JP5219194B2 - 有機分子内包カーボンナノチューブおよび電子デバイス - Google Patents
有機分子内包カーボンナノチューブおよび電子デバイス Download PDFInfo
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- JP5219194B2 JP5219194B2 JP2008084092A JP2008084092A JP5219194B2 JP 5219194 B2 JP5219194 B2 JP 5219194B2 JP 2008084092 A JP2008084092 A JP 2008084092A JP 2008084092 A JP2008084092 A JP 2008084092A JP 5219194 B2 JP5219194 B2 JP 5219194B2
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Description
図5に示すように、C60内包単層カーボンナノチューブ(C60@SWNT)の外壁を共有結合により修飾有機分子で化学修飾し、分散化、光機能化を行った。
C60内包単層カーボンナノチューブ(製作方法は、Kataura,H.ら、Synthetic Metals,2001年,121巻,pp.1195−1196を参照)0.70mgと、パラ−ヨードアニリン(東京化成工業社製、特級)1.5gとをシュレンク管に入れ、アルゴン置換を行った。さらに、オルト−ジクロロベンゼン(ODCB:和光純薬社製、特級、蒸留済み)5mLを加え、バス型の超音波照射機(本多電子社製、W−211)にて5分間超音波照射後、アルゴンバブリングを30分間行った。その後、アルゴン雰囲気下で、65℃に加熱し、亜硝酸イソペンチル(ナカライ社製、特級)2mLを少しずつ加え、3時間加熱撹拌を行った。
C60@SWNT−IP 1.80mgをシュレンク管に加え、アルゴン置換を行った。そこに、N,N−ジメチルホルムアミド(和光純薬社製、脱水、有機合成用)とトルエン(蒸留済み)とを2mLzずつ加え、バス型の超音波照射機(本多電子社製、W−211)により超音波照射を5分間行った。さらに、炭酸セシウム(ナカライ社製、特級)160mg、5,10,15−Tris(3,5−di−tert−butylphenyl)−20−(4,4,5,5−tetramethyl−[1,3,2]dioxaborolan−2−yl)porphyrinato Zinc(II)50mg、テトラキストリフェニルホスフィンパラジウム(東京化成工業社製)6mgを加え、100℃にて24時間加熱撹拌を行った。
C60内包単層カーボンナノチューブ(C60@SWNT)の有機溶媒中への分散を、N,N−ジメチルホルムアミド(和光純薬社製、脱水、有機合成用)10mLにC60@SWNTを0.1mg加え、バス型の超音波照射機(本多電子社製、W−211)を用いて10分間の超音波照射により、行った。30分間静置後、目視により、固体上の浮遊物が確認された。その結果、C60@SWNTのN,N−ジメチルホルムアミド中への分散度は、0.01g/L以下であった。
Claims (3)
- 有機分子を内部空間に内包するカーボンナノチューブであって、
前記カーボンナノチューブの外壁が、共有結合により機能性分子で化学修飾されており、
前記機能性分子が、ポルフィリン系分子であり、
前記有機分子が、フラーレンであることを特徴とする有機分子内包カーボンナノチューブ。 - 有機分子を内部空間に内包するカーボンナノチューブであって、前記カーボンナノチューブの外壁が共有結合により機能性分子で化学修飾されており、前記機能性分子が、ポルフィリン系分子であり、前記有機分子が、フラーレンである有機分子内包カーボンナノチューブを含むことを特徴とする電子デバイス。
- 請求項2に記載の電子デバイスであって、
前記電子デバイスが、太陽電池であることを特徴とする電子デバイス。
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JP2008084092A JP5219194B2 (ja) | 2008-03-27 | 2008-03-27 | 有機分子内包カーボンナノチューブおよび電子デバイス |
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JP2008084092A JP5219194B2 (ja) | 2008-03-27 | 2008-03-27 | 有機分子内包カーボンナノチューブおよび電子デバイス |
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JP2009234866A JP2009234866A (ja) | 2009-10-15 |
JP5219194B2 true JP5219194B2 (ja) | 2013-06-26 |
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JP2008084092A Expired - Fee Related JP5219194B2 (ja) | 2008-03-27 | 2008-03-27 | 有機分子内包カーボンナノチューブおよび電子デバイス |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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US10177314B2 (en) * | 2009-12-03 | 2019-01-08 | Nokia Technologies Oy | Apparatus, methods and devices |
JP5571994B2 (ja) * | 2010-03-30 | 2014-08-13 | 株式会社東芝 | カーボンナノチューブ集合体、太陽電池、及び導波路及びカーボンナノチューブ集合体付き基板 |
JP2014101234A (ja) * | 2012-11-16 | 2014-06-05 | Asahi Kasei Chemicals Corp | 表面処理カーボンナノチューブ |
JP2014101233A (ja) * | 2012-11-16 | 2014-06-05 | Asahi Kasei Chemicals Corp | 表面処理カーボンナノチューブ |
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GB2428135B (en) * | 2005-07-07 | 2010-04-21 | Univ Surrey | Improvements in thin film production |
FI120195B (fi) * | 2005-11-16 | 2009-07-31 | Canatu Oy | Hiilinanoputket, jotka on funktionalisoitu kovalenttisesti sidotuilla fullereeneilla, menetelmä ja laitteisto niiden tuottamiseksi ja niiden komposiitit |
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