JP5225866B2 - トリクロピルブトキシエチルエステルの無溶媒調合物 - Google Patents
トリクロピルブトキシエチルエステルの無溶媒調合物 Download PDFInfo
- Publication number
- JP5225866B2 JP5225866B2 JP2008555225A JP2008555225A JP5225866B2 JP 5225866 B2 JP5225866 B2 JP 5225866B2 JP 2008555225 A JP2008555225 A JP 2008555225A JP 2008555225 A JP2008555225 A JP 2008555225A JP 5225866 B2 JP5225866 B2 JP 5225866B2
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- JP
- Japan
- Prior art keywords
- ester
- herbicidal composition
- surfactant
- ethylene oxide
- propylene oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 45
- -1 triclopyrbutoxyethyl ester Chemical class 0.000 title claims description 32
- 238000009472 formulation Methods 0.000 title description 6
- 230000002363 herbicidal effect Effects 0.000 claims description 21
- 239000004009 herbicide Substances 0.000 claims description 18
- 239000004094 surface-active agent Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 13
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 7
- 229920005682 EO-PO block copolymer Polymers 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 5
- 239000005558 Fluroxypyr Substances 0.000 claims description 3
- HUBANNPOLNYSAD-UHFFFAOYSA-N clopyralid Chemical compound OC(=O)C1=NC(Cl)=CC=C1Cl HUBANNPOLNYSAD-UHFFFAOYSA-N 0.000 claims description 3
- MEFQWPUMEMWTJP-UHFFFAOYSA-N fluroxypyr Chemical compound NC1=C(Cl)C(F)=NC(OCC(O)=O)=C1Cl MEFQWPUMEMWTJP-UHFFFAOYSA-N 0.000 claims description 3
- 239000005595 Picloram Substances 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- NQQVFXUMIDALNH-UHFFFAOYSA-N picloram Chemical compound NC1=C(Cl)C(Cl)=NC(C(O)=O)=C1Cl NQQVFXUMIDALNH-UHFFFAOYSA-N 0.000 claims description 2
- 229940077388 benzenesulfonate Drugs 0.000 claims 1
- 239000000975 dye Substances 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 7
- REEQLXCGVXDJSQ-UHFFFAOYSA-N trichlopyr Chemical compound OC(=O)COC1=NC(Cl)=C(Cl)C=C1Cl REEQLXCGVXDJSQ-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000005627 Triclopyr Substances 0.000 description 3
- 150000001412 amines Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 241000894007 species Species 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- WHKUVVPPKQRRBV-UHFFFAOYSA-N Trasan Chemical compound CC1=CC(Cl)=CC=C1OCC(O)=O WHKUVVPPKQRRBV-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- MZHCENGPTKEIGP-RXMQYKEDSA-N (R)-dichlorprop Chemical compound OC(=O)[C@@H](C)OC1=CC=C(Cl)C=C1Cl MZHCENGPTKEIGP-RXMQYKEDSA-N 0.000 description 1
- RBSXHDIPCIWOMG-UHFFFAOYSA-N 1-(4,6-dimethoxypyrimidin-2-yl)-3-(2-ethylsulfonylimidazo[1,2-a]pyridin-3-yl)sulfonylurea Chemical compound CCS(=O)(=O)C=1N=C2C=CC=CN2C=1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 RBSXHDIPCIWOMG-UHFFFAOYSA-N 0.000 description 1
- UBXILKVIJDEQON-UHFFFAOYSA-N 1-chlorododecane;n,n-dimethylmethanamine Chemical compound CN(C)C.CCCCCCCCCCCCCl UBXILKVIJDEQON-UHFFFAOYSA-N 0.000 description 1
- 239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 description 1
- IRJQWZWMQCVOLA-ZBKNUEDVSA-N 2-[(z)-n-[(3,5-difluorophenyl)carbamoylamino]-c-methylcarbonimidoyl]pyridine-3-carboxylic acid Chemical compound N=1C=CC=C(C(O)=O)C=1C(/C)=N\NC(=O)NC1=CC(F)=CC(F)=C1 IRJQWZWMQCVOLA-ZBKNUEDVSA-N 0.000 description 1
- CABMTIJINOIHOD-UHFFFAOYSA-N 2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]quinoline-3-carboxylic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC2=CC=CC=C2C=C1C(O)=O CABMTIJINOIHOD-UHFFFAOYSA-N 0.000 description 1
