JP5228408B2 - Method for manufacturing ink jet recording head - Google Patents

Description

The present invention relates to a method for manufacturing an ink jet recording head.

  Using ultraviolet curable ink, the ultraviolet curable ink is fixed on the recording medium by irradiating the ultraviolet curable ink discharged onto the recording medium from the ink jet recording head (hereinafter sometimes referred to as a recording head). An ultraviolet curable ink jet recording apparatus is known.

Patent Document 1 discloses a recording head having a nozzle top plate on which an ejection port for discharging ink that is cured by irradiation of ultraviolet rays to a recording medium and a protective top plate for protecting the nozzle top plate, and a recording head. An ultraviolet irradiation device that irradiates the ink ejected onto the recording medium with ultraviolet rays, and at least one of the surface of the nozzle top plate and the surface of the protective top plate is provided with a black colored treatment layer on the substrate. In addition, there is described an ultraviolet curable ink jet recording apparatus provided thereon with an inorganic ultraviolet absorbent coating layer and a water repellent treatment layer.
JP-A-2005-47261

  In Patent Document 1, since the water-repellent treatment layer is formed as the uppermost layer, the light leaked from the ultraviolet irradiation device may reach the water-repellent treatment layer of the recording head.

  It has been found that the leakage light to the water-repellent treatment layer causes unevenness in the water-repellent treatment on the ink ejection surface and tends to lower the ink ejection stability. This is presumed to be because ultraviolet rays promote the decomposition reaction of the fluororesin or the like constituting the water-repellent treatment layer and lower the adhesion to the substrate.

  On the other hand, if a water-repellent treatment layer is provided in the lower layer in order to reduce the light leaked to the water-repellent treatment layer, the feature of the water-repellent treatment on the ink ejection surface cannot be utilized, and the ink ejection stability eventually decreases.

  Patent Document 1 discloses that an inorganic ultraviolet absorbent coating layer is formed by applying a coating agent obtained by mixing an inorganic ultraviolet absorbent that forms an inorganic ultraviolet absorbent coating layer to a water repellent treatment liquid that forms a water repellent treatment layer. It is also described that the water repellent treatment layer may be formed as a single layer.

  However, since the inorganic ultraviolet absorbent is in the form of particles, it is difficult to uniformly disperse it throughout the water-repellent treatment layer, and a water-repellent treatment layer having sufficient ultraviolet-absorbing performance cannot be obtained and adhesion to the substrate is reduced. There is a problem.

The present invention has been made in view of the above problems, and an object of the present invention is to provide an ink jet recording head manufacturing method capable of reducing deterioration due to ultraviolet light of an ink repellent layer containing a fluororesin. Yes.

The object of the present invention is achieved by the following invention.
1.
A coating liquid containing an aqueous dispersion of a fluororesin, a water-soluble polyamideimide resin, and an inorganic ultraviolet absorber having a concentration of 5% by mass or less (excluding 0%) with respect to the fluororesin is at least an ink. An ink jet recording head manufacturing method comprising forming an ink repellent layer by applying to an ejection surface.
2.
2. The method for producing an ink jet recording head according to 1, wherein the inorganic ultraviolet absorber is cerium oxide.
3.
3. The method of manufacturing an ink jet recording head according to 1 or 2, wherein the ink discharge surface is formed on a nozzle forming member.
4).
The ink jet recording head according to 1, 2 or 3, wherein the ink jet recording head is an ink jet recording head used in an ink jet recording apparatus that irradiates ultraviolet curable ink discharged from the ink jet recording head with ultraviolet rays. Production method.

  According to the present invention, it is possible to reduce deterioration due to ultraviolet light of an ink repellent layer containing a fluororesin, and it is possible to prevent a decrease in ink ejection stability.

  Hereinafter, the present invention will be described with reference to embodiments, but the present invention is not limited to the embodiments.

  The ink repellent layer of the present invention contains a fluororesin, a thermoplastic resin, and an ultraviolet absorber.

