JP5478151B2 - Fluid supply device - Google Patents

Fluid supply device Download PDF

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JP5478151B2
JP5478151B2 JP2009195598A JP2009195598A JP5478151B2 JP 5478151 B2 JP5478151 B2 JP 5478151B2 JP 2009195598 A JP2009195598 A JP 2009195598A JP 2009195598 A JP2009195598 A JP 2009195598A JP 5478151 B2 JP5478151 B2 JP 5478151B2
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aqueous solution
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supply path
hydrochloric acid
receiving
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JP2011045823A (en
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元 川崎
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Tacmina Corp
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本発明は、二種類の流体をそれぞれ供給する流体供給装置であって、特に、次亜塩素酸塩水溶液と塩酸水溶液を混合して、食品等の殺菌に用いられる弱酸性塩素水を製造する弱酸性塩素水製造装置に適用される2流体混合装置に関する。   The present invention is a fluid supply device for supplying two kinds of fluids, respectively, and in particular, a weakly acidic chlorine water used for sterilization of foods or the like by mixing a hypochlorite aqueous solution and a hydrochloric acid aqueous solution. The present invention relates to a two-fluid mixing device applied to an acidic chlorine water production device.

例えば、食品等の殺菌対象物を殺菌する殺菌剤としては、次亜塩素酸ナトリウム水溶液といった次亜塩素酸塩水溶液が一般的に使用されている。この次亜塩素酸塩水溶液は、水素イオン指数(以下「pH」という)が比較的高く(例えばpH8以上)、その状態で使用される場合が多いが、pHが高いと、遊離塩素として次亜塩素酸イオンの存在率が高くなり、この場合の殺菌力は、比較的弱い。   For example, a hypochlorite aqueous solution such as a sodium hypochlorite aqueous solution is generally used as a disinfectant for sterilizing an object to be sterilized such as food. This aqueous hypochlorite aqueous solution has a relatively high hydrogen ion index (hereinafter referred to as “pH”) (for example, pH 8 or more) and is often used in this state. The abundance of chlorate ions increases, and the bactericidal power in this case is relatively weak.

そのため、次亜塩素酸塩水溶液に、より強い殺菌力を発揮させるには、pHを低くして、次亜塩素酸の存在率を高めることが望ましいが、このpHが低過ぎると(例えばpH4以下の場合)、有毒な塩素ガスが多量に発生するため、好ましくない。   Therefore, in order to exert a stronger sterilizing power in the hypochlorite aqueous solution, it is desirable to lower the pH and increase the abundance of hypochlorous acid, but if this pH is too low (for example, pH 4 or lower) In this case, a large amount of toxic chlorine gas is generated, which is not preferable.

したがって、塩素ガスの発生を抑制しながらも、高い殺菌力を発揮させるには、次亜塩素酸塩水溶液のpHを6程度の弱酸性の状態になるように調節するのが望ましい。例えば、この次亜塩素酸塩水溶液のpHの調節には、塩酸水溶液が用いられる。次亜塩素酸塩水溶液に塩酸水溶液を混合してpHを調節するには、希釈水を供給する供給経路に次亜塩素酸塩水溶液と塩酸水溶液を混合してスタティックミキサーで混合・希釈する手法が一般的である。このようにすることで、所定のpHに調整された、殺菌効果の高い弱酸性塩素水が生成される。   Therefore, it is desirable to adjust the pH of the hypochlorite aqueous solution to be in a slightly acidic state of about 6 in order to exert high sterilizing power while suppressing generation of chlorine gas. For example, a hydrochloric acid aqueous solution is used for adjusting the pH of the hypochlorite aqueous solution. In order to adjust pH by mixing aqueous hydrochloric acid solution with hypochlorite aqueous solution, a method of mixing hypochlorite aqueous solution and aqueous hydrochloric acid solution in a supply path for supplying dilution water, and mixing and diluting with a static mixer. It is common. By doing in this way, the weak acidic chlorine water with the high bactericidal effect adjusted to predetermined | prescribed pH is produced | generated.

しかしながら、希釈水の供給経路に次亜塩素酸塩水溶液と塩酸水溶液を注入して混合・希釈させた場合、局部的に濃度の高い次亜塩素酸塩水溶液と濃度の高い塩酸水溶液とが接触し、これによって、有毒な塩素ガスが発生するおそれがある。したがって、次亜塩素酸塩水溶液と塩酸水溶液を段階的に希釈することにより、塩素ガスの発生を抑制することが必要になるが、その際に、塩酸水溶液を貯留する第1貯留タンクと、次亜塩素酸塩水溶液を貯留する第2貯留タンクとを取り違えることなく、各溶液を供給する供給経路に確実に取り付けることが肝要になる。   However, when hypochlorite aqueous solution and hydrochloric acid aqueous solution are injected into the dilution water supply path and mixed and diluted, the locally concentrated hypochlorite aqueous solution and the concentrated hydrochloric acid aqueous solution come into contact with each other. As a result, toxic chlorine gas may be generated. Therefore, it is necessary to dilute the hypochlorite aqueous solution and the hydrochloric acid aqueous solution step by step to suppress the generation of chlorine gas. At this time, the first storage tank for storing the hydrochloric acid aqueous solution, It is important that the second storage tank for storing the chlorite aqueous solution is securely attached to the supply path for supplying each solution without being mistaken for the second storage tank.

本発明は、上記の事情に鑑みてなされたものであり、二種類の流体を貯留する第1及び第2タンクを取り違えることなく、対応した供給経路に確実に取り付けるようにした流体供給装置を提供することを課題とする。   The present invention has been made in view of the above circumstances, and provides a fluid supply device that is securely attached to a corresponding supply path without mistaking the first and second tanks that store two types of fluids. The task is to do.

本発明は上記の課題を解決するためのものであり、断面が円形状のタンク本体551,581、該タンク本体551,581の底部の流出孔552a,582aに設けられる開閉弁553,583、及び、該開閉弁553,583を囲むように、タンク本体551,581の底部に形成される挿入部552,582を有し、二種類の流体が個別に貯留される第1及び第2貯留タンク550,580と、タンク本体551,581が挿脱される上側受け部561,591、挿入部552,582が挿脱される下側受け部562,592、及び、開閉弁553,583を押し開けるように、下側受け部562,592内に設けられる突起563,593を有する第1及び第2受け体560,590と、該各受け体560,590に取り付けられた貯留タンク550,580の流体を流出孔552a,582aを通って下流側に流通させるための第1及び第2供給経路3,5とを備えた流体供給装置であって、前記第1貯留タンク550のタンク本体551の断面は、第2貯留タンク580のタンク本体581の断面よりも小径で、第1貯留タンク550の挿入部552の断面は、第2貯留タンク580の挿入部582の断面よりも大きく、前記各受け体560,590は、各貯留タンク550,580のタンク本体551,581及び挿入部552,582の外形に対応する上側受け部561,591及び下側受け部562,592を有し、外径の小さい前記タンク本体551が挿脱される前記第1受け体560の前記上側受け部561の内径は、外径の小さい前記タンク本体551の外径よりも大きく、且つ外径の大きい前記タンク本体581が挿脱される前記第2受け体590の前記上側受け部591の内径と同一であって、前記第1受け体560は、該第1受け体560に挿入された調整部材561aにより、前記外径の小さいタンク本体551の外径に合わせて内径が調整されていることを特徴とする。 The present invention is to solve the above-described problems, and has a tank body 551,581 having a circular cross section, on-off valves 553,583 provided in the outflow holes 552a, 582a at the bottom of the tank body 551,581, and The first and second storage tanks 550 have insertion portions 552 and 582 formed at the bottoms of the tank main bodies 551 and 581 so as to surround the on-off valves 553 and 583, and store two kinds of fluids individually. 580, upper receiving portions 561, 591 into which the tank main bodies 551, 581 are inserted / removed, lower receiving portions 562, 592 from which the inserting portions 552, 582 are inserted / removed, and the open / close valves 553, 583. The first and second receiving bodies 560 and 590 having projections 563 and 593 provided in the lower receiving portions 562 and 592 and attached to the receiving bodies 560 and 590, respectively. A fluid supply device including first and second supply paths 3 and 5 for circulating the fluid in the distillation tanks 550 and 580 through the outflow holes 552a and 582a to the downstream side, and the first storage tank 550 The cross section of the tank main body 551 is smaller in diameter than the cross section of the tank main body 581 of the second storage tank 580, and the cross section of the insertion portion 552 of the first storage tank 550 is smaller than the cross section of the insertion portion 582 of the second storage tank 580. Each of the receiving bodies 560 and 590 has an upper receiving portion 561, 591 and a lower receiving portion 562, 592 corresponding to the outer shapes of the tank main bodies 551, 581 and the insertion portions 552, 582 of the storage tanks 550, 580. The inner diameter of the upper receiving portion 561 of the first receiving body 560 through which the tank main body 551 having a small outer diameter is inserted and removed is that of the tank main body 551 having a small outer diameter. Greater than the diameter, and the tank main body 581 having a large outer diameter I inside diameter identical der of the upper receiving portion 591 of the are inserted and removed a second receiving body 590, the first receiving member 560, said by the inserted adjusting member 561a to 1 receiving body 560, an inner diameter to fit the outside diameter of the outer diameter of a small tank body 551 is characterized that you have been adjusted.

