JP5188887B2 - Vegetable juice and / or fruit juice-containing container-packed beverages - Google Patents
Vegetable juice and / or fruit juice-containing container-packed beverages Download PDFInfo
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- JP5188887B2 JP5188887B2 JP2008158164A JP2008158164A JP5188887B2 JP 5188887 B2 JP5188887 B2 JP 5188887B2 JP 2008158164 A JP2008158164 A JP 2008158164A JP 2008158164 A JP2008158164 A JP 2008158164A JP 5188887 B2 JP5188887 B2 JP 5188887B2
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- Prior art keywords
- alginate
- juice
- vegetable juice
- beverage
- fruit juice
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 235000013361 beverage Nutrition 0.000 title claims description 54
- 235000015192 vegetable juice Nutrition 0.000 title claims description 50
- 235000015203 fruit juice Nutrition 0.000 title description 44
- 235000010443 alginic acid Nutrition 0.000 claims description 41
- 229920000615 alginic acid Polymers 0.000 claims description 41
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 claims description 38
- 229940072056 alginate Drugs 0.000 claims description 38
- 239000007787 solid Substances 0.000 claims description 35
- 229920002148 Gellan gum Polymers 0.000 claims description 30
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- 239000000216 gellan gum Substances 0.000 claims description 30
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 16
- 235000010413 sodium alginate Nutrition 0.000 claims description 16
- 239000000661 sodium alginate Substances 0.000 claims description 16
- 229940005550 sodium alginate Drugs 0.000 claims description 16
- 239000000047 product Substances 0.000 description 17
- 235000013325 dietary fiber Nutrition 0.000 description 16
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- 229920000161 Locust bean gum Polymers 0.000 description 2
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- 244000062780 Petroselinum sativum Species 0.000 description 2
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- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
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- KPGABFJTMYCRHJ-YZOKENDUSA-N ammonium alginate Chemical compound [NH4+].[NH4+].O1[C@@H](C([O-])=O)[C@@H](OC)[C@H](O)[C@H](O)[C@@H]1O[C@@H]1[C@@H](C([O-])=O)O[C@@H](O)[C@@H](O)[C@H]1O KPGABFJTMYCRHJ-YZOKENDUSA-N 0.000 description 2
- 235000010410 calcium alginate Nutrition 0.000 description 2
- 239000000648 calcium alginate Substances 0.000 description 2
- 229960002681 calcium alginate Drugs 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- OKHHGHGGPDJQHR-YMOPUZKJSA-L calcium;(2s,3s,4s,5s,6r)-6-[(2r,3s,4r,5s,6r)-2-carboxy-6-[(2r,3s,4r,5s,6r)-2-carboxylato-4,5,6-trihydroxyoxan-3-yl]oxy-4,5-dihydroxyoxan-3-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylate Chemical compound [Ca+2].O[C@@H]1[C@H](O)[C@H](O)O[C@@H](C([O-])=O)[C@H]1O[C@H]1[C@@H](O)[C@@H](O)[C@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@H](O2)C([O-])=O)O)[C@H](C(O)=O)O1 OKHHGHGGPDJQHR-YMOPUZKJSA-L 0.000 description 2
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Landscapes
- Non-Alcoholic Beverages (AREA)
Description
本発明は、野菜汁及び/又は果汁含有容器詰飲料に関する。 The present invention relates to a vegetable juice and / or fruit juice-containing container-packed beverage.
健康意識の高まる中、近年、日本人に不足がちな食物繊維を効率的に摂取する要望が高くなっており、多量の食物繊維を無理なく摂取できる形態の一つである飲料商品の要望が高まっている。その中でも特に多量に配合しても飲みやすい食物繊維が好まれており、そのような食物繊維としては酸性多糖系水溶性食物繊維が知られている。
例えば、特許文献1には酸性多糖系水溶性食物繊維としてアルギン酸塩を配合した野菜及び/又は果実飲料飲料組成物が開示されており、野菜及び/又は果実由来の固形物を調節することにより飲料の青臭みや加熱殺菌処理後の加熱臭を低減でき、飲みやすさを向上させることができる旨の記載がある(特許文献1参照)。
In recent years, as health consciousness has increased, there has been an increasing demand for efficient intake of dietary fiber, which Japanese people tend to lack, and there has been an increasing demand for beverage products that are one of the forms in which large amounts of dietary fiber can be consumed without difficulty. ing. Among them, dietary fibers that are easy to drink even when blended in large quantities are preferred, and acidic polysaccharide water-soluble dietary fibers are known as such dietary fibers.
For example, Patent Document 1 discloses a vegetable and / or fruit beverage beverage composition in which an alginate is blended as an acidic polysaccharide-based water-soluble dietary fiber, and beverages are prepared by adjusting solids derived from vegetables and / or fruits. There is a description that it is possible to reduce the blue odor and the heat odor after the heat sterilization treatment and to improve the ease of drinking (see Patent Document 1).
一方、アルギン酸塩は産業排水や家庭用排水の清澄化のための凝集剤として利用されることが知られている(非特許文献1参照)。このため、アルギン酸塩を野菜汁や果汁に多量に添加すると野菜汁や果汁由来の不溶性固形分の一部が凝集することにより、沈殿が生じてしまうという問題があった。 On the other hand, alginate is known to be used as a flocculant for clarification of industrial wastewater and household wastewater (see Non-Patent Document 1). For this reason, when alginate was added in a large amount to vegetable juice or fruit juice, there was a problem that a part of insoluble solids derived from vegetable juice or fruit juice aggregated to cause precipitation.
また一方、ジェランガムは沈殿を抑制する分散剤として飲料において利用されている(非特許文献2参照)。
本発明は、アルギン酸塩を含有し、且つ分離・沈殿生成の抑制された野菜及び/又は果実飲料飲料を提供することにある。 It is an object of the present invention to provide a vegetable and / or fruit beverage drink containing an alginate and having suppressed separation / precipitation formation.
かかる課題に対し本発明者らが検討を行ったところ、高濃度のアルギン酸塩含有の野菜及び/又は果実飲料において生成される凝集物質は不溶性固形分由来であるにもかかわらず、意外にも野菜汁及び/又は果汁由来の可溶性固形分のブリックス値を一定の範囲に調整すると、少量のジェランガムの使用においても沈殿の生成を効果的に抑制できることを見出した。 As a result of studies by the present inventors on such problems, the agglomerated substances produced in vegetables and / or fruit drinks containing a high concentration of alginate are surprisingly vegetables despite being derived from insoluble solids. It has been found that when the Brix value of soluble solids derived from juice and / or fruit juice is adjusted to a certain range, the formation of precipitates can be effectively suppressed even when a small amount of gellan gum is used.