  Examples of fluororesins include polytetrafluoroethylene (PTFE), tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (PFA), tetrafluoroethylene-hexafluoropropylene copolymer (FEP), and tetrafluoroethylene-ethylene copolymer. (ETFE), polychlorotrifluoroethylene (PCTFE), polyvinylidene fluoride (PVDF), and the like can be used, but FEP has a low critical surface tension, excellent ink repellency, and a heat treatment temperature of 300. C. to 400.degree. C. is preferable because the melt viscosity is low and a uniform film can be formed.

  As the ultraviolet absorber, an inorganic ultraviolet absorber is preferably used. Since this inorganic ultraviolet absorber has a higher melting point than organic ultraviolet absorbers, there is no volatilization or deterioration due to heat. For example, after forming an ink repellent film, heat treatment at a high temperature (for example, 300 ° C. to 400 ° C.) is applied. In addition, the ultraviolet absorbing ability can be maintained without being decomposed.

  Examples of the inorganic ultraviolet absorber include titanium oxide (melting point 1640 ° C.), cerium oxide (melting point 1950 ° C.), zinc oxide (melting point 1975 ° C.), tin oxide (melting point 1080 ° C.), iron oxide (melting point 1360 ° C.). ), Etc., and particularly preferred is cerium oxide. Since cerium oxide has a high ultraviolet absorbing ability, an effect of preventing the deterioration of the ink repellent layer can be obtained at a lower concentration. As a cerium oxide ultraviolet absorber, for example, Nidral P-10 manufactured by Taki Chemical Co., Ltd. can be used.

  The concentration of the inorganic ultraviolet absorber is preferably 5% by mass or less with respect to the fluororesin. If it exceeds 5% by mass, the concentration of the thermoplastic resin for improving the adhesion to the substrate will decrease, resulting in a decrease in the adhesion to the substrate and an increase in the concentration of the UV absorber that is not ink-repellent. Ink repellency may decrease due to a decrease in the concentration of the fluororesin.

  In the present invention, a thermoplastic resin is used as a substance that improves the adhesion of the ink repellent layer to the substrate and improves the dispersibility of the inorganic ultraviolet absorber.

  Examples of the thermoplastic resin include polyethylene, polypropylene, polyvinyl acetate, polyvinyl alcohol, polyvinyl acetal, poly (meth) acrylic acid copolymer, poly (meth) acrylic acid ester, polyacrylic acid derivative, and polyacrylic acid. Amide, polyether, polyester, polycarbonate, cellulosic resin, polyacrylonitrile, polyimide, polyamide (nylon), polyamideimide, polyvinyl chloride, polyvinylidene chloride, polystyrene, thiocol, polysulfone, polyurethane, polystyrene, and other resins Monomer copolymer, etc. can be used. Polyamideimide resin has excellent adhesion to the substrate and improves the adhesion of the ink-repellent layer to the substrate, and dispersibility of the inorganic ultraviolet absorber. Improve It has excellent results, preferred from the viewpoint capable of uniform film formation.

  As the method for forming the ink repellent layer, coating is preferable, and as the coating method, spray coating, spin coating, brush coating, dip coating, wire bar coating, or the like can be used.

  Use of a water-based coating liquid is preferable because it has advantages in terms of environment, safety, and economy.

  Usually, since a polyamide-imide resin does not dissolve in water, it is more preferable to use a water-soluble polyamide-imide resin. The water-soluble polyamideimide resin is represented by the following general formula 1.

  In the formula, A and B are organic groups.

  A water-soluble polyamideimide resin can be obtained by mixing and stirring the polyamideimide resin in a basic polar solution with a basic compound such as an amine compound and gradually adding water. Further, HPC-1000 manufactured by Hitachi Chemical Co., Ltd. may be used.

  It is a preferred embodiment to form an ink repellent layer by applying a coating liquid containing an aqueous dispersion of a fluororesin, a water-soluble polyamideimide resin, and an inorganic ultraviolet absorber to a substrate.

  After coating and drying, heat treatment is preferably performed to improve the ink repellency of the coating layer. As processing temperature, 300 to 400 degreeC is preferable.

  In addition, in order to improve the wettability with respect to the coating liquid of the nozzle formation member which is a base material, the base-material surface can also be activated prior to application | coating.

  As the activation treatment, plasma treatment, corona treatment, ozone treatment, UV treatment, excimer laser treatment, or the like is used.

