JP5246439B2 - Food containing liquid for microwave heating - Google Patents

Food containing liquid for microwave heating Download PDF

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JP5246439B2
JP5246439B2 JP2009265462A JP2009265462A JP5246439B2 JP 5246439 B2 JP5246439 B2 JP 5246439B2 JP 2009265462 A JP2009265462 A JP 2009265462A JP 2009265462 A JP2009265462 A JP 2009265462A JP 5246439 B2 JP5246439 B2 JP 5246439B2
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貴久 瀧田
学 長野
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Description

本発明は、電子レンジ加熱(マイクロ波加熱)の際に、噴きこぼれの発生が防止ないしは抑制された電子レンジ加熱用液状物含有食品に関する。   The present invention relates to a liquid-containing food for heating a microwave oven in which the occurrence of spilling is prevented or suppressed during microwave heating (microwave heating).

電子レンジ加熱による加温や解凍を想定した液状物含有食品が広く市販されている。例えば、予め加熱調理したカレー、スープ等の料理等をパウチ内に密封してレトルト処理したレトルト食品や、上述した料理等をパウチ内に密封して冷凍処理した冷凍食品等が販売されている。また、最近では、電子レンジ加熱を単純な食品の加温や解凍だけに利用するのではなく、食品の加熱調理に積極的に利用することも行われるようになっている。   Liquid-containing foods that are assumed to be heated and thawed by heating in a microwave oven are widely available on the market. For example, retort foods in which dishes such as curry and soup cooked in advance are sealed in a pouch and retort processed, and frozen foods in which the above-described dishes are sealed in a pouch and frozen are sold. Moreover, recently, microwave heating is not only used for heating and thawing of simple foods but also actively used for cooking foods.

ところで、電子レンジ加熱を液状物含有食品の加温やその冷凍物の解凍に利用する際、液状物を局部的に加熱してしまう場合がある。そのような場合、局部的に激しく沸騰して泡立ち、噴きこぼれが生じることがある。この問題は、電子レンジを加熱調理に利用する場合にも大きな問題となっている。即ち、液状物を含む食品を電子レンジで加熱調理した場合、鍋とガスコンロとを使用する加熱調理の場合と異なり、マイクロウェーブの木目細かい出力調整が困難であり、結果的に、食品を電子レンジ加熱調理する間、液状物が激しい沸騰状態となり、噴きこぼれがいっそう起こりやすい。   By the way, when microwave heating is used for heating a liquid-containing food or thawing the frozen product, the liquid may be locally heated. In such a case, it may boil and boil locally, causing spilling. This problem is a big problem even when the microwave oven is used for cooking. In other words, when food containing liquids is cooked in a microwave oven, unlike in the case of cooking using a pan and gas stove, it is difficult to fine-tune the output of the microwave, and as a result, the food is microwaved. During cooking, the liquid material becomes a violent boiling state, and spilling is more likely to occur.

このような噴きこぼれを防止するためには、通常、HLB(Hydrophile−Lipophile Balance)値が1〜3の消泡剤を配合することが試みられているが、そのような低いHLB値の消泡剤は油溶性であり、実質的に水には溶解しないため、それを食品にそのまま混合すると、製造ラインや製品容器に消泡剤が付着して消泡効果が低下したり、食品の外観、風味や食感に悪影響を及ぼしたり等の問題が生じる。また、このような消泡剤では、食品製造における撹拌工程等の機械的な作用により生じる泡の消泡は実現できるものの、電子レンジ加熱調理の際の液状物の激しい沸騰により生ずる泡の消泡については、十分とはいえない場合があった。   In order to prevent such spilling, it has been attempted to add an antifoaming agent having an HLB (Hydrophile-Lipophile Balance) value of 1 to 3, but the antifoaming of such a low HLB value is usually attempted. Since the agent is oil-soluble and does not substantially dissolve in water, if it is mixed with food as it is, the antifoaming agent will adhere to the production line or product container and the defoaming effect will be reduced, the appearance of the food, Problems such as adversely affecting the flavor and texture occur. In addition, with such an antifoaming agent, foam defoaming caused by mechanical action such as a stirring process in food production can be realized, but foam defoaming caused by intense boiling of a liquid substance during cooking in a microwave oven is possible. There were cases where it was not enough.

そこで、電子レンジ加熱時の液状物含有食品の噴きこぼれを防止するため、電子レンジ加熱調理用食品に消泡性の調味料を添加することが提案されている。具体的には、プロピレングリコール脂肪酸エステルもしくはソルビタン脂肪酸エステル或いはショ糖脂肪酸エステルと、塩化ナトリウム又は塩化カリ或いはそれらの混合物とからなる消泡性組成物を、他の調味料成分に配合したもの(特許文献1)や、グリセリン脂肪酸エステル、レシチンあるいはエタノールなど消泡性物質に酵素やキレート剤などを配合した消泡性組成物(特許文献2)が提案されている。   Therefore, it has been proposed to add a defoaming seasoning to a food for cooking by heating in a microwave oven in order to prevent the liquid-containing food from spilling out during heating in the microwave. Specifically, an antifoaming composition comprising propylene glycol fatty acid ester, sorbitan fatty acid ester or sucrose fatty acid ester and sodium chloride, potassium chloride or a mixture thereof is blended with other seasoning ingredients (patent Document 1) and an antifoaming composition (Patent Document 2) in which an antifoaming substance such as glycerin fatty acid ester, lecithin or ethanol is mixed with an enzyme or a chelating agent have been proposed.

特開平1−101870号公報Japanese Patent Laid-Open No. 1-1101870 特開2001−086943号公報JP 2001-086943 A

しかしながら、特許文献1や特許文献2に記載された調味料に配合される消泡剤組成物の場合、電子レンジ用に開発されたものではあるが、電子レンジ加熱による液状物含有食品、特に甚だしい噴きこぼれを生じさせる乳蛋白質や水溶性蛋白を含有する液状物含有食品に生じた泡の消泡については、十分とは言い難いという問題があった。このため、従来の消泡剤組成物よりも電子レンジ加熱に適した消泡剤組成物を配合した、電子レンジ加熱の際に噴きこぼれのない電子レンジ加熱用液状物含有食品が求められている。   However, in the case of the antifoaming composition to be blended with the seasoning described in Patent Document 1 and Patent Document 2, it was developed for a microwave oven, but it is a liquid-containing food by microwave heating, particularly severe. There has been a problem that foam defoaming in a liquid-containing food containing milk protein or water-soluble protein that causes spillage is not sufficient. For this reason, there is a need for a liquid-containing food for heating a microwave oven that is blended with an antifoaming agent composition that is more suitable for microwave heating than a conventional antifoaming agent composition and that does not spill during microwave heating. .

本発明の目的は、以上の従来の技術の課題を解決しようとするものであり、従来の消泡剤組成物を使用しなくても、電子レンジ加熱による噴きこぼれが抑制又は防止された電子レンジ加熱用液状物含有食品を提供することである。   SUMMARY OF THE INVENTION An object of the present invention is to solve the above-described problems of the prior art, and a microwave oven in which spillage due to microwave heating is suppressed or prevented without using a conventional antifoaming agent composition. It is to provide a liquid-containing food for heating.

本発明者らは、相対的に低いHLB値の親油性乳化剤と相対的に高いHLB値の親水性乳化剤とで食用油脂を乳化することにより得られる消泡剤乳化組成物を、電子レンジ用液状物含有食品に配合することにより、本発明の目的を達成できることを見出し、本願発明を完成させるに至った。   The present inventors have developed a defoamer emulsion composition obtained by emulsifying edible fats and oils with a lipophilic emulsifier having a relatively low HLB value and a hydrophilic emulsifier having a relatively high HLB value. It discovered that the objective of this invention could be achieved by mix | blending with a foodstuff containing food, and came to complete this invention.

即ち、本発明は、食用油脂が親油性乳化剤と親水性乳化剤とで乳化されてなる消泡剤乳化組成物を含有する電子レンジ加熱用液状物含有食品であって、
消泡剤乳化組成物の乳化粒子が0.1〜0.5μmの平均粒子径を有することを特徴とする電子レンジ加熱用液状物含有食品を提供する。
That is, the present invention is a microwave-containing liquid food containing food containing an antifoam emulsifying composition obtained by emulsifying an edible fat with a lipophilic emulsifier and a hydrophilic emulsifier,
Provided is a liquid-containing food for microwave heating, wherein the emulsified particles of the defoamer emulsified composition have an average particle size of 0.1 to 0.5 μm.

また、本発明は、上述の電子レンジ加熱用液状物含有食品が、電子レンジ加熱用容器に充填されていることを特徴とする電子レンジ加熱用容器詰め食品を提供する。電子レンジ加熱用容器は、電子レンジ加熱に必要なワット数と時間の説明表示を備えていることが好ましい。   The present invention also provides a microwave-packed food for heating a microwave oven, wherein the above-mentioned liquid-containing food for microwave heating is filled in a microwave-heating container. It is preferable that the container for microwave heating is equipped with the description display of wattage and time required for microwave heating.