- NQQBTWVFKDDVIB-UHFFFAOYSA-N 2-aminoethanol;3,6-dichloropyridine-2-carboxylic acid Chemical compound NCCO.OC(=O)C1=NC(Cl)=CC=C1Cl NQQBTWVFKDDVIB-UHFFFAOYSA-N 0.000 description 1
- ZMWGIGHRZQTQRE-UHFFFAOYSA-N 2-butoxyethyl 2-(2,4-dichlorophenoxy)acetate Chemical compound CCCCOCCOC(=O)COC1=CC=C(Cl)C=C1Cl ZMWGIGHRZQTQRE-UHFFFAOYSA-N 0.000 description 1
- IVDRCZNHVGQBHZ-UHFFFAOYSA-N 2-butoxyethyl 2-(3,5,6-trichloropyridin-2-yl)oxyacetate Chemical compound CCCCOCCOC(=O)COC1=NC(Cl)=C(Cl)C=C1Cl IVDRCZNHVGQBHZ-UHFFFAOYSA-N 0.000 description 1
- SVOAUHHKPGKPQK-UHFFFAOYSA-N 2-chloro-9-hydroxyfluorene-9-carboxylic acid Chemical compound C1=C(Cl)C=C2C(C(=O)O)(O)C3=CC=CC=C3C2=C1 SVOAUHHKPGKPQK-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- NPSJHQMIVNJLNN-UHFFFAOYSA-N 2-ethylhexyl 4-nitrobenzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=C([N+]([O-])=O)C=C1 NPSJHQMIVNJLNN-UHFFFAOYSA-N 0.000 description 1
- 239000004808 2-ethylhexylester Substances 0.000 description 1
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 description 1
- NGZWZIAGFHOSDS-UHFFFAOYSA-N 6-methylheptyl 4-amino-3,5,6-trichloropyridine-2-carboxylate Chemical compound CC(C)CCCCCOC(=O)C1=NC(Cl)=C(Cl)C(N)=C1Cl NGZWZIAGFHOSDS-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 239000005492 Carfentrazone-ethyl Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000005974 Chlormequat Substances 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 239000005504 Dicamba Substances 0.000 description 1
- 239000005505 Dichlorprop-P Substances 0.000 description 1
- 239000005507 Diflufenican Substances 0.000 description 1
- 239000005510 Diuron Substances 0.000 description 1
- 239000005562 Glyphosate Substances 0.000 description 1
- CAWXEEYDBZRFPE-UHFFFAOYSA-N Hexazinone Chemical compound O=C1N(C)C(N(C)C)=NC(=O)N1C1CCCCC1 CAWXEEYDBZRFPE-UHFFFAOYSA-N 0.000 description 1
- 239000005981 Imazaquin Substances 0.000 description 1
- 239000005567 Imazosulfuron Substances 0.000 description 1
- NAGRVUXEKKZNHT-UHFFFAOYSA-N Imazosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2N3C=CC=CC3=NC=2Cl)=N1 NAGRVUXEKKZNHT-UHFFFAOYSA-N 0.000 description 1
- 239000005574 MCPA Substances 0.000 description 1
- 239000005584 Metsulfuron-methyl Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000209504 Poaceae Species 0.000 description 1
- CNILNQMBAHKMFS-UHFFFAOYSA-M Pyrithiobac-sodium Chemical compound [Na+].COC1=CC(OC)=NC(SC=2C(=C(Cl)C=CC=2)C([O-])=O)=N1 CNILNQMBAHKMFS-UHFFFAOYSA-M 0.000 description 1
- FHNINJWBTRXEBC-UHFFFAOYSA-N Sudan III Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC(C=C1)=CC=C1N=NC1=CC=CC=C1 FHNINJWBTRXEBC-UHFFFAOYSA-N 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000005619 Sulfosulfuron Substances 0.000 description 1
- HBPDKDSFLXWOAE-UHFFFAOYSA-N Tebuthiuron Chemical compound CNC(=O)N(C)C1=NN=C(C(C)(C)C)S1 HBPDKDSFLXWOAE-UHFFFAOYSA-N 0.000 description 1
- YIJZJEYQBAAWRJ-UHFFFAOYSA-N Thiazopyr Chemical compound N1=C(C(F)F)C(C(=O)OC)=C(CC(C)C)C(C=2SCCN=2)=C1C(F)(F)F YIJZJEYQBAAWRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005626 Tribenuron Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- JUZXDNPBRPUIOR-UHFFFAOYSA-N chlormequat Chemical compound C[N+](C)(C)CCCl JUZXDNPBRPUIOR-UHFFFAOYSA-N 0.000 description 1