この場合、第1貯留タンク550のタンク本体551の断面を、第2貯留タンク580のタンク本体581の断面よりも小さくしたので、タンク本体551,581の取り違えを防止できるようになる。さらに、第1貯留タンク550の挿入部552の断面を、第2貯留タンク580の挿入部582の断面よりも大きくしたので、タンク本体551,581を万が一取り違えたとしても、受け体560,590に挿入できないようになっている。即ち、二重の防止構造となっているので、タンク本体551,581を取り違えることなく確実に受け体560,590に挿入できるようになる
In this case, since the cross section of the tank main body 551 of the first storage tank 550 is made smaller than the cross section of the tank main body 581 of the second storage tank 580, it is possible to prevent the tank main bodies 551 and 581 from being mixed up. Furthermore, since the cross section of the insertion portion 552 of the first storage tank 550 is made larger than the cross section of the insertion portion 582 of the second storage tank 580, even if the tank main bodies 551, 581 are mistaken, the receivers 560, 590 It cannot be inserted. That is, since it has a double prevention structure, the tank main bodies 551 and 581 can be reliably inserted into the receiving bodies 560 and 590 without being mistaken .

本発明によれば、第1貯留タンクのタンク本体の断面を、第2貯留タンクのタンク本体の断面よりも小さくすると共に、第1受け体に挿入される第1貯留タンクの挿入部の断面を、第2貯留タンクの挿入部の断面よりも大きくなるようにして、さらに、各受け体の上側受け部及び下側受け部を、各貯留タンクのタンク本体及び挿入部の外形に対応するようにしたので、タンク本体を取り違えることを防止できると共に、対応した受け体に確実に挿入することができる効果がある。 According to the present invention, the cross-section of the tank body of the first storage tank, as well as smaller than the cross section of the tank main body in the second storage tank, the insertion portion of the cross-section of the first storage tank to be inserted into the first receiving member The upper receiving part and the lower receiving part of each receiving body correspond to the outer shape of the tank main body and the inserting part of each storing tank, so that it is larger than the cross section of the inserting part of the second storing tank. Therefore, it is possible to prevent the tank body from being mistaken and to be surely inserted into the corresponding receiving body.

本発明の一実施形態に係る弱酸性塩素水製造装置のフロー図。The flowchart of the weak acidic chlorine water manufacturing apparatus which concerns on one Embodiment of this invention. 弱酸性塩素水製造装置の要部の拡大図。The enlarged view of the principal part of a weak acidic chlorine water manufacturing apparatus. 塩酸水溶液を貯留する第1貯留タンクを示す拡大図。The enlarged view which shows the 1st storage tank which stores hydrochloric acid aqueous solution. 次亜塩素酸塩水溶液を貯留する第2貯留タンクを示す拡大図。The enlarged view which shows the 2nd storage tank which stores hypochlorite aqueous solution. 第1貯留タンクを、第1受け体を介して第1供給容器に取り付けた状態を示す拡大図。The enlarged view which shows the state which attached the 1st storage tank to the 1st supply container via the 1st receiving body. 第2貯留タンクを、第2受け体を介して第2供給容器に取り付けた状態を示す拡大図。The enlarged view which shows the state which attached the 2nd storage tank to the 2nd supply container via the 2nd receiving body. (a),(b)は、第1貯留タンクの変形例で、断面が四角形の第1貯留タンクを示す正面図及び平面図。(A), (b) is the modification of a 1st storage tank, and the front view and top view which show the 1st storage tank whose cross section is a square. (a),(b)は、第2貯留タンクの変形例で、断面が円形の第2貯留タンクを示す正面図及び平面図。(A), (b) is the modification of a 2nd storage tank, and the front view and top view which show the 2nd storage tank with a circular cross section.

以下、本発明に係る流体供給装置につき、一実施形態として、二流体混合装置の一態様である弱酸性塩素水製造装置を例にとって図面を参照しつつ説明する。   Hereinafter, a fluid supply apparatus according to the present invention will be described as an embodiment with reference to the drawings, taking as an example a weakly acidic chlorine water production apparatus which is an aspect of a two-fluid mixing apparatus.

図1、図2に示す弱酸性塩素水製造装置1は、次亜塩素酸塩水溶液、塩酸水溶液を希釈水で希釈し、希釈された次亜塩素酸塩水溶液と塩酸水溶液を混合・希釈させて所定のpHの弱酸性塩素水を製造するものである。本実施形態では、次亜塩素酸塩水溶液として所定濃度の次亜塩素酸ナトリウム水溶液が用いられる。次亜塩素酸塩水溶液のpH調節剤として用いられる塩酸水溶液の原液には、所定の重量パーセント濃度のものが用いられる。この塩酸水溶液は、有機物の影響を受けない点で特に有用である。なお、本実施形態において、「弱酸性」とはpH5〜7の範囲をいう(pH7は厳密に言えば、中性だが、ここでは「弱酸性」として取り扱うこととする)。   The weakly acidic chlorinated water production apparatus 1 shown in FIGS. 1 and 2 dilutes a hypochlorite aqueous solution and a hydrochloric acid aqueous solution with a dilution water, and mixes and dilutes the diluted hypochlorite aqueous solution and the hydrochloric acid aqueous solution. A weakly acidic chlorinated water having a predetermined pH is produced. In this embodiment, a sodium hypochlorite aqueous solution having a predetermined concentration is used as the hypochlorite aqueous solution. As a stock solution of a hydrochloric acid aqueous solution used as a pH adjuster for a hypochlorite aqueous solution, a solution having a predetermined weight percent concentration is used. This aqueous hydrochloric acid solution is particularly useful in that it is not affected by organic substances. In the present embodiment, “weakly acidic” refers to a range of pH 5 to 7 (pH 7 is strictly speaking neutral, but here treated as “weakly acidic”).

弱酸性塩素水製造装置1は、希釈水を供給する主供給経路2と、塩酸水溶液を希釈する希釈水が供給される第1供給経路3と、第1供給経路3に塩酸水溶液を供給する供給装置(以下「第1供給装置」という)4と、次亜塩素酸塩水溶液を希釈する希釈水が供給される第2供給経路5と、第2供給経路5に次亜塩素酸塩水溶液を供給する供給装置(以下「第2供給装置」という)6と、第1供給経路3と第2供給経路5を合流させるとともに、第1供給経路3で希釈された塩酸水溶液と第2供給経路5で希釈された次亜塩素酸塩水溶液とを混合させて希釈することにより、所定の水素イオン指数の弱酸性塩素水を生成する第3供給経路7と、第1供給装置4、第2供給装置6を制御する制御装置8等を備えている。   The weakly acidic chlorinated water production apparatus 1 includes a main supply path 2 for supplying dilution water, a first supply path 3 for supplying dilution water for diluting hydrochloric acid aqueous solution, and a supply for supplying hydrochloric acid aqueous solution to the first supply path 3 A device (hereinafter referred to as “first supply device”) 4, a second supply path 5 for supplying dilution water for diluting the hypochlorite aqueous solution, and supplying a hypochlorite aqueous solution to the second supply path 5 A supply device (hereinafter referred to as a “second supply device”) 6, a first supply path 3 and a second supply path 5, and a hydrochloric acid solution diluted in the first supply path 3 and the second supply path 5. A third supply path 7, a first supply device 4, and a second supply device 6 that generate weakly acidic chlorinated water having a predetermined hydrogen ion index by mixing and diluting the diluted hypochlorite aqueous solution. A control device 8 or the like is provided.

主供給経路2には、送水ポンプ21、流量調整弁(例えばニードル弁)22、流量計23、圧力計24が設けられており、希釈水は送水ポンプ21によって主供給経路2の下流に送水され、その希釈水の流量、圧力を、流量計23、圧力計24で測定できるようになっている。主供給経路2の下流側には、第1供給経路3と第2供給経路5が分岐して設けられている。   The main supply path 2 is provided with a water supply pump 21, a flow rate adjusting valve (for example, a needle valve) 22, a flow meter 23, and a pressure gauge 24, and dilution water is supplied downstream of the main supply path 2 by the water supply pump 21. The flow rate and pressure of the dilution water can be measured with a flow meter 23 and a pressure meter 24. A first supply path 3 and a second supply path 5 are branched from the main supply path 2.

第1供給経路3には、第1供給装置4から供給される塩酸水溶液を注入するための第1注入口31と、第1供給装置4から供給された塩酸水溶液を希釈水と混合して希釈する第1混合希釈部(リアクションタンク)32と、第1供給経路3を流れる塩酸水溶液(希釈水を含む)の流量を調整する第1流量調整弁(例えばニードル弁)33が設けられている。   In the first supply path 3, a first inlet 31 for injecting a hydrochloric acid aqueous solution supplied from the first supply device 4 and a hydrochloric acid aqueous solution supplied from the first supply device 4 are mixed with dilution water for dilution. And a first flow rate adjustment valve (for example, a needle valve) 33 that adjusts the flow rate of the aqueous hydrochloric acid solution (including dilution water) flowing through the first supply path 3.

