JP5405257B2 - Manufacturing method for processed meat products - Google Patents

Manufacturing method for processed meat products Download PDF

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JP5405257B2
JP5405257B2 JP2009229505A JP2009229505A JP5405257B2 JP 5405257 B2 JP5405257 B2 JP 5405257B2 JP 2009229505 A JP2009229505 A JP 2009229505A JP 2009229505 A JP2009229505 A JP 2009229505A JP 5405257 B2 JP5405257 B2 JP 5405257B2
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processed meat
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裕司 林
延吉 持原
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Asahi Kasei Chemicals Corp
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Description

本発明は油で揚げる食肉加工製品の油の染み出しを防止し、歩留まり及び食感を向上させる方法に関する。   The present invention relates to a method for preventing oil from exuding a processed meat product fried in oil and improving yield and texture.

食肉を加工処理して、例えばハンバーグのような食肉加工製品とする場合、加熱による肉の収縮や肉汁のドリップにより歩留まりが悪くなる上に、エキス成分が抜け出てしまうため味が落ちてしまう。従来、これらの問題点を解決するために、天然ガム類の添加、リン酸塩の添加や、pH調整剤、大豆蛋白の添加などの方法を、単独もしくは複数を組み合わせて用いられてきた。   When processing meat into a processed meat product such as a hamburger, for example, the yield deteriorates due to the shrinkage of the meat due to heating or the drip of the gravy, and the extract component escapes, resulting in a loss of taste. Conventionally, in order to solve these problems, methods such as addition of natural gums, addition of phosphate, pH adjuster, and soy protein have been used singly or in combination.

例えば、特許文献1、2ではカラギーナンやカードランを含有するピックル液を食肉に注射し、離水防止、結着性向上などができると開示している。特許文献3では有機酸塩を用いた歩留まり向上方法について、特許文献4には寒天を用いた方法が開示されている。また、特許文献5には、平均粒径が10μm〜20μmの粒子成分の含量が70%以下である微細セルロースと半精製カラギーナンとを用いる方法が開示されている。ただし、ここで示している平均粒径は、非常に強い攪拌力で分散した場合の平均粒径である。この方法では、セルロースの吸水性および吸油性を利用して肉汁のドリップを抑制している。   For example, Patent Documents 1 and 2 disclose that a pickle solution containing carrageenan or curdlan can be injected into meat to prevent water separation and improve binding properties. Patent Document 3 discloses a yield improvement method using an organic acid salt, and Patent Document 4 discloses a method using agar. Patent Document 5 discloses a method using fine cellulose and a semi-purified carrageenan whose content of particle components having an average particle diameter of 10 μm to 20 μm is 70% or less. However, the average particle diameter shown here is an average particle diameter when dispersed with a very strong stirring force. In this method, drip of the gravy is suppressed by utilizing the water absorbency and oil absorbency of cellulose.

一方、チキンナゲットやミンチカツ、さつま揚げなど、油で揚げる食肉加工製品の歩留まりを向上する方法はほとんど知られていない。   On the other hand, there are few known methods for improving the yield of processed meat products fried in oil, such as chicken nuggets, minced pork cutlet, and fried fish.

特開平5−260927号公報Japanese Patent Laid-Open No. 5-260927 特開平4−40849号公報JP-A-4-40849 特開平6−343423号公報JP-A-6-343423 特開平6−292538号公報JP-A-6-292538 特開平11−46723号公報Japanese Patent Laid-Open No. 11-46723

これまでの技術で、食肉加工製品の縮みの防止、歩留まりを向上する方法は上述のとおりいくつか開示されている。しかし、特許文献1および特許文献2に記載されている天然ガム類は粘性が高いために食感が重くなりやすく、不自然な食感になってしまうという問題があった。特許文献3に記載されている有機酸塩やpH調整剤は、食肉のpHを変化させるため風味の違いを生じ、やはり不自然な食感になってしまうという問題があった。前記特許文献3では有機酸塩とセルロース類との併用が開示されている。しかし、有機酸塩が必須成分であるため、前記の問題点は解決されない。また、本願発明のように特定の粒径や形状をもつセルロースを用いると有機酸塩を用いなくても効果が得られることを見出すまでには至っていなかった。また、最も一般的に行われているリン酸塩の添加は、食感をカマボコ様に変化させてしまうことに加え、過剰なリン酸塩の摂取は体からのカルシウムの流出を促進するとも言われており、健康上もあまり好ましいものではなかった。また、リン酸塩と同様に一般的に行われている大豆蛋白を用いた場合は、効果を発揮する添加量とすると、独特の大豆臭が発生する場合があり、食感もパサツキ感が出てくるという問題があった。前述の特許文献4に記載されている寒天を用いた方法は、pHは食肉本来からの変化が少なく、寒天自体の風味もほとんどないため、縮みの防止、歩留まりや食感の向上に優れた方法である。しかし、該方法には、高温で加熱処理した場合に、歩留まり向上効果が出にくいという欠点があった。さらに、これらのいずれの方法でも油で揚げる製造工程を持つような食品加工製品では効果は不十分であった。   As described above, several methods for preventing shrinkage of meat processed products and improving the yield with the conventional techniques have been disclosed. However, the natural gums described in Patent Document 1 and Patent Document 2 have a problem that the texture tends to be heavy because the viscosity is high, resulting in an unnatural texture. The organic acid salt and the pH adjuster described in Patent Document 3 have a problem in that they cause a difference in flavor because the pH of the meat is changed, resulting in an unnatural texture. Patent Document 3 discloses the combined use of an organic acid salt and celluloses. However, since the organic acid salt is an essential component, the above-mentioned problems cannot be solved. Further, it has not yet been found that the effect can be obtained without using an organic acid salt when cellulose having a specific particle size or shape is used as in the present invention. It is also said that the most common addition of phosphate changes the texture to a squirrel-like texture, and that excessive phosphate intake promotes calcium efflux from the body. It was not good for health. In addition, when using soy protein, which is generally used in the same way as phosphates, a unique soy odor may be generated if the added amount is effective, and the texture is also crisp. There was a problem of coming. The method using agar described in Patent Document 4 described above is a method that is excellent in preventing shrinkage and improving yield and texture because the pH has little change from the original meat and there is almost no flavor of the agar itself. It is. However, this method has a drawback in that it is difficult to increase the yield when heat-treated at a high temperature. Furthermore, in any of these methods, the effect is insufficient for a food processing product having a production process that is fried in oil.