すなわち、本発明は、(A)アルギン酸塩含有量がアルギン酸ナトリウム換算で0.9〜4.0質量%、(B)飲料の野菜汁及び/又は果汁由来の可溶性固形分のブリックス値が0.5〜2.5、及び(C)ジェランガム含有量が70〜200質量ppmである野菜汁及び/又は果汁含有容器詰飲料を提供するものである。 That is, in the present invention, (A) the alginate content is 0.9 to 4.0% by mass in terms of sodium alginate, and (B) the Brix value of the soluble solid content derived from vegetable juice and / or fruit juice of the beverage is 0.00. The vegetable juice and / or fruit juice containing container-packed drink whose 5-2.5 and (C) gellan gum content is 70-200 mass ppm are provided.
本発明の野菜汁及び/又は果汁含有容器詰飲料によれば、アルギン酸塩を高濃度に含有できるので、野菜汁及び/又は果汁由来の固形物を少なくし、飲み易くすることができる。アルギン酸塩を高濃度に含有しているにもかかわらず、保存中に沈殿生成が抑制され続けるため、透明容器に充填されても見た目の良好さが維持される。しかも、飲料中のジェランガムの配合量も少なくすることができ、コスト面等で有利である。
このような飲料であれば、日ごろ日本人に不足がちな食物繊維を、多量のアルギン酸塩を含有した飲料として手軽に摂取可能である。
According to the vegetable juice and / or fruit juice-containing container-packed beverage of the present invention, since the alginate can be contained at a high concentration, the solid matter derived from the vegetable juice and / or the fruit juice can be reduced and can be easily taken. Although the alginate is contained at a high concentration, the formation of precipitates continues to be suppressed during storage, so that the appearance is maintained even when filled in a transparent container. In addition, the amount of gellan gum in the beverage can be reduced, which is advantageous in terms of cost.
If it is such a drink, the dietary fiber which is apt to be deficient for Japanese people can be easily ingested as a drink containing a large amount of alginate.
なお、アルギン酸塩を多量に含有するために、整腸効果や便通改善効果、コレステロール低下作用、血圧上昇抑制等の生理的効果が期待できる。 In addition, since it contains a large amount of alginate, physiological effects such as intestinal regulation effect, bowel movement improving effect, cholesterol lowering effect, blood pressure increase suppression and the like can be expected.
本発明の野菜汁及び/又は果汁含有容器詰飲料(以下、単に「飲料」ともいう。)中の(A)アルギン酸塩含有量は、アルギン酸ナトリウム換算で0.9〜4.0質量%である。なお、この濃度範囲は、アルギン酸塩を1回あたり4g摂取する容器詰飲料を想定した場合に、その飲料の容量は約100mL〜約450mLとなり、多量の食物繊維摂取という要望にも対応するものである。
アルギン酸塩の風味を飲料として適切なものとする点、又は粘度を維持する点から、飲料中のアルギン酸塩の含有量は3.6質量%以下であることが好ましく、3質量%以下がより好ましく、2.7質量%以下がさらに好ましく、2.6質量%以下が特に好ましい。また、アルギン酸塩を少ない回数で十分に摂取可能な飲料とする点から、1.3質量%以上が好ましく、1.4質量%以上がより好ましく、1.6質量%以上がさらに好ましい。
なお、本発明の飲料に含まれるアルギン酸塩量の測定方法は後述の(アルギン酸塩の定量法及び重量平均分子量の測定法)に示す。
The (A) alginate content in the vegetable juice and / or fruit juice-containing container-packed beverage of the present invention (hereinafter also simply referred to as “beverage”) is 0.9 to 4.0% by mass in terms of sodium alginate. . In addition, this concentration range is about 100 mL to about 450 mL when a container-packed beverage that ingests 4 g of alginate is taken at a time, and corresponds to the demand for intake of a large amount of dietary fiber. is there.
The content of alginate in the beverage is preferably 3.6% by mass or less, more preferably 3% by mass or less, from the viewpoint of making the alginate flavor suitable as a beverage or maintaining the viscosity. It is more preferably 2.7% by mass or less, and particularly preferably 2.6% by mass or less. Moreover, 1.3 mass% or more is preferable, 1.4 mass% or more is more preferable, and 1.6 mass% or more is further more preferable from the point which makes it a drink which can fully take in alginate.
In addition, the measuring method of the amount of alginate contained in the drink of this invention is shown to the below-mentioned (quantitative method of alginate and the measuring method of a weight average molecular weight).
本発明の飲料に含有される(A)アルギン酸塩としては、例えば、アルギン酸ナトリウム、アルギン酸カリウム等のアルギン酸アルカリ金属塩;低分子化して可溶性を強化したアルギン酸カルシウムやアルギン酸マグネシウム等のアルギン酸アルカリ土類金属塩;アルギン酸アンモニウム等のアルギン酸アンモニウム塩等を使用することができる。また、これ以外に上記塩を2種以上組み合わせたアルギン酸塩を使用してもよい。
なお、本発明の飲料に適したアルギン酸ナトリウムとしては、例えば、褐藻類等から抽出・分離精製したもの、低分子化されたアルギン酸ナトリウム(以後、これらを低分子化アルギン酸ナトリウムという)である、製品名:ソルギン((株)カイゲン)や製品名:キミカアルギンSKAT−ULV((株)キミカ)等が挙げられる。また、アルギン酸カリウムとしては、例えば、低分子化アルギン酸ナトリウムに対してカリウム置換処理したもの(以後、これらを低分子化アルギン酸カリウムという)等が挙げられ、他のアルギン酸塩も同様に塩置換処理で得ることができる。ただし、アルギン酸ナトリウム、アルギン酸カリウム等は、これらの処理が施されたものに限定されるものではない。
Examples of the (A) alginate contained in the beverage of the present invention include, for example, alkali metal alginates such as sodium alginate and potassium alginate; Salt; ammonium alginate such as ammonium alginate and the like can be used. In addition, an alginate in which two or more of the above salts are combined may be used.
Examples of the sodium alginate suitable for the beverage of the present invention include, for example, those extracted / separated and purified from brown algae, etc., low molecular weight sodium alginate (hereinafter referred to as low molecular weight sodium alginate), Name: Solgin (Kaigen Co., Ltd.), Product name: Kimika Argin SKAT-ULV (Kimika Co., Ltd.) and the like. Examples of potassium alginate include those obtained by subjecting low molecular weight sodium alginate to potassium substitution treatment (hereinafter referred to as low molecular weight potassium alginate) and the like, and other alginates are similarly subjected to salt substitution treatment. Can be obtained. However, sodium alginate, potassium alginate and the like are not limited to those subjected to these treatments.
