JP5199683B2 - Fuel cell system - Google Patents

Description

  The present invention relates to a fuel cell system including a scavenging method for scavenging a fuel cell.

  In a fuel cell system installed in a fuel cell vehicle or the like, if water generated during power generation remains in piping including the fuel cell, the water freezes when the system is stopped in a cold environment such as a cold region or winter. As a result, there is a problem that the cold startability at the time of restarting is lowered. For this reason, scavenging treatment is performed by introducing scavenging gas to the anode side and the cathode side of the fuel cell when the system is stopped.

In this type of fuel cell system, for example, fuel gas remains in the anode when the system is stopped, and if the purge valve is opened during scavenging of the anode, high concentration hydrogen may be discharged. A technique has been proposed in which scavenging gas is also introduced into the anode side for purging by cathode scavenging (see Patent Document 1).
JP 2006-139939 A (paragraph 0035, FIG. 2)

  By the way, the hydrogen removal method in the anode system at the time of cathode scavenging in a conventional fuel cell system is a method for discharging the maximum amount of hydrogen remaining in the anode system outside the system at a predetermined concentration or less. there were. However, the amount of residual hydrogen in the anode system is, for example, (1) when operating conditions immediately before the operation stop (for example, when the anode side is operated at a low pressure (for example, idling operation for a long time) immediately before the operation stop) (2) Residual hydrogen amount is less than the maximum hydrogen amount), (2) Power generation stop time from shutdown to anode scavenging (generally, hydrogen in the anode system during crossover or outleak during power stoppage) The amount of residual hydrogen in the anode system decreases as the power generation stop time until the anode scavenging is longer). In other words, the conventional fuel cell system performs more hydrogen removal than necessary (hydrogen removal corresponding to the worst condition) in many scenes as described above. As a result, the scavenging energy is wasted (energy consumption). There is a problem that the scavenging time becomes unnecessarily long (productivity deterioration).

  The present invention solves the above-described conventional problems, and an object thereof is to provide a fuel cell system capable of shortening the scavenging time without wasting scavenging energy wastefully.

The invention according to claim 1 is a fuel cell that generates electric power by a reaction between a fuel gas supplied to the anode and an oxidant gas supplied to the cathode, a fuel gas flow passage for allowing the fuel gas to flow through the fuel cell, an oxidant gas flow path for circulating the cathode oxidant gas, and communication channels for communicating the oxidant gas flow path and the fuel gas flow passage, a communication valve for opening and closing the communication passage, wherein A fuel exhaust gas dilution means for diluting the fuel exhaust gas discharged from the anode with an oxidant gas and discharging it to the outside, a purge valve for purging the fuel exhaust gas from the anode to the fuel exhaust gas dilution means, and a power generation stop of the fuel cell a state monitoring means for monitoring a status change after, when the state change after the power generation stop of the fuel cell becomes a predetermined condition, the scavenging said cathode before Symbol oxidizing gas Performs scavenging, then a scavenging means for performing a second scavenging scavenging the anode and open the communication valve and the purge valve, the required oxidation of the first scavenging and the second scavenging an oxidizing agent gas supply amount calculating means for calculating a supply amount of gas, in the fuel cell system and a purge valve opening time control means for controlling the opening time of the purge valve, opening and closing the purge valve A purge control means for controlling the purge during the first scavenging, and a fuel for predicting the concentration of the fuel gas in the fuel exhaust gas based on the system stop time until the first scavenging after the fuel cell power generation is stopped A gas concentration predicting unit, and a fuel gas discharge amount predictor for predicting a discharge amount of the fuel gas from the anode based on an anode pressure when the state change becomes a predetermined condition after stopping the power generation of the fuel cell. If the system stop time and determining the system stop time determination means for determining whether the predetermined or higher, the valve opening time of the purge valve by the purge valve opening time control means at the time of the first scavenging, Based on the fuel gas concentration and the discharge amount predicted by the fuel gas concentration prediction means and the fuel gas discharge amount prediction means, the higher the concentration of the fuel gas, the shorter the opening time of the purge valve. And a purge valve that corrects the purge valve opening time as a longer time as the fuel gas discharge amount is smaller even when the concentration of the fuel gas is high A valve opening time correcting means , wherein the system stop time determining means determines that the system stop time is greater than or equal to a predetermined value and the concentration of the fuel gas is predicted to be low If the purge control means does not execute the purge during the first scavenging, and the system stop time determination means determines that the system stop time is not a predetermined time or more, the purge valve opening time The purge control means opens the purge valve and calculates the purge during the first scavenging after calculating the valve opening time by the calculating means and correcting the valve opening time by the purge valve opening time correcting means. It is characterized by performing .

According to the first aspect of the present invention, even when the system stop time is short and the internal fuel gas (hydrogen) concentration is high by calculating the valve open time (ON time) of the purge valve from the system stop time and the anode pressure. When the anode pressure is low, the amount of discharged fuel gas is reduced, so that the valve opening time can be set longer. Therefore, by changing the opening time of the purge valve in accordance with the amount of discharged fuel gas, it becomes possible to make the discharged fuel gas amount (concentration) constant, and to prevent unnecessary dilution. As a result, it is possible to shorten the dilution time (hydrogen removal time) and scavenging (first scavenging + second scavenging) time and improve energy efficiency.
Further, if the system shutdown time continues for a long time, the internal anode pressure and concentration are reduced to a predetermined level (no need for purge), so that no purge is required. Therefore, when the system stop time continues for a long time, the purge is not performed during the first scavenging (cathodic scavenging), so that the energy for dilution can be reduced.

  The invention according to claim 2 is characterized in that the purge valve opening time correction means is configured to open the valve in the (N + 1) th purge from the valve opening time in the Nth (N = 1, 2, 3,...) Purge. It is characterized by setting a long time.

