JP5176564B2 - CFRP panel structure - Google Patents

CFRP panel structure Download PDF

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JP5176564B2
JP5176564B2 JP2008013457A JP2008013457A JP5176564B2 JP 5176564 B2 JP5176564 B2 JP 5176564B2 JP 2008013457 A JP2008013457 A JP 2008013457A JP 2008013457 A JP2008013457 A JP 2008013457A JP 5176564 B2 JP5176564 B2 JP 5176564B2
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adhesive
panel member
film
inner panel
outer panel
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JP2008207791A (en
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将士 北川
博英 和田
茂 川嶋
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Toray Industries Inc
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本発明は、内側パネル部材と外側パネル部材を接着してなるCFRP製パネル構造体に関し、特に、自動車用のボンネットフードやドア、屋根などの自動車外板パネルとして好適なCFRP製パネル構造体に関する。   The present invention relates to a CFRP panel structure formed by bonding an inner panel member and an outer panel member, and more particularly to a CFRP panel structure suitable as an automobile outer panel such as a hood hood, a door, or a roof for an automobile.


自動車のボンネットフードなど内側パネル部材と外側パネル部材を接合し、かつ外側パネル部材に歪みのない外観を要求されるパネル構造体は、これまで鋼やアルミなどの金属材料が主として用いられてきた。これに対して、近年軽量化の要求が高まってきたことから、軽量で強度、剛性に優れる炭素繊維強化プラスチック(以下、「CFRP」と称する場合もある)が、最も軽量化にふさわしい材料として用いられるようになってきた。

A panel structure in which an inner panel member and an outer panel member such as a hood hood of an automobile are joined and the outer panel member is required to have an undistorted appearance has been mainly made of a metal material such as steel or aluminum. On the other hand, since the demand for weight reduction has increased in recent years, carbon fiber reinforced plastic (hereinafter sometimes referred to as “CFRP”) that is lightweight and excellent in strength and rigidity is used as the most suitable material for weight reduction. Has come to be.

金属製のパネル構造体は内側パネルの外周部を挟み込むように外側パネルの外周部を曲げ加工(ヘム加工)することにより接合する構造が用いられているが、CFRP製パネル構造体では同じ構造を採用することは出来ない。これはCFRPが脆性材料であり、折り曲げ加工しようとすると曲げた部分が折れてしまうためである。従ってCFRP製パネル構造体を製造する場合には、内側パネル部材と外側パネル部材を接着接合する構造が一般的に用いられてきた。   The metal panel structure is joined by bending (hem processing) the outer peripheral part of the outer panel so as to sandwich the outer peripheral part of the inner panel, but the CFRP panel structure has the same structure. It cannot be adopted. This is because CFRP is a brittle material and the bent portion will be broken when it is bent. Therefore, when manufacturing a CFRP panel structure, a structure in which an inner panel member and an outer panel member are bonded to each other has been generally used.

しかしながら、接着構造を用いたパネル構造部材の外側パネル部材表面には歪みが生じ、美しい表面を得ることが難しいという問題があった。   However, the outer panel member surface of the panel structure member using the adhesive structure is distorted, and there is a problem that it is difficult to obtain a beautiful surface.

図1の様に、少なくとも一部にフランジ部と立ち壁部を有するハット型形状の内側パネル部材と外側パネル部材を接着した場合、互いが相対している部分3aと、内側パネル部材のR部分に接着剤がはみ出した部分3bでは接着剤の厚みが大きく異なる。一般的に接着剤は硬化する際の化学反応により体積が数パーセント収縮するが、ハット型形状を有する内側パネル部材に比べて曲率の小さい外側パネル部材は剛性が低いため、内側パネル部材に引っ張られることになる。このとき、接着剤の厚みが大きく異なった場合、接着剤の収縮する絶対量に差が生じ、図2の如く外側パネル部材が変形し、外観に歪みが生じるのである。   As shown in FIG. 1, when a hat-shaped inner panel member and an outer panel member having a flange portion and a standing wall portion at least partially are bonded, a portion 3a facing each other and an R portion of the inner panel member In the portion 3b where the adhesive protrudes, the thickness of the adhesive is greatly different. Generally, the adhesive shrinks by a few percent due to a chemical reaction during curing, but the outer panel member having a smaller curvature than the inner panel member having a hat shape has a lower rigidity and is pulled by the inner panel member. It will be. At this time, if the thicknesses of the adhesives are greatly different, a difference occurs in the absolute amount of shrinkage of the adhesives, and the outer panel member is deformed as shown in FIG.

これに対して、内側パネル部材のR部にはみ出した接着剤を掻き取ることにより外観の歪みを抑制することも考えられるが、R部の奥まで掻き取ることは難しい。また、フランジ部の内側には手が入らない場合が多く現実的ではない。   On the other hand, it is conceivable to suppress distortion of the appearance by scraping off the adhesive that protrudes from the R portion of the inner panel member, but it is difficult to scrape to the back of the R portion. Moreover, there are many cases in which a hand cannot enter the inside of the flange portion, which is not realistic.

さらに、接着剤の掻き取り作業を軽減させる目的で、特許文献1に開示されているような接着剤のはみ出しを防止する方法が提案されている。しかしながら、接着剤を安定的にはみ出させないようにするためには、接着剤の塗布量を両面テープと被接着部材で構成されるスペースの体積より少なくしておく必要がある。この場合、接着剤は重力で下方向に溜まるため上側の被接着部材と触れあわない部分が生じることから、接着強さを安定して確保することが出来ないという問題が生じる。
特開昭62−135584号公報
Furthermore, for the purpose of reducing the scraping work of the adhesive, a method for preventing the adhesive from protruding as disclosed in Patent Document 1 has been proposed. However, in order to prevent the adhesive from sticking out stably, it is necessary to make the application amount of the adhesive smaller than the volume of the space constituted by the double-sided tape and the adherend. In this case, since the adhesive accumulates in the downward direction due to gravity, a portion that does not come into contact with the upper member to be bonded is generated, which causes a problem that the adhesive strength cannot be secured stably.
JP-A-62-135584

そこで本発明の課題は、上述する従来のパネル構造体の問題点を克服し、軽量かつ高剛性で、外観上の歪みの少ない美しい表面を有し、その上接着強さも安定して強いパネル構造体を提供することにあり、特に、かかる特徴を有する自動車用外板パネル構造体を提供することにある。   Accordingly, the object of the present invention is to overcome the above-mentioned problems of the conventional panel structure, have a beautiful surface that is lightweight and highly rigid, has little distortion in appearance, and has a stable and strong adhesive strength. It is in providing a body, and in particular, in providing an automotive skin panel structure having such features.

上記課題を達成するために本発明は、以下の構成を採用する。すなわち、
(1)少なくとも一部にフランジ部と立ち壁部を有するハット型形状の内側パネル部材と外側パネル部材とが接着されてなるパネル構造体であって、外側パネル部材の内側パネル部材のフランジ部に相対する領域の外縁部 または/および 内側パネル部材のフランジ部に隣接した部分に離型層を有することを特徴とするCFRP製パネル構造体。
To achieve the above object, the present invention adopts the following configuration. That is,
(1) A panel structure in which a hat-shaped inner panel member and an outer panel member having a flange portion and a standing wall portion at least in part are bonded to each other. A CFRP panel structure comprising a release layer in an outer edge portion of an opposing region and / or a portion adjacent to a flange portion of an inner panel member.

