JP5263622B2 - Joining structure and joining method of fiber reinforced plastic - Google Patents
Joining structure and joining method of fiber reinforced plastic Download PDFInfo
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- JP5263622B2 JP5263622B2 JP2009246983A JP2009246983A JP5263622B2 JP 5263622 B2 JP5263622 B2 JP 5263622B2 JP 2009246983 A JP2009246983 A JP 2009246983A JP 2009246983 A JP2009246983 A JP 2009246983A JP 5263622 B2 JP5263622 B2 JP 5263622B2
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/02—Preparation of the material, in the area to be joined, prior to joining or welding
- B29C66/026—Chemical pre-treatments
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/12—Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
- B29C66/122—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section
- B29C66/1222—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section comprising at least a lapped joint-segment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/12—Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
- B29C66/122—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section
- B29C66/1224—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section comprising at least a butt joint-segment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/303—Particular design of joint configurations the joint involving an anchoring effect
- B29C66/3034—Particular design of joint configurations the joint involving an anchoring effect making use of additional elements, e.g. meshes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/40—General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
- B29C66/47—Joining single elements to sheets, plates or other substantially flat surfaces
- B29C66/472—Joining single elements to sheets, plates or other substantially flat surfaces said single elements being substantially flat
- B29C66/4722—Fixing strips to surfaces other than edge faces
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/72—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
- B29C66/721—Fibre-reinforced materials
- B29C66/7214—Fibre-reinforced materials characterised by the length of the fibres
- B29C66/72141—Fibres of continuous length
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/739—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/7392—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/739—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/7392—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic
- B29C66/73921—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic characterised by the materials of both parts being thermoplastics
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
Abstract
Description
本発明は、強化繊維を含む繊維強化型プラスチックと、各種高分子材料との接合構造及び接合方法に関し、特に、電子部品の実装に多用されている繊維強化型プラスチック基板と各種高分子材料との接合構造及び接合方法に関するものである。 TECHNICAL FIELD The present invention relates to a bonding structure and a bonding method between a fiber reinforced plastic containing reinforcing fibers and various polymer materials, and in particular, a fiber reinforced plastic substrate frequently used for mounting electronic components and various polymer materials. The present invention relates to a joining structure and a joining method.
一般的に異種高分子材料を相互に接着するのは困難であり、特に、繊維強化型プラスチック基板においては、マトリックスとして用いる高分子材料として熱硬化型が用いられることが多く、硬化状態または可塑化状態の高分子材料を接触させただけでは、強固な接着状態を得るのは極めて困難である。 In general, dissimilar polymer materials are difficult to adhere to each other. Especially in fiber reinforced plastic substrates, thermosetting type is often used as a polymer material used as a matrix, and it is hardened or plasticized. It is extremely difficult to obtain a strong adhesion state only by bringing the polymer material in a state into contact.
高分子材料には、接着剤として用いられるものもあり、その接着力は、化学結合、水素結合、ファンデルワールス力に起因し、繊維強化型プラスチック基板の表面に接着が可能な接着剤として利用される種類もあるが、部品としての使用目的に合った高分子材料、あるいは加工性に優れた、汎用の高分子材料が、このような接着を可能にする成分や特性を具備することは稀である。 Some polymer materials are used as adhesives, and their adhesive strength is derived from chemical bonds, hydrogen bonds, and van der Waals forces, and can be used as adhesives that can adhere to the surface of fiber-reinforced plastic substrates. However, it is rare that a polymer material suitable for the purpose of use as a component or a general-purpose polymer material excellent in processability has such components and properties that enable such adhesion. It is.
従って、接着性の乏しい高分子材料を、繊維強化型プラスチック基板に接着するには、接着剤を用いるのが一般的であるが、接着の対象となる高分子材料の材質が限定される他、接着剤の管理、塗布方法、接着方法、又は接着面の粗さ、汚れなどに細心の注意を払う必要があり、生産するにあたり、多くの工数が必要とされる。 Therefore, in order to bond a polymer material with poor adhesion to a fiber reinforced plastic substrate, it is common to use an adhesive, but the material of the polymer material to be bonded is limited, It is necessary to pay close attention to the management of the adhesive, the coating method, the bonding method, or the roughness and dirt of the bonding surface, and many man-hours are required for production.