更に、本発明は、上述の電子レンジ加熱用液状物含有食品を、電子レンジで加熱することを特徴とする加熱食品の製造方法を提供する。この製造方法においては、電子レンジ加熱用容器詰め食品の容器内に具材を投入し、電子レンジで加熱することが好ましい。   Furthermore, this invention provides the manufacturing method of the heated food characterized by heating the above-mentioned liquid substance containing foodstuff for microwave oven heating with a microwave oven. In this production method, it is preferable to put ingredients in a container for food packed in a microwave heating container and heat in a microwave oven.

本願発明の電子レンジ加熱用液状物食品は、食用油脂を親油性乳化剤と親水性乳化剤とで、所定の大きさの乳化粒子が形成されるように乳化させたものである。このため、電子レンジ加熱用液状物食品を電子レンジ加熱した場合、噴きこぼれを大きく抑制又は防止することができる。   The liquid food for microwave heating of the present invention is obtained by emulsifying edible fats and oils with a lipophilic emulsifier and a hydrophilic emulsifier so that emulsified particles of a predetermined size are formed. For this reason, when the liquid food for microwave heating is microwave-heated, spilling can be largely suppressed or prevented.

本発明の電子レンジ加熱用容器詰め食品の一態様である電子レンジ調理用パウチ詰め食品の正面図である。It is a front view of the pouch stuffed food for microwave oven cooking which is one mode of the container stuffed food for microwave oven heating of the present invention. 具材を投入するためにジッパー部を開口した電子レンジ調理用パウチ詰め食品の正面図である。It is a front view of the pouch stuffed food for microwave ovens which opened the zipper part in order to throw in ingredients.

本発明の電子レンジ加熱用液状物含有食品は、液状物を含有する食品に消泡剤乳化組成物を含有させたものである。ここで、“液状物”とは、沸騰により水蒸気の気泡が生じるものであり、その形態としては、低〜高粘性の液体に限られず、ペーストのように微細な食用固形分が混入して全体が液状となっているものでもよい。液状物含有食品の具体例としては、各種ソース、たれ等の調味液、お粥、リゾット等の米飯加工品、スープ、シチュー、味噌汁等のスープ類、ココア、紅茶等の飲料、流動食等の液状栄養食品、カスタードクリーム等が挙げられる。   The liquid-containing food for microwave heating of the present invention is a food containing a liquid containing an antifoam emulsifying composition. Here, the “liquid substance” is a gas bubble produced by boiling, and its form is not limited to a low to high viscosity liquid, and the whole is mixed with fine edible solids such as paste. May be liquid. Specific examples of liquid-containing foods include various sauces, seasonings such as sauce, processed rice products such as porridge and risotto, soups such as soup, stew and miso soup, beverages such as cocoa and tea, liquid foods, etc. Examples include liquid nutritional foods and custard cream.

本発明において使用する消泡剤乳化組成物は、食用油脂が水中で親油性乳化剤と親水性乳化剤とにより乳化粒子として安定的に分散してなるものであり、乳化粒子の平均粒子径が0.1〜0.5μmであることを特徴としている。乳化粒子の平均粒子径が0.1μm未満、あるいは、0.5μmを超えると消泡効果が不十分となる。なお、前記平均粒子径(メジアン径)は、レーザー回折式粒度分布測定装置にて体積換算で得た粒度分布から求めた値である。   The antifoam emulsifying composition used in the present invention is obtained by stably dispersing edible oils and fats as emulsified particles in water with a lipophilic emulsifier and a hydrophilic emulsifier, and the average particle size of the emulsified particles is 0.00. It is characterized by being 1 to 0.5 μm. When the average particle diameter of the emulsified particles is less than 0.1 μm or exceeds 0.5 μm, the defoaming effect becomes insufficient. In addition, the said average particle diameter (median diameter) is the value calculated | required from the particle size distribution obtained by volume conversion with the laser diffraction type particle size distribution measuring apparatus.

消泡剤乳化組成物を構成する食用油脂とは、消泡剤組成物に消泡性を付与するためのものであり、具体的には、トリアシルグリセロール又はジアシルグリセロールを主成分とする脂質のことであり、公知の食用の食用油脂、例えば、魚油、卵黄油等の液状動物油、あるいは、菜種油、コーン油、大豆油、これらを精製したサラダ油等の液状植物油等を好ましく使用することができる。   The edible oil and fat constituting the defoaming agent emulsified composition is for imparting defoaming properties to the defoaming agent composition. Specifically, the edible fat is a lipid mainly composed of triacylglycerol or diacylglycerol. Thus, known edible edible fats and oils, for example, liquid animal oils such as fish oil and egg yolk oil, or rapeseed oil, corn oil, soybean oil, and liquid vegetable oils such as salad oil refined from these can be preferably used.

また、消泡剤乳化組成物中の食用油脂の配合量は、好ましくは2〜30質量%、より好ましくは2〜20質量%である。配合量がこの範囲より少ないと噴きこぼれを抑制又は防止する効果が充分に得られず、多くなると調整後の食品において油分量の多さが目立ち、油浮きが生じたりする場合がある。   Moreover, the compounding quantity of the edible fat in the antifoamer emulsion composition becomes like this. Preferably it is 2-30 mass%, More preferably, it is 2-20 mass%. If the blending amount is less than this range, the effect of suppressing or preventing spray spills cannot be obtained sufficiently. If the blending amount is too large, the amount of oil in the adjusted food is conspicuous and oil floating may occur.

消泡剤乳化組成物を構成する親油性乳化剤とは、消泡剤組成物に消泡性を付与するためのものであり、HLB値で表現するならば、HLB値が2〜8、好ましくはHLB値3〜8、より好ましくは5〜7の乳化剤である。このような親油性乳化剤の具体例としては、ショ糖脂肪酸エステル、グリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ポリグリセリン脂肪酸エステル、有機酸モノグリセリド等を例示することができる。脂肪酸の種類としては特に制限されるものではないが、炭素数が12〜22の飽和又は不飽和脂肪酸が挙げられる。中でも、ベヘニン酸、オレイン酸、エルカ酸を好ましく挙げられる。具体的な例としてはポリグリセリンエルカ酸エステル、ショ糖オレイン酸エステル、ショ糖ベヘニン酸エステルが好ましく挙げられる。なお、本発明においては、親油性乳化剤の2種以上を併用することができる。   The lipophilic emulsifier constituting the antifoam emulsifying composition is for imparting antifoaming properties to the antifoaming agent composition. If expressed by the HLB value, the HLB value is 2 to 8, preferably An emulsifier having an HLB value of 3 to 8, more preferably 5 to 7. Specific examples of such lipophilic emulsifiers include sucrose fatty acid esters, glycerin fatty acid esters, sorbitan fatty acid esters, polyglycerin fatty acid esters, and organic acid monoglycerides. Although it does not restrict | limit especially as a kind of fatty acid, C12-C22 saturated or unsaturated fatty acid is mentioned. Of these, behenic acid, oleic acid, and erucic acid are preferred. Specific examples include polyglycerol erucic acid ester, sucrose oleic acid ester, and sucrose behenic acid ester. In the present invention, two or more lipophilic emulsifiers can be used in combination.

消泡剤乳化組成物における親油性乳化剤の配合量は、少なすぎると噴きこぼれを抑制又は防止する効果が充分に得られず、多すぎると乳化組成物における乳化安定性が悪くなる傾向があるので、好ましくは1〜50質量%、より好ましくは5〜30質量%である。また、食用油脂との関係でいえば、親油性乳化剤が食用油脂より少なすぎたり多すぎたりすると噴きこぼれを抑制又は防止することが不十分となるので、親油性乳化剤1質量部に対して食用油脂を好ましくは0.1〜2質量部、より好ましくは0.1〜1質量部の割合である。   If the blending amount of the lipophilic emulsifier in the defoamer emulsified composition is too small, the effect of suppressing or preventing spilling cannot be sufficiently obtained, and if it is too large, the emulsion stability in the emulsified composition tends to deteriorate. The amount is preferably 1 to 50% by mass, more preferably 5 to 30% by mass. In terms of the relationship with edible oils and fats, if the lipophilic emulsifier is too little or too much than the edible oil or fat, it will be insufficient to suppress or prevent spilling, so that it is edible with respect to 1 part by weight of the lipophilic emulsifier. The fat is preferably 0.1 to 2 parts by mass, more preferably 0.1 to 1 part by mass.

消泡剤乳化組成物を構成する親水性乳化剤は、HLB値が10以上、好ましくは10〜16のポリグリセリン脂肪酸エステルやショ糖脂肪酸エステル、あるいは、レシチン等が挙げられる。   Examples of the hydrophilic emulsifier constituting the defoaming agent emulsified composition include polyglycerin fatty acid esters, sucrose fatty acid esters, lecithin and the like having an HLB value of 10 or more, preferably 10 to 16.

親水性乳化剤のうち、ポリグリセン脂肪酸エステルとしては、食品製造に一般的に利用できるものを使用することができ、具体的には、HLB値が10以上であり、且つ炭素数が6〜22の飽和又は不飽和脂肪酸を構成脂肪酸とするポリグリセリン脂肪酸エステル等を挙げることができる。   Among the hydrophilic emulsifiers, polyglycene fatty acid esters that can be generally used for food production can be used. Specifically, the HLB value is 10 or more, and the saturation is 6 to 22 carbon atoms. Or the polyglycerol fatty acid ester etc. which use unsaturated fatty acid as a constituent fatty acid can be mentioned.