また、本発明の飲料に含有される(A)アルギン酸塩としては、飲料の粘度を低く抑え飲みやすいものとするために、低分子量のものが好ましく、GPC測定による重量平均分子量が1万〜20万、好ましくは2万〜10万、さらに好ましくは3万〜7万、特に好ましくは4万〜6万のものが良い。なお、アルギン酸塩の重量平均分子量測定方法は後述の(アルギン酸塩の定量法及び重量平均分子量の測定法)に示す。 In addition, the (A) alginate contained in the beverage of the present invention preferably has a low molecular weight in order to keep the beverage viscosity low and easy to drink, and has a weight average molecular weight of 10,000 to 20 by GPC measurement. 10,000, preferably 20,000 to 100,000, more preferably 30,000 to 70,000, particularly preferably 40,000 to 60,000. In addition, the weight average molecular weight measuring method of an alginate is shown in the later-mentioned (quantitative method of alginate and measuring method of a weight average molecular weight).
本発明の飲料は、(B)野菜汁及び/又は果汁由来の可溶性固形分のブリックス値(品温:20℃)(以下、単に「野菜汁及び/又は果汁由来のブリックス値」ともいう。)を0.5〜2.5とする。(B)野菜汁及び/又は果汁由来のブリックス値を2.5以下とすることで、ジェランガムの添加量を低減した条件においても沈殿の生成を抑制でき、保存上好ましい。また、(B)野菜汁及び/又は果汁由来のブリックス値を0.5以上とすることで飲料の風味を十分に高めることができる。よって、(B)野菜汁及び/又は果汁由来のブリックス値は、0.6〜2.4が好ましく、さらに0.7〜2.4が好ましい。この飲料の野菜汁及び/又は果汁由来の可溶性固形分のブリックス値は、野菜汁及び/又は果汁のブリックス値に基づいて調整することができる。
なお、ブリックス値(ブリックス度)は、糖用屈折計を用いて20℃において測定した値を用いる。
The beverage of the present invention has (B) a brix value of soluble solids derived from vegetable juice and / or fruit juice (product temperature: 20 ° C.) (hereinafter also simply referred to as “brix value derived from vegetable juice and / or fruit juice”). Is set to 0.5 to 2.5. (B) By setting the Brix value derived from vegetable juice and / or fruit juice to 2.5 or less, precipitation can be suppressed even under conditions where the amount of gellan gum added is reduced, which is preferable in terms of storage. Moreover, the flavor of a drink can fully be heightened by making the Brix value derived from (B) vegetable juice and / or fruit juice 0.5 or more. Accordingly, (B) the Brix value derived from vegetable juice and / or fruit juice is preferably 0.6 to 2.4, more preferably 0.7 to 2.4. The brix value of the soluble solids derived from vegetable juice and / or fruit juice of this beverage can be adjusted based on the brix value of vegetable juice and / or fruit juice.
In addition, the value measured at 20 degreeC using the refractometer for sugars is used for a Brix value (Brix degree).
本発明の飲料中の(C)ジェランガム含有量は、70〜200質量ppm(以下、単に「ppm」という。)である。ブリックス値を調整することにより、160ppm以下、さらに140ppm以下、100ppm以下とすることができる。また、70ppm以上とすることで、ジェランガムの分散力をアルギン酸塩による凝集力よりも高めることができ、沈澱の抑制に効果的である。長期の保存安定性を考慮するとジェランガムの含有量は80ppm以上が好ましく、さらに90ppm以上が好ましい。
なお、本発明の飲料に含まれるジェランガム量は、AOAC公定法であるAOAC991.43で測定することができる。
The (C) gellan gum content in the beverage of the present invention is 70 to 200 ppm by mass (hereinafter simply referred to as “ppm”). By adjusting the Brix value, it can be 160 ppm or less, 140 ppm or less, or 100 ppm or less. Moreover, by setting it as 70 ppm or more, the dispersibility of gellan gum can be raised rather than the cohesion force by alginate, and it is effective for suppression of precipitation. In view of long-term storage stability, the gellan gum content is preferably 80 ppm or more, more preferably 90 ppm or more.
In addition, the amount of gellan gum contained in the beverage of the present invention can be measured by AOAC 991.43 which is an official AOAC method.
本発明の飲料に含有される(C)ジェランガムとしては、ネイティブジェランガムと脱アシルジェランガムが挙げられるが、低添加量でシュードプラスチック性を示すネイティブジェランガムが好ましく、例えば、微生物Sphingomonas elodeaが菌体外に産出したもの、製品名:ケルコゲル(登録商標)LT100,HM,HT(三栄源エフ・エフ・アイ(株))等を使用することができる。ただし、シュードプラスチック性を示すネイティブジェランガムであれば、上記製品に限定されるものではない。 Examples of the gellan gum (C) contained in the beverage of the present invention include native gellan gum and deacylated gellan gum. Native gellan gum exhibiting pseudoplastic properties with a low addition amount is preferable. For example, the microorganism Sphingomonas elodea is present outside the cells. Produced product, product name: Kelcogel (registered trademark) LT100, HM, HT (San-Eigen FFI Co., Ltd.) can be used. However, it is not limited to the above products as long as it is a native gellan gum exhibiting pseudo plastic properties.
また、本発明の飲料に用いられる(C)ジェランガムは、20℃で測定した粘度が、0.15質量%において1〜100mPa・sのものが好ましく、10〜90mPa・sのものがより好ましく、20〜80mPa・sのものがさらに好ましい。なお、ジェランガムの粘度測定方法は、後述の(粘度の測定法)に準じればよい。 The gellan gum (C) used in the beverage of the present invention has a viscosity measured at 20 ° C. of preferably 0.1 to 100 mPa · s, more preferably 10 to 90 mPa · s at 0.15% by mass, The thing of 20-80 mPa * s is further more preferable. In addition, the viscosity measuring method of gellan gum should just follow the below-mentioned (measuring method of a viscosity).
また、本発明の飲料に含有される野菜汁及び/又は果汁は、野菜汁として野菜の搾汁、果汁として果物の搾汁からなる。野菜の搾汁に使用される野菜としては、トマト、ニンジン、ホウレンソウ、キャベツ、メキャベツ、ブロッコリー、カリフラワー、セロリ、レタス、パセリ、クレソン、ケール、かぼちゃ、赤ピーマン、ピーマン、ダイコン等が挙げられるが、本発明の野菜の搾汁としては特にトマト、ニンジン、ホウレンソウ、パセリ、セロリ、キャベツのものが好ましい。また野菜の搾汁としてアロエの搾汁も使用できる。これらの野菜汁は単独で使用しても良く、複数を混合して使用しても良い。 Moreover, the vegetable juice and / or fruit juice contained in the drink of this invention consist of vegetable juice as vegetable juice, and fruit juice as fruit juice. Vegetables used for vegetable juice include tomatoes, carrots, spinach, cabbage, me cabbage, broccoli, cauliflower, celery, lettuce, parsley, watercress, kale, pumpkin, red bell pepper, bell pepper, radish, etc. As the vegetable juice of the present invention, tomato, carrot, spinach, parsley, celery and cabbage are particularly preferred. Aloe juice can also be used as vegetable juice. These vegetable juices may be used alone or in combination.