第1混合希釈部32は、その内径が第1供給経路3の内径よりも大きくなっており、その中途部に複数の貫通孔34aを有する板部材(邪魔板)34が設けられている。これにより、第1混合希釈部32の板部材34よりも上流側の部分には、第1混合希釈部32内に流入した塩酸水溶液と希釈水に対する流量抵抗を生じさせて、塩酸水溶液と希釈水とを混合させる領域(以下「第1反応領域」という)35が形成される。   The first mixing dilution section 32 has an inner diameter larger than the inner diameter of the first supply path 3, and a plate member (baffle plate) 34 having a plurality of through holes 34 a is provided in the middle. As a result, a flow resistance against the aqueous hydrochloric acid solution and the diluting water that has flowed into the first mixed diluting unit 32 is generated at a portion upstream of the plate member 34 of the first mixed diluting unit 32, and the aqueous hydrochloric acid solution and the diluting water are generated. A region 35 (hereinafter referred to as “first reaction region”) is formed.

また、第1混合希釈部32は、板部材34より下流側の部分に、板部材34の貫通孔34aを通過して拡散した塩酸水溶液と希釈水をさらに均一に希釈させる領域(以下「第1安定領域」という)36が形成されている。第1供給経路3に供給された希釈水と塩酸水溶液は、板部材34による流量抵抗によって第1反応領域35で所定時間混合され、板部材34の貫通孔34aを通過することによって、第1安定領域36内に拡散し、この第1安定領域36を通過することによって均一に希釈され、所定濃度に希釈された塩酸水溶液となる。   The first mixing / dilution unit 32 further uniformly dilutes the hydrochloric acid aqueous solution and the diluting water diffused through the through hole 34a of the plate member 34 in a portion downstream of the plate member 34 (hereinafter referred to as “first”). 36) is formed. The dilution water and the hydrochloric acid aqueous solution supplied to the first supply path 3 are mixed for a predetermined time in the first reaction region 35 by the flow resistance of the plate member 34, and pass through the through hole 34 a of the plate member 34. By diffusing into the region 36 and passing through the first stable region 36, the solution is uniformly diluted to form a hydrochloric acid aqueous solution diluted to a predetermined concentration.

第1流量調整弁33は、第1混合希釈部32の下流側に設けられており、この第1流量調整弁33を操作することにより、第1混合希釈部32内の圧力を調整するとともに、第1混合希釈部32によって希釈された塩酸水溶液、または、第1混合希釈部32に流入する前の希釈水の流量を調節できるようになっている。   The first flow rate adjustment valve 33 is provided on the downstream side of the first mixing / dilution unit 32. By operating the first flow rate adjustment valve 33, the pressure in the first mixing / dilution unit 32 is adjusted, The flow rate of the aqueous hydrochloric acid diluted by the first mixing / dilution unit 32 or the dilution water before flowing into the first mixing / dilution unit 32 can be adjusted.

第2供給経路5には、第2供給装置6から供給される次亜塩素酸塩水溶液を注入する第2注入口41と、第2供給装置6から供給された次亜塩素酸塩水溶液と希釈水とを混合して希釈する第2混合希釈部(リアクションタンク)42と、第2供給装置6を流れる次亜塩素酸塩水溶液(希釈水を含む)の流量を調整する第2流量調整弁(例えばニードル弁)43が設けられている。   In the second supply path 5, a second inlet 41 for injecting a hypochlorite aqueous solution supplied from the second supply device 6, and a hypochlorite aqueous solution and dilution supplied from the second supply device 6 A second flow dilution valve (reaction tank) 42 for mixing and diluting water, and a second flow rate adjusting valve (for adjusting the flow rate of the hypochlorite aqueous solution (including diluted water) flowing through the second supply device 6) For example, a needle valve) 43 is provided.

第2混合希釈部42は、第1混合希釈部32と同様に、その内径が第2供給経路5の内径よりも大きくなっており、その中途部に複数の貫通孔44aを有する板部材(邪魔板)44が設けられている。これにより、第2混合希釈部42の板部材44よりも上流側の部分には、第2混合希釈部42内に流入した次亜塩素酸塩水溶液と希釈水に対する流量抵抗を生じさせて、塩酸水溶液と希釈水とを混合させる領域(以下「第2反応領域」という)45が形成される。   Similarly to the first mixing / dilution unit 32, the second mixing / dilution unit 42 has an inner diameter larger than the inner diameter of the second supply path 5, and a plate member having a plurality of through-holes 44 a in the middle thereof (disturbance) Plate) 44 is provided. As a result, a flow resistance against the hypochlorite aqueous solution and dilution water that has flowed into the second mixed dilution section 42 is generated in a portion upstream of the plate member 44 of the second mixed dilution section 42, and hydrochloric acid is generated. A region (hereinafter referred to as “second reaction region”) 45 in which the aqueous solution and the dilution water are mixed is formed.

また、第2混合希釈部42は、板部材44より下流側の部分に、板部材44の貫通孔44aを通過して拡散した塩酸水溶液と希釈水をさらに均一に混合させる領域(以下「第2安定領域」という)46が形成されている。第2供給経路5に供給された希釈水と塩酸水溶液は、板部材44による流量抵抗によって第2反応領域45で所定時間混合され、板部材44の貫通孔44aを通過することによって、第2安定領域46内に拡散し、この第2安定領域46を通過することによって、均一に希釈されて所定濃度に希釈された次亜塩素酸塩水溶液となる。   The second mixing / dilution section 42 is a region where the aqueous hydrochloric acid solution and the diluting water diffused through the through hole 44a of the plate member 44 are mixed more uniformly in the downstream portion of the plate member 44 (hereinafter referred to as “second”). 46) (referred to as “stable region”). The diluting water and hydrochloric acid aqueous solution supplied to the second supply path 5 are mixed in the second reaction region 45 for a predetermined time by the flow resistance of the plate member 44 and pass through the through hole 44a of the plate member 44. By diffusing into the region 46 and passing through the second stable region 46, a hypochlorite aqueous solution that has been uniformly diluted to a predetermined concentration is obtained.

第2流量調整弁43は、第2混合希釈部42の下流側に設けられており、この第2流量調整弁43を操作することにより、第2混合希釈部42の内部圧力を調節するとともに、第2混合希釈部42によって希釈された次亜塩素酸塩水溶液、または、第2混合希釈部42に流入する前の稀釈水の流量を調節できるようになっている。   The second flow rate adjustment valve 43 is provided on the downstream side of the second mixing dilution unit 42, and by operating the second flow rate adjustment valve 43, the internal pressure of the second mixing dilution unit 42 is adjusted, The flow rate of the hypochlorite aqueous solution diluted by the second mixing / dilution unit 42 or the flow rate of the diluted water before flowing into the second mixing / dilution unit 42 can be adjusted.

第1供給経路3と第2供給経路5の間には、差圧計51が設けられている。この差圧計51は、第1供給経路3の第1注入口31よりも上流側の位置と、第2供給経路5の第2注入口41よりも上流側の位置との間に設けられており、この位置を流れる希釈水の圧力の差を測定するものである。   A differential pressure gauge 51 is provided between the first supply path 3 and the second supply path 5. The differential pressure gauge 51 is provided between a position upstream of the first inlet 31 of the first supply path 3 and a position upstream of the second inlet 41 of the second supply path 5. The pressure difference of the dilution water flowing through this position is measured.

第1供給装置4は、塩酸水溶液を貯留する第1貯留部55と、この第1貯留部55に貯留された塩酸水溶液を第1供給経路3に送る第1注入ポンプ56を備える。また、第2供給装置6は、次亜塩素酸塩水溶液を貯留する第2貯留部58と、この第2貯留部58に貯留された次亜塩素酸塩水溶液を第2供給経路5に送る第2注入ポンプ59を備える。   The first supply device 4 includes a first storage unit 55 that stores an aqueous hydrochloric acid solution, and a first injection pump 56 that sends the aqueous hydrochloric acid solution stored in the first storage unit 55 to the first supply path 3. The second supply device 6 also includes a second storage unit 58 that stores the hypochlorite aqueous solution, and a second storage unit 58 that sends the hypochlorite aqueous solution stored in the second storage unit 58 to the second supply path 5. Two infusion pumps 59 are provided.

ここで、第1及び第2貯留部55,58の構成について図3〜図6を参照して詳細に説明する。第1貯留部55は、図3及び図5に示すように、所要の薬液、即ち塩酸水溶液が貯留される第1貯留タンク550と、該第1貯留タンク550を着脱自在に受ける第1受け体560と、該第1受け体560が着脱自在に装着される共に、第1貯留タンク550の塩酸水溶液を受容する第1供給容器570とで構成されている。   Here, the structure of the 1st and 2nd storage parts 55 and 58 is demonstrated in detail with reference to FIGS. As shown in FIGS. 3 and 5, the first storage unit 55 includes a first storage tank 550 that stores a required chemical solution, that is, a hydrochloric acid aqueous solution, and a first receiver that detachably receives the first storage tank 550. 560 and a first supply container 570 for receiving the aqueous hydrochloric acid solution in the first storage tank 550 while the first receiver 560 is detachably mounted.

