JP5354633B1 - Function enhancement and function recovery method of inorganic material or organic material using humic liquid produced by organic acid - Google Patents

Function enhancement and function recovery method of inorganic material or organic material using humic liquid produced by organic acid Download PDF

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JP5354633B1
JP5354633B1 JP2013013799A JP2013013799A JP5354633B1 JP 5354633 B1 JP5354633 B1 JP 5354633B1 JP 2013013799 A JP2013013799 A JP 2013013799A JP 2013013799 A JP2013013799 A JP 2013013799A JP 5354633 B1 JP5354633 B1 JP 5354633B1
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JP2014145016A (en
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賢治 田中
義行 飛田和
秀治 飛田和
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Japan Conservation Engineers Co Ltd
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Abstract

【課題】
一般的に鹿沼土に代表される無機質および有機質資材は,農地,林地,海域へ投与されることによって環境を改善することができるが,時間経過に伴い団粒化の促進や酸性土壌への移行の効果が低下していくことが広く知られている。これらの資材の持つ機能が低下することから,投与によって改善した環境を維持する為に,農地,林地,海域に対して、さらに同じ資材を投入し続けていた経緯がある。
また,投与する無機,有機資材については,その機能が低下すると廃材として処分に困っていた。
【解決手段】
本発明は,木,草,残滓等の未分解の有機物を炭の製造過程で産出される極強酸性の酢液(有機酸)に木,草,残滓等の未分解の有機物を適量漬け込み,長期間養生することで製造される腐植液を用いて,機能低下している無機質資材又は有機質資材の機能を増進及び機能回復することを可能とした構成。
【選択図】 図1
【Task】
In general, inorganic and organic materials such as Kanuma soil can improve the environment by being applied to agricultural land, forest land, and sea area. It is well known that the effects of Since the functions of these materials have declined, there has been a history of continuing to add the same materials to farmland, forest land, and sea areas in order to maintain an environment improved by administration.
In addition, the inorganic and organic materials to be administered had difficulty in disposal as waste materials when their functions deteriorated.
[Solution]
In the present invention, an undecomposed organic matter such as wood, grass, and residue is soaked in an appropriate amount of undegraded organic matter such as wood, grass, and residue in an extremely acidic vinegar (organic acid) produced during the production of charcoal. A configuration that allows the function of inorganic or organic materials that have been degraded to be enhanced and restored using humic liquid produced by curing for a long period of time.
[Selection] Figure 1

Description

本発明は,極強酸性の有機酸である木酢液,又は竹酢液に木,草,残滓等の未分解の有機物を漬け込むことによって製造されるのが腐植液であり,機能を改善する有機物も同じ有機物である。しかし,未分解の有機物を有機酸に漬けることで,腐植液ができ,その腐植液を未分解の有機物にしみ込ませると機能が高めることができる。つまり,有機酸は,未分解の有機物と反応して腐植変化するのである。 The present invention is a humic solution produced by immersing undegraded organic materials such as wood, grass, and residue in a wood vinegar solution or bamboo vinegar solution, which is a highly acidic organic acid, and an organic material that improves its function. Is the same organic matter. However, humus liquid can be made by soaking undecomposed organic matter in organic acid, and its function can be improved by soaking the humic liquid in undegraded organic matter. In other words, organic acids react with undegraded organic matter and change humus.

一般的に鹿沼土に代表される無機質および有機質資材は,農地,林地,海域へ投与されることによって環境を改善することができるが,時間経過に伴い団粒化の促進や酸性土壌への移行の効果が低下していくことが広く知られている。これらの資材の持つ機能が低下することから,農地,林地,海域に対して更に同じ資材を投入し続けて改善した環境を維持していた経緯がある。
また,投与する無機質,有機質資材については,その機能が低下すると廃材として処分に困っていた。
In general, inorganic and organic materials such as Kanuma soil can improve the environment by being applied to agricultural land, forest land, and sea area. It is well known that the effects of Since the functions of these materials have declined, there has been a history of maintaining an improved environment by continuing to add the same materials to agricultural land, forest land and sea areas.
In addition, the inorganic and organic materials to be administered had difficulty in disposal as waste materials when their functions deteriorated.

