JP5186409B2 - Negative electrode active material for secondary battery, secondary battery including the same, and manufacturing method thereof - Google Patents

Description

  The present invention relates to a negative electrode active material for a secondary battery. More specifically, the present invention relates to a negative electrode active material for a secondary battery made of a core carbon material in which part or all of an edge is covered with a coated carbon material, a secondary battery including the same, and a method for manufacturing the same.

  Recently, with the rapid spread of electronic devices using batteries, such as mobile phones, notebook PCs, and electric vehicles, demand for secondary batteries having a relatively high capacity while being small and light is rapidly increasing. In particular, lithium secondary batteries are light and have a high energy density, and thus are attracting attention as driving sources for portable devices. As a result, research and development for improving the performance of lithium secondary batteries has been actively conducted.

  In the lithium secondary battery, the lithium ion is filled with an organic electrolyte or a polymer electrolyte between a negative electrode and a positive electrode made of an active material capable of intercalation and deintercalation of lithium ions. Electric energy is produced by oxidation / reduction reactions when inserted / desorbed at the negative electrode.

Transition metal compounds such as lithium cobalt oxide (LiCoO ₂ ), lithium nickel oxide (LiNiO ₂ ), and lithium manganese oxide (LiMnO ₂ ) are mainly used as the positive electrode active material of the lithium secondary battery.

  And, as the negative electrode active material, generally, a crystalline carbon material such as natural graphite or artificial graphite with a large degree of softening, or pseudo graphite obtained by carbonizing a hydrocarbon or a polymer at a low temperature of 1000 to 1500 ° C. ( A low crystallinity carbon material having a pseudo-graphite structure or a turbostructural structure is used.

  Crystalline carbon materials are advantageous in packing active materials because of their high density, and have the advantages of excellent potential flatness, initial capacity, and charge / discharge reversibility. There is a problem that the charge / discharge efficiency and the cycle capacity decrease as the used battery is used. It has been analyzed that such a problem is caused by an electrolyte decomposition reaction being induced at the edge of the crystalline carbon material as the charge / discharge cycle of the battery increases.

  Japanese Patent Laid-Open No. 2002-348109 (Patent Document 1) discloses a carbon material-based negative electrode active coated with a carbide layer in order to prevent a decomposition reaction of an electrolyte solution from being induced at an edge portion of a crystalline carbon material. The substance is disclosed. In the carbon material-based negative electrode active material, the carbide layer is formed by coating the surface of the carbon material with a coating material (which is a coal-based or petroleum heavy oil containing pitch) and then performing a heat treatment at 1000 ° C. or higher. If the carbide layer is coated on the carbon material, the initial capacity of the secondary battery is slightly reduced, but the effect of improving the charge / discharge efficiency and the capacity characteristics of the long-term cycle is exhibited. In particular, when the coating material coating layer is artificially graphitized by high-temperature heat treatment, it is possible to effectively suppress the decomposition reaction of the electrolytic solution while reducing the amount of decrease in the initial capacity.

  The above prior art includes the mass ratio of the carbon material and the carbide layer necessary for effectively suppressing the decomposition reaction of the electrolytic solution, the coating and firing conditions of the carbide layer, the crystallographic properties of the carbide layer through XRD and Raman analysis, The specific surface area conditions of the carbide layer are described in detail.

  By the way, when forming a negative electrode of a secondary battery with a carbon material-based negative electrode active material, the present inventor also considers the formation conditions of the carbide layer itself and various physical property conditions of the carbide layer. It was newly found that the particle size distribution and the bulk density characteristics have a great influence on the electrochemical characteristics of the secondary battery.

  However, the above prior art makes no mention of the fact that the particle size distribution and volume density characteristics of the carbon material powder have a close correlation with the electrochemical characteristics of the secondary battery.

JP 2002-348109 A

  The present invention has been devised to solve the above-mentioned problems of the prior art, and the particle size distribution and the volume density characteristics are such that good electrochemical characteristics of the secondary battery can be derived. An object of the present invention is to provide an optimized carbon material-based negative electrode active material and a method for producing the same.

