JP5389844B2 - Production method of brown rice tea - Google Patents
Production method of brown rice tea Download PDFInfo
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- JP5389844B2 JP5389844B2 JP2011032303A JP2011032303A JP5389844B2 JP 5389844 B2 JP5389844 B2 JP 5389844B2 JP 2011032303 A JP2011032303 A JP 2011032303A JP 2011032303 A JP2011032303 A JP 2011032303A JP 5389844 B2 JP5389844 B2 JP 5389844B2
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- brown rice
- tea
- amino acid
- extract
- rice
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Landscapes
- Tea And Coffee (AREA)
- Non-Alcoholic Beverages (AREA)
Description
本発明は、優れた香味を有する玄米茶飲料の製造方法に関する。 The present invention relates to a method for producing a brown rice tea beverage having an excellent flavor.
従来から、玄米の持つ風味を活かした玄米茶飲料が多くの人に好まれ、飲用されている。玄米茶飲料は、一般に、精白米を蒸し、乾燥し、焙じた米(「炒り米茶」というが、本明細書中、便宜的に「玄米」と表記することもある)と緑茶を混合したものを熱水等で抽出して得られるものであり、玄米の香ばしい香りと緑茶の香味の調和のとれたものが嗜好の高い玄米茶飲料として知られている。 Traditionally, brown rice tea beverages that take advantage of the flavor of brown rice have been favored and drunk by many people. Brown rice tea drinks are generally mixed with steamed, dried, and roasted rice (referred to as “brown rice tea” in this specification for convenience) and green tea. A product obtained by extracting a product with hot water or the like, and a harmonious scent of brown rice and the flavor of green tea are known as highly-preferred brown rice tea beverages.
玄米茶の種類は、緑茶の茶種の違いにより分類されており、例えば、煎茶玄米茶、玉露玄米茶、焙じ玄米茶等がある。また、従来とは違った嗜好性の高い玄米茶飲料を得るために、米麹の甘味と香りを玄米に付加した発酵玄米を用いた玄米茶も提案されている(特許文献1)。 The types of brown rice tea are classified according to the type of green tea, for example, Sencha brown rice tea, Gyokuro brown rice tea, roasted brown rice tea, and the like. In addition, in order to obtain a brown rice tea beverage having a high palatability unlike conventional ones, a brown rice tea using fermented brown rice in which the sweetness and scent of rice bran is added to brown rice has also been proposed (Patent Document 1).
容器詰め玄米茶飲料では、抽出時や保存時に、原料の玄米が含有する澱粉が溶出されやすく、また加熱殺菌や冷蔵状態の保存などの熱履歴の影響もあり、香味の調和がくずれやすいという問題を有している。 In container-packed brown rice tea beverages, the starch contained in the raw brown rice tends to be eluted during extraction and storage, and there is also the effect of heat history such as heat sterilization and storage in the refrigerated state, and the harmony of the flavor tends to be lost. have.
本発明は、香ばしい香りと甘味やコク味が増強され、玄米本来の持つ香ばしさがバランスよく調和された玄米茶用玄米の製造方法、特に容器詰め玄米茶飲料の製造に有利な玄米茶用玄米を提供することを目的とする。 The present invention relates to a method for producing brown rice for brown rice tea, in which the fragrance, sweetness and richness are enhanced, and the original aroma of brown rice is harmonized in a balanced manner. The purpose is to provide.
玄米茶の香味は、緑茶の種類により決定され、玄米は香ばしい香りを出すためのブレンド材料として位置づけられているに過ぎない。本発明者らは、上記課題を解決すべく、玄米の香味を特徴づけるため、玄米の加工法について鋭意検討した結果、玄米に特定のアミノ酸(ロイシン、バリン及びイソロイシンからなる群から選ばれる少なくとも1種以上のアミノ酸)を含む水溶液を含浸させた後、100〜200℃の温度で焙煎することで、玄米の香味に特徴を持たせることができ、従来とは違った嗜好性の高い玄米茶が得られることを見出し、本発明を完成するに至った。 The flavor of brown rice tea is determined by the type of green tea, and brown rice is only positioned as a blend material for producing a fragrant scent. In order to solve the above-mentioned problems, the present inventors have intensively studied the processing method of brown rice in order to characterize the flavor of brown rice, and as a result, at least 1 selected from the group consisting of a specific amino acid (leucine, valine and isoleucine) in brown rice. After impregnating an aqueous solution containing amino acids of at least seeds, roasting at a temperature of 100 to 200 ° C., the flavor of brown rice can be characterized, and the brown rice tea has a higher taste than conventional. Has been found, and the present invention has been completed.
すなわち、本発明は、以下に限定されるものではないが、次の発明を包含する。
(1) ロイシン、バリン及びイソロイシンからなる群から選ばれる少なくとも1種以上のアミノ酸を含有するアミノ酸水溶液を玄米に含浸させる工程、および、浸透処理した玄米を100〜200℃の温度で焙煎処理する工程、を含む、玄米茶用玄米の製造方法。
(2) 原料玄米1kgあたり45mg以上のアミノ酸(A)を添加する、(1)に記載の製造方法。
(3) アミノ酸水溶液が、緑茶葉の抽出液である、(1)又は(2)に記載の製造方法。
(4) 緑茶葉の抽出液が酵素処理を施したものである、(3)に記載の製造方法。
(5) ロイシン、バリン及びイソロイシンからなる群から選ばれる少なくとも1種以上のアミノ酸(A)を含有するアミノ酸水溶液を原料玄米に含浸させる工程、浸透処理した玄米を100〜200℃の温度で焙煎処理する工程、焙煎処理した玄米と緑茶とを重量比2:8〜8:2で混合する工程、および、焙煎処理した玄米と緑茶の混合物1重量部に対して5〜150重量部の水で抽出する工程、を含む、玄米茶飲料の製造方法。
That is, the present invention includes, but is not limited to, the following inventions.
(1) A step of impregnating brown rice with an aqueous amino acid solution containing at least one amino acid selected from the group consisting of leucine, valine and isoleucine, and roasting the brown rice subjected to infiltration treatment at a temperature of 100 to 200 ° C. The manufacturing method of the brown rice for brown rice tea including a process.
(2) The production method according to (1), wherein 45 mg or more of amino acid (A) is added per 1 kg of raw brown rice.
(3) The production method according to (1) or (2), wherein the aqueous amino acid solution is an extract of green tea leaves.
(4) The production method according to (3), wherein the green tea leaf extract is subjected to an enzyme treatment.
(5) A step of impregnating raw rice with an aqueous amino acid solution containing at least one amino acid (A) selected from the group consisting of leucine, valine and isoleucine, roasting the brown rice subjected to infiltration treatment at a temperature of 100 to 200 ° C 5 to 150 parts by weight with respect to 1 part by weight of the step of treating, the step of mixing roasted brown rice and green tea in a weight ratio of 2: 8 to 8: 2, and the mixture of roasted brown rice and green tea A method for producing a brown rice tea beverage, comprising a step of extracting with water.
本発明の玄米茶用玄米を用いると、優れた香味を有する玄米茶飲料を製造することができる。 By using the brown rice for brown rice tea of the present invention, a brown rice tea beverage having an excellent flavor can be produced.
上記したように、本発明においては、玄米に特定のアミノ酸(ロイシン、バリン及びイソロイシンからなる群から選ばれる少なくとも1種以上のアミノ酸)を含む水溶液を浸透させた後、100〜200℃の温度で焙煎する。1つの観点からは本発明は玄米茶用玄米の製造方法であり、また別の観点から本発明は、このようにして得られた玄米茶用玄米を用いる玄米茶の製造方法である。 As described above, in the present invention, brown rice is impregnated with an aqueous solution containing a specific amino acid (at least one amino acid selected from the group consisting of leucine, valine and isoleucine), and then at a temperature of 100 to 200 ° C. Roast. From one point of view, the present invention is a method for producing brown rice for brown rice tea, and from another point of view, the present invention is a method for producing brown rice tea using the brown rice for brown rice tea thus obtained.
