JP5305586B2 - Ground injection agent and ground injection method using the same - Google Patents

Ground injection agent and ground injection method using the same Download PDF

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JP5305586B2
JP5305586B2 JP2006331822A JP2006331822A JP5305586B2 JP 5305586 B2 JP5305586 B2 JP 5305586B2 JP 2006331822 A JP2006331822 A JP 2006331822A JP 2006331822 A JP2006331822 A JP 2006331822A JP 5305586 B2 JP5305586 B2 JP 5305586B2
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agent
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ground
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JP2008144017A (en
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俊一 三島
康宏 中島
貴光 室川
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Denka Co Ltd
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Denki Kagaku Kogyo KK
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/06Inhibiting the setting, e.g. mortars of the deferred action type containing water in breakable containers ; Inhibiting the action of active ingredients
    • C04B40/0641Mechanical separation of ingredients, e.g. accelerator in breakable microcapsules
    • C04B40/065Two or more component mortars
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00732Uses not provided for elsewhere in C04B2111/00 for soil stabilisation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/70Grouts, e.g. injection mixtures for cables for prestressed concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Consolidation Of Soil By Introduction Of Solidifying Substances Into Soil (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Description

本発明は、各種土木工事における地盤改良工事や止水工事で用いられる地盤注入剤及びそれを用いた地盤注入工法に関する。   The present invention relates to a ground injecting agent used in ground improvement work and water stop work in various civil engineering works and a ground pouring method using the same.

トンネル土木や都市土木等で、地山や地盤の安定化を図るために、薬液型の地盤注入剤が用いられてきた。この地盤注入剤には、セメント系粒子を含有する懸濁型と、セメント系粒子を含有しない溶液型が知られている。   In order to stabilize natural ground and ground in tunnel civil engineering and urban civil engineering, chemical-type ground injection agents have been used. As this ground injection agent, a suspension type containing cementitious particles and a solution type not containing cementitious particles are known.

懸濁型は、強度発現性が優れるといったメリットを有する反面、薬液の浸透性が低いので粒子間隔の小さい緻密な砂質層に適さなかった。懸濁型の中でもセメント系注入剤はゲルタイムが長いため止水工事に適さなかった。   The suspension type has the merit that the strength development is excellent, but the penetrability of the chemical solution is low, so that it is not suitable for a dense sandy layer having a small particle interval. Among the suspension types, cement-based injectants were not suitable for waterstop work because of their long gel times.

一方、溶液型は、薬液の浸透性が高いので粒子間隔の小さい緻密な砂質層や止水工事に適している。
溶液型注入剤は、水に溶解する化合物を用いる注入剤であり、有機溶液、酸、及びアルカリ溶液を単体又は複合して使用するものである(特許文献1〜6参照)。
特開昭52−113505号公報 特公昭57−047226号公報 特開昭52−087807号公報 特開昭51−082913号公報 特開昭52−120507号公報 特開昭57−195786号公報
On the other hand, the solution type is suitable for a dense sandy layer having a small particle interval and water-stopping work because it has high chemical permeability.
The solution-type injection is an injection that uses a compound that dissolves in water, and uses an organic solution, an acid, and an alkaline solution alone or in combination (see Patent Documents 1 to 6).
JP 52-11505 A Japanese Examined Patent Publication No. 57-047226 JP 52-087807 A Japanese Patent Laid-Open No. 51-082913 JP-A-52-120507 JP-A-57-195786

上記のような溶液型注入剤に用いられる無機塩としては、例えば炭酸塩、塩化物、硫酸塩、ホウ酸塩、及びリン酸塩が知られている。有機溶液としては、エステル類−酢酸モノエーテルグリコール、プロピレンカーボネート、アルデヒド類−ホルムアルデヒド、ギ酸メチル、及びグリオキザール等が挙げられる。酸としては硫酸が挙げられる。   As inorganic salts used in the above-described solution-type injections, for example, carbonates, chlorides, sulfates, borates, and phosphates are known. Examples of the organic solution include esters-acetic acid monoether glycol, propylene carbonate, aldehydes-formaldehyde, methyl formate, and glyoxal. Examples of the acid include sulfuric acid.