  According to the invention of claim 2, since the concentration of the internal fuel gas decreases every time the purge is repeated, the amount of discharged fuel gas can be made constant by lengthening the opening time of the purge valve. This makes it possible to further reduce the dilution time and the scavenging time.

The invention according to claim 3 is a fuel cell that generates power by a reaction between a fuel gas supplied to the anode and an oxidant gas supplied to the cathode, a fuel gas flow passage for allowing the fuel gas to flow through the fuel cell, an oxidant gas flow path for circulating the cathode oxidant gas, and communication channels for communicating the oxidant gas flow path and the fuel gas flow passage, a communication valve for opening and closing the communication passage, wherein A fuel exhaust gas dilution means for diluting the fuel exhaust gas discharged from the anode with an oxidant gas and discharging it to the outside, a purge valve for purging the fuel exhaust gas from the anode to the fuel exhaust gas dilution means, and a power generation stop of the fuel cell a state monitoring means for monitoring a status change after, when the state change after the power generation stop of the fuel cell becomes a predetermined condition, the scavenging said cathode before Symbol oxidizing gas Performs scavenging, then a scavenging means for performing a second scavenging scavenging the anode and open the communication valve and the purge valve, the required oxidation of the first scavenging and the second scavenging And a purge control means for controlling the purge during the first scavenging by opening and closing the purge valve in a fuel cell system comprising: an oxidant gas supply amount calculating means for obtaining a supply amount of the agent gas; and the purge valve Purge interval time control means for controlling the interval time for opening the valve , and fuel for predicting the concentration of the fuel gas in the fuel exhaust gas based on the system stop time until the first scavenging after the fuel cell power generation is stopped A gas concentration predicting means and a fuel gas discharge amount from the anode based on an anode pressure when the state change becomes a predetermined condition after stopping the power generation of the fuel cell; And the fuel gas discharge amount estimating means, wherein the system downtime and determines the system stop time determination means for determining whether the predetermined or more, the pre-listening interval time by the purge interval control means during the first scavenging The purge interval time in which the higher the fuel gas concentration is, the longer the time is based on the fuel gas concentration predicting means and the fuel gas discharge predicting means predicted by the fuel gas concentration predicting means The system stop time determination means, further comprising: a calculation means; and a purge interval time correction means for correcting a shorter time as the fuel gas discharge amount is smaller even when the concentration of the fuel gas is high. If the system shutdown time is determined to be greater than or equal to a predetermined value and the fuel gas concentration is predicted to be low, the purge When the control means does not execute the purge during the first scavenging and the system stop time determining means determines that the system stop time is not equal to or greater than a predetermined value, the purge interval time calculating means calculates the interval. In addition, the purge control means opens the purge valve and executes the purge during the first scavenging after correcting the interval by the purge interval time correcting means .

According to the invention of claim 3, by calculating the interval time (closed time, OFF time) of the purge valve from the system stop time and the anode pressure, even when the system stop time is short and the internal fuel gas concentration is high When the anode pressure is low, the amount of fuel gas discharged becomes small, so the interval time can be set short. Therefore, by changing the interval time of the purge valve according to the amount of discharged fuel gas, the amount (concentration) of discharged fuel gas can be made constant, and unnecessary dilution can be prevented. As a result, it is possible to shorten the dilution time (hydrogen removal time) and scavenging (first scavenging + second scavenging) time and improve energy efficiency.
Further, if the system shutdown time continues for a long time, the internal anode pressure and concentration are reduced to a predetermined level (no need for purge), so that no purge is required. Therefore, when the system stop time continues for a long time, the purge is not performed during the first scavenging (cathodic scavenging), so that the energy for dilution can be reduced.

  According to a fourth aspect of the present invention, the purge interval time correcting means sets the (N + 1) th purge interval shorter than the Nth (N = 1, 2, 3,...) Purge interval. It is characterized by.

  According to the invention of claim 4, since the concentration of the internal fuel gas decreases every time the purge is repeated, it is possible to make the discharged fuel gas amount (concentration) constant by shortening the interval time. Thus, the dilution time and the scavenging time can be further shortened.

  The invention according to claim 5 is characterized in that a total purge amount is determined based on the system stop time.

  According to the invention of claim 5, by calculating the total purge amount based on the system stop time, it is possible to prevent wasteful purging and reduce energy consumption.

The invention according to claim 6 includes a back pressure valve that is provided in the oxidant gas flow passage on the downstream side of the fuel cell and adjusts the pressure of the oxidant gas supplied to the cathode, and is downstream of the back pressure valve. The oxidant gas flow passage is provided with the fuel exhaust gas dilution means .

  ADVANTAGE OF THE INVENTION According to this invention, the fuel cell system which can shorten scavenging time can be provided, without using scavenging energy wastefully.

(First embodiment)
FIG. 1 is an overall configuration diagram showing the fuel cell system of this embodiment, FIG. 2 is a flowchart showing scavenging control of the first embodiment, and FIG. 3A shows the relationship between the system stop time and the hydrogen concentration in the anode system. (B) is a map showing the relationship between the anode system hydrogen concentration and the purge valve opening time, (c) is a map showing the relationship between the system stop time and the total purge amount, and FIG. 4 is a system for each purge. FIG. 5 is a time chart showing a change in the valve opening time of the purge valve in the anode purge. The map shows the relationship between the stop time and the valve opening time. In this embodiment, a fuel cell system for a vehicle (fuel cell vehicle) will be described as an example. However, the present invention is not limited to this, and is not limited to this. It can be applied to everything such as power supply systems for business use.