第1貯留タンク550は、塩酸水溶液を収容するためのタンク本体551と、該タンク本体551の底部開口から外方に延出して形成される環状の雄ねじ551aと、該雄ねじ551aに螺着する雌ねじからなる挿入部としての蓋体552と、該蓋体552の中央に形成される流出孔552aと、該流出孔552aに設けられる開閉弁553と、蓋体552の底部外面、即ち該流出孔552aの周縁部の外面に形成される環状の口部554と、蓋体552の底部内面、即ち流出孔552aの周縁部の内面に、口部554と同心状に形成された、後述する開閉弁553の環状の弁座553cと、タンク本体551の上部に、両側に跨るように設けられた取手555とを備えている。そして、蓋体(以下、挿入部という)552の外周面が開閉弁553の外側を囲むように位置し、蓋体552よりも口部554の方が外方に突出している。   The first storage tank 550 includes a tank main body 551 for containing a hydrochloric acid aqueous solution, an annular male screw 551a formed to extend outward from the bottom opening of the tank main body 551, and a female screw that is screwed to the male screw 551a. A lid body 552 as an insertion portion, an outflow hole 552a formed in the center of the lid body 552, an on-off valve 553 provided in the outflow hole 552a, and an outer surface of the bottom of the lid body 552, that is, the outflow hole 552a. An annular mouth portion 554 formed on the outer surface of the peripheral portion of the rim, and an opening / closing valve 553 described later formed concentrically with the mouth portion 554 on the inner surface of the bottom portion of the lid body 552, that is, the inner surface of the peripheral portion of the outflow hole 552a. The annular valve seat 553c and a handle 555 provided on the upper part of the tank main body 551 so as to straddle both sides are provided. Then, the outer peripheral surface of the lid (hereinafter referred to as the insertion portion) 552 is positioned so as to surround the outside of the on-off valve 553, and the mouth 554 protrudes outward from the lid 552.

開閉弁553は、流出孔552aに挿通されると共に、往復動自在に設けられる弁棒553aと、該弁棒553aの先端部側に嵌挿され、弁棒553aを出方向に付勢するバネ553bと、弁棒553aの基端部に固着され、弁座553cに接離するフッ素ゴムで構成されるパッキン553dとを有している。   The on-off valve 553 is inserted into the outflow hole 552a and reciprocally movable, and a valve rod 553a that is provided to be freely reciprocated, and a spring 553b that is fitted into the distal end side of the valve rod 553a and biases the valve rod 553a in the outward direction. And a packing 553d that is fixed to the base end portion of the valve stem 553a and is made of fluororubber that contacts and separates from the valve seat 553c.

第1受け体560は、有底筒状を呈しており、タンク本体551の外径に対応するように、内径の大きさがそれぞれ設定されている。具体的には、後述する、外径の大きいタンク本体581に合わせた内径の第2受け体590と同様の受け体560を使用しており、外径の小さいタンク本体551が挿脱される第1受け体560には、環状の調整部材561aが挿入されて、タンク本体551の外径に合わせて内径が調整されている。また、第1受け体560の上側部の側壁は、タンク本体551を受ける上側受け部561となっている。この上側受け部561の開口端部は、第1供給容器570の開口端部よりも突出しており、タンク本体551を充分に支持できる高さを有している。また、第1受け体560の側壁の下部及び底壁の周縁部に環状の下側受け部562が設けられている。この下側受け部562は、タンク本体551の挿入部552の高さよりも大きく、且つ、口部554の開口端面が底部に当接する高さになるように設定されている。即ち、タンク本体551が直立した状態で挿入支持されるように構成されている。また、底壁の中央部に、開閉弁553の弁棒553aを押し開くための柱状の突起563が直立して設けられている。この突起563は、弁棒553aの先端部を流出孔552aの近傍位置にまで押し上げて、パッキン553dの周縁部を環状の弁座553cから離脱させる高さを有している。また、突起563の周縁部に複数の連通孔564,…が放射状に形成されている。この連通孔564,…は、下側受け部562の内径よりも小さく、流出孔552a、口部554の内部空間、挿入部552と受け体560の底部との空間、第1供給容器570の下側部の空間に連通している。   The first receiver 560 has a bottomed cylindrical shape, and the size of the inner diameter is set so as to correspond to the outer diameter of the tank body 551. Specifically, a receiving body 560 similar to a second receiving body 590 having an inner diameter matched to a tank body 581 having a large outer diameter, which will be described later, is used, and a tank body 551 having a small outer diameter is inserted and removed. An annular adjusting member 561 a is inserted into the one receiving body 560, and the inner diameter is adjusted according to the outer diameter of the tank body 551. Further, the side wall of the upper portion of the first receiving body 560 serves as an upper receiving portion 561 that receives the tank body 551. The opening end portion of the upper receiving portion 561 protrudes from the opening end portion of the first supply container 570 and has a height that can sufficiently support the tank body 551. An annular lower receiving portion 562 is provided at the lower portion of the side wall of the first receiving body 560 and the peripheral portion of the bottom wall. The lower receiving portion 562 is set so as to be larger than the height of the insertion portion 552 of the tank body 551 and to have a height at which the opening end surface of the mouth portion 554 contacts the bottom portion. That is, the tank body 551 is configured to be inserted and supported in an upright state. Also, a columnar protrusion 563 for erecting the valve rod 553a of the on-off valve 553 is provided upright at the center of the bottom wall. The protrusion 563 has a height that pushes up the tip of the valve stem 553a to a position in the vicinity of the outflow hole 552a so that the peripheral edge of the packing 553d is detached from the annular valve seat 553c. In addition, a plurality of communication holes 564,... Are formed radially on the peripheral edge of the protrusion 563. The communication holes 564,... Are smaller than the inner diameter of the lower receiving portion 562, and the outflow holes 552a, the inner space of the mouth portion 554, the space between the insertion portion 552 and the bottom portion of the receiving body 560, and the lower side of the first supply container 570. It communicates with the side space.

第1供給容器570は、上側部に、第1受け体560が装着される環状の装着部571と、下側部に、側壁の下側部と底壁とで形成される空間(受容部)572とを備えている。そして、第1供給容器570の底壁は、中央部に向かうにしたがって緩やかに傾斜するテーパ面となっている。また、底部中央に形成された吐出孔573に継ぎ手574を介してポンプ56が接続され、該ポンプ56が第1供給経路3に接続されている。つまり、第1供給容器570に受容された塩酸水溶液は、第1供給経路3に吐出される。   The first supply container 570 has an annular mounting portion 571 on which the first receiving body 560 is mounted on the upper side, and a space (receiving portion) formed on the lower side by the lower side portion and the bottom wall of the side wall. 572. And the bottom wall of the 1st supply container 570 becomes a taper surface which inclines gently toward the center part. A pump 56 is connected to a discharge hole 573 formed in the center of the bottom portion via a joint 574, and the pump 56 is connected to the first supply path 3. That is, the hydrochloric acid aqueous solution received in the first supply container 570 is discharged to the first supply path 3.

第2貯留部58は、前記第1貯留部55の構成と略同様であり、異なる点のみを図4及び図6を参照して説明する。第2貯留タンク580のタンク本体581の外径が、第1貯留タンク550のタンク本体551よりも大きく、タンク本体581の挿入部としての蓋体582の外径が、第1貯留タンク550の挿入部552よりも小さくなっている。また、第2受け体590の上側受け部591に、第2タンク本体581が直接挿入され、調整部材が不要になっている。第2受け体590の下側受け部592の内径、及び連通孔594の開口面積が、第2タンク本体581の蓋体(以下、挿入部という)582の外径に合わせて小さくなっている。   The second reservoir 58 is substantially the same as the configuration of the first reservoir 55, and only different points will be described with reference to FIGS. The outer diameter of the tank main body 581 of the second storage tank 580 is larger than the tank main body 551 of the first storage tank 550, and the outer diameter of the lid 582 serving as the insertion portion of the tank main body 581 is inserted into the first storage tank 550. It is smaller than the portion 552. Further, the second tank main body 581 is directly inserted into the upper receiving portion 591 of the second receiving body 590, and an adjustment member is not necessary. The inner diameter of the lower receiving portion 592 of the second receiving body 590 and the opening area of the communication hole 594 are reduced in accordance with the outer diameter of the lid body (hereinafter referred to as the insertion portion) 582 of the second tank body 581.

ここで、同様に構成されている各部材の説明は省略するが、第2貯留部58の符号と各部名称を整理しておく。符号580は第2貯留タンク、581はタンク本体、581aは雄ねじ、582は挿入部、582aは流出孔、583は開閉弁、583aは弁棒、583bはバネ、583cは弁座、583dはパッキン、584は口部、585は取手、590は第2受け体、591は上側受け部、592は下側受け部、593は突起、594は連通孔、600は第2供給容器、601は装着部、602は受容部、603は吐出孔、604は継ぎ手である。   Here, although explanation of each member constituted similarly is omitted, the code of the 2nd storage part 58 and each part name are arranged. Reference numeral 580 is a second storage tank, 581 is a tank body, 581a is an external thread, 582 is an insertion portion, 582a is an outflow hole, 583 is an open / close valve, 583a is a valve rod, 583b is a spring, 583c is a valve seat, 583d is a packing, 584 is a mouth portion, 585 is a handle, 590 is a second receiver, 591 is an upper receiving portion, 592 is a lower receiving portion, 593 is a projection, 594 is a communication hole, 600 is a second supply container, 601 is a mounting portion, Reference numeral 602 denotes a receiving portion, 603 denotes a discharge hole, and 604 denotes a joint.