また、果物の搾汁に使用される果物としては、レモン、りんご、みかん、オレンジ、グレープフルーツ、スウィーティ、もも、メロン、スイカ、ウメ、キウィ、グアバ、プルーン等が挙げられるが、本発明の果物の搾汁としては特にレモン、りんご、みかん、オレンジ、グレープフルーツ、もも等が好ましい。これらの果汁は単独で使用しても良く、複数を混合して使用しても良い。 Examples of fruits used for fruit juice include lemons, apples, tangerines, oranges, grapefruits, sweeties, peaches, melons, watermelons, plums, kiwis, guava, prunes and the like. As the squeezed juice, lemon, apple, tangerine, orange, grapefruit, thigh and the like are particularly preferable. These fruit juices may be used alone or in combination.
本発明の野菜汁及び/又は果汁含有容器詰飲料は、(D)野菜汁及び/又は果汁由来の不溶性固形物(以下、単に「固形物」という。)を含むことが好ましい。
野菜汁及び/又は果汁由来の固形物とは、後述の(固形物量測定法)によって含水状態の体積として測定されたものであり、野菜汁及び/又は果汁由来の成分が他の配合成分等と相互作用したものを含む。すなわち、不溶性セルロースやヘミセルロース、ペクチン、たんぱく質等の複合体を含有するものである。この野菜汁及び/又は果汁由来の固形物の存在は野菜汁及び/又は果汁飲料の食感、特にパルプ感に影響する。野菜汁及び/又は果汁由来の固形物量が0.01体積%以上であると野菜汁及び/又は果汁飲料は食感が均一とならず天然感や本格感の点で優れたものとなり、固形物量が8体積%以下であると粘性が高くなりすぎず飲用時に抵抗感が少なく飲み易いものとなる。
すなわち、飲用時の飲み易さの点から、野菜汁及び/又は果汁由来の固形物の量は0.01〜8体積%であることが好ましく、食感上、より好ましくは0.02〜6体積%、さらに好ましくは、0.05〜4.5体積%である。
The vegetable juice and / or fruit juice-containing container-packed beverage of the present invention preferably includes (D) an insoluble solid derived from vegetable juice and / or fruit juice (hereinafter simply referred to as “solid”).
The vegetable juice and / or fruit juice-derived solid matter is measured as a water-containing volume by the below-described (solid amount measurement method), and the component derived from the vegetable juice and / or fruit juice is other compounding ingredients, etc. Includes those that interact. That is, it contains a complex such as insoluble cellulose, hemicellulose, pectin, or protein. The presence of the solid matter derived from the vegetable juice and / or fruit juice affects the texture of the vegetable juice and / or the fruit juice beverage, particularly the pulp feeling. If the amount of solids derived from vegetable juice and / or fruit juice is 0.01% by volume or more, the vegetable juice and / or fruit juice beverage will not have a uniform texture and will be excellent in terms of naturalness and authenticity. When the content is 8% by volume or less, the viscosity does not become excessively high, and there is little resistance when drinking and it is easy to drink.
That is, from the viewpoint of ease of drinking during drinking, the amount of solids derived from vegetable juice and / or fruit juice is preferably 0.01 to 8% by volume, and more preferably 0.02 to 6 in terms of texture. % By volume, more preferably 0.05 to 4.5% by volume.
当該野菜汁及び/又は果汁由来の固形物量は、遠心分離やろ過等の固液分離操作による野菜汁及び/又は果汁由来の固形物の一部除去・添加・濃縮等の操作により調整することで上記好ましい範囲に調整しても良い。 The amount of solids derived from vegetable juice and / or fruit juice is adjusted by operations such as partial removal, addition and concentration of vegetable juice and / or fruit juice-derived solids by solid-liquid separation operations such as centrifugation and filtration. You may adjust to the said preferable range.
本発明の野菜汁及び/又は果汁含有容器詰飲料の水分含有量は75質量%以上が好ましく、さらに好ましくは85質量%以上、よりさらに好ましくは90質量%以上が飲料として好ましい。なお、水分量の測定法は、例えば、常圧にて、105℃、2時間の加熱乾燥法によって測定することができる。 The water content of the vegetable juice and / or fruit juice-containing container-packed beverage of the present invention is preferably 75% by mass or more, more preferably 85% by mass or more, and still more preferably 90% by mass or more. In addition, the measuring method of a moisture content can be measured with the heat drying method of 105 degreeC and 2 hours at a normal pressure, for example.
本発明の野菜汁及び/又は果汁含有容器詰飲料のpH(品温:20℃)は、保存安定性及び飲み易さの点からpH3.5〜5、好ましくは3.7〜4.6、さらに好ましくは3.8〜4.5、もっとさらに好ましくは3.9〜4.3が良い。pHが上記範囲内であると保存安定性及び飲み易さの点で好ましい。
pHの調整は、通常、本発明の野菜汁及び/又は果汁含有容器詰飲料の製造工程において加熱殺菌を施す前に行う。
pHの調整には、野菜汁や果汁由来の有機酸に加え、有機酸類、有機酸塩類、無機酸類、無機酸塩類、無機塩類、pH調整剤等の添加剤を単独、あるいは併用して用いることができる。このとき、これらの添加剤を直接、又は適当な濃度に希釈した水溶液として適量加えて調整する。このときpHメーター等によりpHを確認しながら加えても良い。これらの添加剤には、例えば、アジピン酸、クエン酸、グルコン酸、コハク酸、酢酸、酒石酸、乳酸、フマル酸、リンゴ酸、アスコルビン酸又はそれらの塩等が挙げられる。加熱殺菌の前後でpHが変化する場合は、予め変化分を考慮して加熱殺菌前のpHを調整すると良い。
The pH (product temperature: 20 ° C.) of the vegetable juice and / or fruit juice-containing container beverage of the present invention is pH 3.5 to 5, preferably 3.7 to 4.6, from the viewpoint of storage stability and ease of drinking. More preferably, it is 3.8 to 4.5, and still more preferably 3.9 to 4.3. A pH within the above range is preferable from the viewpoint of storage stability and ease of drinking.
Adjustment of pH is normally performed before heat-sterilizing in the manufacturing process of the vegetable juice and / or fruit juice containing container-packed drink of this invention.
For adjusting pH, in addition to organic acids derived from vegetable juice and fruit juice, additives such as organic acids, organic acid salts, inorganic acids, inorganic acid salts, inorganic salts, pH adjusters, etc., may be used alone or in combination. Can do. At this time, these additives are adjusted by adding appropriate amounts directly or as an aqueous solution diluted to an appropriate concentration. At this time, you may add, confirming pH with a pH meter etc. Examples of these additives include adipic acid, citric acid, gluconic acid, succinic acid, acetic acid, tartaric acid, lactic acid, fumaric acid, malic acid, ascorbic acid, and salts thereof. When the pH changes before and after heat sterilization, the pH before heat sterilization may be adjusted in consideration of the change.