  As shown in FIG. 1, the fuel cell system 1 of the present embodiment includes a fuel cell 10, an anode system 20, a cathode system 30, a scavenging system 40, a control system 50, and the like.

  The fuel cell 10 is, for example, a PEM type fuel cell that is a solid polymer type, and an electrolyte membrane 11 is sandwiched between an anode 12 containing a catalyst and a cathode 13 containing a catalyst, and a pair of conductive separators 14, 15 has a structure in which a plurality of unit cells sandwiched between 15 are stacked in the thickness direction. An anode channel 14a through which hydrogen (fuel gas) flows is formed in the separator 14 facing the anode 12, and a cathode channel 15a through which air (oxidant gas) flows is formed in the separator 15 facing the cathode 13. Is formed. FIG. 1 schematically shows one single cell for convenience of explanation.

  The anode system 20 is a system for supplying and discharging hydrogen (fuel gas) to and from the anode 12 of the fuel cell 10, and includes a hydrogen tank 21, a shutoff valve 22, a purge valve 23, pipes a1 to a5, and the like. Yes.

  The hydrogen tank 21 is formed of, for example, an aluminum alloy, and has a tank chamber (not shown) that stores high-purity hydrogen gas at a high pressure therein. The periphery of the tank chamber is CFRP (Carbon Fiber Reinforced Plastic: A cover (not shown) formed of carbon fiber reinforced plastic) or GFRP (Glass Fiber Reinforced Plastic) is used.

  The shut-off valve 22 is an electromagnetically operated ON / OFF valve having a solenoid, and is connected to the hydrogen tank 21 via a pipe a1 and connected to the inlet of the anode flow path 14a of the fuel cell 10 via a pipe a2. Yes. The shut-off valve 22 may be a so-called in-tank type that is configured integrally with the hydrogen tank 21.

  The outlet of the anode flow path 14a is connected to the pipe a2 via a pipe a3 and an ejector (not shown) so that unreacted hydrogen discharged from the anode 12 is returned to the inlet of the anode flow path 14a and recirculated. It is configured. Thereby, the hydrogen accumulated in the hydrogen tank 21 is used effectively.

  The purge valve 23 is an electromagnetically operated ON / OFF valve having a solenoid, and is provided in a pipe a4 connected in the middle of the pipe a3. The purge valve 23 is opened under the control of an ECU (Electric Control Unit) 51 described later, thereby discharging impurities remaining in the flow path including the anode flow path 14a. The impurities are nitrogen in the air, generated water, and the like that are transmitted from the cathode 13 to the anode 12 through the electrolyte membrane 11.

  A dilution box 35 is connected downstream of the purge valve 23 via a pipe a5. The dilution box 35 has a space for diluting hydrogen, and hydrogen in the fuel exhaust gas (anode offgas) discharged from the anode 12 (anode system 20) in the space is discharged from the cathode flow path 15a of the fuel cell 10. It is diluted with the cathode off gas and discharged to the outside (outside the vehicle).

  The anode system 20 is provided with a regulator (not shown) for reducing the high-pressure hydrogen supplied from the hydrogen tank 21 to the pipe a2 (upstream of the ejector).

  The cathode system 30 is a system for supplying and discharging air (oxidant gas) to and from the cathode 13 of the fuel cell 10, and includes an air pump 31, a back pressure valve 32, pipes c1 to c3, and the like.

  The air pump 31 is composed of a supercharger or the like, and supplies air (oxygen) to the cathode 13 via a pipe c1 connected to the inlet of the cathode channel 15a. In addition, the humidifier (not shown) for humidifying the air from the air pump 31 moderately is provided in the piping c1.

  The back pressure valve 32 is configured with a valve whose opening degree can be adjusted, such as a butterfly valve, and the pressure of the air supplied to the cathode 13 of the fuel cell 10 can be adjusted by changing the opening degree under the control of the ECU 51 described later. It is like that. Further, the back pressure valve 32 is connected to the outlet of the cathode flow path 15a via the pipe c2, and is connected to the dilution box 35 via the pipe c3.

  The scavenging system 40 is a system for introducing air (air) as scavenging gas into the anode 12 after the operation of the fuel cell system 1 is stopped, and includes an air introduction pipe 41, an air introduction valve 42, and the like. .

  The air introduction pipe 41 has an upstream side connected to the pipe c1 and a downstream side connected to the pipe a2. The upstream end of the air introduction pipe 41 is connected to, for example, a pipe c1 located upstream of a humidifier (not shown), and the downstream end is a pipe a2 located downstream of an ejector (not shown). It is connected to the.

  The air introduction valve 42 is an electromagnetically operated ON / OFF valve, and is a valve that communicates and blocks the air introduction pipe 41. The air introduction valve 42 is opened by the control of the ECU 51 described later during scavenging of the fuel cell system 1, so that air from the air pump 31 passes through the air introduction pipe 41 and the anode flow path 14 a (anode) of the fuel cell 10. 12).

  The control system 50 includes an ECU 51, a temperature sensor 52, a pressure sensor 53, and the like.

  The ECU 51 includes a CPU (Central Processing Unit), a RAM, a ROM in which a program is stored, various circuits, and the like. The shut-off valve 22, the purge valve 23 and the air introduction valve 42 are opened and closed, the back pressure valve 32 is opened, and the air pump 31. The rotational speed of the motor is controlled, and the temperature (state) of the fuel cell 10 and the pressure (anode pressure) in the anode system 20 are acquired.

  Further, the ECU 51 includes oxidant gas supply amount calculation means, purge valve opening time control means, fuel gas concentration prediction means, fuel gas discharge amount prediction means, purge valve opening time calculation means, and purge valve opening time correction means. I have. The purge valve opening time control means has a function of controlling the opening time of the purge valve 23 when discharging hydrogen from the anode 12 to the dilution box 35 during cathode scavenging.

