JP5400497B2 - Sheet-like peeling member for electrophotographic apparatus and electrophotographic apparatus - Google Patents

Sheet-like peeling member for electrophotographic apparatus and electrophotographic apparatus Download PDF

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JP5400497B2
JP5400497B2 JP2009152652A JP2009152652A JP5400497B2 JP 5400497 B2 JP5400497 B2 JP 5400497B2 JP 2009152652 A JP2009152652 A JP 2009152652A JP 2009152652 A JP2009152652 A JP 2009152652A JP 5400497 B2 JP5400497 B2 JP 5400497B2
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sheet
electrophotographic apparatus
resin
resin coating
filler
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JP2011008103A (en
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明 芝原
覚 福澤
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NTN Corp
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Description

この発明は、複写機やレーザープリンタ等の電子写真装置に組み込まれた定着ローラや定着ベルト等の定着部材から用紙を剥離させるシート状の剥離部材、およびこれを用いた電子写真装置に関する。   The present invention relates to a sheet-like peeling member for peeling a sheet from a fixing member such as a fixing roller and a fixing belt incorporated in an electrophotographic apparatus such as a copying machine or a laser printer, and an electrophotographic apparatus using the same.

複写機やレーザープリンタ等の電子写真装置には、感光ドラム上に形成された静電潜像をトナー等の現像剤を用いて用紙上に現像した後、用紙に転写された現像剤を定着ローラや定着ベルト等の定着部材により加熱溶融するとともに加圧して用紙に定着させる定着部がある。この定着部には、現像剤が定着した用紙を定着部材からスムーズに剥離させるためのシート状剥離部材が併設されていることが多い。   In an electrophotographic apparatus such as a copying machine or a laser printer, an electrostatic latent image formed on a photosensitive drum is developed on a sheet using a developer such as toner, and then the developer transferred to the sheet is fixed to a fixing roller. In addition, there is a fixing unit that is heated and melted by a fixing member such as a fixing belt or the like and is fixed to a sheet by applying pressure. In many cases, the fixing unit is provided with a sheet-like peeling member for smoothly peeling the paper on which the developer is fixed from the fixing member.

上記シート状剥離部材は、シート状基材の先端部を定着部材に接触または近接させることにより、用紙を定着部材から剥離させるものである。ここで、接触とは、シート状基材の先端側の一辺が定着部材とその軸方向で線接触することを言い、近接とは、用紙の定着部材への巻き付きを防止できる程度に、基材の先端側の一辺が定着部材に接近配置されていることをいう。このような剥離部材としては、用紙剥離性を向上させるとともにトナー付着による用紙の汚れを防止するために、先端部をフッ素樹脂で覆ったものが増えてきている。   The sheet-like peeling member peels the sheet from the fixing member by bringing the leading end of the sheet-like base material into contact with or close to the fixing member. Here, the contact means that one side of the front side of the sheet-like base material is in line contact with the fixing member in the axial direction thereof, and the proximity means that the base material can be prevented from being wound around the fixing member. This means that one side of the front end side is located close to the fixing member. As such a peeling member, in order to improve the paper peelability and prevent the paper from being soiled due to toner adhesion, an increasing number of the peeling members are covered with a fluororesin.

フッ素樹脂で基材先端部を覆ったシート状剥離部材としては、例えば、フッ素樹脂フィルムをシリコーン系粘着剤で基材に貼り付けたもの(特許文献1参照)、基材表面にフッ素樹脂をコーティングして塗膜を形成したもの(特許文献2参照)等がある。   Examples of the sheet-like release member that covers the tip of the substrate with a fluororesin include, for example, a fluororesin film attached to a substrate with a silicone-based adhesive (see Patent Document 1), and the substrate surface is coated with a fluororesin And a coating film is formed (see Patent Document 2).

特開2001−235959号公報JP 2001-235959 A 特開2003−248393号公報JP 2003-248393 A

しかしながら、上記特許文献1に記載されたシート状剥離部材は、印字速度の高速化等に伴い定着部材が200℃以上の高温になると、シリコーン系粘着剤の密着力が低下してフッ素樹脂フィルムが剥がれるおそれがある。   However, in the sheet-like peeling member described in Patent Document 1, when the fixing member becomes a high temperature of 200 ° C. or more with an increase in printing speed, the adhesive strength of the silicone-based adhesive is reduced, and the fluororesin film becomes There is a risk of peeling.

また、特許文献2のシート状剥離部材は、フッ素樹脂塗膜が定着部材や用紙との摺動によって摩耗し、用紙が剥離しにくくなったり、トナーが付着しやすくなったりするおそれがある。特に、近年の粘着性の高いカラートナーを用いる場合では、よりトナーが付着しやすく用紙を汚染するという問題がある。   Further, in the sheet-like peeling member of Patent Document 2, the fluororesin coating film is worn by sliding with the fixing member or the paper, so that the paper may be difficult to peel off or the toner may be easily attached. In particular, in the case of using a color toner having high adhesiveness in recent years, there is a problem that the toner is more easily attached and the paper is contaminated.

本発明はこのような問題に対処するためになされたものであり、高温条件下でも使用可能で、長期にわたって優れた用紙剥離性を維持できるシート状剥離部材およびこのシート剥離部材を用いる電子写真装置を提供することを目的とする。   The present invention has been made in order to cope with such a problem, and is a sheet-like peeling member that can be used even under high temperature conditions and can maintain excellent paper peeling properties over a long period of time, and an electrophotographic apparatus using this sheet peeling member The purpose is to provide.