また、注入後、直に注入物がゲル化して地盤を安定化させるものが求められているが、「(1)ケイ酸ソーダ、(2)グリオキサール、(3)水溶性のアルミニウム塩、および(4)水溶性の有機酸、水溶性の無機酸および水溶性の酸性無機塩のうちの少なくとも一種、が添加された水性混合液」を用いた地盤注入剤の発明(特許文献7)に挙げられるように、主剤と反応剤を混合してからゲル化するまでに数分を要するようなものであった。
特開昭62−199684号公報
In addition, there is a demand for a product that gels immediately after injection and stabilizes the ground. However, “(1) sodium silicate, (2) glyoxal, (3) water-soluble aluminum salt, and ( 4) Invention of ground injecting agent using a water-soluble organic acid, an aqueous mixed solution to which at least one of a water-soluble inorganic acid and a water-soluble acidic inorganic salt is added ”(Patent Document 7) As described above, it took several minutes from the mixing of the main agent and the reactant to gelation.
JP-A 62-199684

さらに、特許文献8〜10には、水ガラスと酸性材を有効成分として含有するゲルタイムの調整可能な地盤注入剤の発明が開示され、酸として、酢酸、クエン酸、グルコン酸等の有機酸を用いることが記載されている(特許文献8の段落[0043]、段落[0094]の表2、特許文献9の段落[0048]、段落[0103]、特許文献10の段落[0052]、段落[0117]の表2)が、ゲルタイムを調整するために、有機酸塩(カルボン酸塩)を用いることは示されていない。
特開2004−196915号公報 特開2004−196922号公報 特開2005−75899号公報
Further, Patent Documents 8 to 10 disclose an invention of a ground injection capable of adjusting gel time containing water glass and an acidic material as active ingredients, and an organic acid such as acetic acid, citric acid or gluconic acid is used as the acid. (Patent Document 8, Paragraph [0043], Paragraph [0094] Table 2, Paragraph [0048], Paragraph [0048], Paragraph [0103], Patent Document 10, Paragraph [0052], Paragraph [ [0117] Table 2) does not show the use of organic acid salts (carboxylates) to adjust the gel time.
JP 2004-196915 A JP 2004-196922 A JP-A-2005-75899

また、特許文献11には、「アルカリ金属珪酸塩を含有する水溶液のA剤と、アルカリ金属アルミン酸塩と有機酸を含有する水溶液のB剤とからなる地盤注入剤。」(請求項1)の発明において、クエン酸ソーダを用いることが示されているが、このクエン酸ソーダは、クエン酸、グルコン酸、リンゴ酸、酒石酸等の有機酸と同等のものとして示されている(段落[0014]、[0021]、[0027]、[0028])だけであり、特にゲルタイムを調整するために用いるものではなく、また、「アルカリ金属アルミン酸塩」という特定の反応剤を必須とするものであるから、アルカリ金属珪酸塩と、「アルカリ金属アルミン酸塩」以外の無機塩を用いた場合のゲルタイムを調整するために、クエン酸ソーダを用いることを示唆するものではない。
特開2005−146161号公報
Further, Patent Document 11 discloses a “ground injection agent comprising an aqueous solution A containing an alkali metal silicate and an aqueous solution B containing an alkali metal aluminate and an organic acid” (Claim 1). In this invention, it is shown that sodium citrate is used, and this sodium citrate is shown as being equivalent to organic acids such as citric acid, gluconic acid, malic acid, tartaric acid (paragraph [0014]. ], [0021], [0027], [0028]), and is not particularly used for adjusting the gel time, and also requires a specific reagent called “alkali metal aluminate”. Therefore, it is suggested to use sodium citrate to adjust the gel time when using inorganic salts other than alkali metal silicate and "alkali metal aluminate". Not.
JP 2005-146161 A