親水性乳化剤のうち、ショ糖脂肪酸エステルとしては、食品製造に一般的に利用できるものを使用することができ、具体的には、HLB値が10以上であり、且つ炭素数が6〜22の飽和又は不飽和脂肪酸を構成脂肪酸とするショ糖脂肪酸エステル等を挙げることができる。   Among the hydrophilic emulsifiers, as the sucrose fatty acid ester, those that can be generally used for food production can be used. Specifically, the HLB value is 10 or more, and the carbon number is 6-22. Examples thereof include sucrose fatty acid esters having a saturated or unsaturated fatty acid as a constituent fatty acid.

親水性乳化剤のうち、レシチンとしては、大豆レシチン、卵黄レシチンの様な天然由来の他、合成レシチンでもよく、これらを2種以上併用することもできる。中でも、酵素分解レシチン等の親水性の高いリゾレシチンを好ましく使用することができる。   Among the hydrophilic emulsifiers, the lecithin may be derived from natural sources such as soybean lecithin and egg yolk lecithin, or may be synthetic lecithin, or two or more of these may be used in combination. Among them, lysolecithin having high hydrophilicity such as enzymatically decomposed lecithin can be preferably used.

消泡剤乳化組成物における親水性乳化剤の配合量は、少な過ぎても多過ぎても噴きこぼれを抑制又は防止する効果が充分に得られない傾向があるので、好ましくは0.4〜10質量%、より好ましくは0.4〜4質量%である。また、親水性乳化剤と親油性乳化剤との関係でいえば、親油性乳化剤1質量部に対し、好ましくは親水性乳化剤0.02〜0.5質量部、より好ましくは0.02〜0.2質量部となる割合である。配合割合がこの範囲にあれば、消泡効果と乳化効果とが良好となる。   The blending amount of the hydrophilic emulsifier in the antifoam emulsified composition is preferably 0.4 to 10 mass because there is a tendency that the effect of suppressing or preventing spilling is not sufficiently obtained even if the amount is too small or too large. %, More preferably 0.4 to 4% by mass. In terms of the relationship between the hydrophilic emulsifier and the lipophilic emulsifier, the hydrophilic emulsifier is preferably 0.02 to 0.5 parts by weight, more preferably 0.02 to 0.2 parts by weight with respect to 1 part by weight of the lipophilic emulsifier. It is the ratio which becomes a mass part. If a mixture ratio exists in this range, the defoaming effect and the emulsification effect will become favorable.

消泡剤乳化組成物の分散媒として使用する水としては、飲料用の水を使用でき、特にイオン交換水を好ましく使用することができる。消泡剤乳化組成物における水の配合割合は、少なすぎると乳化物とし難く、多すぎると消泡剤組成物として有効成分の濃度が下がるので、好ましくは20〜90質量%、より好ましくは40〜80質量%である。   As water used as the dispersion medium of the defoaming agent emulsion composition, water for drinking can be used, and ion-exchanged water can be particularly preferably used. If the blending ratio of water in the defoamer emulsified composition is too small, it is difficult to obtain an emulsion, and if it is too large, the concentration of the active ingredient as the defoamer composition is lowered, and therefore preferably 20 to 90% by mass, more preferably 40%. -80 mass%.

本発明で使用する消泡剤乳化組成物は、公知の方法により調製することができる。例えば、まず、親油性乳化剤を食用油脂に加熱溶解させて油性乳化剤溶液を調製し、それとは別に親水性乳化剤を清水に投入して必要により加熱して溶解させて水性乳化剤溶液を調製し、次に、油性乳化剤溶液と水性乳化剤溶液とを混合し、必要に応じて清水を加え、高圧乳化装置により所定の乳化粒子径となるように乳化処理することにより調製することができる。   The defoaming agent emulsion composition used in the present invention can be prepared by a known method. For example, first, prepare an oily emulsifier solution by dissolving lipophilic emulsifiers in edible fats and oils, and separately add a hydrophilic emulsifier to fresh water and heat to dissolve as necessary to prepare an aqueous emulsifier solution. In addition, an oil emulsifier solution and an aqueous emulsifier solution are mixed, fresh water is added as necessary, and the mixture is emulsified with a high-pressure emulsifier so as to obtain a predetermined emulsified particle size.

本発明の電子レンジ用液状物含有食品は、液状物含有食品に前述した消泡剤乳化組成物を、液状物含有食品100質量部に対し好ましくは0.01〜10質量部、より好ましくは0.05〜5質量部の割合で配合し、常法により混合することにより調製することができる。   The liquid-containing food for a microwave oven of the present invention is preferably 0.01 to 10 parts by mass, more preferably 0, with respect to 100 parts by mass of the anti-foaming agent emulsion described above for the liquid-containing food. It mix | blends in the ratio of 0.05-5 mass parts, and can prepare by mixing by a conventional method.

以上説明した本発明の電子レンジ用液状物含有食品は、電子レンジ加熱用容器に充填することにより電子レンジ加熱用容器詰め食品とすることができる。この電子レンジ加熱用容器詰め食品も本発明の一部である。また、電子レンジ加熱用容器詰め食品には、電子レンジ加熱に必要なワット数と時間の説明表示を設けることが好ましい。   The liquid-containing food for a microwave oven according to the present invention described above can be made into a microwave-packed food for heating by filling it in a microwave heating container. This packaged food for microwave heating is also part of the present invention. Moreover, it is preferable to provide an explanation display of the wattage and time required for microwave heating in the microwave-packed food.

また、本発明の電子レンジ加熱用液状物含有食品を耐熱容器に移し替え、あるいは電子レンジ加熱用容器詰め食品形態のまま、電子レンジで加熱することにより、加熱食品を製造することができる。この製造方法も本発明の一部である。後者の場合、電子レンジ加熱用液状物含有食品が充填された電子レンジ加熱用容器詰め食品の容器内に更に具材を投入し、電子レンジで加熱することができる。具材としては、例えば、キャベツ、ホウレン草、小松菜、ナス、インゲン、ブロッコリー、ダイコン、ニンジン、カブ、カボチャ、ジャガイモなどの野菜類、まいたけ、しめじなどのきのこ類、鶏肉、豚肉、牛肉、羊肉などの獣肉類、スズキ、タラ、たこ、いか、エビ、ムール貝、ホタテなどの魚介類などを挙げることができる。これらの具材は、容器に投入する前に予め、下茹で、油通し、あく抜きなどの下処理をしておくことができる。   Moreover, a heated food can be manufactured by transferring the liquid food containing foodstuff for microwave heating of this invention to a heat-resistant container, or by heating with a microwave oven with the foodstuff container-packed food form for microwave heating. This manufacturing method is also a part of the present invention. In the latter case, the ingredients can be further put into the container of the microwave heating container filled with the liquid-containing food for microwave heating, and heated in the microwave oven. Ingredients include, for example, cabbage, spinach, komatsuna, eggplant, green beans, broccoli, radish, carrots, turnips, pumpkins, potatoes and other mushrooms, maitake, shimeji mushrooms, chicken, pork, beef, lamb, etc. Examples include meats, seafood such as sea bass, sea bass, cod, octopus, squid, shrimp, mussels, and scallops. These ingredients can be subjected to a pretreatment such as oiling or punching with a lower punch before being put into the container.

また、電子レンジ加熱は、例えば、加えた具材の好ましいテクスチャーや旨みを加熱により引き出し、また、電子レンジ加熱用液状物含有食品である調味液(好ましくはレトルト調味液)で具材を調味する点から少なくとも調味液が沸騰する加熱条件、具体的には、調味液と加えた具材の合計300gあたり、好ましくは出力600W×3分相当以上の加熱をすることが好ましい。ここで600W×3分相当とは、出力300Wであれば6分、出力400Wであれば、4.5分、出力800Wであれば2.25分というように、出力ワット数と時間との積の値が同じになるように換算して計算した条件以上の電子レンジ加熱を行うことである。また、レトルト調味液と具材の合計が例えば600gであれば、出力ワット数と時間との積の値が300gの場合の2倍となるように電子レンジ加熱を行う。前記加熱条件の上限としては、沸騰状態を持続して投入した具材が適度に加熱調理される条件とすればよく、具体的には、投入した具材の種類にもよるが、レトルト調味液と加えた具材の合計300gあたり、好ましくは出力600W×20分相当以下の加熱条件とすればよい。   In addition, the microwave heating, for example, pulls out the preferred texture and taste of the added ingredients by heating, and seasons the ingredients with a seasoning liquid (preferably a retort seasoning liquid) that is a liquid-containing food for microwave heating. From the point of view, it is preferable to heat at least the equivalent of 600 W × 3 minutes per 300 g of the total of the seasoning liquid and the ingredients added, specifically, the heating conditions under which the seasoning liquid boils. Here, 600W × 3 minutes equivalent is the product of output wattage and time, such as 6 minutes for an output of 300W, 4.5 minutes for an output of 400W, and 2.25 minutes for an output of 800W. It is to perform microwave oven heating above the condition calculated by conversion so that the values of are the same. If the total of the retort seasoning liquid and ingredients is 600 g, for example, microwave heating is performed so that the product of the output wattage and time is twice that of 300 g. The upper limit of the heating condition may be a condition in which the ingredients that have been put into a boiling state are appropriately heated and cooked, and specifically, depending on the type of ingredients that have been added, the retort seasoning liquid The heating conditions are preferably equivalent to an output of 600 W × 20 minutes or less per 300 g of the added ingredients.