本発明の電子写真装置のシート状剥離部材は、電子写真装置の定着部材にシート状基材の先端部を接触または近接させて、定着部材から用紙を剥離させるシート状剥離部材において、上記シート状基材の用紙が通過する側の表面(通紙側表面)に、球状充填材を含む樹脂被膜が形成されていることを特徴とする。ここで、球状とは長径に対する短径の比が0.8〜1.0である球の形状をいう。   The sheet-like peeling member of the electrophotographic apparatus of the present invention is the above sheet-like peeling member in the sheet-like peeling member that peels the sheet from the fixing member by bringing the leading end portion of the sheet-like substrate into contact with or close to the fixing member of the electrophotographic apparatus. A resin film containing a spherical filler is formed on the surface of the base material on the side through which the paper passes (sheet passing side surface). Here, the spherical shape refers to a spherical shape having a ratio of the minor axis to the major axis of 0.8 to 1.0.

上記樹脂被膜は樹脂塗膜であり、上記樹脂塗膜における樹脂成分の膜厚よりも上記球状充填材の粒子径の方が大きいことを特徴とする。また、上記樹脂塗膜の樹脂成分の膜厚は、5μm〜35μmであることを特徴とする。   The resin coating is a resin coating, and the spherical filler has a larger particle size than the thickness of the resin component in the resin coating. The film thickness of the resin component of the resin coating film is 5 to 35 μm.

上記球状充填材は、粒子径50μm〜500μmの球状充填材であることを特徴とする。また、上記球状充填材は、樹脂被膜1cm2当たり30個〜1800個含まれることを特徴とする。 The spherical filler is a spherical filler having a particle diameter of 50 μm to 500 μm. The spherical filler is contained in 30 to 1800 per 1 cm 2 of the resin coating.

上記球状充填材は、中空状充填材または粒子状充填材であることを特徴とする。また、上記中空状充填材は、樹脂バルーン、セラミックバルーン、シラスバルーンまたはガラスバルーンのいずれかであることを特徴とする。また、上記粒子状充填材は、樹脂ビーズ、セラミックスビーズ、シリカビーズ、ガラスビーズまたはカーボンビーズのいずれかであることを特徴とする。   The spherical filler is a hollow filler or a particulate filler. The hollow filler is any one of a resin balloon, a ceramic balloon, a shirasu balloon, or a glass balloon. Further, the particulate filler is any of resin beads, ceramic beads, silica beads, glass beads, or carbon beads.

上記シート状基材の先端部の厚さ方向は、曲面とされていることを特徴とする。また、上記樹脂被膜において、シート状基材の先端部に形成された部分には上記球状充填材を含まないことを特徴とする。また、シート状基材の用紙が通過する側の表面の反対側表面(反通紙表面)が平滑面であることを特徴とする。   The thickness direction of the front-end | tip part of the said sheet-like base material is made into the curved surface, It is characterized by the above-mentioned. In the resin coating, the spherical filler is not included in the portion formed at the tip of the sheet-like base material. Further, the surface opposite to the surface through which the sheet of the sheet-like base material passes (reverse paper passing surface) is a smooth surface.

上記樹脂塗膜は、含フッ素重合体を主成分とすることを特徴とする。また、上記含フッ素重合体が、ポリテトラフルオロエチレン(以下、PTFEと記す)重合体、テトラフルオロエチレン−パーフルオロアルキルビニルエーテル(以下、PFAと記す)共重合体およびテトラフルオロエチレン−ヘキサフルオロプロピレン(以下、FEPと記す)共重合体のうちのいずれかであることを特徴とする。   The resin coating film has a fluorine-containing polymer as a main component. The fluorine-containing polymer is a polytetrafluoroethylene (hereinafter referred to as PTFE) polymer, a tetrafluoroethylene-perfluoroalkyl vinyl ether (hereinafter referred to as PFA) copolymer, and a tetrafluoroethylene-hexafluoropropylene ( (Hereinafter referred to as FEP).

本発明の電子写真装置は、現像剤が定着した用紙を定着部材から剥離させるためのシート状剥離部材を有する電子写真装置であって、本発明のシート状剥離部材を用いることを特徴とする。また、上記電子写真装置はカラートナーを用いるフルカラー電子写真装置であることを特徴とする。   The electrophotographic apparatus of the present invention is an electrophotographic apparatus having a sheet-like peeling member for peeling off the sheet on which the developer is fixed from the fixing member, and is characterized by using the sheet-like peeling member of the present invention. The electrophotographic apparatus is a full-color electrophotographic apparatus using color toner.

本発明のシート状剥離部材(請求項1)は、上述したように、シート状基材の通紙側表面に、球状充填材が配合された樹脂被膜を形成した構成であるので、用紙との接触面積が小さく用紙との低摩擦特性が優れる。また、球状充填材により、シート状基材の放熱性が高くなるのでシート状剥離部材が高温になることが防止でき、長期にわたって優れたシート剥離性が維持される。   Since the sheet-like release member of the present invention (Claim 1) has a structure in which a resin film in which a spherical filler is blended is formed on the sheet-passing side surface of the sheet-like base material as described above, Small contact area and excellent low friction characteristics with paper. Moreover, since the heat dissipation of a sheet-like base material becomes high with a spherical filler, it can prevent that a sheet-like peeling member becomes high temperature, and the sheet | seat peelability excellent over the long term is maintained.