その他、本発明の野菜汁及び/又は果汁含有容器詰飲料には、糖質、ビタミン類、各種エステル類、色素類、酸化防止剤、香料、甘味料、乳化剤、保存料、調味料、品質安定剤等の食品添加物を単独、あるいは併用してさらに適宜配合しても良い。 In addition, the vegetable juice and / or fruit juice-containing container-packed beverages of the present invention include sugars, vitamins, various esters, pigments, antioxidants, fragrances, sweeteners, emulsifiers, preservatives, seasonings, and quality stability. You may mix | blend suitably food additives, such as an agent, individually or in combination.
本発明の野菜汁及び/又は果汁含有容器詰飲料には、さらに食物繊維を補充する目的で上記以外の食物繊維を配合することができる。他の食物繊維としては、(E)水溶性中性多糖系食物繊維、すなわち具体的には、難消化性デキストリン、グアーガム、グアーガム分解物、プルラン、水溶性コーンファイバー、ヘミセルロース、低分子ヘミセルロース、大豆食物繊維、ローカストビーンガム、コンニャクマンナン、ガードラン、ポリデキストロース、寒天等が挙げられる。このうち、グアーガム分解物、難消化性デキストリン、ポリデキストロース等が飲料全体の風味に影響しないため好ましい。 The vegetable juice and / or fruit juice-containing container-packed beverage of the present invention may further contain dietary fibers other than those described above for the purpose of supplementing dietary fiber. Other dietary fibers include (E) water-soluble neutral polysaccharide dietary fiber, specifically, indigestible dextrin, guar gum, guar gum degradation product, pullulan, water-soluble corn fiber, hemicellulose, low molecular weight hemicellulose, soybean Examples thereof include dietary fiber, locust bean gum, konjac mannan, guard run, polydextrose, and agar. Of these, guar gum degradation products, indigestible dextrin, polydextrose and the like are preferable because they do not affect the flavor of the entire beverage.
これらの他の食物繊維の含有量は、飲料の粘度を低く抑えて飲みやすくするという点、更に、沈殿の生成に影響を及ぼさないという点で、野菜汁及び/又は果汁容器詰飲料中に、0.2〜8質量%、さらに0.6〜4質量%、特に1.2〜3質量%が好ましい。 The content of these other dietary fibers keeps the viscosity of the beverage low and makes it easy to drink, and further does not affect the formation of precipitates, so in vegetable juice and / or fruit juice packaged beverages, 0.2-8 mass%, 0.6-4 mass%, especially 1.2-3 mass% are preferable.
なお、本発明に用いられる食物繊維は、AOAC公定法であるAOAC991.43やAOAC2001.03、及びこれらに準拠した方法にて定量される。例えば、グアーガム、グアーガム分解物、プルラン、水溶性コーンファイバー、ヘミセルロース、低分子ヘミセルロース、大豆食物繊維、ローカストビーンガム、コンニャクマンナン、ガードランは、AOAC991.43で、難消化性デキストリン、ポリデキストロースは、AOAC2001.03で測定することが可能である。 In addition, the dietary fiber used for this invention is quantified by AOAC991.43 and AOAC2001.03 which are AOAC official methods, and the method based on these. For example, guar gum, guar gum degradation product, pullulan, water-soluble corn fiber, hemicellulose, low molecular weight hemicellulose, soy dietary fiber, locust bean gum, konjac mannan, guard run are AOAC 991.43, and indigestible dextrin, polydextrose is AOAC2001 .03 can be measured.
本発明の飲料の粘度(品温:20℃)は、飲み易さの点から好ましくは400mPa・s以下であり、より好ましくは200mPa・s以下、さらに好ましくは100mPa・s以下、さらに好ましくは50mPa・s以下、さらに好ましくは25mPa・s以下、特に好ましくは11mPa・s以下、ことさらに好ましくは10mPa・s以下である。また、本発明の飲料の粘度は野菜汁や果汁の官能的本物感のために2mPa・s以上が好ましい。 The viscosity (product temperature: 20 ° C.) of the beverage of the present invention is preferably 400 mPa · s or less, more preferably 200 mPa · s or less, still more preferably 100 mPa · s or less, further preferably 50 mPa from the viewpoint of ease of drinking. S or less, more preferably 25 mPa · s or less, particularly preferably 11 mPa · s or less, and even more preferably 10 mPa · s or less. Moreover, the viscosity of the beverage of the present invention is preferably 2 mPa · s or more for the sensory real feeling of vegetable juice and fruit juice.
本発明の野菜汁及び/又は果汁含有容器詰飲料に使用される容器は、一般の飲料と同様にポリエチレンテレフタレートを主成分とする成形容器(いわゆるPETボトル)、金属缶、金属箔やプラスチックフィルムと複合された紙容器、ガラス瓶、金属や紙製の蓋が複合された樹脂製容器、チューブ状の樹脂製容器等、通常の形態で提供することができる。特に、PETボトル、ガラス瓶、金属や紙製の蓋が複合された樹脂製容器、チューブ状の樹脂製容器等の透明容器では、沈殿生成がわずかに起こっただけでも商品陳列時にはっきりと見て取れるため、商品の外観が特に問題となる。本発明はこれら透明性を有する容器詰飲料における上記外観上の課題を解決するものである。なお、着色された酸素透過性の容器であっても、透明性を有する容器であれば上記課題が生じる。 The container used for the vegetable juice and / or fruit juice-containing container-packed beverage of the present invention is a molded container (so-called PET bottle) mainly composed of polyethylene terephthalate, a metal can, a metal foil, a plastic film, and the like, as with a general beverage. A composite paper container, a glass bottle, a resin container in which a metal or paper lid is combined, a tubular resin container, or the like can be provided in a normal form. In particular, in transparent containers such as PET bottles, glass bottles, resin containers combined with metal and paper lids, tube-shaped resin containers, etc., even if slight precipitation occurs, it can be clearly seen at the time of product display, The appearance of the product is particularly problematic. This invention solves the said subject on the external appearance in the container-packed drink which has these transparency. In addition, even if it is a colored oxygen permeable container, the said subject will arise if it is a container which has transparency.
本発明の野菜汁及び/又は果汁含有容器詰飲料は適宜殺菌が施され、例えば、金属缶のように容器に充填後、加熱殺菌できる場合にあっては食品衛生法に定められた殺菌条件で製造される。またPETボトル、紙容器のようにレトルト殺菌できないものについては、あらかじめ上記と同等の殺菌条件、例えばプレート式熱交換器等で高温短時間殺菌後、一定の温度迄冷却して容器に充填する等の方法が採用される。その際、無菌下で容器に充填してもよい。また無菌下で充填された容器に別の成分を無菌下で後から充填してもよい。さらに、酸性下で加熱殺菌後、無菌下でpHを中性に戻すことや、中性下で加熱殺菌後、無菌下でpHを酸性に戻す等の操作も可能である。 The vegetable juice and / or fruit juice-containing container-packed beverages of the present invention are appropriately sterilized. For example, in the case where heat sterilization can be performed after filling the container like a metal can, the sterilization conditions defined in the Food Sanitation Law Manufactured. For those that cannot be sterilized by retort, such as PET bottles and paper containers, sterilize under the same conditions as above, for example, sterilize at high temperature and short time in a plate heat exchanger, etc. The method is adopted. At that time, the container may be filled under aseptic conditions. Further, another component may be filled later under aseptic conditions into a container filled under aseptic conditions. Furthermore, after sterilization by heating under acidic conditions, the pH may be returned to neutrality under aseptic conditions, or after sterilization by heating under neutral conditions, the pH may be returned to acidic conditions under aseptic conditions.