特許文献12にも、「アルカリ金属珪酸塩を含有する水溶液のA剤と、アルカリ金属アルミン酸塩、アルカリ金属炭酸塩、及び有機酸を含有する水溶液のB剤とからなる地盤注入剤。」(請求項1)の発明において、クエン酸ソーダを用いることが示されているが、このクエン酸ソーダは、クエン酸、グルコン酸、リンゴ酸、酒石酸等の有機酸と同等のものとして示されている(段落[0015]、[0022]、[0028]、[0029])だけであり、特にゲルタイムを調整するために用いるものではなく、また、「アルカリ金属アルミン酸塩、アルカリ金属炭酸塩」という特定の反応剤を必須とするものであるから、アルカリ金属珪酸塩と、「アルカリ金属アルミン酸塩、アルカリ金属炭酸塩」以外の無機塩を用いた場合のゲルタイムを調整するために、クエン酸ソーダを用いることを示唆するものではない。
特開2005−146163号公報
Patent Document 12 also discloses a “ground injection agent composed of an aqueous solution A containing an alkali metal silicate and an aqueous solution B containing an alkali metal aluminate, an alkali metal carbonate, and an organic acid.” In the invention of claim 1), it is shown that sodium citrate is used, but this sodium citrate is shown to be equivalent to organic acids such as citric acid, gluconic acid, malic acid, tartaric acid and the like. (Paragraphs [0015], [0022], [0028], [0029]), not specifically used to adjust the gel time, and also specified as “alkali metal aluminate, alkali metal carbonate” In this case, the gel tie when using an alkali metal silicate and an inorganic salt other than “alkali metal aluminate, alkali metal carbonate” is essential. To adjust, not intended to suggest that the use of sodium citrate.
JP 2005-146163 A

さらに、これらの技術では、ゲルタイムを調製するのに、反応剤の種類を変えたり、主剤と反応剤の混合割合を変える必要があった。施工現場では、2連式の注入ポンプで主剤と反応剤を別々に圧送して使用することが多いが、2連式のポンプではその構造上、主剤と反応剤は等容積での圧送となり、例えば反応剤の種類は1種類で、その濃度を変えることでゲルタイムが調整できるようなものが利便性が高く、求められていた。   Further, in these techniques, it is necessary to change the kind of the reactant or the mixing ratio of the main agent and the reactant in order to prepare the gel time. At the construction site, the main agent and the reactant are often separately pumped and used with a double injection pump. However, due to the structure of the dual pump, the main agent and the reactant are pumped in equal volumes. For example, there is one kind of reactant, and it is highly convenient that the gel time can be adjusted by changing its concentration.

本発明は、ゲルタイムの調整が容易で、硬化後の溶液の流出が少ない地盤注入剤及びそれを用いた地盤注入工法を提供することを課題とする。   It is an object of the present invention to provide a ground injecting agent in which gel time can be easily adjusted and the outflow of a solution after curing is small, and a ground injecting method using the same.

本発明者は種々検討を重ねた結果、特定の反応剤を使用することにより、水ガラス系溶液型注入剤の中でもゲルタイムの調整が容易で、硬化後の溶液の流出が少ない注入剤が得られるという知見を得て本発明を完成するに至った。   As a result of repeated studies by the present inventors, by using a specific reactant, it is easy to adjust the gel time among water glass-based solution-type injections, and an injection with less outflow of the solution after curing can be obtained. As a result, the present invention has been completed.