(玄米茶用玄米の製造方法)
本発明においては、原料米に特定のアミノ酸(ロイシン、バリン及びイソロイシンからなる群から選ばれる少なくとも1種以上のアミノ酸)を含む水溶液を浸透させるが、原料米の種類は限定されず、例えば、ジャポニカ型米、インディカ型米及びその中間体、ウルチ米、モチ米などを、所望する香味に合わせて1種または複数種使用することができる。ウルチ米を使用すると本発明の効果が顕著に発現するため好ましい。
(Method for producing brown rice for brown rice tea)
In the present invention, the raw rice is impregnated with an aqueous solution containing a specific amino acid (at least one amino acid selected from the group consisting of leucine, valine and isoleucine), but the type of raw rice is not limited. For example, japonica Type rice, indica type rice and its intermediates, uruchi rice, glutinous rice, and the like can be used according to a desired flavor. Use of glutinous rice is preferable because the effects of the present invention are remarkably exhibited.
以下、図面に基づいて本発明にかかるアミノ酸を利用した玄米茶用玄米の具体的実施形態の例を説明する。図1〜3は、本実施形態にかかる玄米茶用玄米の製造工程例を示すフロー図であり、精白工程、浸漬工程、蒸し工程、乾燥工程、混合工程、焙煎工程、冷却工程を経て玄米茶用玄米が製造される。 Hereinafter, examples of specific embodiments of brown rice for brown rice tea using amino acids according to the present invention will be described with reference to the drawings. 1-3 is a flowchart which shows the manufacturing process example of the brown rice for brown rice tea concerning this embodiment, and passes through a whitening process, a soaking process, a steaming process, a drying process, a mixing process, a roasting process, a cooling process, and brown rice Brown rice for tea is produced.
まず、ステップ1の精白工程では、精選した玄米の穀粒から籾殻を外し、玄米を白くなるまで削って白米を得る。精白の度合いは、特に限定されないが、九分ヅキ以上精白された、いわゆる白米が好適に用いられる。ステップ2の浸漬工程では、前記ステップ1で得られた白米を水に浸漬し、蒸し易くする。好ましい浸漬条件は、10〜40℃の水に、1〜24時間、好ましくは1〜3時間程度である。浸漬後に白米を取り出して、ステップ3の蒸し工程では、100℃程度の水蒸気で、10〜120分、好ましくは10〜30分程度蒸す。蒸し工程の後、米の粒同士がくっつかないように、ステップ4の乾燥工程では、ばらしながらお米を乾燥させる。乾燥は、120〜180℃程度の温度で、米の水分含量が0.1〜10%程度になるまで行う。 First, in the whitening process of Step 1, the rice husk is removed from the grain of the carefully selected brown rice, and the brown rice is shaved until white to obtain white rice. The degree of milling is not particularly limited, but so-called white rice that has been milled more than 9 minutes is suitably used. In the dipping process of Step 2, the white rice obtained in Step 1 is dipped in water to facilitate steaming. Preferable immersion conditions are about 1 to 24 hours, preferably about 1 to 3 hours in water at 10 to 40 ° C. White rice is taken out after the immersion, and in the steaming step of Step 3, steam is steamed at about 100 ° C. for 10 to 120 minutes, preferably about 10 to 30 minutes. After the steaming process, the rice is dried while being loosened in the drying process of Step 4 so that the grains of rice do not stick to each other. Drying is performed at a temperature of about 120 to 180 ° C. until the water content of the rice reaches about 0.1 to 10%.
本発明では、アミノ酸としてロイシン(Leu)、バリン(Val)及びイソロイシン(Ile)からなる群から選ばれる少なくとも1種以上のアミノ酸(以下、アミノ酸(A)ともいう)を含む水溶液を用い、これを米に含浸させる。なお、本発明でいうアミノ酸水溶液とは、アミノ酸を含有する液体を意味し、アミノ酸の懸濁液も含まれるものとするが、アミノ酸が原料となる玄米に均一に混合できるという観点からは、アミノ酸水溶液として用いることが好ましい。 In the present invention, an aqueous solution containing at least one amino acid selected from the group consisting of leucine (Leu), valine (Val), and isoleucine (Ile) as an amino acid (hereinafter also referred to as amino acid (A)) is used. Impregnate rice. The amino acid aqueous solution as used in the present invention means a liquid containing amino acids and includes a suspension of amino acids. From the viewpoint that amino acids can be uniformly mixed with brown rice as a raw material, amino acids It is preferable to use it as an aqueous solution.
図1〜3の態様では、原料米を処理するステップと並行して、ステップ8でアミノ酸水溶液を調製している。好ましい態様において、アミノ酸水溶液は、アミノ酸(A)すなわち、ロイシン、バリン及びイソロイシンの総量がアミノ酸水溶液中0.01〜10重量%、好ましくは0.1〜2重量%となるように調製する。 1-3, the aqueous amino acid solution is prepared in Step 8 in parallel with the step of processing the raw rice. In a preferred embodiment, the aqueous amino acid solution is prepared so that the total amount of amino acid (A), that is, leucine, valine and isoleucine is 0.01 to 10% by weight, preferably 0.1 to 2% by weight in the aqueous amino acid solution.
また、抽出の際に玄米中の澱粉が溶出し、のり状感を生じることがあるが、フェニルアラニン、グルタミン酸、グリシン、プロリン及びテアニンからなる群から選ばれる1種以上のアミノ酸(以下、アミノ酸(B)ともいう)を上記アミノ酸(A)と併用すると、のり状感を顕著に改善する効果があり、好ましい。これらのアミノ酸(B)を併用する場合、アミノ酸(B)の総量が、アミノ酸水溶液中に含まれるアミノ酸の総量(具体的には、アスパラギン酸、グルタミン酸、セリン、グリシン、ヒスチジン、アルギニン、トレオニン、アラニン、プロリン、テアニン、チロシン、バリン、メチオニン、イソロイシン、ロイシン、リジン、フェニルアラニンの17種類のアミノ酸の総量)に対して10〜80重量%、となるように調製することが好ましく、15〜25重量%となるように調製することがより好ましい。 In addition, the starch in brown rice elutes during extraction and may give a paste-like feeling. However, one or more amino acids selected from the group consisting of phenylalanine, glutamic acid, glycine, proline and theanine (hereinafter referred to as amino acids (B) )) In combination with the amino acid (A) is preferable because it has an effect of remarkably improving the glue feeling. When these amino acids (B) are used in combination, the total amount of amino acids (B) is the total amount of amino acids contained in the aqueous amino acid solution (specifically, aspartic acid, glutamic acid, serine, glycine, histidine, arginine, threonine, alanine). , Proline, theanine, tyrosine, valine, methionine, isoleucine, leucine, lysine, phenylalanine), preferably 10 to 80% by weight, and preferably 15 to 25% by weight. It is more preferable to prepare so that.
図1および図3に示すステップ5の混合工程では、上記ステップ8で得られたアミノ酸水溶液を、ステップ4で得られた水分を浸透できる程度にまで柔らかく蒸した米(以下、「原料玄米」とも表記する)に混合して含浸させる。 In the mixing process of Step 5 shown in FIG. 1 and FIG. 3, rice (hereinafter referred to as “raw brown rice”), which is obtained by steaming the amino acid aqueous solution obtained in Step 8 above to the extent that it can penetrate the water obtained in Step 4. Mixed) and impregnated.
本発明においてアミノ酸水溶液を含浸させる方法は、アミノ酸が原料玄米に浸透又は付着できる方法であれば特に手段は制限されない。例えば、アミノ酸水溶液を原料玄米に噴霧、散布又は塗布する方法、アミノ酸水溶液に原料玄米を浸漬させる方法などが挙げられる。アミノ酸が原料玄米に均一に含浸できる観点からは、アミノ酸水溶液を原料玄米に噴霧する方法が好ましい。 In the present invention, the method for impregnating the aqueous amino acid solution is not particularly limited as long as the amino acid can permeate or adhere to the raw brown rice. For example, a method of spraying, spreading or applying an amino acid aqueous solution to raw brown rice, a method of immersing raw brown rice in an aqueous amino acid solution, and the like can be mentioned. From the viewpoint of uniformly impregnating raw brown rice with amino acids, a method of spraying an aqueous amino acid solution onto raw brown rice is preferable.