  The temperature sensor 52 is a state monitoring unit having a function of detecting the temperature (system temperature) of the fuel cell 10 (monitoring a state change). For example, the temperature sensor 52 is provided in the pipe a2 near the inlet of the anode flow path 14a of the fuel cell 10. It has been. The position of the temperature sensor 52 is not limited to the inlet of the anode flow path 14a as long as the temperature of the fuel cell 10 can be detected. The pipe a3 and the cathode flow path 15a near the outlet of the anode flow path 14a. May be a pipe c1 near the inlet, a pipe c2 near the outlet of the cathode flow path 15a, a pipe through which a cooling system refrigerant circulates, or may directly measure the temperature of the fuel cell 10.

  The pressure sensor 53 has a function of detecting the pressure in the anode system 20 and is provided, for example, in the vicinity of the inlet of the anode 12 of the fuel cell 10. The position of the pressure sensor 53 is not limited to the present embodiment as long as the pressure in the anode system 20 can be detected.

  Next, scavenging control after operation stop in the fuel cell system 1 of the present embodiment will be described with reference to FIGS. 2 to 5 (refer to FIG. 1 as appropriate). During operation of the fuel cell system 1, the shutoff valve 22 is opened by the control of the ECU 51, hydrogen is supplied from the hydrogen tank 21 to the anode 12 of the fuel cell 10, and the air compressor 31 is driven to drive the fuel. Humidified air is supplied to the cathode 13 of the battery 10.

  As a result, at the anode 12 of the fuel cell 10, electrons are separated from hydrogen by the action of the catalyst, the electrons move to the cathode 13 through an external load (travel motor, air pump, etc.), and hydrogen ions (protons) are transferred to the electrolyte membrane. 11 passes through the cathode 13. In the cathode 13, water is generated by a reaction between hydrogen ions, electrons, and oxygen in the air supplied from the air pump 31. The electric power generated by the fuel cell 10 is supplied to an auxiliary machine such as a travel motor (not shown) or an air pump 31 and is charged into a power storage device (not shown) as necessary. Note that the power storage device includes a lithium ion battery, a nickel metal hydride battery, a capacitor, and the like.

  As shown in FIG. 2, when an ignition switch (not shown) is turned off (IG-OFF) by the driver, the shutoff valve 22 is closed, the supply of hydrogen is stopped, the air pump 31 is stopped, and the air Supply is stopped and power generation stops. In addition, the system temperature is periodically detected and the system temperature is periodically detected. Monitoring of the system temperature by the temperature sensor 52 is performed by using a timer function built in the ECU 51.

  In step S100, the ECU 51 determines whether or not the temperature (system temperature) periodically acquired from the temperature sensor 52 is equal to or lower than a predetermined temperature. The predetermined temperature (predetermined condition) is set to, for example, a temperature (for example, 5 ° C.) before the temperature drops and the water freezes. By setting to such a low temperature before freezing, the water vapor in the fuel cell system 1 is sufficiently condensed, and the water in the fuel cell system 1 can be sufficiently discharged outside and dried during scavenging. .

  In step S100, if the ECU 51 determines that the system temperature is not lower than the predetermined temperature (No), the process of step S100 is repeated. When the system temperature is not lower than the predetermined temperature (S100, No), the scavenging control is terminated when the ignition switch is turned on. In step S100, if the ECU 51 determines that the system temperature is equal to or lower than the predetermined temperature (Yes), the ECU 51 proceeds to step S110.

  In step S110, the ECU 51 acquires time (system stop time, power generation stop time) until the system temperature becomes equal to or lower than a predetermined temperature after IG-OFF. The system stop time is acquired using a timer function built in the ECU 51.

  In step S120, the ECU 51 determines whether or not the system stop time is equal to or longer than a predetermined time (predetermined or longer). The predetermined time is a threshold value for determining whether or not to purge the anode 12 (anode purge, hydrogen removal) simultaneously with the cathode scavenging. In step S120, when the ECU 51 determines that the system stop time is not longer than the predetermined time (No), the ECU 51 proceeds to step S150, and when it is determined that the system stop time is longer than the predetermined time (Yes), the step Proceed to S130.

  In step S150, the ECU 51 estimates the hydrogen concentration in the anode off-gas (fuel exhaust gas) discharged from the anode system 20 based on the system stop time (fuel gas concentration prediction means). In addition, the estimation method of the hydrogen concentration in the anode system 20 is estimated based on the map of Fig.3 (a), for example. That is, as the system stop time becomes longer, the hydrogen concentration in the anode system 20 decreases. Incidentally, the hydrogen concentration in the anode system 20 decreases as the system stop time becomes longer because hydrogen on the anode 12 side permeates the cathode 13 through the electrolyte membrane 11 (so-called cross leak), and hydrogen molecules are very Therefore, a small amount of hydrogen leaks to the outside (so-called outleak) from a sealing member between single cells (between separators). Note that the method for estimating the hydrogen concentration is not limited to a map, and may be estimated using a table or a function.

  In step S160, the ECU 51 detects the anode pressure from the pressure sensor 53, and estimates the amount of hydrogen discharged from the anode system 20 (fuel gas discharge amount) (fuel gas discharge amount predicting means). The anode pressure is not limited to that detected by the pressure sensor 53, and may be estimated based on the system stop time, for example.