- JXCGFZXSOMJFOA-UHFFFAOYSA-N chlorotoluron Chemical compound CN(C)C(=O)NC1=CC=C(C)C(Cl)=C1 JXCGFZXSOMJFOA-UHFFFAOYSA-N 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- IWEDIXLBFLAXBO-UHFFFAOYSA-N dicamba Chemical compound COC1=C(Cl)C=CC(Cl)=C1C(O)=O IWEDIXLBFLAXBO-UHFFFAOYSA-N 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- WYEHFWKAOXOVJD-UHFFFAOYSA-N diflufenican Chemical compound FC1=CC(F)=CC=C1NC(=O)C1=CC=CN=C1OC1=CC=CC(C(F)(F)F)=C1 WYEHFWKAOXOVJD-UHFFFAOYSA-N 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- MLKCGVHIFJBRCD-UHFFFAOYSA-N ethyl 2-chloro-3-{2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl]-4-fluorophenyl}propanoate Chemical group C1=C(Cl)C(CC(Cl)C(=O)OCC)=CC(N2C(N(C(F)F)C(C)=N2)=O)=C1F MLKCGVHIFJBRCD-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000013020 final formulation Substances 0.000 description 1
- 239000013022 formulation composition Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 1
- 229940097068 glyphosate Drugs 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000007726 management method Methods 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- RSMUVYRMZCOLBH-UHFFFAOYSA-N metsulfuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=NC(OC)=N1 RSMUVYRMZCOLBH-UHFFFAOYSA-N 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000003359 percent control normalization Methods 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- TVRGPOFMYCMNRB-UHFFFAOYSA-N quinizarine green ss Chemical compound C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1 TVRGPOFMYCMNRB-UHFFFAOYSA-N 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- KZOJQMWTKJDSQJ-UHFFFAOYSA-M sodium;2,3-dibutylnaphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CCCC)C(CCCC)=CC2=C1 KZOJQMWTKJDSQJ-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- FZMKKCQHDROFNI-UHFFFAOYSA-N sulfometuron Chemical compound CC1=CC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(O)=O)=N1 FZMKKCQHDROFNI-UHFFFAOYSA-N 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- LOQQVLXUKHKNIA-UHFFFAOYSA-N thifensulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C2=C(SC=C2)C(O)=O)=N1 LOQQVLXUKHKNIA-UHFFFAOYSA-N 0.000 description 1
- XOPFESVZMSQIKC-UHFFFAOYSA-N triasulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)OCCCl)=N1 XOPFESVZMSQIKC-UHFFFAOYSA-N 0.000 description 1
- BQZXUHDXIARLEO-UHFFFAOYSA-N tribenuron Chemical compound COC1=NC(C)=NC(N(C)C(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(O)=O)=N1 BQZXUHDXIARLEO-UHFFFAOYSA-N 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
Agnique(商標)ABS 60C−ドデシルベンゼンスルホン酸カルシウム塩(60%有効)−(50g)を、40℃まで加温した。攪拌しながら、溶融(35℃)Agnique(商標)BP NP−1530−ノニルフェノールブロックコポリマーPO(30)EO(15)−(30g)、次いでDehypon(商標)LS 36−C12〜C14脂肪族アルコールPO(6)E0(3)−(20g)を加えた。単一相が得られるまで混合物を攪拌した。
実施例1からの界面活性剤混合物(14g)を、室温で攪拌しながら工業用トリクロピルブトキシエチルエステル86gに加えた。単一相が得られるまで攪拌を継続した。
試行を、混合および単一種木本サイトの4つの場所で実施した。標的木本雑木林は、6フィート以下であり、施用は、手持ちブームによって頂部から実施した。研究は、実施例2の無溶媒調合物を、ケロシンを含有する市販のGarlon4調合物と比較するように設計した。選定した施用量は、標的種を基準とした。混合雑木林では、施用量は、1.5および3.0ポンド酸当量/エーカー(lbs ae/ac)(1.68および3.36キログラム酸当量/ヘクタール(kg ae/ha))であった。エニシダに対しては、施用量は、1.25lbs ae/ac(1.4kg ae/ha)であった。調合物は、水で希釈し、20ガロン/エーカー(gpa)(187リットル/ヘクタール(L/ha))の送達体積で施用した。混合物に界面活性剤は一切加えなかった。サイトは、成長期において処理し、制御の評価は翌年実施した。結果(制御%)を表Iに要約する。
Claims (4)
- 70から95重量%のトリクロピルブトキシエチルエステルおよび5から30重量%の界面活性剤からなる除草組成物であって、前記界面活性剤が、30から60重量%のアルキルベンゼンスルホン酸塩と、25から45重量%のエチレンオキシド−プロピレンオキシドブロックコポリマーと、15から35重量%のエトキシル化−プロポキシル化脂肪族アルコールとの混合物を含む、除草組成物。