  Another object of the present invention is to provide an electrode made of a carbon material-based negative electrode active material with optimized particle size distribution and volume density characteristics, and a secondary battery including the same.

The negative electrode active material for a secondary battery according to the present invention for solving the above technical problem is coated with a coated carbon material in which part or all of the edge of the core carbon material having a particle form is formed of a carbide layer, and PSD ( (Particle Size Distribution) has d ₁ and d _max of 0.5 μm or more and 60 μm or less, respectively, and a volume density of 1.0 to 1.3 g / cm ³ .

Here, PSD means the particle size distribution when the negative electrode active material powders are arranged in the order of the particle size. PSD was measured using “CILAS920, France” manufactured by CILAS and “Mastersizer2000, USA” manufactured by MARVERN. “CILAS920, France” was used to measure the PSD of the fine powder in the negative electrode active material powder, and “Mastersizer 2000, USA” was used to measure the PSD of the coarse powder in the negative electrode active material powder. d ₁ is the upper limit size of particles when the cumulative volume of particles obtained from particles having a smaller size by PSD is 1% based on the total particle volume, and d _max is the maximum particle size in PSD. The volume density means the density of the carbon material-based negative electrode active material filled in the tapping cell when the negative electrode active material powder is dropped into a 20 cc capacity tapping cell through a 200 μm sieve and completely filled with the tapping cell.

The negative electrode active material according to the present invention desirably has a lower crystallinity of the coated carbon material than the core carbon material.
Desirably, the tap density of the negative electrode active material is 0.7 g / cm ³ or more, and the specific surface area is 5 m ² / g or less.

  Here, the tap density conforms to JIS-K5101 and is measured using “Powder Tester PT-R” manufactured by Hosokawa Micron. That is, the carbon material-based negative electrode active material powder is dropped onto a 20 cc capacity tapping cell through a sieve having a graduation interval of 200 μm and completely filled with the tapping cell, and then the tapping with a stroke length of 18 mm is performed 3000 times once per second. Then, the density of the tapped negative electrode active material is measured to determine the tap density. The specific surface area of the negative electrode active material is measured using a “nitrogen adsorption BET specific surface area measuring apparatus ASAP2400” manufactured by Micromeritics.

The method for producing a negative electrode active material for a secondary battery according to the present invention for solving the above technical problem is a first step of coating a raw material material of a coated carbon material on a core carbon material having a particle form; A second stage in which the coated carbon material is fired to form a coated carbon material made of a carbide layer on part or all of the edges of the core carbon material; and in PSD, d ₁ and d _max are each 0.5 μm or more And a third step of classifying the core carbon material on which the covering carbon material is formed so as to be 60 μm or less.

Desirably, in the second stage, the core carbon material coated with the raw material is fired at a temperature of 1000 to 2500 ° C. for 1 to 48 hours.
Preferably, the third step is a step of classifying the negative electrode active material using an air cyclone classifier, and the d ₁ of the PSD is set to be 0.1 on the condition that the pressure of the blower is 10 to 200 mmHg. In this step, the fine powder is removed so as to be 5 μm or more, and the negative electrode active material is classified so that d _max is 60 μm or less under the condition that the blower pressure is 400 to 800 mmHg.

  The other technical problem of the present invention can also be solved by an electrode manufactured using the above-described carbon material-based negative electrode active material for a secondary battery and a secondary battery including the electrode.

  If the negative electrode of the secondary battery is manufactured using the negative electrode active material for the secondary battery according to the present invention, the processability and the press-bonding property are improved, and the discharge capacity and efficiency of the secondary battery and the discharge capacity maintenance rate in the long-term cycle are improved. Can be improved.

  Hereinafter, preferred embodiments of the present invention will be described in detail. Prior to this, the terms and words used in this specification and claims should not be construed to be limited to ordinary or lexicographic meanings, and the inventor shall make his invention the best way. In accordance with the principle that the concept of terms can be appropriately defined for the purpose of explanation, the meaning and concept consistent with the technical idea of the present invention should be interpreted. Therefore, the embodiment described in the present specification is only the most preferred embodiment of the present invention, and does not represent all of the technical idea of the present invention. It should be understood that there can be equivalents and variations.