  1 and 2 are views showing an example of an ink jet recording head. FIG. 1 is a schematic perspective view, and FIG. 2 is a cross-sectional view. In the figure, 1 is an ink jet recording head, 11 is an ink tube, 12 is a nozzle forming member (nozzle plate), 13 is a nozzle, 14 is a cover plate, 15 is an ink supply port, 16 is a substrate, and 17 is a partition. An ink channel 18 is formed by the partition wall 17, the cover plate 14, and the substrate 16.

  The ink jet recording head 1 includes an ink channel separated between a cover plate 14 and a substrate 16 by a plurality of partition walls 17 (only a part of which is shown) made of a piezoelectric material such as PZT which is an electromechanical conversion means. 18 (only a part of which is shown) is a shear mode (shear mode) type recording head arranged in parallel.

  As the nozzle forming member 12, for example, ceramic, metal, glass, or resin having high mechanical strength, ink resistance, and excellent dimensional stability can be used. As the glass, for example, quartz, synthetic quartz, high-purity glass or the like may be appropriately selected. Examples of the resin include polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polyimide (PI), polyphenylene sulfide (PPS), and the like. You can choose from as appropriate. The thickness of the nozzle plate 12 is preferably about 50 μm to 500 μm.

  The partition wall 17 is deformed by the drive signal, the volume of the ink channel 18 is changed, the ink is ejected from the nozzle 13, and the ink is allowed to flow into the ink channel 18.

  The ink repellent layer 12 a is formed on the outer surface of the nozzle forming member 12, that is, the ink ejection surface.

  As described above, the ink repellent layer 12a is formed by a conventionally known coating method. However, after the ink repellent layer 22a is formed, a laser beam is irradiated to form the nozzles 23, or An ink repellent layer 12a is formed after nozzle formation.

  The ink jet recording head 1 is formed by forming the ink channel 18 by the partition wall 17 and adhering the nozzle forming member 12 having the nozzle 13 to the front surface of the head main body H.

  FIG. 3 is a schematic diagram showing an example of an ink jet recording apparatus to which the ink jet recording head of the present invention is applied.

  The carriage 21 includes YMCK four-color ink jet recording heads (1Y, 1M, 1C, 1K), an ultraviolet irradiation device 23 provided on both sides of the ink jet recording head, a support frame 24 that supports the ink jet recording head and the ultraviolet irradiation device 23, and the like. And is reciprocally scanned on the recording medium P in the direction of arrow A.

  Each ink jet recording head has a lower surface serving as an ink ejection surface, and is disposed so as to face the recording medium P.

  The ultraviolet irradiation device 23 irradiates the ultraviolet curable ink discharged from the nozzle 13 of each inkjet recording head onto the recording medium P with ultraviolet rays.

  As described above, according to the present embodiment, since ultraviolet light is absorbed by the ultraviolet absorbent contained in the ink repellent layer, deterioration of the ink repellent layer containing the fluororesin due to ultraviolet light can be reduced, and the ink A decrease in ejection stability can be suppressed. In addition, the thermoplastic resin contained in the ink repellent layer provides excellent adhesion between the ink repellent layer and the substrate.

(1) Example 1
An aqueous dispersion of FEP (ND-1 manufactured by Daikin Industries, Ltd.), a water-soluble polyamideimide resin (HPC-1000 manufactured by Hitachi Chemical Co., Ltd.), and an ultraviolet absorber (Nidral manufactured by Taki Chemical Co., Ltd.) P-10) was added to water to prepare a coating solution. In addition, solid content of FEP was 10 mass%, solid content of water-soluble polyamide-imide resin was 6 mass%, and the ultraviolet absorber density | concentration with respect to FEP was 3.8 mass%.
(2) Example 2
A coating solution was prepared in the same manner as in Example 1 except that the ultraviolet absorber concentration with respect to FEP was changed to 0.2% by mass.
(3) Example 3
A coating solution was prepared in the same manner as in Example 1 except that the ultraviolet absorber concentration with respect to FEP was 7.5% by mass.
(4) Comparative Example A coating solution was prepared in the same manner as in Example 1 without adding an ultraviolet absorber.