このような技術の一例として、特許文献1には、接着面に予め微小な凹凸部を形成して、接着性を向上する技術が開示されている。また、特許文献2には、繊維強化型プラスチック部材同士を接合する手段として、強化繊維を露出させた部分を重ね合わせた部分に、樹脂材を充填する技術が開示されている。 As an example of such a technique, Patent Document 1 discloses a technique for improving adhesion by forming a minute uneven portion on an adhesive surface in advance. Patent Document 2 discloses a technique of filling a resin material in a portion where overlapping portions of reinforcing fibers are exposed as means for joining fiber reinforced plastic members.
しかしながら、特許文献1に開示されている技術では、対象となる材質が限定されるという課題に、必ずしも十分に対処したものではないと考えられる。また、特許文献2に開示されている技術は、繊維強化プラスチック同士の接合方法であり、接合したい部材の両方に強化繊維が含まれていない場合には接合することができない。 However, it is considered that the technique disclosed in Patent Document 1 does not necessarily sufficiently deal with the problem that the target material is limited. Moreover, the technique currently disclosed by patent document 2 is a joining method of fiber reinforced plastics, and cannot join, when the reinforcement fiber is not contained in both the members to join.
従って、本発明の課題は、多くの種類の高分子材料を、接着剤を使わずに、少ない工数で、繊維強化型プラスチック基板に強固に接合することが可能な接合構造と接合方法を提供することである。 Accordingly, an object of the present invention is to provide a bonding structure and a bonding method capable of firmly bonding many types of polymer materials to a fiber reinforced plastic substrate with a small number of man-hours without using an adhesive. That is.
本発明は、前記の課題解決のため、従来の技術を改良することを検討した結果なされたものであり、繊維材料と高分子材料からなる、繊維強化型プラスチックの、マトリックスを構成する高分子材料の少なくとも一部を除いて形成される、前記繊維材料が露出した部分に、可塑化した第二の高分子材料を充填してなることを特徴とする、繊維強化型プラスチックの接合構造である。 In order to solve the above problems, the present invention has been made as a result of studying improvement of the prior art, and a polymer material constituting a matrix of a fiber reinforced plastic comprising a fiber material and a polymer material. The fiber-reinforced plastic joining structure is formed by filling the exposed portion of the fiber material with a plasticized second polymer material formed by excluding at least a part thereof.
また本発明は、繊維材料と高分子材料からなる、繊維強化型プラスチックの、マトリックスを構成する高分子材料の少なくとも一部を、物理的方法または化学的方法の少なくともいずれかの方法を用いて除くことにより、前記繊維材料を露出させる工程と、前記繊維材料が露出した部分に、第二の高分子材料を充填する工程を有することを特徴とする、繊維強化型プラスチックの接合方法である。 In the present invention, at least a part of the polymer material constituting the matrix of the fiber reinforced plastic composed of the fiber material and the polymer material is removed using at least one of a physical method and a chemical method. Thus, there is provided a fiber-reinforced plastic joining method, comprising: exposing the fiber material; and filling a portion where the fiber material is exposed with a second polymer material.
本発明においては、繊維強化型プラスチックのマトリックスを形成する高分子材料の一部を、前記のように物理的方法または化学的方法で除去するが、マトリックスが熱可塑性高分子材料である場合は、適当な溶媒を用いて溶解することにより除去できるし、加熱によって溶融させることで除去できる。いずれの場合も、強化繊維が溶解しない溶媒を用いたり、強化繊維を破壊しない温度を用いたりすることで、強化繊維の形状や特性を損なうことなく、マトリックスのみを除去できる。 In the present invention, a part of the polymer material forming the fiber-reinforced plastic matrix is removed by a physical method or a chemical method as described above. When the matrix is a thermoplastic polymer material, It can be removed by dissolving using an appropriate solvent, or by melting by heating. In either case, by using a solvent that does not dissolve the reinforcing fibers or using a temperature that does not destroy the reinforcing fibers, only the matrix can be removed without impairing the shape and characteristics of the reinforcing fibers.
