JP5256662B2 - Fluidized bed gasification method and equipment - Google Patents

Fluidized bed gasification method and equipment Download PDF

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JP5256662B2
JP5256662B2 JP2007207395A JP2007207395A JP5256662B2 JP 5256662 B2 JP5256662 B2 JP 5256662B2 JP 2007207395 A JP2007207395 A JP 2007207395A JP 2007207395 A JP2007207395 A JP 2007207395A JP 5256662 B2 JP5256662 B2 JP 5256662B2
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克明 松澤
哲也 平田
俊之 須田
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Description

本発明は、原料を流動層によりガス化する流動層ガス化方法及び設備に関するものである。   The present invention relates to a fluidized bed gasification method and equipment for gasifying a raw material with a fluidized bed.

石炭、バイオマス、汚泥等の原料をガス化するための流動層ガス化設備としては、流動層ガス化炉に高温の流動媒体と原料を導入すると共にガス化剤を供給して流動層を形成することにより原料のガス化を行い、生成したガス化ガスは外部に取り出し、一方、流動層ガス化炉でのガス化時に生成したチャーと流動媒体は流動層燃焼炉に供給してチャーを流動燃焼させることにより流動媒体を加熱し、加熱した流動媒体は排気ガスと分離して再び前記流動層ガス化炉に導入するようにした2塔式と呼ばれる流動層ガス化設備が既に提案されている(特許文献1等参照)。   As fluidized bed gasification equipment for gasifying raw materials such as coal, biomass and sludge, a fluidized bed is formed by introducing a high-temperature fluidized medium and raw materials into a fluidized bed gasification furnace and supplying a gasifying agent. The gasification of the raw material is performed, and the generated gasification gas is taken out to the outside. On the other hand, the char generated during gasification in the fluidized bed gasification furnace and the fluidized medium are supplied to the fluidized bed combustion furnace to fluidize the char. A fluidized bed gasification facility called a two-column system has already been proposed in which the fluidized medium is heated to separate the exhausted gas from the exhaust gas and introduced again into the fluidized bed gasification furnace ( (See Patent Document 1).

図4、図5は2塔式の流動層ガス化設備の概略を示している。1は流動層燃焼炉であり、該流動層燃焼炉1は、流動層ガス化炉2において原料12のガス化により生成したチャーと流動媒体とを下部から導入すると共に、空気管3から風箱4等を介して空気を吹き出すことによりチャーを流動燃焼させて上昇流動する間に流動媒体を加熱するようにしている。   4 and 5 schematically show a two-column fluidized bed gasification facility. Reference numeral 1 denotes a fluidized bed combustion furnace. The fluidized bed combustion furnace 1 introduces char and fluidized medium generated by gasification of the raw material 12 in the fluidized bed gasification furnace 2 from the lower part, and from the air pipe 3 to the wind box. The fluid medium is heated while the char is fluidized and combusted by being blown out through the air 4 or the like to rise and flow.

流動層燃焼炉1の上部にはサイクロンからなる分離器7が移送管5により接続されており、流動層燃焼炉1の上部から排出される燃焼ガス6は移送管5により分離器7に導入されて流動媒体と排気ガスとに遠心分離される。粒径が細かい灰分を含む排気ガス8は分離器7の上部に排出され、粒径の粗い未燃チャーを含む流動媒体9は、分離器7の下端に接続され降下管10に分離されて流動層ガス化炉2に導入される。ここで、図5では、流動層燃焼炉1に対して2個の分離器7,7'が接続してあり、各分離器7,7'で分離した流動媒体9を別個の降下管10により、流動層ガス化炉2内の流動層燃焼炉1に近く且つ左右の隅部(図5では上下の隅部)に導入するようにしている。この時、流動層燃焼炉1の燃焼ガス6を移送管5,5'により分離器7,7'に導く際には、燃焼ガス6中の流動媒体等の粒子が移送管5,5'に分離堆積して閉塞を起こす問題があるために、移送管5,5'の長さはできるだけ短くしており、このために分離器7,7'は流動層燃焼炉1に近い位置に配置され、従って降下管10により流動層ガス化炉2内の流動層燃焼炉1に近い位置に流動媒体9を導入するようにしている。   A separator 7 made of a cyclone is connected to the upper part of the fluidized bed combustion furnace 1 through a transfer pipe 5, and the combustion gas 6 discharged from the upper part of the fluidized bed combustion furnace 1 is introduced into the separator 7 through the transfer pipe 5. The fluid medium and the exhaust gas are then centrifuged. The exhaust gas 8 containing ash with a fine particle size is discharged to the upper part of the separator 7, and the fluid medium 9 containing unburned char with a coarse particle size is connected to the lower end of the separator 7 and separated into the downcomer 10 to flow. It is introduced into the bed gasifier 2. Here, in FIG. 5, two separators 7, 7 ′ are connected to the fluidized bed combustion furnace 1, and the fluidized medium 9 separated by each separator 7, 7 ′ is separated by a separate downcomer 10. The fluidized bed gasification furnace 2 is introduced near the fluidized bed combustion furnace 1 and at the left and right corners (upper and lower corners in FIG. 5). At this time, when the combustion gas 6 of the fluidized bed combustion furnace 1 is guided to the separators 7 and 7 ′ by the transfer pipes 5 and 5 ′, particles such as a fluidized medium in the combustion gas 6 are transferred to the transfer pipes 5 and 5 ′. Due to the problem of clogging due to separation and deposition, the lengths of the transfer pipes 5 and 5 ′ are made as short as possible. For this reason, the separators 7 and 7 ′ are arranged close to the fluidized bed combustion furnace 1. Accordingly, the fluidized medium 9 is introduced into the fluidized bed gasification furnace 2 at a position close to the fluidized bed combustion furnace 1 by the downcomer 10.