A negative active material for a secondary battery according to a preferred embodiment of the present invention includes a core carbon material in which part or all of an edge is covered with a carbide layer, and d ₁ and d _{max in} PSD are 0.5 μm or more, respectively. It is 60 μm or less and is characterized by a volume density of 1.0 to 1.3 g / cm ³ .

  Desirably, the core carbon material is spherical highly crystalline natural graphite. Alternatively, the core carbon material may be natural graphite, artificial graphite, mesocarbon microbead (MCMB), mesophase pitch (mesophase pitch) having an elliptical shape, a particulate shape, a crushed shape, a scale shape, or a whisker shape. ) Fine powder, isotropic pitch fine powder, resin charcoal, and low crystalline carbon fine powder having a pseudo-graphite structure or a turbostructural structure. Any one or a mixture thereof may be used.

  Preferably, the carbide layer is a low crystalline carbide layer formed by coating a core carbon material with coal-based or petroleum-based pitch, tar, or a mixture thereof and then carbonizing and firing. Here, low crystallinity means that the crystallinity of the carbide layer is lower than that of the core carbon material. If the carbide layer has lower crystallinity than the core carbon material, it is possible to effectively prevent the decomposition reaction of the electrolytic solution from being induced at the edge portion of the core carbon material. In addition, it is possible to improve process properties such as pressure-bonding properties during the electrode manufacturing process.

In the present invention, PSD means a particle size distribution when the carbon material-based negative electrode active material powders are arranged in order of particle size. PSD was measured using “CILAS920, France” manufactured by CILAS and “Mastersizer2000, USA” manufactured by MARVERN. “CILAS920, France” was used to measure the PSD of the fine powder in the negative electrode active material powder, and “Mastersizer 2000, USA” was used to measure the PSD of the coarse powder in the negative electrode active material powder. Here, d ₁ means the upper limit size of the particles when the cumulative volume of the particles obtained from the small particles by PSD is 1% based on the total particle volume. D _max means the maximum particle size in PSD. The volume density means the density of the negative electrode active material filled in the tapping cell when the powder of the negative electrode active material is dropped into a tapping cell having a capacity of 20 cc through a sieve having a scale interval of 200 μm and completely filled with the tapping cell.

Regarding the numerical range of d ₁ above, if d ₁ is smaller than 0.5 μm, the binding force between the negative electrode active material and the current collector metal is reduced when the electrode is produced with the negative electrode active material, and the secondary battery is charged. There is a risk that the negative electrode active material may peel off from the current collector during discharge. Such peeling of the negative electrode active material causes a decrease in charge / discharge capacity of the secondary battery. In addition, in the numerical range of d _max described above, if d _max is larger than 60 μm, the electrode cannot be sufficiently pressed after the negative electrode active material is applied to the current collector when the electrode is manufactured with the negative electrode active material. There is a problem of thickening.

It is further desirable that the carbon material-based negative electrode active material according to the present invention satisfies not only PSD and volume density but also tap density and specific surface area satisfying certain conditions. That is, the negative electrode active material according to the present invention has a tap density of 0.7 g / cm ³ or more and a specific surface area of 5 m ² / g or less.

  Here, the tap density conforms to JIS-K5101 and is measured using “Powder Tester PT-R” manufactured by Hosokawa Micron. That is, the carbon material-based negative electrode active material powder is dropped onto a tapping cell having a capacity of 20 cc through a sieve having a graduation interval of 200 μm, completely filled with the tapping cell, and then tapped with a stroke length of 18 mm once per second. After tapping, the tap density is measured by measuring the density of the tapped negative electrode active material.