次に、本発明の電子レンジ加熱用容器詰め食品に関し、容器内に具材を投入し、電子レンジで加熱調理することにより調味液煮を得られるようにする電子レンジ調理用容器詰め食品について説明する。   Next, the microwaveable cooking container-packed food according to the present invention is described with respect to the microwave-cooked food packed in the container so that the ingredients can be put into the container and cooked in the microwave oven to obtain the seasoned liquid. To do.

この電子レンジ加熱用容器詰め食品に使用する電子レンジ加熱用容器としては、レトルト処理及びレンジ調理が可能な種々の容器を用いることができる。このような容器としては、例えば、耐熱性樹脂性の成形容器の他、底面にマチをもたせたスタンディングパウチ、底面及び側面にマチをもたせたガゼット袋、四方シール袋などが挙げられる。また、これら容器としては、容器を開封して具材を投入した後電子レンジ調理する前に当該容器を再封するための再封機能や、電子レンジ加熱調理時に蒸気を容器外に排出する蒸気抜き機構を備えていることが好ましい。   As the microwave heating container used for the microwave-packed food, various containers capable of retorting and cooking can be used. Examples of such a container include a heat-resistant resin molded container, a standing pouch with a gusset on the bottom surface, a gusset bag with a gusset on the bottom surface and side surfaces, and a four-side seal bag. In addition, these containers include a resealing function for resealing the container after the container is opened and the ingredients are added and before cooking in the microwave, or steam that discharges steam outside the container during microwave cooking. A punching mechanism is preferably provided.

以下、電子レンジ加熱用容器詰め食品の一態様を、図面を参照しつつ詳細に説明する。各図中、同一符号は同一又は同等の要素を表す。   Hereinafter, one aspect of the microwaveable heating container-packed food will be described in detail with reference to the drawings. In each figure, the same reference numerals represent the same or equivalent elements.

図1は、本発明の電子レンジ加熱用容器詰め食品の一実施態様の電子レンジ調理用パウチ詰食品1の正面図である。   FIG. 1 is a front view of a microwave cooking pouched food 1 according to an embodiment of the present invention.

この電子レンジ調理用パウチ詰め食品1は、電子レンジ対応のフィルム材料からなる袋状のパウチ10に、予め下調理した調味液30を充填密封し、レトルト処理したものであって、これを食するときに、所定の具材をパウチ10内に投入し、電子レンジで加熱調理するようにしたものである。ここで、レトルト処理としては、レトルト調味液30の中心部の品温を120℃で4分間相当加熱する処理又はこれと同等以上の加熱調理レベルを有する処理を挙げることができる。   This microwave-cooked pouch-packed food 1 is a bag-shaped pouch 10 made of a film material compatible with a microwave oven, filled with a seasoning liquid 30 prepared in advance, sealed, and retort-treated. Sometimes, predetermined ingredients are put into the pouch 10 and cooked in a microwave oven. Here, as a retort process, the process which heats the product temperature of the center part of the retort seasoning liquid 30 for 4 minutes at 120 degreeC, or the process which has a cooking level equal to or more than this can be mentioned.

図1に示す様に、パウチ10は、底面にマチができるようにプラスチックフィルムを折り曲げて重ね合わせ、両側縁部及び上縁部をヒートシールして側縁シール部11及び上縁シール部12を形成したスタンディングパウチからなる平袋状のレトルトパウチであり、パウチ10の片面の上縁シール部12の近傍には、ジッパー部13が設けられている。   As shown in FIG. 1, the pouch 10 is formed by folding and overlapping a plastic film so that a gusset is formed on the bottom surface, and heat-sealing both side edges and upper edges to form side edge seal parts 11 and upper edge seal parts 12. A flat bag-shaped retort pouch made of a standing pouch is formed. A zipper portion 13 is provided in the vicinity of the upper edge seal portion 12 on one side of the pouch 10.

ジッパー部13の外方もヒートシールされてジッパーシール部14が形成されており、このジッパーシール部14近傍の側縁シール部11において、ジッパー部13より上の部分に、引き裂きによりジッパーシール部14を切除し、ジッパー部13を開口可能とするためのノッチ15が形成されている。このようにジッパーシール部14をジッパー部13の外方に設けることにより、レトルト処理の間にジッパー部13が開口することなく、密封状態を維持することが可能となる。   The outside of the zipper part 13 is also heat-sealed to form a zipper seal part 14. In the side edge seal part 11 in the vicinity of the zipper seal part 14, the zipper seal part 14 is formed by tearing the part above the zipper part 13. A notch 15 is formed so that the zipper portion 13 can be opened. By providing the zipper seal portion 14 outside the zipper portion 13 in this manner, the sealed state can be maintained without opening the zipper portion 13 during the retort process.

また、側縁シール部11において、ジッパー部13と上縁シール部12との間には、料理の取出用開口部を引き裂きにより形成するためのノッチ16が形成されている。後述するように、このノッチ16から、電子レンジ加熱調理後のパウチ10を開封し、内容物を一気に皿に移すことにより内容物が撹拌されるので、料理の加熱ムラを容易に解消することが可能となる。   Further, in the side edge seal portion 11, a notch 16 is formed between the zipper portion 13 and the upper edge seal portion 12 for forming an opening for taking out food by tearing. As will be described later, since the contents are stirred from the notch 16 by opening the pouch 10 after cooking by heating in a microwave oven and transferring the contents to the dish at once, it is possible to easily eliminate cooking unevenness of cooking. It becomes possible.

また、パウチ10の表面には、電子レンジ加熱調理時にパウチ10が過度に膨張して破裂することを防止する蒸気抜き機構17が設けられている。蒸気抜き機構17としては、従来より電子レンジ対応包装袋で使用されているものを設けることができ、例えば、側縁シール部11の近傍に、弱化シール部18を設け、その弱化シール部18内に切欠19を形成したものとする。また、パウチ10の蒸気抜き機構17としては、密封されていたジッパー部13が電子レンジ加熱時にパウチ10が膨張する際の圧力で部分的に開口するようにジッパー部の嵌合を調整してもよい。   Moreover, the surface of the pouch 10 is provided with a steam release mechanism 17 that prevents the pouch 10 from excessively expanding and rupturing during microwave cooking. As the steam release mechanism 17, those conventionally used in microwave-compatible packaging bags can be provided. For example, a weakened seal portion 18 is provided in the vicinity of the side edge seal portion 11, and the weakened seal portion 18 It is assumed that a notch 19 is formed in the. Further, the steam venting mechanism 17 of the pouch 10 may be adjusted by fitting the zipper part so that the sealed zipper part 13 is partially opened by the pressure when the pouch 10 expands during microwave heating. Good.

また、本発明の電子レンジ調理用パウチ詰め食品1には、電子レンジ加熱調理で最終的に得ようとする料理の種類、電子レンジ加熱の際にパウチ内に投入することが予定されている具材の種類、その具材の好ましい切り方、大きさ、投入量、パウチへの投入方法、電子レンジ加熱する際のパウチの姿勢、電子レンジ加熱に必要なワット数と時間、電子レンジ加熱後のパウチの開封方法などの説明表示40を備えることが好ましい。特に、説明表示40の具体的な内容として、具材の投入量、大きさ、電子レンジ加熱のワット数と時間については、これらが電子レンジ加熱後の調理の出来の善し悪しに大きく影響するため、できるだけ表示することが望まれる。   Moreover, in the pouched food 1 for cooking a microwave oven according to the present invention, the type of dish to be finally obtained by cooking in a microwave oven and the ingredients that are planned to be put into the pouch when heating the microwave oven. Kind of material, preferred cutting method of the material, size, input amount, input method to pouch, posture of pouch when heating microwave oven, wattage and time required for microwave heating, after heating microwave oven It is preferable to provide an explanation display 40 such as a pouch opening method. In particular, as the specific contents of the explanation display 40, the amount of ingredients, the size, the wattage and time of microwave heating, because these greatly affect the quality of cooking after microwave heating, It is desirable to display as much as possible.

このような説明表示40は、図1に示したように、パウチ10の表面に印刷することにより形成してもよく、電子レンジ調理用パウチ詰め食品1の梱包箱等の外装材に印刷することにより形成してもよく、パウチ10とは別個の紙片に印刷し、その紙片を電子レンジ調理用パウチ詰食品1に添付するようにしてもよい。   Such an explanation display 40 may be formed by printing on the surface of the pouch 10 as shown in FIG. 1, and printed on an exterior material such as a packing box of the pouched food 1 for microwave cooking. It may be formed by printing on a piece of paper separate from the pouch 10, and the piece of paper may be attached to the pouched food 1 for microwave cooking.

本発明の電子レンジ調理用パウチ詰め食品1の製造方法としては、例えば、上縁シール部12が未シール状態のパウチ10を用意し、それに調味液30を充填して、上縁シール部12をヒートシールし、レトルト処理を施すことが挙げられる。   As a manufacturing method of the pouch stuffing food 1 for microwave oven cooking of this invention, for example, the upper edge seal part 12 prepares the pouch 10 in an unsealed state, is filled with the seasoning liquid 30, and the upper edge seal part 12 is used. Heat sealing and performing a retort process are mentioned.