特開平11―090478公開公報Japanese Patent Laid-Open No. 11-090478 特開平11−090468公開公報Japanese Patent Laid-Open No. 11-090468

上記の特許文献1は、有機性廃水を、脱臭も含めて、植物に有害な成分を消失させた処理水と、有益微生物を保持育成する団粒の多い処理汚泥することにより、短時間で安全に土に戻すことができる腐植ペレットによる有機性廃水の処理方法を提供するものであるが、先ず特許文献1の内容が有機性廃水の処理方法であるのと比較すると,本発明は無機質資材,又は有機質資材に腐植液をしみ込ませることによって,その資材そのものの性質を改善して用いることを主目的にしていることに大きな違いがある。また,微生物を用いないことも異なっている。
特許文献2は、有機廃棄物中の有機物の生物学的な分解能力が高い共に、有機物から発生する悪臭を減少または除去することができる微生物材料を提供するものであるが、本発明では微生物群を利用しないことに大きな違いがある。
また,特許文献2の発明は,有機物から発生する悪臭を無くすことに主眼が置かれた発明であり,本発明で無機質資材又は有機質資材に腐植液をしみ込ませることによって,その資材そのものの性質を改善して用いることを主目的にしているのとは大きな違いがある。
Patent Document 1 discloses that organic wastewater is safely treated in a short time by treating treated water from which harmful components to plants, including deodorization, have been eliminated, and treated sludge having a large number of aggregates that retain and grow beneficial microorganisms. The organic wastewater treatment method using humus pellets that can be returned to the soil is provided. First, the content of Patent Document 1 is compared with the organic wastewater treatment method. Another major difference is that the main purpose is to improve the properties of the material itself by impregnating it with organic material. Another difference is that no microorganisms are used.
Patent Document 2 provides a microbial material that has a high biological decomposition ability of organic matter in organic waste and can reduce or eliminate malodor generated from the organic matter. There is a big difference in not using.
The invention of Patent Document 2 is an invention that focuses on eliminating malodors generated from organic substances. By impregnating humic liquid into inorganic materials or organic materials according to the present invention, the properties of the materials themselves can be obtained. There is a big difference from the main purpose of improving.

そこで,本発明は,木,草,残滓等の未分解の有機物を炭の製造過程で産出される極強酸性の酢液(有機酸)に木,草,残滓等の未分解の有機物を適量漬け込み,長期間養生することで製造される腐植液を用いて,機能低下している無機質資材又は有機質資材の機能を増進すること,及び/又は機能を回復することを可能としたものである。   Accordingly, the present invention provides an appropriate amount of undecomposed organic matter such as wood, grass, and residue to the extremely acidic vinegar (organic acid) produced during the charcoal production process. By using humus liquid produced by soaking and curing for a long time, it is possible to improve and / or restore the function of inorganic or organic materials whose function has been reduced.

本発明の第1は,有機酸によって製造された腐植液を用いた無機・有機資材の機能増進および機能回復方法において,木,草,残滓等の未分解の有機物を炭の製造過程で産出される極強酸性の酢液(有機酸)に適量漬け込み,長期間養生することで製造される腐植液を用いて,無機又は有機物の機能を増進及び/又は機能回復できるようにしたものである。   The first aspect of the present invention is a method for enhancing and recovering the function of inorganic and organic materials using humic liquid produced by an organic acid. In this method, undecomposed organic matter such as wood, grass and residue is produced in the process of charcoal production. It is possible to enhance and / or restore the function of inorganic or organic substances by using a humic solution produced by immersing an appropriate amount in an extremely acidic vinegar (organic acid) and curing for a long time.

本発明の第2は,第1の発明に係る有機酸によって製造された腐植液を用いた無機・有機資材の機能増進および機能回復方法において,腐植液を対象となる無機質資材又は有機質資材の容量換算で100%に対し,容量換算70%以下の液体をしみ込ませることによって,腐植液の有機酸による化学的緩衝機能や還元機能,凝集効果による団粒化機能を付加したことにある。   According to a second aspect of the present invention, there is provided a method for enhancing and recovering the function of inorganic and organic materials using a humic solution produced by the organic acid according to the first invention, and the capacity of the inorganic material or organic material targeted for the humic solution. By impregnating a liquid with a volume conversion of 70% or less with respect to 100% in terms of conversion, a chemical buffering function, a reduction function, and an agglomeration function with an agglomeration effect by an organic acid in the humic liquid are added.