流動層ガス化炉2には、前記分離器7,7'からの加熱された流動媒体9が導入されると共に、原料供給装置11により石炭等の原料12が供給され、更に、流動層ガス化炉2の下部から水蒸気等のガス化剤13が風箱14等により供給されており、ガス化剤13によって形成される流動層15により原料12のガス化が行われる。石炭或いはバイオマス等の原料12を供給してガス化を行うと、水素(H)、一酸化炭素(CO)、メタン(CH)等のガス成分が混在したガス化ガス16が生成される。 The fluidized bed gasification furnace 2 is supplied with the heated fluidized medium 9 from the separators 7 and 7 ′ and supplied with a raw material 12 such as coal by a raw material supply device 11, and further fluidized bed gasification. A gasifying agent 13 such as water vapor is supplied from the lower part of the furnace 2 by a wind box 14 or the like, and the raw material 12 is gasified by a fluidized bed 15 formed by the gasifying agent 13. When gasification is performed by supplying a raw material 12 such as coal or biomass, a gasification gas 16 in which gas components such as hydrogen (H 2 ), carbon monoxide (CO), and methane (CH 4 ) are mixed is generated. .

流動層ガス化炉2内でガス化によって生成したガス化ガス16は取出口17から外部に取り出され、加圧して例えばガスタービン等に燃料として供給したり、精製装置に供給することによりガス化ガス16から所要目的の製品ガスを製造する。   The gasification gas 16 generated by gasification in the fluidized bed gasification furnace 2 is taken out from the outlet 17 and pressurized to be supplied as fuel to, for example, a gas turbine or the like, or gasified by being supplied to a purification apparatus. The required product gas is produced from the gas 16.

流動層ガス化炉2でガス化されなかったチャーと流動媒体は、オーバーフロー管等からなる供給流路18により再び前記流動層燃焼炉1へ供給されて循環し、流動媒体はチャーの燃焼によって再度加熱される。
特開2005−41959号公報
The char and the fluidized medium that have not been gasified in the fluidized bed gasification furnace 2 are supplied again to the fluidized bed combustion furnace 1 through the supply flow path 18 composed of an overflow pipe or the like and circulate. Heated.
JP 2005-41959 A

しかし、従来の流動層ガス化設備においては、図4、図5に示したように、分離器7,7'で分離して流動層ガス化炉2に導入された流動媒体9を、流動層ガス化炉2の平面の隅々まで満遍なく巡るように移動させることが困難であるという問題があった。   However, in the conventional fluidized bed gasification equipment, as shown in FIGS. 4 and 5, the fluidized medium 9 separated by the separators 7 and 7 ′ and introduced into the fluidized bed gasification furnace 2 is used as the fluidized bed. There was a problem that it was difficult to move the gasification furnace 2 so that it could travel all over the plane.

即ち、図5に示すように、分離器7,7'から降下管10によって流動層ガス化炉2に導入された流動媒体9は、その導入位置から供給流路18に向かって最短経路19を通って移動するようになる。このため、流動層ガス化炉2内における降下管10から遠い側(図5では右側のハッチングを施した部分)には、流動媒体の移動が停滞するデッドスペース部分20が生じる。このデッドスペース部分20には高温の新たな流動媒体が供給されないばかりか原料12も移動され難いために、デッドスペース部分20の温度は低下してしまう。   That is, as shown in FIG. 5, the fluid medium 9 introduced from the separators 7 and 7 ′ into the fluidized bed gasification furnace 2 by the downcomer 10 has a shortest path 19 from the introduction position toward the supply passage 18. To move through. For this reason, a dead space portion 20 in which the movement of the fluidized medium stagnates is formed on the side farther from the downcomer pipe 10 in the fluidized bed gasification furnace 2 (the portion hatched on the right side in FIG. 5). The dead space portion 20 is not supplied with a new high-temperature fluid medium, and the raw material 12 is not easily moved, so that the temperature of the dead space portion 20 is lowered.

本発明は、チャーを燃焼させて流動媒体を加熱する流動層燃焼炉と、
流動層燃焼炉から導出される燃焼ガスから流動媒体を分離する分離器と、
分離器で分離した流動媒体を降下管を介して導入すると共に原料とガス化剤を供給して流動層により原料をガス化する流動層ガス化炉と、
流動層ガス化炉で原料をガス化する際に生成したチャーと流動媒体とを流動層燃焼炉に循環する供給流路と、を有する流動層ガス化方法であって、
流動層ガス化炉を複数のガス化装置により構成し、
各ガス化装置の温度を原料のガス化に適したガス化温度に保持するようにした温度変化手段を備え、高温で好適にガス化できる原料と、ガス化時に低融点の灰が生成する原料とを、対応するガス化温度に保持したガス化装置に供給して同時にガス化し
各ガス化装置において生成したガス化ガスを別個に取り出すようにしたことを特徴とする流動層ガス化方法、に係るものである。
The present invention includes a fluidized bed combustion furnace that burns char to heat a fluidized medium;
A separator for separating the fluidized medium from the combustion gas derived from the fluidized bed combustion furnace;
A fluidized bed gasification furnace for introducing a fluidized medium separated by a separator through a downcomer and supplying a raw material and a gasifying agent to gasify the raw material by a fluidized bed;
A fluidized bed gasification method having a supply flow path for circulating a char generated when gasifying a raw material in a fluidized bed gasification furnace and a fluidized medium to the fluidized bed combustion furnace,
The fluidized bed gasifier is composed of multiple gasifiers,
A raw material that can be suitably gasified at a high temperature, and a raw material from which low melting point ash is produced at the time of gasification, provided with a temperature changing means that keeps the temperature of each gasifier at a gasification temperature suitable for the gasification of the raw material Are supplied to a gasifier maintained at the corresponding gasification temperature and gasified at the same time ,
The present invention relates to a fluidized bed gasification method characterized in that the gasification gas generated in each gasifier is separately taken out.

一方、原料には、石炭、石油残渣等のように高温で好適にガス化されて多くのガス化ガスを生成する原料と、ガス化時に低融点の灰が生成しこの低融点灰がガス化ガスと共に取り出されて配管及び機器等に付着する問題があるために低温でガス化することが好ましい原料とがあるが、従来、このようなガス化処理すべき温度が異なる原料を1つの流動層ガス化設備で同時にガス化するようなことはできなかった。   On the other hand, the raw material is a gas that is suitably gasified at high temperatures to produce many gasification gases, such as coal and petroleum residues, and low melting point ash is generated during gasification, and this low melting point ash is gasified. There are some raw materials that are preferably gasified at a low temperature because they are taken out together with gas and adhere to pipes and equipment. Conventionally, such raw materials having different temperatures to be gasified are used in one fluidized bed. It was not possible to gasify at the same time in the gasification facility.