本発明では、原料玄米1kgに対してアミノ酸(A)を45mg以上含浸させることが好ましい。45mg以上の場合、本発明の特徴である香ばしい香りを十分に増強することができ、香ばしい香りと甘味、コク味の調和のとれた玄米茶飲料を製造できる。したがって、本発明では、ロイシン、バリン及びイソロイシンの総量が、原料大玄米100重量部に対して0.005〜0.25重量%程度であることが好ましく、0.05〜0.1重量%程度であることがより好ましい。 In this invention, it is preferable to impregnate 45 mg or more of amino acids (A) with respect to 1 kg of raw material brown rice. In the case of 45 mg or more, the fragrant aroma characteristic of the present invention can be sufficiently enhanced, and a brown rice tea drink in which the fragrant aroma, sweetness and richness are harmonized can be produced. Therefore, in the present invention, the total amount of leucine, valine and isoleucine is preferably about 0.005 to 0.25% by weight, and about 0.05 to 0.1% by weight, based on 100 parts by weight of the raw large brown rice. It is more preferable that
次に、本発明においては、上記のアミノ酸水溶液を含浸させた玄米に対して100〜200℃の温度で焙煎を行う。水分を少し含む状態で乾燥時よりも強い熱が与えられ、これにより、玄米茶の香ばしい香りである2−ブタナール及び/又は3−ブタナールを増強させることができると考えられる。加熱の程度が深いと、単純火香、すなわち焦げ臭に近い香りが強くなり、2−ブタナール及び/又は3−ブタナールなどの好ましい香気の知覚を阻害することがある。したがって、2−メチルブタナール及び/又は3−ブタナールが火香である2,5−(あるいは2,6−)ジメチルピラジン(2,5(6)-dimethylpyrazine)に対して好ましくは0.5〜50倍量、より好ましくは1〜30倍量含有されるように焙煎することが望ましい。ここで、焙煎された玄米中の2−ブタナール、3−ブタナール含量及び2,5−(あるいは2,6−)ジメチルピラジン含量は、ガスクロマトグラフィーにより測定することができる。 Next, in this invention, it roasts at the temperature of 100-200 degreeC with respect to the brown rice impregnated with said amino acid aqueous solution. It is thought that 2-butanal and / or 3-butanal, which is a fragrant scent of brown rice tea, can be enhanced in a state containing a little moisture than that during drying. When the degree of heating is deep, simple incense, i.e., a scent close to a burning odor, becomes strong and may inhibit the perception of preferred fragrances such as 2-butanal and / or 3-butanal. Accordingly, it is preferable that 2-methylbutanal and / or 3-butanal is 0.5 to 2,5- (or 2,6-) dimethylpyrazine (2,5 (6) -dimethylpyrazine), which is an incense. It is desirable to roast so as to contain 50 times, more preferably 1 to 30 times. Here, the 2-butanal, 3-butanal content and 2,5- (or 2,6-) dimethylpyrazine content in the roasted brown rice can be measured by gas chromatography.
2−ブタナール及び/又は3−ブタナール含量及び2,5−(あるいは2,6−)ジメチルピラジン含量が上記範囲となる焙煎方法として、具体的には、アミノ酸を含浸させた玄米の品温が100〜200℃、好ましくは110〜170℃、より好ましくは130〜150℃に到達するように加熱する方法が挙げられる。焙煎の装置や方法は特に制限されず、通常、玄米茶用玄米の焙煎に用いられる方法、例えばフクレ炒り焙煎、カタ炒り焙煎等が挙げられる。 As a roasting method in which 2-butanal and / or 3-butanal content and 2,5- (or 2,6-) dimethylpyrazine content are within the above ranges, specifically, the temperature of brown rice impregnated with amino acids is The method of heating to 100-200 degreeC, Preferably it is 110-170 degreeC, More preferably, it reaches 130-150 degreeC is mentioned. The apparatus and method for roasting are not particularly limited, and methods that are usually used for roasting brown rice for brown rice tea, such as roasted roasted burdock, roasted kataka and the like, can be mentioned.
図1〜3に示す態様では、ステップ6で米を焙煎し、ステップ7で焙煎した米を冷却している。ステップ7の冷却は、焙煎後に釜から原料を取り出すと該原料が発火する惧れがあるため、この発火を防止することが主目的である。 1-3, the rice is roasted in step 6 and the roasted rice in step 7 is cooled. The cooling of step 7 is mainly intended to prevent this ignition because the raw material may ignite when it is taken out of the kettle after roasting.
このように焙煎して得られる焙煎玄米の水分含量は、5%以下であることが好ましく、1%以下程度であることがより好ましい。
また、本発明においては、ステップ2における精白した玄米を浸漬する工程において玄米に特定のアミノ酸を含浸させてもよい。図2に示す態様では、水に代えてアミノ酸水溶液を用い、アミノ酸水溶液に精白した玄米を浸漬して、アミノ酸を玄米に含浸させている。ただし、この場合、アミノ酸が含浸しにくく浸漬時間に長時間を要することになるため、好ましくは図1又は図3に示すように、蒸して柔らかくした米にアミノ酸水溶液を含浸させるのがよい。
The water content of the roasted brown rice obtained by roasting in this way is preferably 5% or less, more preferably about 1% or less.
In the present invention, the brown rice may be impregnated with a specific amino acid in the step of immersing the polished brown rice in Step 2. In the embodiment shown in FIG. 2, an amino acid aqueous solution is used instead of water, and brown rice refined in the amino acid aqueous solution is immersed to impregnate the brown rice with amino acid. However, in this case, since it is difficult to impregnate the amino acid and it takes a long time to immerse, it is preferable to impregnate the steamed and softened rice with the aqueous amino acid solution as shown in FIG. 1 or FIG.
本発明においては、玄米へのアミノ酸の含浸を多段階で行ってもよく、例えば、精白した玄米をアミノ酸水溶液に浸漬させた後、蒸して柔らかくし、さらにアミノ酸水溶液を含浸させて焙煎する方法も本発明に含まれるものとする。 In the present invention, brown rice may be impregnated with amino acids in multiple stages, for example, a method in which polished brown rice is immersed in an aqueous amino acid solution, then steamed and softened, and further impregnated with an aqueous amino acid solution and roasted. Are also included in the present invention.
本発明では、原料玄米に上記特定のアミノ酸水溶液を含浸させ特定の条件で焙煎することにより、玄米茶の香ばしい香りが増強され、その結果、こげ臭や雑味を伴うことなく、香ばしい香りが増強された玄米茶飲料を製造することができる。本発明者らの検討によると、この香ばしい香りは、ロイシン、バリン及びイソロイシンからなる群から選ばれる少なくとも1種以上のアミノ酸を含む水溶液を使用した場合に発現する。特に、ロイシンは、香ばしい香りだけでなく、甘味やコクも増強する効果を有する。したがって、本発明の好適な態様の一つは、アミノ酸含有溶液がロイシンを含み、さらにバリン及び/又はイソロイシンを含むものである。本発明によって、玄米茶の香ばしい香りが増強される理由の詳細は明らかでなく、本発明は以下の推測に拘束されるものでないが、特定のアミノ酸を原料玄米に含浸させてから焙煎処理すると、香ばしい香りである2−メチルブタナール(2-methylbutanal)及び/又は3−ブタナール(3-methylbutanal)が増強するためであると推測される。 In the present invention, by impregnating raw brown rice with the above-mentioned specific amino acid aqueous solution and roasting under specific conditions, the fragrant fragrance of brown rice tea is enhanced, and as a result, the fragrant fragrance is not accompanied by burnt odor and miscellaneous taste. An enhanced brown rice tea beverage can be produced. According to the study by the present inventors, this fragrant scent is expressed when an aqueous solution containing at least one amino acid selected from the group consisting of leucine, valine and isoleucine is used. In particular, leucine has an effect of enhancing not only a fragrant scent but also sweetness and richness. Accordingly, one preferred embodiment of the present invention is one in which the amino acid-containing solution contains leucine and further contains valine and / or isoleucine. The details of the reason why the fragrant aroma of brown rice tea is enhanced by the present invention is not clear, and the present invention is not limited to the following assumptions, but when the raw material brown rice is impregnated with a specific amino acid and then roasted. It is speculated that this is because 2-methylbutanal and / or 3-methylbutanal, which are fragrant scents, are enhanced.