つぎに、第1及び第2貯留タンク550,580を、第1及び第2供給容器570,600に装着された第1及び第2受け体560,590に挿脱する態様について説明する。まず、各受け体560,590に各貯留タンク550,580が挿入されていない状態において、各貯留タンク550,580の取手555,585を把持して、各受け体560,590の上側受け部561,591に沿って各タンク本体551,581を挿入すると、各タンク本体551,581が直立した状態で挿入されると共に、各タンク本体551,581の挿入部552,582が受け体560,590の下側受け部592の空洞部に挿入される。この際、各タンク本体551,581が各受け体560,590に挿入された状態においては、各タンク本体551,581の上部が各受け体560,590の上面開口部よりも突出する一方、各受け体560,590の突起563,593が弁棒553a,583aをバネ553b、583bに抗して押し上げて、弁座553c,583cからパッキン553d,583dが離脱すると共に、各タンク本体551,581の口部554,584の開口端部が各受け体560,590の底部に当接する。これによって、弁座553c,583cの開口部、流出孔552a,582a、口部554,584の開口部、流出孔552a,582aが連通することになり、その結果として、各タンク本体551,581と各供給容器570,600の下側部とが連通することになる。つまり、第1タンク本体551に貯留されている塩酸水溶液と、第2タンク本体581に貯留されている次亜塩素酸塩水溶液が、第2受け容器600の下側部に受容されることになる。そして、ポンプ56,59の駆動によって、各供給容器570,600に受容された流体が第1及び第2供給経路3,5に供給される。   Next, a mode in which the first and second storage tanks 550 and 580 are inserted into and removed from the first and second receiving bodies 560 and 590 attached to the first and second supply containers 570 and 600 will be described. First, in a state where the storage tanks 550 and 580 are not inserted into the receiving bodies 560 and 590, the handles 555 and 585 of the storage tanks 550 and 580 are gripped, and the upper receiving portions 561 of the receiving bodies 560 and 590 are held. , 591, the tank main bodies 551, 581 are inserted in an upright state, and the insertion portions 552, 582 of the tank main bodies 551, 581 are inserted into the receiving bodies 560, 590. It is inserted into the hollow portion of the lower receiving portion 592. At this time, in a state where the tank main bodies 551 and 581 are inserted into the receiving bodies 560 and 590, the upper portions of the tank main bodies 551 and 581 protrude from the upper surface openings of the receiving bodies 560 and 590, respectively. The protrusions 563 and 593 of the receivers 560 and 590 push up the valve rods 553a and 583a against the springs 553b and 583b, the packings 553d and 583d are detached from the valve seats 553c and 583c, and the tank main bodies 551 and 581 The opening end portions of the mouth portions 554 and 584 are in contact with the bottom portions of the receiving bodies 560 and 590. As a result, the opening portions of the valve seats 553c and 583c, the outflow holes 552a and 582a, the opening portions of the mouth portions 554 and 584, and the outflow holes 552a and 582a communicate with each other. The lower side of each supply container 570, 600 communicates. That is, the aqueous hydrochloric acid solution stored in the first tank main body 551 and the hypochlorite aqueous solution stored in the second tank main body 581 are received in the lower side portion of the second receiving container 600. . Then, the fluids received in the supply containers 570 and 600 are supplied to the first and second supply paths 3 and 5 by driving the pumps 56 and 59.

そして、大径のタンク本体581を有する第2貯留タンク580を、第1受け体560に誤って挿入しようとしても、第1受け体560の上側受け部591の開口径が第2タンク本体581の外径よりも小さいため、挿入できない。これと同様に、小径の第1タンク本体551を有する第1貯留タンク550を、第2受け体590に挿入しようとしても、第2タンク本体581の外径と第1受け体560の上側受け部561の開口径との相違により挿入することができない。   Even if the second storage tank 580 having the large-diameter tank body 581 is erroneously inserted into the first receiving body 560, the opening diameter of the upper receiving portion 591 of the first receiving body 560 is the same as that of the second tank body 581. Cannot be inserted because it is smaller than the outer diameter. Similarly, even if the first storage tank 550 having the first tank main body 551 having a small diameter is to be inserted into the second receiver 590, the outer diameter of the second tank main body 581 and the upper receiver of the first receiver 560. It cannot be inserted due to the difference with the opening diameter of 561.

また、各受け体560,590からタンク本体551,581を引き出すと、タンク本体551,581が受け体560,590の上側受け部561,591に沿って直立した状態で引き出されると共に、突起563,593によって押し開いていた弁棒553a,583aがバネ553b、583bの弾性付勢によって進出方向に付勢されるようになり、パッキン553d,583dが弁座553c,583cに圧接して、弁座553c,583cの開口部が閉塞され、各貯留タンク550,580に貯留された塩酸水溶液及び次亜塩素酸塩水溶液の流出が阻止される。   Further, when the tank main bodies 551 and 581 are pulled out from the respective receiving bodies 560 and 590, the tank main bodies 551 and 581 are pulled out in an upright state along the upper receiving portions 561 and 591 of the receiving bodies 560 and 590, and the protrusions 563 The valve rods 553a and 583a pushed open by the spring 593 are biased in the advancing direction by the elastic biasing of the springs 553b and 583b, the packings 553d and 583d are pressed against the valve seats 553c and 583c, and the valve seat 553c , 583c are closed, and the aqueous hydrochloric acid solution and hypochlorite aqueous solution stored in the storage tanks 550 and 580 are prevented from flowing out.

こうすることで、希釈された塩酸水溶液と次亜塩素酸塩水溶液を、後述する下流側の第3供給経路7で混合して、段階的に希釈することができ、濃度の高い次亜塩素酸塩水溶液と、濃度の高い塩酸水溶液とが接触することがなくなり、弱酸性塩素水は、塩素ガスの発生を抑制できるものになる。以下、第3供給経路7について詳細に説明する。   By carrying out like this, the diluted hydrochloric acid aqueous solution and hypochlorite aqueous solution can be mixed in the downstream 3rd supply path 7 mentioned later, and can be diluted in steps, and hypochlorous acid with high concentration can be obtained. The salt aqueous solution and the hydrochloric acid aqueous solution having a high concentration are not brought into contact with each other, and the weakly acidic chlorinated water can suppress generation of chlorine gas. Hereinafter, the third supply path 7 will be described in detail.

第3供給経路7には、流量抵抗を生じさせて、第1混合希釈部32で希釈された塩酸水溶液と第2混合希釈部42で希釈された次亜塩素酸塩水溶液とを混合して希釈することにより、所定のpHの弱酸性塩素水を生成する第3混合希釈部61と、第3混合希釈部61によって生成された弱酸性塩素水の流量を調整する第3流量調整弁(例えばニードル弁)62が設けられている。   In the third supply path 7, flow resistance is generated, and the hydrochloric acid aqueous solution diluted in the first mixing / dilution unit 32 and the hypochlorite aqueous solution diluted in the second mixing / dilution unit 42 are mixed and diluted. 3rd dilution part 61 which generates weak acidic chlorine water of predetermined pH, and the 3rd flow control valve (for example, needle) which adjusts the flow volume of weak acidic chlorine water generated by the 3rd mixed dilution part 61 Valve) 62 is provided.

第3混合希釈部61は、その内径が第3供給経路7の内径よりも大きくなっており、その中途部に複数の貫通孔63aが形成された板部材63が設けられている。これにより、第3混合希釈部61の板部材63よりも上流側の部分には、第3混合希釈部61内に流入した次亜塩素酸塩水溶液と希釈水に対する流量抵抗を生じさせて、塩酸水溶液と希釈水とを混合させる領域(以下「第3反応領域」という)64が形成される。   The inner diameter of the third mixing / dilution unit 61 is larger than the inner diameter of the third supply path 7, and a plate member 63 having a plurality of through holes 63 a formed in the middle thereof. As a result, a flow resistance against the hypochlorite aqueous solution and the diluted water that has flowed into the third mixed dilution section 61 is generated in a portion upstream of the plate member 63 of the third mixed dilution section 61, and hydrochloric acid is generated. A region (hereinafter referred to as “third reaction region”) 64 in which the aqueous solution and the dilution water are mixed is formed.

また、第3混合希釈部61は、板部材63より下流側の部分に、板部材63の貫通孔63aを通過して拡散した塩酸水溶液と希釈水をさらに均一に希釈させる領域(以下「第3安定領域」という)65が形成されている。所定濃度に希釈されて第3供給経路7に供給された塩酸水溶液と次亜塩素酸塩水溶液は、板部材63による流量抵抗によって第3反応領域64で所定時間混合され、板部材63の貫通孔63aを通過することによって、第3安定領域65内に拡散し、この第3安定領域65を通過することによって、均一に希釈されて所定のpHに調整された弱酸性塩素水となる。   The third mixing / dilution unit 61 further uniformly dilutes the aqueous hydrochloric acid solution and the diluting water diffused through the through hole 63a of the plate member 63 in the downstream portion of the plate member 63 (hereinafter referred to as “third”). 65) (referred to as “stable region”). The hydrochloric acid aqueous solution and the hypochlorite aqueous solution diluted to a predetermined concentration and supplied to the third supply path 7 are mixed in the third reaction region 64 for a predetermined time by the flow resistance of the plate member 63, and the through holes of the plate member 63 are mixed. By passing through 63a, it diffuses into the third stable region 65, and by passing through the third stable region 65, it becomes weakly acidic chlorinated water that is uniformly diluted and adjusted to a predetermined pH.