  In step S170a, the ECU 51 determines the valve opening time of the purge valve 23. The opening time of the purge valve 23 is determined based on the hydrogen concentration in the anode system 20 and the anode pressure. First, based on the map of FIG. 3B, the opening time of the purge valve 23 is set to be shorter in proportion to the increase in the hydrogen concentration in the anode system 20 (purge valve opening time). Calculation means). This is because if the valve opening time is increased when the hydrogen concentration is high, the dilution capacity of the dilution box 35 is exceeded. Note that the vertical axis of the map of FIG. 3B is the time for which the purge valve 23 is opened once.

  Then, the map of FIG. 3B is corrected based on the anode pressure detected in step S160. That is, when the anode pressure is low, the purge valve 23 is corrected so that the valve opening time becomes longer even when the hydrogen concentration in the anode system 20 is high (purge valve opening time correcting means).

  In step S180, the ECU 51 determines the total purge amount based on the map of FIG. As shown in FIG. 3C, as the system stop time becomes longer, the hydrogen concentration in the anode system 20 decreases due to cross leak or out leak, so that the total purge amount when purging the anode system 20 can be reduced. . The anode pressure at the end of the previous operation may be detected, and correction may be made so that the total purge amount is increased when the anode pressure is high and the total purge amount is decreased when the anode pressure is low.

  In step S190, the ECU 51 executes cathode scavenging (first scavenging). That is, the ECU 51 operates the back pressure valve 32 and the air pump 31 using the power of a power storage device (battery or the like) (not shown), and the air (air) from the air pump 31 is fully opened. Is introduced into the cathode 13 side of the fuel cell 10. Thereby, water (product water, condensed water, etc.) remaining in the cathode flow path 15a of the fuel cell 10 and the pipes c1 to c3 is discharged outside (outside the vehicle).

  In step S200, the ECU 51 performs control for purging (dehydrogenating or diluting) the anode 12 side simultaneously with the cathode scavenging. That is, the ECU 51 opens the purge valve 23 for the valve opening time (predetermined time) determined in step S170a in a state where the air introduction valve 42 is opened. As a result, part of the air from the air pump 31 is introduced from the air introduction pipe 41 to the anode 12 side, and hydrogen remaining in the anode system 20, that is, the anode flow path 14a and the pipes a2 to a5 passes through the dilution box 35. To the outside (outside the vehicle). The hydrogen introduced into the dilution box 35 is discharged after being diluted to a predetermined hydrogen concentration or less by air or the like (cathode off-gas) discharged from the cathode 13.

  In step S210, the ECU 51 determines whether or not anode purge (hydrogen removal) has been completed. In step S210, when the anode purge is not completed (No), the process proceeds to step S220a. As the determination condition for the completion of the anode purge, for example, the hydrogen discharge amount during the opening of the purge valve 23 is calculated, and when it is determined that the hydrogen discharge amount has reached a predetermined threshold 1, or from the start of the anode purge This is a case where the elapsed time of time reaches a predetermined threshold value 2.

  In step S220a, the ECU 51 changes the valve opening time of the purge valve 23 based on the map of FIG. That is, as shown in FIG. 4, in the second purge, hydrogen is discharged by the first purge and the hydrogen concentration is lowered, so the opening time of the purge valve 23 is set to the first purge as shown by the broken line. Can be set longer. Further, when the opening time of the purge valve 23 is changed again, since the hydrogen concentration is further lowered, the opening time of the third purge valve 23 is longer than that of the second time, as indicated by a one-dot chain line. Can be set. In this manner, the anode purge is executed while changing the valve opening time of the purge valve 23 longer until the anode purge is completed. Each OFF time (valve closing time) of the purge valve 23 between the anode purge and the anode purge is set to the same time.

  In step S210, when the ECU 51 determines that the anode purge is completed (Yes), the ECU 51 proceeds to step S230 and determines whether the cathode scavenging is completed. The determination condition for the completion of cathode scavenging can be determined, for example, when a predetermined time has elapsed since the start of cathode scavenging. Further, the predetermined time (cathode scavenging + anode scavenging described later) can be determined using a map or the like obtained in advance by experiments or the like, and the system stop time from the power generation stop of the fuel cell 10 to the first scavenging (cathode scavenging). Is set to a shorter time as the value becomes longer (oxidant gas supply amount calculating means). The scavenging completion condition is not limited to time, and a flow rate sensor is provided downstream of the air pump 31 so that scavenging is completed when a predetermined integrated flow rate (which can be determined as scavenging completed) is exceeded. It may be.

  In step S230, if the ECU 51 determines that the cathode scavenging has not been completed (No), the ECU 51 repeats step S230. If the ECU 51 determines that the cathode scavenging has been completed (Yes), the ECU 51 proceeds to step S240. Perform scavenging (second scavenging). In the anode scavenging, the back pressure valve 32 is closed and the air from the air pump 31 is introduced to the anode 12 side of the fuel cell 10 through the air introduction pipe 41. Thereby, the generated water and condensed water remaining in the anode flow path 14a and the pipes a2 to a5 are blown off by the pressure of the air and discharged to the outside (outside the vehicle).

  In step S250, the ECU 51 determines whether or not anode scavenging has been completed. If it is determined that anode scavenging has not been completed (No), step S250 is repeated to determine that anode scavenging has been completed. In the case (Yes), the process is terminated. The determination condition for completion of anode scavenging can be determined, for example, based on whether a predetermined time has elapsed.

  On the other hand, if the ECU 51 determines in step S120 that the system stop time is equal to or longer than the predetermined time (Yes), the ECU 51 determines that the hydrogen concentration in the anode system 20 is very low, and proceeds to step S130. Perform cathode scavenging without purging. In the cathode scavenging in this case, air (scavenging gas) is supplied to the cathode 13 of the fuel cell 10 and scavenging without opening the air introduction valve 42 and the purge valve 23. In step S140, the ECU 51 determines whether the cathode scavenging has been completed based on whether a predetermined time has elapsed. Then, after completion of the cathode scavenging, the anode scavenging is executed (S240, S250). In this case (when hydrogen removal is not necessary), anode scavenging and cathode scavenging may be performed in this order.