(2)前記離型層がフィルムを接着したものであることを特徴とする、前記(1)に記載のCFRP製パネル構造体。   (2) The CFRP panel structure as described in (1) above, wherein the release layer is a film bonded thereto.

(3)内側パネルと外側パネルとの接着層の厚みをt1、離型層の厚みをt2とすると、t1とt2の関係が以下の式を満足することを特徴とする、前記(1)または(2)に記載の炭素繊維強化プラスチック製パネル構造体。   (3) When the thickness of the adhesive layer between the inner panel and the outer panel is t1, and the thickness of the release layer is t2, the relationship between t1 and t2 satisfies the following formula, (1) or The panel structure made of carbon fiber reinforced plastic according to (2).

t2/t1≦0.6・・・(式)。   t2 / t1 ≦ 0.6 (formula).

(4)前記フィルムの水との接触角が75°以上であることを特徴とする、前記(2)に記載のCFRP製パネル構造体。   (4) The CFRP panel structure according to (2), wherein a contact angle of the film with water is 75 ° or more.

(5)前記フィルムと外側パネル部材との間引き剥がし力 または/および 前記フィルムと内側パネル部材との間引き剥がし力がフィルム幅25mm当たり4N以下であることを特徴とする、前記(2)〜(4)いずれかに記載のCFRP製パネル構造体。   (5) Peeling force between the film and the outer panel member or / and Peeling force between the film and the inner panel member is 4 N or less per 25 mm of film width, (2) to (4) ) A CFRP panel structure according to any one of the above.

(6)前記離型層が離型剤であることを特徴とする、前記(1)に記載のCFRP製パネル構造体。   (6) The CFRP panel structure according to (1), wherein the release layer is a release agent.

(7)前記離型層が塗膜であり、前記塗膜の水との接触角が75°以上であることを特徴とする、前記(1)に記載のCFRP製パネル構造体。   (7) The CFRP panel structure according to (1), wherein the release layer is a coating film, and the contact angle of the coating film with water is 75 ° or more.

本発明によれば、内側パネル部材のR部分にはみ出した接着剤が外側パネル部材 または/および 内側パネル部材と接着していないため、接着剤が収縮しても外側パネル部材が内側パネル部材側に引っ張られる力が著しく軽減される。また、必要とされる量以上に接着剤を塗布し、積極的にはみ出させるために接着剤の不足による強度不足を生じる恐れが少ない。従って、従来のパネル構造体では困難であった、軽量かつ高剛性で、外観上の歪みの少ない美しい表面を有し、その上接着強さも安定して強いパネル構造体が得られるのである。   According to the present invention, since the adhesive protruding from the R portion of the inner panel member is not bonded to the outer panel member and / or the inner panel member, the outer panel member is moved toward the inner panel member even when the adhesive shrinks. The pulling force is significantly reduced. In addition, since the adhesive is applied more than the required amount and actively protrudes, there is little risk of insufficient strength due to insufficient adhesive. Accordingly, it is possible to obtain a panel structure that has a beautiful surface that is light and highly rigid, has little distortion in appearance, and has a stable and strong adhesive strength, which is difficult with a conventional panel structure.

以下、本発明の望ましい実施の形態について、詳細に説明する。   Hereinafter, preferred embodiments of the present invention will be described in detail.

本発明は、少なくとも一部にフランジ部と立ち壁部を有するハット型形状の内側パネル部材と外側パネル部材とが接着されてなるパネル構造体であって、外側パネル部材の内側パネル部材のフランジ部に相対する領域の外縁部 または/および 内側パネル部材のフランジ部に隣接した部分に離型層を有することを特徴とするCFRP製パネル構造体である。   The present invention is a panel structure in which a hat-shaped inner panel member and an outer panel member having a flange portion and a standing wall portion at least in part are bonded to each other, and the flange portion of the inner panel member of the outer panel member A CFRP panel structure having a release layer in an outer edge portion of a region opposite to and / or a portion adjacent to a flange portion of an inner panel member.

本発明の内側パネル部材は、図1に示す通りハット型形状をしており、少なくとも一部にフランジ部と立ち壁部を有し、本発明に係るCFRP製パネル構造体は、当該内側パネル部材のフランジ部の一部と外側パネル部材とが接着されて構成される。   The inner panel member of the present invention has a hat shape as shown in FIG. 1 and has a flange portion and a standing wall portion at least in part, and the CFRP panel structure according to the present invention includes the inner panel member. A part of the flange portion and the outer panel member are bonded to each other.

ここで、本発明に係るCFRP製パネル構造体は、離型層を有することを特徴とする。離型層は、外側パネル部材の内側パネル部材のフランジ部に相対する領域の外縁部(図3,4の3a:点線部の内側)、内側パネル部材のフランジ部に隣接した部分(図3,4の3c:点線部の外側)のいずれか、もしくは両方に設けられていれば良い。接着面積に十分な安全率が設定されていれば、離型層の位置はバラツキを考慮して、図3,4の4の様にフランジ領域にかかる位置に離型層が配置されていることが、歪みの抑制の点ではより好ましい。   Here, the CFRP panel structure according to the present invention has a release layer. The release layer includes an outer edge portion (3a in FIGS. 3 and 4: inside the dotted line portion) of the outer panel member facing the flange portion of the inner panel member, and a portion adjacent to the flange portion of the inner panel member (FIG. 3). 4-3c: outside of the dotted line part) or both. If a sufficient safety factor is set for the bonding area, the release layer should be placed at the flange area as shown in 4 in FIGS. However, it is more preferable in terms of suppressing distortion.

なお、本発明の効果、すなわち、接着剤が収縮しても外側パネル部材が内側パネル部材側に引っ張られる力が軽減され、また、必要とされる量以上に接着剤を塗布し、積極的にはみ出させるために接着剤の不足による強度不足を生じにくくなるという効果を奏する限りにおいて、前記外縁部、もしくは前記内側パネル部材のフランジ部に隣接した部分のいずれかの箇所に離型層を有さない部分があっても差し支えはない。   The effect of the present invention, that is, even when the adhesive contracts, the force with which the outer panel member is pulled toward the inner panel member is reduced, and the adhesive is more actively applied than the required amount. As long as the effect of insufficient strength due to the lack of adhesive is less likely to occur, it has a release layer at either the outer edge portion or the portion adjacent to the flange portion of the inner panel member. There is no problem even if there is no part.

本発明に係るCFRP製パネル構造体は、特に用途を限定するものではないが、特に自動車外板パネルに好適である。具体的な使用例を挙げると、ボンネットフードや屋根、ドア、トランクリッド、フェンダーなどである。   The CFRP panel structure according to the present invention is not particularly limited in use, but is particularly suitable for an automobile outer panel. Specific examples include hood hoods, roofs, doors, trunk lids, and fenders.