前述の特許文献5に開示されている微細セルロースと精製カラギーナンを用いる方法では、微細セルロースの平均粒径を20μm以下、好ましくは12μm以下と規定しており、実施例では微細セルロースの平均粒径は8〜11μmのものを用いている。しかし、該明細書の[0020]に記載されている平均粒径の測定方法から明らかなように、この平均粒径は、実際の食肉加工製品の製造工程では使用されない強力な攪拌力で分散をして測定されたものである。特許文献5の微細セルロースを、実際の製造工程における攪拌力で分散し平均粒径を測定した場合、粒径は20μm程度となる。このように、特許文献5では、実際の平均粒径が20μm程度でも歩留まりの向上機能を発揮しているといえるが、その対象は焼成する食肉加工品(ハンバーグ)などであり、油で揚げる食肉加工製品では効果が発揮できなかった。本発明は、現実的な製造設備を用い、加熱処理として油で揚げる工程を含む食肉加工製品の食感を損なわずに歩留まりを向上し、油の染み出しを防止できる方法を提供することを目的とする。   In the method using fine cellulose and purified carrageenan disclosed in Patent Document 5 described above, the average particle size of fine cellulose is defined as 20 μm or less, preferably 12 μm or less. In the examples, the average particle size of fine cellulose is The thing of 8-11 micrometers is used. However, as is apparent from the method for measuring the average particle size described in [0020] of the specification, this average particle size is dispersed with a strong stirring force that is not used in the actual manufacturing process of processed meat products. Measured. When the fine cellulose of Patent Document 5 is dispersed with stirring force in an actual production process and the average particle size is measured, the particle size is about 20 μm. Thus, in Patent Document 5, it can be said that the function of improving the yield is exhibited even when the actual average particle size is about 20 μm, but the target is a processed meat product (hamburger) to be baked and the meat fried in oil The processed product could not be effective. An object of the present invention is to provide a method capable of improving yield and preventing oil seepage without impairing the texture of processed meat products including a step of frying in oil as a heat treatment using a realistic manufacturing facility. And

本発明者らは、前記課題を解決するために鋭意検討した結果、弱い攪拌力で分散した時でも特定の粒径以下となる結晶セルロースを用いることにより、油で揚げる工程を含む食肉加工製品で、油の染み出しを抑制し、歩留まりを向上させられることを見出し、本発明を成すに至った。すなわち本発明は下記の通りである。
(1)食肉100質量部に対して、平均粒径が10μm以下の結晶セルロースを0.01〜10質量部混合し、油で揚げることを特徴とする食肉加工製品の製造方法。
(2)さらに部分アルファー化澱粉を混合することを特徴とする、(1)に記載の食肉加工製品の製造方法。
(3)食肉、結晶セルロース、部分アルファー化澱粉の質量比が100:(0.01〜10):(0.01〜10)であることを特徴とする、(2)に記載の食肉加工製品の製造方法。
(4)食肉加工製品がチキンナゲット、メンチカツ又はさつま揚げである、(1)〜(3)のいずれかに記載の食肉加工製品の製造方法。
(5)食肉100質量部に対して、平均粒径が10μm以下の結晶セルロースを0.01〜10質量部含有する、油で揚げられた食肉加工製品。
(6)食肉100質量部に対して、さらに部分アルファー化澱粉を0.01〜10質量部含有する、(5)に記載の油で揚げられた食肉加工製品。
(7)食肉加工製品がチキンナゲット、メンチカツ又はさつま揚げである(5)又は(6)に記載の食肉加工製品。
As a result of intensive investigations to solve the above problems, the inventors of the present invention are processed meat products including a step of frying in oil by using crystalline cellulose having a specific particle size or less even when dispersed with a weak stirring force. The present inventors have found that the oil can be prevented from bleeding and the yield can be improved. That is, the present invention is as follows.
(1) A method for producing a processed meat product, wherein 0.01 to 10 parts by mass of crystalline cellulose having an average particle size of 10 μm or less is mixed with 100 parts by mass of meat and fried in oil.
(2) The method for producing a processed meat product according to (1), further comprising mixing partially pregelatinized starch.
(3) The processed meat product according to (2), wherein the mass ratio of meat, crystalline cellulose, and partially pregelatinized starch is 100: (0.01-10) :( 0.01-10). Manufacturing method.
(4) The method for producing a processed meat product according to any one of (1) to (3), wherein the processed meat product is chicken nugget, meat cutlet, or fried fish cake.
(5) A processed meat product fried in oil containing 0.01 to 10 parts by mass of crystalline cellulose having an average particle size of 10 μm or less with respect to 100 parts by mass of meat.
(6) The processed meat product fried in oil according to (5), further containing 0.01 to 10 parts by mass of partially pregelatinized starch with respect to 100 parts by mass of meat.
(7) The processed meat product according to (5) or (6), wherein the processed meat product is chicken nugget, meat cutlet or fried fish cake.

本発明により、油で揚げる食肉加工製品の食感を損なわずに、油の染み出しを抑制し、歩留まりを向上できる方法を提供できる。   According to the present invention, it is possible to provide a method capable of suppressing oil seepage and improving yield without impairing the texture of processed meat products fried in oil.

以下、本発明につき詳しく説明する。本発明で言う結晶セルロースとは、例えば木材パルプ、精製リンターなどのセルロース系素材を、酸加水分解、アルカリ酸化分解、酵素分解などにより解重合処理して得られる平均重合度30〜400、結晶性部分が10%を超えるものをいう。本発明の結晶セルロースとして、結晶セルロースと水溶性高分子とを複合体化した結晶セルロース製剤を用いても構わない。   Hereinafter, the present invention will be described in detail. The crystalline cellulose referred to in the present invention means an average degree of polymerization of 30 to 400 obtained by depolymerizing cellulose materials such as wood pulp and refined linter by acid hydrolysis, alkaline oxidative decomposition, enzymatic decomposition, etc., crystallinity The part exceeds 10%. As the crystalline cellulose of the present invention, a crystalline cellulose preparation in which crystalline cellulose and a water-soluble polymer are combined may be used.