請求項2に記載のシート状剥離部材は、シート状基材の通紙側表面に形成される樹脂被膜が樹脂塗膜であるので、球状充填材を樹脂被膜内に容易に含有させることが可能である。   In the sheet-like release member according to claim 2, since the resin coating formed on the sheet passing side surface of the sheet-like base material is a resin coating, a spherical filler can be easily contained in the resin coating. It is.

請求項3に記載のシート状剥離部材は、シート状基材の通紙側表面に形成される樹脂塗膜における樹脂成分の膜厚よりも球状充填材の粒子径の方が大きいので、樹脂塗膜から球状充填材が突き出たように形成され、シート状基材表面に球状充填材の凹凸が形成されることにより、シート状基材の放熱性が高くなる。また、用紙との接触面積が小さく用紙との低摩擦特性が優れる。   In the sheet-like release member according to claim 3, since the particle diameter of the spherical filler is larger than the film thickness of the resin component in the resin coating film formed on the sheet passing side surface of the sheet-like base material, The spherical filler is formed so as to protrude from the film, and the irregularity of the spherical filler is formed on the surface of the sheet-like substrate, so that the heat dissipation of the sheet-like substrate is enhanced. Further, the contact area with the paper is small, and the low friction characteristic with the paper is excellent.

請求項4に記載のシート状剥離部材は、樹脂塗膜の樹脂成分の膜厚が5μm〜35μmであるので、球状充填材の保持性がよく、特に球状充填材の粒子径が50μm〜500μmであれば(請求項5)、シート状基材表面に球状充填材の凹凸が明確に形成されるので、低摩擦特性と放熱効果が優れるシート状剥離部材を得ることができる。   In the sheet-like release member according to claim 4, since the film thickness of the resin component of the resin coating film is 5 μm to 35 μm, the retention of the spherical filler is good, and in particular, the particle diameter of the spherical filler is 50 μm to 500 μm. If it exists (Claim 5), since the unevenness | corrugation of a spherical filler is clearly formed in the sheet-like base material surface, the sheet-like peeling member which is excellent in the low friction characteristic and the heat dissipation effect can be obtained.

請求項6に記載のシート状剥離部材は、樹脂被膜に含まれる球状充填材が樹脂被膜1cm2当たり30個〜1800個含まれるので、シート状基材表面に形成される球状充填材の凹凸部にシートが引っ掛かることがなくシートガイド性に優れる効果が得られる。 In the sheet-like release member according to claim 6, since 30 to 1800 spherical fillers contained in the resin coating are contained per 1 cm 2 of the resin coating, the uneven portions of the spherical filler formed on the surface of the sheet-like substrate. The sheet is not caught on the sheet, and an effect of excellent sheet guide property is obtained.

請求項7に記載のシート状剥離部材は、樹脂被膜に含まれる球状充填材が、中空状充填材または粒子状充填材であるので、中空状充填材の場合には放熱効果に優れ、また、粒子状充填材の場合には耐久性に優れる。   In the sheet-like release member according to claim 7, since the spherical filler contained in the resin film is a hollow filler or a particulate filler, in the case of a hollow filler, the heat dissipation effect is excellent. In the case of a particulate filler, the durability is excellent.

請求項10に記載のシート状剥離部材は、シート状基材の先端部の厚さ方向が曲面とされているので、定着ローラや定着ベルト等の定着部材に対して定圧以上の圧接状態になった場合でも定着部材の表面を傷付けることがない。   Since the thickness direction of the front-end | tip part of a sheet-like base material is made into a curved surface, the sheet-like peeling member of Claim 10 will be in the pressure contact state more than fixed pressure with respect to fixing members, such as a fixing roller and a fixing belt. Even in the case of damage, the surface of the fixing member is not damaged.

請求項11に記載のシート状剥離部材は、上記樹脂被膜において、シート状基材の先端部に形成された部分に球状充填材を含まないので、先端部の水平精度が高く維持できる。   Since the sheet-like peeling member according to claim 11 does not include a spherical filler in a portion formed at the tip portion of the sheet-like base material in the resin film, the horizontal accuracy of the tip portion can be maintained high.

請求項12に記載のシート状剥離部材は、シート状基材の反通紙表面を平滑面とするので、支持部材との一体化において精度劣化が発生しない。   Since the sheet-like peeling member according to claim 12 makes the sheet passing surface of the sheet-like base material a smooth surface, accuracy deterioration does not occur in integration with the support member.

請求項13に記載のシート状剥離部材は、シート状基材の表面に含フッ素重合体を主成分とする塗膜が形成されているので、トナーに対する離型性が優れる。   The sheet-like release member according to claim 13 is excellent in releasability with respect to the toner since the coating film mainly containing the fluoropolymer is formed on the surface of the sheet-like substrate.

請求項14に記載のシート状剥離部材は、上記含フッ素重合体が、PTFE重合体、PFA共重合体およびFEP共重合体のうちのいずれかであるので、長時間の使用においてもトナーに対する優れた離型性が維持できる。   The sheet-like release member according to claim 14, wherein the fluoropolymer is any one of a PTFE polymer, a PFA copolymer, and an FEP copolymer. Releasability can be maintained.