また、マトリックスが熱硬化型高分子材料である場合は、一般的には溶媒による溶解や、加熱による可塑化が不可能なので、例えばレーザービームを照射することで、マトリックスを熱分解させる方法を用いることができる。この場合は、強化繊維としてケブラー(登録商標)のような高耐熱性の有機繊維を用いたとしても、加熱により、その形状や機械的特性を損なう可能性があるので、熱分解によりマトリックスを除去する場合は、強化繊維として、ガラス繊維などの無機繊維を使用したものが望ましい。 In addition, when the matrix is a thermosetting polymer material, it is generally impossible to dissolve with a solvent or plasticize by heating. For example, a method of thermally decomposing the matrix by irradiating a laser beam is used. be able to. In this case, even if a high heat-resistant organic fiber such as Kevlar (registered trademark) is used as the reinforcing fiber, the shape and mechanical properties may be damaged by heating, so the matrix is removed by thermal decomposition. When doing so, what uses inorganic fibers, such as glass fiber, as a reinforced fiber is desirable.
また、本発明においては、未硬化状態の熱硬化性高分子材料や、可塑化状態の熱可塑性高分子材料で、強化繊維間の隙間や凹凸に充填できる粘度を持つ高分子材料全般に適用でき、投錨効果を発現できることから、多くの種類の高分子材料を強固に接合可能である。さらに、繊維強化型プラスチックのマトリックスと、化学的結合などにより接着性を発現する場合であれば、接着強度をより向上できる。 Further, in the present invention, it can be applied to uncured thermosetting polymer materials and plasticized thermoplastic polymer materials, and to all polymer materials having a viscosity capable of filling gaps and irregularities between reinforcing fibers. Since the anchoring effect can be expressed, many kinds of polymer materials can be firmly joined. Furthermore, the adhesive strength can be further improved if the adhesiveness is expressed by a chemical bond or the like with a fiber reinforced plastic matrix.
しかも本発明によれば、接着剤を使用せずに繊維強化基板と合成樹脂を接着できるので、前記の接着剤を利用するにあたっての工数やコストを削減できる他、接着剤を使用しないことにより、接着剤に含まれる環境負荷物質の削減が可能である。 In addition, according to the present invention, since the fiber reinforced substrate and the synthetic resin can be bonded without using an adhesive, it is possible to reduce man-hours and costs in using the adhesive, and by not using an adhesive, It is possible to reduce environmentally hazardous substances contained in the adhesive.
図1に示したように、本発明においては、まず繊維強化型プラスチック基板のマトリックス2aにおける、他の高分子材料を接合したい部分を除去して、交互に織り込んだ、縦方向の強化繊維1a、横方向の強化繊維1bを露出させる。次に、マトリックスを除去した空間3に、第二の高分子材料4を充填する。第二の高分子材料4の充填は、未硬化状態の熱硬化型高分子材料を塗布するか、基板を金型に取り付けてトランスファーモールドなどの方法で充填する。また、この工程で、可塑化した熱可塑性高分子材料を用いる場合は、基板を金型に取り付け、射出成形などの方法で充填する。As shown in FIG. 1, in the present invention, first , the reinforcing
図1に示したように、本発明においては、まず繊維強化型プラスチック基板のマトリックス2aにおける、他の高分子材料を接合したい部分を除去して、強化繊維1a、1bを露出させる。次に、マトリックスを除去した空間3に、第二の高分子材料4を充填する。第二の高分子材料4の充填は、未硬化状態の熱硬化型高分子材料を塗布するか、基板を金型に取り付けてトランスファーモールドなどの方法で充填する。また、この工程で、可塑化した熱可塑性高分子材料を用いる場合は、基板を金型に取り付け、射出成形などの方法で充填する。 As shown in FIG. 1, in the present invention, first, a portion of the
このような方法で高分子材料を充填することにより、強化繊維間の空隙に当該高分子材料が入り込み、投錨効果が生じ、強固な接合状態を得ることができる。 By filling the polymer material by such a method, the polymer material enters into the gaps between the reinforcing fibers, a throwing effect is produced, and a strong bonded state can be obtained.