固形物量、アルギン酸塩量・重量平均分子量、ジェランガム量、ブリックス値、飲料のpH・粘度についての測定法を以下1)〜6)に記す。
1)(固形物量測定法)
固形物量は日本農林規格検査法(日本果汁協会監修:最新果汁・果実飲料事典566頁から575頁,出版:朝倉書店に記載)それに準じた方法により測定される。
試料を固形物測定用遠心沈殿管にとり、遠心分離機で3000回転数を示してから正確に10分間遠心する。上清を5mL抜き取り、蒸留水を5mL加えて、遠心分離機で3000回転数を示してから正確に10分間遠心する。さらに、上清を5mL抜き取り、蒸留水を5mL加えて同様に、遠心分離機で3000回転数を示してから正確に10分間遠心する。操作は回転半径14.5cmの遠心分離機を用いて20℃で行い自然停止してから直ちに沈殿の平均した上端までの容積を固形物量とする。なお、固形物が少量で、固形物測定用遠心沈殿管の最小目盛り以下となる場合には、予め固形物測定用遠心沈殿管に水をマイクロピペット等を用いて正確に測りとり、上端に印をつけることにより目盛りの代わりとする等の方法を取って対応すると良い。
Measurement methods for the amount of solid matter, the amount of alginate / weight average molecular weight, the amount of gellan gum, the Brix value, and the pH / viscosity of beverages are described in 1) to 6) below.
1) (Solid matter measurement method)
The amount of solids is measured by a method according to the Japanese Agricultural Standards Inspection Method (supervised by the Japan Juice Association: described in pages 566 to 575 of the latest fruit juice and fruit beverage encyclopedia, published by Asakura Shoten).
Take the sample in a centrifugal sedimentation tube for measuring solids, and after centrifuging at 3000 rpm, centrifuge for exactly 10 minutes. Remove 5 mL of the supernatant, add 5 mL of distilled water, and after centrifuging at 3000 rpm, centrifuge for exactly 10 minutes. Further, 5 mL of the supernatant is extracted, 5 mL of distilled water is added, and similarly, after centrifuging at 3000 rpm, the mixture is accurately centrifuged for 10 minutes. The operation is carried out at 20 ° C. using a centrifuge with a radius of rotation of 14.5 cm, and the volume from the spontaneous stop to the average upper end of precipitation is taken as the amount of solid matter. If the amount of solids is small and falls below the minimum scale of the solids measurement centrifugal sedimentation tube, accurately measure the water in the solids measurement centrifugal sedimentation tube in advance using a micropipette, etc. It is better to take measures such as substituting the scale by adding
2)(アルギン酸塩の定量及び重量平均分子量の測定)
2)1 前処理(HPLC用分析試料の調製)
2)1−1 アルギン酸カルシウム沈殿の生成
ビーカーに、被験試料2gを加える。さらに水35mLを加えて均一になるように攪拌する。渦動攪拌器により適宜攪拌しながら、2mol/L塩化カルシウム水溶液1.5mLを5〜10分かけて徐々に滴下した。壁面に付着した析出物を流し落としながら水約5mLを加え、その後pHが11以上となるように1mol/L水酸化ナトリウム溶液を加える。ビーカー内の溶液をよく分散させて容量50mLのメスフラスコに移しかえ、ビーカー内に付着した析出物を水で流し落として全量50mLに定容する。共栓をした後、この溶液を渦動攪拌器により20秒攪拌し、その後20分室温に放置する(溶液A)。
2) (Quantification of alginate and measurement of weight average molecular weight)
2) 1 Pretreatment (Preparation of analytical sample for HPLC)
2) 1-1 Formation of calcium alginate precipitate 2 g of a test sample is added to a beaker. Further, 35 mL of water is added and stirred uniformly. While appropriately stirring with a vortex stirrer, 1.5 mL of 2 mol / L calcium chloride aqueous solution was gradually added dropwise over 5 to 10 minutes. About 5 mL of water is added while pouring off deposits adhering to the wall surface, and then a 1 mol / L sodium hydroxide solution is added so that the pH becomes 11 or higher. The solution in the beaker is well dispersed and transferred to a volumetric flask having a volume of 50 mL, and the deposit adhering to the beaker is washed away with water to make a total volume of 50 mL. After stoppering, the solution is stirred with a vortex stirrer for 20 seconds and then left at room temperature for 20 minutes (solution A).
2)1−2 アルギン酸カルシウム沈殿の回収
直径25mmのメンブランフィルタをメンブランフィルタカートリッジに装着し、さらに5mLのシリンジを接続する。このシリンジ内に、よく分散させた溶液A5mLをホールピペットで入れる。装着したシリンジのピストンを押し、内溶液をメンブランフィルタでろ過する。その後、水酸化ナトリウムでpH11.3とした40mmol/L塩化カルシウム水溶液約3mLで、ホールピペットとシリンジ内の付着物を同一シリンジ内へ流し落とし、メンブランフィルタでろ過する。さらにこの洗浄動作をもう一度繰り返す。
2) 1-2 Collection of calcium alginate precipitate A membrane filter with a diameter of 25 mm is attached to the membrane filter cartridge, and a 5 mL syringe is connected. A well-dispersed solution A (5 mL) is put into the syringe with a whole pipette. The piston of the attached syringe is pushed, and the inner solution is filtered with a membrane filter. After that, about 3 mL of 40 mmol / L calcium chloride aqueous solution adjusted to pH 11.3 with sodium hydroxide is used, and the deposits in the whole pipette and syringe are poured into the same syringe and filtered through a membrane filter. This cleaning operation is repeated once more.
