JP5394635B2 - Cleaning additive and method for producing the same - Google Patents
Cleaning additive and method for producing the same Download PDFInfo
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Description
本発明は、化粧水、液体ソープ、シャンプー、入浴剤、歯磨き剤、浴槽や流し台洗浄剤等の家庭用洗浄剤又は医療機械器具用洗浄剤と共に使用される洗浄添加剤及びその製造方法に関する。 The present invention relates to a cleaning additive used together with a cleaning agent for household use such as a lotion, a liquid soap, a shampoo, a bath agent, a dentifrice, a bath or a sink cleaning agent, and a cleaning agent for medical equipment, and a method for producing the same.
光触媒活性物質の代表的な例としては、二酸化チタン（ＴｉＯ２）がよく知られている。粉末状の二酸化チタンを液体中に入れて光を照射すると、水の分解反応が進行し、液体中の水分が水素と酸素とに分解される。光触媒は、このような強力な酸化作用、還元作用により、殺菌、有害物質の分解、消臭等の浄化作用を発揮することができる。そこで、このような効果を利用して、従来から光触媒活性物質を含有させた洗浄剤が知られている（例えば、特許文献１）。
しかしながら、上記した従来の光触媒活性物質を含有する洗浄剤は、製造後長い時間に亘って光触媒活性物質が水分を含む洗浄剤中に置かれてしまうため、上記の作用が減退してしまうという問題があった。 However, the above-described conventional cleaning agent containing a photocatalytically active substance has a problem in that the above-mentioned action is reduced because the photocatalytically active substance is placed in a cleaning agent containing moisture for a long time after the production. was there.
一方、使用する直前に洗浄剤に光触媒活性物質を添加すれば、より少量の光触媒活性物質で、より大きな作用効果を発揮し得ることが確認された。 On the other hand, it was confirmed that if a photocatalytically active substance is added to the cleaning agent immediately before use, a greater effect can be achieved with a smaller amount of the photocatalytically active substance.
そこで本発明は、上記状況に鑑みて、化粧水、シャンプー、入浴剤、歯磨き剤、浴槽や流し台洗浄剤等の家庭用洗浄剤又は医療機械器具用洗浄剤に使用直前に添加して使用できる洗浄添加剤及びその製造方法を提供することを目的とする。 Therefore, in view of the above situation, the present invention is a cleaning that can be used by adding to a cleaning agent for household use such as a lotion, a shampoo, a bath agent, a toothpaste, a bathtub or a sink cleaning agent, or a cleaning agent for medical equipment immediately before use. It aims at providing an additive and its manufacturing method.
本発明は、上記課題を解決するために、少なくとも、二酸化チタン粒子と、炭酸ナトリウム粒子と、炭酸水素ナトリウム粒子と、を含有し、各粒子が粉状に粉砕混合され、洗浄剤と混ぜ合わされて使用され、前記二酸化チタン粒子は、アパタイトにより被覆された複合体粒子であり、さらに、トリポリ燐酸ナトリウム、クエン酸、サイクロデキストリン、メタ珪酸ナトリウム及び珪酸カルシウムが添加されており、前記複合体粒子の重量成分比は、０．３乃至１．０％であり、前記炭酸ナトリウム粒子と前記炭酸水素ナトリウム粒子の重量成分比は、それぞれ２０乃至３０％であることを特徴とする洗浄添加剤を提供する。 In order to solve the above problems, the present invention contains at least titanium dioxide particles, sodium carbonate particles, and sodium hydrogen carbonate particles, and each particle is pulverized and mixed in a powder form and mixed with a cleaning agent. The titanium dioxide particles used are composite particles coated with apatite, and further added with sodium tripolyphosphate, citric acid, cyclodextrin, sodium metasilicate and calcium silicate, and the weight of the composite particles A cleaning additive is provided , wherein a component ratio is 0.3 to 1.0%, and a weight component ratio of the sodium carbonate particles and the sodium hydrogen carbonate particles is 20 to 30%, respectively .
さらに、前記洗浄剤は、洗浄用化粧水、液体ソープ、シャンプー、入浴剤、歯磨き剤、家庭用一般洗浄剤又は医療機械器具用洗浄剤であるのが好適である。 Further, the cleaning agent is preferably cleaning lotion, liquid soap, shampoo, bathing agent, toothpaste, household general cleaning agent or cleaning device for medical equipment.