次に、本発明の電子レンジ調理用パウチ詰め食品を使用して調味液煮料理を調理又は製造する方法を説明する。この方法は、電子レンジ調理用容器詰め食品のジッパー部を開封し、そこから具材をパウチ内に投入し、ジッパー部を閉じ、電子レンジで加熱調理することを特徴とする。また、この調理又は製造方法は、観点を変えれば電子レンジ調理用パウチ詰め食品の使用方法という意義を有する。   Next, a method for cooking or manufacturing a seasoned boiled dish using the pouch-stuffed food for microwave oven cooking of the present invention will be described. This method is characterized in that the zipper portion of the microwave-packed container-packed food is opened, and then the ingredients are put into the pouch, the zipper portion is closed, and cooking is performed in the microwave oven. Moreover, this cooking or manufacturing method has the meaning of using the pouched food for microwave oven cooking from a different viewpoint.

まず、パウチ内に投入する具材を電子レンジ調理用パウチ詰め食品1に付された説明表示40を参照して選択し、説明表示40の内容に沿って必要に応じてパウチ10への投入サイズにカットする。   First, the ingredients to be put into the pouch are selected with reference to the explanation display 40 attached to the microwave cooking pouch-stuffed food 1, and the size to be put into the pouch 10 according to the contents of the explanation display 40 as required. Cut into.

次に、図2に示すように、電子レンジ調理用パウチ詰め食品1のジッパー部13外方のノッチ15からパウチ10を引き裂いてジッパーシール部14を切除した後、ジッパー部13を開封し、そこから具材20を矢印のようにパウチ10内に投入する。この場合、具材20の洗浄水などが具材20に付着してパウチ10内に入るのは別として、具材20とは別に、味の調整などの目的でパウチ10内に水を加えてもよいが、原則として避けた方が無難である。水を加えると、ほとんどの場合、合パウチ10内で具材20が接するレトルト調味液30の濃度にバラツキが生じ、電子レンジ加熱調理後の具材20の味付けにもバラツキが生じるからである。なお、具材20の投入時に、必要に応じてパウチ10内にあく取りシートを投入してもよい。   Next, as shown in FIG. 2, after tearing the pouch 10 from the notch 15 outside the zipper part 13 of the pouch stuffed food 1 for microwave cooking, the zipper seal part 14 is excised, and then the zipper part 13 is opened. The ingredients 20 are put into the pouch 10 as shown by arrows. In this case, apart from the fact that the cleaning water of the ingredient 20 adheres to the ingredient 20 and enters the pouch 10, water is added to the pouch 10 for the purpose of adjusting the taste separately from the ingredient 20. However, in principle it is safer to avoid it. This is because when water is added, in most cases, the concentration of the retort seasoning liquid 30 with which the ingredient 20 comes into contact in the joint pouch 10 will vary, and the ingredient 20 will also vary in the seasoning after microwave cooking. It should be noted that a cutting sheet may be inserted into the pouch 10 as necessary when the ingredient 20 is introduced.

次に、ジッパー部13を閉じた後、蒸気抜き機構17から内容物がこぼれ難いように蒸気抜き機構17が上部にくるようにパウチ10を電子レンジ内に寝かせ、あるいは立て、その状態で所定のワット数と時間で電子レンジ加熱調理を行う。加熱調理の具体的条件としては、パウチ10に充填されているレトルト調味液30及び投入した具材20の合計100gあたり、好ましくは600W×3分相当以上の電子レンジ加熱条件が挙げられる。   Next, after closing the zipper portion 13, the pouch 10 is laid in the microwave oven or stood so that the contents of the steam venting mechanism 17 are at the top so that the contents are not easily spilled from the steam venting mechanism 17. Microwave cooking is done in wattage and time. Specific conditions for cooking by heating include microwave heating conditions preferably equivalent to 600 W × 3 minutes or more per 100 g of the total amount of the retort seasoning liquid 30 filled in the pouch 10 and the added ingredients 20.

電子レンジ加熱調理により直接的にレトルト調味液30と具材20が加熱されるのに加え、ジッパー部が閉じられていることから、発生した蒸気によってもレトルト調味液30と具材20とがいわゆる蒸らし効果により加熱される。発生した蒸気は、蒸気抜き機構17から排出されるため、パウチ10は膨張しても、その破裂は防止される。これにより、パウチ10内に充填されていたレトルト調味液30と、それに浸漬していた及び浸漬していない具材20とがそれぞれ適度に加熱調理され、見た目も味も美味しい料理を作ることができる。そして、加熱調理後は、直ちに上縁シール部12近傍のノッチ16からパウチ10の上端部を引き裂いて開口し、パウチ10の料理を一気に大皿にあけて、レトルト調味液30に、それに浸漬していない具材20を絡め混合すればよい。また、パウチ10内では料理に加熱ムラがあっても、パウチ10内の料理を大皿にあけることにより、料理が撹拌され、温度の均一化が図られる。また、加熱調理後のパウチ10は大変熱くなっていて、ジッパー部13を手で開封する作業を行うことが困難であるが、このようにノッチ16からパウチ10の上端部を引き裂いて料理を取り出すと開封作業を安全に行うことができる。   In addition to heating the retort seasoning liquid 30 and the ingredients 20 directly by microwave cooking, the zipper part is closed, so that the retort seasoning liquid 30 and the ingredients 20 are also so-called by the generated steam. Heated by the steaming effect. Since the generated steam is discharged from the steam venting mechanism 17, even if the pouch 10 expands, its burst is prevented. Thereby, the retort seasoning liquid 30 filled in the pouch 10 and the ingredients 20 that have been immersed and not immersed in the pouch 10 are appropriately heated and cooked, and a dish that looks and tastes delicious can be made. . Then, immediately after cooking, the upper end portion of the pouch 10 is opened by tearing from the notch 16 near the upper edge seal portion 12, and the dish of the pouch 10 is immediately opened on a large plate and immersed in the retort seasoning liquid 30. What is necessary is just to entangle and mix the ingredient 20 which is not. Moreover, even if there is uneven heating in cooking in the pouch 10, the cooking is stirred and the temperature is made uniform by opening the cooking in the pouch 10 on a large plate. In addition, the cooked pouch 10 is very hot and it is difficult to open the zipper portion 13 by hand. In this way, the upper end portion of the pouch 10 is torn from the notch 16 and the dish is taken out. And can be opened safely.

以下に、本発明を実施例にて説明する。実施例において、「%」及び「部」は、特に言及しない限り、それぞれ「質量%」及び「質量部」を意味する。   Hereinafter, the present invention will be described with reference to examples. In Examples, “%” and “part” mean “% by mass” and “part by mass”, respectively, unless otherwise specified.

参考例1(消泡剤組成物の調製と評価)
<乳化物の調製>
以下に説明する各試験において、所定の成分A(乳化剤)、B(乳化剤)及びC(食用油脂)を用い、消泡剤乳化組成物を調製した。得られた消泡剤乳化組成物を用いて試験1〜4を行い、消泡効果の確認と調製後の試験溶液の状態を目視観察した。
Reference Example 1 (Preparation and evaluation of antifoam composition)
<Preparation of emulsion>
In each test described below, an antifoam emulsifying composition was prepared using predetermined components A (emulsifier), B (emulsifier) and C (edible oil and fat). Tests 1 to 4 were performed using the obtained antifoaming agent emulsion composition, and the state of the test solution after confirmation of the antifoaming effect and preparation was visually observed.

<消泡剤乳化組成物の調製>
所定量の乳化剤(成分B)を60質量部のイオン交換水に添加し、加熱溶解して水性乳化剤溶液を得た。それとは別に、所定量の乳化剤(成分A)と食用油脂(成分C)とを混合し、加熱溶解して油性乳化剤溶液を得た。得られた水性乳化剤溶液と油性乳化剤溶液とを混合し、混合物の全量が100質量部となるように、イオン交換水を添加した。得られた混合物を高圧乳化装置により、所定の乳化粒子の平均粒子径が得られる条件にて乳化処理し、消泡剤乳化組成物を調製した。
<Preparation of defoaming agent emulsion composition>
A predetermined amount of the emulsifier (component B) was added to 60 parts by mass of ion-exchanged water and dissolved by heating to obtain an aqueous emulsifier solution. Separately, a predetermined amount of emulsifier (component A) and edible fat (component C) were mixed and dissolved by heating to obtain an oily emulsifier solution. The obtained aqueous emulsifier solution and oily emulsifier solution were mixed, and ion-exchanged water was added so that the total amount of the mixture was 100 parts by mass. The obtained mixture was emulsified with a high-pressure emulsifier under the condition that an average particle diameter of predetermined emulsified particles was obtained, to prepare an antifoaming agent emulsion composition.

得られた乳化組成物の平均粒子径は、レーザー回折式粒度分布計SALD−1100((株)島津製作所製)にて体積換算で得られた粒度分布よりメジアン径を求めた。   The average particle size of the obtained emulsified composition was determined as the median size from the particle size distribution obtained by volume conversion using a laser diffraction particle size distribution analyzer SALD-1100 (manufactured by Shimadzu Corporation).