本発明は、上記課題を解決するために、以下の手段を採用する。
(1)アルカリ金属珪酸塩を含有するアルカリ性水溶液のA剤と、水溶性マグネシウム塩とクエン酸ナトリウム及び/又はクエン酸カリウムを含有する酸性水溶液のB剤を用いた地盤注入剤であって、前記アルカリ金属珪酸塩が珪酸ナトリウムであり、前記水溶性マグネシウム塩が硫酸マグネシウムであり、前記B剤中、前記水溶性マグネシウム塩が2.1〜3.1%で、前記クエン酸ナトリウム及び/又はクエン酸カリウムが2.1〜7.5%(但し、「重炭酸ソーダおよび/または重炭酸カリ100重量部に対しマグネシウムの硫酸塩、塩化物の単独または混合物(無水物換算)5〜100重量部、クエン酸のソーダ塩,カリウム塩の単独または混合物3〜200重量部よりなる成分」を除く。)で、前記B剤の固形分濃度が4.2〜10.0%である地盤注入剤である。
(2)前記水溶性マグネシウム塩100部に対して、前記クエン酸ナトリウム及び/又はクエン酸カリウム(以下、カルボン酸塩という)を50〜200部含有する前記(1)の地盤注入剤である。
)前記(1)又は(2)に記載のA剤とB剤とを別々に圧送し、注入口付近で合流混合する地盤注入工法である。
)前記A剤とB剤の混合比率が容積比で20:80〜80:20である前記()の地盤注入工法である。
)前記B剤の固形分濃度30〜50%の水溶液の原液を希釈して、ゲルタイムを調整する前記()又は()の地盤注入工法である。
なお、本発明における部や%は、特に規定のない限り質量基準である。
The present invention employs the following means in order to solve the above problems.
(1) and A dosage of the alkaline aqueous solution containing an alkali metal silicate, a ground infusate with B agent of an acidic aqueous solution containing sodium water soluble magnesium salt and citric acid and / or potassium citrate, said The alkali metal silicate is sodium silicate, the water-soluble magnesium salt is magnesium sulfate, and in the agent B, the water-soluble magnesium salt is 2.1 to 3.1%, and the sodium citrate and / or potassium citrate is 2.1. ~ 7.5% (However, "sodium bicarbonate and / or potassium bicarbonate 100 parts by weight magnesium sulfate, chloride alone or in mixture (anhydride equivalent) 5-100 parts by weight, citric acid soda salt, potassium salt Or a mixture of 3 to 200 parts by weight of the mixture "), and the solid injection concentration of the B agent is 4.2 to 10.0%.
(2) The ground injecting agent according to (1), comprising 50 to 200 parts of the sodium citrate and / or potassium citrate (hereinafter referred to as carboxylate salt) with respect to 100 parts of the water-soluble magnesium salt.
( 3 ) A ground injection method in which the agent A and the agent B according to (1) or (2) are separately pumped and merged and mixed in the vicinity of the injection port.
( 4 ) The ground injection method according to ( 3 ), wherein a mixing ratio of the agent A and the agent B is 20:80 to 80:20 in volume ratio.
( 5 ) The ground injection method according to ( 3 ) or ( 4 ), wherein the gel time is adjusted by diluting a stock solution of an aqueous solution having a solid content concentration of 30 to 50% of the B agent.
In the present invention, “parts” and “%” are based on mass unless otherwise specified.

本発明の地盤注入剤及びそれを用いた地盤注入工法を採用することによって、ゲルタイムの調整が容易で、硬化後の溶液の流出が少なくなるといった効果を奏する。   By adopting the ground injecting agent and the ground injecting method using the same of the present invention, the gel time can be easily adjusted, and the effect of reducing the outflow of the solution after curing is achieved.

以下、本発明をさらに詳しく説明する。
(アルカリ金属珪酸塩)
本発明で使用するアルカリ金属珪酸塩は、珪酸ナトリウムの水溶液である。アルカリ金属珪酸塩のSiO/ROモル比(Rはアルカリ金属)は2〜5程度が好ましく、これらの混合液も使用可能である。これらの中でも安価に入手可能な珪酸ソーダ水溶液(水ガラス)を使用することが好ましい。水ガラスの中でもJIS3号珪酸ソーダがより好ましい。
Hereinafter, the present invention will be described in more detail.
(Alkali metal silicate)
The alkali metal silicate used in the present invention is an aqueous solution of sodium silicate. The alkali metal silicate has a SiO 2 / R 2 O molar ratio (R is an alkali metal) of preferably about 2 to 5, and a mixture thereof can also be used. Among these, it is preferable to use a sodium silicate aqueous solution (water glass) that can be obtained at low cost. Among water glasses, JIS No. 3 sodium silicate is more preferable.

アルカリ金属珪酸塩溶液の固形分濃度は、水溶液100部中、5〜40部が好ましく、10〜30部がより好ましい。固形分濃度が低いと固まらない場合があり、固形分濃度が高いと粘度が高くなり、反応剤との混合性や注入作業時の圧送性が悪くなる場合がある。   The solid content concentration of the alkali metal silicate solution is preferably 5 to 40 parts, more preferably 10 to 30 parts, in 100 parts of the aqueous solution. If the solid content concentration is low, it may not solidify, and if the solid content concentration is high, the viscosity increases, and the mixing property with the reactant and the pumpability during the injection operation may deteriorate.

(水溶性マグネシウム塩)
本発明で使用する水溶性マグネシウム塩とは、水に溶解してマグネシウムを供給し酸性を示す物質である。水溶性マグネシウム塩としては、本発明では、硫酸マグネシウムを使用する。
(Water-soluble magnesium salt)
The water-soluble magnesium salt used in the present invention is a substance that is acidic by being dissolved in water and supplying magnesium. The water-soluble magnesium salt, in the present invention, that use magnesium sulfate.

