption peak wavelength of the second colorant The inks for ink-jet recording of the respective colors of Examples having an absorbance of 1 to 10 in terms of a measurement optical path length of 1 mm showed good results for ink detection evaluation, color difference evaluation and comprehensive evaluation. On the other hand, the ink jet recording ink of the comparative example lacking any of these conditions has a problem in at least one of ink detection evaluation and color difference evaluation, and the overall evaluation is not a preferable example.

  The ink for ink jet recording of the present invention uses a pigment as a colorant for color development, and in addition to the pigment, the colorant for color development exhibits an absorption peak wavelength different from the maximum absorption peak wavelength of the colorant for color development. A colorant for detection which exhibits a relatively low absorbance as compared with the above and does not substantially participate in the color development of the ink is used in combination. Therefore, when the ink for inkjet recording is irradiated with light having the absorption peak wavelength of the colorant for detection, the presence of the colorant for detection in the ink can be detected because it is not strongly influenced by the colorant for color development. . Therefore, it is possible to surely grasp whether or not an ink jet cartridge suitable for the ink jet recording apparatus is mounted, and it is possible to realize acquisition of a good quality color image and prevention of a malfunction of the ink jet recording apparatus. it can. Accordingly, the inkjet recording ink of the present invention is an ink having great advantages as an inkjet recording ink.

3 is an absorbance curve of ink for inkjet recording. It is an absorbance curve near the detection absorption peak wavelength of the second colorant. 1 is a schematic perspective view of an ink jet recording apparatus main body.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Inkjet recording device 2 Ink cartridge 3 Inkjet head 4 Head unit 4a Mounting part 4b Side cover 5 Carriage 6 Drive unit 7 Platen roller 8 Purge device 9 Carriage shaft 10 Guide plate 101 Carriage motor 11 Pulley 12 Pulley 13 Endless belt 14 Purge cap 15 Pump 16 Cam 17 Ink reservoir 18 Cap 20 Wiper member P Recording material

Claims (7)

A first colorant for color development and a second colorant to be detected for identifying whether or not a predetermined ink cartridge filled with a predetermined color ink is mounted on the ink jet recording apparatus An ink for ink jet recording containing
When the inkjet recording ink is a yellow ink, the first colorant is a pigment exhibiting a maximum absorption peak wavelength within a wavelength range of 360 to 450 nm, and the second colorant has a wavelength of 550 to 780 nm. A dye or pigment having a detected absorption peak wavelength in the range;
When the inkjet recording ink is a magenta ink, the first colorant is a pigment exhibiting a maximum absorption peak wavelength within a wavelength range of 500 to 570 nm, and the second colorant is a wavelength range of 600 to 780 nm. It is a dye or pigment having a detection absorption peak wavelength inside,
When the ink for inkjet recording is a cyan ink, the first colorant is a pigment exhibiting a maximum absorption peak wavelength within a wavelength range of 570 to 780 nm, and the second colorant is a wavelength range of 450 to 500 nm. It is a dye or pigment having a detection absorption peak wavelength inside,
The content of the first colorant is 0.3 to 13% by weight, the content of the second colorant is 0.01 to 0.1% by weight,
The maximum absorption peak wavelength of the first colorant and the detected absorption peak wavelength of the second colorant are present in the visible light region;
The absorbance (b) at the detection absorption peak wavelength of the second colorant is 1.2 times or more the baseline absorbance (c) at the detection absorption peak wavelength of the second colorant,
The color difference (ΔE) between the ink for inkjet recording and the ink prepared by removing the second colorant from the ink is 3 or less, and the absorbance at the detection absorption peak wavelength of the second colorant ( Ink for ink jet recording, wherein b) is 1 to 10 in terms of 1 mm of the measured optical path length.   The absorbance (b) at the detection absorption peak wavelength of the second colorant is 1.5 times or more the baseline absorbance (c) at the detection absorption peak wavelength of the second colorant. Ink for ink jet recording.   The ink for inkjet recording according to claim 1 or 2, wherein the difference between the maximum absorption peak wavelength of the first colorant and the detected absorption peak wavelength of the second colorant is at least 50 nm. The ink for inkjet recording according to any one of claims 1 to 3 , wherein the second colorant is a pigment. The absorbance (a) at the maximum absorption peak wavelength of the first colorant and the absorbance (b) at the detection absorption peak wavelength of the second colorant are expressed by the formula (1).

The ink for ink-jet recording according to any one of claims 1 to 4, which satisfies: An ink jet recording apparatus in which the ink cartridge filled with the ink for ink jet recording according to any one of claims 1 to 5 is detachably mounted, and an optical sensor for detecting the second colorant is incorporated. The inkjet recording apparatus according to claim 6 , wherein the optical sensor is an optical sensor that recognizes light having two or more wavelengths.

Images