The tap density is affected by the diameter, cross-sectional shape, surface shape, etc. of the powder of the carbon material-based negative electrode active material. Therefore, the value of the tap density varies depending on the particle size distribution, that is, PSD even if the average particle size of the negative electrode active material particles is the same. Generally, the tap density is increased by coating the core carbon material. On the other hand, if there are many scale-shaped particles in the powder of the core carbon material, or if there are many fine powders having a size of less than d _{1 in} the PSD, the tap density does not increase. Since the carbon material-based negative electrode active material according to the present invention has no fine powder of less than d ₁ and part or all of the edge of the core carbon material is covered with the carbide layer, the carbon material-based negative electrode active material is comparatively 0.7 g / cm ³ or more. Has a high tap density. If the tap density of the negative electrode active material satisfies the above conditions, the packing density when the negative electrode active material is pressure-bonded to the current collector metal can be increased without hindering the electrolyte from penetrating into the negative electrode active material. .

The specific surface area of the negative electrode active material according to the present invention is measured using a “nitrogen adsorption BET specific surface area measuring apparatus ASAP2400” manufactured by Micromeritics. The negative electrode active material according to the present invention has a specific surface area of 5 m ² / g or less because the pores of the core carbon material are filled with coal-based or petroleum-based carbon adhesion or coating. When the specific surface area is small as described above, the number of sites where the decomposition reaction of the electrolytic solution can occur is reduced, so that it is possible to prevent a long-term cycle characteristic deterioration of the secondary battery due to the decomposition reaction of the electrolytic solution.

The negative electrode active material for a secondary battery according to the present invention described above is obtained by mixing a core carbon material in the form of particles and a coal-based or petroleum-based pitch, tar, or a mixture thereof in a wet or dry manner. A first step of coating a raw material material of the coated carbon material on the surface; firing the core carbon material coated with the raw material material to form part or all of the edge of the core carbon material into a coated carbon material comprising a carbide layer; A second step of forming; and a third step of classifying the core carbon material coated with the coating carbon material so that d ₁ and d _{max in the} PSD are 0.5 μm or more and 60 μm or less, respectively. Can do.

  In the second stage, the carbonization firing temperature, the carbonization firing time, the carbonization firing pressure, the type of carbonization firing atmosphere gas, and the like are appropriately selected so that the coated carbon material has lower crystallinity than the core carbon material. It is desirable to control the conditions.

As an example, when carbonizing and firing is performed after pitching natural graphite, the carbonization and firing temperature is controlled to 1000 to 2500 ° C., the carbonization and firing time is 1 to 48 hours, and the carbonization and firing pressure is controlled to ₂ to 10 mmH ₂ O. As the firing atmosphere gas, an inert atmosphere gas capable of forming a non-oxidizing atmosphere such as N ₂ or Ar can be used.

Preferably, in the third step, the negative electrode active material is classified using a classifier using an air cyclone method. As an example, fine powder is removed by adjusting the blower pressure of the classifier to 10 to 200 mmHg so that d ₁ becomes 0.5 μm or more in PSD, and the blower pressure of the classifier is adjusted to 400 to 800 mmHg to form a negative electrode active material The negative electrode active material is classified so that d _max does not exceed 60 μm.

However, the present invention is not limited by the classification method of the negative electrode active material and the specific process conditions related to classification.
The negative electrode active material for a secondary battery manufactured according to the above-described method can be manufactured as an active material paste by mixing with a conductive material, a binder, and an organic solvent. Then, after applying the active material paste to a metal current collector such as copper foil, the electrode for a secondary battery (negative electrode) can be manufactured by drying, heat treatment and pressure bonding.

  Moreover, the electrode for secondary batteries manufactured in this way can be used for manufacture of a lithium secondary battery. That is, after the metal current collector with the negative electrode active material according to the present invention bound at a predetermined thickness and the metal current collector with the Li-based transition metal compound bound at a predetermined thickness are opposed to each other with the separator interposed therebetween, the separator If the battery is impregnated with an electrolyte for a lithium secondary battery, it is possible to manufacture a lithium secondary battery that can be repeatedly charged and discharged. Such an electrode for a secondary battery and a method for manufacturing the secondary battery are widely known to those having ordinary knowledge in the technical field to which the present invention belongs, and thus detailed description thereof is omitted.