本発明におけるパネル構造体はCFRPからなる。CFRPとは、炭素繊維により強化されている樹脂(すなわち、炭素繊維強化プラスチック)を指す。CFRPは鋼やアルミなどの金属材料に比べて軽量で、強度、剛性の面でも優れるため、軽量で強度、剛性の高いパネル構造体、特に自動車外板パネルの材料として好適である。   The panel structure in the present invention is made of CFRP. CFRP refers to a resin reinforced with carbon fibers (ie, carbon fiber reinforced plastic). CFRP is lighter than metal materials such as steel and aluminum and is superior in terms of strength and rigidity. Therefore, CFRP is suitable as a material for a panel structure that is lightweight and has high strength and rigidity, particularly an automobile outer panel.

本発明に用いられる炭素繊維の種類としては何ら限定されるものではない。アクリル繊維を原料とし強度面で優れた特性を持つPAN系炭素繊維でも、石油ピッチなど原料とし弾性率の面で優れた特性を持つピッチ系炭素繊維の何れであってもよい。炭素繊維の形態も特に制限されるものではない。高い強度が必要であれば連続繊維が好ましく、安価であることを求める場合には炭素繊維を短くカットしたSMC(シートモールディングコンパウンド)や、ペレット材料を選択することも出来る。連続繊維を用いる場合には炭素繊維を一方向に引き揃えた一方向材(UD材)でも織布材でもよいが、成形する上では織布材の方が容易である。織布の種類としては平織りや朱子織り、綾織り、ノンクリンプクロスなどが適宜選択できるが、クリア塗装で織り目を製品表面に見せる場合には平織りを用いると意匠性が高くなる。また、朱子織りや綾織りはドレープ性が良いため、深さの深い3次元形状を成形する場合に使用すると良い。   The type of carbon fiber used in the present invention is not limited at all. A PAN-based carbon fiber having an excellent property in terms of strength using acrylic fiber as a raw material, or a pitch-based carbon fiber having an excellent property in terms of elastic modulus such as petroleum pitch may be used. The form of the carbon fiber is not particularly limited. If high strength is required, continuous fibers are preferable. When it is desired to be inexpensive, SMC (sheet molding compound) obtained by cutting carbon fibers and pellet materials can be selected. When continuous fibers are used, a unidirectional material (UD material) in which carbon fibers are aligned in one direction or a woven material may be used, but the woven material is easier to form. Plain weaving, satin weaving, twill weaving, non-crimp cloth, etc. can be appropriately selected as the type of woven fabric. However, when clear weaving is used to show the weave on the product surface, the use of plain weaving increases design. In addition, satin weave and twill weave are good for drape, so they are preferably used when forming a three-dimensional shape with a deep depth.

また、炭素繊維以外にも表面意匠性や成形性、樹脂含浸性を向上させることを目的に、マットや不織布、充填材など他の補強繊維や補助材料を用いることもできる。例えば、ガラスサーフェースマットなどを用いることにより、表面が平滑性や樹脂の含浸性を向上できることがある。また、かかる炭素繊維以外の他の補強繊維として、例えば、ガラス繊維、アラミド繊維、PBO(ポリパラフェニレンベンゾビスオキサゾール)繊維、チラノ(チタンアルミナ)繊維、ナイロン繊維などが挙げられるが、炭素繊維以外の他の補強繊維が、強化繊維全体の50質量%未満の含有量であれば、本発明で言うCFRPに含まれるものとする。   In addition to carbon fibers, other reinforcing fibers and auxiliary materials such as mats, non-woven fabrics, and fillers can be used for the purpose of improving surface design, moldability, and resin impregnation. For example, the use of a glass surface mat or the like may improve the smoothness of the surface and the resin impregnation property. Examples of the reinforcing fibers other than the carbon fibers include glass fibers, aramid fibers, PBO (polyparaphenylene benzobisoxazole) fibers, tyrano (titanium alumina) fibers, and nylon fibers. If the other reinforcing fiber has a content of less than 50% by mass of the entire reinforcing fiber, it is included in the CFRP referred to in the present invention.

さらに、CFRPの積層構成は特に制限されることはなく、パネル構造体に加わる力の方向や大きさに合わせて適宜配向させることができる。自動車外板パネルの場合は0°、90°、+45°、−45°の各方向に繊維を均等に配した疑似等方積層を基本に配向させることが一般的である。自動車外板パネルは大きく浅い板状の形状が多く、働く荷重も曲げ荷重とねじり等の剪断荷重が共に想定されるためである。しかしながら、車両の種類や適応される部位に応じて適宜異方性を持たせることは好ましい。   Furthermore, the laminated structure of CFRP is not particularly limited, and can be appropriately oriented according to the direction and magnitude of the force applied to the panel structure. In the case of an automobile outer panel, the orientation is generally based on a quasi-isotropic laminate in which fibers are evenly arranged in directions of 0 °, 90 °, + 45 °, and −45 °. This is because automobile outer panel has many large and shallow plate-like shapes, and working load is assumed to be both bending load and shear load such as torsion. However, it is preferable to provide anisotropy as appropriate according to the type of vehicle and the part to which it is applied.

本発明のCFRPを構成するマトリックス樹脂としては、繊維との接着性が良く高い強度が得られることからエポキシ樹脂が好ましい。エポキシ樹脂以外にもビニルエステル樹脂や不飽和ポリエステル樹脂などを選択できる。また、ナイロン樹脂やABS(アクリルニトリルブタジエンストレン)樹脂、PPS(ポリフェニレンスルホン)樹脂などの熱可塑性樹脂を選択することもできる。高温に晒される場所で使用する場合には、ビスマレイミド樹脂やポリイミド樹脂などを利用してもよい。その他、各種添加剤を用いることもでき、例えばマトリックス樹脂に紫外線吸収剤を混合すると、紫外線によるマトリックス樹脂の劣化を防止する効果も得ることができる。   As the matrix resin constituting the CFRP of the present invention, an epoxy resin is preferable because of its good adhesion to fibers and high strength. In addition to epoxy resins, vinyl ester resins and unsaturated polyester resins can be selected. A thermoplastic resin such as nylon resin, ABS (acrylonitrile butadiene strain) resin, or PPS (polyphenylene sulfone) resin can also be selected. When used in a place exposed to a high temperature, a bismaleimide resin or a polyimide resin may be used. In addition, various additives can also be used. For example, when an ultraviolet absorber is mixed with a matrix resin, an effect of preventing the matrix resin from being deteriorated by ultraviolet rays can be obtained.