- 木本植生の葉面、または基部樹皮もしくは茎に、請求項1に記載の除草組成物の希釈水溶液を施用するステップを含む、望ましくない木本植生を制御するための方法。
- 除草組成物が、追加の除草剤と共に使用される、請求項2に記載の方法。
- 追加の除草剤が、アミノピラリド、クロピラリド、フルロキシピル、またはピクロラムである、請求項3に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US77341706P | 2006-02-15 | 2006-02-15 | |
US60/773,417 | 2006-02-15 | ||
PCT/US2006/044751 WO2007094836A1 (en) | 2006-02-15 | 2006-11-17 | Solventless formulation of triclopyr butoxyethyl ester |
Publications (3)
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JP2009526843A JP2009526843A (ja) | 2009-07-23 |
JP2009526843A5 JP2009526843A5 (ja) | 2009-12-24 |
JP5225866B2 true JP5225866B2 (ja) | 2013-07-03 |
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JP2008555225A Active JP5225866B2 (ja) | 2006-02-15 | 2006-11-17 | トリクロピルブトキシエチルエステルの無溶媒調合物 |
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US (1) | US7488702B2 (ja) |
EP (1) | EP1983829B8 (ja) |
JP (1) | JP5225866B2 (ja) |
KR (1) | KR101375958B1 (ja) |
CN (1) | CN101304657B (ja) |
AU (1) | AU2006338192B2 (ja) |
BR (1) | BRPI0621351B8 (ja) |
CA (1) | CA2630847C (ja) |
CR (1) | CR10159A (ja) |
DE (1) | DE602006011790D1 (ja) |
ES (1) | ES2337300T3 (ja) |
MY (1) | MY177114A (ja) |
NZ (1) | NZ567245A (ja) |
RU (1) | RU2413414C2 (ja) |
WO (1) | WO2007094836A1 (ja) |
ZA (1) | ZA200804632B (ja) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
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US7488702B2 (en) | 2006-02-15 | 2009-02-10 | Pompeo Michael P | Solventless formulation of triclopyr butoxyethyl ester |
EP2180784B2 (en) * | 2007-08-30 | 2019-05-29 | Dow AgroSciences LLC | Stable emulsion formulation hindering interaction across the water-oil interface |
AR069011A1 (es) * | 2007-10-24 | 2009-12-23 | Dow Agrosciences Llc | Formulaciones herbicidas libres de solvente aromaticas de ester de fluroxipir meptilo con esteres c₄₋₈ de triclopir, 2,4-d o mcpa |
US20090155142A1 (en) * | 2007-12-12 | 2009-06-18 | Bauer John E | Molecular sieve and catalyst incorporating the sieve |
EP2252146A2 (en) * | 2008-02-05 | 2010-11-24 | Arysta LifeScience North America, LLC | Solid formulation of low melting active compound |
DK2361012T3 (en) | 2008-10-29 | 2016-08-22 | Dow Agrosciences Llc | STABLE emulsifiable concentrates CONTAINING A FIRST herbicidal carboxylic acid salt AND ANOTHER HERBICIDAL carboxylic acid ester |
JP2012073978A (ja) * | 2010-09-30 | 2012-04-12 | Hitachi Ltd | サーバ装置の筐体構造 |
AU2013315646B2 (en) | 2012-09-13 | 2016-04-07 | Corteva Agriscience Llc | Herbicidal compositions comprising aminopyralid and triclopyr |
ES2734482T3 (es) | 2012-12-21 | 2019-12-10 | Dow Agrosciences Llc | Herbicida que contiene aminopiralida, triclopir y tensioactivo de organosilicona |
US20160183521A1 (en) | 2013-07-31 | 2016-06-30 | Akzo Nobel Chemicals International B.V. | Solvent Free Liquid Alkylbenzene Sulfonate Composition and Its Use in Agrochemical Formulations |
CN107926955B (zh) * | 2017-04-25 | 2021-03-09 | 湖南比德生化科技股份有限公司 | 一种含绿草定酯与毒莠定的混合乳油 |
BR112021014078A2 (pt) * | 2019-01-18 | 2021-09-21 | Sbm Developpment Sas | Misturas e composições herbicidas sinérgicas compreendendo triclopir e adjuvantes éster de fosfato |
WO2021219505A1 (de) * | 2020-04-30 | 2021-11-04 | Evonik Operations Gmbh | Verwendung von polyethern als träger für wirkstoffe |
Family Cites Families (15)
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AU612347B2 (en) * | 1987-02-24 | 1991-07-11 | Rhone-Poulenc Agrochimie | Herbicidal composition and method |