本発明で言う平均粒径は、具体的な測定方法は実施例に記載しているが、セルロース換算で1質量%の分散液となるように一般的な1〜2Lのステンレスビーカーに、結晶セルロース及び脱イオン水を、攪拌が十分できる量、例えば、2Lビーカーに1500mlを仕込み、半径30〜40mmの4枚パドル翼を取り付けたプロペラ攪拌機を用いて25℃、500rpmで20分間、水に分散させた場合の平均粒径のことを言う。例えばセオラスDX−2(商品名、旭化成ケミカルズ株式会社製)が、このような平均粒径10μm以下の要件を満たした結晶セルロースである。結晶セルロースの粒径は、強力な攪拌機、例えばエースホモジナイザー(日本精機製AM−T)などにより、10000回転/分以上の回転数で5分程度分散した粒径をさすことが多いが、この条件は非常に強い分散条件であるため、実際の食肉加工製品を製造する際にかかる攪拌力よりも遥かに強いものである。よって該条件で測定した粒径と、実際の製造工程で使用したときの結晶セルロースの平均粒径、すなわち実際の製品中の結晶セルロースの平均粒径とは大きく乖離したものであった。   The average particle diameter referred to in the present invention is described in Examples in the specific measuring method, but in a general 1 to 2 L stainless steel beaker so as to obtain a 1% by mass dispersion in terms of cellulose, crystalline cellulose is used. And deionized water is dispersed in water for 20 minutes at 25 ° C. and 500 rpm using a propeller stirrer with a sufficient amount of stirring, for example, 1500 ml in a 2 L beaker and equipped with four paddle blades with a radius of 30 to 40 mm. The average particle diameter in the case of For example, Theolas DX-2 (trade name, manufactured by Asahi Kasei Chemicals Corporation) is a crystalline cellulose that satisfies the requirement of such an average particle size of 10 μm or less. The particle size of crystalline cellulose often refers to a particle size dispersed for about 5 minutes at a rotation speed of 10,000 rotations / minute or more by a powerful stirrer such as ACE homogenizer (AM-T manufactured by Nippon Seiki). Is a very strong dispersion condition, so it is much stronger than the stirring force required when manufacturing an actual processed meat product. Therefore, the particle size measured under these conditions and the average particle size of the crystalline cellulose when used in the actual production process, that is, the average particle size of the crystalline cellulose in the actual product were greatly different.

本発明ではより実際の分散力、実際の製品中の結晶セルロースの平均粒径に近い値となるように弱い分散条件での平均粒径を定義しており、より意味のある値となっている。もちろん、予め強力な攪拌機で予備分散して平均粒径が10μm以下にして使用することも可能であるが、通常の食肉加工製品の製造設備において、そのような強力な攪拌機を所持していることは極めて稀である。   In the present invention, the average particle size under weak dispersion conditions is defined so as to be closer to the actual dispersion force and the average particle size of crystalline cellulose in the actual product, which is a more meaningful value. . Of course, it is possible to pre-disperse with a powerful stirrer in advance and use it with an average particle size of 10 μm or less. However, it is necessary to have such a strong stirrer in the production equipment for ordinary processed meat products. Is extremely rare.

油で揚げる工程を含まない食肉加工製品では、分散が不十分なほうが歩留まり向上の効果を発揮する。しかし、油で揚げる工程を含む食肉加工製品では、結晶セルロースを十分に分散させないと、歩留まり向上の機能が不十分となる。そのため、本願では、あらかじめ実際の製造工程で使用される条件と同程度の攪拌条件である攪拌機でも分散可能なように、分散助剤を含んだ結晶セルロース製剤を用いることが好ましい。そのような結晶セルロース製剤の製造例は後述する。   For processed meat products that do not include a frying process, an insufficient dispersion will have the effect of improving yield. However, in a processed meat product including a step of frying, if the crystalline cellulose is not sufficiently dispersed, the function of improving the yield becomes insufficient. Therefore, in the present application, it is preferable to use a crystalline cellulose preparation containing a dispersion aid so that it can be dispersed with a stirrer having stirring conditions similar to those used in an actual production process in advance. A production example of such a crystalline cellulose preparation will be described later.

本発明で言う食肉としては、牛肉、豚肉、猪肉、羊肉、鹿肉、馬肉、鯨肉、鶏肉、魚肉、もしくはこれらの二以上の混合物であり、本発明の食肉加工製品とは、前記の食肉を油で揚げる加熱処理工程を経るものである。例えばチキンナゲット、ミンチカツ、さつま揚げ、揚げ身、はんぺん、コロッケ、から揚げなどが挙げられる。本発明は、上記の食肉と結晶セルロースをニーディングなどで混練する工程、若しくは結晶セルロースを分散したピックル液を食肉に注射する工程と、油で揚げる加熱処理工程を施して食肉加工製品を製造することに関連し、前記食肉中に結晶セルロースを混合することにより、加熱処理をしたあとの製品の歩留まりを向上し、油の染み出し及び食感が悪化するのを抑制するものである。本発明の食肉加工製品は、加熱処理として油で揚げる工程を必ず経るものであるが、その他の加熱処理、例えば蒸したり焼いたりといった加熱処理の一つもしくは複数と組み合わせてもよい。油で揚げる際は、一般的なフライヤーや真空フライヤーで行うことができる。フライに用いる油も通常用いられる油脂から適宜選択すればよく、例えば、パーム油、米油、大豆油、菜種油、綿実油、ごま油、サフラワー油、ヤシ油、牛脂、豚油、これらの硬化油、エステル化油、ジアシルグリセロール、中鎖脂肪酸などが挙げられる。これらは一種類もしくは二種類以上を混合したものでもよい。フライの温度や時間は、製品の大きさや形状により適宜調整されるものであるが、通常のフライ温度は150℃〜205℃、好ましくは170〜190℃である。フライ時間は1〜10分程度である。   The meat referred to in the present invention is beef, pork, salmon meat, lamb, venison, horse meat, whale meat, chicken meat, fish meat, or a mixture of two or more thereof, and the processed meat product of the present invention is the aforementioned meat It goes through a heat treatment process in which the oil is fried in oil. Examples include chicken nuggets, minced cutlet, deep-fried sweet potato, fried meat, hampen, croquettes, and fried chicken. The present invention produces a processed meat product by subjecting the above meat and crystalline cellulose to a kneading process or the like, or a step of injecting a pickle solution in which crystalline cellulose is dispersed into the meat, and a heat treatment step of frying the oil. In particular, by mixing crystalline cellulose in the meat, the yield of the product after the heat treatment is improved, and oil exudation and texture are prevented from deteriorating. The processed meat product of the present invention necessarily undergoes a step of frying with oil as a heat treatment, but may be combined with one or more of other heat treatments, for example, steaming or baking. When frying with oil, it can be performed with a general fryer or a vacuum fryer. Oil used for frying may be appropriately selected from oils and fats commonly used, for example, palm oil, rice oil, soybean oil, rapeseed oil, cottonseed oil, sesame oil, safflower oil, coconut oil, beef tallow, pork oil, these hardened oils, Examples include esterified oils, diacylglycerols, and medium chain fatty acids. These may be one kind or a mixture of two or more kinds. The temperature and time of the frying are appropriately adjusted according to the size and shape of the product, but the usual frying temperature is 150 ° C to 205 ° C, preferably 170 to 190 ° C. The fly time is about 1 to 10 minutes.