水溶性マグネシウム塩の中ではアルカリ金属珪酸塩との反応性や反応後の安定性、コスト面から硫酸マグネシウムが好ましい。硫酸マグネシウムとしては無水や結晶水を持ったもの等の使用が可能であるが、溶解して溶液化することからコスト面で安価である結晶水を持ったタイプを原料として使用することが好ましい。   Among the water-soluble magnesium salts, magnesium sulfate is preferable from the viewpoint of reactivity with alkali metal silicate, stability after reaction, and cost. Magnesium sulfate may be anhydrous or have water of crystallization. However, it is preferable to use a material having water of crystallization, which is inexpensive in terms of cost, as a raw material because it dissolves into a solution.

本発明では、カルボン酸塩として、クエン酸ナトリウム及び/又はクエン酸カリウムを使用する。カルボン酸塩は無水物であっても水和物であってよい。In the present invention, sodium citrate and / or potassium citrate is used as the carboxylate. The carboxylate may be an anhydride or a hydrate.

カルボン酸塩と水溶性マグネシウム塩との混合比率は、水溶性マグネシウム塩(結晶水を含む場合、結晶水は水として換算)100部に対してカルボン酸塩50〜200部が好ましく、80〜150部がより好ましい。上記範囲であれば、硬化後の溶液の流出が少なく、良好な硬化状態と適度な粘度が得られる。   The mixing ratio of the carboxylate and the water-soluble magnesium salt is preferably 50 to 200 parts of carboxylate with respect to 100 parts of water-soluble magnesium salt (when water of crystallization is converted as water), 80 to 150 parts. Part is more preferred. If it is the said range, there will be little outflow of the solution after hardening, and a favorable hardening state and moderate viscosity will be obtained.

本発明においては、各成分を一度に混合してもよく、また、アルカリ金属珪酸塩をA剤とし、水溶性マグネシウム塩とカルボン酸塩の混合溶液をB剤とし、A剤とB剤を混合して用いてもよい。   In the present invention, each component may be mixed at once, and alkali metal silicate is used as agent A, a mixed solution of water-soluble magnesium salt and carboxylate is used as agent B, and agent A and agent B are mixed. May be used.

A剤とB剤を混合する場合、B剤の固形分濃度は、4〜50%が好ましく、5〜25%がより好ましい。また、A剤とB剤の合計の固形分濃度は、3〜50%が好ましく、5〜25%がより好ましい。上記範囲であれば、硬化後の溶液の流出が少なく、良好な硬化状態と適度な粘度が得られる。   When mixing agent A and agent B, the solid content concentration of agent B is preferably 4 to 50%, more preferably 5 to 25%. Moreover, 3-50% is preferable and, as for the total solid content density | concentration of A agent and B agent, 5-25% is more preferable. If it is the said range, there will be little outflow of the solution after hardening, and a favorable hardening state and moderate viscosity will be obtained.

本発明の地盤注入剤の混合方法及び注入方法は、例えば、A剤とB剤を別々に調製した後、それらを別々に圧送し、地盤注入前又は地盤注入後に両者を混合して反応させる方法が挙げられる。A剤とB剤の混合比率は容積比で20:80〜80:20とすることが好ましい。   The mixing method and the injecting method of the ground injecting agent of the present invention are, for example, a method in which the agent A and the agent B are prepared separately, then they are separately pumped, and both are mixed and reacted before or after injecting the ground. Is mentioned. The mixing ratio of agent A and agent B is preferably 20:80 to 80:20 in volume ratio.

A剤とB剤を別々に調製する場合、B剤については所定量の水溶性マグネシウム塩とカルボン酸塩と水を混合して溶解させて調製する。溶解時に加熱して溶解させることが溶解時間を短くする観点から好ましい。固形分濃度で30〜50%の水溶液とし、使用現場にて所定のゲルタイムを得るように数倍〜10倍程度に希釈して使用する方法が好ましい。   When preparing the A agent and the B agent separately, the B agent is prepared by mixing and dissolving a predetermined amount of water-soluble magnesium salt, carboxylate and water. From the viewpoint of shortening the dissolution time, it is preferable to dissolve by heating at the time of dissolution. A method of using an aqueous solution having a solid concentration of 30 to 50% and diluting to several to 10 times so as to obtain a predetermined gel time at the use site is preferable.