本発明の内側パネル部材および外側パネル部材を成形する方法としては、一般に知られたCFRPの成形法を適用することができる。中でもRTM成形(レジン・トランスファー・モールディング)は大型で軽量、高剛性の製品を短い成形サイクルで生産することができるため、自動車外板パネルの成形に適している。より大量生産される用途に対してはSMCを用いたプレス成形や熱可塑性樹脂をマトリックス樹脂とした材料での射出成形が適している。もちろん一般的なプリプレグ材料を使用してオートクレーブ成形やプレス成形、バキュームバッグ成形することもできるし、ハンドレイアップや、VaRTM法(バッグ材内を真空吸引して樹脂注入する成形法)などを適用することもできる。   As a method of molding the inner panel member and the outer panel member of the present invention, a generally known CFRP molding method can be applied. Among them, RTM molding (resin transfer molding) is suitable for molding automobile outer panel because it can produce large, lightweight, and highly rigid products in a short molding cycle. For applications that are mass-produced, press molding using SMC and injection molding using a material in which a thermoplastic resin is a matrix resin are suitable. Of course, autoclave molding, press molding and vacuum bag molding can be performed using general prepreg materials, and hand lay-up and VaRTM method (molding method in which the inside of the bag material is injected by vacuum suction) are applied. You can also

次に、本発明に用いられる接着剤の種類についても、何ら制限されるものではない。具体的には接着強度に優れ種類も豊富なエポキシ系接着剤や、耐衝撃に優れ短時間硬化できるウレタン系、被接着物の油汚れに強いアクリル系接着剤などが挙げられる。接着剤の強度は一般的に厚み依存性があり、また軽量性の点からも、接着層厚みは薄く設定することが好ましい。   Next, the type of adhesive used in the present invention is not limited at all. Specific examples include epoxy adhesives with excellent adhesive strength and abundant types, urethane adhesives that have excellent impact resistance and can be cured in a short time, and acrylic adhesives that are resistant to oil stains on the adherend. The strength of the adhesive generally depends on the thickness, and the thickness of the adhesive layer is preferably set thin from the viewpoint of lightness.

本発明に用いられる離型層としては、用いられる接着剤に対して離型性を有するものであれば機能を満足することが出来る。平面や浅い3次元曲面に設けるには離型性のあるフィルムを貼り付けると作業性もよい。フィルムの片面に粘着剤を予め塗布した離型性ある粘着テープが市販されているので、これを用いるとさらに簡単に作業することができ、剥離紙ライナー付きフィルムであれば自動裁断機などで事前にカットしておくことで量産にも対応できる。   The release layer used in the present invention can satisfy the function as long as it has releasability with respect to the adhesive used. In order to provide a flat or shallow three-dimensional curved surface, workability can be improved by attaching a film having releasability. Release tapes with a pre-applied adhesive on one side of the film are available on the market, so you can work more easily with this, and if it is a film with a release paper liner, use an automatic cutting machine in advance. It can also be used for mass production by cutting into two.

深い3次元曲面や広い面積に離型層を設けるには離型剤を塗布するか、あるいは離型性を有する塗料を塗布して、乾燥させることにより塗膜を構成する方が作業性がよい。離型剤や塗料を使用する場合には、塗布前に接着部分を予めマスキングしておき、離型剤や塗料が付着しないように注意する必要がある。離型剤や離型性のある塗料が接着部分に付着すると接着強度が著しく低下するためである。また、離型剤や塗料は熱風乾燥機や赤外線ヒータ、または自然乾燥などの方法を用いて充分に乾燥させておく必要がある。乾燥が不充分であると、後から塗布された接着剤に溶け込み接着剤の強度を低下させてしまう恐れがあるためである。   In order to provide a release layer on a deep three-dimensional curved surface or a large area, it is better to apply a release agent or to apply a release paint and dry it to form a coating film. . When using a release agent or paint, it is necessary to mask the adhesive portion in advance before application so that the release agent or paint does not adhere. This is because when a release agent or a releasable paint adheres to the bonded portion, the adhesive strength is remarkably reduced. Moreover, it is necessary to dry the release agent and paint sufficiently using a hot air dryer, an infrared heater, or a method such as natural drying. This is because if the drying is insufficient, the adhesive may be dissolved in the adhesive applied later and the strength of the adhesive may be reduced.

フィルムや塗料を使用する場合、充分な離型性を有するものを選択する必要がある。離型性の指標としては水との接触角を用いることが簡便である。一般的な接着剤に対する必要な離型性は水との接触角が75°以上である。水との接触角が75°以下であると接着剤と接着する場合が生じてしまい、外観の歪みを防止することができなくなることがある。具体的な材料の例として、フィルムの場合はPTFE(ポリテトラフルオロエチレン)やFEP(テトラフロオロエチレン−ヘキサフロオロプロピレン共重合体)、PFA(テトラフロオロエチレン−パーフロオロアルキルビニルエーテル共重合体),ETFE(テトラフロオロエチレン−エチレン共重合体)などのフッ素樹脂、ポリエチレンやポリプロピレンなどのポリオレフィンなどが挙げられ、塗料の場合はシリコン系、フッ素系、無機系などの塗料が挙げられる。また、フィルムを用いる場合にはフィルムと外側パネル部材または内側パネル部材との間の粘着剤を調整し、フィルム幅25mm当たり4N以下の力で剥がれる様にしてもよい。接着剤の収縮によりフィルムが剥がれてしまい、外側パネル部材の歪みが発生しないためである。離型剤は元々樹脂成型品と成形型との離型を目的としているものであり、熱硬化性樹脂成型用の離型剤であれば特に制限されるものではない。特にフッ素系離型剤は、接着剤への溶け込みも殆どないため好ましい。   When using a film or paint, it is necessary to select one having sufficient releasability. As an index of releasability, it is convenient to use a contact angle with water. The required releasability for a general adhesive is that the contact angle with water is 75 ° or more. If the contact angle with water is 75 ° or less, the adhesive may adhere to the adhesive, and the appearance distortion may not be prevented. Examples of specific materials include PTFE (polytetrafluoroethylene), FEP (tetrafluoroethylene-hexafluoropropylene copolymer), and PFA (tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer) in the case of a film. ), ETFE (tetrafluoroethylene-ethylene copolymer) and the like, and polyolefins such as polyethylene and polypropylene. In the case of paints, silicone-based, fluorine-based and inorganic-based paints are listed. Moreover, when using a film, you may make it peel with the force of 4 N or less per film width 25mm by adjusting the adhesive between a film and an outer side panel member or an inner side panel member. This is because the film is peeled off due to the shrinkage of the adhesive and the outer panel member is not distorted. The release agent is originally intended to release the resin molded product and the mold, and is not particularly limited as long as it is a release agent for thermosetting resin molding. In particular, a fluorine-based mold release agent is preferable because it hardly dissolves in the adhesive.

特に離型層にフィルムを採用する場合、内側パネルと外側パネルとの接着層の厚みをt1、離型層の厚みをt2とすると、t1とt2の関係が以下の式を満足することが好ましい。なお、内側パネルと外側パネルとの接着層、離型層の厚みに分布が存在する場合は、理想的には、接着層、離型層の全面において以下の式を満足することが望ましいが、少なくとも接着層、離型層の平均厚みが以下の式を満足することが望ましい。また、より好ましくは、さらに、全接着層、全離型層の50%以上の領域が以下の式を満足すること、さらに好ましくは、さらに、全接着層、全離型層の80%以上の領域が以下の式を満足することである。
t2/t1≦0.6・・・(式)。
In particular, when a film is used for the release layer, it is preferable that the relationship between t1 and t2 satisfies the following formula, where the thickness of the adhesive layer between the inner panel and the outer panel is t1, and the thickness of the release layer is t2. . In addition, when there is a distribution in the thickness of the adhesive layer between the inner panel and the outer panel and the release layer, ideally, it is desirable to satisfy the following formula on the entire surface of the adhesive layer and the release layer, It is desirable that the average thickness of at least the adhesive layer and the release layer satisfy the following formula. More preferably, the region of 50% or more of the total adhesive layer and the total release layer satisfies the following formula, more preferably 80% or more of the total adhesive layer and the total release layer. The region satisfies the following formula.
t2 / t1 ≦ 0.6 (formula).