本発明の電子写真装置(請求項15)は、現像剤が定着した用紙を定着ローラや定着ベルト等の定着部材から剥離させるための剥離部材に、上記したシート状剥離部材を用いるので、シート剥離性の優れる電子写真装置となる。   The electrophotographic apparatus according to the present invention (Claim 15) uses the above-described sheet-like release member as a release member for releasing the paper on which the developer is fixed from a fixing member such as a fixing roller or a fixing belt. It becomes an electrophotographic apparatus having excellent properties.

請求項16に記載の電子写真装置は、そのシート状剥離部材が粘着性の高いカラートナーに対する離型性に優れるので、フルカラー電子写真装置として好適に採用できる。   The electrophotographic apparatus according to claim 16 can be suitably used as a full-color electrophotographic apparatus because the sheet-like release member is excellent in releasability from highly adhesive color toner.

シート状剥離部材を用いた定着装置の概要図である。It is a schematic diagram of a fixing device using a sheet-like release member. 図2(a)はシート状剥離部材の一例として示す斜視図、図2(b)は図2(a)のC部分の拡大正面図、図2(c)は図2(b)のD−D線で切断した部分拡大断面図である。2A is a perspective view showing an example of a sheet-like peeling member, FIG. 2B is an enlarged front view of a portion C in FIG. 2A, and FIG. 2C is a D- in FIG. 2B. It is the partial expanded sectional view cut | disconnected by D line.

本発明のシート状剥離部材および電子写真装置の一例を図1を参照して説明する。図1はシート状剥離部材を用いた定着装置の概要図である。図1に示すように、定着装置は、ヒータ5aが内蔵され、矢印A方向に回転する定着ローラ5と、この定着ローラ5に接触して矢印B方向に回転する加圧ローラ6と、定着ローラ5および加圧ローラ6が接触して形成されるニップ部7の付近に配置されるシート状剥離部材1とから構成される。定着ローラ5は内部に発泡ゴム層を有するソフトローラである。用紙8上に形成されたトナー像がニップ部7で定着されて定着された画像となる。シート状剥離部材1はニップ部7を通過した用紙8を定着ローラ5から剥離できるように定着ローラ5に接触または近接する位置に設けられている。   An example of the sheet-like peeling member and electrophotographic apparatus of the present invention will be described with reference to FIG. FIG. 1 is a schematic view of a fixing device using a sheet-like peeling member. As shown in FIG. 1, the fixing device includes a heater 5 a, a fixing roller 5 that rotates in the direction of arrow A, a pressure roller 6 that contacts the fixing roller 5 and rotates in the direction of arrow B, and a fixing roller. 5 and the sheet-like peeling member 1 disposed in the vicinity of the nip portion 7 formed by contact with the pressure roller 6. The fixing roller 5 is a soft roller having a foam rubber layer inside. The toner image formed on the paper 8 is fixed at the nip portion 7 and becomes a fixed image. The sheet-like peeling member 1 is provided at a position in contact with or close to the fixing roller 5 so that the paper 8 that has passed through the nip portion 7 can be peeled off from the fixing roller 5.

シート状剥離部材1を図2を参照して詳細に説明する。図2(a)はシート状剥離部材の一例として示す斜視図であり、図2(b)は図2(a)のC部分の拡大正面図であり、図2(c)は図2(b)のD−D線で切断した一部拡大断面図である。図2(a)および図2(c)に示すように、シート状剥離部材1は、取付部4を有する金属製の支持部材3と、金属薄板からなるシート状基材2と、離型層となる樹脂被膜2dとから構成されている。樹脂被膜2dは、球状充填材2cを含んでいる。シート状基材2において、支持部材3と固定される側の反対側面が、用紙が通過する側の表面(通紙側表面)であり、この通紙側表面に上記樹脂被膜2dが形成されている。   The sheet-like peeling member 1 will be described in detail with reference to FIG. 2A is a perspective view showing an example of a sheet-like peeling member, FIG. 2B is an enlarged front view of a portion C in FIG. 2A, and FIG. 2C is FIG. It is a partially expanded sectional view cut | disconnected by the DD line | wire of FIG. As shown in FIGS. 2A and 2C, the sheet-like release member 1 includes a metal support member 3 having an attachment portion 4, a sheet-like substrate 2 made of a thin metal plate, and a release layer. And a resin coating 2d. The resin coating 2d includes a spherical filler 2c. In the sheet-like substrate 2, the side opposite to the side fixed to the support member 3 is the surface (sheet passing side surface) through which the sheet passes, and the resin coating 2d is formed on the sheet passing side surface. Yes.

シート状基材2の一端(固定端)2bは、支持部材3に接着剤または溶接で固定されている。シート状基材2の他端は、自由端(先端)2aとなり、この自由端2aを定着ローラ5に接触または近接する位置に配置して、定着ローラ5から剥がれた用紙8の端部を拾い取る(図1参照)。   One end (fixed end) 2b of the sheet-like substrate 2 is fixed to the support member 3 with an adhesive or welding. The other end of the sheet-like substrate 2 becomes a free end (tip) 2a, and the free end 2a is arranged at a position in contact with or close to the fixing roller 5 to pick up the end portion of the paper 8 peeled off from the fixing roller 5. Take (see FIG. 1).

支持部材3は金属製であり、シート状基材2は、金属製、合成樹脂製、セラミックス製の何れでもよいが、ばね鋼、ステンレス鋼、黄銅等の銅合金、アルミニウム合金等の金属製であれば加工が容易であり安価なため好ましい。   The support member 3 is made of metal, and the sheet-like substrate 2 may be made of metal, synthetic resin, or ceramic, but is made of metal such as spring alloy, copper alloy such as stainless steel or brass, or aluminum alloy. It is preferable if it is easy to process and inexpensive.