本発明において効率的に歩留まり及び食感を向上させるためには、結晶セルロースの平均粒径は10μm以下のものを用いることが好ましい。10μm以下であると、十分な歩留まり向上効果が得られる。下限は特に制限はないが、実質的には1μm未満のものは製造が極めて困難である。   In order to improve the yield and texture efficiently in the present invention, it is preferable to use crystalline cellulose having an average particle size of 10 μm or less. When the thickness is 10 μm or less, a sufficient yield improvement effect can be obtained. The lower limit is not particularly limited, but it is substantially difficult to produce a material having a thickness of less than 1 μm.

ところで、ハンバーグなどの焼成し、油で揚げる工程のない食肉加工食品でも、結晶セルロースなどの食物繊維類を用いると歩留まりが向上することが知られている。この場合、結晶セルロース等の粒径が大きいほど吸水性及び吸油性が良い。このため、大きい粒径の結晶セルロース等を用いると、ドリップが減り、歩留まり向上効果は良好となるが、逆に食感は悪化する。このため、食感に悪影響の出ない範囲で粒径の大きいものを用いる必要があった。このことは下記の参考例として示している。一方、油で揚げる食肉加工食品においては、驚くべきことに、結晶セルロースの粒径が小さいもののほうが歩留まり向上効果が高いという、逆の結果が得られた。   By the way, it is known that even if processed meat products such as hamburgers that are not baked and fried in oil are used, the yield is improved by using dietary fibers such as crystalline cellulose. In this case, the larger the particle size of crystalline cellulose or the like, the better the water absorption and oil absorption. For this reason, when crystalline cellulose or the like having a large particle size is used, drip is reduced and the yield improvement effect is improved, but the texture is adversely affected. For this reason, it was necessary to use a thing with a large particle size in the range which does not have a bad influence on food texture. This is shown as a reference example below. On the other hand, in the processed meat food fried with oil, surprisingly, the opposite result was obtained that the yield improvement effect was higher when the particle size of the crystalline cellulose was smaller.

結晶セルロースを食肉に混合する際の添加方法は、特に限定はない。食肉に直接添加することはもちろん、食肉加工製品を製造する際に用いる調味料等の粉末と予め粉混合して添加、調味液や水、卵などに懸濁し添加、その他の原料と共に添加、他の原料を食肉に混合した後に最後に添加、などの方法が考えられるが、いずれの方法でも構わない。混合方法も一般的なニーダーやミキサー等による混合でよく、特に制限はないが、結晶セルロースが偏在しないように混合することは、必要である。   There is no particular limitation on the method of adding the crystalline cellulose to the meat. In addition to adding directly to meat, it is added by mixing with powders such as seasonings used in the manufacture of processed meat products in advance, suspended in seasoning liquid, water, eggs, etc., added with other ingredients, etc. Although the method of adding to the meat after adding this raw material to the meat is conceivable, any method may be used. The mixing method may be mixing with a general kneader or a mixer and is not particularly limited, but it is necessary to mix so that the crystalline cellulose is not unevenly distributed.

本発明の食肉加工製品には、食肉や玉ねぎ、卵、パン粉などの食品素材、結晶セルロース以外に、単糖類、オリゴ糖類、糖アルコール類、澱粉類、加工澱粉類、油脂類、蛋白類、アミノ酸類、食塩、各種リン酸塩類、乳化剤、増粘安定剤、ゲル化剤、酸味料、pH調整剤、香料、保存料、色素など食品に使用できる成分を適宜配合してもよい。   In the processed meat product of the present invention, in addition to food materials such as meat, onions, eggs and bread crumbs, crystalline cellulose, monosaccharides, oligosaccharides, sugar alcohols, starches, processed starches, fats and oils, proteins, amino acids Ingredients, salt, various phosphates, emulsifiers, thickening stabilizers, gelling agents, acidulants, pH adjusters, fragrances, preservatives, pigments, and other ingredients that can be used in foods may be appropriately blended.

また、本発明では部分アルファー化澱粉を結晶セルロースと併用すると、より風味が増すため好ましい。食肉、結晶セルロース、部分アルファー化澱粉の質量比が100:(0.01〜10):(0.01〜10)の範囲で使用するのが好ましい。より好ましくは100:(0.1〜5):(0.1〜5)である。部分アルファー化澱粉は、予め結晶セルロースと混合しておいて用いてもよいし、食肉加工製品を製造する際に別々に添加してもよい。   In the present invention, it is preferable to use partially pregelatinized starch together with crystalline cellulose because the flavor is further increased. The mass ratio of meat, crystalline cellulose, and partially pregelatinized starch is preferably 100: (0.01-10) :( 0.01-10). More preferably, it is 100: (0.1-5) :( 0.1-5). The partially pregelatinized starch may be used by previously mixing with crystalline cellulose, or may be added separately when producing a processed meat product.