一方、本発明は、上記課題を解決するために、二酸化チタン粒子、炭酸ナトリウム粒子及び炭酸水素ナトリウム粒子を混合する工程と、トリポリ燐酸ナトリウム、クエン酸、サイクロデキストリン、メタ珪酸ナトリウム及び珪酸カルシウムを添加する工程と、前記二酸化チタン粒子、炭酸ナトリウム粒子及び炭酸水素ナトリウム粒子と、トリポリ燐酸ナトリウム、クエン酸、サイクロデキストリン、メタ珪酸ナトリウム及び珪酸カルシウムと、の混合物を粉砕し、前記粒子の直径を少なくとも１００μメートル以下にする工程と、の各工程を有し、前記二酸化チタン粒子は、アパタイトにより被覆された複合体粒子であり、前記複合体粒子の重量成分比は、０．３乃至１．０％であり、前記炭酸ナトリウム粒子と前記炭酸水素ナトリウム粒子の重量成分比は、それぞれ２０乃至３０％であることを特徴とする、洗浄剤と混ぜ合わされて使用される洗浄添加剤の製造方法を提供する。 On the other hand, the present invention adds a step of mixing titanium dioxide particles, sodium carbonate particles and sodium hydrogen carbonate particles and adding sodium tripolyphosphate, citric acid, cyclodextrin, sodium metasilicate and calcium silicate in order to solve the above problems. Crushing a mixture of the titanium dioxide particles, sodium carbonate particles and sodium hydrogen carbonate particles and sodium tripolyphosphate, citric acid, cyclodextrin, sodium metasilicate and calcium silicate, and the diameter of the particles is at least 100 μm. possess a step of meters below the steps of the titanium dioxide particles are composite particles coated with apatite, the weight ratio of components of said composite particles is 0.3 to 1.0% The sodium carbonate particles and the sodium hydrogen carbonate particles Weight ratio of components, characterized in that it is a 20 to 30%, respectively, to provide a method for manufacturing a detergent and commingled with cleaning additives used.
さらに、前記洗浄剤は、洗浄用化粧水、液体ソープ、シャンプー、入浴剤、歯磨き剤、家庭用一般洗浄剤又は医療機械器具用洗浄剤であるのが好適である。 Further, the cleaning agent is preferably cleaning lotion, liquid soap, shampoo, bathing agent, toothpaste, household general cleaning agent or cleaning device for medical equipment.
本発明の洗浄添加剤及びその製造方法によれば、シャンプー、液体ソープ、入浴剤、歯磨き剤、浴槽や流し台洗浄剤又は医療機械器具用洗浄剤等の家庭用洗浄剤に添加することにより、洗浄剤の効果に加えてアパタイトに被覆された光触媒の殺菌、有害物質の分解、消臭効果を発揮させることができる。また、本発明の洗浄添加剤は使用直前に各種洗浄剤に添加されることによって、より少量の光触媒活性物質で、より大きな作用効果を発揮することができる。 According to the cleaning additive of the present invention and the method for producing the same, cleaning is performed by adding to household cleaning agents such as shampoos, liquid soaps, bathing agents, dentifrices, bath and sink cleaning agents, or cleaning agents for medical equipment. In addition to the effect of the agent, the sterilization of the photocatalyst coated with apatite, the decomposition of harmful substances, and the deodorizing effect can be exhibited. Moreover, the cleaning additive of the present invention can exert a larger effect with a smaller amount of photocatalytically active substance by being added to various cleaning agents immediately before use.
以下、本発明の実施の形態について、図面を参照しながら詳細に説明する。 Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.
図１は、本発明の一実施形態に係る洗浄添加剤の成分表である。図１に示すように、本発明の洗浄添加剤は少なくとも二酸化チタン又はアパタイトに被覆された二酸化チタンの複合体を重量比にして０．３〜１．０％、炭酸ナトリウムを２０〜３０％、炭酸水素ナトリウムを２０〜３０％含有した粉末である。このほか、サイクロデキストリンを４〜５％、トリポリ燐酸ナトリウムとクエン酸を４０〜５０％、メタ珪酸ナトリウムを４〜５％、珪酸カルシウムを０．３％、さらに含有している。 FIG. 1 is a component table of cleaning additives according to an embodiment of the present invention. As shown in FIG. 1, the cleaning additive of the present invention is at least 0.3 to 1.0% by weight of titanium dioxide or a composite of titanium dioxide coated with apatite, 20 to 30% sodium carbonate, It is a powder containing 20-30% sodium hydrogen carbonate. In addition, it contains 4 to 5% cyclodextrin, 40 to 50% sodium tripolyphosphate and citric acid, 4 to 5% sodium metasilicate, and 0.3% calcium silicate.