シート状基材2の板厚は60〜500μmの範囲が好ましい。60μm未満では強度不足であり、取り扱い時において容易に変形するおそれがある。500μmをこえるとシート状剥離部材1の柔軟性が損なわれ、用紙がシート状剥離部材1に当たったときに排紙方向に用紙を円滑に逃がすことができず、跳ね返りが起こりジャミングの発生原因となるおそれがある。   The sheet thickness of the sheet-like substrate 2 is preferably in the range of 60 to 500 μm. If the thickness is less than 60 μm, the strength is insufficient, and there is a possibility of being easily deformed during handling. If the thickness exceeds 500 μm, the flexibility of the sheet-like peeling member 1 is impaired, and when the paper hits the sheet-like peeling member 1, the paper cannot be smoothly discharged in the paper discharge direction, causing rebound and causing jamming. There is a risk.

シート状基材2の用紙が通過する側の表面の反対側表面(反通紙表面)は、平滑面とすることが好ましい。シート状基材2は、金属製の支持部材3と接着剤または溶接によって一体化するため、シート状基材2の裏面が平滑面であると支持部材3と接着剤または溶接によって一体化する際に密着性が高くなり、特に先端部の水平精度が劣化しない。   It is preferable that the surface opposite to the surface through which the sheet of the sheet-like substrate 2 passes (the anti-sheet passing surface) is a smooth surface. Since the sheet-like substrate 2 is integrated with the metal support member 3 by an adhesive or welding, when the back surface of the sheet-like substrate 2 is a smooth surface, the sheet-like substrate 2 is integrated with the support member 3 by an adhesive or welding. Adhesiveness is improved, and the horizontal accuracy of the tip is not particularly deteriorated.

シート状基材2は、定着ローラ5の軸方向長さと略同じ長さの接触幅を有している。ここで、定着ローラの軸方向長さと略同じ長さとは、少なくとも定着ローラの軸方向長さの半分程度以上であって、定着ローラの軸方向長さと同じか僅かに長くてもよい。   The sheet-like substrate 2 has a contact width that is substantially the same as the axial length of the fixing roller 5. Here, the length substantially the same as the axial length of the fixing roller is at least about half or more of the axial length of the fixing roller, and may be the same as or slightly longer than the axial length of the fixing roller.

樹脂被膜2dは、球状充填材2cが配合された樹脂塗料組成物をシート状基材2の通紙側表面に塗布して形成した樹脂塗膜であることが好ましい。塗膜とすることで、球状充填剤2cを樹脂被膜2d内に容易に含有させることができる。また、樹脂被膜2dは、シート状剥離部材1のトナーに対する離型性を向上させるため、含フッ素重合体を主成分とする樹脂塗膜であることが好ましい。特に、含フッ素重合体として、PTFE重合体、PFA共重合体およびFEP共重合体のうちのいずれかを用いることで、トナーに対する離型性を長時間維持できる。また、本発明ではシート状基材2の放熱性に優れるので、含フッ素重合体を主成分とする樹脂被膜の物性劣化も抑制される。   The resin coating 2d is preferably a resin coating formed by applying a resin coating composition containing a spherical filler 2c to the sheet-passing side surface of the sheet-like substrate 2. By setting it as a coating film, the spherical filler 2c can be easily contained in the resin coating 2d. The resin coating 2d is preferably a resin coating containing a fluoropolymer as a main component in order to improve the releasability of the sheet-like release member 1 with respect to the toner. In particular, by using any one of PTFE polymer, PFA copolymer and FEP copolymer as the fluoropolymer, the releasability with respect to the toner can be maintained for a long time. Moreover, in this invention, since it is excellent in the heat dissipation of the sheet-like base material 2, the physical-property deterioration of the resin film which has a fluoropolymer as a main component is also suppressed.

含フッ素重合体を主成分とする樹脂塗膜を得るための樹脂塗料組成物を得る方法としては、(1)含フッ素重合体粉末を樹脂溶媒に分散してなる樹脂ワニスに、球状充填材を配合して、均一に撹拌する方法や、(2)含フッ素重合体粉末、球状充填材を樹脂溶媒に配合し、均一に撹拌する方法が挙げられる。また、静電気による紙剥離性の低下を防止するため、ケッチェンブラックやアセチレンブラック等のカーボン微粉末を上記樹脂塗料組成物に配合することが好ましい。上記樹脂塗料組成物をシート状基材2の通紙側表面に塗布する方法は、ディッピング法、ローラ塗布法、刷毛塗り法、スプレー塗布法、印刷塗布法など種々の方法を採用することができる。   As a method of obtaining a resin coating composition for obtaining a resin coating film containing a fluoropolymer as a main component, (1) a spherical filler is applied to a resin varnish obtained by dispersing a fluoropolymer powder in a resin solvent. A method of blending and stirring uniformly, and a method of (2) blending a fluoropolymer powder and a spherical filler in a resin solvent and stirring uniformly are mentioned. Further, in order to prevent a decrease in paper peelability due to static electricity, it is preferable to blend carbon fine powders such as ketjen black and acetylene black into the resin coating composition. Various methods such as a dipping method, a roller coating method, a brush coating method, a spray coating method, and a printing coating method can be adopted as a method for applying the resin coating composition to the sheet passing side surface of the sheet-like substrate 2. .