本発明の第3は,第1の発明に係る有機酸によって製造された腐植液を用いた無機質資材又は有機資材の機能増進および機能回復方法において,腐植液は,水分量が80%以上,有機酸含有量が1.0%以上のものを用いるようにしたことにある。   According to a third aspect of the present invention, in the method for enhancing and recovering the function of an inorganic material or organic material using a humic solution produced by the organic acid according to the first invention, the humic solution has a water content of 80% or more, an organic material. This is because an acid content of 1.0% or more is used.

本発明の第4は,第1の発明に係る有機酸によって製造された腐植液を用いた無機質資材又は有機質資材の機能増進および機能回復方法において,腐植液は,pH(H2O)5.0以下で電気伝導度が1.0mS/cm以上のものを用いるようにしたことにある。 According to a fourth aspect of the present invention, in the method for enhancing and recovering the function of an inorganic material or an organic material using a humus solution produced by the organic acid according to the first invention, the humus solution has a pH (H 2 O) of 5. This is because a material having an electric conductivity of 1.0 mS / cm or more at 0 or less is used.

本発明の第5は,第1の発明に係る有機酸によって製造された腐植液を用いた無機質資材又は有機質資材の機能増進および機能回復方法において,腐植液は,酸化還元電位で250mV以下の還元電位のものを用いるようにしたことにある。 According to a fifth aspect of the present invention, in the method for enhancing and recovering the function of an inorganic material or an organic material using a humic solution produced by the organic acid according to the first invention, the humic solution is reduced at a redox potential of 250 mV or less. This is because the electric potential is used.

本発明の第6は,第1の発明に係る有機酸によって製造された腐植液を用いた無機質資材又は有機質資材の機能増進および機能回復方法において,腐植液は,粒径φが1.0mm以下の固形物しか含まれていないものを用いるようにしたことにある。   According to a sixth aspect of the present invention, in the method for enhancing and recovering the function of an inorganic material or an organic material using a humus solution produced by the organic acid according to the first invention, the humus solution has a particle diameter φ of 1.0 mm or less. In other words, the one containing only the solid matter is used.

本発明の第7は,第1の発明に係る有機酸によって製造された腐植液を用いた無機質資材又は有機質資材の機能増進および機能回復方法において,腐植液は,その濃度を10倍以上に希釈したものを用いるようにしたことにある。   According to a seventh aspect of the present invention, in the method for enhancing and recovering the function of an inorganic material or organic material using a humic solution produced by the organic acid according to the first invention, the concentration of the humic solution is diluted 10 times or more. It is to use what I did.

本発明の第8は,第1の発明に係る有機酸によって製造された腐植液を用いた無機質又は有機質資材の機能増進および機能回復方法において,腐植液は,木質系の有機質資材のみならず,魚介類から抽出した酸性溶液を用いるようにしたものである。   According to an eighth aspect of the present invention, in the method for enhancing and recovering the function of an inorganic or organic material using a humic solution produced by the organic acid according to the first invention, the humic solution is not limited to a wooden organic material, An acidic solution extracted from seafood is used.

本発明の第9は,第1の発明に係る有機酸によって製造された腐植液を用いた無機質又は有機質資材の機能増進および機能回復方法において,腐植液には,窒素,リン,カルシウム,マグネシウム,カリウム,ナトリウム,鉄,マンガン等のミネラルを添加することでミネラルの供給も可能としたものである。   According to a ninth aspect of the present invention, in the method for enhancing and recovering the function of an inorganic or organic material using a humus solution produced by the organic acid according to the first invention, the humus solution includes nitrogen, phosphorus, calcium, magnesium, Minerals can be supplied by adding minerals such as potassium, sodium, iron and manganese.