この洗浄添加剤は、使用直前にその都度各種洗浄剤に適量混合して使用される。各種洗浄剤とは、例えば、化粧水、液体ソープ、シャンプー、入浴剤、歯磨き剤、家庭一般洗浄剤又は医療機械器具用洗浄剤等を指すが、光触媒の殺菌作用、有害物質の分解作用、消臭作用等が活かされるものならば何であっても良い。例えばシャンプーに添加すれば頭皮の皮脂汚れを分解すると共に消臭することができる。また歯磨き剤に添加すれば煙草のヤニや飲食物等による着色、及び歯石等を分解し、さらに口臭を除去することもできる。 This cleaning additive is used by mixing it with various cleaning agents each time just before use. Examples of various cleaning agents include lotions, liquid soaps, shampoos, bathing agents, toothpastes, household general cleaning agents, and cleaning agents for medical equipment, and the like. Anything can be used as long as the odor effect is utilized. For example, if it is added to a shampoo, it can decompose and deodorize sebum stains on the scalp. If it is added to a dentifrice, it can decompose cigarettes, coloring caused by food and drinks, tartar, etc., and remove bad breath.
なお、炭酸ナトリウムと炭酸水素ナトリウムに代えて、溶解性の高いセスキ炭酸ナトリウム（炭酸ナトリウムと炭酸水素ナトリウムを混合し結晶化させたもの）を用いても良い。 Instead of sodium carbonate and sodium bicarbonate, sodium sesquicarbonate (highly soluble and crystallized by mixing sodium carbonate and sodium bicarbonate) may be used.
次に、上記した洗浄添加剤の製造方法について説明する。
（ａ）まず、計量した酸化チタン粒子、炭酸ナトリウム粒子、炭酸水素ナトリウム粒子を混合する。
Next, a method for manufacturing the above-described cleaning additive will be described.
(A) First, weighed titanium oxide particles, sodium carbonate particles, and sodium hydrogen carbonate particles are mixed.
（ｂ）次に、計量したトリポリ燐酸ナトリウム、クエン酸、サイクロデキストリン、メタ珪酸ナトリウム、珪酸カルシウムを（ａ）の混合物に添加する。 (B) Next, weighed sodium tripolyphosphate, citric acid, cyclodextrin, sodium metasilicate, calcium silicate are added to the mixture of (a).
（ｃ）そして（ｂ）の混合物を粉砕機により粉砕し、粒径が１００μメートル以下になるようにする。 The mixture of (c) and (b) is pulverized by a pulverizer so that the particle size is 100 μm or less.
このように、本発明によれば化粧水、シャンプー、液体ソープ、入浴剤、歯磨き剤、浴槽や流し台洗浄剤又は医療機械器具用洗浄剤等の家庭用洗浄剤に添加することにより、洗浄剤の効果に加えて光触媒の殺菌、有害物質の分解、消臭効果を発揮させることができる。また、本発明の洗浄添加剤は使用直前に各種洗浄剤に添加されることによって、より少量の光触媒活性物質で、より大きな作用効果を発揮することができる。 Thus, according to the present invention, by adding to a cleaning agent for household use such as a lotion, shampoo, liquid soap, bath preparation, toothpaste, bathtub or sink cleaning agent or cleaning device for medical equipment, In addition to the effects, the photocatalyst can be sterilized, harmful substances decomposed, and deodorized. Moreover, the cleaning additive of the present invention can exert a larger effect with a smaller amount of photocatalytically active substance by being added to various cleaning agents immediately before use.
以上、本発明の実施形態について説明したが、本発明は上記実施形態に限定されるものではなく、本発明の趣旨に基づき種々の変形が可能であり、これらを本発明の範囲から排除するものではない。 As mentioned above, although embodiment of this invention was described, this invention is not limited to the said embodiment, Based on the meaning of this invention, various deformation | transformation are possible, These are excluded from the scope of the present invention. is not.
本発明は、化粧水、液体ソープ、シャンプー、入浴剤、歯磨き剤、浴槽や流し台洗浄剤等の家庭用洗浄剤又は医療機械器具用洗浄剤と共に使用される洗浄添加剤及びその製造方法に関するものであり、産業上の利用可能性を有する。 The present invention relates to a cleaning additive used together with a cleaning agent for household use such as a lotion, a liquid soap, a shampoo, a bath agent, a dentifrice, a bath or a sink cleaning agent, and a cleaning agent for medical equipment, and a method for producing the same. Yes, it has industrial applicability.