  The operation of the fuel cell system 1 of the present embodiment will be described with reference to FIG. That is, when the ignition switch is turned off (IG-OFF) (time t1), the contactor (not shown) (electrically connected / disconnected between the fuel cell 10 and the traveling motor, auxiliary equipment, etc.) ) Is cut off, and the extraction of the generated current (electric power) from the fuel cell 10 is stopped. Further, the shutoff valve 22 is closed, the supply of hydrogen is stopped, and the driving of the air pump 31 is stopped.

  When the system temperature reaches a predetermined temperature (time t2), the system stop time is determined, whereby the hydrogen concentration in the anode system 20 can be estimated, and the purge valve 23 is opened based on the hydrogen concentration and the anode pressure. Time etc. are determined (S100-S180).

  At time t2, the air pump 31 is driven to introduce air into the cathode 13 to perform cathode scavenging (S190), the air introduction valve 42 is opened, the purge valve 23 is opened and closed, and anode purge is performed. (S200). In this anode purge, for example, the purge valve 23 is opened for a predetermined time Tm1, closed for a predetermined time Ts, opened for a predetermined time Tm2, closed for a predetermined time Ts, opened for a predetermined time Tm3, and opened for a predetermined time Ts. The valve is closed (S200 to S220a). Incidentally, the first valve opening time Tm1 is set to a short valve opening time because the hydrogen concentration is high, and the third valve opening time Tm3 is set to a long valve opening time because hydrogen discharge is progressing ( Tm1 <Tm2 <Tm3). This is because, since hydrogen having a high hydrogen concentration is discharged at the first time, if the valve opening time is lengthened, the dilution capacity of the dilution box 35 is exceeded.

  As described above, the valve closing time Ts is made constant, and the opening time of the purge valve 23 is increased for each purge, so that the hydrogen is discharged from the dilution box 35 with a uniform amount of hydrogen, and the hydrogen in the anode system 20 has a predetermined concentration. Gradually decreases.

  When the cathode scavenging is completed together with the anode purge (S230, Yes), at time t3, the purge valve 23 is continuously opened while the air introduction valve 42 is opened, and the anode scavenging is executed (S240). , S250). As a result, hydrogen of a predetermined concentration or less remaining in the anode system 20 is discharged to the outside together with the generated water and condensed water remaining in the anode system 20 (the anode flow path 14a and the pipes a2 to a4).

  As described above, according to the present embodiment, by determining the valve opening time of the purge valve 23 based on the system stop time (anode system hydrogen concentration) and the anode pressure, the system stop time is short. Even when the hydrogen concentration is high, the amount of hydrogen discharged becomes small when the anode pressure is low, so that the opening time of the purge valve 23 can be set long. Therefore, by changing the valve opening time of the purge valve 23 according to the amount of hydrogen to be discharged (anode pressure), it becomes possible to discharge the hydrogen amount (hydrogen concentration) in a constant state. It is possible to prevent dilution from being performed. As a result, the hydrogen dilution time (time required for hydrogen removal) in the anode purge can be shortened, the scavenging time can be shortened, and the energy required for scavenging can be reduced to the minimum necessary.

  Further, according to the present embodiment, as described with reference to FIG. 5, the hydrogen concentration in the anode system 20 decreases every time the anode purge is repeated, so that the discharge is performed by increasing the opening time of the purge valve 23. This makes it possible to make the amount of hydrogen to be constant and further shorten the dilution time and scavenging time.

  Further, according to the present embodiment, by determining the total purge amount based on the system stop time (see FIG. 3C), the hydrogen concentration can be determined with high accuracy, so that the anode purge is performed wastefully. Can be prevented, and energy consumption can be reduced.

  In addition, according to the present embodiment, when the system stop time is extended for a long time, the pressure and the hydrogen concentration in the anode system 20 are reduced to a state where the anode purge is unnecessary (a predetermined concentration or less), so that the anode purge is unnecessary. Become. Therefore, when the system stop time is extended for a long time, by controlling so as not to perform the anode purge during the cathode scavenging, energy necessary for dilution (for example, necessary for opening and closing the purge valve 23) Power) can be reduced.

(Second Embodiment)
FIG. 6 is a flow chart showing scavenging control of the second embodiment, FIG. 7 is a map showing the relationship between the anode system hydrogen concentration and the purge valve interval time, and FIG. 8 is a system stop time and purge valve opening for each purge. FIG. 9 is a time chart showing a change in the interval operation of the purge valve in the anode purge. In the second embodiment, the ECU 51 of the fuel cell system 1 shown in FIG. 1 corrects the purge interval time control time instead of the purge valve opening time control means and the purge interval time correction instead of the purge valve opening time correction means. The present embodiment is different from the first embodiment in that a means is provided. In FIG. 6, processes (steps) similar to those in the first embodiment are denoted by the same step symbols and description thereof is omitted. Moreover, the vertical axis | shaft of FIG. 7 is one interval time.

  As shown in FIG. 6, in step S170b, the ECU 51 determines the interval time (OFF time, valve closing time) of the purge valve 23. The interval time of the purge valve 23 is determined based on the system stop time (hydrogen concentration) in the anode system 20 and the pressure. First, as shown in the map of FIG. 7, the interval time of the purge valve 23 is set to be longer in proportion to the increase in the hydrogen concentration in the anode system 20 (purge interval time calculating means). This is because the dilution ability of the dilution box 35 cannot be recovered if the interval time is shortened when the hydrogen concentration is high. Further, as shown in the map of FIG. 7, when the anode pressure is low, correction is made so that the interval time of the purge valve 23 becomes shorter even when the hydrogen concentration in the anode system 20 is high (purge interval time). Correction means). The interval time is set to such a time that the discharged hydrogen is sufficiently diluted.