地盤注入剤の使用方法は、例えば2連式の注入ポンプでA剤及びB剤を別々に圧送して使用する方法が挙げられる。2連式のポンプではA剤及びB剤は等容積で別々に圧送を行って注入口付近で合流混合した後に地盤に注入する。   The method of using the ground injecting agent includes, for example, a method in which the agent A and the agent B are separately pumped and used by a double infusion pump. In the dual-type pump, the A agent and the B agent are separately pumped in equal volumes, mixed and mixed in the vicinity of the inlet, and then injected into the ground.

JIS3号珪酸ナトリウムを水で希釈して固形分濃度20%のpH13の水溶液を調整し、これをA剤とした。一方、水溶性マグネシウム塩として硫酸マグネシウム、カルボン酸塩としてクエン酸Naを使用し、硫酸マグネシウム100部に対してクエン酸ナトリウムを100部混合し、60℃まで加熱して固形分濃度50%のB剤原液を調製した。このB剤は表1−1に示す希釈率でB剤原液を希釈して使用した。   JIS No. 3 sodium silicate was diluted with water to prepare an aqueous solution of pH 13 having a solid concentration of 20%, and this was designated as agent A. On the other hand, magnesium sulfate is used as a water-soluble magnesium salt, and sodium citrate is used as a carboxylate salt. 100 parts of sodium citrate is mixed with 100 parts of magnesium sulfate, and heated to 60 ° C. to obtain a solid content of 50% B A drug stock solution was prepared. This B agent was used by diluting the B agent stock solution at the dilution rate shown in Table 1-1.

A剤と各希釈率のB剤を、20℃、相対湿度80%の室内で50:50の容積比率で混合し、ゲルタイム、ゲル状態、分離水を評価した。また、比較のため、1A族元素を含有しないクエン酸を用いてB剤を調製し、同様に試験した。結果を表1−2に併記する。   A agent and B agent of each dilution rate were mixed at a volume ratio of 50:50 in a room at 20 ° C. and a relative humidity of 80%, and gel time, gel state, and separated water were evaluated. For comparison, an agent B was prepared using citric acid containing no Group 1A element, and tested in the same manner. The results are also shown in Table 1-2.

<使用材料>
3号珪酸ナトリウム :JIS珪酸3号品、NaO=9.4%、SiO=28.4%、SiONa モル比=3.12
水溶性マグネシウム塩:無水硫酸マグネシウム、市販品
カルボン酸塩 :無水クエン酸ナトリウム、無水クエン酸カリウム、市販品
比較用カルボン酸 :無水クエン酸、市販品
水 :水道水
<Materials used>
No. 3 sodium silicate: JIS silicic acid No. 3 product, Na 2 O = 9.4%, SiO 2 = 28.4%, SiO 2 / Na 2 O molar ratio = 3.12
Water-soluble magnesium salt: anhydrous magnesium sulfate, commercially available carboxylate salt: anhydrous sodium citrate, anhydrous potassium citrate, commercially available carboxylic acid for comparison: anhydrous citric acid, commercially available water: tap water

<評価方法>
ゲルタイム:A剤100mlとB剤100mlを混合後、著しく増粘して流動しなくなるまでの時点の時間を測定した。
<Evaluation method>
Gel time: After mixing 100 ml of agent A and 100 ml of agent B, the time at the point of time when it thickened significantly and stopped flowing was measured.

分離水量:ゲルタイムから1時間経過した時点での分離水をデカンテーションで採取して秤量した。
◎:分離水量が全重量中の分離水量が3%の未満
○:分離水量が3%以上で7%未満
△:分離水量が7%以上
Separation water amount: Separation water was collected by decantation after 1 hour from the gel time and weighed.
◎: The amount of separated water is less than 3% of the total weight ○: The amount of separated water is 3% or more and less than 7% △: The amount of separated water is 7% or more

ゲル状態:A剤とB剤が均一に混合されているか否か、目視で調べた。
○:均一なゲル体が得られた
△:A剤とB剤の混合が十分でなく、ゲル状態が不均一である
Gel state: It was visually examined whether the agent A and the agent B were uniformly mixed.
○: A uniform gel was obtained. Δ: Mixing of agent A and agent B was insufficient, and the gel state was non-uniform.