Claims (4)
前記二酸化チタン粒子は、アパタイトにより被覆された複合体粒子であり、
さらに、トリポリ燐酸ナトリウム、クエン酸、サイクロデキストリン、メタ珪酸ナトリウム及び珪酸カルシウムが添加されており、
前記複合体粒子の重量成分比は、０．３乃至１．０％であり、
前記炭酸ナトリウム粒子と前記炭酸水素ナトリウム粒子の重量成分比は、それぞれ２０乃至３０％であることを特徴とする洗浄添加剤。 At least titanium dioxide particles, sodium carbonate particles, and sodium hydrogen carbonate particles are contained, and each particle is pulverized and mixed into a powder, mixed with a cleaning agent, and used .
The titanium dioxide particles are composite particles coated with apatite,
In addition, sodium tripolyphosphate, citric acid, cyclodextrin, sodium metasilicate and calcium silicate are added,
The weight ratio of the composite particles is 0.3 to 1.0%,
A cleaning additive , wherein the weight component ratio of the sodium carbonate particles and the sodium hydrogen carbonate particles is 20 to 30%, respectively .
トリポリ燐酸ナトリウム、クエン酸、サイクロデキストリン、メタ珪酸ナトリウム及び珪酸カルシウムを添加する工程と、
前記二酸化チタン粒子、炭酸ナトリウム粒子及び炭酸水素ナトリウム粒子と、トリポリ燐酸ナトリウム、クエン酸、サイクロデキストリン、メタ珪酸ナトリウム及び珪酸カルシウムと、の混合物を粉砕し、前記粒子の直径を少なくとも１００μメートル以下にする工程と、
の各工程を有し、
前記二酸化チタン粒子は、アパタイトにより被覆された複合体粒子であり、
前記複合体粒子の重量成分比は、０．３乃至１．０％であり、
前記炭酸ナトリウム粒子と前記炭酸水素ナトリウム粒子の重量成分比は、それぞれ２０乃至３０％であることを特徴とする、洗浄剤と混ぜ合わされて使用される洗浄添加剤の製造方法。 Mixing titanium dioxide particles, sodium carbonate particles and sodium bicarbonate particles;
Adding sodium tripolyphosphate, citric acid, cyclodextrin, sodium metasilicate and calcium silicate;
Grinding a mixture of the titanium dioxide particles, sodium carbonate particles and sodium hydrogen carbonate particles and sodium tripolyphosphate, citric acid, cyclodextrin, sodium metasilicate and calcium silicate to reduce the diameter of the particles to at least 100 μm or less Process,
Possess the steps of,
The titanium dioxide particles are composite particles coated with apatite,
The weight ratio of the composite particles is 0.3 to 1.0%,
The method for producing a cleaning additive used in combination with a cleaning agent, wherein the weight component ratio of the sodium carbonate particles and the sodium hydrogen carbonate particles is 20 to 30%, respectively .
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| KR101221074B1 (en) * | 2012-07-06 | 2013-01-11 | 주식회사 시라이트 | Natural anti-bacterial toothpaste composition containing improvement in tooth pain, antibacterial mouth and nerve stability |
| JP6431251B2 (en) * | 2013-02-13 | 2018-11-28 | 株式会社メディプラス製薬 | Teeth whitening agent and whitening method |
| JP7201975B2 (en) * | 2017-11-07 | 2023-01-11 | タイレックス工業株式会社 | Quantum catalyst manufacturing method |
| DE102018220966A1 (en) * | 2018-12-04 | 2020-06-04 | Henkel Ag & Co. Kgaa | DEODORANT COMPOSITIONS INCLUDING CALCIUM SILICATE AND SODIUM BICARBONATE |
| JP7463047B1 (en) | 2023-09-01 | 2024-04-08 | 小林製薬株式会社 | Oral appliance cleaner |
| JP7502577B1 (en) | 2024-03-13 | 2024-06-18 | 小林製薬株式会社 | Oral appliance cleaner for effervescent tablets |
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| JPH029811A (en) * | 1988-06-28 | 1990-01-12 | Lion Corp | Bathing agent composition |
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| GB9216454D0 (en) * | 1992-08-03 | 1992-09-16 | Ici Plc | Detergent compositions |
| GB9500746D0 (en) * | 1995-01-14 | 1995-03-08 | Procter & Gamble | Oral compositions |
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