ロイシン、バリン及び/又はイソロイシンを用いて発現する香味改善作用は、フェニルアラニン(Phe)、グルタミン酸(Glu)、グリシン(Gly)、プロリン(Pro)、及びテアニン(Theanine)からなる群から選ばれる1種以上のアミノ酸を併用することで、より大きな効果を奏し、特にコク、甘味の増強に有効である。ロイシン、バリン及びイソロイシンを用いずに、フェニルアラニン、グルタミン酸、グリシン、プロリン及びテアニンからなる群から選ばれる1種以上のアミノ酸を添加した場合には、香味改善作用は得られないことから、この効果は、特定のアミノ酸(ロイシン、バリン、イソロイシン:アミノ酸A)と特定のアミノ酸(フェニルアラニン、グルタミン酸、グリシン、プロリン、テアニン:アミノ酸B)とが協働的に機能して得られるものと考えられる。 The flavor improving action expressed by using leucine, valine and / or isoleucine is one selected from the group consisting of phenylalanine (Phe), glutamic acid (Glu), glycine (Gly), proline (Pro), and theanine (Theanine) By using the above amino acids in combination, a greater effect is obtained, and particularly effective for enhancing richness and sweetness. When one or more amino acids selected from the group consisting of phenylalanine, glutamic acid, glycine, proline and theanine are added without using leucine, valine and isoleucine, the effect of improving flavor is not obtained. It is considered that a specific amino acid (leucine, valine, isoleucine: amino acid A) and a specific amino acid (phenylalanine, glutamic acid, glycine, proline, theanine: amino acid B) function cooperatively.
ステップ8で用意するアミノ酸水溶液としては、精製されたアミノ酸を用いてこれを水に溶解(又は懸濁)させたものを用いてもよいし、アミノ酸を含有する植物抽出物をそのまま又は精製(粗精製を含む)して用いてもよい。図3に示す態様では、緑茶抽出物をアミノ酸含有溶液として使用しており、緑茶抽出物をろ過、濃縮してから、玄米に含浸させている。ここで、アミノ酸を含有する植物抽出物として、緑茶抽出物が好適に例示される。通常、緑茶抽出物には、テアニン、グルタミン酸、アスパラギン酸、メチオニン等のアミノ酸が多く含まれるが、本発明の有効成分であるアミノ酸(A)バリン、ロイシン、イソロイシンや、これらアミノ酸(A)と相加的又は相乗的に作用して澱粉由来ののり状感を改善するアミノ酸(B)フェニルアラニン、グリシン、プロリンの含有量は少ないことが知られている。したがって、緑茶抽出物を用いる場合は、物理的又は化学的処理を施して、アミノ酸(A)やアミノ酸(B)の濃度を高める処理を行うのが好ましい。ここで物理的又は化学的処理としては、酵素処理、酸処理、高温高圧処理、微細化処理、超音波処理等が挙げられる。中でもアミノ酸の反応を選択的に制御できる観点から、酵素処理が好ましい。 As the aqueous amino acid solution prepared in Step 8, a purified amino acid dissolved in water (or suspended) may be used, or a plant extract containing an amino acid may be used as it is or purified (crude). (Including purification). In the embodiment shown in FIG. 3, the green tea extract is used as an amino acid-containing solution, and the green tea extract is filtered and concentrated before impregnating brown rice. Here, a green tea extract is preferably exemplified as a plant extract containing amino acids. Usually, the green tea extract contains many amino acids such as theanine, glutamic acid, aspartic acid, and methionine. The amino acid (A) valine, leucine, and isoleucine, which are the active ingredients of the present invention, are compatible with these amino acids (A). It is known that the contents of amino acids (B) phenylalanine, glycine, and proline that act additively or synergistically to improve the starch-like glue feel are low. Therefore, when using a green tea extract, it is preferable to perform a treatment that increases the concentration of amino acid (A) or amino acid (B) by applying a physical or chemical treatment. Here, examples of the physical or chemical treatment include enzyme treatment, acid treatment, high-temperature and high-pressure treatment, miniaturization treatment, and ultrasonic treatment. Of these, enzyme treatment is preferable from the viewpoint of selectively controlling the reaction of amino acids.
緑茶抽出物の酵素処理としては、酵素が緑茶葉及び/又は茶抽出液中のタンパク質や繊維質に作用することにより、抽出液中のアミノ酸濃度を高めることができる方法であれば、いずれの方法でもよい。例えば、酵素抽出(酵素を添加混合した緑茶葉を水(熱水)で抽出する方法又は酵素を添加した水(熱水)で緑茶葉の抽出を行う方法)、或いは緑茶はより水(熱水)で抽出した緑茶抽出液に酵素を添加混合して処理する方法が挙げられる。酵素としてはプロテアーゼ、α−アミラーゼ、セルラーゼ、ヘミセルラーゼ、ペクチナーゼ、プロトペクチナーゼ及びグルタミナーゼ等を1種又は複数種類併用して用いることができる。酵素処理の条件は、用いる酵素の至適条件を鑑みて適宜選択すればよい。 As the enzyme treatment of the green tea extract, any method can be used as long as the enzyme acts on proteins and fibers in the green tea leaves and / or tea extract to increase the amino acid concentration in the extract. But you can. For example, enzyme extraction (a method of extracting green tea leaves mixed with enzymes with water (hot water) or a method of extracting green tea leaves with water added with enzymes (hot water)), or green tea is more water (hot water) The method of adding and mixing an enzyme with the green tea extract extracted by (1) is mentioned. As the enzyme, protease, α-amylase, cellulase, hemicellulase, pectinase, protopectinase, glutaminase and the like can be used singly or in combination. The conditions for the enzyme treatment may be appropriately selected in view of the optimum conditions for the enzyme used.