  The coating liquid prepared in Examples 1 to 3 and Comparative Example was applied to one side of a 75 μm-thick polyimide sheet (Upilex manufactured by Ube Industries, Ltd.) using a wire bar so that the film thickness was about 50 μm.

  After coating and drying, heat treatment was performed at 350 ° C. for 4 hours to form an ink repellent layer on the ink ejection surface.

  Nozzle holes were drilled with an excimer laser in a polyimide sheet having an ink-repellent layer formed on the ink ejection surface by the above treatment, to produce a nozzle plate.

  This nozzle plate was attached to the front surface of the head body to produce an ink jet recording head.

For the ink jet recording head produced by the above processing, after irradiating the ink ejection surface with ultraviolet light, rubbing it 50 times with a nonwoven fabric, the initial value of the receding contact angle and the value after 50 times rubbing are contacted by Kyowa Interface Science Co., Ltd. It was measured with a goniometer CA-X. The irradiation amount of ultraviolet rays was 4500 mJ / cm ² .

  The receding contact angle was measured for UV curable ink. The measurement results are shown in Table 1.

  In an ink jet recording head, wetting with residual ink on the ink discharge surface greatly affects the ink discharge performance and becomes a problem. Therefore, it is important that the receding contact angle is large. Further, since the ink repellent layer is usually rubbed by a rubber blade or a nonwoven fabric, durability is important.

  As shown in Table 1, in Examples 1 to 3 in which the ink repellent layer contains an ultraviolet absorber, the ink repellent with a large receding contact angle after 50 times of ultraviolet irradiation and rubbing is better than in the comparative example not containing the ultraviolet absorber. It can be seen that sex is maintained.

  In particular, in Example 1.2, the decrease in the receding contact angle is small.

  Further, the ink jet recording head prepared by adjusting the coating solution in the same manner as in Example 1 without adding the water-soluble polyamideimide resin was rubbed 50 times with a non-woven fabric without irradiating ultraviolet rays, and the initial value of the receding contact angle was obtained. When the value after 50 times of rubbing was measured, the initial receding contact angle was 40 °, but it decreased to 0 ° after 50 times of rubbing. This is presumably because the adhesion between the ink repellent layer and the substrate was lowered because the water-soluble polyamideimide resin, which is a thermoplastic resin, was not included in the ink repellent layer.

  In addition, using the inkjet recording apparatus described in the above embodiment, an ejection test was performed by continuously ejecting ultraviolet curable ink from an inkjet recording head while irradiating the recording medium with ultraviolet rays using an ultraviolet irradiation apparatus.

  In the ink jet recording heads of Examples 1 to 3, the ink ejection surface maintains high ink repellency even after long-time ink ejection and ultraviolet irradiation, and the ejection stability is stable without adhesion of ink or cured material. It was kept.

  On the other hand, in the ink jet recording head of the comparative example, the ink repellency of the ink ejection surface was lowered, and ink or a cured product adhered to the ink ejection surface, and continuous ejection was not possible.

  As described above, the ink jet recording head having the ink repellent layer of the present invention provided on the ink discharging surface can maintain good ink discharging performance for a long period of time, and can provide a highly durable ink jet recording head. became.

It is a perspective view of an example of an ink jet recording head. It is sectional drawing of an example of an inkjet recording head. It is a schematic diagram of an example of an inkjet recording apparatus to which the inkjet recording head is applied.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Inkjet recording head 12 Nozzle formation member 12a Ink-repellent layer

Claims (4)

A coating liquid containing an aqueous dispersion of a fluororesin, a water-soluble polyamideimide resin, and an inorganic ultraviolet absorber having a concentration of 5% by mass or less (excluding 0%) with respect to the fluororesin is at least an ink. An ink jet recording head manufacturing method comprising forming an ink repellent layer by applying to an ejection surface.   The method of manufacturing an ink jet recording head according to claim 1, wherein the inorganic ultraviolet absorber is cerium oxide.   The method of manufacturing an ink jet recording head according to claim 1, wherein the ink discharge surface is formed on a nozzle forming member.   The inkjet recording head according to claim 1, wherein the inkjet recording head is an inkjet recording head used in an inkjet recording apparatus that irradiates ultraviolet curable ink discharged from the inkjet recording head with ultraviolet rays. Manufacturing method of the head.

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