本発明は、上記従来の問題点に鑑みてなしたもので、高いガス化効率で原料をガス化することができ、且つガス化処理すべき温度が異なる原料を1つの流動層ガス化設備でガス化できるようにした流動層ガス化方法及び設備を提供することを目的とする。   The present invention has been made in view of the above-described conventional problems, and can be used to gasify a raw material with high gasification efficiency, and use a single fluidized bed gasification facility for raw materials having different temperatures to be gasified. It aims at providing the fluidized bed gasification method and equipment which enabled gasification.

本発明は、チャーを燃焼させて流動媒体を加熱する流動層燃焼炉と、
流動層燃焼炉から導出される燃焼ガスから流動媒体を分離する分離器と、
分離器で分離した流動媒体を降下管を介して導入すると共に原料とガス化剤を供給して流動層により原料をガス化する流動層ガス化炉と、
流動層ガス化炉で原料をガス化する際に生成したチャーと流動媒体とを流動層燃焼炉に循環する供給流路と、を有する流動層ガス化方法であって、
流動層ガス化炉を複数のガス化装置により構成し、各ガス化装置において生成したガス化ガスを別個に取り出すようにしたことを特徴とする流動層ガス化方法、に係るものである。
The present invention includes a fluidized bed combustion furnace that burns char to heat a fluidized medium;
A separator for separating the fluidized medium from the combustion gas derived from the fluidized bed combustion furnace;
A fluidized bed gasification furnace for introducing a fluidized medium separated by a separator through a downcomer and supplying a raw material and a gasifying agent to gasify the raw material by a fluidized bed;
A fluidized bed gasification method having a supply flow path for circulating a char generated when gasifying a raw material in a fluidized bed gasification furnace and a fluidized medium to the fluidized bed combustion furnace,
The present invention relates to a fluidized bed gasification method characterized in that a fluidized bed gasification furnace is constituted by a plurality of gasifiers, and the gasification gas generated in each gasifier is separately taken out.

本発明は、チャーを燃焼させて流動媒体を加熱する流動層燃焼炉と、
流動層燃焼炉から導出される燃焼ガスから流動媒体を分離する分離器と、
分離器で分離した流動媒体を降下管を介して導入すると共に原料とガス化剤を供給して流動層により原料をガス化する流動層ガス化炉と、
流動層ガス化炉で原料をガス化する際に生成したチャーと流動媒体とを流動層燃焼炉に循環する供給流路と、を有する流動層ガス化設備であって、
分離器からの流動媒体を流動化して原料のガス化を行うようにした複数のガス化装置を備え、
各ガス化装置の温度を原料のガス化に適したガス化温度に保持するようにした温度変化手段を備え、
高温で好適にガス化できる原料と、ガス化時に低融点の灰が生成する原料とを、対応するガス化温度に保持したガス化装置に供給する原料供給装置を備え、
各ガス化装置において生成するガス化ガスを取り出すための取出口を各ガス化装置に備えたことを特徴とする流動層ガス化設備、に係るものである。
The present invention includes a fluidized bed combustion furnace that burns char to heat a fluidized medium;
A separator for separating the fluidized medium from the combustion gas derived from the fluidized bed combustion furnace;
A fluidized bed gasification furnace for introducing a fluidized medium separated by a separator through a downcomer and supplying a raw material and a gasifying agent to gasify the raw material by a fluidized bed;
A fluidized bed gasification facility having a supply flow path for circulating a char and a fluidized medium generated when gasifying a raw material in a fluidized bed gasification furnace to the fluidized bed combustion furnace,
Comprising a plurality of gasifiers that fluidize the fluid medium from the separator to gasify the raw material;
Equipped with temperature changing means adapted to maintain the temperature of each gasifier at a gasification temperature suitable for gasification of the raw material,
A raw material supply device that supplies a raw material that can be suitably gasified at a high temperature and a raw material from which low melting point ash is generated at the time of gasification to a gasifier that maintains the corresponding gasification temperature,
The present invention relates to a fluidized bed gasification facility characterized in that each gasifier is provided with an outlet for taking out gasified gas produced in each gasifier.

上記流動層ガス化設備において、複数のガス化装置は上下に配置され、且つ、上下のガス化装置は平面的に見て少なくとも一部が相互にラップして配置されることが好ましい。 In the fluidized bed gasification facility, it is preferable that the plurality of gasifiers are arranged one above the other, and that the upper and lower gasifiers are arranged so that at least a part thereof is overlapped with each other when seen in a plan view .

又、上記流動層ガス化設備において、温度変化手段は、分離器で分離した流動媒体を分岐して各ガス化装置に導く分岐装置であってもよい。   In the fluidized bed gasification facility, the temperature changing means may be a branching device that branches the fluidized medium separated by the separator and leads it to each gasifier.

又、上記流動層ガス化設備において、温度変化手段は、燃焼ガスの取り入れ量を調整した燃焼ガスから流動媒体を分離し、分離した流動媒体を各ガス化装置に導く複数の分離器であってもよい。   Further, in the fluidized bed gasification facility, the temperature changing means is a plurality of separators for separating the fluid medium from the combustion gas whose combustion gas intake amount is adjusted, and for guiding the separated fluid medium to each gasifier. Also good.

又、上記流動層ガス化設備において、温度変化手段は、各ガス化装置が上下方向に多段に接続され、上段のガス化装置の流動媒体がオーバーフロー管により下段のガス化装置に流下するようにしてあり、上段のガス化装置の温度に対して下段のガス化装置の温度が低いことからなっていてもよい。   In the fluidized bed gasification facility, the temperature changing means is configured such that each gasifier is connected in multiple stages in the vertical direction, and the fluidized medium of the upper gasifier flows down to the lower gasifier through the overflow pipe. The temperature of the lower gasifier may be lower than the temperature of the upper gasifier.