シート状基材2の先端部2eの水平精度を高く維持するため、樹脂被膜2dにおいて、この先端部2eに形成される部分には、球状充填材2cを含まないことが好ましい。このように形成するには、先端部2eにあらかじめ球状充填材2cを含まない樹脂被膜を形成しておき、マスキング等でこの部分を被覆した後、通紙側表面に球状充填材2cを含む樹脂被膜を形成する等の方法によって行なうことができる。なお、シート状基材の先端部とは、電子写真装置の定着部材に接触または近接する部位であり、該シート状基材において定着部材との接触側となる先端から約1mm〜3mmの範囲である。   In order to keep the horizontal accuracy of the tip 2e of the sheet-like substrate 2 high, it is preferable that the portion formed on the tip 2e in the resin coating 2d does not include the spherical filler 2c. In order to form in this way, a resin film not containing the spherical filler 2c is formed in advance on the tip 2e, and after covering this part with masking or the like, the resin containing the spherical filler 2c on the paper passing side surface It can be performed by a method such as forming a film. Note that the front end portion of the sheet-like base material is a portion that is in contact with or close to the fixing member of the electrophotographic apparatus, and is within a range of about 1 mm to 3 mm from the front end that is in contact with the fixing member in the sheet-like base material. is there.

塗膜である樹脂被膜2dの樹脂成分の膜厚は、5μm〜35μmとすることが好ましい。樹脂被膜2dの樹脂成分の膜厚が5μmより薄膜であれば、球状充填材2cの保持性が悪く、球状充填材2cの脱落が生じる。35μmより厚膜であると、樹脂被膜2dの形成工程で割れや吐物等の不具合が発生するおそれがあるため好ましくない。   The film thickness of the resin component of the resin coating 2d that is a coating film is preferably 5 μm to 35 μm. If the film thickness of the resin component of the resin coating 2d is less than 5 μm, the retention of the spherical filler 2c is poor, and the spherical filler 2c falls off. If it is thicker than 35 μm, there is a possibility that defects such as cracks and discharges may occur in the step of forming the resin coating 2d, which is not preferable.

また、球状充填材2cの粒子径は50μm〜500μmとすることが好ましい。球状充填材2cの粒子径が50μmより小径であれば、放熱効果が期待できず、500μmをこえる大径であればシートガイド性が低下する。   The particle diameter of the spherical filler 2c is preferably 50 μm to 500 μm. If the particle diameter of the spherical filler 2c is smaller than 50 μm, the heat dissipation effect cannot be expected, and if it is larger than 500 μm, the sheet guide property is lowered.

樹脂被膜2dにおける樹脂成分の膜厚よりも球状充填材2cの粒子径の方を大きくすることが好ましい。樹脂被膜2dにおける樹脂成分の膜厚よりも球状充填材2cの粒子径を大きくすることで、樹脂被膜2dから球状充填材2cが突き出たように形成され、シート状基材2表面に球状充填材2cの凹凸が明確に形成されることにより、シート状基材2の放熱性が高くなる(図2(c)参照)。また、用紙との接触面積が小さく用紙との低摩擦特性が優れる。なお、樹脂製の球状充填材を使用する場合であっても樹脂製球状充填材は樹脂被膜(塗膜)における樹脂成分に該当しないこととする。   It is preferable to make the particle diameter of the spherical filler 2c larger than the film thickness of the resin component in the resin coating 2d. By making the particle diameter of the spherical filler 2c larger than the film thickness of the resin component in the resin coating 2d, the spherical filler 2c is formed so as to protrude from the resin coating 2d, and the spherical filler is formed on the surface of the sheet-like substrate 2 When the unevenness of 2c is clearly formed, the heat dissipation of the sheet-like substrate 2 is increased (see FIG. 2C). Further, the contact area with the paper is small, and the low friction characteristic with the paper is excellent. Even when a resin spherical filler is used, the resin spherical filler does not correspond to the resin component in the resin coating (coating film).

樹脂被膜2d中の球状充填材2cは、樹脂被膜1cm2当たり30個〜1800個含有させることが好ましい。球状充填材2cが樹脂被膜1cm2当たり30個未満であるとシートガイド性が低下するおそれがあり、1800個をこえる場合では球状充填材2cの凹凸が明確に形成されず放熱効果が期待できない。 It is preferable to contain 30 to 1800 spherical fillers 2c in the resin coating 2d per 1 cm 2 of the resin coating. If the number of the spherical fillers 2c is less than 30 per 1 cm 2 of the resin coating, the sheet guiding property may be deteriorated.

球状充填材2cは、中空状充填材または粒子状充填材であることが好ましい。中空状充填材を用いることで樹脂被膜2dの放熱効果を向上でき、粒子状充填材を用いることで樹脂被膜2dの耐久性を向上できる。中空状充填材としては、樹脂バルーン、セラミックバルーン、シラスバルーンまたはガラスバルーンが好ましく、粒子状充填材としては、樹脂ビーズ、セラミックスビーズ、シリカビーズ、ガラスビーズまたはカーボンビーズが好ましい。これらの球状充填材は放熱効果が優れており、上述の粒子径50μm〜500μmのものが製造可能であり、さらに安価であるため好ましい。   The spherical filler 2c is preferably a hollow filler or a particulate filler. By using the hollow filler, the heat dissipation effect of the resin coating 2d can be improved, and by using the particulate filler, the durability of the resin coating 2d can be improved. The hollow filler is preferably a resin balloon, ceramic balloon, shirasu balloon or glass balloon, and the particulate filler is preferably resin beads, ceramic beads, silica beads, glass beads or carbon beads. These spherical fillers are preferable because they have an excellent heat dissipation effect, can be manufactured with the above-mentioned particle diameter of 50 μm to 500 μm, and are inexpensive.