2)1−3 アルギン酸ナトリウムへの塩交換と回収
上記操作で得られたメンブランフィルタカートリッジを解体し、メンブランフィルタとパッキンをとり出し、ビーカーに入れる。水4.8mLでメンブランフィルタカートリッジの残りの部品を洗浄しながらビーカーに加える。この溶液に1.5mol/L炭酸ナトリウム水溶液を200μL加えて、溶液が均一になるよう軽く攪拌する(全量約5mL)。途中、3回しんとう混和を行いながら1時間〜2時間室温に置く。再度攪拌し、メスフラスコ(容量10mL)に溶液を全量移す。水約5mLでビーカー内に残った部品を洗浄し、その液をメスフラスコに加えた後全量を10mLに定容する。これらの操作により、飲料中のアルギン酸をアルギン酸ナトリウムとして溶解し回収する。この溶液を直径25mmのメンブランフィルタ(GLクロマトディスク 0.45μm)でろ過したものをHPLC用分析試料とする。
2) 1-3 Salt exchange and recovery to sodium alginate Disassemble the membrane filter cartridge obtained by the above operation, take out the membrane filter and packing, and put them in a beaker. Add the remaining parts of the membrane filter cartridge to the beaker with 4.8 mL of water while washing. To this solution, 200 μL of a 1.5 mol / L sodium carbonate aqueous solution is added, and lightly stirred so that the solution becomes uniform (total amount of about 5 mL). In the middle, the mixture is allowed to stand at room temperature for 1 to 2 hours while mixing 3 times. Stir again and transfer the entire volume to a volumetric flask (capacity 10 mL). The remaining parts in the beaker are washed with about 5 mL of water, and the liquid is added to the volumetric flask. By these operations, alginic acid in the beverage is dissolved and recovered as sodium alginate. A solution obtained by filtering this solution through a membrane filter having a diameter of 25 mm (GL chromatodisc 0.45 μm) is used as an analytical sample for HPLC.
2)2 アルギン酸塩の定量
HPLC用分析試料100μLを高速液体クロマトグラフィー(HPLC)で測定する。純度既知のアルギン酸ナトリウム標準試料0.1%溶液を同様にHPLCで測定し、得られたクロマトグラムの面積の比較から試料中のアルギン酸ナトリウムを定量する。
なお、HPLC操作条件は以下の通りである。
2) Determination of 2 alginate 100 μL of analytical sample for HPLC is measured by high performance liquid chromatography (HPLC). A 0.1% solution of a standard sodium alginate sample of known purity is similarly measured by HPLC, and sodium alginate in the sample is quantified by comparing the areas of the obtained chromatograms.
The HPLC operating conditions are as follows.
HPLC操作条件
カラム:1)Super AW-L(ガードカラム):東ソー(株)製
2)TSK-GEL Super AW4000(GPC用カラム)
:排除限界分子量4×105PEO/DMF、長さ15cm,内径6mm、東ソー(株)製
3)TSK-GEL Super AW2500(GPC用カラム)
:排除限界分子量2×103PEO/DMF、長さ15cm,内径6mm、東ソー(株)製
※上記カラムはAW-L,AW4000,AW2500の順で連結する。
カラム温度:40℃
検出器:示差屈折計
移動相:0.2mol/L硝酸ナトリウム水溶液
流速:0.6mL/min
注入量:100μL
HPLC operating conditions Column: 1) Super AW-L (guard column): manufactured by Tosoh Corporation
2) TSK-GEL Super AW4000 (GPC column)
: Exclusion limit molecular weight 4 × 105 PEO / DMF, length 15 cm, inner diameter 6 mm, manufactured by Tosoh Corporation
3) TSK-GEL Super AW2500 (GPC column)
: Exclusion limit molecular weight 2 × 103 PEO / DMF, length 15 cm, inner diameter 6 mm, manufactured by Tosoh Corporation
* Connect the above columns in the order of AW-L, AW4000, and AW2500.
Column temperature: 40 ° C
Detector: Differential refractometer Mobile phase: 0.2 mol / L sodium nitrate aqueous solution Flow rate: 0.6 mL / min
Injection volume: 100 μL
2)3 アルギン酸塩の重量平均分子量の測定(重量平均分子量測定法)
アルギン酸塩の重量平均分子量は高速液体クロマトグラフィー(HPLC)にて測定する。HPLC操作条件は、(2 アルギン酸塩の定量)と同様の条件とする。分子量算出用の検量線には、標準プルラン(昭和電工(株)製 Shodex STANDARD P−82)を用いる。HPLC用分析試料をHPLCに100μL注入し、得られたクロマトチャートより、試料中のアルギン酸ナトリウムの重量平均分子量を算出する。
2) Measurement of weight average molecular weight of 3 alginate (weight average molecular weight measurement method)
The weight average molecular weight of the alginate is measured by high performance liquid chromatography (HPLC). The HPLC operating conditions are the same as those in (2 Determination of alginate). A standard pullulan (Shodex STANDARD P-82 manufactured by Showa Denko KK) is used for the calibration curve for molecular weight calculation. 100 μL of the analytical sample for HPLC is injected into the HPLC, and the weight average molecular weight of sodium alginate in the sample is calculated from the obtained chromatographic chart.
3)(ジェランガムの定量法)
ジェランガム量は、AOAC公定法であるAOAC991.43に従い、試料1gに一連の酵素処理を行った後約80%のエタノールで1時間室温に置き不溶成分を回収した。次に回収したエタノール不溶成分の乾燥物を0.1%濃度となるように蒸留水に溶解させ、溶液100μLを高速液体クロマトグラフィー(HPLC)で測定する。純度既知のジェランガム標準試料を0.1%の溶液を同様にHPLCで測定し、得られたクロマトグラムの面積の比較から試料中のジェランガムを定量する。このときの、HPLC操作条件は上記(アルギン酸塩の定量及び重量平均分子量の測定)の通りである。
3) (Quantitative method of gellan gum)
In accordance with AOAC 991.43, which is an official method of AOAC, the gellan gum amount was subjected to a series of enzyme treatments on 1 g of a sample, and then insoluble components were recovered by placing them at room temperature with about 80% ethanol for 1 hour. Next, the collected dried ethanol-insoluble component is dissolved in distilled water to a concentration of 0.1%, and 100 μL of the solution is measured by high performance liquid chromatography (HPLC). A 0.1% solution of a gellan gum standard sample of known purity is similarly measured by HPLC, and the gellan gum in the sample is quantified by comparing the areas of the obtained chromatograms. The HPLC operating conditions at this time are as described above (quantification of alginate and measurement of weight average molecular weight).
4)(pH測定法)
pHは、(株)堀場製作所製pHメーター(F−22)を使用し品温20℃の条件にて測定する。
4) (pH measurement method)
The pH is measured using a pH meter (F-22) manufactured by HORIBA, Ltd. at a product temperature of 20 ° C.
5)(粘度の測定法)
粘度は、20℃においてB型粘度計を用いて測定する。実施例においては(株)トキメック製B8L型粘度計を使用した(回転子:No.1、回転速度:60回転/分、品温:20℃)。
5) (Measurement method of viscosity)
The viscosity is measured with a B-type viscometer at 20 ° C. In the examples, a B8L viscometer manufactured by Tokimec Co., Ltd. was used (rotor: No. 1, rotational speed: 60 revolutions / minute, product temperature: 20 ° C.).