本発明の流動層ガス化方法及び設備によれば、流動層ガス化炉を複数のガス化装置で構成し、各ガス化装置からガス化ガスを取り出すようにしたので、各ガス化装置が小容積化されることにより流動媒体が各ガス化装置の隅々まで移動するようになって流動媒体が停滞するデッドスペース部分の発生を防止することができ、よって、ガス化装置の容積が有効に活用されて流動層ガス化炉のガス化能力が高められ、原料の処理量、ガス化ガスの生成量を大幅に増加できるという優れた効果を奏し得る。   According to the fluidized bed gasification method and facility of the present invention, the fluidized bed gasification furnace is constituted by a plurality of gasifiers, and the gasification gas is taken out from each gasifier. By increasing the volume, the fluidized medium moves to every corner of each gasifier, and the occurrence of dead space where the fluidized medium stagnates can be prevented, so that the volume of the gasifier is effectively increased. By being utilized, the gasification capacity of the fluidized bed gasification furnace is enhanced, and an excellent effect can be obtained that the throughput of raw materials and the generation amount of gasification gas can be significantly increased.

更に、温度変化手段にて各ガス化装置の温度を原料のガス化に適したガス化温度に保持することにより、高温で好適にガス化できる原料と、ガス化時に低融点の灰が生成する原料とを1つの流動層ガス化設備で同時にガス化できる効果がある。   Furthermore, by maintaining the temperature of each gasifier at a gasification temperature suitable for gasification of the raw material by the temperature changing means, a raw material that can be suitably gasified at a high temperature and a low melting point ash are generated during gasification. There is an effect that the raw material can be gasified simultaneously with one fluidized bed gasification facility.

各ガス化装置を上下に配置することによって、流動層ガス化炉の設置スペースを大幅に小さくできる効果がある。   By arranging each gasifier vertically, there is an effect that the installation space of the fluidized bed gasifier can be greatly reduced.

以下、本発明の実施の形態を添付図面を参照して説明する。   Embodiments of the present invention will be described below with reference to the accompanying drawings.

図1は本発明の形態の一例を示すものであり、流動層燃焼炉1と、該流動層燃焼炉1から排出される燃焼ガス6を移送管35を介して導入し排気ガス8と流動媒体9とに分離する1つの分離器21とを備えた流動層ガス化設備において、流動層ガス化炉2を複数のガス化装置22a,22bにより構成している。ここで、各ガス化装置22a,22bは、流動層燃焼炉1と流動層ガス化炉2とが熱バランスした状態において、1つの流動層ガス化炉2で原料を良好にガス化するのに必要なガス化容積を複数に分割した容積としている。図1では2つのガス化装置22a,22bによって流動層ガス化炉2を構成した場合について示したが、3つ以上のガス化装置によって構成するようにしてもよい。   FIG. 1 shows an example of an embodiment of the present invention, in which a fluidized bed combustion furnace 1 and a combustion gas 6 discharged from the fluidized bed combustion furnace 1 are introduced via a transfer pipe 35, and an exhaust gas 8 and a fluid medium. In a fluidized bed gasification facility including one separator 21 that separates the fluidized bed 9 from the fluidized bed gasification furnace 2, the fluidized bed gasification furnace 2 is constituted by a plurality of gasifiers 22a and 22b. Here, each gasifier 22a, 22b is used to gasify the raw material in one fluidized bed gasification furnace 2 in a state where the fluidized bed combustion furnace 1 and the fluidized bed gasification furnace 2 are in thermal balance. The required gasification volume is divided into a plurality of volumes. Although FIG. 1 shows the case where the fluidized bed gasification furnace 2 is constituted by two gasifiers 22a and 22b, it may be constituted by three or more gasifiers.

前記分離器21の降下管23には、流動媒体9を分岐する分岐装置24からなる温度変化手段25が設けてあり、前記分岐装置24で分岐量を調節した流動媒体9を分岐管26a,26bにて各ガス化装置22a,22bに供給することにより、各ガス化装置22a,22bを必要温度に保持できるようにしている。ここで、分岐装置24により例えばガス化装置22aに供給する流動媒体9の供給量を増加するとガス化装置22aの温度は高められ、ガス化装置22bに供給する流動媒体9の供給量を減少するとガス化装置22bの温度は低下される。   The descending pipe 23 of the separator 21 is provided with a temperature changing means 25 comprising a branching device 24 for branching the fluidized medium 9, and the fluidizing medium 9 whose branching amount is adjusted by the branching device 24 is branched into the branching tubes 26a and 26b. Is supplied to the gasifiers 22a and 22b so that the gasifiers 22a and 22b can be maintained at a required temperature. Here, for example, when the supply amount of the fluidized medium 9 supplied to the gasifier 22a is increased by the branching device 24, the temperature of the gasifier 22a is increased, and the supply amount of the fluidized medium 9 supplied to the gasifier 22b is decreased. The temperature of the gasifier 22b is lowered.

各ガス化装置22a,22bには、水蒸気等のガス化剤27を風箱28等により供給して流動層29を形成するようにしてあり、又、原料供給装置30a,30bにより原料31a,31bを供給することにより、各ガス化装置22a,22bにおいて原料31a,31bのガス化を行うようにしている。この時、原料供給装置30a,30bによって各ガス化装置22a,22bに供給する原料31a,31bは同一の原料であってもよく、又は各ガス化装置22a,22bに対して異なる原料を供給するようにしてもよい。又、各ガス化装置22a,22bに供給するガス化剤27も同一のものを用いても或いは異なったガス化剤を用いてもよい。   Each gasifier 22a, 22b is supplied with a gasifying agent 27 such as water vapor through a wind box 28 or the like to form a fluidized bed 29. Also, the raw material supply devices 30a, 30b supply raw materials 31a, 31b. In this way, the raw materials 31a and 31b are gasified in the gasifiers 22a and 22b. At this time, the raw materials 31a and 31b supplied to the gasifiers 22a and 22b by the raw material supply devices 30a and 30b may be the same raw material, or different raw materials are supplied to the gasifiers 22a and 22b. You may do it. Further, the same gasifying agent 27 may be used for each gasifier 22a, 22b, or different gasifying agents may be used.