  In addition, this invention has the characteristics in the physical property of the negative electrode active material for secondary batteries. Therefore, when manufacturing a secondary battery electrode and a secondary battery including the same using the negative electrode active material according to the present invention, various methods known in the technical field to which the present invention belongs can be applied. Further, it is obvious that the types of secondary batteries that can utilize the negative electrode active material according to the present invention are not limited to lithium secondary batteries.

<Examples and comparative examples>
[Example 1]
A spherical natural graphite was dry-mixed with a pitch of 20% by weight relative to the weight of natural graphite at a high speed for about 10 minutes to obtain a mixture. The mixture was subjected to a primary and secondary carbonization firing step at 1100 ° C. and 2200 ° C. for 1 hour, respectively, followed by a classification and fine powder removal step to produce a negative electrode active material. At the time of classification and fine powder removal, PSD was set so that d ₁ was 4.4 μm and d _max was 45 μm. 100 g of the produced negative electrode active material was put into a 500 ml reactor, a small amount of N-methylpyrrolidone (NMP) and a binder (PVDF) were added, and then mixed using a mixer to produce a negative electrode production slurry. . The negative electrode manufacturing slurry was uniformly applied to an 8 μm thick copper foil, vacuum-dried at 120 ° C., and then pressure bonded to manufacture a negative electrode for a secondary battery. Then, after performing the normal manufacturing process of the lithium secondary battery and producing a coin cell of 2016 standard (diameter: 20 mm, height: 16 mm) using the manufactured negative electrode and lithium foil (counter electrode), the coin cell The charge / discharge characteristics of were evaluated. At the time of producing the coin cell, a porous polyethylene membrane (Celgard 2300, thickness 20 μm) was used as a separator, and the liquid electrolyte was 1 in a mixed solvent of ethylene carbonate: diethyl carbonate: ethyl-methyl carbonate = 1: 1: 1 (volume ratio). An electrolytic solution to which a molar-LiPF ₆ solution was added was used.

[Example 2]
In the negative electrode active material classification and fine powder removal step, the process conditions were set so that d ₁ was 2.0 μm and d _max was 56 μm, and the other steps were performed in the same manner as in Example 1, and the negative electrode for the secondary battery. An active material was produced. Then, a coin cell was manufactured and the charge / discharge characteristics of the negative electrode active material were evaluated. The coin cell was manufactured by applying the same conditions as in Example 1.

[Example 3]
Coke was baked at 3000 ° C. for 24 hours to produce artificial graphite. Then, a classification and fine powder removal step was performed under conditions where d ₁ and d _max in the PSD were 0.7 μm and 56 μm, respectively, to manufacture a negative electrode active material for a secondary battery. Then, a coin cell was manufactured and the charge / discharge characteristics of the negative electrode active material were evaluated. The coin cell was manufactured by applying the same conditions as in Example 1.

[Comparative Example 1]
In the negative electrode active material classification and fine powder removal step, the process conditions were set so that d ₁ was 0.3 μm and d _max was 56 μm, and the other steps were performed in the same manner as in Example 1 and the negative electrode for secondary battery. An active material was produced. Then, a coin cell was manufactured and the charge / discharge characteristics of the negative electrode active material were evaluated. The coin cell was manufactured by applying the same conditions as in Example 1.

[Comparative Example 2]
In the negative electrode active material classification and fine powder removal step, the process conditions were set so that d ₁ was 0.9 μm and d _max was 85 μm, and the other steps were performed in the same manner as in Example 1 to form a negative electrode for a secondary battery. An active material was produced. Then, a coin cell was manufactured and the charge / discharge characteristics of the negative electrode active material were evaluated. The coin cell was manufactured by applying the same conditions as in Example 1.