  In step S210, when the ECU 51 determines that the anode purge is not completed (No), the ECU 51 proceeds to step S220b and changes the interval time of the purge valve 23 based on the map of FIG. That is, as shown in FIG. 8, in the second purge, since hydrogen is discharged by the first purge and the hydrogen concentration is lowered, the interval time of the purge valve 23 is set to be different from the first purge as shown by the broken line. Can be set shorter. Further, when the interval time of the purge valve 23 is changed again, since the hydrogen concentration is further lowered, the interval time of the third purge valve 23 can be set shorter than the second time, as indicated by a one-dot chain line. . In this way, the anode purge is executed while the interval time of the purge valve 23 is changed short until the anode purge is completed. Note that the opening time (ON time) of the purge valve 23 is set to the same time.

  As shown in FIG. 9, when the ignition switch is turned off (IG-OFF) (time t <b> 1), the contactor (not shown) is cut off, and extraction of the generated current (electric power) from the fuel cell 10 is stopped. Further, the shutoff valve 22 is closed, the supply of hydrogen is stopped, and the driving of the air pump 31 is stopped.

  When the system temperature decreases to a predetermined temperature (time t2), the interval time of the purge valve 23 and the like are determined based on the hydrogen concentration and the anode pressure (S100 to S180).

  At time t2, with the air introduction valve 42 opened, the air pump 31 is driven, air is introduced into the cathode 13 to perform cathode scavenging (S190), and the purge valve 23 is opened and closed to perform anode purge. Is executed (S200). In this anode purge, for example, the purge valve 23 is opened for a predetermined time Tm, closed for a predetermined time Ts1 (interval), opened for a predetermined time Tm, closed for a predetermined time Ts2 (interval), and opened for a predetermined time Tm. Then, the valve is closed (interval) for a predetermined time Ts3 (S200 to S220a). By the way, the first interval time Ts1 is short because the hydrogen concentration is high and the dilution ability of the dilution box 35 cannot be recovered unless a long interval time is set, and the third interval time Ts3 is short because hydrogen discharge is progressing. The dilution capacity of the dilution box 35 can be recovered in the interval time (Ts1> Ts2> Ts3).

  As described above, the predetermined time (opening time) Tm of the purge valve 23 is made constant, and the interval time Ts1 to Ts3 of the purge valve 23 is shortened for each purge, so that the hydrogen is discharged from the dilution box 35 with a uniform amount of hydrogen. However, the hydrogen in the anode system 20 gradually decreases to a predetermined concentration.

  As described above, according to the second embodiment, the interval time of the purge valve 23 in the anode purge is determined by the system stop time (hydrogen concentration in the anode system) and the anode pressure, so that the system stop time is short. Even when the hydrogen concentration is high, the amount of discharged hydrogen is reduced when the anode pressure is low, so the interval time of the purge valve 23 can be set short. Therefore, by changing the interval time of the purge valve 23 according to the amount of hydrogen to be discharged (anode pressure), the amount of hydrogen (hydrogen concentration) can be discharged in a constant state. Can be prevented. As a result, the hydrogen dilution time (time required for hydrogen removal) in the anode purge can be shortened, the scavenging time can be shortened, and the energy required for scavenging can be reduced to the minimum necessary.

  Further, according to the second embodiment, as described with reference to FIG. 9, the hydrogen concentration in the anode system 20 decreases every time the anode purge is repeated, so that the discharge is performed by shortening the interval time of the purge valve 23. This makes it possible to make the amount of hydrogen to be constant, further reducing the dilution time and the scavenging time.

  The present invention is not limited to the above-described embodiment. For example, in this embodiment, the purge valve 23 and the air introduction valve 42 are each configured in a single configuration, but may be configured in a plurality. . In addition, the first embodiment and the second embodiment may be combined so that the valve opening time of the purge valve 23 becomes longer for each anode purge, and the interval time of the purge valve 23 becomes shorter.

It is a whole lineblock diagram showing the fuel cell system of this embodiment. It is a flowchart which shows the scavenging control of 1st Embodiment. (A) is a map showing the relationship between the system stop time and the anode system hydrogen concentration, (b) is a map showing the relationship between the anode system hydrogen concentration and the purge valve opening time, and (c) is the system stop time. And a total purge amount. It is a map which shows the relationship between the system stop time for every purge, and the valve opening time of a purge valve. It is a time chart which shows the change of the valve opening time of the purge valve in anode purge. It is a flowchart which shows the scavenging control of 2nd Embodiment. It is a map which shows the relationship between anode system hydrogen concentration and the interval time of a purge valve. It is a map which shows the relationship between the system stop time for every purge, and the valve opening time of a purge valve. It is a time chart which shows the change of interval operation of the purge valve in anode purge.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Fuel cell system 10 Fuel cell 12 Anode 13 Cathode 23 Purge valve 35 Dilution box (Fuel exhaust gas dilution means)
41 Air introduction piping (communication flow path)
42 Air introduction valve (communication valve)
51 ECU
52 Temperature sensor (status monitoring means)
a1 to a5 piping (fuel gas flow passage)
c1 to c3 piping (oxidant gas flow path)

Claims (6)