ここでいう部分アルファー化澱粉とは、澱粉を湿熱処理により部分的にアルファー化したものである。その原料は特に制限はなく、とうもろこし澱粉、小麦澱粉、米澱粉、馬鈴薯澱粉などいずれの澱粉原料でもよい。部分アルファー化澱粉のなかでも、澱粉粒の内部がより多くアルファー化され、外郭部はアルファー化の程度が低いものが好ましい。具体的には冷水可溶分が6質量%以下のものが好ましい。冷水可溶分が6質量%以下のとき、糊成分の流出が少なく、良好な食感を維持できる。   The partially pregelatinized starch as used herein is a product obtained by partially pregelatinizing starch by wet heat treatment. The raw material is not particularly limited, and any starch raw material such as corn starch, wheat starch, rice starch, and potato starch may be used. Among the partially pregelatinized starches, it is preferable that the inside of the starch granules is more pregelatinized and the outer portion has a low degree of pregelatinization. Specifically, those having a cold water soluble content of 6% by mass or less are preferable. When the cold water soluble content is 6% by mass or less, there is little outflow of the paste component, and a good texture can be maintained.

実施例により本発明をさらに具体的に説明するが、これらによって本発明は何ら制限されるものではない。なお、測定及び評価は以下の通りに行った。 The present invention will be described more specifically with reference to examples, but the present invention is not limited to these examples. Measurement and evaluation were performed as follows.

<平均粒径>
(1)固形分濃度が1%、総量1300〜1700mlの水分散液となるようにサンプルと純水を2Lステンビーカーに量り取り、汎用攪拌翼かい十字(半径35mm)を取り付けたプロペラ攪拌機(スリーワンモーターHEIDON(商品名)BL−600)を用いて25℃、500rpmで20分間分散した。
(2)レーザー回折散乱装置(堀場製作所製 LA−910、超音波分散1分)により積算体積が50%になる値(メジアン径)を読み取り、平均粒径とした。
<Average particle size>
(1) A propeller stirrer (three-one) equipped with a general-purpose stirring blade and cross (radius 35 mm) was weighed in a 2 L stainless steel beaker so that the aqueous dispersion had a solid content of 1% and a total amount of 1300 to 1700 ml. Motor HEIDON (trade name) BL-600) was dispersed at 25 ° C. and 500 rpm for 20 minutes.
(2) A value (median diameter) at which the integrated volume becomes 50% was read by a laser diffraction scattering apparatus (LA-910, manufactured by Horiba, Ltd., ultrasonic dispersion 1 minute) and used as an average particle diameter.

[製造例1]
60℃の温水10kgを用意し、軽く攪拌しながら、結晶性セルロース80質量%とカラヤガム10質量%とデキストリン10質量%からなる乾燥状態のセルロース複合体(商品名:セオラスRC−N81、旭化成ケミカルズ(株)製)を1.35kg加えた後、分散助剤として、デキストリン(商品名:パインデックス#3、松谷化学工業(株)製)1.65kgを加え、さらに20分間攪拌した。この分散溶解液を高圧ホモジナイザー(APV社製)を用いて15MPaの圧力で2パスして混合処理したのち、スプレードライヤーを用いて入り口温度が90〜100℃、出口温度が70〜80℃の条件で噴霧乾燥して、易分散性の結晶セルロース製剤Aを得た。この結晶セルロース製剤Aは、分散助剤を加えて高圧ホモジナイザーで処理し、スプレードライで乾燥しているので、非常に分散し易い結晶セルロース製剤であり、一般的な食肉加工製品の製造工程において分散可能なものである。
[Production Example 1]
Prepare 10 kg of hot water at 60 ° C., and with light agitation, dry cellulose composite consisting of 80% by weight of crystalline cellulose, 10% by weight of Karaya gum and 10% by weight of dextrin (trade name: Theolas RC-N81, Asahi Kasei Chemicals ( After the addition of 1.35 kg), 1.65 kg of dextrin (trade name: Paindex # 3, manufactured by Matsutani Chemical Co., Ltd.) was added as a dispersion aid, and the mixture was further stirred for 20 minutes. After this dispersion solution was mixed by two passes at a pressure of 15 MPa using a high-pressure homogenizer (manufactured by APV), an inlet temperature was 90-100 ° C. and an outlet temperature was 70-80 ° C. using a spray dryer. Was spray-dried to obtain an easily dispersible crystalline cellulose preparation A. This crystalline cellulose preparation A is a crystalline cellulose preparation that is very easy to disperse because it is treated with a high-pressure homogenizer with the addition of a dispersion aid and dried by spray drying, and is dispersed in the production process of general processed meat products. It is possible.

[実施例1、2、比較例1〜4](チキンナゲットでの評価)
表1の処方にてチキンナゲットを作成した。実施例1、2は結晶セルロース成分として、製造例1の結晶セルロース製剤A(平均粒径8μm、結晶セルロース36質量%の製剤)を食肉100質量部に対して1.1質量部(結晶セルロースとして0.4質量部)を添加し、比較例1、2は結晶セルロース成分を無添加とし、比較例3、4は結晶セルロース成分として平均粒径25μmのセオラスUF−F702(製品名、旭化成ケミカルズ株式会社製、結晶セルロース100%)を食肉100質量部に対して1.1質量部添加した例である。
[Examples 1 and 2, Comparative Examples 1 to 4] (Evaluation with chicken nuggets)
Chicken nuggets were prepared according to the formulation shown in Table 1. In Examples 1 and 2, as a crystalline cellulose component, 1.1 parts by mass (as crystalline cellulose) of crystalline cellulose preparation A (preparation having an average particle size of 8 μm and crystalline cellulose of 36% by mass) of Production Example 1 with respect to 100 parts by mass of meat. 0.4 mass parts) was added, Comparative Examples 1 and 2 were without the addition of the crystalline cellulose component, and Comparative Examples 3 and 4 were the Ceolas UF-F702 (product name, Asahi Kasei Chemicals Corporation) having an average particle size of 25 μm as the crystalline cellulose component. This is an example in which 1.1 parts by mass of 100% by mass of meat made by company, 100% crystalline cellulose) is added.