第3流量調整弁62は、第3混合希釈部61の下流側に設けられており、この第3流量調整弁62を操作することにより、第3混合希釈部61の圧力を調整するとともに、第3混合希釈部61で生成された弱酸性塩素水の流量を調整できるようになっている。   The third flow rate adjustment valve 62 is provided on the downstream side of the third mixing / dilution unit 61. By operating the third flow rate adjustment valve 62, the pressure of the third mixing / dilution unit 61 is adjusted, It is possible to adjust the flow rate of the weakly acidic chlorinated water generated by the three-mixing / dilution unit 61.

なお、第1混合希釈部32、第2混合希釈部42、第3混合希釈部61の内部圧力は、第1流量調整弁(圧力調整弁)33、第2流量調整弁(圧力調整弁)43、第3流量調整弁(圧力調整弁)62を操作することにより、いずれも0.2Mpa以上に保たれている。   The internal pressures of the first mixing dilution unit 32, the second mixing dilution unit 42, and the third mixing dilution unit 61 are the first flow rate adjustment valve (pressure adjustment valve) 33 and the second flow rate adjustment valve (pressure adjustment valve) 43. By operating the third flow rate regulating valve (pressure regulating valve) 62, both are maintained at 0.2 Mpa or more.

制御装置8は、第1供給装置4の第1注入ポンプ56を制御するコントローラ(以下「第1コントローラ」という)71と、第2供給装置6の第2注入ポンプ59を制御するコントローラ(以下「第2コントローラ」という)72、主供給経路2の流量計23のデータを取り込んで、その値を第2コントローラ72に送信する流量指示計73と、第3供給経路7から供給される弱酸性塩素水の温度を表示する温度指示計74、弱酸性塩素水のpHを表示するpH指示調節計75、弱酸性塩素水の塩素濃度を表示する塩素濃度指示計76、記録計77等を備えている。   The control device 8 includes a controller (hereinafter referred to as “first controller”) 71 that controls the first infusion pump 56 of the first supply device 4 and a controller (hereinafter referred to as “the first controller” hereinafter) that controls the second infusion pump 59 of the second supply device 6. 72, a flow indicator 73 that takes in data of the flow meter 23 of the main supply path 2 and transmits the value to the second controller 72, and weakly acidic chlorine supplied from the third supply path 7 A temperature indicator 74 that displays the temperature of water, a pH indicator controller 75 that displays the pH of weakly acidic chlorine water, a chlorine concentration indicator 76 that displays the chlorine concentration of weakly acidic chlorine water, a recorder 77, and the like are provided. .

制御装置8は、予め設定された所定のpHの弱酸性塩素水を製造すべく、第1供給装置4と第2供給装置6を制御する。すなわち、制御装置8は、流量比例制御によって第1供給経路3に供給すべき塩酸水溶液、および第2供給経路5に供給すべき次亜塩素酸塩水溶液の量を決定する。具体的には、制御装置8は、流量計23で測定された希釈水の流量データを流量指示計73で読み取り、第2コントローラ72は、流量指示計73から送られた流量データを基に、この流量データに比例した、第1供給経路3に供給されるべき次亜塩素酸塩水溶液の量を決定する。そして、第2コントローラ72から第2供給装置6の第2注入ポンプ59を作動させて決定された量の次亜塩素酸塩水溶液を第2供給経路5に送る。   The control device 8 controls the first supply device 4 and the second supply device 6 to produce weakly acidic chlorinated water having a predetermined pH set in advance. That is, the control device 8 determines the amount of the aqueous hydrochloric acid solution to be supplied to the first supply path 3 and the amount of the hypochlorite aqueous solution to be supplied to the second supply path 5 by flow rate proportional control. Specifically, the control device 8 reads the flow rate data of the dilution water measured by the flow meter 23 with the flow rate indicator 73, and the second controller 72 is based on the flow rate data sent from the flow rate indicator 73. The amount of hypochlorite aqueous solution to be supplied to the first supply path 3 in proportion to the flow rate data is determined. Then, the second controller 72 operates the second injection pump 59 of the second supply device 6 to send the determined amount of hypochlorite aqueous solution to the second supply path 5.

そして、第1コントローラ71は、第2コントローラ72で決定された次亜塩素酸塩水溶液の量に応じて第1供給経路3に供給されるべき塩酸水溶液の量を決定する。なお、この塩酸水溶液の量は、次亜塩素酸塩水溶液の量に比例するものである。さらに、第1コントローラ71は、第1供給装置4の第1注入ポンプ56を作動させて決定された量の塩酸水溶液を第2供給経路5に送る。以上により、第2供給装置6は、流量計23で測定された希釈水の流量に応じた量の次亜塩素酸塩水溶液を供給するように制御され、第1供給装置4は、第2供給装置6から供給される次亜塩素酸塩水溶液の量に応じた量の塩酸水溶液を供給するように制御される。   Then, the first controller 71 determines the amount of the hydrochloric acid aqueous solution to be supplied to the first supply path 3 according to the amount of the hypochlorite aqueous solution determined by the second controller 72. The amount of the hydrochloric acid aqueous solution is proportional to the amount of the hypochlorite aqueous solution. Furthermore, the first controller 71 operates the first injection pump 56 of the first supply device 4 to send the determined amount of aqueous hydrochloric acid solution to the second supply path 5. As described above, the second supply device 6 is controlled to supply a hypochlorite aqueous solution in an amount corresponding to the flow rate of the dilution water measured by the flow meter 23, and the first supply device 4 Control is performed to supply an aqueous hydrochloric acid solution in an amount corresponding to the amount of the hypochlorite aqueous solution supplied from the device 6.

第3供給経路7の第3混合希釈部61の下流側には、温度センサ80、pHセンサ81、塩素濃度センサ82が設けられており、制御装置8の温度指示計74は、温度センサ80によって測定された温度データを指示し、pH指示調節計75は、pHセンサ81によって測定された弱酸性塩素水のpH値を指示し、塩素濃度指示計76は、塩素濃度センサ82によって測定された弱酸性塩素水の塩素濃度を指示するようになっている。記録計77は、温度指示計74、pH指示調節計75、塩素濃度指示計76で指示された値を記録するようになっている。   A temperature sensor 80, a pH sensor 81, and a chlorine concentration sensor 82 are provided on the downstream side of the third mixing and dilution unit 61 in the third supply path 7, and the temperature indicator 74 of the control device 8 is controlled by the temperature sensor 80. The measured temperature data is indicated, the pH indicating controller 75 indicates the pH value of the weakly acidic chlorinated water measured by the pH sensor 81, and the chlorine concentration indicator 76 is the weakly measured by the chlorine concentration sensor 82. The chlorine concentration of acidic chlorine water is indicated. The recorder 77 records values indicated by the temperature indicator 74, the pH indicator controller 75, and the chlorine concentration indicator 76.

以下、弱酸性塩素水製造装置1を使用して弱酸性塩素水を製造する方法を説明する。   Hereinafter, a method for producing weakly acidic chlorine water using the weakly acidic chlorine water production apparatus 1 will be described.

弱酸性塩素水製造装置1は、送水ポンプ21を作動させることにより、希釈水を主供給経路2から第1供給経路3、第2供給経路5へと送水する。主供給経路2を流れる希釈水は第1供給経路3と第2供給経路5とに分流(分岐)され、それぞれの供給経路を流れる。   The weakly acidic chlorinated water manufacturing apparatus 1 supplies dilution water from the main supply path 2 to the first supply path 3 and the second supply path 5 by operating the water supply pump 21. The dilution water flowing through the main supply path 2 is branched (branched) into the first supply path 3 and the second supply path 5 and flows through the respective supply paths.

第2供給装置6は、制御装置8に制御されて、必要な次亜塩素酸塩水溶液を、第2注入口41を介して第2供給経路5に供給する。第1供給装置4は、制御装置8に制御されて、第2供給装置6から供給される次亜塩素酸塩水溶液の量に応じた塩酸水溶液を、第1注入口31を介して第1供給経路3に供給する。   The second supply device 6 is controlled by the control device 8 to supply a necessary hypochlorite aqueous solution to the second supply path 5 via the second inlet 41. The first supply device 4 is controlled by the control device 8 to supply a first aqueous solution of hydrochloric acid corresponding to the amount of hypochlorite aqueous solution supplied from the second supply device 6 through the first inlet 31. Supply to path 3.