A fuel cell that generates power by a reaction between a fuel gas supplied to the anode and an oxidant gas supplied to the cathode;
A fuel gas flow passage for flowing fuel gas through the fuel cell;
An oxidant gas flow passage for flowing an oxidant gas to the cathode;
A communication flow path for communicating the fuel gas flow passage and the oxidant gas flow passage;
A communication valve for opening and closing the communication channel;
A fuel exhaust gas dilution means for diluting the fuel exhaust gas discharged from the anode with an oxidant gas and discharging it to the outside;
A purge valve for purging the fuel exhaust gas from the anode to the fuel exhaust gas dilution means;
State monitoring means for monitoring a change in state of the fuel cell after power generation is stopped;
When the state change after the power generation stop of the fuel cell becomes a predetermined condition, the previous SL oxidant gas performing a first scavenging scavenging the cathode, then, opens the communication valve and the purge valve and scavenging means for performing a second scavenging scavenging the anode Te,
An oxidant gas supply amount calculating means for obtaining a supply amount of the oxidant gas required for the first scavenging and the second scavenging, and a fuel cell system comprising :
A purge valve opening time control means for controlling the valve opening time of the purge valve,
Purge control means for opening and closing the purge valve to control purge during the first scavenging;
Fuel gas concentration predicting means for predicting the concentration of fuel gas in the fuel exhaust gas based on a system stop time until the first scavenging after power generation stop of the fuel cell;
Fuel gas discharge amount predicting means for predicting the discharge amount of the fuel gas from the anode based on the anode pressure when the state change becomes a predetermined condition after stopping the power generation of the fuel cell;
System stop time determination means for determining whether or not the system stop time is a predetermined time or more;
During the first scavenging, the purge valve opening time control means determines the opening time of the purge valve, and the fuel gas concentration predicted by the fuel gas concentration prediction means and the fuel gas discharge amount prediction means, and Based on emissions
A purge valve opening time calculating means for making the opening time of the purge valve shorter as the concentration of the fuel gas is higher;
A purge valve opening time correction means for correcting the opening time of the purge valve as a longer time as the emission amount of the fuel gas is smaller even when the concentration of the fuel gas is high ,
When the system stop time determining means determines that the system stop time is equal to or greater than a predetermined value and the concentration of the fuel gas is predicted to be low, the purge control means does not execute the purge during the first scavenging. When the system stop time determining means determines that the system stop time is not equal to or greater than a predetermined value, the purge valve open time calculating means calculates the valve opening time and the purge valve open time correcting means The fuel cell system , wherein after the valve opening time is corrected, the purge control means opens the purge valve to perform the purge during the first scavenging .   The purge valve opening time correction means sets the valve opening time for the (N + 1) th purge longer than the valve opening time for the Nth (N = 1, 2, 3,...) Purge. The fuel cell system according to claim 1. A fuel cell that generates power by a reaction between a fuel gas supplied to the anode and an oxidant gas supplied to the cathode;
A fuel gas flow passage for flowing fuel gas through the fuel cell;
An oxidant gas flow passage for flowing an oxidant gas to the cathode;
A communication flow path for communicating the fuel gas flow passage and the oxidant gas flow passage;
A communication valve for opening and closing the communication channel;
A fuel exhaust gas dilution means for diluting the fuel exhaust gas discharged from the anode with an oxidant gas and discharging it to the outside;
A purge valve for purging the fuel exhaust gas from the anode to the fuel exhaust gas dilution means;
State monitoring means for monitoring a change in state of the fuel cell after power generation is stopped;
When the state change after the power generation stop of the fuel cell becomes a predetermined condition, the previous SL oxidant gas performing a first scavenging scavenging the cathode, then, opens the communication valve and the purge valve and scavenging means for performing a second scavenging scavenging the anode Te,
An oxidant gas supply amount calculating means for obtaining a supply amount of the oxidant gas required for the first scavenging and the second scavenging, and a fuel cell system comprising:
Purge control means for opening and closing the purge valve to control purge during the first scavenging;
A purge interval control means for controlling the interval time for opening the purge valve,
Fuel gas concentration predicting means for predicting the concentration of fuel gas in the fuel exhaust gas based on a system stop time until the first scavenging after power generation stop of the fuel cell;
Fuel gas discharge amount predicting means for predicting the discharge amount of the fuel gas from the anode based on the anode pressure when the state change becomes a predetermined condition after stopping the power generation of the fuel cell;
System stop time determination means for determining whether or not the system stop time is a predetermined time or more;
The pre-listening interval time by the purge interval time control means at the time of the first scavenging, to the concentration and emissions of the fuel gas and the predicted the fuel gas concentration prediction means by the fuel gas discharge amount prediction means On the basis of,
A purge interval time calculating means for making the time longer as the concentration of the fuel gas is higher;
Purging interval time correction means for correcting as a shorter time as the amount of discharged fuel gas is smaller even when the concentration of the fuel gas is high ,
When the system stop time determining means determines that the system stop time is equal to or greater than a predetermined value and the concentration of the fuel gas is predicted to be low, the purge control means does not execute the purge during the first scavenging. When the system stop time determination means determines that the system stop time is not equal to or greater than a predetermined value, the purge interval time calculation means calculates the interval and the purge interval time correction means corrects the interval. The fuel cell system, wherein the purge control means opens the purge valve to perform the purge during the first scavenging .   4. The purge interval time correcting means sets the (N + 1) -th purge interval shorter than the N-th (N = 1, 2, 3,...) Purge interval. The fuel cell system described.   The fuel cell system according to any one of claims 1 to 4, wherein a total purge amount of the fuel gas is calculated based on the system stop time. A back pressure valve that is provided in the oxidant gas flow path downstream of the fuel cell and adjusts the pressure of the oxidant gas supplied to the cathode;
The fuel cell system according to any one of claims 1 to 5 , wherein the fuel exhaust gas diluting means is provided in the oxidant gas flow passage on the downstream side of the back pressure valve .

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