表1にある鶏胸肉とラード以外の成分は、予め粉体のまま混合した。鶏肉(ムネ肉)を包丁で叩いて繊維状に割いた後、ラード、粉体混合品を練りこみ、この練りこみ品15gを成型し、薄力粉で打ち粉し、バッター液(配合;薄力粉45.7g、とうもろこし粉45g、アルファー化デンプン5g、砂糖3g、食塩1g、クチナシ色素0.15g、全卵液50g、水100g)につけた。実施例1及び比較例1、3では180℃で1分間揚げた後、−20℃で18時間冷凍し、再度170℃で3分間揚げた。実施例2及び比較例2、4では、170℃で4分間揚げた後、−20℃で18時間冷凍し、電子レンジで600Wにて4分間加熱した。それぞれの練りこみ後の重量と最終重量を比較して、最終重量/練りこみ後の重量×100を歩留まりとして計算した。また、官能試験はパネラー3名(20代女性、30代及び50代の男性)で行い、硬さ、スパイシー感を評価した。   Ingredients other than chicken breast and lard in Table 1 were previously mixed in powder form. After pouring chicken meat with a knife and breaking it into fibers, knead lard and powder mixture, mold 15 g of this kneaded product, dust with soft flour, batter liquid (compound; soft flour 45. 7 g, corn flour 45 g, pregelatinized starch 5 g, sugar 3 g, salt 1 g, gardenia pigment 0.15 g, whole egg solution 50 g, water 100 g). In Example 1 and Comparative Examples 1 and 3, they were fried at 180 ° C. for 1 minute, then frozen at −20 ° C. for 18 hours, and fried again at 170 ° C. for 3 minutes. In Example 2 and Comparative Examples 2 and 4, they were fried at 170 ° C. for 4 minutes, then frozen at −20 ° C. for 18 hours, and heated in a microwave at 600 W for 4 minutes. The weight after each kneading and the final weight were compared, and the final weight / the weight after kneading × 100 was calculated as a yield. The sensory test was conducted by 3 panelists (20s female, 30s male and 50s male) to evaluate hardness and spicy feeling.

その結果、歩留まりは実施例1で140.5%、実施例2で144.6%であったのに対し、比較例1で111.7%、比較例2が126.2%、比較例3が124.8%、比較例4が127.9%であった。この結果から、実施例1、2において良好な歩留まりとなることが判明した。また官能試験では結晶セルロース成分を添加した実施例1、2は、結晶セルロース成分を添加していない比較例1、2と比べて肉質が柔らかくジューシーであり、好ましい食感であった。一方、比較例3は肉質が柔らか過ぎ、比較例4は逆に肉質が硬過ぎる食感となった。また、実施例2、比較例2及び4のレンジ加熱後のチキンナゲットをキッチンペーパの上におき、10分後の油の染み出し状況を目視にて観察したところ、比較例4、実施例2では、油の染み出しが少なかった。一方、比較例1はこれらと比較して、明らかに油の染み出しが多かった。以上の結果を表2にまとめて示す。   As a result, the yield was 140.5% in Example 1 and 144.6% in Example 2, whereas 111.7% in Comparative Example 1, 126.2% in Comparative Example 2, and Comparative Example 3 Was 124.8%, and Comparative Example 4 was 127.9%. From this result, it was found that good yields were obtained in Examples 1 and 2. In the sensory test, Examples 1 and 2 to which the crystalline cellulose component was added were softer and juicy in meat quality than Comparative Examples 1 and 2 to which the crystalline cellulose component was not added, and were preferable textures. On the other hand, Comparative Example 3 had a texture that was too soft, and Comparative Example 4 had a texture that was too hard. Moreover, when the chicken nugget after the range heating of Example 2 and Comparative Examples 2 and 4 was placed on the kitchen paper and the oil oozing state after 10 minutes was visually observed, in Comparative Example 4 and Example 2, The oil oozes out little. On the other hand, Comparative Example 1 clearly had more oil ooze out than these. The above results are summarized in Table 2.

Figure 0005405257
Figure 0005405257

Figure 0005405257
Figure 0005405257

[参考例](ハンバーグでの評価)
参考として、油で揚げる工程を含まない食肉加工製品の例を示す。表3の基本処方に対して、表4に示すように各添加剤(参考例2は、特開平11−46723号公報(特許文献5)の実施例1の複合体Dを該文献に従って作成したものを用いた。なお、表4中の平均粒径は本願明細書にて開示した方法で添加剤を水に分散した時の結晶セルロース成分の平均粒径である。他は製品名、旭化成ケミカルズ株式会社製)を外割りで加えてハンバーグを作成した。参考例7のセオラスDX−2は結晶セルロース製剤Aと同等の分散性を持った結晶セルロース製剤である。参考例4では部分アルファー化澱粉(製品名 PCS、旭化成ケミカルズ株式会社製)を結晶セルロースと併用した。
[Reference Example] (Evaluation with hamburger)
For reference, an example of a processed meat product that does not include a frying process is shown. With respect to the basic formulation of Table 3, as shown in Table 4, each additive (Reference Example 2 was prepared in accordance with the document D of Example 1 of JP-A No. 11-46723 (Patent Document 5). The average particle size in Table 4 is the average particle size of the crystalline cellulose component when the additive is dispersed in water by the method disclosed in the present specification, others are product names, Asahi Kasei Chemicals. A hamburger was made by adding outside the company). Thesaurus DX-2 of Reference Example 7 is a crystalline cellulose preparation having dispersibility equivalent to that of crystalline cellulose preparation A. In Reference Example 4, partially pregelatinized starch (product name: PCS, manufactured by Asahi Kasei Chemicals Corporation) was used in combination with crystalline cellulose.