本願発明は上記の構成であることから,次の効果がある。
すなわち,極強酸性の有機酸である木酢液,又は竹酢液に木,草,残滓等の未分解の有機物を漬け込むことによって製造されるのが腐植液であり,機能を改善する有機物も同じ有機物である。しかし,未分解の有機物を有機酸に漬けることで,腐植液ができ,その腐植液を未分解の有機物にしみ込ませると機能が高める効果がある。つまり,有機酸は,未分解の有機物と反応して腐植変化するのである。
Since the present invention has the above configuration, the following effects are obtained.
In other words, humus liquid is produced by immersing undegraded organic materials such as wood, grass, and residue in bamboo vinegar or bamboo vinegar, which is a highly acidic organic acid, and the same is true for organic substances that improve functions. Organic matter. However, by soaking undecomposed organic matter in an organic acid, a humus solution is formed, and soaking the humic solution in the undecomposed organic matter has the effect of improving the function. In other words, organic acids react with undegraded organic matter and change humus.

また,各々の資材の機能が上がるのに加えて,廃材の再生利用も可能となった。   In addition to improving the functions of each material, it is also possible to recycle waste materials.

そして,本発明にあっては,木,又は草,又は野菜屑,又は落葉落枝の未分解の有機物を炭の製造過程で産出される極強酸性の酢液(有機酸)に漬け込むことから,未分解の有機物も腐植化することから利用が可能であることにより廃棄物が発生しないので,周辺環境への負荷が少ないという効果がある。   And in the present invention, since the undecomposed organic matter of wood, grass, vegetable waste, or litter is immersed in the extremely acidic vinegar (organic acid) produced in the process of charcoal production, Since undecomposed organic matter is also humus, it can be used and no waste is generated.

図1は、本発明の実施工程を示す概略説明図である。FIG. 1 is a schematic explanatory view showing an implementation process of the present invention.

本発明に係る腐植液の利用形態は,次の2通りが考えられる。
すなわち,機能増進及び/又は回復する無機質資材又は有機質資材に対して容量換算で70%以下の腐植液を散布,または,5時間以上漬け込むことによって,腐植液の化学的緩衝機能や還元機能,凝集効果による団粒化機能を加えることが可能である。
The following two ways of using the humic liquid according to the present invention can be considered.
In other words, by spraying 70% or less of humic solution in terms of volume on inorganic or organic materials that promote and / or recover functions, or submerge for more than 5 hours, the chemical buffering function, reducing function, and aggregation of humic liquid It is possible to add an agglomeration function by effect.

腐植液を無機質資材又は有機質資材にしみ込ませることにより,固体での利用が可能である。   It can be used in solid form by impregnating humic liquid into inorganic or organic materials.

次に,本発明の実施例を説明する。図1において,1は無機質資材又は有機質資材であり,具体的には,無機質資材として,鹿沼土,又は赤玉土,又はマサ土,又はゼオライト,又は軽石(スコリア),又はマサ土がある。また,有機質資材としては,ピートモス,又はココピート,又は草炭,又は泥炭,又はバーク堆肥,又は炭があるが,本発明にあっては,木,又は草,木,又は草,又は野菜屑,又は落葉落枝の未分解の有機物が用いられている。同じ未分解の有機物原料であっても,最初の有機資材は腐植液を作る原料で,後の有機物はそれをしみ込ませて機能を高める資材となる。上記の「未分解」とは、草,木などが朽ちたりせずに,その原型を留めていることを意味している。無機質資材においても同様である。
2は腐植液であり,粒径φが1.0mm以下の固形物しか含まれていないものを用いるものである。
Next, examples of the present invention will be described. In FIG. 1, reference numeral 1 denotes an inorganic material or an organic material. Specifically, examples of the inorganic material include Kanuma soil, Akadama soil, Masa soil, zeolite, pumice (scoria), or Masa soil. The organic material includes peat moss, coco pate, grass charcoal, peat, bark compost, or charcoal. In the present invention, wood, grass, wood, grass, vegetable scrap, or Undecomposed organic matter of litter is used. Even with the same undegraded organic material, the first organic material is a raw material that makes humus liquid, and the later organic material soaks it into a material that enhances its function. The above "undecomposed" means that grass, trees, etc. are kept intact without declining. The same applies to inorganic materials.
Numeral 2 is a humus liquid that uses only solids having a particle diameter φ of 1.0 mm or less.