アミノ酸水溶液として緑茶抽出物を用いる場合、カテキン類が多い緑茶抽出液を用いると、本発明の焙煎工程で苦味や渋味を発生したり、茶飲料製造における加熱殺菌時に異味を発生したりする場合がある。したがって、本発明に用いる緑茶抽出液としては、カテキン類の除去工程を施したものが好ましい。ここで、本明細書におけるカテキン類とは、カテキン、エピカテキン、ガロカテキン、エピガロカテキン、カテキンガレート、エピカテキンガレート、ガロカテキンガレートおよびエピガロカテキンガレートの総称を表す。具体的には、緑茶抽出液中、茶葉由来固形分に対してカテキン類の総量の割合が15.0重量%以下、好ましくは13.5重量%以下、より好ましくは10.0重量%以下、特に好ましくは8.0重量%以下となるように除去する。なお、茶抽出液のBrix(可溶性固形成分量)は、通常、0.2〜20%程度、好ましくは5〜20%、より好ましくは10〜20%である。カテキン類の除去方法は特に制限されないが、例えば、緑茶抽出液から樹脂(吸着)によりカテキン類を除去する方法、緑茶葉に水性溶媒を接触させて緑茶葉抽出液を得てからこの抽出液を除去(廃棄)する方法等が挙げられる。特に、カテキン類は高温で抽出されやすいという性質を有することから、緑茶葉に高温の水を接触させて高温抽出液を得て、この高温抽出液を除去(廃棄)する方法が好適である。 When a green tea extract is used as an aqueous amino acid solution, if a green tea extract containing a large amount of catechins is used, bitterness and astringency may be generated in the roasting process of the present invention, or a taste may be generated during heat sterilization in tea beverage production. There is a case. Therefore, the green tea extract used in the present invention is preferably subjected to a catechin removal process. Here, the catechins in the present specification represent a generic name of catechin, epicatechin, gallocatechin, epigallocatechin, catechin gallate, epicatechin gallate, gallocatechin gallate and epigallocatechin gallate. Specifically, in the green tea extract, the ratio of the total amount of catechins to the tea leaf-derived solid content is 15.0 wt% or less, preferably 13.5 wt% or less, more preferably 10.0 wt% or less, It is particularly preferably removed so as to be 8.0% by weight or less. In addition, the Brix (soluble solid component amount) of the tea extract is usually about 0.2 to 20%, preferably 5 to 20%, more preferably 10 to 20%. The method for removing catechins is not particularly limited. For example, a method for removing catechins from a green tea extract by resin (adsorption), an aqueous solvent is brought into contact with green tea leaves to obtain a green tea leaf extract, and then the extract is used. The method of removing (disposing) is mentioned. In particular, since catechins have the property of being easily extracted at high temperatures, a method of obtaining a high temperature extract by bringing high temperature water into contact with green tea leaves and removing (discarding) the high temperature extract is suitable.
(玄米茶飲料の製造方法)
本明細書でいう玄米茶飲料とは、本発明で得られる玄米茶用玄米より抽出して得られる抽出液を含有する飲料をいう。好ましい態様としては、本発明で得られる玄米茶用玄米を緑茶と混合し、水または温水で抽出して得られる飲料が挙げられる。この際、玄米と緑茶の混合割合は、重量比で2:8〜8:2、好ましくは3:7〜8:2、より好ましくは4:6〜8:2程度である。
(Manufacturing method of brown rice tea beverage)
The brown rice tea drink as used in this specification means the drink containing the extract obtained by extracting from the brown rice for brown rice tea obtained by this invention. A preferable embodiment includes a beverage obtained by mixing brown rice for brown rice tea obtained in the present invention with green tea and extracting it with water or warm water. At this time, the mixing ratio of brown rice and green tea is about 2: 8 to 8: 2, preferably 3: 7 to 8: 2, and more preferably about 4: 6 to 8: 2 in weight ratio.
玄米茶飲料の抽出原料となる玄米には、本発明のアミノ酸含浸処理を行った玄米を全て用いてもよいし、アミノ酸含浸処理を行った玄米を一部に用い、従来の玄米茶(アミノ酸含浸処理を行っていないもの)と混合して用いてもよい。具体的には、本発明の玄米茶用玄米は、抽出原料となる玄米全量に対して、10〜100重量%、好ましくは50〜100重量%となるように配合する。 The brown rice used as a raw material for extracting brown rice tea beverages may be all of the brown rice subjected to the amino acid impregnation treatment of the present invention, or a portion of the brown rice subjected to the amino acid impregnation treatment, You may mix and use the thing which is not processing. Specifically, the brown rice for brown rice tea of the present invention is blended so as to be 10 to 100% by weight, preferably 50 to 100% by weight, based on the total amount of brown rice as an extraction raw material.
本発明の玄米茶用玄米と混合する緑茶は、特に限定されず、所望する香味に応じて適宜選択すればよい。具体的には、煎茶、玉露、被せ茶、ほうじ茶、深蒸し茶、釜煎り茶、玉緑茶、碾茶、茎茶、抹茶、粉茶などが選択される。
玄米と緑茶を混合した抽出原料を、水道水若しくは脱イオン水等任意の水で、好ましくは75〜100℃、好ましくは80〜95℃の抽出水温度において抽出することによって玄米茶飲料を得ることができる。抽出時には、攪拌してもよいし攪拌しなくてもよい。抽出比(重量比)は、抽出原料1重量部に対し抽出水5〜150部、好ましくは5〜30部である。また、本発明における抽出時間は抽出温度にもよるが、好ましくは3〜60分、より好ましくは5〜30分程度である。
The green tea mixed with the brown rice for brown rice tea of the present invention is not particularly limited, and may be appropriately selected according to the desired flavor. Specifically, sencha, gyokuro, topped tea, roasted tea, deep-steamed tea, kettle roasted tea, tama green tea, strawberry tea, stem tea, matcha tea, powdered tea, and the like are selected.
Obtaining a brown rice tea beverage by extracting an extraction raw material in which brown rice and green tea are mixed with any water such as tap water or deionized water, preferably at an extraction water temperature of 75 to 100 ° C., preferably 80 to 95 ° C. Can do. At the time of extraction, it may or may not be stirred. The extraction ratio (weight ratio) is 5 to 150 parts, preferably 5 to 30 parts, of extraction water with respect to 1 part by weight of the extraction raw material. Moreover, although the extraction time in this invention is based also on extraction temperature, Preferably it is 3 to 60 minutes, More preferably, it is about 5 to 30 minutes.
好ましい態様において、抽出された玄米茶抽出液は、直ぐに段階的に金網などをしようしてろ過をして茶殻などの残渣を除去して、10〜40℃まで、例えばプレート式交換機などを用いて冷却する。さらに、連続式遠心分離機若しくはネルろ過等を用いて不溶成分を取り除くことが好ましく、遠心分離の条件は、通常4000〜9000Gである。遠心分離機はどのような型式のものでもよいが、好ましくは玄米茶抽出液の上層部に浮上する油分を除去できるので3相型遠心分離機がよい。また、ネルろ過を行ってもよく、例えばネル布等を用いることにより行うことができる。 In a preferred embodiment, the extracted brown rice tea extract is immediately filtered in a stepwise manner using a wire mesh to remove residues such as tea husks, and the temperature is 10 to 40 ° C., for example, using a plate-type exchanger. Cooling. Furthermore, it is preferable to remove insoluble components using a continuous centrifugal separator or flannel filtration, and the centrifugal conditions are usually 4000 to 9000G. The centrifugal separator may be of any type, but preferably a three-phase centrifugal separator is preferable because oil components floating on the upper layer of the brown rice tea extract can be removed. Further, flannel filtration may be performed, for example, by using flannel cloth or the like.
その後、必要に応じて、得られたろ液にL−アスコルビン酸、炭酸水素ナトリウム等の酸化防止剤やpH調整剤を添加して、pHを5.0〜7.0に調整してもよい。pH調整された抽出液を、最終調合液の可溶性固形分(Brix)が所望の値(0.1〜0.5)になるように希釈して、固形分濃度を調整してもよい。 Thereafter, if necessary, an antioxidant or a pH adjuster such as L-ascorbic acid or sodium bicarbonate may be added to the obtained filtrate to adjust the pH to 5.0 to 7.0. The pH-adjusted extract may be diluted so that the soluble solid content (Brix) of the final preparation solution becomes a desired value (0.1 to 0.5) to adjust the solid content concentration.
保存性を高めるため好ましい態様において、このようにして得られた調合液に対して殺菌処理を行う。殺菌処理は、調合液を密封容器に充填してから行ってもよいし、殺菌後に容器に充填してもよい。容器は特に限定されず、紙パック、瓶、缶、ペットボトル等が用いられる。殺菌は、容器の種類や保存条件に合わせて、UHT殺菌、レトルト殺菌、プレート殺菌等、適宜選択すればよい。具体的には、缶や瓶の容器のように容器に充填後、加熱殺菌できる場合には食品衛生法に定められた殺菌条件でレトルト殺菌が採用され、ペットボトル、紙パックのようにレトルト殺菌できないものについては、予め上記と同様の殺菌条件、例えばプレート式熱交換器で高温短時間殺菌後、一定の温度まで冷却して、ホットパック充填又は無菌下での充填などの方法により容器に充填する等の方法が採用される。 In a preferred embodiment, the sterilization treatment is performed on the preparation liquid thus obtained in order to improve the storage stability. The sterilization treatment may be performed after the preparation liquid is filled into a sealed container, or may be filled into the container after sterilization. A container is not specifically limited, A paper pack, a bottle, a can, a plastic bottle etc. are used. Sterilization may be appropriately selected according to the type of container and storage conditions, such as UHT sterilization, retort sterilization, and plate sterilization. Specifically, if the container can be sterilized by heating after filling into a container such as a can or bottle, retort sterilization is adopted under the sterilization conditions stipulated in the Food Sanitation Law, and retort sterilization is performed like a plastic bottle or paper pack. For those that cannot, pre-sterilization conditions similar to the above, for example after sterilization at high temperature and short time in a plate heat exchanger, cooled to a certain temperature, and filled into a container by a method such as hot pack filling or aseptic filling Such a method is adopted.