接着層厚みにおけるフィルム厚みの割合が高いと、フィルム自体が封止効果を有し、接着剤が必要範囲に延伸されることを阻害するとともに、フィルム層端面が壁となり接着剤が3次元的に周囲を引張り、応力が集中するためである。これはフィルムが基材層部分と粘着層部分の2層からなり、基材は離型効果を有するが、粘着剤と接着剤とは接着されるためである。接着層厚みを薄くすることが強度面、軽量性より好ましいと前述したが、前式を満たす範囲で接着層厚み/フィルム層厚みを選定することで、より歪みを抑えられる。   When the ratio of the film thickness in the adhesive layer thickness is high, the film itself has a sealing effect and inhibits the adhesive from being stretched to the required range, and the end face of the film layer becomes a wall and the adhesive is three-dimensionally. This is because the stress is concentrated by pulling around. This is because the film is composed of two layers of a base material layer portion and an adhesive layer portion, and the base material has a mold release effect, but the adhesive and the adhesive are bonded. As described above, it is preferable to reduce the thickness of the adhesive layer from the viewpoint of strength and light weight. However, by selecting the adhesive layer thickness / film layer thickness within the range satisfying the previous formula, the distortion can be further suppressed.

以下、実施例に基づいてさらに詳細に説明する。なお、各物性については以下の通りに測定を行った。   Hereinafter, it demonstrates still in detail based on an Example. In addition, about each physical property, it measured as follows.

[水との接触角]
接触角はθ/2法で測定した。水平に保持したサンプル上に少量の水滴を滴下し、これを真横からCCDカメラで拡大撮影した。この画像から水滴の半径rと高さhを測定し、次式により接触角θを求めた。
θ=2tan−1(h/r)。
[Contact angle with water]
The contact angle was measured by the θ / 2 method. A small amount of water droplets were dropped on the horizontally held sample, and this was magnified by a CCD camera from the side. The radius r and height h of the water droplet were measured from this image, and the contact angle θ was determined by the following equation.
θ = 2 tan −1 (h / r).

[フィルム幅25mm当たりの引き剥がし力]
引き剥がし力はJIS Z 0237(2000)に規定の180°引き剥がし法に準じて測定した。テープ幅は25mmとし、CFRPの板にこのテープを貼り付け、試験片を準備した。試験には万能試験機を用い、テープの先端とCFRPをそれぞれチャックして、テープが180°折り返えされる方向に300mm/分の速度で引き剥がしたときの力を測定した。
[Stripping force per 25 mm film width]
The peeling force was measured according to the 180 ° peeling method defined in JIS Z 0237 (2000). The tape width was set to 25 mm, and this tape was attached to a CFRP plate to prepare a test piece. A universal testing machine was used for the test, the tip of the tape and the CFRP were chucked, and the force when the tape was peeled off at a speed of 300 mm / min in the direction in which the tape was folded back 180 ° was measured.

各実施例、比較例においては、図5に示す形状の外側パネル部材と図6に示す形状の内側パネル部材を接着接合してなるCFRP製自動車ボンネットフードを成形し、このボンネットフードの表面に写り込む蛍光灯の像の歪みの具合を目視で観察して比較した。また、このボンネットフードの一部分を10mm幅に切り出し、接着部分に引き剥がし力を加えて破壊の様子を比較した。   In each of the examples and comparative examples, a CFRP automobile bonnet hood formed by adhesively bonding the outer panel member having the shape shown in FIG. 5 and the inner panel member having the shape shown in FIG. 6 is formed, and is reflected on the surface of the hood. The degree of distortion of the image of the fluorescent lamp was visually observed and compared. Moreover, a part of this bonnet hood was cut out to a width of 10 mm, and the state of destruction was compared by applying a peeling force to the bonded portion.

実施例および比較例には、材料として、炭素繊維としては引張強さ4.9GPaのPAN系炭素繊維を目付200g/m、300g/mに平織りした2種類の織物、マトリックス樹脂としてはRTM成形用に調合された低粘度エポキシ樹脂、接着剤は加熱硬化型の2液混合ウレタン接着剤を用いた。 In Examples and Comparative Examples, as materials, two kinds of woven fabrics in which a PAN-based carbon fiber having a tensile strength of 4.9 GPa as a carbon fiber is plain woven to a basis weight of 200 g / m 2 and 300 g / m 2, and RTM as a matrix resin are used. A low-viscosity epoxy resin and an adhesive prepared for molding were heat-curable two-component mixed urethane adhesives.

また、外側パネル部材および内側パネル部材は以下の方法で成型した。   The outer panel member and the inner panel member were molded by the following method.

まず炭素繊維織物を外側パネル部材の形状に切り出し、離型剤を塗布した雌型の上に車体の前後方向に対して0°/90°、±45°、±45°、0°/90°の順に4枚積層した。この上に、ピールプライとしてポリエステルタフタを置き、さらにポリプロピレン製のネットを置いた。さらに、概略の製品形状にあわせたカウルプレートを置き、内部の空気を抜くためのホースと樹脂を注入するためのホースをセットした後、全体をナイロン製バッグフィルムで覆った。   First, the carbon fiber fabric is cut into the shape of the outer panel member, and 0 ° / 90 °, ± 45 °, ± 45 °, 0 ° / 90 ° with respect to the longitudinal direction of the vehicle body on the female die coated with the release agent. 4 sheets were laminated in this order. A polyester taffeta was placed thereon as a peel ply, and a polypropylene net was further placed thereon. Further, a cowl plate adapted to the approximate product shape was placed, a hose for extracting the air inside and a hose for injecting resin were set, and then the whole was covered with a nylon bag film.

次に、内部の空気を抜いて真空状態とした後、樹脂注入用ホースからエポキシ樹脂を吸引させ、樹脂が行き渡った状態で真空用、樹脂注入用それぞれのホースを折り曲げて樹脂を封入し、樹脂が硬化するまで1時間放置した。なお、このとき金型の温度は85℃になるよう温水を循環させることにより加熱しておいた。樹脂が硬化後、バッグフィルムをはぎ取り、さらにカウルプレート、ネット、ピールプライをはぎ取った後、成形品を型から取り外し、外側パネル部材を得た。次に内側パネル部材パネル部材も同様の方法で成型した。得られた外側パネルは平均厚みが1.3mm、内側パネルは1.1mmであった。   Next, after the inside air is evacuated to make a vacuum state, the epoxy resin is sucked from the resin injection hose, and the resin is sealed by bending the vacuum and resin injection hoses with the resin spread. It was left for 1 hour until it cured. At this time, the mold was heated by circulating hot water so that the temperature of the mold was 85 ° C. After the resin was cured, the bag film was peeled off, the cowl plate, the net, and the peel ply were peeled off, and then the molded product was removed from the mold to obtain an outer panel member. Next, the inner panel member panel member was also molded by the same method. The obtained outer panel had an average thickness of 1.3 mm and the inner panel was 1.1 mm.