<消泡効果の確認方法>
100mlメスフラスコに4%脱脂粉乳水溶液69.93質量部に、上記調製方法にて得られた消泡剤乳化組成物0.07質量部を添加し、全体を70質量部とした。この混合物を縦型振とう機にて振とうし、泡立ち量と消泡時間とを測定し、以下の消泡効果基準に従って消泡効果を評価した。また、振とう後の溶液の状態について、目視観察し、以下の溶液評価基準に従って評価した。
<Method for confirming defoaming effect>
0.069 parts by mass of the defoamer emulsion composition obtained by the above preparation method was added to 69.93 parts by mass of a 4% non-fat dry milk aqueous solution in a 100 ml volumetric flask to make the whole 70 parts by mass. The mixture was shaken with a vertical shaker, the amount of foaming and the defoaming time were measured, and the defoaming effect was evaluated according to the following defoaming effect criteria. Further, the state of the solution after shaking was visually observed and evaluated according to the following solution evaluation criteria.

<消泡効果評価基準>
◎ ・・・ 消泡効果高い
○ ・・・ 消泡効果あり
△ ・・・ 消泡効果低い
× ・・・ 消泡効果殆どなし
<Defoaming effect evaluation criteria>
◎ ・ ・ ・ Defoaming effect high ○ ・ ・ ・ Defoaming effect △ ・ ・ ・ Defoaming effect low × ・ ・ ・ Almost no defoaming effect

<溶液の状態評価基準>
◎ ・・・ 状態良好(析出物なし)
○ ・・・ 状態やや良好(少し析出物あり)
△ ・・・ 析出物あり
× ・・・ 析出物多く、油浮きあり
<Solution state evaluation criteria>
◎ ... Good condition (no precipitate)
○ ... Slightly good condition (slight deposits)
△ ... There are precipitates × ... Many precipitates and oil floats

試験1
下記の成分A〜Cを用いて所定の平均粒子径を有する消泡剤乳化組成物を調製し、消泡効果と溶液の状態を評価した。得られた結果を表1に示す。
成分A : ポリグリセリンエルカ酸エステル(HLB 5.0) 20部
成分B : ショ糖ステアリン酸エステル(HLB 16) 2部、酵素分解レシチン0.5部
成分C : 食用油脂(サラダ油) 10部
Test 1
An antifoaming agent emulsion composition having a predetermined average particle diameter was prepared using the following components A to C, and the antifoaming effect and the state of the solution were evaluated. The obtained results are shown in Table 1.
Component A: 20 parts of polyglycerin erucic acid ester (HLB 5.0) Component B: 2 parts of sucrose stearate (HLB 16), 0.5 part of enzymatically decomposed lecithin Component C: 10 parts of edible fat (salad oil)

Figure 0005246439
Figure 0005246439

表1からわかるように、平均粒子径を0.05μmとなるように調製した消泡剤乳化組成物では、消泡効果が不十分であった。また、平均粒子径を0.7μm、1.0μmとした消泡剤乳化組成物では、消泡効果は得られたものの溶液に析出や油浮きが生じ、好ましくない状態となっていた。   As can be seen from Table 1, the antifoaming emulsion composition prepared to have an average particle size of 0.05 μm had an insufficient antifoaming effect. Moreover, in the antifoaming agent emulsion composition having an average particle size of 0.7 μm and 1.0 μm, although the antifoaming effect was obtained, precipitation and oil floating occurred in the solution, which was not preferable.

一方、平均粒子径を0.1〜0.5μmとして調製した消泡剤乳化組成物では、消泡効果、溶液の状態ともに良好な結果が得られ、特に、高い消泡効果が得られた。   On the other hand, in the defoaming agent emulsion composition prepared with an average particle size of 0.1 to 0.5 μm, good results were obtained for both the defoaming effect and the state of the solution, and in particular, a high defoaming effect was obtained.

試験2
表2に記載の成分A〜Cの所定量を組み合わせて消泡剤乳化組成物(乳化粒子の平均粒子径0.1μm)を調製し、消泡効果と溶液の状態を評価した。得られた結果を表2に示す。
Test 2
A predetermined amount of components A to C shown in Table 2 were combined to prepare an antifoaming agent emulsion composition (average particle diameter of emulsified particles 0.1 μm), and the antifoaming effect and the state of the solution were evaluated. The obtained results are shown in Table 2.

Figure 0005246439
Figure 0005246439

表1において使用した乳化剤
<成分A>
*1: モノグリセリンステアリン酸エステル
*2: ショ糖脂肪酸ベヘニン酸エステル
*3: ポリグリセリンエルカ酸エステル
*4: ポリグリセリンオレイン酸エステル
*5: ショ糖脂肪酸ステアリン酸エステル
*6: ショ糖脂肪酸ステアリン酸エステル
<成分B>
*7: ポリグリセリンオレイン酸エステル(HLB16)
*8: 酵素分解レシチン
*9: ショ糖ステアリン酸エステル(HLB16)
Emulsifier used in Table 1 <Component A>
* 1: Monoglycerin stearate * 2: Sucrose fatty acid behenic acid ester * 3: Polyglycerin erucic acid ester * 4: Polyglycerin oleate * 5: Sucrose fatty acid stearate * 6: Sucrose fatty acid stearic acid Esters <Component B>
* 7: Polyglycerin oleate (HLB16)
* 8: Enzymatic degradation lecithin * 9: Sucrose stearate (HLB16)

表2の結果からわかるように、テスト区1〜6においては、HLBが2〜8の親油性乳化剤を使用していないテスト区5及び6で、充分な消泡効果が得られなかった。この結果より、HLBが2〜8の親油性乳化剤を利用することにより、消泡効果と良好な状態の溶液を得られることが明らかとなった。   As can be seen from the results in Table 2, in test groups 1 to 6, in test groups 5 and 6 in which no lipophilic emulsifier having an HLB of 2 to 8 was used, a sufficient defoaming effect was not obtained. From this result, it became clear that a solution having a defoaming effect and a good state can be obtained by using a lipophilic emulsifier having an HLB of 2 to 8.

また、親油性乳化剤のみのテスト区7、親水性乳化剤のみのテスト区8及び食用油脂のみのテスト区9では、いずれも消泡効果、溶液状態の何れかが満足できる結果ではなかった。次いで親水性乳化剤と食用油脂を併用したテスト区10、親油性乳化剤と食用油脂を併用したテスト区11でも充分な効果は得られなかった。   Further, in the test group 7 with only the lipophilic emulsifier, the test group 8 with only the hydrophilic emulsifier, and the test group 9 with only the edible fats and oils, none of the defoaming effect and the solution state was satisfactory. Next, sufficient effects could not be obtained even in test section 10 in which a hydrophilic emulsifier and edible oil and fat were used in combination, and in test section 11 in which a lipophilic emulsifier and edible oil and fat were used in combination.

テスト区7〜11の結果より、親油性乳化剤、親水性乳化剤及び食用油脂のいずれかを単独で使用しただけでは充分な消泡効果、良好な溶液状態を得ることができず、親油性乳化剤または親水性乳化剤のいずれかと食用油脂の組み合わせでも良好な結果は得られなかった。   From the results of the test groups 7 to 11, it was not possible to obtain a sufficient defoaming effect and a good solution state by using any one of lipophilic emulsifier, hydrophilic emulsifier and edible oil and fat. Even when any of the hydrophilic emulsifiers and edible fats and oils were combined, good results were not obtained.

また、親油性乳化剤、親水性乳化剤、食用油脂を併用したテスト区13では、充分な効果が得られることが確認できた。   In addition, it was confirmed that a sufficient effect was obtained in the test section 13 in which a lipophilic emulsifier, a hydrophilic emulsifier, and an edible fat / oil were used in combination.

さらにテスト区14〜17では、親水性乳化剤がレシチン、ショ糖脂肪酸エステルそれぞれ単独で使用した場合の効果と、ポリグリセリン脂肪酸エステルを含む併用の場合でも、充分な効果が得られることが明らかとなった。   Furthermore, in the test groups 14 to 17, it is clear that sufficient effects can be obtained even when the hydrophilic emulsifier is used alone for each of lecithin and sucrose fatty acid ester and in the case of the combined use including polyglycerin fatty acid ester. It was.

試験3
表3に記載の成分A〜Cの所定量を組み合わせて消泡剤乳化組成物(乳化粒子の平均粒子径0.1μm)を調製し、本試験では乳化剤Bの添加量を変化させた場合の消泡効果と溶液の状態を評価した。なお、成分A〜Cは、試験例2テスト区16と同じものを使用した。得られた結果を表3に示す。
Test 3
An antifoam emulsifying composition (average particle diameter of emulsified particles 0.1 μm) was prepared by combining predetermined amounts of components A to C shown in Table 3, and in this test, the amount of emulsifier B added was changed. The defoaming effect and the state of the solution were evaluated. In addition, the component A-C used the same thing as Test Example 2 test section 16. The obtained results are shown in Table 3.

Figure 0005246439
Figure 0005246439

本試験により、親油性乳化剤の添加量1部に対し、親水性乳化剤の添加量を0.02〜0.5部とすることで、消泡効果が充分に発揮され、溶液の状態も良好となることが判明した。   By this test, the amount of hydrophilic emulsifier added is 0.02 to 0.5 parts with respect to 1 part of the lipophilic emulsifier added, so that the defoaming effect is sufficiently exhibited and the state of the solution is also good. Turned out to be.