各ガス化装置22a,22b内でのガス化によって生成したガス化ガス32a,32bは、各ガス化装置22a,22bに設けられた取出口33から別個に取り出すようにしている。又、各ガス化装置22a,22bでガス化されなかったチャーと流動媒体は、オーバーフロー管等からなる供給流路34a,34bにより再び前記流動層燃焼炉1へ供給されて循環されるようになっている。   The gasified gases 32a and 32b generated by gasification in the gasifiers 22a and 22b are separately taken out from the outlets 33 provided in the gasifiers 22a and 22b. In addition, the char and the fluidized medium that have not been gasified by the gasifiers 22a and 22b are again supplied to the fluidized bed combustion furnace 1 through the supply passages 34a and 34b made of overflow pipes and circulated. ing.

図2は、温度変化手段25の他の例を示したもので、この例では複数備えた分離器21a,21bを移送管35a,35bにより流動層燃焼炉1に接続すると共に、各分離器21a,21bで分離した流動媒体9を降下管36a,36bにより各ガス化装置22a,22bに導入するようにしている。そして、前記移送管35a,35bの少なくとも一方にダンパ等の流量調節器37を設置する、或いは、移送管35a,35bの断面積を設定することにより構成した温度変化手段25によって、各ガス化装置22a,22bに供給する流動媒体9の流量を調整することにより、各ガス化装置22a,22bの温度を所定の温度に保持できるようにしている。   FIG. 2 shows another example of the temperature changing means 25. In this example, a plurality of separators 21a and 21b are connected to the fluidized bed combustion furnace 1 by transfer pipes 35a and 35b, and each separator 21a is connected. , 21b is introduced into the gasifiers 22a, 22b through the downcomers 36a, 36b. Each gasifier is provided with a temperature changing means 25 configured by installing a flow rate regulator 37 such as a damper in at least one of the transfer pipes 35a and 35b, or by setting a cross-sectional area of the transfer pipes 35a and 35b. By adjusting the flow rate of the fluid medium 9 supplied to 22a and 22b, the temperature of each gasifier 22a and 22b can be maintained at a predetermined temperature.

次に、上記図1、図2に示した形態の作動を説明する。   Next, the operation of the embodiment shown in FIGS. 1 and 2 will be described.

流動層ガス化炉2を複数のガス化装置22a,22bで構成し、各ガス化装置22a,22bに降下管36a,36bを介して流動媒体9を導入すると共に、水蒸気等のガス化剤27と、原料31a,31bとを供給すると、原料31a,31bが流動層29によってガス化され、各ガス化装置22a,22bで生成したガス化ガス32a,32bは夫々の取出口33から取り出される。   The fluidized bed gasification furnace 2 is composed of a plurality of gasifiers 22a and 22b, and the fluidized medium 9 is introduced into the gasifiers 22a and 22b via the downcomers 36a and 36b, and a gasifying agent 27 such as water vapor is used. When the raw materials 31a and 31b are supplied, the raw materials 31a and 31b are gasified by the fluidized bed 29, and the gasified gases 32a and 32b generated by the gasifiers 22a and 22b are taken out from the respective outlets 33.

上記したように、流動層ガス化炉2による原料のガス化に必要なガス化容積を複数に分割した小容積のガス化装置22a,22bを備えたことにより、各ガス化装置22a,22bに導入された流動媒体9は各ガス化装置22a,22bの隅々まで移動されるようになり、流動媒体が停滞したデッドスペース部分の発生を防止することができる。このため、各ガス化装置22a,22bの容積が有効に活用されることにより流動層ガス化炉2のガス化能力が高められ、よって原料31a,31bの処理量、ガス化ガス32a,32bの生成量を増加することができる。   As described above, by providing the gasifiers 22a and 22b having a small volume obtained by dividing the gasification volume necessary for the gasification of the raw material by the fluidized bed gasifier 2, each gasifier 22a and 22b is provided with each gasifier. The introduced fluid medium 9 is moved to every corner of the gasifiers 22a and 22b, and it is possible to prevent a dead space portion where the fluid medium is stagnant. For this reason, the gasification capacity of the fluidized bed gasification furnace 2 is enhanced by effectively utilizing the volumes of the gasifiers 22a and 22b, so that the throughput of the raw materials 31a and 31b and the gasification gases 32a and 32b are increased. The amount of production can be increased.

又、前記したように小容積に形成された各ガス化装置22a,22bは、図1、図2に示すように平面的に見て相互にラップするように上下に積み重ねるように配置することにより、流動層ガス化炉2の設置スペースを小さくすることができる。   In addition, as described above, the gasifiers 22a and 22b formed in a small volume are arranged so as to be stacked one above the other so as to wrap each other in plan view as shown in FIGS. The installation space of the fluidized bed gasification furnace 2 can be reduced.

更に、図1、図2に示した温度変化手段25によって各ガス化装置22a,22bに供給する流動媒体9の供給量を調整して、各ガス化装置22a,22bの温度を調整することにより、原料供給装置30a,30bによって異なる原料31a,31bを各ガス化装置22a,22bに供給して同時にガス化することができる。例えば800℃〜900℃の温度に保持されたガス化装置22aには、その温度で良好なガス化が行われて多くのガス化ガス32aを生成する石炭、石油残渣等の高炭素含有の原料31aを供給し、他方、600℃〜700℃の温度に保持されたガス化装置22bには、前記800℃〜900℃の温度ではガス化時に低融点の灰が生成されてしまうバイオマス、籾がら、稲わら、下水汚泥等の低炭素含有の原料31bを供給するようにして、高温で好適にガス化できる原料31aとガス化時に低融点の灰が生成する原料31bとを1つの流動層ガス化設備で同時にガス化することができる。   Further, by adjusting the supply amount of the fluidized medium 9 supplied to each gasifier 22a, 22b by the temperature changing means 25 shown in FIGS. 1 and 2, the temperature of each gasifier 22a, 22b is adjusted. Different raw materials 31a and 31b can be supplied to the gasifiers 22a and 22b depending on the raw material supply devices 30a and 30b and simultaneously gasified. For example, in the gasifier 22a maintained at a temperature of 800 ° C. to 900 ° C., a high carbon content raw material such as coal, petroleum residue, etc., which is gasified satisfactorily at that temperature to produce a large amount of gasified gas 32a. On the other hand, the gasifier 22b supplied with 31a and maintained at a temperature of 600 ° C. to 700 ° C. has a low melting point ash produced at the temperature of 800 ° C. to 900 ° C., and biomass and soot. A fluidized bed gas comprising a raw material 31a that can be suitably gasified at a high temperature and a raw material 31b that produces low melting point ash upon gasification by supplying raw material 31b having a low carbon content such as rice straw and sewage sludge It can be gasified at the same time with a gasification facility.