(実施例1)
成型した外側パネル部材の接着位置に隣接してPTFE製フィルムの片面に粘着剤と塗布した粘着テープを貼り付けた。この粘着テープの水に対する接触角は108°であり、該部材との引き剥がし力は25mmのテープ幅で9.1Nであった。この外側パネルの接着位置に専用の混合吐出装置を用いて接着剤を塗布した。このとき、接着剤の吐出量は毎分250gに設定し、吐出ガンを1m当たり8秒の速さで動かした。この外側パネル部材を成型に使用した型に載せ、さらに内側パネル部材を被せ、これらをフィルムで覆ったあと、砂袋を350kg分載せた。5分後一旦砂袋とフィルムをおろし、内側パネル部材の外側にはみ出した接着剤を掻き取った後、もう一度フィルムと砂袋を載せ、1時間硬化させた。このとき、金型の温度は60℃に調整しておいた。
Example 1
Adhesive tape coated with an adhesive was attached to one side of the PTFE film adjacent to the bonding position of the molded outer panel member. The contact angle of this pressure-sensitive adhesive tape with respect to water was 108 °, and the peeling force with the member was 9.1 N with a tape width of 25 mm. Adhesive was applied to the bonding position of the outer panel using a dedicated mixing and discharging device. At this time, the discharge amount of the adhesive was set to 250 g per minute, and the discharge gun was moved at a speed of 8 seconds per meter. This outer panel member was placed on a mold used for molding, further covered with an inner panel member, covered with a film, and then 350 kg of sand bags were placed thereon. After 5 minutes, the sand bag and the film were once removed, the adhesive protruding outside the inner panel member was scraped off, and then the film and sand bag were placed again and cured for 1 hour. At this time, the temperature of the mold was adjusted to 60 ° C.

得られた自動車用ボンネットフードの外観は美しい仕上がりであり、表面に蛍光灯を写し込んでも像が歪むことはなかった。さらに、この自動車用ボンネットフードの端部付近から接着部分をダイヤモンドカッターで幅25mmに切り出し、万能試験機で引き剥がし試験を行ったところ、荷重530Nにおいて接着剤ではなく内側パネル部材が破壊した。   The appearance of the resulting hood hood for automobiles was a beautiful finish, and the image was not distorted even when a fluorescent lamp was projected on the surface. Furthermore, when the bonded portion was cut out with a diamond cutter to a width of 25 mm from the vicinity of the end portion of the hood hood for automobiles, and peeled off with a universal testing machine, the inner panel member, not the adhesive, was destroyed at a load of 530N.

(実施例2〜6、比較例1〜3)
実施例1と同様に、表1に示す様に離型層の種類を変更して実施例2から比較例3を製作し、観察、試験を行った。
(Examples 2-6, Comparative Examples 1-3)
In the same manner as in Example 1, the type of the release layer was changed as shown in Table 1 to produce Comparative Example 3 from Example 2 and observed and tested.

実施例2ではPE(ポリエチレン)製フィルムに粘着剤を貼り合わせた粘着テープを用いたが、実施例1と同様に表面に写り込んだ蛍光灯の像は歪むことはなかった。PEテープの水との接触角も94°であり接着剤と離型する硬化が充分に確保できるためである。   In Example 2, an adhesive tape in which an adhesive was bonded to a PE (polyethylene) film was used. As in Example 1, the image of the fluorescent lamp reflected on the surface was not distorted. This is because the contact angle of the PE tape with water is 94 °, and sufficient curing for releasing from the adhesive can be secured.

実施例3ではPET(ポリエステル)製フィルムの片面に低粘着力の粘着剤を貼り合わせた粘着テープを使用したが、実施例1と同様に表面に写り込んだ蛍光灯の像は歪むことはなかった。このフィルムの水との接触角は70°であったが、粘着力は25mm幅で3.1Nと低かったため、接着剤の収縮による力のために粘着剤が外側パネル部材と剥がれ、実質的に接着剤と外側パネル部材が接着していなかったためである。   In Example 3, an adhesive tape in which a low adhesive strength adhesive was bonded to one side of a PET (polyester) film was used, but the fluorescent lamp image reflected on the surface was not distorted as in Example 1. It was. Although the contact angle with water of this film was 70 °, the adhesive strength was as low as 3.1 N with a width of 25 mm, so that the adhesive peeled off from the outer panel member due to the force due to the shrinkage of the adhesive, This is because the adhesive and the outer panel member were not bonded.

実施例4では成型した外側パネル部材の接着位置に隣接して、フッ素系離型剤を塗布した。離型剤を塗布する前には接着する箇所に離型剤が付着しないようマスキングテープで養生しておき、離型剤を塗布した後にこのマスキングテープを剥がした。さらに乾燥のため85℃に加熱された金型の上にのせ、1時間放置した。この後実施例1と同様の手順で内側パネル部材を接着し外観を観察したところ、表面に写り込んだ蛍光灯の像は歪むことはなかった。   In Example 4, a fluorine-based mold release agent was applied adjacent to the bonding position of the molded outer panel member. Before applying the release agent, it was cured with a masking tape so that the release agent did not adhere to the part to be bonded. After applying the release agent, the masking tape was peeled off. Furthermore, it was put on the metal mold | die heated at 85 degreeC for drying, and was left to stand for 1 hour. Thereafter, the inner panel member was bonded in the same procedure as in Example 1 and the appearance was observed. The image of the fluorescent lamp reflected on the surface was not distorted.

実施例5では成型した外側パネル部材の接着位置に隣接して、フッ素系塗料を塗布した。塗料を塗布する前には接着する箇所に塗料が付着しないようマスキングテープで養生しておき、塗料を刷毛で塗布した後にこのマスキングテープを剥がした。さらに常温で3時間乾燥したあと、85℃に加熱された金型の上にのせ、3時間放置した。この後実施例1と同様の手順で内側パネル部材を接着し外観を観察したところ、表面に写り込んだ蛍光灯の像は歪むことはなかった。   In Example 5, a fluorine-based paint was applied adjacent to the bonding position of the molded outer panel member. Before applying the paint, it was cured with a masking tape so that the paint would not adhere to the part to be adhered, and after applying the paint with a brush, the masking tape was peeled off. Furthermore, after drying at room temperature for 3 hours, it was placed on a mold heated to 85 ° C. and left for 3 hours. Thereafter, the inner panel member was bonded in the same procedure as in Example 1 and the appearance was observed. The image of the fluorescent lamp reflected on the surface was not distorted.

実施例6では実施例2と同じPE(ポリエチレン)製フィルムに粘着剤を貼り合わせた粘着テープを用いた。ただし、粘着テープを貼る位置は外側パネル部材ではなく、内側パネル部材接着位置に隣接して貼り付けたが、実施例1と同様に表面に写り込んだ蛍光灯の像は歪むことはなかった。   In Example 6, an adhesive tape in which an adhesive was bonded to the same PE (polyethylene) film as in Example 2 was used. However, the position where the adhesive tape was applied was not the outer panel member but was attached adjacent to the inner panel member adhesion position, but the fluorescent lamp image reflected on the surface was not distorted as in Example 1.