まず、玉ねぎを3mm程度にみじん切りし、みじん切りした玉ねぎ約400gを電子レンジで600Wで10分間調理し、容器をラップで覆って10分蒸して表2に従って所定量に小分けした。パン粉、食塩、こしょう、ナツメグ、グルタミン酸ソーダ(調味料)をポリ袋に量り取り、粉で十分に混合した。フードプロセッサー(OHMICHI SANGYO社製 POT−33)の容器に牛豚合挽ミンチ、調理した玉ねぎ、全卵、トマトケチャップ、ポリ袋で混合した粉混合物を入れて、2000rpmで10秒攪拌し、一度、容器内壁の付着物を掻き落して、再度、2000rpmで20秒攪拌した。空気を抜きながら約70gの団子を作り、ハンバーグ成型器に入れて成型し重量を測定した。成型物をオーブンレンジ230℃で11分間焼成し、ドリップ液の重量、ハンバーグの重量を測定した。室温で30℃以下まで放冷し、−20℃で3日間保管した。レンジで2個ずつを600Wにて3分間加熱解凍して官能評価を実施した。官能評価はパネラー3名(20代女性、30代及び50代の男性)で行い、美味しさ、ジューシー感、ネチャ付感、パサツキ感を添加剤無添加の比較例5と比較して下記の基準にしたがって5段階評価で行い、各人の評価点の平均点を算出した。その平均点の結果を表5に示す。
(ハンバーグの官能評価)
美味しさ (優)5 参考例6と比べて、明らかに美味しい。
(良)4 参考例6と比べて、どちらかといえば美味しい。
(普)3 参考例6と違いが分からない。
(可)2 参考例6と比べて、どちらかというと美味しくない。
(不可)1 参考例6と比べて、明らかにまずい。

ジューシー感 (優)5 参考例6と比べて、明らかにジューシー。
(良)4 参考例6と比べて、どちらかといえばジューシー。
(普)3 参考例6と違いが分からない。
(可)2 参考例6と比べて、どちらかというとジューシー感がない。
(不可)1 参考例6と比べて、明らかにジューシー感がない。

ネチャ付感 (優)5 参考例6と比べて、明らかにネチャ付きがない。
(良)4 参考例6と比べて、どちらかといえばネチャ付きがない。
(普)3 参考例6と違いが分からない。
(可)2 参考例6と比べてどちらかといえばネチャ付く感じがする。
(不可)1 参考例6と比べて、明らかにネチャ付く。

パサツキ感 (優)5 参考例6と比べて、明らかにパサツキがない。
(良)4 参考例6と比べて、どちらかといえばパサツキがない。
(普)3 参考例6と違いが分からない。
(可)2 参考例6と比べて、どちらかというとパサツキ感がする。
(不可)1 参考例6と比べて、明らかにパサツキ感がある。粉っぽい。
First, the onion was chopped to about 3 mm, and about 400 g of chopped onion was cooked in a microwave oven at 600 W for 10 minutes, covered with a wrap and steamed for 10 minutes, and subdivided into predetermined amounts according to Table 2. Bread crumbs, salt, pepper, nutmeg and sodium glutamate (condiment) were weighed into a plastic bag and mixed thoroughly with the flour. Put the powder mixture mixed with minced beef pork, cooked onion, whole egg, tomato ketchup, plastic bag in the container of the food processor (OHMICHI SANGYO POT-33), and stir at 2000 rpm for 10 seconds. The deposits on the inner wall of the container were scraped off and stirred again at 2000 rpm for 20 seconds. About 70 g of dumplings were made while ventilating the air, put into a hamburger molding machine, and weighed. The molded product was baked at 230 ° C. for 11 minutes, and the weight of the drip solution and the weight of the hamburger were measured. The mixture was allowed to cool to 30 ° C. or lower at room temperature and stored at −20 ° C. for 3 days. Sensory evaluation was carried out by heating and thawing two pieces at 600 W for 3 minutes in the range. The sensory evaluation was performed by 3 panelists (20s, 30s and 50s) and compared to Comparative Example 5 with no additives, the following criteria for taste, juiciness, feeling of stickiness, and crispness: According to the above, the evaluation was performed in a five-step evaluation, and the average score of each person was calculated. The average score results are shown in Table 5.
(Sensory evaluation of hamburger)
Deliciousness (excellent) 5 Compared to Reference Example 6, it is clearly delicious.
(Good) 4 Compared to Reference Example 6, it is rather delicious.
(Ordinary) 3 I do not know the difference from Reference Example 6.
(Yes) 2 Compared to Reference Example 6, it is rather not delicious.
(Improper) 1 Compared with Reference Example 6, clearly worse.

Juicy (excellent) 5 Compared to Reference Example 6, it is clearly juicy.
(Good) 4 Compared to Reference Example 6, rather juicy.
(Ordinary) 3 I do not know the difference from Reference Example 6.
(Yes) 2 Compared to Reference Example 6, there is no succulent feeling.
(Improper) 1 Compared to Reference Example 6, there is clearly no succulent feeling.

Sense of stickiness (excellent) 5 Compared to Reference Example 6, there is clearly no stickiness.
(Good) 4 Compared to Reference Example 6, there is no stickiness.
(Ordinary) 3 I do not know the difference from Reference Example 6.
(Yes) 2 Compared to Reference Example 6, it feels more sticky.
(Improper) 1 Compared with Reference Example 6, it is clearly sticky.

Pasaki feeling (excellent) 5 Compared with Reference Example 6, there is no apparent pasaki.
(Good) 4 Compared to Reference Example 6, there is no looseness.
(Ordinary) 3 I do not know the difference from Reference Example 6.
(Yes) 2 Compared with Reference Example 6, it feels more rustic.
(Improper) 1 Compared with Reference Example 6, there is clearly a feeling of smoothness. It ’s powdery.

Figure 0005405257
Figure 0005405257

Figure 0005405257
Figure 0005405257

Figure 0005405257
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平均粒径が10μmを超える結晶セルロースを用いている、参考例1〜5においてはいずれも歩留まりが向上しているだけでなく、美味しさやジューシー感が向上しており、特に部分アルファー化澱粉を添加した参考例4では、官能評価が良好な結果となった。参考例7では平均粒径8.1μmの結晶セルロース製剤を用いているが、若干歩留まりが悪く、官能評価ではネチャ付感が強くなっていた。   In Reference Examples 1-5, which uses crystalline cellulose with an average particle size exceeding 10 μm, not only the yield is improved, but also the taste and juicy feeling are improved, especially with the addition of partially pregelatinized starch In Reference Example 4, the sensory evaluation was good. In Reference Example 7, a crystalline cellulose preparation having an average particle size of 8.1 μm was used, but the yield was slightly poor and the feeling of stickiness was strong in sensory evaluation.