例えば600℃〜700℃に保持したガス化装置22bにおいて低炭素含有の原料31bをガス化すると、ガス化装置22bで低融点の灰が生成する問題が防止され、よって低融点灰がガス化ガス32bと共に取り出されて配管及び機器等に付着する問題は回避される。一方、上記低融点灰は、流動媒体及びチャーに付着して流動層燃焼炉1に供給されるが、流動層燃焼炉1では例えば1000℃〜1100℃の高温で燃焼されるため、低融点の灰はベイパーとなって排気ガス8と共に排出される。   For example, when the raw material 31b having a low carbon content is gasified in the gasifier 22b maintained at 600 ° C. to 700 ° C., the problem of generating low melting point ash in the gasifier 22b is prevented. The problem of being taken out together with 32b and adhering to piping and equipment is avoided. On the other hand, the low melting point ash adheres to the fluidized medium and the char and is supplied to the fluidized bed combustion furnace 1. In the fluidized bed combustion furnace 1, for example, it burns at a high temperature of 1000 ° C. to 1100 ° C. Ashes become vapor and are discharged together with the exhaust gas 8.

図3は本発明の形態の他の例を示すものであり、この例では流動層ガス化炉2を、複数のガス化装置22a,22b,22c,22dにより構成し、各ガス化装置22a,22b,22c,22dをオーバーフロー管38により上下方向に直列に多段に接続している。各ガス化装置22a,22b,22c,22dには、水蒸気等のガス化剤27が風箱28等により供給されて流動層29を形成している。最上段のガス化装置22aには分離器21からの流動媒体9を供給すると共に、原料供給装置30により原料31が供給されており、供給された前記流動媒体9は、堰板39を乗り越えてオーバーフロー管38により下段のガス化装置22bに流下し、この時、オーバーフロー管38の下部が下段のガス化装置22bの流動層29内に没入した挿入板40を備えていることにより、流動媒体9はオーバーフロー管38の内部を満たした状態を保持して下段のガス化装置22bに供給されるようになっている。ガス化装置22bよりも更に下段のガス化装置22c,22dについても同様に構成されている。   FIG. 3 shows another example of the embodiment of the present invention. In this example, the fluidized bed gasification furnace 2 is constituted by a plurality of gasifiers 22a, 22b, 22c, 22d, and each gasifier 22a, 22b, 22c and 22d are connected in multiple stages in series in the vertical direction by an overflow pipe 38. Each gasifier 22a, 22b, 22c, 22d is supplied with a gasifying agent 27 such as water vapor by a wind box 28 or the like to form a fluidized bed 29. The uppermost gasifier 22 a is supplied with the fluid medium 9 from the separator 21 and is supplied with the raw material 31 by the raw material supply device 30, and the supplied fluid medium 9 gets over the weir plate 39. By flowing into the lower gasifier 22b through the overflow pipe 38, the lower portion of the overflow pipe 38 is provided with the insertion plate 40 immersed in the fluidized bed 29 of the lower gasifier 22b. Is supplied to the lower gasifier 22b while maintaining a state in which the inside of the overflow pipe 38 is filled. The lower gasifiers 22c and 22d are configured in the same manner as the gasifier 22b.

図3では、最上段のガス化装置22aに供給された原料31aは、分離器21から降下管23により導入される流動媒体9とガス化剤27の作用によってガス化され、生成したガス化ガス32aはガス化装置22aの取出口33から取り出され、又、流動媒体とチャーは堰板39を乗り越えてオーバーフロー管38により下段のガス化装置22bに供給され、下段のガス化装置22bでチャーがガス化されることにより生成したガス化ガス32bはガス化装置22bの取出口33から取り出され、このようにして順次下段に送られてガス化され、最下段のガス化装置22dでガス化されなかったチャーと流動媒体は供給流路34により流動層燃焼炉1に供給される。   In FIG. 3, the raw material 31 a supplied to the uppermost gasifier 22 a is gasified by the action of the fluidizing medium 9 and the gasifying agent 27 introduced from the separator 21 through the downcomer 23, and generated gasified gas. 32a is taken out from the outlet 33 of the gasifier 22a, and the fluid medium and char get over the weir plate 39 and are supplied to the lower gasifier 22b through the overflow pipe 38. The gasified gas 32b generated by gasification is taken out from the outlet 33 of the gasifier 22b, and is thus sequentially sent to the lower stage for gasification, and is gasified by the lowermost gasifier 22d. The char and fluid medium that have not been supplied are supplied to the fluidized bed combustion furnace 1 through the supply flow path 34.

上記において、最上段のガス化装置22aに導入される流動媒体9は、原料供給装置30から供給される原料31による冷却を受け、更にオーバーフロー管38を流下する間に外部からの冷却を受けるために、流動媒体9は下段に流下するに従って温度が低下する。このように、上段のガス化装置の温度に対して下段のガス化装置の温度が低くなることによって温度変化手段25を形成している。   In the above, the fluidized medium 9 introduced into the uppermost gasifier 22a is cooled by the raw material 31 supplied from the raw material supply device 30, and further receives external cooling while flowing down the overflow pipe 38. In addition, the temperature of the fluidized medium 9 decreases as it flows downward. In this way, the temperature changing means 25 is formed by lowering the temperature of the lower gasifier with respect to the temperature of the upper gasifier.