[Comparative Example 3]
In the negative electrode active material classification and fine powder removal step, the process conditions were set so that d ₁ was 0.4 μm and d _max was 86 μm, and the other steps were performed in the same manner as in Example 3 to obtain a negative electrode for secondary battery. An active material was produced. Then, a coin cell was manufactured and the charge / discharge characteristics of the negative electrode active material were evaluated. The coin cell was manufactured by applying the same conditions as in Example 1.

[Comparative Example 4]
In the negative electrode active material classification and fine powder removal step, process conditions were set so that d ₁ was 4.7 μm and d _max was 90 μm, and the other steps were performed in the same manner as in Example 3 to obtain a negative electrode for a secondary battery. An active material was produced. Then, a coin cell was manufactured and the charge / discharge characteristics of the negative electrode active material were evaluated. The coin cell was manufactured by applying the same conditions as in Example 1.

<Characteristic evaluation of negative electrode active material>
The following characteristic evaluation experiments were conducted using the negative electrode active materials for secondary batteries manufactured according to Examples 1 to 3 and Comparative Examples 1 to 4 as samples.

1. Volume density (Bulk density: g / cm ³ )
A sample of the negative electrode active material was passed through a sieve having a graduation interval of 200 μm, and a volume density was measured after completely filling a 20 cc capacity tapping cell.

2. PSD (Particle Size Distribution)
The PSD of the negative electrode active material sample was measured using “CILAS920, France” manufactured by CILAS and “Mastersizer2000, USA” manufactured by MALVERN.

3. Specific surface area The specific surface area of the negative electrode active material sample was measured using a “nitrogen adsorption BET specific surface area measuring device ASAP2400” manufactured by Micromeritics.

4). Tap density The tap density of the negative electrode active material sample was measured according to JIS-K5101 using “Powder Tester PT-R” manufactured by Hosokawa Micron. A sieve having a scale interval of 200 μm was used as a sieve through which the sample powder was passed. After the sample powder passed through the sieve is dropped into a 20 cc capacity tapping cell and completely filled, after tapping with a stroke length of 18 mm at a frequency of once per second, 3000 times, the powder of the tapping cell filled The tap density was measured.

5. Charging / discharging characteristics In order to evaluate the charging / discharging characteristics of the negative electrode active material sample, the charging / discharging experiment of the coin cell was performed over 25 cycles. The charge / discharge test of each cycle using a coin cell was performed by charging the battery to 0.01 V at a charging current of 0.5 mA / cm ² while regulating the potential within a range of 0.01 to 1.5 V, and a voltage of 0.01 V. The charging was continued until the charging current reached 0.02 mA / cm ² . A discharge current of 0.5 mA / cm ² was discharged up to 1.5 V. Through such a charge / discharge cycle test, the charge / discharge efficiency of the first cycle of the coin cell, the discharge capacity of the second cycle, and the discharge capacity maintenance rate in the 25th cycle based on the discharge capacity of the second cycle were calculated.

6). Processability 100 g of a sample of the negative electrode active material was put into a 500 ml reactor, a small amount of N-methylpyrrolidone (NMP) and a binder (PVDF) were added, and then a slurry was produced by mixing using a mixer. 35 g of the slurry was put into a sieve having a scale interval of 100 μm, and then vacuum pumped for a sufficient time to pass through the sieve. At this time, the processability was evaluated by Out / In (%), which is the ratio of the input amount of slurry and the discharge amount. The evaluation criteria for processability are determined that the processability is “good” if Out / In (%) is greater than 70%, and the processability is determined to be “normal” for 50 to 70%. If less than 50%, the processability was determined to be “bad”.

7). Crimpability 100 g of sample powder was put into a 500 ml reactor, a small amount of N-methylpyrrolidone (NMP) and a binder (PVDF) were added, and then mixed using a mixer to prepare a slurry. Then, the slurry was uniformly applied to an 8 μm-thick copper foil, and the slurry was vacuum-dried at 120 ° C. to produce an electrode before pressure bonding. The electrode was then crimped several times. At this time, the electrode density at a certain point according to the number of times of crimping was obtained, and the crimping property of the negative electrode active material was evaluated. The evaluation standard of the crimping property is that if the electrode density in the first to third crimping sections is 1.7 (g / cc) or more, the crimping property is evaluated as “good” and less than 1.7 (g / cc). If so, the crimpability was evaluated as “bad”.