上記の腐植液2は,水分量が80%以上,有機酸含有量が1%以上のものを用いるようにしてある。当該「有機酸」は,具体的には木酢液,又は竹酢液を用いる。
また,腐植液2は,pH(H2O)5.0以下で電気伝導度が1.0mS/cm以上のものを用いる。
次いで,腐植液2は,酸化還元電位で250mV以下の還元電位のものを用いるようにしてある。
続いて,腐植液2は,粒径が1.0mm以下の固形物しか含まれていないものを用いるようにしてある。
さらに,腐植液2は,その濃度を10倍以上に希釈したものを用いるようにしてある。
また,腐植液は,木質系の有機質資材のみならず魚介類から抽出した酸性溶液を用いるようにしてある。
そして,当該腐植液2には,窒素,リン,カルシウム,マグネシウム,カリウム,ナトリウム,鉄,マンガン等のミネラルを添加することでミネラルの供給も可能である。
The humic solution 2 has a water content of 80% or more and an organic acid content of 1% or more. Specifically, wood vinegar or bamboo vinegar is used as the “organic acid”.
The humic solution 2 is one having a pH (H 2 O) of 5.0 or less and an electric conductivity of 1.0 mS / cm or more.
Next, as the humus liquid 2, a redox potential having a reduction potential of 250 mV or less is used.
Subsequently, as the humus liquid 2, a liquid containing only solids having a particle size of 1.0 mm or less is used.
Further, the humic solution 2 is diluted with a concentration 10 times or more.
The humic solution is not only a woody organic material but also an acidic solution extracted from seafood.
The humic liquid 2 can be supplied with minerals by adding minerals such as nitrogen, phosphorus, calcium, magnesium, potassium, sodium, iron, and manganese.

3は容器であり,当該容器には,酢液を可とする有機酸を,無機質資材や有機質資材1を十分に漬け込める量で収容してある。
容器3に入っている腐植液2に無機質資材又は有機質資材1を漬け込む。その腐植液は,水分が80%以上,有機酸含有量が1.0%以上でpH(H2O)5.0以下,電気伝導度が1.0mS/cm以上のものを利用する。
Reference numeral 3 denotes a container, which contains an organic acid capable of vinegar in an amount sufficient to immerse the inorganic material or the organic material 1.
The inorganic material or organic material 1 is soaked in the humic liquid 2 contained in the container 3. As the humus liquid, one having a water content of 80% or more, an organic acid content of 1.0% or more, a pH (H 2 O) of 5.0 or less, and an electric conductivity of 1.0 mS / cm or more is used.

「具体的な施工例における施工順序」
(1) 容器3に入れる無機質資材又は有機質資材1に対して,容量換算で50%の腐植液2を混合する。
(2) そして,容器3内に投入する当該無機質資材又は有機質資材を少なくとも5時間以上,腐植液2に漬け込んで養生期間をおく。
(3) もう一つの方法では,無機質資材又は有機質資材1に対して,腐植液2を散布して含水率(%)で70%以上となるまで散布を続ける。
"Construction order in specific construction examples"
(1) Mix 50% of the humic liquid 2 in terms of volume with the inorganic material or organic material 1 put in the container 3.
(2) And the said inorganic material or organic material thrown in in the container 3 is immersed in the humic liquid 2 for at least 5 hours or more, and a curing period is given.
(3) In another method, humic solution 2 is sprayed on inorganic material or organic material 1 and spraying is continued until the moisture content (%) becomes 70% or more.

本発明は,木,草,残滓等の未分解の有機物を炭の製造過程で産出される極強酸性の酢液(有機酸)に木,草,残滓等の未分解の有機物を適量漬け込み,長期間養生することで製造される腐植液を用いて,機能低下している無機質資材又は有機質資材の機能を増進および回復することが可能となった。   In the present invention, an undecomposed organic matter such as wood, grass, and residue is soaked in an appropriate amount of undegraded organic matter such as wood, grass, and residue in an extremely acidic vinegar (organic acid) produced during the production of charcoal. Using the humic liquid produced by curing for a long period of time, it has become possible to enhance and recover the function of inorganic or organic materials whose function has been reduced.