シート状基材2の先端部2eの厚さ方向を、エッジのない曲面とすることが好ましい(図2(c)参照)。先端部の厚さ方向を曲面とすることで、定着ローラや定着ベルト等の定着部材に対して定圧以上の圧接状態になった場合でも定着部材の表面を傷付けることがない。上記曲面は金属製のシート状基材2を所定形状に加工した後で機械加工してもよいが、カッティングと同時に加圧成形することができるプレスカットにより加工することが望ましい。プレスカットにより先端部2eのプレス方向側のエッジはプレスダレによってR形状を形成するとともに、反プレス方向側のエッジは微小なバリの発生を防ぐために基材表面に対し45°傾斜したプレス板を押し付けることで面取り部を形成でき、先端部2eを曲面とできる。また、金属製のシート状基材において、先端部の厚さ方向の形状は、切断する際のダレ面を通紙側に設定し、バリ取りを片面だけしたものであってもよい。   It is preferable to make the thickness direction of the front-end | tip part 2e of the sheet-like base material 2 into a curved surface without an edge (refer FIG.2 (c)). By making the thickness direction of the tip part a curved surface, the surface of the fixing member is not damaged even when the pressure member is in a pressure contact state higher than a constant pressure with respect to a fixing member such as a fixing roller or a fixing belt. The curved surface may be machined after the metal sheet-like base material 2 is processed into a predetermined shape, but it is desirable to process by a press cut that can be pressure-formed simultaneously with cutting. The edge on the pressing direction side of the front end portion 2e is formed into an R shape by press sag by press cutting, and the edge on the anti-pressing direction side presses a press plate inclined by 45 ° with respect to the substrate surface in order to prevent generation of minute burrs. Thus, a chamfered portion can be formed, and the distal end portion 2e can be a curved surface. Further, in the metal sheet-like base material, the shape in the thickness direction of the tip portion may be set such that the sagging surface at the time of cutting is set to the paper side, and deburring is performed only on one side.

フルカラー電子写真装置では、発色性を向上させるため、カラートナーの構成要素の一つであるバインダー(結着)樹脂として、透明度の高いポリエステル系バインダー樹脂などを用いる。この樹脂は、非常に粘着性の高いものである。本発明のシート状剥離部材は、シート状基材の通紙側表面に、球状充填材が配合された含フッ素重合体を主成分とする樹脂塗膜を形成することで、このようなカラートナーの付着を長期にわたり防止できるため、フルカラー電子写真装置にも好適に利用できる。   In a full-color electrophotographic apparatus, a polyester-based binder resin having high transparency is used as a binder (binding) resin that is one of the constituent elements of color toner in order to improve color developability. This resin is very sticky. The sheet-like release member of the present invention forms such a color toner by forming on the surface of the sheet-like base material the paper passing side by forming a resin coating film mainly composed of a fluoropolymer compounded with a spherical filler. Can be suitably used for a full-color electrophotographic apparatus.

本発明の電子写真装置のシート状剥離部材は、通紙側表面に、球状充填材が配合された樹脂被膜を形成した構成であるので、用紙との接触面積が小さく用紙との低摩擦特性および放熱性に優れる。このため、定着部材が200℃以上の高温となるような条件で使用される、高速・フルカラー等の電子写真装置のシート状剥離部材として好適に利用できる。   Since the sheet-like release member of the electrophotographic apparatus of the present invention has a structure in which a resin film in which a spherical filler is blended is formed on the paper passing side surface, the contact area with the paper is small, and the low friction characteristic with the paper and Excellent heat dissipation. For this reason, the fixing member can be suitably used as a sheet-like peeling member of a high-speed, full-color electrophotographic apparatus that is used under conditions where the fixing member has a high temperature of 200 ° C. or higher.

1 シート状剥離部材
2 シート状基材
2a 自由端(先端)
2b 固定端
2c 球状充填材
2d 樹脂被膜(塗膜)
2e 先端部
3 支持部材
4 取付部
5 定着ローラ
6 加圧ローラ
7 ニップ部
8 用紙
DESCRIPTION OF SYMBOLS 1 Sheet-like peeling member 2 Sheet-like base material 2a Free end (tip)
2b Fixed end 2c Spherical filler 2d Resin coating (coating)
2e Tip part 3 Support member 4 Mounting part 5 Fixing roller 6 Pressure roller 7 Nip part 8 Paper

Claims (15)