Figure 0005305586
Figure 0005305586

Figure 0005305586
Figure 0005305586

表1−2に示すように、クエン酸を使用した場合には、溶解度が低いために完全に溶解した溶液が得られず、希釈率を変えた場合でもゲルタイムはほとんど変わらない(実験No.1-1〜1-4)。これに対して、クエン酸ナトリムやクエン酸カリウムを使用した場合には、完全に溶解した溶液が得られ、希釈率によってゲルタイムを調整することが可能となる(実験No.1-5〜1-11)。したがって、クエン酸等のカルボン酸ではなく、クエン酸ナトリウム、クエン酸カリウム等の1A族元素を含むカルボン酸塩を用いることにより、効果を奏することが分かる。
また、クエン酸ナトリウムやクエン酸カリウムを用いた場合、固形分濃度が4〜50%で硬化状態が良好で、ゲルタイムの適当な注入剤が得られ、固形分濃度が高く、ゲルタイムが短い場合でも、クエン酸ナトリウムやクエン酸カリウムを用いることにより、クエン酸を用いた場合と比較して、分離水量を少なくすることができる(実験No.1-5〜1-10)。
As shown in Table 1-2, when citric acid was used, a completely dissolved solution was not obtained due to low solubility, and the gel time was hardly changed even when the dilution rate was changed (Experiment No. 1). -1 to 1-4). In contrast, when sodium citrate or potassium citrate is used, a completely dissolved solution is obtained, and the gel time can be adjusted by the dilution rate (Experiment No. 1-5 to 1- 1). 11). Therefore, it turns out that there exists an effect by using carboxylate containing 1A group elements, such as sodium citrate and potassium citrate, instead of carboxylic acids, such as a citric acid.
In addition, when sodium citrate or potassium citrate is used, a solid state concentration of 4 to 50% and a cured state is good, and an appropriate injection time of gel time is obtained, even when the solid content concentration is high and the gel time is short. By using sodium citrate or potassium citrate, the amount of separated water can be reduced as compared with the case of using citric acid (Experiment No. 1-5 to 1-10).

水溶性マグネシウム塩として硫酸マグネシウム、カルボン酸塩としてクエン酸ナトリウムを使用し、硫酸マグネシウム2.5部に対して表2に示すクエン酸ナトリウムを使用してB剤を調整したこと以外は実施例1と同様に試験した。結果を表2に併記する。   Example 1 except that magnesium sulfate was used as the water-soluble magnesium salt, sodium citrate was used as the carboxylate, and B agent was prepared using sodium citrate shown in Table 2 with respect to 2.5 parts of magnesium sulfate. Were tested in the same manner. The results are also shown in Table 2.

Figure 0005305586
Figure 0005305586

表2に示すように、水溶性マグネシウム塩(硫酸マグネシウム)100部に対してカルボン酸塩を50〜200部含有することにより、分離水量が少なく、硬化状態が良好であり、ゲルタイムの適当な注入剤が得られ、また、カルボン酸塩の含有量が少なく、ゲルタイムが短い場合でも、カルボン酸塩を用いることにより、カルボン酸を用いた場合と比較して、分離水量を少なくすることができる(実験No.2-2、1-8、2-3)。   As shown in Table 2, by containing 50 to 200 parts of carboxylate with respect to 100 parts of water-soluble magnesium salt (magnesium sulfate), the amount of separated water is small, the cured state is good, and the gel time is appropriately injected. Even when the content of carboxylate is low and the gel time is short, the amount of separated water can be reduced by using carboxylate compared to the case of using carboxylic acid ( Experiment No.2-2, 1-8, 2-3).

水溶性マグネシウム塩として硫酸マグネシウム、カルボン酸塩としてクエン酸ナトリウムを使用し、硫酸マグネシウム100部に対してクエン酸ナトリウムを100部使用し、固形分濃度50%のB剤を調製して5倍希釈液のB剤を調整し、表3に示す比率のA剤とB剤を使用して、ゲルタイムとゲル状態を測定したこと以外は、実施例1と同様に試験した。結果を表3に併記する。   Use magnesium sulfate as the water-soluble magnesium salt, sodium citrate as the carboxylate, use 100 parts of sodium citrate to 100 parts of magnesium sulfate, and prepare a B agent with a solid content concentration of 50% and dilute 5 times The liquid B agent was adjusted and tested in the same manner as in Example 1 except that the gel time and gel state were measured using the A agent and B agent in the ratios shown in Table 3. The results are also shown in Table 3.