第1供給経路3に供給された塩酸水溶液は希釈水とともに第1混合希釈部32に流入する。そして、第1混合希釈部32で塩酸水溶液と希釈水とが混合され、均一に希釈化された所定濃度の塩酸水溶液が生成される。第2供給経路5に供給された次亜塩素酸塩水溶液は、希釈水とともに第2混合希釈部42に流入する。そして第2混合希釈部42で次亜塩素酸塩水溶液と希釈水が混合され、均一に希釈化された所定濃度の次亜塩素酸塩水溶液が生成される。   The aqueous hydrochloric acid solution supplied to the first supply path 3 flows into the first mixing / dilution unit 32 together with the dilution water. Then, the hydrochloric acid aqueous solution and the dilution water are mixed in the first mixing / dilution unit 32 to generate a hydrochloric acid aqueous solution having a predetermined concentration that is uniformly diluted. The hypochlorite aqueous solution supplied to the second supply path 5 flows into the second mixing dilution section 42 together with the dilution water. Then, the hypochlorite aqueous solution and the diluting water are mixed in the second mixing / dilution unit 42 to produce a hypochlorite aqueous solution having a predetermined concentration that is uniformly diluted.

第1供給経路3で希釈された塩酸水溶液と、第2供給経路5で希釈された次亜塩素酸塩水溶液は、第3供給経路7で合流するとともに第3混合希釈部61に流入する。次亜塩素酸塩水溶液と塩酸水溶液は、第3混合希釈部61で均一に混合して希釈化され、所定のpHの弱酸性塩素水となる。この弱酸性塩素水は、第3供給経路7から、例えば食品等の洗浄槽等の供給対象に供給される。   The aqueous hydrochloric acid solution diluted in the first supply path 3 and the hypochlorite aqueous solution diluted in the second supply path 5 merge in the third supply path 7 and flow into the third mixing and dilution unit 61. The hypochlorite aqueous solution and the hydrochloric acid aqueous solution are uniformly mixed and diluted by the third mixing and dilution unit 61 to become weakly acidic chlorinated water having a predetermined pH. The weakly acidic chlorinated water is supplied from the third supply path 7 to a supply target such as a washing tank for food, for example.

上記構成の弱酸性塩素水製造装置1によれば、第1供給経路3の第1混合希釈部32によって塩酸水溶液と希釈水を混合して均一に希釈するとともに、第2供給経路5の第2混合希釈部42によって次亜塩素酸塩水溶液と希釈水を混合して均一に希釈して、希釈された塩酸水溶液と次亜塩素酸塩水溶液を第3供給経路7の第3混合希釈部61で混合して希釈することによって、塩酸水溶液と次亜塩素酸塩水溶液は段階的に希釈され、均一でムラのない弱酸性塩素水として生成される。これにより、弱酸性塩素水は、局部的に濃度の高い次亜塩素酸塩水溶液と濃度の高い塩酸水溶液とが接触することがなく、したがって、塩素ガスの発生を抑制できるものになる。   According to the weakly acidic chlorinated water production apparatus 1 having the above configuration, the hydrochloric acid aqueous solution and the dilution water are mixed and uniformly diluted by the first mixing and dilution unit 32 of the first supply path 3, and the second supply path 5 The hypochlorite aqueous solution and the diluting water are mixed and uniformly diluted by the mixing and diluting unit 42, and the diluted hydrochloric acid aqueous solution and the hypochlorite aqueous solution are mixed by the third mixing and diluting unit 61 of the third supply path 7. By mixing and diluting, the hydrochloric acid aqueous solution and the hypochlorite aqueous solution are diluted stepwise, and are produced as weakly acidic chloric water that is uniform and free from unevenness. As a result, the weakly acidic chlorinated water does not contact the locally concentrated hypochlorite aqueous solution and the highly concentrated hydrochloric acid aqueous solution, and therefore can suppress generation of chlorine gas.

また、第1注入口31、第2注入口41よりも上流側で第1供給経路3と第2供給経路5の間に差圧計51を設けることによって、第1供給経路3と第2供給経路5の圧力差が生じた場合に、第1供給経路3の第1流量調整弁33又は第2供給経路5の第2流量調整弁43を操作することによって、圧力差をなくすことで、第1供給経路3と第2供給経路5を流れる希釈水の流量を均等にできる。   Further, by providing a differential pressure gauge 51 between the first supply path 3 and the second supply path 5 upstream of the first inlet 31 and the second inlet 41, the first supply path 3 and the second supply path. When the pressure difference of 5 occurs, the first flow rate adjustment valve 33 of the first supply path 3 or the second flow rate adjustment valve 43 of the second supply path 5 is operated to eliminate the pressure difference, thereby The flow rate of the dilution water flowing through the supply path 3 and the second supply path 5 can be made equal.

また、第1混合希釈部32の中途部に板部材(邪魔板)34を設けることによって、この板部材34の上流側の第1反応領域35に流量抵抗(圧力抵抗)を生じさせ、第1反応領域35に流入した塩酸水溶液と希釈水とを一定時間混合させ、さらに、これらを板部材34の貫通孔34aを通過させて第1安定領域36に拡散させることによって、塩酸水溶液は、ムラなく均一に希釈されることになる。   Further, by providing a plate member (baffle plate) 34 in the middle of the first mixing / dilution unit 32, a flow resistance (pressure resistance) is generated in the first reaction region 35 on the upstream side of the plate member 34. By mixing the aqueous hydrochloric acid solution and the diluting water that have flowed into the reaction region 35 for a certain period of time, and passing these through the through holes 34a of the plate member 34 and diffusing into the first stable region 36, the aqueous hydrochloric acid solution is evenly distributed. It will be diluted uniformly.

同様に、第2混合希釈部42の中途部に板部材(邪魔板)44を設けることによって、この板部材44の上流側の第2反応領域45に流量抵抗(圧力抵抗)を生じさせ、第2反応領域45に流入した次亜塩素酸塩水溶液と希釈水とを一定時間混合させ、さらに、これらを板部材44の貫通孔44aを通過させて第2安定領域46に拡散させることによって、次亜塩素酸塩水溶液は、ムラなく均一に希釈されることになる。   Similarly, by providing a plate member (baffle plate) 44 in the middle of the second mixing / dilution unit 42, a flow resistance (pressure resistance) is generated in the second reaction region 45 on the upstream side of the plate member 44. 2 The hypochlorite aqueous solution and the dilution water that have flowed into the reaction region 45 are mixed for a certain period of time, and further, these are passed through the through-hole 44a of the plate member 44 and diffused into the second stable region 46, so that The aqueous chlorite solution is diluted uniformly without unevenness.

同様に、第3混合希釈部61の中途部に板部材(邪魔板)63を設けることによって、この板部材63の上流側の第3反応領域64に流量抵抗を生じさせ、第3反応領域64に流入した塩酸水溶液と次亜塩素酸塩水溶液とを一定時間混合させ、さらに、これらを板部材63の貫通孔63aを通過させて第3安定領域65に拡散させることによって、塩酸水溶液と次亜塩素酸塩水溶液はムラなく均一に混合・希釈され、塩素ガスの発生しにくい弱酸性塩素水が生成される。   Similarly, by providing a plate member (baffle plate) 63 in the middle of the third mixing / dilution unit 61, a flow resistance is generated in the third reaction region 64 on the upstream side of the plate member 63, and the third reaction region 64. The aqueous hydrochloric acid solution and the hypochlorite aqueous solution that flowed into the plate member are mixed for a certain period of time, and further, these are passed through the through holes 63a of the plate member 63 and diffused into the third stable region 65, whereby the aqueous hydrochloric acid solution and the hypochlorous acid solution are mixed. The aqueous chlorate solution is evenly mixed and diluted evenly, producing weakly acidic chlorinated water that hardly generates chlorine gas.

また、主供給経路2に流量計23を設け、制御装置8によって、流量計23で測定された希釈水の量に応じた(比例した)量の次亜塩素酸塩水溶液を供給するように第2供給装置6を制御するとともに、第2供給装置6から供給される次亜塩素酸塩水溶液の量に応じた(比例した)量の塩酸水溶液を供給するように第1供給装置4を制御することにより、所定の濃度でかつ所定のpHの弱酸性塩素水を確実に生成できる。   Further, a flow meter 23 is provided in the main supply path 2, and the controller 8 supplies a hypochlorite aqueous solution in an amount (proportional) corresponding to the amount of dilution water measured by the flow meter 23. 2 controls the supply device 6 and controls the first supply device 4 so as to supply an aqueous hydrochloric acid solution in an amount proportional to the amount of the hypochlorite aqueous solution supplied from the second supply device 6. Thus, weakly acidic chlorine water having a predetermined concentration and a predetermined pH can be reliably generated.

なお、本発明は上記の実施形態に限らず、種々の変更・変形が可能である。例えば、前記実施形態の場合、タンク本体551,581の形状については特に限定していないが、タンク本体5510の形状を、断面が非円形(図7(a),(b)参照)または円形とし、タンク本体5810の形状を、断面が円形(図8(a),(b)参照)または非円形とするようにしてもよい。要は、タンク本体551,581の外形、即ち大きさ及び形状の少なくとも一方が異なるようにすればよい。但し、図7及び図8において、開閉弁5530,5830の構成は図3及び図4と同一である。また、挿入部552,582の形状を、断面が非円形または円形とするようにしてもよい。この場合も、タンク本体551,581と同様に、外形、即ち大きさ及び形状の少なくとも一方が異なるようにすればよい。また、タンク本体551,581及び挿入部552,582の外面に、凹凸嵌合させるための凹部又は凸部を形成し、その数によって、第1及び第2貯留タンク550,580の取り違えを防止するようにしてもよい。   In addition, this invention is not restricted to said embodiment, A various change and deformation | transformation are possible. For example, in the case of the above embodiment, the shape of the tank main body 551, 581 is not particularly limited, but the shape of the tank main body 5510 is a non-circular cross section (see FIGS. 7A and 7B) or a circular shape. The cross section of the tank body 5810 may be circular (see FIGS. 8A and 8B) or non-circular. In short, the tank bodies 551 and 581 may have different outer shapes, that is, at least one of size and shape. However, in FIGS. 7 and 8, the configuration of the on-off valves 5530 and 5830 is the same as in FIGS. 3 and 4. The shape of the insertion portions 552 and 582 may be non-circular or circular in cross section. Also in this case, similar to the tank main bodies 551 and 581, the outer shape, that is, at least one of the size and the shape may be different. In addition, concave portions or convex portions for fitting the concave and convex portions are formed on the outer surfaces of the tank main bodies 551 and 581 and the insertion portions 552 and 582, and the number of the concave portions or convex portions is prevented depending on the number of the concave portions or convex portions. You may do it.