玄米茶飲料は、澱粉成分が抽出されてのり状の食感を呈する問題があることが知られている。特に、室温以下(好ましくは20℃以下、より好ましくは15℃以下、特に好ましくは10℃以下)で冷蔵保存され、飲用に供される容器詰め玄米茶飲料では、澱粉由来のベトツキ感が顕著になり、その口当たりや飲用後の後味(すっきりした味)を損なうという問題がある。一方、本発明者らは、2−メチルブタナール及び/又は3−ブタナールが、飲料中の澱粉由来ののり状感(ベトツキ感)を改善する作用があることを見出している。本発明の玄米茶用玄米では、2−メチルブタナール及び/又は3−ブタナールが増強されるので、これを抽出して得られる本発明の茶飲料は、容器詰め飲料として冷蔵状態で保存したり、飲用したりした場合にも、香ばしい香りを損なわずに、澱粉由来ののり状感が低減され、優れた香味を有するものとして製造される。 It is known that brown rice tea beverages have a problem of having a paste-like texture as the starch component is extracted. In particular, in container-packed brown rice tea beverages that are refrigerated and stored at room temperature or lower (preferably 20 ° C. or lower, more preferably 15 ° C. or lower, particularly preferably 10 ° C. or lower), starch-derived stickiness is prominent. There is a problem that the taste and the aftertaste (clean taste) after drinking are impaired. On the other hand, the present inventors have found that 2-methylbutanal and / or 3-butanal has an effect of improving a sticky feeling (stickiness) derived from starch in beverages. In the brown rice for brown rice tea of the present invention, since 2-methylbutanal and / or 3-butanal is enhanced, the tea beverage of the present invention obtained by extracting this can be stored in a refrigerated state as a container-packed beverage. Even when it is drunk, the starch-derived glue-like sensation is reduced without deteriorating the fragrant fragrance, and it is produced as having an excellent flavor.
こののり状感改善作用は、玄米茶用玄米の製造におけるアミノ酸含浸工程において、フェニルアラニン、グルタミン酸、グリシン、プロリン及びテアニンからなる群から選ばれる1種以上のアミノ酸を併用した場合に、より大きな効果を奏する。この玄米茶抽出液の澱粉由来ののり状感低減という観点からも、アミノ酸含浸工程では、ロイシン、バリン及びイソロイシンからなる群から選ばれる少なくとも1種以上のアミノ酸(A)に加えて、フェニルアラニン、グルタミン酸、グリシン、プロリン及びテアニンからなる群から選ばれる1種以上のアミノ酸(B)を含む水溶液を、原料玄米に含浸させることが好ましい。 This glue-like improvement effect is greater when one or more amino acids selected from the group consisting of phenylalanine, glutamic acid, glycine, proline and theanine are used in combination in the amino acid impregnation step in the production of brown rice for brown rice tea. Play. From the viewpoint of reducing the glue-like feeling derived from starch of this brown rice tea extract, in the amino acid impregnation step, in addition to at least one amino acid (A) selected from the group consisting of leucine, valine and isoleucine, phenylalanine and glutamic acid The raw brown rice is preferably impregnated with an aqueous solution containing one or more amino acids (B) selected from the group consisting of glycine, proline and theanine.
さらに、本発明者らは、2−メチルブタナール及び/又は3−ブタナールには緑茶抽出液の加熱殺菌に起因する好ましくない香味をマスキングできる作用があることを見出している。本発明の2−メチルブタナール及び/又は3−ブタナールが増強された玄米茶用玄米と緑茶とを混合して得られる玄米茶より抽出して得られる玄米茶飲料は、長期間の保存に渡って、加熱臭などの異味・異臭がマスキングされた、優れた香味を有する茶飲料となる。 Furthermore, the present inventors have found that 2-methylbutanal and / or 3-butanal has an action capable of masking an unfavorable flavor resulting from heat sterilization of a green tea extract. The brown rice tea beverage obtained by extracting from brown rice tea obtained by mixing 2-methylbutanal and / or 3-butanal-enhanced brown rice tea and green tea according to the present invention can be stored for a long period of time. Thus, it becomes a tea beverage having an excellent flavor masked with off-flavors such as a heated odor.
このような本発明は、1つの観点からは、玄米茶または玄米茶用玄米の香味改善方法であり、また、玄米茶ののり状感を低減する方法と把握することができる。 From one viewpoint, the present invention can be understood as a method for improving the flavor of brown rice tea or brown rice for brown rice tea, and a method for reducing the sticky feeling of brown rice tea.
以下、実施例を示して本発明の詳細を具体的に説明するが、本発明はこれに限定されるものではない。本明細書において特記しない限り、濃度等は重量基準であり、数値範囲はその端点を含むものとして記載される。 EXAMPLES Hereinafter, although an Example is shown and the detail of this invention is demonstrated concretely, this invention is not limited to this. Unless otherwise specified in the present specification, the concentration and the like are based on weight, and the numerical range is described as including the end points.
実施例1.玄米茶飲料の製造−アミノ酸の添加
市販の精米を用い、水分を浸透しやすくするため水に40分間浸漬し、30分間蒸した。これに各種アミノ酸の1%水溶液を玄米:アミノ酸水溶液の重量比が0.2:1となるように噴霧して含浸させた後、焙煎機(アイ・シー電子工業株式会社 TORNADE KING TypeT)を用い、150℃で15分間焙煎して玄米茶用玄米(焙煎玄米)を得た。ここで、玄米に添加したアミノ酸量は、2000mg/kg程度である。アミノ酸としては、(i)アスパラギン酸(Asp)、(ii)グルタミン酸(Glu)、(iii)セリン(Ser)、(iv)グリシン(Gly)、(v)ヒスチジン(His)、(vi) アルギニン(Arg)、(vii)トレオニン(Thr)、(viii)アラニン(Ala)、(ix)プロリン(Pro)、(x)テアニン(Theanin)、(xi)チロシン(Tyr)、(xii)バリン(Val)、(xiii)メチオニン(Met)、(xiv)イソロイシン(Ile)、(xv)ロイシン(Leu)、(xvi)リシン(Lys)、(xvii)フェニルアラニン(Phe)の17種類を用いた(すべてナカライテスク社製、L体)。また、対照として、アミノ酸含浸工程を行わない、すなわちアミノ酸水溶液を噴霧しないこと以外は同様にして、焙煎玄米を得た。
Example 1. Production of Brown Rice Tea Beverage-Addition of Amino Acid Commercially available polished rice was used, soaked in water for 40 minutes, and steamed for 30 minutes in order to facilitate the penetration of moisture. This was sprayed with 1% aqueous solution of various amino acids so that the weight ratio of brown rice: amino acid aqueous solution was 0.2: 1 and then impregnated, and then a roasting machine (IC Electronics Co., Ltd. TORNADE KING TypeT) was used. It was roasted at 150 ° C. for 15 minutes to obtain brown rice for brown rice tea (roasted brown rice). Here, the amount of amino acid added to the brown rice is about 2000 mg / kg. As amino acids, (i) aspartic acid (Asp), (ii) glutamic acid (Glu), (iii) serine (Ser), (iv) glycine (Gly), (v) histidine (His), (vi) arginine ( Arg), (vii) threonine (Thr), (viii) alanine (Ala), (ix) proline (Pro), (x) theanine (xi) tyrosine (Tyr), (xii) valine (Val) (Xiii) Methionine (Met), (xiv) Isoleucine (Ile), (xv) Leucine (Leu), (xvi) Lysine (Lys), (xvii) Phenylalanine (Phe) L type). As a control, roasted brown rice was obtained in the same manner except that the amino acid impregnation step was not performed, that is, the amino acid aqueous solution was not sprayed.