比較例1ではフィルムなどの離型層を設けなかった。製作した自動車用ボンネットフードに写り込んだ蛍光灯の光は、接着部の境界部で曲がって見えた。   In Comparative Example 1, a release layer such as a film was not provided. The fluorescent light reflected in the hood hood for automobiles was bent at the boundary of the adhesive.

比較例2はPET製フィルムの片面に粘着剤を塗布した粘着テープを用いたところ、製作した自動車用ボンネットフードに写り込んだ蛍光灯の光が、接着部の境界部で曲がって見える部分と、曲がらない部分が混在していた。   Comparative Example 2 uses a pressure-sensitive adhesive tape coated with a pressure-sensitive adhesive on one side of a PET film, and the portion of the fluorescent light reflected in the manufactured automobile hood hood appears to bend at the boundary of the adhesive portion; The part which does not bend was mixed.

比較例3では実施例5と同様の手順でウレタン系塗料を使用いたが、やはり写り込んだ蛍光灯の光は曲がって見える部分が散見された。   In Comparative Example 3, a urethane-based paint was used in the same procedure as in Example 5. However, the reflected fluorescent light had some parts that look bent.

(比較例4)
図4に示すように成型した外側パネル部材の接着位置の両端に厚さ0.75mmの両面テープを貼り付けた。このとき、接着位置の幅は25mmであり、その両端に幅5mmの両面テープを貼り付けたため実質的な接着幅は15mmになった。この外側パネルの接着位置に専用の混合吐出装置を用いて、接着剤の吐出量を毎分125gに設定し、吐出ガンを1m当たり6秒の速さで接着剤を塗布した。接着剤の塗布量は、実質的な接着幅15mmと両面テープの厚さ0.75mmで作る空間を完全に埋めるためには、接着長さ1m当たり15gの接着剤が必要になるが、塗布量のバラツキがあっても接着剤をはみ出させないために、接着剤塗布量を接着長さ1m当たり12.5gとした。この外側パネル部材を成型に使用した型に載せ、さらに内側パネル部材を被せ、これらをフィルムで覆ったあと、砂袋を350kg分載せた。5分後一旦砂袋とフィルムをおろし、接着剤のはみ出しを確認したが接着剤ははみ出していなかった。さらに、もう一度フィルムと砂袋を載せ、1時間硬化させた。このとき、金型の温度は60℃に調整しておいた。得られた自動車用ボンネットフードの表面に蛍光灯を写し込んでも像が歪むことはなかったが、実施例1と同様に接着部分を切り出し、万能試験機で引き剥がし試験を行ったところ、荷重250Nにおいて接着剤部分が破壊した。破壊した面を観察すると接着剤にCFRPが黒く付着した部分と、CFRPが付着せず光沢を有した部分がおよそ半分ずつ見られた。光沢のある部分はCFRPと接着されず、空気に触れた状態で固まったものである。実施例では接着幅25mmが全て接着していたのに対し、比較例4では実質的な接着幅15mmの半分程度しか接着していなかったため、7.5mm分しか有効に接着されていなかった。
(Comparative Example 4)
A double-sided tape having a thickness of 0.75 mm was affixed to both ends of the bonding position of the molded outer panel member as shown in FIG. At this time, the width of the bonding position was 25 mm, and a double-sided tape having a width of 5 mm was attached to both ends thereof, so that the substantial bonding width was 15 mm. Using an exclusive mixing and discharging device at the bonding position of the outer panel, the discharge amount of the adhesive was set to 125 g / min, and the adhesive was applied to the discharge gun at a speed of 6 seconds per meter. The amount of adhesive applied is 15 g per 1 m of adhesive length to completely fill the space created by a substantial adhesive width of 15 mm and a double-sided tape thickness of 0.75 mm. In order to prevent the adhesive from protruding even if there is a variation in the thickness of the adhesive, the amount of adhesive applied was 12.5 g per meter of adhesive length. This outer panel member was placed on a mold used for molding, further covered with an inner panel member, covered with a film, and then 350 kg of sand bags were placed thereon. After 5 minutes, the sand bag and the film were once unloaded, and the protruding adhesive was confirmed, but the adhesive did not protrude. Further, a film and a sand bag were placed again and cured for 1 hour. At this time, the temperature of the mold was adjusted to 60 ° C. Although the image was not distorted even when a fluorescent lamp was imprinted on the surface of the obtained hood hood for automobiles, the bonded portion was cut out in the same manner as in Example 1, and the peel test was performed with a universal testing machine. The adhesive part broke down. When the broken surface was observed, a portion where the CFRP adhered to the adhesive in black and a portion where the CFRP did not adhere and had a gloss were found approximately half each. The glossy part is not adhered to the CFRP and is solidified in contact with air. In the example, all of the bonding width of 25 mm was bonded, whereas in Comparative Example 4, only about half of the substantial bonding width of 15 mm was bonded, and therefore only 7.5 mm was effectively bonded.

Figure 0005176564
Figure 0005176564

(実施例7)
成型した外側パネル部材の接着位置に隣接してPE(ポリエチレン)製フィルムの片面に粘着剤を塗布した粘着テープを貼り付けた。テープ厚みは約0.3mmであった。外側パネル、内側パネルともに接着位置はサンディングを行った。この外側パネルの接着位置に専用の混合吐出装置を用いて接着剤を塗布した。このとき、接着剤の吐出量は毎分250gに設定し、吐出ガンを1m当たり8秒の速さで動かした。
(Example 7)
Adhesive tape coated with an adhesive was applied to one side of a PE (polyethylene) film adjacent to the adhesion position of the molded outer panel member. The tape thickness was about 0.3 mm. The outer panel and inner panel were sanded at the bonding position. Adhesive was applied to the bonding position of the outer panel using a dedicated mixing and discharging device. At this time, the discharge amount of the adhesive was set to 250 g per minute, and the discharge gun was moved at a speed of 8 seconds per meter.

接着はプレス装置に上下型構造からなる接着型を組み付け、外側パネル部材と内側パネル部材とを接着型にセットしプレスさせることで接着させた。この時、接着層厚みは上下型間のクリアランスで任意で設定できたため接着層厚み0.5mm、1.0mmを狙った2水準で接着した。   Adhesion was performed by assembling an adhesive mold having an upper and lower mold structure in a press apparatus, and setting the outer panel member and the inner panel member to the adhesive mold and pressing them. At this time, since the adhesive layer thickness could be arbitrarily set by the clearance between the upper and lower molds, the adhesive layers were bonded at two levels aiming at the adhesive layer thicknesses of 0.5 mm and 1.0 mm.

接着5分後一旦内側パネル部材の外側にはみ出した接着剤を掻き取った後、もう一度接着型に戻し、1時間硬化させた。この時、金型の温度は60℃に調整しておいた。脱型後100℃程度でアフターキュアを行い、接着剤を完全硬化させた。   After 5 minutes of adhesion, the adhesive that protruded to the outside of the inner panel member was scraped off, then returned to the adhesive mold and cured for 1 hour. At this time, the temperature of the mold was adjusted to 60 ° C. After demolding, after-curing was performed at about 100 ° C. to completely cure the adhesive.