6)(ブリックス(Brix)値(度)の測定法)
Brix計(ATAGO RX−5000)で品温20℃にて測定した。
6) (Measurement method of Brix value (degree))
It measured at the product temperature of 20 degreeC with the Brix meter (ATAGO RX-5000).
(飲料の製造方法)
表1に示す配合処方で、飲料組成物を製造した。
トマト汁における固形物量の調整は、固形物を豊富に含むトマト汁から遠心分離や濾過によって固形物を除去することによって行った。より具体的にはトマト濃縮汁1(6.2倍濃縮)はトマトペーストの原液(可溶性固形分のブリックス値28)を遠心分離した後にろ過し、不溶性固形物量を調整した。一方、トマト濃縮汁2(6.2倍濃縮)は市販トマトペースト原液(可溶性固形分のブリックス値28)をそのまま用いた。
アルギン酸塩として、市販品の低分子化アルギン酸塩(製品名:ソルギン、(株)カイゲン製)を用いた。低分子化アルギン酸塩において、低分子化アルギン酸ナトリウムの重量平均分子量は58000、低分子化アルギン酸カリウムの重量平均分子量は59000であった。グアーガム分解物としてサンファイバーR(製品名、太陽化学(株)製)を用いた。ネイティブジェランガム含有製剤としてビストップD−1677、D−1796、およびビストップD−1796(D)(それぞれ製品名、三栄源エフ・エフ・アイ(株)製)を用いた。
成分(A)の低分子化アルギン酸塩を55〜65℃、成分(C)のネイティブジェランガムを80℃〜85℃の温水にそれぞれ溶解した後常温に冷却し、成分(A)水溶液、成分(C)水溶液、トマト汁、及びその他の成分を混合することにより調合液を調製した。
調合液をチューブ式熱交換器で高温短時間殺菌後、PETボトルに熱間充填を行い、密栓後室温まで冷却し、飲料組成物を製造した。
(Beverage production method)
A beverage composition was produced with the formulation shown in Table 1.
Adjustment of the amount of solids in tomato juice was performed by removing solids from tomato juice rich in solids by centrifugation or filtration. More specifically, the tomato concentrate 1 (6.2 times concentrated) was filtered after centrifuging the tomato paste stock solution (brix value 28 of soluble solids) to adjust the amount of insoluble solids. On the other hand, for tomato concentrate 2 (6.2 times concentrated), the commercially available tomato paste stock solution (Brix value 28 of soluble solid content) was used as it was.
As the alginate, a commercially available low molecular weight alginate (product name: Solgin, manufactured by Kaigen Co., Ltd.) was used. In the low molecular weight alginate, the weight average molecular weight of the low molecular weight sodium alginate was 58,000, and the weight average molecular weight of the low molecular weight potassium alginate was 59000. Sunfiber R (product name, manufactured by Taiyo Chemical Co., Ltd.) was used as a guar gum decomposition product. Bistop D-1677, D-1796, and Bistop D-1796 (D) (product names, manufactured by San-Ei Gen FFI Co., Ltd.) were used as native gellan gum-containing preparations.
The low molecular weight alginate of the component (A) is dissolved in 55 to 65 ° C. and the native gellan gum of the component (C) is dissolved in warm water of 80 ° C. to 85 ° C. and then cooled to room temperature, and the component (A) aqueous solution, component (C ) A mixed solution was prepared by mixing an aqueous solution, tomato juice, and other components.
The prepared solution was sterilized at a high temperature for a short time using a tube heat exchanger, hot filled into a PET bottle, cooled to room temperature after sealing, and a beverage composition was produced.
上記の測定法を用いて、飲料中の固形物量、トマト汁濃度、アルギン酸塩量・重量平均分子量、ジェランガム量、pH、粘度を測定し、その結果を表1に示した。
なお、表中、アルギン酸塩(質量%)はアルギン酸ナトリウム換算での質量%を意味する。
また、トマト汁濃度はストレート換算(JAS規格に準拠)濃度(質量%)を意味する。よってJAS規格に準拠するとトマト汁の場合はブリックス4.5のトマト汁がストレート汁100質量%のものになる。
Using the above measurement method, the amount of solids in the beverage, the concentration of tomato juice, the amount of alginate / weight average molecular weight, the amount of gellan gum, pH, and viscosity were measured, and the results are shown in Table 1.
In the table, alginate (mass%) means mass% in terms of sodium alginate.
Moreover, a tomato juice density | concentration means the straight conversion (based on JAS standard) density | concentration (mass%). Therefore, according to the JAS standard, in the case of tomato juice, the tomato juice of Brix 4.5 becomes 100% by mass of the straight juice.
(沈殿生成の判断基準)
上記方法にて調製した実施例及び比較例の飲料を室温にて静置保存し、1週間後の分離・沈殿生成の様子について外観を目視により評価(外観評価)し、その結果を表1に示した。
(Criteria for precipitation formation)
The beverages of the examples and comparative examples prepared by the above method were stored at room temperature, and the appearance of separation / precipitation after 1 week was visually evaluated (appearance evaluation). The results are shown in Table 1. Indicated.
実施例1〜8は分離・沈殿物のどちらも生じず、外観評価において合格であった。
比較例1、5はジェランガムを配合しなかった結果、沈殿物が生じ外観評価において不合格であった。
比較例2又は3は、ジェランガムをそれぞれ96及び100ppm配合しているが、ブリックス値はそれぞれ2.9及び3.0で、沈殿物が生じた。なお、比較例2〜3の不溶性固形分はそれぞれ0.17%及び18%であった。
比較例4は、ジェランガムを100ppm配合しているがBrixが4.3で、沈殿物が生じた。
In Examples 1 to 8, neither separation nor precipitation occurred, and the appearance evaluation was acceptable.
In Comparative Examples 1 and 5, as a result of not containing gellan gum, a precipitate was formed and the appearance evaluation was unacceptable.
In Comparative Example 2 or 3, gellan gum was blended in 96 and 100 ppm, respectively, but the Brix values were 2.9 and 3.0, respectively, and precipitates were formed. In addition, the insoluble solid contents of Comparative Examples 2 to 3 were 0.17% and 18%, respectively.
In Comparative Example 4, 100 ppm of gellan gum was blended, but Brix was 4.3, and a precipitate was formed.
Claims (4)
(B)飲料の野菜汁由来の可溶性固形分のブリックス値が0.5〜2.5、
(C)ジェランガム含有量が70〜100質量ppm、及び
(D)野菜汁由来の不溶性固形物量が0.01〜8体積%
である野菜汁含有容器詰飲料。 (A) The alginate content is 0.9 to 4.0% by mass in terms of sodium alginate,
(B) Brix value of soluble solid content derived from vegetable juice of beverage is 0.5 to 2.5 ,
(C) Gellan gum content is 70-100 mass ppm, and
(D) The amount of insoluble solids derived from vegetable juice is 0.01 to 8% by volume.
Is a vegetable juice-containing container-packed beverage.
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