アミノ酸を噴霧して焙煎した17種類の焙煎玄米と対照(アミノ酸未添加)の焙煎玄米を2gずつ軽量し、200gの熱湯(95℃)で5分間抽出して抽出液(Brix:約0.15)を得た。 17 g roasted brown rice sprayed with amino acids and 2 g of roasted brown rice for comparison (no amino acid added) were lightened and extracted with 200 g of hot water (95 ° C.) for 5 minutes to extract (Brix: approx. 0.15) was obtained.
官能評価の結果、アルキル鎖を持つ分子量100以上の中性アミノ酸であるVal、Ile、Leuが、焦げ臭や雑味を伴わずに好ましいと知覚される香ばしい香りを増強できることがわかった。特に、Leuは香ばしい香りとともに甘味やコク味が増強され、調和がとれた優れた香味を有する玄米茶抽出液となった。一方、Pheはフローラルな甘い香りが付与され、Asp、Glu、Ser、Gly、His、Arg、Thr、Ala、Pro、Theanin、Tyr、Lysは、対照と差がなかった。また、Metはイモ臭が発現し、対照よりも好ましくない香味となった。 As a result of sensory evaluation, it was found that Val, Ile, and Leu, which are neutral amino acids having an alkyl chain of 100 or more molecular weight, can enhance a fragrant fragrance that is perceived as preferable without a burning odor or miscellaneous taste. In particular, Leu became a brown rice tea extract with an excellent harmonious flavor with enhanced sweetness and richness as well as a fragrant scent. On the other hand, Phe was given a floral sweet scent, and Asp, Glu, Ser, Gly, His, Arg, Thr, Ala, Pro, Theanin, Tyr, and Lys were not different from the controls. In addition, Met developed a potato odor and became a less preferred flavor than the control.
実施例2.玄米茶飲料の製造−茶抽出物の含浸
(1)茶抽出物の製造
以下の方法で、アミノ酸を高濃度に含有する抽出物を製造した。まず、攪拌機付き密閉容器に10gの緑茶葉(火入れ度:中)を封入し、40℃のイオン交換水を180mL加え、緑茶葉を浸漬させた。そこにプロテアーゼ製剤(三菱化学フーズ社「コクラーゼ・P」)を0.2g添加し、40℃に保持したまま16時間攪拌を行い、酵素処理を行った。その後、得られた酵素処理液を90℃で10分加熱して酵素を失活させ、酵素抽出液を得た(試料A:酵素あり)。また、酵素を添加しないこと以外は同様にして緑茶抽出液(茶抽出物)を得た(試料B:酵素なし)。
Example 2 Manufacture of brown rice tea beverage-impregnation of tea extract (1) Manufacture of tea extract An extract containing an amino acid at a high concentration was manufactured by the following method. First, 10 g of green tea leaves (heating degree: medium) were sealed in an airtight container with a stirrer, and 180 mL of 40 ° C. ion exchange water was added to immerse the green tea leaves. Thereto was added 0.2 g of protease preparation (Mitsubishi Chemical Foods Co., Ltd. “Coclase P”), and the mixture was stirred for 16 hours while being kept at 40 ° C. to perform enzyme treatment. Thereafter, the obtained enzyme-treated solution was heated at 90 ° C. for 10 minutes to deactivate the enzyme to obtain an enzyme extract (sample A: with enzyme). Further, a green tea extract (tea extract) was similarly obtained except that no enzyme was added (sample B: no enzyme).
試料Aおよび試料Bのアミノ酸組成をHPLCで分析した。具体的測定条件は以下のとおりであり、標準物質として、アミノ酸18種(アルギニン、リジン、ヒスチジン、フェニルアラニン、チロシン、ロイシン、イソロイシン、メチオニン、バリン、アラニン、グリシン、プロリン、グルタミン酸、セリン、スレオニン、アルパラギン酸、トリプトファン、シスチン)およびテアニンを用いた。 The amino acid composition of Sample A and Sample B was analyzed by HPLC. Specific measurement conditions are as follows, and 18 kinds of amino acids (arginine, lysine, histidine, phenylalanine, tyrosine, leucine, isoleucine, methionine, valine, alanine, glycine, proline, glutamic acid, serine, threonine, asparagine as standard substances. Acid, tryptophan, cystine) and theanine were used.
表2および図4に、茶抽出物のアミノ酸分析結果を示す。図4より明らかなように、酵素処理した茶抽出物(試料A)は、酵素処理しなかった茶抽出物(試料B)と比較して、Val、Ile、Leuの割合が高められている。実施例1で好ましくない香味を発現するアミノ酸Metとの比〔(Val+Ile+Leu)/(Met)〕を算出すると、酵素処理を行わないと0.16、酵素処理を行うと1.47となった。 Table 2 and FIG. 4 show the amino acid analysis results of the tea extract. As is clear from FIG. 4, the ratio of Val, Ile, and Leu is increased in the tea extract (sample A) that has been subjected to enzyme treatment, compared to the tea extract that has not been subjected to enzyme treatment (sample B). When the ratio [(Val + Ile + Leu) / (Met)] with the amino acid Met expressing an unfavorable flavor in Example 1 was calculated, 0.16 was obtained when the enzyme treatment was not carried out, and 1.47 when the enzyme treatment was carried out. It became.
(2)茶抽出物を含浸させた玄米茶用玄米の製造
(1)で製造した茶抽出物(試料A)を、17種のアミノ酸(Asp, Glu, Ser, Gly, His, Arg, Thr, Ala, Pro, Theanin, Tyr, Val, Met, Ile, Leu, Lys, Phe)の総量が抽出物全体に対して1重量%となるように減圧濃縮して、茶抽出物の濃縮液(試料A’)を調製した。
(2) Production of brown rice for brown rice tea impregnated with tea extract The tea extract (sample A) produced in (1) was converted into 17 kinds of amino acids (Asp, Glu, Ser, Gly, His, Arg, Thr, Concentrate under reduced pressure so that the total amount of Ala, Pro, Theanin, Tyr, Val, Met, Ile, Leu, Lys, Phe is 1% by weight with respect to the whole extract, and then concentrate the tea extract (Sample A ') Was prepared.
市販の精米を用意し、これを水に浸漬し、およそ4時間後に水を切った後、30分間蒸気で蒸した。この蒸した米に茶抽出物の濃縮液(試料A’)を重量比で0.2:1となるよう噴霧した。このとき、玄米に添加されたアミノ酸(上記17種類)の総量は2000mg/kgであり、このうちバリン、イソロイシン、ロイシンの総量(Val+Ile+Leu)は460mg/kgであった。 Commercially available polished rice was prepared, immersed in water, drained after about 4 hours, and steamed with steam for 30 minutes. The steamed rice was sprayed with a concentrated tea extract (sample A ') at a weight ratio of 0.2: 1. At this time, the total amount of amino acids (the above 17 types) added to brown rice was 2000 mg / kg, of which the total amount of valine, isoleucine and leucine (Val + Ile + Leu) was 460 mg / kg.