1…無機質資材又は有機質資材
2…腐植液(極強酸性木酢液又は竹酢液(有機酸))
3…容器

1 ... Inorganic material or organic material 2 ... Humic liquid (extremely acidic wood vinegar or bamboo vinegar (organic acid))
3 ... Container

Claims (9)

木,又は草,又は野菜屑,又は落葉落枝の未分解の有機物を炭の製造過程で産出される極強酸性の有機酸である木酢液又は竹酢液に適量漬け込み,長期間養生することで製造される腐植液を無機質資材又は有機質資材にしみ込ませることにより,無機質資材又は有機質資材に腐植酸の機能である化学的緩衝能力や還元機能,凝集効果による団粒化の機能を付加することを特徴とする無機質資材又は有機質資材の機能増進および機能回復方法。 By immersing an appropriate amount of undecomposed organic matter from wood, grass, vegetable waste, or litter, into wood vinegar or bamboo vinegar, which is a very acidic organic acid produced during the charcoal production process, and curing for a long time. By impregnating the produced humus liquid into inorganic or organic materials, it is possible to add the chemical buffering capacity, the reducing function , and the function of agglomeration due to the agglomeration effect , which are functions of humic acid, to the inorganic or organic materials. A function enhancement and function recovery method of a characteristic inorganic material or organic material. 腐植液を対象となる無機質資材又は有機質資材の容量換算で100%に対し,容量換算70%以下の液体をしみ込ませることによって,腐植液の有機酸による化学的緩衝機能や還元機能,凝集効果による団粒化機能を付加するようにした請求項1記載の無機質資材又は有機質資材の機能増進および機能回復方法。   By impregnating the liquid of 70% or less in volume conversion with respect to 100% of the volume conversion of inorganic or organic material targeted for humic liquid, the chemical buffer function, reduction function, and aggregation effect of organic acid in humic liquid The function enhancement and function recovery method of an inorganic material or an organic material according to claim 1, wherein a function of aggregating is added. 腐植液は,水分量が80%以上,有機酸含有量が1%以上のものを用いるようにした請求項1記載の無機質資材又は有機質資材の機能増進および機能回復方法。   2. The method for enhancing and recovering the function of an inorganic material or an organic material according to claim 1, wherein the humic solution has a water content of 80% or more and an organic acid content of 1% or more. 腐植液は,pH(HO)5.0以下で電気伝導度が1.0mS/cm以上のものを用いるようにした請求項1記載の無機・有機資材の機能増進および機能回復方法。 The method for enhancing and recovering the function of inorganic and organic materials according to claim 1, wherein the humus solution has a pH (H 2 O) of 5.0 or less and an electric conductivity of 1.0 mS / cm or more. 腐植液は,酸化還元電位で250mV下の還元電位のものを用いるようにした請求項1記載の無機質資材又は有機質資材の機能増進および機能回復方法。   The method for enhancing and recovering the function of an inorganic material or an organic material according to claim 1, wherein the humic solution has a reduction potential of 250 mV at the oxidation-reduction potential. 腐植液は,粒径が1.0mm以下の固形物しか含まれていないものを用いるようにした請求項1記載の無機質資材又は有機質資材の機能増進および機能回復方法。   2. The method for enhancing and recovering the function of an inorganic material or an organic material according to claim 1, wherein the humic liquid contains only a solid having a particle size of 1.0 mm or less. 腐植液は,その濃度を10倍以上に希釈したものを用いるようにした請求項1記載の無機質資材又は有機質資材の機能増進および機能回復方法。   The method for enhancing and restoring the function of an inorganic material or an organic material according to claim 1, wherein the humic solution is diluted 10 times or more. 腐植液は,木質系の有機質資材のみならず魚介類から抽出した酸性溶液を用いるようにした請求項1記載の無機質資材又は有機質資材の機能増進および機能回復方法。   2. The method for enhancing and restoring the function of an inorganic material or an organic material according to claim 1, wherein the humic solution is an acidic solution extracted from fish and shellfish as well as a wooden organic material. 腐植液には,窒素,リン,カルシウム,マグネシウム,カリウム,ナトリウム,鉄,マンガン等のミネラルを添加することでミネラルの供給も可能とした請求項1記載の無機質資材又は有機質資材の機能増進および機能回復方法。
The function enhancement and function of the inorganic or organic material according to claim 1, wherein the humic liquid can be supplied with minerals such as nitrogen, phosphorus, calcium, magnesium, potassium, sodium, iron and manganese. Recovery method.
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