参考例では加熱処理が焼成であり、結晶セルロールの平均粒径が大きい方が歩留まりが良い結果となっている。一方、加熱処理が油で揚げる場合(実施例1、2、比較例1〜4)では反対の結果となっている。   In the reference example, the heat treatment is firing, and the larger the average particle size of the crystal cellulose roll, the better the yield. On the other hand, when the heat treatment is fried in oil (Examples 1 and 2, Comparative Examples 1 to 4), the opposite results are obtained.

[実施例3、4、比較例5](さつま揚げでの評価)
イワシのすり身600gに、ゴボウ1/2本とニンジン40gのさきがき、溶き卵1/2個分、白味噌大さじ2杯、醤油小さじ1/2杯、酒大さじ1杯、塩小さじ1/2杯に対し、実施例3ではセオラスDX−2(製品名、旭化成ケミカルズ株式会社製)を2.8質量%(結晶セルロース換算で1質量%)添加した。実施例4では、セオラスDX−2に加えてさらにPCS(製品名、旭化成ケミカルズ株式会社製、冷水可溶分3%の部分アルファー化デンプン)を3質量%添加した。比較例5ではセオラスDX−2を0.025質量%(結晶セルロース換算で0.009質量%)添加した。それぞれの混合物は、小判型に成型し、油で170℃にて5分間揚げた。その後、油を十分に切り、揚げた前後の重量を測定して歩留まりを計算した。実施例3では歩留まりが95%、実施例4では97%であったのに対し、比較例5では91%となった。このため実施例3、4では、比較例5に比べて、良好な歩留まりとなった。食感も、実施例3、4は、比較例5に比べジューシーであり、実施例4が最もジューシーで、且つ美味しかった。
[Examples 3 and 4, Comparative Example 5] (Evaluation with fried fish cake)
600g of sardine surimi, 1/2 burdock and 40g carrot, 1/2 melted egg, 2 tablespoons white miso, 1/2 teaspoon soy sauce, 1 tablespoon sake, 1/2 teaspoon salt On the other hand, in Example 3, 2.8% by mass (1% by mass in terms of crystalline cellulose) of Theorax DX-2 (product name, manufactured by Asahi Kasei Chemicals Corporation) was added. In Example 4, 3 mass% of PCS (product name, manufactured by Asahi Kasei Chemicals Co., Ltd., partially pregelatinized starch having a cold water soluble content of 3%) was added in addition to Theolas DX-2. In Comparative Example 5, 0.025 mass% (0.009 mass% in terms of crystalline cellulose) was added to Theolas DX-2. Each mixture was molded into an oval mold and fried in oil at 170 ° C. for 5 minutes. Then, the oil was cut out sufficiently, the weight before and after frying was measured, and the yield was calculated. In Example 3, the yield was 95%, and in Example 4, it was 97%, while in Comparative Example 5, it was 91%. Therefore, in Examples 3 and 4, the yield was better than that in Comparative Example 5. In terms of texture, Examples 3 and 4 were more juicy than Comparative Example 5, and Example 4 was the most juicy and delicious.

本発明は食肉加工製品の油の染み出しを防止し、歩留まり及び食感を向上できるので食肉加工製品の製造に好適に利用できる。   INDUSTRIAL APPLICABILITY The present invention prevents oil from bleeding into processed meat products and can improve yield and texture, so that it can be suitably used for manufacturing processed meat products.

Claims (7)

食肉100質量部に対して、プロペラ撹拌機による25℃、500rpm、20分間分散後の固形分濃度1%の水分散液における平均粒径が10μm以下の結晶セルロースを0.01〜10質量部混合し、油で揚げることを含む食肉加工製品の製造方法であって、前記結晶セルロースが分散助剤を含んだ結晶セルロース製剤として混合されることを特徴とする食肉加工製品の製造方法。 0.01 to 10 parts by mass of crystalline cellulose having an average particle diameter of 10 μm or less in an aqueous dispersion having a solid content concentration of 1% after dispersion for 20 minutes at 25 ° C. and 500 rpm with a propeller stirrer with 100 parts by mass of meat and a method of manufacturing a processed meat product comprising frying said crystalline cellulose, characterized in that it is mixed as a crystalline cellulose preparations containing a dispersing aid, a manufacturing method of processed meat products. さらに部分アルファー化澱粉を混合することを特徴とする、請求項1に記載の食肉加工製品の製造方法。   Furthermore, the partially pregelatinized starch is mixed, The manufacturing method of the processed meat product of Claim 1 characterized by the above-mentioned. 食肉、結晶セルロース、部分アルファー化澱粉の質量比が100:(0.01〜10):(0.01〜10)であることを特徴とする、請求項2に記載の食肉加工製品の製造方法。   The method for producing a processed meat product according to claim 2, wherein the mass ratio of meat, crystalline cellulose, and partially pregelatinized starch is 100: (0.01-10) :( 0.01-10). . 食肉加工製品がチキンナゲット、メンチカツ又はさつま揚げである、請求項1〜3のいずれかに記載の食肉加工製品の製造方法。   The method for producing a processed meat product according to any one of claims 1 to 3, wherein the processed meat product is chicken nugget, meat cutlet or fried fish cake. 食肉100質量部に対して、プロペラ撹拌機による25℃、500rpm、20分間分散後の固形分濃度1%の水分散液における平均粒径が10μm以下の結晶セルロース0.01〜10質量部と分散助剤とを含有する、油で揚げられた食肉加工製品。 Respect Meat 100 parts by weight, 25 ° C. by a propeller stirrer, 500 rpm, the average particle size in 20 minutes after dispersing a solid concentration of 1% aqueous dispersion of the following 10μm crystal cellulose scan 0. A processed meat product fried in oil, containing 01-10 parts by weight and a dispersion aid . 食肉100質量部に対して、さらに部分アルファー化澱粉を0.01〜10質量部含有する、請求項5に記載の油で揚げられた食肉加工製品。   The meat processed product fried in oil of Claim 5 which contains 0.01-10 mass parts of partial pregelatinized starch with respect to 100 mass parts of meat. 食肉加工製品がチキンナゲット、メンチカツ又はさつま揚げである、請求項5又は6に記載の食肉加工製品。   The processed meat product according to claim 5 or 6, wherein the processed meat product is chicken nugget, meat cutlet, or deep-fried fish cake.
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