茶抽出液の噴霧によるアミノ酸含浸工程の後、150℃または230℃で焙煎処理を行った。また、対照として、茶抽出物を噴霧しないこと以外は同様にして焙煎玄米を製造した。焙煎処理条件は以下の通りである。なお、火入れ時間とは、アミノ酸含浸玄米を火入れ機に投入してから取出すまでの時間を指し、火入れ温度とは、火入れ機の釜の中の雰囲気温度を指す。
・火入れ機 : アイ・シー電子工業株式会社 TORNADE KING TypeT
・火入れ時間 : 10分
・火入れ温度 : 150℃,230℃
(3)玄米茶飲料の製造
茶抽出物(試料A)を含浸させ焙煎して得られた焙煎玄米及び対照玄米(試料Aの含浸を行わなかったもの)をそれぞれ2gずつ計量し、200gの熱湯で5分間抽出し、玄米茶飲料を得た。
After the amino acid impregnation step by spraying the tea extract, roasting was performed at 150 ° C or 230 ° C. As a control, roasted brown rice was produced in the same manner except that the tea extract was not sprayed. The roasting treatment conditions are as follows. In addition, the firing time refers to the time from when the amino acid-impregnated brown rice is put into the quenching machine until it is removed, and the firing temperature refers to the atmospheric temperature in the kettle of the firing machine.
・ Fire Maker: IC Electronics Co., Ltd. TORNADE KING TypeT
・ Taking time: 10 minutes ・ Taking temperature: 150 ℃, 230 ℃
(3) Manufacture of brown rice tea beverage 2 g each of roasted brown rice and control brown rice obtained by impregnating and roasting tea extract (sample A), and measuring 200 g For 5 minutes to obtain a brown rice tea beverage.
約60℃の玄米茶飲料について官能評価を行った。香ばしさ、甘い香り(甘香)、こげ臭について4段階で評価し、評価基準は、感じない(0点)、やや感じる(1点)、感じる(2点)、強く感じる(3点)とした。結果を表3に示す。対照の方法では、火入れ温度が低いと甘い香りが立つものの香ばしさが弱く、火入れ温度が高いと香ばしさが強くなる代わりにこげ臭が出る傾向があり、甘い香りと香ばしさを両立させることができなかった。その一方、本発明の方法、すなわち酵素処理緑茶抽出液を添加して焙煎したものは、こげ臭が少ないながらも香ばしさ、甘い香りを両立した大玄米であり、優れた香味を有する玄米茶飲料となった。 Sensory evaluation was performed on a brown rice tea beverage at about 60 ° C. The fragrance, sweet scent (sweet scent), and dark odor are evaluated in four stages, and the evaluation criteria are as follows: No feel (0 points), Somewhat feel (1 point), Feel (2 points), Strongly feel (3 points) did. The results are shown in Table 3. In the control method, a sweet scent stands at a low firing temperature, but the fragrance is weak, and a high scent tends to give a burnt odor instead of a strong scent. could not. On the other hand, the method of the present invention, that is, roasted with the addition of the enzyme-treated green tea extract, is a large brown rice that has both aroma and sweet scent while having a small burnt odor, and has an excellent flavor. It became a drink.
実施例3.容器詰め玄米茶飲料の製造
実施例2(2)で得られた玄米茶用玄米(アミノ酸として茶抽出物(試料A)を含浸して焙煎処理したもの)を用い、容器詰め玄米茶飲料を製造した。すなわち、実施例2(2)で得られた玄米茶用玄米と緑茶(煎茶)を5:5で混合したものを7g計量して250gの熱湯で5分間抽出し、茶殻を除いた後、30℃以下まで冷却して遠心分離により清澄化処理を行った後、得られたろ液に酸化防止剤としてL−アスコルビン酸を、pH調整剤として炭酸水素ナトリウムを添加してpHを6.0に調整した。その後、pH調整された抽出液を、1Lまでメスアップし、最終調合液の可溶性固形分(Brix)が0.15となるようにした。得られた調合液を缶に充填し、130℃で1分間、レトルト殺菌を行い、5℃の冷蔵庫にて冷却して容器詰め玄米茶飲料を得た。また、対照として実施例2(2)の対照(茶抽出物を噴霧しないこと以外は同様にした焙煎玄米)を用い、同様にして容器詰め飲料を製造した。
Example 3 FIG. Production of Container-packed Brown Rice Tea Beverage Brown rice tea for brown rice tea obtained in Example 2 (2) (impregnated with a tea extract (sample A) as an amino acid and roasted) was used to prepare a container-packed brown rice tea beverage. Manufactured. That is, 7 g of a mixture of brown rice for brown rice tea obtained in Example 2 (2) and green tea (sencha) in a ratio of 5: 5 was weighed and extracted with 250 g of hot water for 5 minutes. After cooling to below ℃ and clarified by centrifugation, L-ascorbic acid is added to the obtained filtrate as an antioxidant and sodium bicarbonate is added as a pH adjuster to adjust the pH to 6.0. did. Thereafter, the pH-adjusted extract was made up to 1 L so that the soluble solid content (Brix) of the final preparation was 0.15. The obtained preparation was filled in a can, retort sterilized at 130 ° C. for 1 minute, and cooled in a refrigerator at 5 ° C. to obtain a container-packed brown rice tea beverage. In addition, a container-packed beverage was produced in the same manner using the control of Example 2 (2) as a control (roasted brown rice made in the same manner except that the tea extract was not sprayed).
本発明品の容器詰め玄米茶飲料は、殺菌後にも、香ばしい香りと甘味やコク味が増強され、玄米本来の持つ香ばしさがバランスよく調和された玄米茶飲料で、加熱臭などの異味・異臭が感じられない優れた香味を有するものであった。また、冷蔵保管した後も玄米茶飲料がのり状の食感(ベトツキ感)を呈することはなく、保存後も、優れた香味と口当たりや飲用後の後味(すっきりした味)を維持していた。 The container-packed brown rice tea beverage of the present invention is a brown rice tea beverage whose fragrance, sweetness and richness are enhanced even after sterilization, and the original fragrance of brown rice is balanced in a balanced manner. It has an excellent flavor that cannot be felt. In addition, brown rice tea beverages did not exhibit a paste-like texture (tackiness) even after refrigerated storage, and maintained excellent flavor and mouthfeel and aftertaste (clean taste) even after storage .
Claims (5)
浸透処理した玄米を100〜200℃の温度で焙煎処理する工程、
を含む、玄米茶用玄米の製造方法。 A step of impregnating brown rice with an aqueous amino acid solution containing at least one amino acid (A) selected from the group consisting of leucine, valine and isoleucine, and a step of roasting the permeated brown rice at a temperature of 100 to 200 ° C. ,
A method for producing brown rice for brown rice tea.
浸透処理した玄米を100〜200℃の温度で焙煎処理する工程、
焙煎処理した玄米と緑茶とを重量比2:8〜8:2で混合する工程、および
焙煎処理した玄米と緑茶の混合物1重量部に対して5〜150重量部の水で抽出する工程、
を含む、玄米茶飲料の製造方法。 A step of impregnating raw brown rice with an aqueous amino acid solution containing at least one amino acid (A) selected from the group consisting of leucine, valine and isoleucine,
Roasting the osmotically treated brown rice at a temperature of 100 to 200 ° C.,
The step of mixing roasted brown rice and green tea in a weight ratio of 2: 8 to 8: 2, and the step of extracting with 5 to 150 parts by weight of water with respect to 1 part by weight of the mixture of roasted brown rice and green tea ,
A method for producing brown rice tea beverages.
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JPS503399B2 (en) * | 1972-01-19 | 1975-02-04 | ||
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JPS596867A (en) * | 1982-07-02 | 1984-01-13 | Hitachiya Honpo:Kk | Preparation of barley water for cold water |
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JPH0763315B2 (en) * | 1988-05-25 | 1995-07-12 | 興亜製茶株式会社 | Method for producing powdered green tea containing matcha and powdered green tea containing green tea obtained thereby |
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JP2005204527A (en) * | 2004-01-21 | 2005-08-04 | Tsuboichi Seicha Honpo:Kk | Green tea, and method for producing the same |
US7232585B2 (en) * | 2004-06-24 | 2007-06-19 | Xel Herbaceuticals, Inc. | Green tea formulations and methods of preparation |
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