得られた接着層厚みを0.5mmに設定したフードは、外側パネルと内側パネルとの接着位置に対応する表面部分に写り込んだ蛍光灯に歪みが発生していた。しかし、接着層厚み1.0mmに設定したフードには、外側パネルと内側パネルとの接着位置に対応する表面部分に写り込んだ蛍光灯に歪みは見受けられなかった。   In the obtained hood with the adhesive layer thickness set to 0.5 mm, the fluorescent lamp reflected in the surface portion corresponding to the adhesion position between the outer panel and the inner panel was distorted. However, in the hood set to have an adhesive layer thickness of 1.0 mm, no distortion was observed in the fluorescent lamp reflected on the surface portion corresponding to the adhesion position between the outer panel and the inner panel.

歪み部周辺の断面を観察したところ、接着層を0.5mmに設定したフードは、実測で接着層厚みが0.3〜0.5mmで、広範囲においてPEテープと内側パネルとの距離が極めて近い/接触している箇所が見受けられ部分的に接着剤はみ出し量が不足していた。また、蛍光灯の歪みが発生していた位置に対応する断面位置は、接着位置側のPEテープ端部周辺であった。接着層を1.0mmに設定したフードは実測で接着層厚みが0.7〜0.9mm程度であった。   When the cross section around the strained part was observed, the hood with the adhesive layer set to 0.5 mm had a measured adhesive layer thickness of 0.3 to 0.5 mm, and the distance between the PE tape and the inner panel was extremely close over a wide range. / The place where it contacted was seen and the adhesive protrusion amount was partially insufficient. The cross-sectional position corresponding to the position where the fluorescent lamp was distorted was around the edge of the PE tape on the bonding position side. The hood with the adhesive layer set to 1.0 mm had an adhesive layer thickness of about 0.7 to 0.9 mm by actual measurement.

Figure 0005176564
Figure 0005176564

本発明に係るは、CFRP製パネル構造体は、自動車用のボンネットフードやドア、屋根などの自動車外板パネルに適用して特に好適な物であるが、本発明の適用範囲はこれらに限られるものではない。   The CFRP panel structure according to the present invention is particularly suitable when applied to an automobile outer panel such as a hood hood, a door, or a roof for automobiles, but the scope of application of the present invention is limited to these. It is not a thing.

従来のCFRP製パネル構造体の横断面の一例。An example of the cross section of the conventional panel structure made from CFRP. 従来のCFRP製パネル構造体の横断面の変形の一例を示す模式図。The schematic diagram which shows an example of the deformation | transformation of the cross section of the conventional panel structure made from CFRP. 本発明に係るCFRP製パネル構造体(離型層を外側パネル部材の内側パネル部材のフランジ部に相対する領域の外縁部に設けた場合)の横断面の一例。An example of the cross section of the panel structure made from CFRP which concerns on this invention (when a mold release layer is provided in the outer edge part of the area | region facing the flange part of the inner side panel member of an outer side panel member). 本発明に係るCFRP製パネル構造体(離型層を内側パネル部材のフランジ部に隣接した部分に設けた場合)の横断面の一例。An example of the cross section of the panel structure made from CFRP which concerns on this invention (when a mold release layer is provided in the part adjacent to the flange part of an inner side panel member). 実施例に係る外側パネル部材の斜視図。The perspective view of the outer side panel member which concerns on an Example. 実施例に係る内側パネル部材の斜視図。The perspective view of the inner side panel member which concerns on an Example.

符号の説明Explanation of symbols

1:外側パネル部材
2:内側パネル部材
3:接着剤
3a:内側パネル部材のフランジ部と外側パネル部材が互いに相対した部分
3b:内側パネル部材のR部分に接着剤がはみ出した部分
3c:外側パネル部材の内側パネル部材のフランジ部に相対する領域の外縁部
3d:内側パネル部材のフランジ部に隣接した部分
4:離型層
1: Outer panel member 2: Inner panel member 3: Adhesive 3a: A portion where the flange portion and the outer panel member of the inner panel member face each other 3b: A portion where the adhesive protrudes from the R portion of the inner panel member 3c: Outer panel Outer edge portion of region opposite to flange portion of inner panel member of member 3d: Portion adjacent to flange portion of inner panel member 4: Release layer

Claims (7)

少なくとも一部にフランジ部と立ち壁部を有するハット型形状の内側パネル部材と外側パネル部材とが接着されてなるパネル構造体であって、外側パネル部材の内側パネル部材のフランジ部に相対する領域の外縁部 または/および 内側パネル部材のフランジ部に隣接した部分に離型層を有することを特徴とする炭素繊維強化プラスチック製パネル構造体。 A panel structure in which a hat-shaped inner panel member and an outer panel member each having a flange portion and a standing wall portion at least in part are bonded to each other, and is a region facing the flange portion of the inner panel member of the outer panel member A panel structure made of carbon fiber reinforced plastic having a release layer at a portion adjacent to the flange portion of the inner panel member and / or the inner panel member. 前記離型層がフィルムを接着したものであることを特徴とする、請求項1に記載の炭素繊維強化プラスチック製パネル構造体。 The panel structure made of carbon fiber reinforced plastic according to claim 1, wherein the release layer is formed by adhering a film. 内側パネルと外側パネルとの接着層の厚みをt1、離型層の厚みをt2とすると、t1とt2の関係が以下の式を満足することを特徴とする、請求項1または2に記載の炭素繊維強化プラスチック製パネル構造体。
t2/t1≦0.6・・・(式)。
The relationship between t1 and t2 satisfies the following expression, where t1 is the thickness of the adhesive layer between the inner panel and the outer panel, and t2 is the thickness of the release layer. Carbon fiber reinforced plastic panel structure.
t2 / t1 ≦ 0.6 (formula).
前記フィルムの水との接触角が75°以上であることを特徴とする、請求項2に記載の炭素繊維強化プラスチック製パネル構造体。 The carbon fiber reinforced plastic panel structure according to claim 2, wherein a contact angle of the film with water is 75 ° or more. 前記フィルムと外側パネル部材との間引き剥がし力 または/および 前記フィルムと内側パネル部材との間引き剥がし力がフィルム幅25mm当たり4N以下であることを特徴とする、請求項2〜4のいずれかに記載の炭素繊維強化プラスチック製パネル構造体。 5. The stripping force between the film and the outer panel member or / and the stripping force between the film and the inner panel member is 4 N or less per 25 mm of film width, according to claim 2. Carbon fiber reinforced plastic panel structure. 前記離型層が離型剤であることを特徴とする、請求項1に記載の炭素繊維強化プラスチック製パネル構造体。 2. The carbon fiber reinforced plastic panel structure according to claim 1, wherein the release layer is a release agent. 前記離型層が塗膜であり、前記塗膜の水との接触角が75°以上であることを特徴とする、請求項1に記載の炭素繊維強化プラスチック製パネル構造体。 The carbon fiber-reinforced plastic panel structure according to claim 1, wherein the release layer is a coating film, and the contact angle of the coating film with water is 75 ° or more.
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