Figure 0005305586
Figure 0005305586

表3に示すように、A剤とB剤の混合比率を容積比で20:80〜80:20の範囲で変えることにより、ゲルタイムを調整することができ、良好な硬化状態を得ることができる(実験No.3-2、1-8、3-3)。   As shown in Table 3, the gel time can be adjusted and a good cured state can be obtained by changing the mixing ratio of the A agent and the B agent in a volume ratio of 20:80 to 80:20. (Experiment No. 3-2, 1-8, 3-3).

本発明の地盤注入剤及びそれを用いた地盤注入工法は、例えば、トンネル土木や都市土木等で地山や地盤の安定化を図るために使用され、より安全でかつより性能の良い注入剤として利用可能である。   The ground injection agent and the ground injection method using the same according to the present invention are used, for example, to stabilize ground and ground in tunnel civil engineering and urban civil engineering, etc., and as a safer and better performance injection. Is available.

Claims (5)

アルカリ金属珪酸塩を含有するアルカリ性水溶液のA剤と、水溶性マグネシウム塩とクエン酸ナトリウム及び/又はクエン酸カリウムを含有する酸性水溶液のB剤を用いた地盤注入剤であって、前記アルカリ金属珪酸塩が珪酸ナトリウムであり、前記水溶性マグネシウム塩が硫酸マグネシウムであり、前記B剤中、前記水溶性マグネシウム塩が2.1〜3.1%で、前記クエン酸ナトリウム及び/又はクエン酸カリウムが2.1〜7.5%(但し、「重炭酸ソーダおよび/または重炭酸カリ100重量部に対しマグネシウムの硫酸塩、塩化物の単独または混合物(無水物換算)5〜100重量部、クエン酸のソーダ塩、カリウム塩の単独または混合物3〜200重量部よりなる成分」を除く。)で、前記B剤の固形分濃度が4.2〜10.0%であることを特徴とする地盤注入剤。 An alkaline aqueous solution containing an alkali metal silicate, and a ground injecting agent using an aqueous solution B containing an aqueous solution containing an aqueous magnesium salt and sodium citrate and / or potassium citrate, the alkali metal silicate The salt is sodium silicate, the water-soluble magnesium salt is magnesium sulfate, and in the agent B, the water-soluble magnesium salt is 2.1 to 3.1%, and the sodium citrate and / or potassium citrate is 2.1 to 7.5%. (However, "sodium bicarbonate and / or potassium bicarbonate 100 parts by weight, magnesium sulfate, chloride alone or mixture (anhydride equivalent) 5-100 parts by weight, citric acid soda salt, potassium salt alone or mixture) 3), and the solid content concentration of the B agent is 4.2 to 10.0%. 前記水溶性マグネシウム塩100部に対して、前記クエン酸ナトリウム及び/又はクエン酸カリウムを50〜200部含有することを特徴とする請求項1に記載の地盤注入剤。   The ground injection agent according to claim 1, wherein 50 to 200 parts of the sodium citrate and / or potassium citrate is contained with respect to 100 parts of the water-soluble magnesium salt. 請求項1又は2に記載のA剤とB剤とを別々に圧送し、注入口付近で合流混合することを特徴とする地盤注入工法。 The ground injection method characterized by pumping A agent and B agent of Claim 1 or 2 separately, and merging and mixing in the injection hole vicinity. 前記A剤とB剤の混合比率が容積比で20:80〜80:20であることを特徴とする請求項に記載の地盤注入工法。 The ground injection method according to claim 3 , wherein a mixing ratio of the agent A and the agent B is 20:80 to 80:20 in volume ratio. 前記B剤の固形分濃度30〜50%の水溶液の原液を希釈して、ゲルタイムを調整することを特徴とする請求項又はに記載の地盤注入工法。 The ground injection method according to claim 3 or 4 , wherein the gel time is adjusted by diluting a stock solution of an aqueous solution of the B agent having a solid content concentration of 30 to 50%.
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