試験4
試験3と同様に、表4に記載の成分A〜Cの所定量を組み合わせて消泡剤乳化組成物(乳化粒子の平均粒子径0.1μm)を調製し、本試験では食用油脂Cの添加量を変化させた場合の消泡効果と溶液の状態を評価した。なお、成分A〜Cは、試験例2テスト区16と同じものを使用した。得られた結果を表4に示す。
Test 4
Similarly to Test 3, an antifoam emulsifying composition (average particle diameter of emulsified particles 0.1 μm) was prepared by combining predetermined amounts of components A to C described in Table 4, and in this test, edible oil C was added. The defoaming effect and the state of the solution when the amount was changed were evaluated. In addition, the component A-C used the same thing as Test Example 2 test section 16. Table 4 shows the obtained results.

Figure 0005246439
Figure 0005246439

本試験の結果、親油性乳化剤の添加量1部に対し、食用油脂の添加量を0.1〜2部とすることで、消泡効果が充分に発揮されることが判明した。   As a result of this test, it was found that the defoaming effect was sufficiently exhibited by setting the amount of edible oil / fat to 0.1 to 2 parts with respect to 1 part of the lipophilic emulsifier.

参考例2
以下の実施例及び比較例において使用する表5の配合の消泡剤乳化組成物X、Y及びZを、参考例1と同様に調製した。
Reference example 2
Antifoam emulsifying compositions X, Y and Z having the composition shown in Table 5 used in the following Examples and Comparative Examples were prepared in the same manner as in Reference Example 1.

Figure 0005246439
Figure 0005246439

実施例1
<アサリのボンゴレソース煮(蒸し)>
(1)投入する具材
パウチ内に後に加える具材をアサリ150gとした。
Example 1
<Simmered clams with bongole sauce (steamed)>
(1) Ingredients to be added Ingredients to be added later in the pouch were 150 g of clams.

(2)レトルトボンゴレソース、電子レンジ調理用容器詰め液状食品の調製
下記表6に示す配合原料を用意した。次に、二重釜に、大豆油、ニンニクペースト、ニンニクエキス粉末、砂糖、食塩、加工澱粉及び清水を投入し撹拌混合しながら品温90℃になるまで加熱することによりボンゴレソースを調製した。
(2) Preparation of retort bongole sauce, microwave-packed container-packed liquid food The blended raw materials shown in Table 6 below were prepared. Next, soybean oil, garlic paste, garlic extract powder, sugar, salt, processed starch, and fresh water were added to the double kettle and heated until the product temperature reached 90 ° C. with stirring and mixing to prepare a bongole sauce.

続いて、得られたボンゴレソース150gを弱化シール部と切欠とからなる蒸気抜き機構を有する図1のジッパー付きスタンドパウチ(パウチサイズ:縦220mm×横140mm×折込(マチ)40mm、材質:(パウチ)ポリエステル/ポリアミド/無延伸ポリプロピレン、(ジッパー部)ポリプロピレン、最大密封充填可能容量:820mL)に充填密封後、レトルト処理(115℃、20分間)し、パウチ内にレトルトボンゴレソース(200mL)が充填されている電子レンジ調理用容器詰め液状食品を得た。レトルトボンゴレソースの粘度は1Pa・sであった。   Subsequently, the obtained bongo sauce 150g is a stand-up pouch with a zipper of FIG. 1 having a steam venting mechanism composed of a weakened seal portion and a notch (pouch size: length 220 mm × width 140 mm × folding (gusset) 40 mm, material: (pouch) Polyester / Polyamide / Unstretched polypropylene, (Zipper part) Polypropylene, Maximum sealed filling capacity: 820 mL) After filling and sealing, retort treatment (115 ° C., 20 minutes) and retort bongole sauce (200 mL) is filled in the pouch. A microwave-cooked container-packed liquid food was obtained. The viscosity of the retort bongole sauce was 1 Pa · s.

Figure 0005246439
Figure 0005246439

(3)電子レンジによる加熱調理
前述の(2)の電子レンジ調理用容器詰め液状食品のジッパーを開封し、(1)のアサリ150gを入れ、再度ジッパーを閉じた。次に、電子レンジ内にアサリ投入後の電子レンジ調理用容器詰め液状食品を蒸気抜き機構が上面になるように平置きした。これを電子レンジで加熱調理(600W×6分間)をし、料理の取出用のノッチから開封してこれを大皿にあけた。電子レンジ加熱中の液状食品は、沸騰しても容器からふきこぼれが発生しなかった。
(3) Cooking with a microwave oven The zipper of the above-mentioned (2) microwave cooking container-packed liquid food was opened, 150 g of clams (1) were added, and the zipper was closed again. Next, the container-packed liquid food for cooking the microwave oven after placing the clams in the microwave oven was placed flat so that the steam release mechanism was on the upper surface. This was cooked in a microwave oven (600 W × 6 minutes), opened from the notch for taking out the dish, and opened on a large plate. The liquid food during microwave heating did not spill out of the container even when it boiled.

なお、消泡剤乳化組成物を配合していない対照品についても同様に電子レンジで加熱調理したところ容器からふきこぼれが発生した。   In addition, about the control | contrast goods which are not mix | blended with an antifoamer emulsion composition, when it cooked similarly with the microwave oven, the spilling generate | occur | produced from the container.

実施例2
<ブロッコリーのクリーム煮>
(1)加える具材
パウチ内に後に加える具材を一口大(約3cm角)にカットしたブロッコリー約100gとした。
Example 2
<Simmered broccoli in cream>
(1) Ingredients to be added Ingredients to be added later in the pouch were about 100 g of broccoli cut into bite-sized pieces (about 3 cm square).

(2)クリームソース
表7に示す配合原料を用意した。まず、カゼインナトリウム、卵黄リゾレシチン、キサンタンガム、脱脂粉乳、加工澱粉、食塩及び香辛料を粉体混合した。次に、ミキサーにこの粉体混合物及び清水を投入して撹拌混合した後、菜種油を徐々に加えながら更に撹拌混合した。続いて、加熱した二重釜に、得られた混合液を加えて撹拌しながら品温90℃になるまで加熱することによりクリームソースを得た。
(2) Cream sauce The raw materials shown in Table 7 were prepared. First, casein sodium, egg yolk lysolecithin, xanthan gum, skim milk powder, processed starch, salt and spices were powder mixed. Next, the powder mixture and fresh water were added to a mixer and mixed with stirring, and then further mixed with stirring while gradually adding rapeseed oil. Subsequently, a cream sauce was obtained by adding the obtained liquid mixture to a heated double kettle and heating it to 90 ° C. with stirring.

(3)電子レンジ調理用容器詰め食品(レトルトクリームソース入り)
次に、得られたクリームソース200gを弱化シール部と切欠とからなる蒸気抜き機構を有するジッパー付きスタンドパウチ(実施例1と同じ)に充填密封後、レトルト処理(115℃、15分間)し、パウチ内にレトルトクリームソース(200mL)が充填されている電子レンジ調理用容器詰め食品を得た。また、レトルトクリームソースの粘度は2Pa・sであった。
(3) Packaged food for microwave oven cooking (with retort cream sauce)
Next, 200 g of the obtained cream sauce was filled and sealed in a stand pouch with a zipper (same as in Example 1) having a vapor venting mechanism consisting of a weakened seal part and a notch, and then retorted (115 ° C., 15 minutes), The container food for microwave cooking with which the retort cream sauce (200 mL) was filled in the pouch was obtained. The viscosity of the retort cream sauce was 2 Pa · s.

Figure 0005246439
Figure 0005246439

(4)電子レンジによる加熱調理
(3)の電子レンジ調理用容器詰め食品のジッパーを開封し、(1)のブロッコリー100gを入れ、再度ジッパーを閉じた。次に、電子レンジ内にブロッコリー投入後の電子レンジ調理用容器詰め液状食品を蒸気抜き機構が上面になるように平置きした。これを電子レンジで加熱調理(600W×4分間)をし、料理の取出用のノッチから開封してこれを大皿にあけた。電子レンジ加熱中の液状食品は、沸騰しても容器からふきこぼれが発生しなかった。
(4) Heat cooking by microwave oven The zipper of the microwaveable cooking container-packed food of (3) was opened, 100 g of broccoli of (1) was added, and the zipper was closed again. Next, the container-packed liquid food for cooking the microwave oven after the broccoli was put in the microwave oven was placed flat so that the steam release mechanism was on the upper surface. This was cooked in a microwave oven (600 W × 4 minutes), opened from the notch for taking out the dish, and opened on a large plate. The liquid food during microwave heating did not spill out of the container even when it boiled.

なお、消泡剤を配合していない対照品についても同様に電子レンジで加熱調理したところ容器からふきこぼれが発生した。   In addition, when the control product which did not contain the antifoaming agent was also cooked in a microwave oven, spilling occurred from the container.

実施例3
<タラのみぞれ煮>
(1)投入する具材
パウチ内に後に加える具材をタラ(厚みが2cmの切り身2切れ)200gとした。
Example 3
<Simmered cod>
(1) Ingredients to be added The ingredients to be added later in the pouch were 200 g of cod (2 slices of 2 cm thick).