電子写真装置の定着部材にシート状基材の先端部を接触または近接させて、定着部材から用紙を剥離させるシート状剥離部材において、
前記シート状基材の用紙が通過する側の表面に、球状充填材を含む樹脂被膜が形成され
前記樹脂被膜において、前記シート状基材の先端部に形成された部分には前記球状充填材を含まないことを特徴とする電子写真装置のシート状剥離部材。
In the sheet-like peeling member that peels the sheet from the fixing member by bringing the leading end of the sheet-like base material into contact with or close to the fixing member of the electrophotographic apparatus,
A resin film containing a spherical filler is formed on the surface of the sheet-like base material on which the paper passes ,
The sheet-like release member of an electrophotographic apparatus, wherein the resin coating does not include the spherical filler in a portion formed at a tip portion of the sheet-like base material .
前記樹脂被膜は、樹脂塗膜であることを特徴とする請求項1記載の電子写真装置のシート状剥離部材。   The sheet-like release member of an electrophotographic apparatus according to claim 1, wherein the resin coating is a resin coating. 前記樹脂塗膜における樹脂成分の膜厚よりも前記球状充填材の粒子径の方が大きいことを特徴とする請求項2記載の電子写真装置のシート状剥離部材。   3. The sheet-like release member for an electrophotographic apparatus according to claim 2, wherein the spherical filler has a larger particle diameter than the film thickness of the resin component in the resin coating film. 前記樹脂塗膜の樹脂成分の膜厚は、5μm〜35μmであることを特徴とする請求項2または請求項3記載の電子写真装置のシート状剥離部材。   4. The sheet-like release member for an electrophotographic apparatus according to claim 2, wherein the resin component of the resin coating film has a thickness of 5 to 35 [mu] m. 前記球状充填材は、粒子径50μm〜500μmの球状充填材であることを特徴とする請求項1ないし請求項4のいずれか一項記載の電子写真装置のシート状剥離部材。   The sheet-like release member for an electrophotographic apparatus according to any one of claims 1 to 4, wherein the spherical filler is a spherical filler having a particle diameter of 50 µm to 500 µm. 前記球状充填材は、前記樹脂被膜1cm2当たり30個〜1800個含まれることを特徴とする請求項1ないし請求項5のいずれか一項記載の電子写真装置のシート状剥離部材。 6. The sheet-like release member for an electrophotographic apparatus according to claim 1, wherein 30 to 1800 spherical fillers are contained per 1 cm 2 of the resin coating. 前記球状充填材は、中空状充填材または粒子状充填材であることを特徴とする請求項1ないし請求項6のいずれか一項記載の電子写真装置のシート状剥離部材。   The sheet-like peeling member for an electrophotographic apparatus according to any one of claims 1 to 6, wherein the spherical filler is a hollow filler or a particulate filler. 前記中空状充填材は、樹脂バルーン、セラミックバルーン、シラスバルーンまたはガラスバルーンのいずれかであることを特徴とする請求項7記載の電子写真装置のシート状剥離部材。   8. The sheet-like peeling member for an electrophotographic apparatus according to claim 7, wherein the hollow filler is any one of a resin balloon, a ceramic balloon, a shirasu balloon, and a glass balloon. 前記粒子状充填材は、樹脂ビーズ、セラミックスビーズ、シリカビーズ、ガラスビーズまたはカーボンビーズのいずれかであることを特徴とする請求項7記載の電子写真装置のシート状剥離部材。   8. The sheet-like release member for an electrophotographic apparatus according to claim 7, wherein the particulate filler is any one of resin beads, ceramic beads, silica beads, glass beads, and carbon beads. 前記シート状基材の先端部の厚さ方向は、曲面とされていることを特徴とする請求項1ないし請求項9のいずれか一項記載の電子写真装置のシート状剥離部材。   The sheet-like peeling member of an electrophotographic apparatus according to any one of claims 1 to 9, wherein a thickness direction of a tip portion of the sheet-like substrate is a curved surface. 前記シート状基材の用紙が通過する側の表面の反対側表面が平滑面であることを特徴とする請求項1ないし請求項10のいずれか一項記載の電子写真装置のシート状剥離部材。 The sheet-like peeling member of an electrophotographic apparatus according to any one of claims 1 to 10 , wherein the surface of the sheet-like substrate opposite to the surface through which the paper passes is a smooth surface. 前記樹脂塗膜は、含フッ素重合体を主成分とすることを特徴とする請求項2ないし請求項11のいずれか一項記載の電子写真装置のシート状剥離部材。 The sheet-like release member of an electrophotographic apparatus according to any one of claims 2 to 11 , wherein the resin coating film contains a fluoropolymer as a main component. 前記含フッ素重合体が、ポリテトラフルオロエチレン重合体、テトラフルオロエチレン−パーフルオロアルキルビニルエーテル共重合体およびテトラフルオロエチレン−ヘキサフルオロプロピレン共重合体のうちのいずれかであることを特徴とする請求項12記載の電子写真装置のシート状剥離部材。 The fluoropolymer is any one of a polytetrafluoroethylene polymer, a tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer, and a tetrafluoroethylene-hexafluoropropylene copolymer. 12. A sheet-like peeling member for an electrophotographic apparatus according to 12 . 現像剤が定着した用紙を定着部材から剥離させるためのシート状剥離部材を有する電子写真装置であって、前記シート状剥離部材は、請求項1ないし請求項13のいずれか一項記載のシート状剥離部材であることを特徴とする電子写真装置。 A electrophotographic apparatus having a sheet-like peeling member for peeling the sheet on which the developer has been fixed from fixing member, the sheet separation member is a sheet-like according to one of claims 1 to 13 An electrophotographic apparatus which is a peeling member. 前記電子写真装置は、カラートナーを用いるフルカラー電子写真装置であることを特徴とする請求項14記載の電子写真装置。 The electrophotographic apparatus according to claim 14 , wherein the electrophotographic apparatus is a full color electrophotographic apparatus using color toner.
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