  Tables 1 and 2 below show the results of various characteristic evaluations on the negative electrode active materials for secondary batteries manufactured according to Examples 1 to 3 and Comparative Examples 1 to 4 described above. In Tables 1 and 2 below, BD indicates volume density, SSA indicates specific surface area, and TD indicates tap density.

Referring to Table 1 and Table 2 above, the negative electrode active materials of Examples 1 to 3 are both better in processability and pressure-bonding properties than the negative electrode active materials of Comparative Examples 1 to 4, and in the 25th cycle. It can be confirmed that the discharge capacity retention rate of the is high. Moreover, the negative electrode active materials of Examples 1 to 3 have a higher volume density BD than the negative electrode active materials of Comparative Examples 2 to 4. This is analyzed because the fine powder and the coarse powder are mixed at an appropriate ratio in the particle distribution of the negative electrode active material, so that the fine powder is densely filled in the space between the coarse powders. Further, when Example 3 and Comparative Example 2 are compared, only the d _{1 of} PSD shows a slight difference, but the d ₁ value satisfies the condition proposed by the present invention, so that the negative electrode active material of Example 3 is a comparative example. It can be seen that the discharge capacity retention rate characteristic in the 25th cycle is superior to the negative electrode active material of No. 2. The excellent discharge capacity retention rate characteristic in the 25th cycle means that even when the secondary battery is used for a long time, the decomposition reaction of the electrolyte is effectively suppressed, and the long-term characteristic deterioration of the secondary battery becomes remarkable. Confirm that there was nothing.

  As described above, the present invention has been described with reference to the embodiments. However, even if the embodiments and drawings are limited, the present invention is not limited thereto, and the technical field to which the present invention belongs. It goes without saying that various modifications and variations can be made by those having ordinary knowledge within the scope of the technical idea of the present invention and the scope of the claims.

Claims (5)

A first step of coating the surface of the core carbon material having a particle form with a raw material of the coated carbon material;
A second step of firing the core carbon material coated with the raw material to form a coated carbon material comprising a carbide layer on part or all of the edge of the core carbon material; and d ₁ and d _{max in} PSD Including a third step of classifying the core carbon material on which the coated carbon material is formed such that the carbon material is 0.5 μm or more and 60 μm or less,
The third step is a step of classifying the negative electrode active material using a classifier using an air cyclone method, and fine powder so that PSD d ₁ is 0.5 μm or more under the condition that the pressure of the blower is 10 to 200 mmHg. And the negative electrode active material is classified so that d _max is 60 μm or less under the condition that the pressure of the blower is 400 to 800 mmHg.
(However, PSD is the size distribution of the particles when the negative electrode active material powders are arranged in the order of the size of the particles, and d ₁ is the cumulative volume of particles obtained from the smaller particles based on the total particle volume. It is the upper limit size of the particle when it becomes 1%, and d _max is the maximum particle size.)   2. The production of a negative electrode active material for a secondary battery according to claim 1, wherein in the second step, the core carbon material coated with the raw material is fired at a temperature of 1000 to 2500 ° C. for 1 to 48 hours. Method.   The method for producing a negative electrode active material for a secondary battery according to claim 1, wherein the core carbon material is highly crystalline spherical natural graphite.   The core carbon material is oval, particulate, scale, whisker or crushed natural graphite, artificial graphite, mesocarbon microbeads, mesophase pitch fines, isotropic pitch fines, resin charcoal, 2. The negative electrode active for secondary battery according to claim 1, wherein the negative electrode active material is selected from the group consisting of fine powder of low crystalline carbon having a pseudo graphite structure or a turbulent layer structure, or a mixture thereof. A method for producing a substance.   2. The method for producing a negative electrode active material for a secondary battery according to claim 1, wherein the raw material of the coated carbon material is a coal-based or petroleum-based pitch, tar, or a mixture thereof.