(2)みぞれ煮調味液、電子レンジ調理用容器詰め液状食品 (2) Simmered seasoning liquid, container-packed liquid food for microwave oven cooking

表8に示す配合原料を用意した。ここで、大根おろしは大根を5mm目のチョッパーで粉砕処理することにより調製した。次に、二重釜に、大根おろし、醤油、かつおだし、食塩、加工澱粉及び清水を投入し撹拌混合しながら品温90℃になるまで加熱することによりみぞれ煮調味液を調製した。   The raw materials shown in Table 8 were prepared. Here, the radish grated was prepared by pulverizing the radish with a 5 mm chopper. Next, daikon boiled seasoning liquid was prepared by adding daikon grated radish, soy sauce, bonito, salt, processed starch and fresh water to a double kettle and heating them to 90 ° C. with stirring and mixing.

続いて、得られたみぞれ煮調味液200gを弱化シール部と切欠とからなる蒸気抜き機構を有するジッパー付きスタンドパウチ(実施例1と同じ)に充填密封後、レトルト処理(115℃、20分間)し、パウチ内にレトルトみぞれ煮調味液(200mL)が充填されている電子レンジ調理用容器詰め液状食品を得た。レトルトみぞれ煮調味液の粘度(品温60℃)は0.3Pa・sであった。   Subsequently, 200 g of the obtained simmered seasoning liquid was filled and sealed in a zippered stand pouch (same as Example 1) having a steam venting mechanism consisting of a weakened seal part and a notch, followed by retort treatment (115 ° C., 20 minutes) And the container-packed liquid food for microwave ovens with which the retort simmered seasoning liquid (200 mL) was filled in the pouch was obtained. The viscosity (article temperature 60 ° C.) of the retort simmered seasoning liquid was 0.3 Pa · s.

Figure 0005246439
Figure 0005246439

(3)電子レンジによる加熱調理 (3) Cooking with a microwave oven

(2)の電子レンジ調理用容器詰め液状食品のジッパーを開封し、(1)のタラ200gを入れ、再度ジッパーを閉じた。次に、電子レンジ内にタラ投入後の電子レンジ調理用容器詰め液状食品を蒸気抜き機構が上面になるように平置きした。これを電子レンジで加熱調理(600W×6分間)をし、料理の取出用のノッチから開封してこれを大皿にあけた。電子レンジ加熱中の液状食品は、沸騰しても容器からふきこぼれが発生しなかった。   The zipper of the container-packed liquid food for microwave oven cooking in (2) was opened, 200 g of cod in (1) was added, and the zipper was closed again. Next, the container-packed liquid food for microwave oven cooking after the cod was put in the microwave oven was placed flat so that the steam release mechanism was on the upper surface. This was cooked in a microwave oven (600 W × 6 minutes), opened from the notch for taking out the dish, and opened on a large plate. The liquid food during microwave heating did not spill out of the container even when it boiled.

なお、消泡剤乳化組成物を配合していない対照品についても同様に電子レンジで加熱調理したところ容器からふきこぼれが発生した。   In addition, about the control | contrast goods which are not mix | blended with an antifoamer emulsion composition, when it cooked similarly with the microwave oven, the spilling generate | occur | produced from the container.

<泡立ちとふきこぼれの試験評価>
消泡剤乳化組成物の組成の、クリーム煮における泡立ちとふきこぼれに与える影響を調べるために以下の試験を行った。即ち、実施例2において、消泡剤乳化組成物Xに代えて消泡剤乳化組成物Y、Z、シリコーン又は消泡剤乳化組成物Xに代えて清水を使用すること以外は、実施例2と同様に電子レンジ調理用容器詰め液状食品を調製し、同様にブロッコリーのクリーム煮を電子レンジ加熱により調理し、泡立ちとふきこぼれの有無を以下の基準に従って評価した。得られた結果を表9に示す。
<Test evaluation of foaming and spilling>
In order to investigate the influence of the composition of the defoamer emulsifying composition on foaming and spilling during cream cooking, the following tests were conducted. That is, in Example 2, it replaces with the antifoamer emulsion composition X, and it replaces with the antifoamer emulsion composition Y, Z, silicone, or replaces with the antifoamer emulsion composition X, and Example 2 uses it. In the same manner as above, a liquid food packaged in a container for microwave cooking was prepared. Similarly, broccoli cream was cooked by heating in a microwave oven, and the presence or absence of foaming and spilling was evaluated according to the following criteria. Table 9 shows the obtained results.

<泡立ち>
◎: 沸騰しているが、液面上に泡が沸き上がっていない。
○: 沸騰して液面上に泡が沸きあがっており、泡が沸きあがっている高さは、液面から20mm以下である。
△: 沸騰して液面上に泡が沸きあがっており、泡が沸きあがっている高さは、液面から20mmを超える高さである。
<Bubbling>
A: Boiling but no bubbles are boiling on the liquid surface.
○: Boiled and bubbles boiled on the liquid surface, and the height at which the bubbles boiled is 20 mm or less from the liquid surface.
(Triangle | delta): It boiled and the bubble boiled on the liquid level, and the height which the bubble boiled is a height exceeding 20 mm from a liquid level.

<ふきこぼれ>
有: 容器から泡がふきあがり、蒸気口から下にソースがこぼれる状態
無: 容器の蒸気口から下にソースがこぼれていない状態
<Blowout>
Existence: Bubbles are blowing from the container and the source spills down from the steam outlet. None: Source is not spilled from the container's steam outlet.

Figure 0005246439
Figure 0005246439

本発明の電子レンジ用液状物含有食品は、油性乳化剤溶液が水性乳化剤溶液中で乳化粒子として分散してなる消泡剤乳化組成物を含有しているので、従来の消泡剤組成物を使用せずとも、電子レンジ加熱による噴きこぼれが抑制又は防止されたものとなっている。従って、電子レンジ調理に非常に有用である。   The liquid-containing food for microwave oven of the present invention contains a defoamer emulsion composition in which an oily emulsifier solution is dispersed as emulsified particles in an aqueous emulsifier solution. Therefore, the conventional antifoam composition is used. Even if it does not, the spill from the microwave oven heating is suppressed or prevented. Therefore, it is very useful for microwave oven cooking.

1 電子レンジ調理用パウチ詰め食品
10 パウチ
11 側縁シール部
12 上縁シール部
13 ジッパー部
14 ジッパーシール部
15 ノッチ
16 ノッチ
17 蒸気抜き機構
18 弱化シール部
19 切欠
20 具材
30 (レトルト)調味液
40 説明表示
DESCRIPTION OF SYMBOLS 1 Pouch filling food for microwave oven 10 Pouch 11 Side edge seal part 12 Upper edge seal part 13 Zipper part 14 Zipper seal part 15 Notch 16 Notch 17 Steam release mechanism 18 Weak seal part 19 Notch 20 Ingredient 30 (Retort) seasoning liquid 40 Explanation display

Claims (6)

食用油脂が親油性乳化剤と親水性乳化剤とで乳化されてなる消泡剤乳化組成物を含有する電子レンジ加熱用液状物含有食品であって、
親油性乳化剤が、HLB2〜8の乳化剤であり、
親水性乳化剤が、HLB10以上のポリグリセリン脂肪酸エステル、HLB10以上のショ糖脂肪酸エステル、及びレシチンから選ばれる少なくとも1種であり、
消泡剤乳化組成物の乳化粒子が0.1〜0.5μmの平均粒子径を有することを特徴とする電子レンジ加熱用液状物含有食品。
A liquid-containing food for microwave heating containing an antifoam emulsifying composition in which an edible fat is emulsified with a lipophilic emulsifier and a hydrophilic emulsifier,
The lipophilic emulsifier is an emulsifier of HLB 2-8,
The hydrophilic emulsifier is at least one selected from polyglycerin fatty acid ester of HLB10 or higher, sucrose fatty acid ester of HLB10 or higher, and lecithin,
A liquid-containing food for microwave heating, wherein the emulsified particles of the defoamer emulsion composition have an average particle size of 0.1 to 0.5 µm.
消泡剤乳化組成物が、親油性乳化剤1質量部に対し、親水性乳化剤を0.02〜0.5質量部、食用油脂を0.1〜2質量部の割合で含有する請求項1記載の電子レンジ加熱用液状物含有食品。   The antifoam emulsifying composition contains 0.02 to 0.5 parts by mass of a hydrophilic emulsifier and 0.1 to 2 parts by mass of edible fat / oil with respect to 1 part by mass of a lipophilic emulsifier. Liquid food for microwave oven heating. 請求項1又は2記載の電子レンジ加熱用液状物含有食品が、電子レンジ加熱用容器に充填されていることを特徴とする電子レンジ加熱用容器詰め食品。 A microwave-heated container-packed food, wherein the microwave-heating liquid-containing food according to claim 1 or 2 is filled in a microwave-heated container. 電子レンジ加熱に必要なワット数と時間の説明表示を備えている請求項記載の電子レンジ加熱用容器詰め食品。 The container-packed food for microwave heating according to claim 3, which is provided with an explanation display of the wattage and time required for microwave heating. 請求項1又は2記載の電子レンジ加熱用液状物含有食品を、電子レンジで加熱することを特徴とする加熱食品の製造方法。 A method for producing a heated food, comprising heating the liquid-containing food for heating a microwave oven according to claim 1 or 2 using a microwave oven. 請求項3又は4記載の電子レンジ加熱用容器詰め食品の容器内に具材を投入し、電子レンジで加熱することを特徴とする加熱食品の製造方法。 A method for producing a heated food, wherein the ingredients are put into a container for food in a microwave heating container according to claim 3 and heated in a microwave oven.
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