US5834006A (en) | 1990-04-05 | 1998-11-10 | Dow Agrosciences Llc | Latex-based agricultural compositions |
US5466659A (en) | 1993-01-15 | 1995-11-14 | Dowelanco | Triclopyr butoxyethyl ester compositions comprising vegetable oil esters as carriers |
CA2120375A1 (en) | 1993-04-02 | 1994-10-03 | John Klier | A laundry pretreater having enhanced oily soil removal |
GB9315501D0 (en) | 1993-07-27 | 1993-09-08 | Ici Plc | Surfactant compositions |
GB9414318D0 (en) | 1994-07-15 | 1994-09-07 | Dowelanco Ltd | Preparation of aqueous emulsions |
IT1275167B (it) | 1995-02-23 | 1997-07-30 | Isagro Spa | Adiuvanti per fungicidi sistemici composizioni fungicide che li contengono e loro impiego |
GB9505204D0 (en) | 1995-03-15 | 1995-05-03 | Dowelanco | Mixed herbicidal compositions |
CZ20023378A3 (cs) * | 2000-03-13 | 2003-01-15 | Basf Aktiengesellschaft | Zemědělský prostředek |
DE10035930A1 (de) | 2000-07-21 | 2002-01-31 | Clariant Gmbh | Feinemulsionen |
AU2004100006A4 (en) | 2003-01-06 | 2004-03-11 | Nufarm Australia Limited | Herbicidal composition |
CA2520228A1 (en) * | 2003-03-26 | 2004-10-07 | Bayer Cropscience Gmbh | Use of aromatic compounds as safeners |
EP2712503A3 (en) | 2003-04-22 | 2016-03-23 | Monsanto Technology LLC | Herbicidal compositions containing glyphosate and a pyridine analog |
JP4377612B2 (ja) * | 2003-05-21 | 2009-12-02 | 日本曹達株式会社 | つる性植物の生育抑制用塗料及びつる性植物の生育抑制方法 |
US7488702B2 (en) | 2006-02-15 | 2009-02-10 | Pompeo Michael P | Solventless formulation of triclopyr butoxyethyl ester |
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2006
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- 2006-11-17 DE DE602006011790T patent/DE602006011790D1/de active Active
- 2006-11-17 NZ NZ567245A patent/NZ567245A/en not_active IP Right Cessation
- 2006-11-17 WO PCT/US2006/044751 patent/WO2007094836A1/en active Application Filing
- 2006-11-17 AU AU2006338192A patent/AU2006338192B2/en active Active
- 2006-11-17 RU RU2008136885/21A patent/RU2413414C2/ru not_active IP Right Cessation
- 2006-11-17 BR BRPI0621351A patent/BRPI0621351B8/pt active IP Right Grant
- 2006-11-17 CN CN2006800421362A patent/CN101304657B/zh active Active
- 2006-11-17 CA CA2630847A patent/CA2630847C/en active Active
- 2006-11-17 ES ES06837962T patent/ES2337300T3/es active Active
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Also Published As
Publication number | Publication date |
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CN101304657B (zh) | 2011-08-31 |
BRPI0621351B1 (pt) | 2015-02-24 |
RU2413414C2 (ru) | 2011-03-10 |
CA2630847A1 (en) | 2007-08-23 |
EP1983829B1 (en) | 2010-01-13 |
KR20080093053A (ko) | 2008-10-17 |
ZA200804632B (en) | 2009-12-30 |
KR101375958B1 (ko) | 2014-03-18 |
EP1983829B8 (en) | 2010-03-17 |
RU2008136885A (ru) | 2010-03-20 |
NZ567245A (en) | 2010-07-30 |
CN101304657A (zh) | 2008-11-12 |
MY177114A (en) | 2020-09-07 |
DE602006011790D1 (de) | 2010-03-04 |
BRPI0621351A2 (pt) | 2011-12-06 |
CA2630847C (en) | 2013-09-10 |
JP2009526843A (ja) | 2009-07-23 |
CR10159A (es) | 2008-10-29 |
EP1983829A1 (en) | 2008-10-29 |
AU2006338192A1 (en) | 2007-08-23 |
US20070191229A1 (en) | 2007-08-16 |
BRPI0621351B8 (pt) | 2022-06-28 |
ES2337300T3 (es) | 2010-04-22 |
US7488702B2 (en) | 2009-02-10 |
AU2006338192B2 (en) | 2012-03-22 |
WO2007094836A1 (en) | 2007-08-23 |
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