次に本発明の具体的な応用例として、外部端子付きICカードの製造工程におけるICモジュールとカード基材との接着を行う場合について説明する。 Next, as a specific application example of the present invention, a case where the IC module and the card base material are bonded in the manufacturing process of the IC card with external terminals will be described.
外部端子付きICカードで使用されるICモジュールは、繊維強化型プラスチック基板、一般的にはガラスエポキシ基板に、ICチップや外部端子が搭載されている。反外部接触端子側の繊維強化型プラスチック基板の表面の一部、または全部のマトリックスを、例えばレーザービーム照射による熱で、除去し、強化繊維を露出させる。 An IC module used in an IC card with an external terminal includes an IC chip and an external terminal mounted on a fiber reinforced plastic substrate, generally a glass epoxy substrate. A part or all of the matrix of the surface of the fiber reinforced plastic substrate on the side opposite to the external contact terminal is removed by, for example, heat by laser beam irradiation to expose the reinforcing fibers.
強化繊維が露出したICモジュールを、カード部成形用の金型に設置し、インサート成形を行なう。成形時にカード基材に使用したカード部成形用の高分子材料が、露出した強化繊維間の空隙に入り込み、その状態のまま高分子材料が硬化することで、ICモジュールとカード基材である高分子材料の間に、機械的結合が形成され、強固に接合される。 The IC module from which the reinforcing fibers are exposed is placed in a mold for molding the card portion, and insert molding is performed. The polymer material for molding the card part used for the card substrate during molding enters the voids between the exposed reinforcing fibers, and the polymer material is cured in this state, so that the IC module and the card substrate Mechanical bonds are formed between the molecular materials and are firmly bonded.
1a 縦方向の強化繊維
1b 横方向の強化繊維
2a,2b マトリックス
3 マトリックスを除去した空間
4 第二の高分子材料1a Longitudinal reinforcing
1a,1b 強化繊維
2a,2b マトリックス
3 マトリックスを除去した空間
4 第二の高分子材料1a,
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009246983A JP5263622B2 (en) | 2009-10-05 | 2009-10-05 | Joining structure and joining method of fiber reinforced plastic |
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DE112014000775T5 (en) | 2013-02-12 | 2015-10-22 | Polyplastics Co., Ltd. | Grooved resin molding |
US9205629B2 (en) * | 2013-03-15 | 2015-12-08 | Ann Livingston-Peters | Composite structure with a flexible section forming a hinge |
CN106062052B (en) * | 2014-03-25 | 2017-06-06 | 宝理塑料株式会社 | Composite formed article and its manufacture method |
JP6355405B2 (en) * | 2014-04-18 | 2018-07-11 | ポリプラスチックス株式会社 | Composite molded article and manufacturing method thereof |
JP6377990B2 (en) * | 2014-07-31 | 2018-08-22 | ポリプラスチックス株式会社 | Grooved resin molded product and composite molded product manufacturing method, grooved hollow resin molded product and composite molded product |
JP6107787B2 (en) | 2014-10-29 | 2017-04-05 | トヨタ自動車株式会社 | Manufacturing method of fiber reinforced resin molded member and connecting method of member |
EP3238921B1 (en) | 2014-12-26 | 2019-03-13 | Nissan Motor Co., Ltd. | Method for modifying surface of composite material, method for bonding composite material, composite material, and bonded structure |
CN107530926A (en) * | 2015-04-17 | 2018-01-02 | 三菱化学株式会社 | Fibre reinforced composites products formed and its manufacture method |
GB201718387D0 (en) * | 2017-11-07 | 2017-12-20 | Univ College Dublin Nat Univ Ireland Dublin | Surface preparation |
JP2021113477A (en) * | 2020-01-21 | 2021-08-05 | 三菱重工業株式会社 | Resin molded panel, access door panel, and method of manufacturing resin molded panel |
DE102021103497B3 (en) * | 2021-02-15 | 2022-01-13 | Universität Kassel, Körperschaft des öffentlichen Rechts | Composite component and method for producing a composite component |
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