また、前記実施形態の場合、挿入部552,582と流出孔552a,582aとの位置をタンク本体551,581の底部中央に配置するようにしたが、挿入部552,582を両側に、流出孔552a,582aを中央にそれぞれ異なる位置に配置するようにしてもよい。   In the case of the above embodiment, the positions of the insertion portions 552 and 582 and the outflow holes 552a and 582a are arranged at the center of the bottom of the tank main bodies 551 and 581. 552a and 582a may be arranged at different positions in the center.

また、前記実施形態の場合、2流体混合装置を例にとって説明したが、それぞれの流体を個別に供給する装置にも適用できることは言うまでもない。   In the above embodiment, the two-fluid mixing device has been described as an example, but it goes without saying that the present invention can also be applied to a device that supplies each fluid individually.

また、前記実施形態の場合、第1受け体560の上側受け部561に調整部材561aを設けるようにしたが、第1貯留タンク550のタンク本体551の外径に対応した受け体を使用するようにしてもよい。つまり、第1及び第2受け体560,590を個別に作製するようにしてもよい。   In the embodiment, the adjustment member 561a is provided in the upper receiving portion 561 of the first receiving body 560. However, a receiving body corresponding to the outer diameter of the tank main body 551 of the first storage tank 550 is used. It may be. That is, you may make it produce the 1st and 2nd receiving bodies 560 and 590 separately.

1…弱酸性塩素水製造装置、2…主供給経路、3…第1供給経路、4…第1供給装置、5…第2供給経路、6…第2供給装置、7…第3供給経路、8…制御装置、31…第1注入口、32…第1混合希釈部、33…第1流量調整弁、34…板部材、34a…貫通孔、41…第2注入口、42…第2混合希釈部、43…第2流量調整弁、44…板部材、55,58…第1及び第2貯留部、56,59…注入ポンプ、550,580、5500,5800…第1及び第2貯留タンク、551,581、5510,5810…タンク本体、551a,581a…雄ねじ、552,582、5520,5820…蓋体(挿入部)、552a,582a、5520a,5820a…流出孔、553,583、5530,5830…開閉弁、553a,583a、5530a,5830a…弁棒、553b,583b、5530b,5830b…バネ、553c,583c、5530c,5830c…弁座、553d,583d、5530d,5830d…パッキン、554,584、5540,5840…口部、555,585、5550,5850…取手、560,590…第1及び第2受け体、561,591…上側受け部、561a…調整部材、562,592…下側受け部、563,593…突起、564,594…連通孔、570,600…第1及び第2供給容器、571,601…装着部、572,602…受容部、573,603…吐出孔、574,604…継ぎ手、61…第3混合希釈部。   DESCRIPTION OF SYMBOLS 1 ... Weakly acidic chlorine water manufacturing apparatus, 2 ... Main supply path, 3 ... 1st supply path, 4 ... 1st supply apparatus, 5 ... 2nd supply path, 6 ... 2nd supply apparatus, 7 ... 3rd supply path, DESCRIPTION OF SYMBOLS 8 ... Control apparatus, 31 ... 1st inlet, 32 ... 1st mixing dilution part, 33 ... 1st flow control valve, 34 ... Plate member, 34a ... Through-hole, 41 ... 2nd inlet, 42 ... 2nd mixing Dilution part 43 ... 2nd flow regulating valve 44 ... Plate member 55, 58 ... 1st and 2nd storage part 56, 59 ... Infusion pump 550, 580, 5500, 5800 ... 1st and 2nd storage tank 551, 581, 5510, 5810 ... tank body, 551a, 581a ... male screw, 552, 582, 5520, 5820 ... lid (insertion part), 552a, 582a, 5520a, 5820a ... outflow hole, 553, 583, 5530, 5830 ... Open / close valve, 553a, 5 3a, 5530a, 5830a ... valve rod, 553b, 583b, 5530b, 5830b ... spring, 553c, 583c, 5530c, 5830c ... valve seat, 553d, 583d, 5530d, 5830d ... packing, 554, 584, 5540, 5840 ... mouth , 555, 585, 5550, 5850 ... handle, 560, 590 ... first and second receivers, 561, 591 ... upper receiving portion, 561a ... adjusting member, 562, 592 ... lower receiving portion, 563, 593 ... projection , 564, 594 ... communication hole, 570, 600 ... first and second supply containers, 571, 601 ... mounting portion, 572, 602 ... receiving portion, 573, 603 ... discharge hole, 574, 604 ... joint, 61 ... first 3 mixed dilution sections.

Claims (1)

断面が円形状のタンク本体(551,581)、該タンク本体(551,581)の底部の流出孔(552a,582a)に設けられる開閉弁(553,583)、及び、該開閉弁(553,583)を囲むように、タンク本体(551,581)の底部に形成される挿入部(552,582)を有し、二種類の流体が個別に貯留される第1及び第2貯留タンク(550,580)と、
タンク本体(551,581)が挿脱される上側受け部(561,591)、挿入部(552,582)が挿脱される下側受け部(562,592)、及び、開閉弁(553,583)を押し開けるように、下側受け部(562,592)内に設けられる突起(563,593)を有する第1及び第2受け体(560,590)と、
該各受け体(560,590)に取り付けられた貯留タンク(550,580)の流体を流出孔(552a,582a)を通って下流側に流通させるための第1及び第2供給経路(3,5)とを備えた流体供給装置であって、
前記第1貯留タンク(550)のタンク本体(551)の断面は、第2貯留タンク(580)のタンク本体(581)の断面よりも小径で、第1貯留タンク(550)の挿入部(552)の断面は、第2貯留タンク(580)の挿入部(582)の断面よりも大きく、
前記各受け体(560,590)は、各貯留タンク(550,580)のタンク本体(551,581)及び挿入部(552,582)の外形に対応する上側受け部(561,591)及び下側受け部(562,592)を有し、
外径の小さい前記タンク本体(551)が挿脱される前記第1受け体(560)の前記上側受け部(561)の内径は、外径の小さい前記タンク本体(551)の外径よりも大きく、且つ外径の大きい前記タンク本体(581)が挿脱される前記第2受け体(590)の前記上側受け部(591)の内径と同一であって、
前記第1受け体(560)は、該第1受け体(560)に挿入された調整部材(561a)により、前記外径の小さいタンク本体(551)の外径に合わせて内径が調整されていることを特徴とする流体供給装置。
A tank body (551, 581) having a circular cross section, an on-off valve (553, 583) provided in an outflow hole (552a, 582a) at the bottom of the tank body (551, 581), and the on-off valve (553, 553) 583), the first and second storage tanks (550) have an insertion portion (552, 582) formed at the bottom of the tank body (551, 581) and store two kinds of fluids separately. , 580),
An upper receiving part (561, 591) through which the tank body (551, 581) is inserted and removed, a lower receiving part (562, 592) through which the insertion part (552, 582) is inserted, and an on-off valve (553, 553) 583) first and second receivers (560, 590) having protrusions (563, 593) provided in the lower receiving parts (562, 592) to push open,
First and second supply paths (3, 3) for circulating fluid in storage tanks (550, 580) attached to the respective receivers (560, 590) through the outflow holes (552a, 582a) to the downstream side. 5) a fluid supply device comprising:
The cross section of the tank main body (551) of the first storage tank (550) is smaller in diameter than the cross section of the tank main body (581) of the second storage tank (580), and the insertion portion (552) of the first storage tank (550). ) Is larger than the cross section of the insertion portion (582) of the second storage tank (580),
Each of the receivers (560, 590) includes an upper receiver (561, 591) and a lower part corresponding to the outer shape of the tank body (551, 581) and the insertion part (552, 582) of each storage tank (550, 580). Side receiving part (562, 592),
An inner diameter of the upper receiving portion (561) of the first receiving body (560) through which the tank body (551) having a small outer diameter is inserted and removed is larger than an outer diameter of the tank body (551) having a small outer diameter. large and I the upper receiving portion inner diameter and the same der of (591) of the second receiving member large the tank body of an outer diameter (581) is inserted and removed (590),
The inner diameter of the first receiver (560) is adjusted by the adjusting member (561a) inserted into the first receiver (560) in accordance with the outer diameter of the tank body (551) having the smaller outer diameter. A fluid supply device.
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