図3の形態によれば、流動層ガス化炉2による原料のガス化に必要なガス化容積を複数に分割した小容積のガス化装置22a,22b,22c,22dを備えたことにより、各ガス化装置22a,22b,22c,22dに導入された流動媒体9は各ガス化装置22a,22b,22c,22dの隅々まで移動されるようになり、流動媒体が停滞したデッドスペース部分の発生を防止することができる。このため、各ガス化装置22a,22b,22c,22dの容積が有効に活用されることにより流動層ガス化炉2のガス化能力が高められ、よって原料31の処理量、ガス化ガス32a,32b,32c,32dの生成量を増加することができる。   According to the form of FIG. 3, each of the gasification devices 22a, 22b, 22c, and 22d having a small volume obtained by dividing the gasification volume required for gasification of the raw material by the fluidized bed gasification furnace 2 into a plurality is provided. The fluidized medium 9 introduced into the gasifiers 22a, 22b, 22c, and 22d is moved to every corner of the gasifiers 22a, 22b, 22c, and 22d, and a dead space portion where the fluidized medium is stagnated is generated. Can be prevented. For this reason, the gasification capacity of the fluidized bed gasification furnace 2 is enhanced by effectively utilizing the volumes of the gasifiers 22a, 22b, 22c, and 22d, so that the throughput of the raw material 31 and the gasification gas 32a, The generation amount of 32b, 32c, 32d can be increased.

又、複数のガス化装置22a,22b,22c,22dを上下方向に直列に多段に接続した構成としたので、流動層ガス化炉2の設置スペースを著しく小さなものとすることができる。   Further, since the plurality of gasifiers 22a, 22b, 22c, and 22d are connected in series in the vertical direction, the installation space of the fluidized bed gasification furnace 2 can be made extremely small.

更に、上段のガス化装置の温度に対して下段のガス化装置の温度が低いことによって温度変化手段25を形成しているので、分離器21からの流動媒体9によって例えば800℃〜900℃の温度に保持された最上段のガス化装置22aに対しては、上記温度で良好なガス化が行われて多くのガス化ガス32aを生成することができる石炭、石油残渣等の高炭素含有の原料31aを供給し、また、600℃〜700℃の温度に低下した下段のガス化装置22bには、前記800℃〜900℃の温度ではガス化時に低融点の灰が生成されてしまうバイオマス、籾がら、稲わら、下水汚泥等の低炭素含有の原料31bを供給することにより、高温で好適にガス化できる原料31aとガス化時に低融点の灰が生成する原料31bとを同時にガス化することができる。   Furthermore, since the temperature change means 25 is formed by the temperature of the lower gasifier being lower than the temperature of the upper gasifier, the temperature of the fluidizer 9 from the separator 21 is, for example, 800 ° C. to 900 ° C. For the uppermost gasifier 22a maintained at a temperature, high gas content such as coal, petroleum residue, etc., which can generate a large amount of gasification gas 32a by performing good gasification at the above temperature. In the lower gasifier 22b supplied with the raw material 31a and lowered to a temperature of 600 ° C. to 700 ° C., a biomass in which low melting point ash is generated at the temperature of 800 ° C. to 900 ° C. during gasification, By supplying raw material 31b containing low carbon such as rice straw, rice straw, sewage sludge, etc., raw material 31a that can be suitably gasified at high temperature and raw material 31b that generates low melting point ash upon gasification are simultaneously gasified. It is possible.

ここで、図3では、2段目のガス化装置22bに低炭素含有の原料31bを供給しているが、低炭素含有の原料31bは、該低炭素含有の原料31bをガス化するのに適した温度である600℃〜700℃の温度に低下している下段のいずれかのガス化装置を選定して供給することができる。又、図3中破線で示すように、前記分離器21の降下管23に流動媒体9を分岐して供給する分岐装置24を設けて、該分岐装置24で分岐した流動媒体9を分岐管26,26bにより最上段のガス化装置22aと下段の任意のガス化装置に供給するようにして、下段のガス化装置の温度が、前記低炭素含有の原料31bを供給してガス化するのに適した温度になるように調整してもよい。   Here, in FIG. 3, the low carbon-containing raw material 31b is supplied to the second stage gasifier 22b, but the low-carbon containing raw material 31b is used to gasify the low-carbon containing raw material 31b. Any one of the gasifiers in the lower stage, which is lowered to a suitable temperature of 600 ° C. to 700 ° C., can be selected and supplied. Further, as shown by a broken line in FIG. 3, a branching device 24 is provided to branch and supply the fluid medium 9 to the descending pipe 23 of the separator 21, and the fluid medium 9 branched by the branching device 24 is supplied to the branch pipe 26. 26b is supplied to the uppermost gasifier 22a and an arbitrary lower gasifier, and the temperature of the lower gasifier supplies the low-carbon-containing raw material 31b to gasify it. You may adjust so that it may become suitable temperature.

なお、本発明の流動層ガス化方法及び設備は、上記形態にのみ限定されるものではなく、本発明の要旨を逸脱しない範囲内において種々変更を加え得ることは勿論である。   In addition, the fluidized bed gasification method and equipment of the present invention are not limited to the above embodiments, and it is needless to say that various changes can be made without departing from the scope of the present invention.

本発明の形態の一例を示す概略側面図である。It is a schematic side view which shows an example of the form of this invention. 図1の形態の変更例を示す概略側面図である。It is a schematic side view which shows the example of a change of the form of FIG. 本発明の形態の他の例を示す概略側面図である。It is a schematic side view which shows the other example of the form of this invention. 2塔式の流動層ガス化設備の概略側面図である。It is a schematic side view of a two-column fluidized bed gasification facility. 図4の切断平面図である。FIG. 5 is a cut plan view of FIG. 4.

符号の説明Explanation of symbols

1 流動層燃焼炉
2 流動層ガス化炉
8 燃焼ガス
9 流動媒体
21,21a,21b 分離器
22a,22b,22c,22d ガス化装置
23 降下管
24 分岐装置
25 温度変化手段
27 ガス化剤
29 流動層
30,30a,30b 原料供給装置
31,31a,31b 原料
32a,32b,32c,32d ガス化ガス
33 取出口
34,34a,34b 供給流路
36a,36b 降下管
38 オーバーフロー管
DESCRIPTION OF SYMBOLS 1 Fluidized bed combustion furnace 2 Fluidized bed gasification furnace 8 Combustion gas 9 Fluidized medium 21,21a, 21b Separator 22a, 22b, 22c, 22d Gasifier 23 Downcomer 24 Branch device 25 Temperature change means 27 Gasifying agent 29 Flow Layer 30, 30a, 30b Raw material supply device 31, 31a, 31b Raw material 32a, 32b, 32c, 32d Gasification gas 33 Outlet 34, 34a, 34b Supply flow path 36a, 36b Downcomer pipe 38 Overflow pipe

Claims (6)

チャーを燃焼させて流動媒体を加熱する流動層燃焼炉と、
流動層燃焼炉から導出される燃焼ガスから流動媒体を分離する分離器と、
分離器で分離した流動媒体を降下管を介して導入すると共に原料とガス化剤を供給して流動層により原料をガス化する流動層ガス化炉と、
流動層ガス化炉で原料をガス化する際に生成したチャーと流動媒体とを流動層燃焼炉に循環する供給流路と、を有する流動層ガス化方法であって、
流動層ガス化炉を複数のガス化装置により構成し、
各ガス化装置の温度を原料のガス化に適したガス化温度に保持するようにした温度変化手段を備え、高温で好適にガス化できる原料と、ガス化時に低融点の灰が生成する原料とを、対応するガス化温度に保持したガス化装置に供給して同時にガス化し
各ガス化装置において生成したガス化ガスを別個に取り出すようにしたことを特徴とする流動層ガス化方法。
A fluidized bed combustion furnace for burning the char to heat the fluidized medium;
A separator for separating the fluidized medium from the combustion gas derived from the fluidized bed combustion furnace;
A fluidized bed gasification furnace for introducing a fluidized medium separated by a separator through a downcomer and supplying a raw material and a gasifying agent to gasify the raw material by a fluidized bed;
A fluidized bed gasification method having a supply flow path for circulating a char generated when gasifying a raw material in a fluidized bed gasification furnace and a fluidized medium to the fluidized bed combustion furnace,
The fluidized bed gasifier is composed of multiple gasifiers,
A raw material that can be suitably gasified at a high temperature, and a raw material from which low melting point ash is produced at the time of gasification, provided with a temperature changing means that keeps the temperature of each gasifier at a gasification temperature suitable for the gasification of the raw material Are supplied to a gasifier maintained at the corresponding gasification temperature and gasified at the same time ,
A fluidized bed gasification method characterized in that the gasification gas generated in each gasifier is separately taken out.
チャーを燃焼させて流動媒体を加熱する流動層燃焼炉と、
流動層燃焼炉から導出される燃焼ガスから流動媒体を分離する分離器と、
分離器で分離した流動媒体を降下管を介して導入すると共に原料とガス化剤を供給して流動層により原料をガス化する流動層ガス化炉と、
流動層ガス化炉で原料をガス化する際に生成したチャーと流動媒体とを流動層燃焼炉に循環する供給流路と、を有する流動層ガス化設備であって、
分離器からの流動媒体を流動化して原料のガス化を行うようにした複数のガス化装置を備え、
各ガス化装置の温度を原料のガス化に適したガス化温度に保持するようにした温度変化手段を備え、
高温で好適にガス化できる原料と、ガス化時に低融点の灰が生成する原料とを、対応するガス化温度に保持したガス化装置に供給する原料供給装置を備え、
各ガス化装置において生成するガス化ガスを取り出すための取出口を各ガス化装置に備えたことを特徴とする流動層ガス化設備。
A fluidized bed combustion furnace for burning the char to heat the fluidized medium;
A separator for separating the fluidized medium from the combustion gas derived from the fluidized bed combustion furnace;
A fluidized bed gasification furnace for introducing a fluidized medium separated by a separator through a downcomer and supplying a raw material and a gasifying agent to gasify the raw material by a fluidized bed;
A fluidized bed gasification facility having a supply flow path for circulating a char and a fluidized medium generated when gasifying a raw material in a fluidized bed gasification furnace to the fluidized bed combustion furnace,
Comprising a plurality of gasifiers that fluidize the fluid medium from the separator to gasify the raw material;
Equipped with temperature changing means adapted to maintain the temperature of each gasifier at a gasification temperature suitable for gasification of the raw material,
A raw material supply device that supplies a raw material that can be suitably gasified at a high temperature and a raw material from which low melting point ash is generated at the time of gasification to a gasifier that maintains the corresponding gasification temperature,
A fluidized bed gasification facility, wherein each gasifier is provided with an outlet for taking out gasified gas produced in each gasifier.
複数のガス化装置は上下に配置され、且つ、上下のガス化装置は平面的に見て少なくとも一部が相互にラップして配置された請求項2に記載の流動層ガス化設備。 The fluidized-bed gasification facility according to claim 2, wherein the plurality of gasifiers are arranged one above the other, and at least part of the upper and lower gasifiers are arranged so as to overlap each other when seen in a plan view . 温度変化手段は、分離器で分離した流動媒体を分岐して各ガス化装置に導く分岐装置である請求項2に記載の流動層ガス化設備。   The fluidized bed gasification facility according to claim 2, wherein the temperature changing means is a branching device that branches the fluidized medium separated by the separator and guides it to each gasifier. 温度変化手段は、燃焼ガスの取り入れ量を調整した燃焼ガスから流動媒体を分離し、分離した流動媒体を各ガス化装置に導く複数の分離器である請求項2に記載の流動層ガス化設備。   The fluidized bed gasification equipment according to claim 2, wherein the temperature changing means is a plurality of separators for separating the fluidized medium from the combustion gas whose amount of combustion gas has been adjusted and guiding the separated fluidized medium to each gasifier. . 温度変化手段は、各ガス化装置が上下方向に多段に接続され、上段のガス化装置の流動媒体がオーバーフロー管により下段のガス化装置に流下するようにしてあり、上段のガス化装置の温度に対して下段のガス化装置の温度が低いことからなる請求項2に記載の流動層ガス化設備。   The temperature change means is configured such that each gasifier is connected in multiple stages in the vertical direction, and the fluid medium of the upper gasifier flows down to the lower gasifier via the overflow pipe, and the temperature of the upper gasifier The fluidized bed gasification facility according to claim 2, wherein the temperature of the lower gasifier is lower than that of the gasification device.
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